CN118251522A - Knitted fabric and application thereof - Google Patents
Knitted fabric and application thereof Download PDFInfo
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- CN118251522A CN118251522A CN202380014498.4A CN202380014498A CN118251522A CN 118251522 A CN118251522 A CN 118251522A CN 202380014498 A CN202380014498 A CN 202380014498A CN 118251522 A CN118251522 A CN 118251522A
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- knitted fabric
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- humidity
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- 239000004744 fabric Substances 0.000 title claims abstract description 95
- 238000010521 absorption reaction Methods 0.000 claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 claims abstract description 4
- 239000004952 Polyamide Substances 0.000 claims description 50
- 229920002647 polyamide Polymers 0.000 claims description 50
- 210000002268 wool Anatomy 0.000 claims description 46
- 239000000835 fiber Substances 0.000 claims description 22
- 229920002972 Acrylic fiber Polymers 0.000 claims description 20
- 229920000297 Rayon Polymers 0.000 claims description 17
- 229920000728 polyester Polymers 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 238000010276 construction Methods 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 abstract description 10
- 238000009940 knitting Methods 0.000 description 34
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 21
- 238000004043 dyeing Methods 0.000 description 17
- 238000000034 method Methods 0.000 description 15
- 229920000742 Cotton Polymers 0.000 description 12
- 230000000694 effects Effects 0.000 description 12
- 239000000203 mixture Substances 0.000 description 12
- 239000002253 acid Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 7
- 238000001816 cooling Methods 0.000 description 7
- 238000001035 drying Methods 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 210000001519 tissue Anatomy 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 238000005303 weighing Methods 0.000 description 7
- 239000002216 antistatic agent Substances 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 125000002091 cationic group Chemical group 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- -1 modal Polymers 0.000 description 5
- 229920000433 Lyocell Polymers 0.000 description 4
- 239000000980 acid dye Substances 0.000 description 4
- 230000001276 controlling effect Effects 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 3
- 230000004087 circulation Effects 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 238000009413 insulation Methods 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 239000000985 reactive dye Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004902 Softening Agent Substances 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000002657 fibrous material Substances 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 210000004243 sweat Anatomy 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004089 microcirculation Effects 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 230000001932 seasonal effect Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04B—KNITTING
- D04B1/00—Weft knitting processes for the production of fabrics or articles not dependent on the use of particular machines; Fabrics or articles defined by such processes
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Knitting Of Fabric (AREA)
Abstract
A knitted fabric and its use are disclosed. The knitted fabric is of a double-sided structure comprising a surface A and a surface B, wherein the moisture absorption difference delta MR A of the surface A and the moisture absorption difference delta MR B of the surface B meet the following relational expression, (delta MR A+ΔMRB)/2≥0.5,|ΔMRA-ΔMRB I is more than or equal to 0.1. Because of the specific moisture absorption difference relation between the surface A and the surface B, the clothing manufactured by the knitted fabric has excellent temperature and humidity regulating effect and excellent durability, and can be widely used for manufacturing underwear and T-shirts.
Description
The invention relates to a knitted fabric and application thereof, in particular to a knitted fabric with a temperature and humidity regulating function and application thereof.
With the increasing standard of living in today's society, consumer demands for wearing comfort and functionality of garments are increasing. In addition, people generally increase or decrease clothes according to the cold and hot degree of weather to achieve the aim of temperature and humidity adjustment, but the method is not only troublesome, but also sometimes difficult to achieve, and is particularly prominent in the leisure and sports fields.
For this reason, many studies have been conducted. For example, japanese patent application laid-open No. 2004-316005 discloses a fibrous structure having hygroscopic and exothermic properties, and specifically discloses that the fibrous structure is made of a material having hygroscopic and exothermic properties, and a temperature-sensitive irritant substance is adhered to the surface of the fiber to enhance blood circulation, so that the fibrous structure has more excellent heat-insulating properties and hygroscopic properties, and is mainly used for heat-insulating clothing in winter, but cannot achieve the purpose of temperature adjustment and humidity adjustment for winter and summer.
For another example, chinese patent CN103584385A discloses a garment for cooling and warming, and specifically discloses a garment formed by vertically connecting a cooling layer and a warming layer, wherein the cooling layer is made of ultra-fine imitation silk, the warming layer is made of ultra-smooth imitation wool, and the cooling layer and the warming layer are sewn together by cotton threads, so that the cooling and warming properties are obtained, but the cooling layer and the warming layer are connected by the cotton threads, so that the cotton threads are easy to break after washing for many times, and the durability is required to be further improved.
For another example, chinese patent CN204994641U discloses a moisture-absorbing and heat-generating antistatic sweater, and specifically discloses that the outer layer of the fabric is made of antistatic nylon fiber, the inner layer is made of moisture-absorbing and heat-generating acrylic fiber, the collar part is made of mosquito-repellent regenerated cellulose fiber, and the button is made of magnetotherapy stone, wherein, conductive substances such as carbon black are added into the antistatic nylon fiber, and because the raw materials of the fibers have strong heat absorption, the antistatic sweater is relatively suitable for autumn and winter, and the dual purpose of temperature adjustment, humidity adjustment, winter and summer cannot be realized.
