CN1183463A - Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof - Google Patents
Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof Download PDFInfo
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- CN1183463A CN1183463A CN 97103607 CN97103607A CN1183463A CN 1183463 A CN1183463 A CN 1183463A CN 97103607 CN97103607 CN 97103607 CN 97103607 A CN97103607 A CN 97103607A CN 1183463 A CN1183463 A CN 1183463A
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Abstract
A durable composition for disinfecting, cleaning and deodourising toilet is prepared from non-ionic surfactant, anionic surfactant, metallic salt, oxide, dye, essence and water. After 15-20 g of such composition is put in cistern, it can play its role for one month. It does not corrode drainage pipeline and pollute environment.
Description
The invention relates to a kind of cleaning composition, more especially substitute the liquid product that contains hydrochloric acid, aqueous sulfuric acid flushing water closet pan about a kind of, but solid shape composition product.International Classification of Patents is D06L1/100.
In the prior art, relevant cleaning composition patent report is more, in the relevant patent information report of U.S. chemical abstract and China just relevant for the patent of washing water closet pan, but majority is a flowing product, for the hydrochloric acid or the vitriolic aqueous solution, add water-soluble metal inhibitor, tensio-active agent and essence, dyestuff.Though also have plenty of the product of solid shape, contain more anion surfactant and a large amount of class materials such as phosphoric acid salt.Each ball is heavy up to being not less than 50 grams.Usage period is short, just water closet pan is no longer produced scale removal, sterilization and disinfection, de-odorised effect in 20 days at the most with several days.
One of purpose of the present invention is that preparation weight only can be soaked in water tank 30-35 days for 15-20 restrains, and can use 12-15 time solids every day, and its principle is that calcium, the magnesium ion that composition makes hard water can not be deposited on the water closet pan surface, and is dashed to water drain.
Two of the object of the invention is a kind of Gram-negative bacterias that can kill in the water closet pan of preparation, and gram-positive microorganism also can be killed the treponema pallidum that causes syphilis; Cause the gonorrhoea bacterium of gonorrhoea.
Three of purpose of the present invention is a kind of compositions that can remove the water closet pan stink of preparation.Its principle is can kill the insatiable hunger that makes in the ight soil to close the lipid acid fermentation and the different oxygen bacterium of generation stink.
Advantage of the present invention will further be illustrated by following specific descriptions.
Composition of the present invention contains the nonionogenic tenside of (weight) 4.6%-40.0%, the anion surfactant of (weight) 3.34%-77.12%, the sodium salt of the sterilant of (weight) 0.1%-15% and (weight) 0.1%-8%, the oxide compound of (weight) 2.3%-5.0%, (weight) 6%-39% dyestuff, the essence of surplus and water.
In the present invention, if not refer in particular to, the nonionogenic tenside of composition (weight) 4.6%-30.0% preferably, the anion surfactant of (weight) 9.2%-55.0%, the sodium salt of the sterilant of (weight) 0.1%-5.0% and (weight) 0.1%-6.5%, (weight) 6.0-10.0% dyestuff, 2.3%-5.0% oxide compound, the essence of surplus and water.
In the present invention, nonionogenic tenside can be the tensio-active agent of polyethylene glycol type: C
12Aliphatic alcohol polyethenoxy (4) ether, C
12Aliphatic alcohol polyethenoxy (3) ether, C
12Aliphatic alcohol polyethenoxy (7) ether or C
12Aliphatic alcohol polyethenoxy (9) ether, or C
12-18Aliphatic alcohol polyethenoxy (10) ether, or aliphatic alcohol polyethenoxy (15) ether, or aliphatic alcohol polyethenoxy (20) ether, or styryl phenyl Soxylat A 25-7.More than can use with, also can use separately.If use the polyethylene glycol type tensio-active agent with: the ratio of EPE polyol EPE is 27: 1.
In the present invention, operable anion surfactant be alkylbenzene sulfonate, higher alcohols sulfuric acid ,-alkene sulfonate and metallic soap salt etc.Above material can mix use, also can use separately.The ratio best with composition is 25: 1.
