CN118215702A - Thermoplastic resin and optical lens comprising the same - Google Patents
Thermoplastic resin and optical lens comprising the same Download PDFInfo
- Publication number
- CN118215702A CN118215702A CN202280074108.8A CN202280074108A CN118215702A CN 118215702 A CN118215702 A CN 118215702A CN 202280074108 A CN202280074108 A CN 202280074108A CN 118215702 A CN118215702 A CN 118215702A
- Authority
- CN
- China
- Prior art keywords
- carbon atoms
- group
- substituent
- general formula
- thermoplastic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920005992 thermoplastic resin Polymers 0.000 title claims abstract description 96
- 230000003287 optical effect Effects 0.000 title claims description 73
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 239000011347 resin Substances 0.000 claims abstract description 65
- 150000002009 diols Chemical class 0.000 claims abstract description 44
- 125000004432 carbon atom Chemical group C* 0.000 claims description 168
- -1 alkylene glycol Chemical compound 0.000 claims description 100
- 125000001424 substituent group Chemical group 0.000 claims description 95
- 229920005668 polycarbonate resin Polymers 0.000 claims description 92
- 239000004431 polycarbonate resin Substances 0.000 claims description 92
- 125000003118 aryl group Chemical group 0.000 claims description 52
- 125000001072 heteroaryl group Chemical group 0.000 claims description 27
- 125000002947 alkylene group Chemical group 0.000 claims description 25
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 25
- 229910052717 sulfur Inorganic materials 0.000 claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 claims description 23
- 229910052760 oxygen Inorganic materials 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 125000003545 alkoxy group Chemical group 0.000 claims description 16
- 125000000000 cycloalkoxy group Chemical group 0.000 claims description 15
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 15
- 125000004104 aryloxy group Chemical group 0.000 claims description 14
- 239000000178 monomer Substances 0.000 claims description 13
- 239000000155 melt Substances 0.000 claims description 11
- 239000012788 optical film Substances 0.000 claims description 11
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 10
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 125000005843 halogen group Chemical group 0.000 claims description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 description 50
- 238000000034 method Methods 0.000 description 32
- 239000011342 resin composition Substances 0.000 description 28
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 25
- 239000003054 catalyst Substances 0.000 description 24
- 238000000465 moulding Methods 0.000 description 24
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 23
- 235000014113 dietary fatty acids Nutrition 0.000 description 22
- 239000000194 fatty acid Substances 0.000 description 22
- 229930195729 fatty acid Natural products 0.000 description 22
- 150000002148 esters Chemical class 0.000 description 20
- 239000003963 antioxidant agent Substances 0.000 description 17
- 230000003078 antioxidant effect Effects 0.000 description 16
- 239000003795 chemical substances by application Substances 0.000 description 15
- 239000012535 impurity Substances 0.000 description 14
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000006227 byproduct Substances 0.000 description 12
- 150000004650 carbonic acid diesters Chemical class 0.000 description 12
- 125000003367 polycyclic group Chemical group 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000005259 measurement Methods 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 239000000654 additive Substances 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
- 238000004519 manufacturing process Methods 0.000 description 10
- 125000002950 monocyclic group Chemical group 0.000 description 10
- 238000006116 polymerization reaction Methods 0.000 description 10
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 9
- 230000004075 alteration Effects 0.000 description 9
- 150000004665 fatty acids Chemical class 0.000 description 9
- 239000010408 film Substances 0.000 description 9
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 9
- 235000011187 glycerol Nutrition 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000002994 raw material Substances 0.000 description 9
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 9
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 8
- 239000006096 absorbing agent Substances 0.000 description 8
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 8
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 238000001746 injection moulding Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 229920006395 saturated elastomer Polymers 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 8
- 239000012760 heat stabilizer Substances 0.000 description 7
- 238000006068 polycondensation reaction Methods 0.000 description 7
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 6
- SFDGJDBLYNJMFI-UHFFFAOYSA-N 3,1-benzoxazin-4-one Chemical compound C1=CC=C2C(=O)OC=NC2=C1 SFDGJDBLYNJMFI-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 6
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 150000002430 hydrocarbons Chemical group 0.000 description 6
- 150000002989 phenols Chemical class 0.000 description 6