The invention aims to provide a knitted fabric with temperature and humidity regulating function and excellent durability and application thereof.
In order to achieve the above object, the technical solution of the present invention is as follows:
The knitted fabric of the present invention is a double-sided structure including a face a and a face B, wherein a moisture absorption difference Δmr A of the face a and a moisture absorption difference Δmr B of the face B satisfy the following relational expression,
(ΔMR A+ΔMR B)/2≥0.5,
|ΔMR A-ΔMR B|≥0.1。
The knitted fabric has the advantages that the specific moisture absorption rate difference relation exists between the surface A and the surface B, so that the knitted fabric has excellent temperature and humidity regulating effects, can be worn in hot summer and cold winter, has excellent durability, and can be widely used for manufacturing underwear, T-shirts and the like.
Fig. 1 is a weave pattern of an air layer structure according to embodiment 1 of the present invention.
Fig. 2 is a weave pattern change according to embodiment 15 of the present invention.
Fig. 3 is a weave pattern of an air layer according to embodiment 20 of the present invention.
Fig. 4 is a weave pattern of an air layer structure according to embodiment 21 of the present invention.
The ability of fibrous materials to absorb moisture from a gaseous environment is known as hygroscopicity. Moisture absorption is a dynamic process in which the fibers continually absorb moisture and continually release moisture.
The knitted fabric of the invention has a double-sided structure and comprises a surface A and a surface B, wherein the moisture absorption difference delta MR A of the surface A and the moisture absorption difference delta MR B of the surface B meet the following relational expression,
(ΔMR A+ΔMR B)/2≥0.5,
|ΔMR A-ΔMR B|≥0.1
Wherein,
Δmr A = equilibrium moisture absorption at 30 ℃, 90% rh for plane a-equilibrium moisture absorption at 20 ℃, 65% rh,
Δmr B = equilibrium moisture absorption at 30 ℃, 90% rh for plane B-equilibrium moisture absorption at 20 ℃, 65% rh.
The equilibrium moisture absorption rate herein refers to the moisture regain when the moisture absorption and release effects of the fibrous material reach equilibrium stability under specific atmospheric conditions, also referred to as equilibrium moisture regain. The higher the Δmr of the fabric, the lower the water vapor pressure in the garment during medium-strength exercises (e.g., fast walking, dancing), the less the sultry, and the better the comfort.
The knitted fabric of the invention is of a double-sided construction, comprising a face a and a face B. The fabric is of a double-sided structure, and when the fabric is of a double-sided structure, different delta MR can be realized on two sides, and the fabric enters into another temperature and humidity environment from different temperature and humidity environments along with the change of indoor and outdoor temperature difference and air pressure difference, the climate microcirculation in the garment can be changed.
When (DeltaMR A+ΔMR B)/2<0.5、|ΔMR A-ΔMR B | < 0.1), the hygroscopicity of both sides of the fabric is poor and cannot bring about the effect of temperature and humidity adjustment, therefore, the invention requires (DeltaMR A+ΔMR B)/2 to be more than or equal to 0.5, preferably 1.0 to 8.0, more preferably 1.5 to 7.0, and requires that the absolute value of DeltaMR A-ΔMR B | be more than or equal to 0.1, preferably 0.5 to 9.0, more preferably 1.0 to 5.0.
In hot summer, the outdoor temperature is high and the humidity is high; and the indoor temperature is low and the humidity is low. When a person enters outdoors from indoors, namely from a low-temperature low-humidity environment to a high-temperature high-humidity environment, the sweat yield of the human body is increased, and at the moment, the proper moisture absorption rate difference (delta MR) can enable the fabric to absorb moisture in the air around the skin, so that the stuffiness and discomfort are reduced. In addition, the outside high temperature causes the water to evaporate, a part of vaporization heat is taken away, the temperature and humidity in the microclimate environment between the clothes and the human body can be kept in a lower range, and the human body feels cool.
In cold winter, the outdoor temperature is low, and the humidity is low; and the indoor temperature is high and the humidity is high. When a person enters outdoors from indoors, namely from a comfortable high-temperature high-humidity environment to a low-temperature low-humidity environment, moisture or sweat in the human body is less, fibers with proper moisture absorption rate difference (delta MR) absorb moisture in a microclimate environment, water molecules in motion are absorbed by fiber macromolecules, and the water molecules can convert kinetic energy into heat energy to release heat, so that the microcirculatory environment between clothes and the human body is maintained or regulated, the temperature is kept even higher, and the purposes of heat preservation or temperature rise are realized.
The double-sided structure of the present invention is not particularly limited, and may be a double-sided structure of a single-sided structure, such as a single-sided polyester cotton (or cotton) and cotton) and the like; the multi-layer structure of the single-sided stitch may be a full stitch plating, a partial stitch plating, or the like. Can be a double-layer structure of double-sided tissues, such as double-sided rib, double-sided cotton wool, double-sided variable tissues and the like; the structure can also be a multi-layer structure of double-sided tissue, such as double-sided air layer tissue (sandwich tissue or Wuming tissue), etc. In the case of a double-layer construction of a double-sided weave, the inner yarn is preferably connected in such a way that it does not appear in the surface weave, for example in the form of tuck loops.