In the present invention, alternative sterilant is cresols and isomers thereof: (1) meta-cresol (2) ortho position cresols (3) paracresol, tetramethylthiuram disulfide, 2-sec.-propyl-5-methylphenol, or copper sulfate, sulphur or cyhexatin, oxinecopper, dichloroisopropyl ether, 1.2-dibromochloropropane, organochlorine insecticide 4,5,6,7 ,-phthalide, santochlor, a chlorobenzene, ortho position chlorobenzene, 4,4 ,-three chloro-trihydroxy-phenyl ether.Best ratio is 0.1%-5.0%.
In the present invention, alternative dyestuff is acid lake blue 5R, the gorgeous blue GAW of slightly acidic, and neutral blue BNLP, direct light turquoise blue GL, EX-SF DISPERSE BLUE EX-SF 300 can be mixed use, also can use separately.Best ratio is 6.0%-10.0%.In the present invention, alternative metal sodium salt is a sodium phosphate salt, sodium sulfate salt, sodium carbonate salt, disodium ethylene diamine tetraacetate.Can mix use, also can use separately.Best ratio is 0.1%-6.5%.In the present invention, all compositions all can be bought to market, or according to the common expertise of chemist, easy manufacture can make.Some relevant professional books are introduced by reference at this.
Composition of the present invention prepares by following method.
At first with the nonionogenic tenside of weighing, anion surfactant, salt is put into reactor, at this reactor can be metal or thermally resistant container, enamel reaction still in the preferably commercially available jacketed type is heated to 65 ℃-95 ℃, is incubated 2 hours, put into dyestuff then, essence, sterilant, oxide compound and excess water are cooled to 0 ℃-30 ℃, taking-up pours into mould inner pressure and makes shape, can make product of the present invention.
Product of the present invention is put into water tank, through 5 minutes, emits the blue aqueous solution to water closet pan, anti-caking urine dirt, and sterilization and disinfection, deodorize, the heavy 15-20 gram of product can use about 30 days, and use 12-15 average every day.
Below to further specify the embodiment of the invention by specific embodiment be to explanation of the present invention, do not place restrictions on scope in claim.
Example 1 takes by weighing the nonionogenic tenside of 10.15Kg, the anion surfactant of 40.40Kg, the sodium salt of 3.20Kg, put into reactor, heat 65 ℃-95 ℃, be incubated 2 hours, add the sterilant of 1.55Kg then, 2.66Kg oxide compound, 6.05Kg dyestuff, 0.05Kg essence and water 0.6Kg.Stir, be cooled to 30 ℃, take out and pour into the mould coagulation forming, make product of the present invention.
Example 2-6
| Embodiment numbering/weight (Kg) | 2 | ?3 | ?4 | ?5 | ?6 |
| Nonionogenic tenside | 4.60 | ?4.61 | ?4.62 | ?4.80 | ?4.81 |
| Anion surfactant | 40.60 | ?40.80 | ?40.85 | ?41.0 | ?41.50 |
| The metal sodium salt | 7.60 | ?7.80 | ?7.90 | ?8.00 | ?8.20 |
| Dyestuff | 8.55 | ?8.89 | ?8.90 | ?8.95 | ?9.00 |
| Sterilant | 2.10 | ?2.40 | ?2.50 | ?2.60 | ?2.90 |
| Oxide compound | 3.20 | ?3.70 | ?3.80 | ?3.90 | ?4.00 |
| Essence | 0.50 | ?0.60 | ?0.70 | ?0.75 | ?0.80 |
| Water | 0.70 | ?0.75 | ?0.80 | ?0.85 | ?0.90 |
Those skilled in the art are according to content disclosed by the invention, can make many variations, for example wash clothes smeary block and liquid object, chopsticks disinfectant block and liquid object wash the dishes, the block and the liquid object of washing machine and hard surface detergent and disinfection, workman's flush away is greasy dirt and disinfectant block and liquid object etc. on hand, all should understand within the scope of the invention, limited by claim of the present invention.
Claims (13)
1. long-acting, the sterilization and disinfection of flushing water closet pan, scale removal, de-odorised composition, it is characterized in that containing the nonionogenic tenside of (weight) 4.6%-40.0%, the anion surfactant of (weight) 3.34%-77.12%, the sodium salt of the sterilant of (weight) 0.1%-15.0% and (weight) 0.1%-8.0%, the oxide compound of (weight) 2.3%-5.0%, (weight) 6.0%-39.0% dyestuff, the essence of surplus and water.