The underfill coefficient characterizes the tightness of the fabric, and refers to the ratio between the length of the loops (mm) and the diameter of the yarn (mm). The longer the loop length, the finer the yarn, the greater the underfill coefficient value, and the more space in the facing that is not filled with yarn, the more open the facing. When the ratio a of the underfill coefficients is less than 0.5 or a is more than 2.0, the difference of tightness of the two sides of the fabric is large, namely, the difference of styles of the two sides is large, and the quality of the fabric tends to be reduced, so that the ratio a of the underfill coefficients of the surface A and the surface B in one complete organization and yarn using cycle preferably satisfies the following relation: 2.0 More than or equal to a is more than or equal to 0.5.
In the present invention, the filament number of the yarn forming the surface a and the surface B is not particularly limited, and the filament number of the yarn forming the surface B is preferably 2.2dtex or less. When face B is used as a muscle face (the face closer to the skin), a suitable denier per filament facilitates the face B to absorb more moisture; meanwhile, when the single filament number of the yarn is below 2.2dtex, the yarn is soft in hand feeling, the whole surface B is smoother, a larger contact area is easier to obtain, and heat release and instant conduction are more facilitated for hot summer.
In the present invention, when the fabric is formed of spun yarn and filament multifilament, the exposure rate of the spun yarn on the surface a and the surface B has a large influence on the heat insulation property and the contact cold feeling of the fabric. The staple yarns may be formed from wool, acrylic, cotton, modal, tencel, lyocell, viscose, and the like, and may be formed from far infrared yarns. Far infrared yarns are obtained by adding far infrared particles to the yarns or by means of coatings or the like, such as far infrared polyesters, far infrared acrylons and the like. Preferably, the exposure rate of the spun yarn on the surface A is more than 50%, and the fiber raw material is one or more of wool, acrylic fiber and viscose. Of these, wool is more preferably shrink-proof wool. The shrink-proof wool refers to wool subjected to shrink-proof treatment, namely, scales are removed by chemical, biological and other methods, or scales on the surface of wool fibers are removed by a resin filling and coating method and a combination method of the two methods. When the wool is shrink-proof wool, the gloss and the dimensional stability of the fabric are better. The acrylic fibers can be common acrylic fibers, ultrafine acrylic fibers, and more preferably ultrafine acrylic fibers. The ultra-fine acrylic fiber herein refers to an acrylic fiber having a single filament fineness of 1.1dtex or less. When the acrylic fibers are superfine acrylic fibers, the fabric is softer, has better quality and is more suitable for skin-adhering wearing. In the present invention, the exposure rate of the spun yarn on the surface A is more preferably 70 to 100%. When the exposure rate of the spun yarn on both surfaces exceeds 50%, the surface having a large exposure rate of the spun yarn is used as the surface a and the other surface is used as the surface B in consideration of the temperature and humidity adjustment property.
In the present invention, the total fineness of the yarn on the face a is not particularly limited, and is preferably 30 to 80 denier. When the total fineness of the yarn is lower than 30 inches, the yarn is thicker, the style of the fabric is rough, and the fine sense tends to be reduced; when the total fineness of the yarn is higher than 80 inches, the yarn is thin, the yarn strength is low, and yarn breakage is likely to occur, and in addition, the yarn count is increased, and the cost tends to be increased.
Examples of the fiber raw material of the multifilament yarn on the surface B include polyamide, polyester, viscose, tencel, modal, lyocell, cuprammonium fiber, silk and the like. Preferably, the exposure rate of the filament multifilament yarn on the face B in the present invention is more than 50%, and the fiber raw material thereof is one or more of polyamide, polyester and viscose. The polyester fiber can be common polyester fiber (PET), cationic dye dyeable polyester fiber (CDP), polytrimethylene terephthalate fiber (PTT) and the like. The cross-sectional shape of the fiber raw material is not particularly limited, and may be a circular cross-section, or may be a special cross-section such as a triangle, a cross-shape, or a multi-leaf shape, and the form of the filament is not particularly limited, and may be FDY, DTY, or the like, and preferably FDY. Of these fiber raw materials, fibers having a high thermal conductivity such as polyamide fibers are more preferable. When the exposure rate of the filament multifilament on the surface B is more than 50%, a good cool touch can be imparted to the surface B. In the present invention, the exposure rate of the filament multifilament yarn on the surface B is more preferably 70 to 100%. When the exposure rate of the filament multifilament on both surfaces exceeds 50%, the surface having a large exposure rate of the filament multifilament is used as the surface B and the other surface is used as the surface a in view of temperature and humidity adjustment.
In the present invention, the total fineness of the yarn on the surface B is not particularly limited, and is preferably 33 to 165dtex, more preferably 55 to 84dtex. When the total fineness of the yarn exceeds 165dtex, the yarn is thicker, the fabric style is rough and thick, evaporation of water is possibly affected, and the temperature and humidity regulating effect tends to be reduced; when the total fineness of the yarn is lower than 33dtex, the yarn is thinner, the strength is lower, the phenomenon of yarn breakage possibly occurs during weaving, and meanwhile, the thinner the yarn is, the thinner the fabric is, and the temperature and humidity regulating effect tends to be reduced.
The temperature and humidity regulating effect of the invention refers to the capability of generating a temperature difference value with the surrounding environment after a fabric enters one fixed temperature and humidity condition from another temperature and humidity condition. The simulation conditions during the specific test are as follows: when the environment changes from indoor to outdoor in winter, the indoor temperature and humidity are 20 ℃ multiplied by 65%RH, and the outdoor temperature and humidity are 10 ℃ multiplied by 30%RH; when the environment changes from indoor to outdoor in summer, the indoor temperature and humidity are 20 ℃ multiplied by 65%RH, and the outdoor temperature and humidity are 30 ℃ multiplied by 90%RH.
In the present invention, it is more preferable that the ratio of exposure of the spun yarn on the surface a is more than 50%, the ratio of exposure of the filament multifilament is less than 50%, and the ratio of exposure of the spun yarn on the surface B is less than 50%, so that the difference in performance between the surfaces can be ensured to the maximum extent, that is, the surface a has excellent heat insulating property, the surface B has excellent contact cold feeling, and the difference is remarkable.
In the present invention, the clo value of the surface A is preferably 0.65 or more, and the qmax value of the surface B is preferably 0.12 or more.
In the process of manufacturing the fabric of the present invention, water absorbing agent, softening agent, antistatic agent, etc. may be selected for processing at the time of finishing as needed. The water absorbing agent may be a polyester resin, an acrylic resin, or the like. The softening agent may be silicone resin or the like. The antistatic agent may be cationic, anionic, nonionic, compound, etc., such as alkyl sulfonate type anionic antistatic agent, quaternary ammonium salt type cationic antistatic agent, etc.
The clothing made of the knitted fabric is not limited in wearing scene, can be worn on one side all the year round, and can be worn on two sides alternately according to seasonal changes.
The present invention will be further described with reference to examples and comparative examples.
The testing method of each parameter related by the invention is as follows:
(1) Exposure rate of spun yarn
A flat, wrinkle-free knitted fabric was prepared, and 5 pieces of the specimen having a size of about 20 cm. Times.20 cm were cut. Taking 1 sample, determining a complete structure and yarn circulation, disassembling yarns, drawing a structure chart of the fabric, distinguishing spun yarns and filament multifilaments according to yarn forms, and then calculating the exposure rate of the spun yarns on the surface according to the following formula:
z=x d/y×100%
Wherein x d: the number of loops of the loop formation formed by the spun yarn,
Y: the number of coils of all the looping tissues on the surface;
The percentage of exposed spun yarn on the same side of the remaining 4 samples was measured and calculated in the same manner, and the average value was taken as the percentage of exposed spun yarn of the present invention.
(2) Exposure rate of filament multifilament yarn
Exposure rate of filament multifilament = 100% -z.
(3) Moisture absorption difference Δmr A for plane a and moisture absorption difference Δmr for plane B B
① Sample preparation
Preparing a flat and wrinkle-free knitted fabric, and shearing 5 samples with the size of about 20cm multiplied by 20 cm;
② Difference in moisture absorption ΔMR
1 Block is selected, a complete structure is determined, yarn circulation is carried out, one surface is marked as a surface A, the other surface is marked as a surface B (for example, when the exposure rate of the spun yarn on one surface is more than 50 percent and the exposure rate of the spun yarn on the other surface is less than 50 percent, the surface with the exposure rate of the spun yarn being more than 50 percent is taken as the surface A, the other surface is taken as the surface B, when the exposure rate of the spun yarn on the two surfaces is more than 50 percent, the surface with the larger exposure rate of the spun yarn is taken as the surface A, the other surface is taken as the surface B, and when the exposure rate of the filament multifilament yarn on the two surfaces is more than 50 percent, the surface with the larger exposure rate of the filament multifilament is taken as the surface B, and the other surface is taken as the surface A);
A. When there is no yarn present in the sample that is present in both sides A and B
A1 At least one complete weave and all yarns in the yarn cycle are respectively disassembled, marks are made, the yarn of the surface A is marked as a, and the yarn of the surface B is marked as B;
a2 Weighing the yarn marked as a (ensuring the weight of the yarn to be more than 1 g), putting the yarn into a constant temperature and humidity machine, and pre-drying the yarn at 60 ℃ for 30 minutes;
a3 Placing the pre-dried yarn into a constant temperature and humidity machine with the temperature of 20 ℃ multiplied by 65%RH, carrying out humidity adjustment and balancing for 24 hours, weighing and recording as W1;
a4 Placing the yarn in the step a 3) into a constant temperature and humidity machine with the conditions of 30 ℃ multiplied by 90% RH, carrying out humidity adjustment and balancing for 24 hours, weighing and recording as W2;
a5 Placing the yarn in the step a 4) into a constant temperature drying oven with the condition of 105 ℃, taking out after being absolute dried for 2 hours, placing the yarn in a drying vessel, cooling the yarn in the environment of 20 ℃ for 30 minutes, weighing and recording the yarn as W3;
a6 Then Δmr (%) of the face a is calculated according to the following formula,
ΔMR=MR 2-MR 1
MR 1=(W1-W3)/W3×100%
MR 2=(W2-W3)/W3×100%
Wherein,
W1: mass (g) of test piece (weight of weighing bottle) after humidity balance was adjusted under 20 ℃ x 65% RH
W2: mass (g) of test piece (weight of weighing bottle) after humidity balance was adjusted under 30 ℃ x 90% RH
W3: the mass (g) of the test piece (divided by the weight of the weighing flask) in the dry state;
a7 According to steps a 2) to a 6), measuring and calculating the difference in moisture absorption of the yarn marked a in the remaining 4 samples, taking the average value as the difference in moisture absorption Δmr A of the face a of the present invention;
a8 In the same way, the moisture absorption difference Δmr B of the face B is measured and calculated.