2. composition as claimed in claim 1, it is characterized in that containing preferably the nonionogenic tenside of (weight) 4.6%-4.83%, the anion surfactant of (weight) 73.36%-74.10%, the sterilant of (weight) 0.1%-5.0%, the dyestuff of 6.0%-39.0%, the oxide compound of 2.3%-5.0%, 0.1%-8.0% metal sodium salt and surplus essence and water.
3. composition as claimed in claim 1 is characterized in that as wherein nonionogenic tenside can be the tensio-active agent of polyethylene glycol type: C
12Aliphatic alcohol polyethenoxy (4) ether:
R-O-(CH
2CH
2O)
4-H R=C
12, C
11-13, C
12-18Or C
12Aliphatic alcohol polyethenoxy (3) ether
R-O-(CH
2CH
2O)
3-H R=C
12, C
11-13, C
12-18Or C
12Aliphatic alcohol polyethenoxy (7) ether
R-O-(CH
2CH
2O)
7-H R=C
12, C
11-13, C
12-18Or C
12Aliphatic alcohol polyethenoxy (9) ether
R-O-(CH
2CH
2O)
9-H R=C
12, C
11-13, C
12-18Or C
12-18Aliphatic alcohol polyethenoxy (10) ether
R-O-(CH
2CH
2O)
10-H R=C
12-18Or aliphatic alcohol polyethenoxy (15) ether
R-O-(CH
2CH
2O)
15-H R=alkyl or aliphatic alcohol polyethenoxy (20) ether
R-O-(CH
2CH
2O)
20-H R=C
12-18Alkyl or styryl phenyl Soxylat A 25-7
Or alkyl phenol formaldehyde resin polyoxyethylene ether
N=n
1+ n
2=20 R=C
8-9Or polyoxypropylene glyceryl ether
N=n wherein
1+ n
2+ n
3Or polysiloxane-many alkoxyl groups ether copolymer
The P+Q=n+m nonionogenic tenside can also be the fatty acid amide type, as:
Non-ionic surfactant, can also be for the polyvalent alcohol type, as polyols such as glycerine tetramethylolmethane, Sorbitol Powder, anhydrosorbitols, with the formed ester of higher aliphatic acid.
Nonionogenic tenside also can be the fatty alkanol amide type, as polyethenoxy alkanolamide.
R is a cocoyl
The polyethylene glycol type tensio-active agent, lipid acid ethylene oxide adduct and for example, polyprotonic acid ethylene oxide adduct, polyol fatty acid ethylene oxide adduct, polypropylene glycol ethylene oxide adduct or the like.Their HLB value all can be between 1.5-18.
More than these materials can use or mix use separately.
4. anion surfactant as claimed in claim 1 can be alkylbenzene sulfonate, higher alcohols sulfuric acid ,-alkene sulfonate and metallic soap salt etc.Can singly use, also can use with.
5. composition as claimed in claim 3, if its feature is when using with, and the nonionogenic tenside of polyethylene glycol type: the surfactivity of polyvalent alcohol type is 27: 1 by weight.
6. as composition as described in the claim 4, its feature when using with by weight, (alkylbenzene sulfonate+higher alcohol sulfate+-alkene sulfonate): metallic soap salt=25: 1.
7. composition according to claim 1, wherein sterilant is characterised in that and utilizes cresols and isomers thereof: (1) meta-cresol (2) ortho position cresols (3) paracresol
Sterilant also can be tetramethylthiuram disulfide
Sterilant also can be 2-sec.-propyl-5-methylphenol
Sterilant also can be sulphur S, or copper sulfate C
uSO
4 Or oxinecopper
Or dichloroisopropyl ether
Or 1,2-dibromochloropropane CH
2Br-CHBr-CH
2CL or organochlorine insecticide, as 4,5,6,7 ,-phthalide
Or santochlor
An or chlorobenzene
Or ortho position chlorobenzene
Or 2,4,4 ,-three chloro-three-dihydroxy diphenyl ether
Above sterilant is used with, also can use separately.
8. composition according to claim 1, wherein dyestuff is characterised in that and uses slightly acidic acid blue 5R
Or the gorgeous blue GAW of slightly acidic
Or neutral blue BNL
Or direct light turquoise blue GL
Or disperse bright blue
Or disperse bright blue BF
Above-mentioned substance mixes use, also can use separately.