B. when yarn simultaneously present on both sides A and B is present in the sample
The yarn that appears on both sides a and B is defined as yarn ab,
B1 Calculating the ratio z of the yarn ab exposed on the surface A a
The proportion z a of yarn ab on face a can be calculated according to the following formula:
z a=x/y×100%
wherein x: the number of loops of the loop formation formed by yarn ab on face a,
Y: the total number of loops of the loop forming structure in the yarn circulation is completely organized on the surface A;
b2 According to B1), calculating the exposed proportion z b of the yarn ab on the surface B;
b3 Cutting the sample into 5cm by 5cm (if the sample has a complete weave and the yarn cycle is greater than 5cm, a complete cycle must be ensured), removing all the yarns and marking. The yarn of the face a is marked as a, the yarn of the face B is marked as B, and the yarns appearing on the faces a and B are marked as a yarn ab;
b4 Testing the yarn marked a, the yarn marked b and the yarn marked ab according to the steps a 2) to a 7), and marking the test results as delta MR a、ΔMR b、ΔMR ab respectively;
b5 The moisture absorption rate differences Δmr A、ΔMR B of the calculated surfaces a, B are calculated according to the following formula, respectively, wherein,
ΔMR A=ΔMR a×(1-z a)+(ΔMR ab×z a)
ΔMR B=ΔMR b×(1-z b)+(ΔMR ab×z b)。
(4) Temperature and humidity regulating effect
① 5 Pieces of 5 cm. Times.5 cm samples were taken. All the samples are put into a drying box for pre-drying: the temperature and humidity changes of all samples are immediately recorded by a temperature and humidity sensor, and the average value is taken as data of temperature and humidity regulation effect in winter;
② 5 pieces of 5 cm. Times.5 cm samples were taken. All the samples are put into a drying box for pre-drying: and (3) placing the sample in an environment with the temperature and humidity of 20 ℃ multiplied by 65%RH for more than 24 hours at 50 ℃ multiplied by 1 hour, balancing the sample, placing the sample in the environment with the temperature and humidity of 30 ℃ multiplied by 90%RH, immediately recording the temperature and humidity changes of all the samples by using a temperature and humidity sensor, and taking the average value as the data of the temperature and humidity regulating effect in summer.
(5) Thermal insulation
Referring to the KES-method of KatoTech company, KES style instrument model: KES-F7-II (hotplate temperature set at 40 ℃).
(6) Contact cold feeling
Referring to the KES-method of KatoTech company, KES style instrument model: KES-F7-ii (Δt=20℃).
The knitting fabric of the invention is obtained by knitting 43-inch wool/acrylic fiber blended yarn (blending ratio is 20:80), 110dtex/36f CDP DTY and 44dtex/36f polyamide FDY on a double-sided circular knitting machine in an air layer structure shown in the attached figure 1 to obtain grey cloth, and then performing pretreatment (scouring agent 2 g/L), dyeing (one bath method: acid dye/cationic dye, 110 ℃ for 30min, dyeing acid 2g/L and leveling agent 2 g/L) and post finishing (antistatic agent 1g/L and neutralizing acid 1 g/L) to obtain the knitted fabric of the invention, wherein specific parameters are shown in tables 1 and 3.
Wherein, during knitting, polyamide FDY is fed into the 1 st path and the 2 nd path, CDP DTY is fed into the 3 rd path, wool/acrylic blended yarn is fed into the 4 th path, and the length ratio between the wool/acrylic blended yarn and the CDP DTY is 1.25.
Blend ratio was 20:80 wool/acrylic blend yarn was replaced with a blend ratio of 45:55, the length ratio between the wool/acrylic fiber blended yarn and CDP DTY was adjusted to 1.30, and the knitting fabric of the invention was obtained by the same method as in example 1, and the specific parameters are shown in tables 1 and 3.
Blend ratio was 20:80 wool/acrylic blend yarn was replaced with a blend ratio of 60:40, the length ratio between the wool/acrylic fiber blended yarn and CDP DTY is adjusted to be 1.35, and the knitting fabric of the invention is obtained by the same method as in example 1, and specific parameters are shown in tables 1 and 3.
Blend ratio was 20:80 wool/acrylic blend yarn was replaced with a blend ratio of 65:35, the length ratio between the wool/acrylic fiber blended yarn and the CDP DTY is adjusted to be 1.36, and the knitting fabric of the invention is obtained by the same method as in example 1, and the specific parameters are shown in tables 1 and 3.
The knitting fabric of the present invention was obtained by knitting a 43-count wool/acrylic fiber blended yarn with a 43-count 100% wool yarn, a 110dtex/36f CDP DTY with a 77dtex/68f polyamide DTY, and then performing pretreatment (scouring agent 2 g/L), dyeing (acid dye, 95 ℃ C. For 30min, dyeing acid 2g/L, leveling agent 2 g/L), finishing (antistatic agent 1g/L, neutralizing acid 1 g/L), and the other steps as in example 1, wherein the line length ratio between the 100% wool yarn and the polyamide DTY was adjusted to 1.00.
The knitting fabric of the present invention was obtained by adjusting the line length ratio between 100% wool yarn and polyamide DTY to 0.81 and the rest was the same as in example 5, and specific parameters are shown in tables 1 and 3.
The length ratio between 100% wool yarn and polyamide DTY was adjusted to 1.45, and the knitting fabric of the invention was obtained by the same procedure as in example 5, with specific parameters shown in tables 1 and 3.
The length ratio between 100% wool yarn and polyamide DTY was adjusted to 3.23, and the knitting fabric of the invention was obtained by the same procedure as in example 5, with specific parameters shown in tables 1 and 3.
The length ratio between 100% wool yarn and polyamide DTY was adjusted to 4.03, and the rest was the same as in example 5, to obtain the knitted fabric of the present invention, and specific parameters are shown in tables 1 and 3.
The knitting fabric of the invention is obtained by replacing the 43-count wool/acrylic blended yarn with 38-count acrylic/viscose blended yarn (blending ratio 80:20), and replacing the 110dtex/36f CDP DTY with 77dtex/68f polyamide DTY, wherein the line length ratio between the acrylic/viscose blended yarn and the 77dtex/68f polyamide DTY is adjusted to be 1.20, and dyeing (two bath method: reactive dye 60 ℃ for 30min, cationic dye 110 ℃ for 30min, dyeing acid 2g/L and leveling agent 2 g/L), and the rest of the same example 1.
Blend ratio was 80:20 acrylic/viscose blend yarn was replaced with blend ratio 65:35, and the length ratio between the acrylic/viscose blended yarn and the 77dtex/68f polyamide DTY is adjusted to be 0.76, and the knitting fabric of the invention is obtained by the rest of example 10, and the specific parameters are shown in tables 1 and 3.
The 38-count acrylic/viscose blended yarn is replaced by 40-count viscose 100% spun yarn, 77dtex/68f polyamide DTY is replaced by 55dtex/36f CDP DTY, the line length ratio between the viscose 100% spun yarn and the CDP DTY is adjusted to 0.63, and the knitting fabric of the invention is obtained by the rest of example 10, and specific parameters are shown in tables 1 and 3.
The knitting fabric of the invention is obtained by replacing 77dtex/68f polyamide DTY with 84dtex/36f viscose filament FDY, adjusting the line length ratio between 100% wool yarn and viscose filament FDY to be 1.77, dyeing (dyeing viscose: reactive dye, 60 ℃ for 30min, dyeing acid 2g/L, levelling agent 2 g/L), and the rest of example 5, wherein the specific parameters are shown in tables 1 and 3.
The knitting fabric of the present invention was obtained by replacing the 43 count 100% wool yarn with the 40 count pure cotton yarn, adjusting the line length ratio between the pure cotton yarn and the viscose filament FDY to 1.31, dyeing (reactive dye, 60 ℃ C. For 30min, dyeing acid 2g/L, leveling agent 2 g/L) to obtain a grey cloth, and the rest of the same as in example 13, with specific parameters shown in tables 1 and 3.
Selecting 100% wool yarn with 43 count and PET DTY with 55dtex/36f, and knitting on a double-sided circular knitting machine with a variable double-sided structure as shown in figure 2, wherein the 1 st path is fed with 100% wool yarn, the 2 nd and 3 rd paths are fed with PET DTY, the line length ratio between the 100% wool yarn and the PET DTY is adjusted to 2.30, and the dyeing conditions are as follows: the knitted fabric of the invention was obtained by dyeing PET only, disperse dye, 130 ℃ for 30min, dyeing acid 2g/L, leveling agent 2g/L, and the rest of example 5, and the specific parameters are shown in tables 2 and 4.
The knitting fabric of the present invention was obtained by replacing the 43-count wool/acrylic blended yarn with 40-count 100% acrylic spun yarn, replacing the 110dtex/36f CDP DTY with 55dtex/36f polyamide DTY, adjusting the line length ratio between the 100% acrylic spun yarn and the 55dtex/36f polyamide DTY to 3.18, dyeing (acid dye, 95 ℃ C. For 30min, dyeing acid for 2g/L, and leveling agent for 2 g/L), and the rest with example 1, and the specific parameters are shown in tables 2 and 4.
The 77dtex/68f polyamide DTY was replaced with 77dtex/36f polyamide DTY, the ratio of the length of the 100% wool yarn to the 77dtex/36f polyamide DTY was adjusted to 1.45, and the knitted fabric was obtained by knitting with a polyester cotton fabric on a single-side circular knitting machine, and the other examples 5 were repeated, with the specific parameters shown in tables 2 and 4.
The knitting fabric of the invention was obtained by replacing 77dtex/68f of polyamide DTY with 77dtex/36f of polyethylene FDY, adjusting the line length ratio between 100% wool yarn and polyethylene FDY to 1.33, and the rest of example 5, with specific parameters shown in tables 2 and 4.