9. composition according to claim 1, metal-salt are sodium phosphate salt, sodium sulfate salt, and sodium carbonate salt, the salt acid sodium-salt, disodium ethylene diamine tetraacetate can be mixed use, uses (weight) 0.1%-8% separately.
10. composition according to claim 1, wherein oxide compound can be calcium oxide, and strontium oxide, barium oxide, titanium dioxide, silicon-dioxide can mix use, also can use (weight) 2.3%-5.0% separately.
11. composition according to claim 1, wherein essence is water-soluble or oil soluble all can.
12. composition according to claim 1, pH value are 5-13.
13. according to claim 1,2 described preparation method of composition, it is characterized in that nonionogenic tenside and anion surfactant and metal-salt material are put into reactor, the 65-95 that heats is incubated 2 hours and then adds sterilant, spices, dyestuff, oxide compound stirs, be cooled to 0-30, the taking-up filling is sent into mould inner pressure and is made shape, is product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97103607 CN1183463A (en) | 1997-03-31 | 1997-03-31 | Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 97103607 CN1183463A (en) | 1997-03-31 | 1997-03-31 | Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1183463A true CN1183463A (en) | 1998-06-03 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 97103607 Pending CN1183463A (en) | 1997-03-31 | 1997-03-31 | Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103635566A (en) * | 2012-09-25 | 2014-03-12 | 李代虹 | Environmentally-friendly phosphorus-free cleaning agent for toilet |
| CN104531402A (en) * | 2014-12-10 | 2015-04-22 | 广州市浪奇实业股份有限公司 | Neutral toilet cleaner |
| WO2015172281A1 (en) * | 2014-05-12 | 2015-11-19 | The Procter & Gamble Company | Anti-microbial laundry detergent composition |
| CN106318661A (en) * | 2016-07-25 | 2017-01-11 | 启东市方圆塑胶制品有限公司 | Anti-scaling agent for water scale and oil stains |
| CN106318679A (en) * | 2016-07-25 | 2017-01-11 | 启东市方圆塑胶制品有限公司 | Sterilization and disinfection detergent |
| CN109536306A (en) * | 2018-12-29 | 2019-03-29 | 河南绿澳化工科技有限公司 | A kind of liquid toilet cleaner and preparation method thereof |
| CN110724607A (en) * | 2019-11-15 | 2020-01-24 | 四川百科乐化学科技有限公司 | Shower room cleaning cream and preparation method thereof |
-
1997
- 1997-03-31 CN CN 97103607 patent/CN1183463A/en active Pending
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103635566A (en) * | 2012-09-25 | 2014-03-12 | 李代虹 | Environmentally-friendly phosphorus-free cleaning agent for toilet |
| WO2014047744A1 (en) * | 2012-09-25 | 2014-04-03 | Li Daihong | Environmentally-friendly phosphorus-free cleaning agent for toilet |
| CN103635566B (en) * | 2012-09-25 | 2015-06-03 | 李代虹 | Environmentally-friendly phosphorus-free cleaning agent for toilet |
| WO2015172281A1 (en) * | 2014-05-12 | 2015-11-19 | The Procter & Gamble Company | Anti-microbial laundry detergent composition |
| CN106232790A (en) * | 2014-05-12 | 2016-12-14 | 宝洁公司 | Antimicrobial laundry detergent composition |
| CN104531402A (en) * | 2014-12-10 | 2015-04-22 | 广州市浪奇实业股份有限公司 | Neutral toilet cleaner |
| CN106318661A (en) * | 2016-07-25 | 2017-01-11 | 启东市方圆塑胶制品有限公司 | Anti-scaling agent for water scale and oil stains |
| CN106318679A (en) * | 2016-07-25 | 2017-01-11 | 启东市方圆塑胶制品有限公司 | Sterilization and disinfection detergent |
| CN109536306A (en) * | 2018-12-29 | 2019-03-29 | 河南绿澳化工科技有限公司 | A kind of liquid toilet cleaner and preparation method thereof |
| CN110724607A (en) * | 2019-11-15 | 2020-01-24 | 四川百科乐化学科技有限公司 | Shower room cleaning cream and preparation method thereof |
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