The knitting fabric of the invention was obtained by substituting 77dtex/36f of polyamide DTY with 77dtex/24f of polyamide DTY and the rest was the same as in example 17, and the specific parameters are shown in tables 2 and 4.
The knitting fabric of the present invention was obtained by selecting a yarn length ratio between a polyamide DTY of 77dtex/24f, a polyamide FDY of 44dtex/36f, a yarn length of 43 dtex/24f, a polyamide DTY of 3, 7, 11, 15, 19, 23, 27, 31, 32, 36, 40 paths, a yarn length of 4, 8, 12, 16, 20, 24, 28, 35, 39 paths, a yarn length of 43 dtex/24f, a polyamide FDY of 44dtex/36f, a yarn length of 100% dtex/24f, and a polyamide DTY of 77dtex/24f to be 1.17, and the other paths, as in example 16.
The knitting fabric of the present invention was obtained by selecting a polyamide DTY of 43 dtex/24f, a polyamide DTY of 77dtex/24f, and a polyamide FDY of 44dtex/36f, knitting with the structure shown in fig. 4, and adjusting the line length ratio between the polyamide FDY of 44dtex/36f, the polyamide DTY of 100% dtex/24f, the polyamide FDY of 4,8, 12, 16, 20, 24, 28, 32, 35, 36, 39, 75, 79 to 43 dtex/24f, and the polyamide DTY of the polyamide FDY of the polyamide dtex/24f of the polyamide dtex/36f of the other line to 0.69, with the other line length ratios of 0.69.
The knitting fabric of the present invention was obtained by selecting a yarn of 100% acrylic staple yarn of 43 dtex/24f, a polyamide DTY of 77dtex/24f and a polyamide FDY of 44dtex/36f and knitting the yarn of 100% acrylic staple yarn in the structure shown in FIG. 3, and feeding the yarn length ratio between the yarn of 100% acrylic staple yarn and the polyamide DTY of 77dtex/24f to the yarn of 27 th and 31 th paths to be adjusted to 2.65, and the other steps were the same as in example 20, with specific parameters shown in tables 2 and 4.
Garments were made using the knitted fabrics of examples 1-22.
Comparative example 1
The knitting is carried out by selecting a wool/acrylic fiber blended yarn (blending ratio is 20:80) and 44dtex/36f polyamide FDY, when knitting, the 1 st and 2 nd paths of fed polyamide FDY, the 3 rd and 4 th paths of fed wool/acrylic fiber blended yarn, the length ratio between the 4 th path of wool/acrylic fiber blended yarn and the 3 rd path of wool/acrylic fiber blended yarn is 1.00, the knitting (acid dye, 95 ℃ for 30min, 2g/L of dyeing acid and 2g/L of leveling agent) is carried out, and the rest is the same as in the example 1, thus obtaining the knitted fabric, and the specific parameters are shown in tables 2 and 4.
Comparative example 2
The 43-count wool/acrylic blended yarn (blending ratio 20:80) was replaced with the wool/acrylic blended yarn (blending ratio 7:93), the length ratio between the wool/acrylic blended yarn and CDP DTY was 1.21, and the rest was the same as in example 1, to obtain a knitted fabric, and specific parameters are shown in tables 2 and 4.
Comparative example 3
Knitting is carried out by selecting CDP DTY of 110dtex/36f and polyamide FDY of 44dtex/36f, 1 st and 2 nd paths of feeding polyamide FDY, 3 rd and 4 th paths of feeding CDP DTY, the line length ratio between the 4 th path of CDP DTY and the 3 rd path of CDP DTY is adjusted to be 1.00, and the knitting fabric is obtained by the rest of example 1, wherein the specific parameters are shown in tables 2 and 4.
TABLE 1
TABLE 2
TABLE 3 Table 3
TABLE 4 Table 4
According to the tables 1 to 4,
(1) As is clear from examples 4 and 3, the knitted fabric having the average value of the sum of the two-sided moisture absorption differences of 1.5 and the absolute value of the difference between the moisture absorption differences of 2.7 was comparable to the knitted fabric having the average value of the sum of the two-sided moisture absorption differences of 1.3 and the absolute value of the difference between the moisture absorption differences of 2.5 under the same conditions, but the temperature and humidity controlling properties of the former were better than the latter and the heat insulating properties of the face a were slightly better than the latter.
(2) As is clear from examples 6 and 5, the knitted fabric having a ratio of the coefficient of double-sided underfill of 0.5 and the knitted fabric having a ratio of the coefficient of double-sided underfill of 0.3 had comparable temperature control effects, and the former had better humidity control effect, heat retaining property of the surface a, and contact cold feel of the surface B than the latter.
(3) As is clear from examples 8 and 9, the knitted fabric having a ratio of the two-sided underfill coefficient of 2.0 and the knitted fabric having a ratio of the two-sided underfill coefficient of 2.5 were comparable in the humidity control effect, and the temperature control effect, the heat retaining property of the surface a and the contact cold feeling of the surface B were all better than those of the former.
(4) As is clear from examples 13 and 14, under the same conditions, the knitted fabric having a wool yarn exposure rate of 100% on the face a had a moisture control effect equivalent to that of the knitted fabric having a pure cotton yarn exposure rate of 100% on the face a, and the contact cold feeling of the face B was better than that of the face a.
(5) As is clear from examples 7 and 18, the knitted fabric having a polyamide fiber exposure rate of 100% on the surface B was slightly inferior to the knitted fabric having a polyethylene fiber exposure rate of 100% on the surface B in terms of the contact cold feel, but the temperature and humidity controlling effect and the heat retaining property of the surface a were both better than those of the latter.
(6) As is clear from examples 17 and 19, the knitted fabric having a single filament fineness of 2.1dtex of the yarn on the face B was superior to the knitted fabric having a single filament fineness of 3.2dtex of the yarn on the face B under the same conditions, although the temperature adjusting effect was equivalent to the temperature adjusting effect, both the humidity adjusting effect and the contact cold feeling were superior to the latter.
(7) As is clear from examples 20 and 21, the knitted fabric having a wool yarn exposure rate of 70% on the face a and the knitted fabric having a wool yarn exposure rate of 30% on the face a had comparable cold feeling in contact with each other, and the former had higher temperature and humidity controlling effects and heat retaining properties than the latter.
(8) As is clear from examples 20 and 22, the knitted fabric having an exposure rate of 80% of the polyamide DTY on the surface B and the knitted fabric having an exposure rate of 40% of the polyamide DTY on the surface B were comparable in heat insulation properties to each other, and the temperature and humidity controlling effect and the contact cold feeling of the former were higher than those of the latter under the same conditions.
(9) As is clear from comparative example 1 and example 1, the knitted fabric having an absolute value of difference between both side moisture absorption differences of 0 had a poor temperature and humidity control effect and the knitted fabric having an absolute value of difference between both side moisture absorption differences of 0.8 had no good contact cold feeling in the face B.
(10) As is clear from comparative example 2 and example 1, the knitted fabric having the average value of the sum of the two-sided moisture absorption differences of 0.2 and the absolute value of the difference between the moisture absorption differences of 0.2 was inferior to the knitted fabric having the average value of the sum of the two-sided moisture absorption differences of 0.5 and the absolute value of the difference between the moisture absorption differences of 0.8 in the same condition.
(11) As is clear from comparative example 3 and example 1, the knitted fabric having the average value of the sum of the difference of the moisture absorption at both sides of 0.1 and the absolute value of the difference of the moisture absorption of 0 was inferior to the knitted fabric having the average value of the sum of the difference of the moisture absorption at both sides of 0.5 and the absolute value of the difference of the moisture absorption of 0.8 in the same condition, and the heat insulating property of the surface A was not good.
Claims (6)
- A knitted fabric, the fabric being of a double-sided construction comprising a face a and a face B, characterized by: the moisture absorption rate difference Δmr A of the face a and the moisture absorption rate difference Δmr B of the face B satisfy the following relation,(ΔMR A+ΔMR B)/2≥0.5,|ΔMR A-ΔMR B|≥0.1。
- The knitted fabric of claim 1, wherein: the ratio a of the underfill coefficients of the surface a and the surface B satisfies the following relation,2.0≥a≥0.5。
- The knitted fabric according to claim 1 or 2, characterized in that: the yarn forming the face B has a single filament fineness of 2.2dtex or less.
- The knitted fabric according to claim 1 or 2, characterized in that: the exposure rate of the spun yarn on the surface A is more than 50%, and the fiber raw material of the spun yarn is one or more of wool, acrylic fiber and viscose.
- The knitted fabric according to claim 1 or 2, characterized in that: the exposure rate of the filament multifilament on the surface B is more than 50%, and the fiber raw material of the filament multifilament is one or more of polyamide, polyester and viscose.
- Use of the knitted fabric according to any one of claims 1 to 5 in the manufacture of a garment.
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CN202210148946 | 2022-02-18 | ||
CN2022101489467 | 2022-02-18 | ||
PCT/CN2023/076657 WO2023155860A1 (en) | 2022-02-18 | 2023-02-17 | Knitted fabric and use thereof |
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JP2004036012A (en) * | 2002-07-01 | 2004-02-05 | Toray Ind Inc | Water absorbing knitted fabric |
JP4390514B2 (en) * | 2003-09-29 | 2009-12-24 | ミツカワ株式会社 | Multilayer structure knitted fabric |
CN204994641U (en) * | 2015-07-19 | 2016-01-27 | 浩沙实业(福建)有限公司 | Moisture absorption antistatic sweater that generates heat |
CN107227551A (en) * | 2016-03-24 | 2017-10-03 | 东丽纤维研究所(中国)有限公司 | A kind of two-sided knitting fabric |
DE102017001494A1 (en) * | 2017-02-16 | 2018-08-16 | Christian Zwiesler | functional underwear |
CN109112708A (en) * | 2017-06-23 | 2019-01-01 | 东丽纤维研究所(中国)有限公司 | A kind of heat preservation water-absorbing fast-drying fabric |
CN107574544A (en) * | 2017-09-29 | 2018-01-12 | 上海嘉麟杰纺织品股份有限公司 | A kind of wet-guide quick-drying wool knitting fabrics and preparation method thereof |
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