- 125000006413 ring segment Chemical group 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 238000005809 transesterification reaction Methods 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 229920001519 homopolymer Polymers 0.000 description 5
- 235000011007 phosphoric acid Nutrition 0.000 description 5
- 230000000704 physical effect Effects 0.000 description 5
- 229920000515 polycarbonate Polymers 0.000 description 5
- 239000004417 polycarbonate Substances 0.000 description 5
- 229920000728 polyester Polymers 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 4
- YYROPELSRYBVMQ-UHFFFAOYSA-N 4-toluenesulfonyl chloride Chemical compound CC1=CC=C(S(Cl)(=O)=O)C=C1 YYROPELSRYBVMQ-UHFFFAOYSA-N 0.000 description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 125000002619 bicyclic group Chemical group 0.000 description 4
- 239000004305 biphenyl Substances 0.000 description 4
- 235000010290 biphenyl Nutrition 0.000 description 4
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 4
- 235000010338 boric acid Nutrition 0.000 description 4
- XSIFPSYPOVKYCO-UHFFFAOYSA-N butyl benzoate Chemical compound CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 4
- 238000000748 compression moulding Methods 0.000 description 4
- VBVCYAZECWLFHP-UHFFFAOYSA-N dodecyl benzenesulfonate;tetrabutylphosphanium Chemical compound CCCC[P+](CCCC)(CCCC)CCCC.CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 VBVCYAZECWLFHP-UHFFFAOYSA-N 0.000 description 4
- 239000000428 dust Substances 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 4
- 150000008376 fluorenones Chemical class 0.000 description 4
- 150000004820 halides Chemical class 0.000 description 4
- 239000010410 layer Substances 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 125000001624 naphthyl group Chemical group 0.000 description 4
- WRKCIHRWQZQBOL-UHFFFAOYSA-N octyl dihydrogen phosphate Chemical compound CCCCCCCCOP(O)(O)=O WRKCIHRWQZQBOL-UHFFFAOYSA-N 0.000 description 4
- CDXVUROVRIFQMV-UHFFFAOYSA-N oxo(diphenoxy)phosphanium Chemical compound C=1C=CC=CC=1O[P+](=O)OC1=CC=CC=C1 CDXVUROVRIFQMV-UHFFFAOYSA-N 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 150000004671 saturated fatty acids Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 4
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 4
- UONCERAQKBPLML-UHFFFAOYSA-N (6-ethoxypyridin-3-yl)boronic acid Chemical compound CCOC1=CC=C(B(O)O)C=N1 UONCERAQKBPLML-UHFFFAOYSA-N 0.000 description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 3
- OVJPYIRGUFWANT-UHFFFAOYSA-N 2-[1-[2-(2-hydroxyethoxy)naphthalen-1-yl]naphthalen-2-yl]oxyethanol Chemical group C1=CC=C2C(C3=C4C=CC=CC4=CC=C3OCCO)=C(OCCO)C=CC2=C1 OVJPYIRGUFWANT-UHFFFAOYSA-N 0.000 description 3
- HBTONAMIPDVQRI-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)-3-phenylphenyl]fluoren-9-yl]-2-phenylphenoxy]ethanol Chemical compound OCCOC1=CC=C(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(C(OCCO)=CC=2)C=2C=CC=CC=2)C=C1C1=CC=CC=C1 HBTONAMIPDVQRI-UHFFFAOYSA-N 0.000 description 3
- NQXNYVAALXGLQT-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]fluoren-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 NQXNYVAALXGLQT-UHFFFAOYSA-N 0.000 description 3
- SSADPHQCUURWSW-UHFFFAOYSA-N 3,9-bis(2,6-ditert-butyl-4-methylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C)=CC(C(C)(C)C)=C1OP1OCC2(COP(OC=3C(=CC(C)=CC=3C(C)(C)C)C(C)(C)C)OC2)CO1 SSADPHQCUURWSW-UHFFFAOYSA-N 0.000 description 3
- CYHYIIFODCKQNP-UHFFFAOYSA-N 5,7-ditert-butyl-3-(3,4-dimethylphenyl)-3h-1-benzofuran-2-one Chemical compound C1=C(C)C(C)=CC=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O CYHYIIFODCKQNP-UHFFFAOYSA-N 0.000 description 3
- JYFHYPJRHGVZDY-UHFFFAOYSA-N Dibutyl phosphate Chemical compound CCCCOP(O)(=O)OCCCC JYFHYPJRHGVZDY-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 150000001341 alkaline earth metal compounds Chemical class 0.000 description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 3
- 125000000499 benzofuranyl group Chemical group O1C(=CC2=C1C=CC=C2)* 0.000 description 3
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 3
- 239000012965 benzophenone Substances 0.000 description 3
- 125000006267 biphenyl group Chemical group 0.000 description 3
- QYJXDIUNDMRLAO-UHFFFAOYSA-N butyl 4-methylbenzenesulfonate Chemical compound CCCCOS(=O)(=O)C1=CC=C(C)C=C1 QYJXDIUNDMRLAO-UHFFFAOYSA-N 0.000 description 3
- HDFRDWFLWVCOGP-UHFFFAOYSA-N carbonothioic O,S-acid Chemical compound OC(S)=O HDFRDWFLWVCOGP-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 230000009849 deactivation Effects 0.000 description 3
- VZEGPPPCKHRYGO-UHFFFAOYSA-N diethoxyphosphorylbenzene Chemical compound CCOP(=O)(OCC)C1=CC=CC=C1 VZEGPPPCKHRYGO-UHFFFAOYSA-N 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- HTDKEJXHILZNPP-UHFFFAOYSA-N dioctyl hydrogen phosphate Chemical compound CCCCCCCCOP(O)(=O)OCCCCCCCC HTDKEJXHILZNPP-UHFFFAOYSA-N 0.000 description 3
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 125000005842 heteroatom Chemical group 0.000 description 3
- 125000001041 indolyl group Chemical group 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 description 3
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 125000001725 pyrenyl group Chemical group 0.000 description 3
- 125000000168 pyrrolyl group Chemical group 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- OKMWKBLSFKFYGZ-UHFFFAOYSA-N 1-behenoylglycerol Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)OCC(O)CO OKMWKBLSFKFYGZ-UHFFFAOYSA-N 0.000 description 2
- CYXGBTZYTXLVDN-UHFFFAOYSA-N 1-octoxyphosphonoyloxyoctane Chemical compound CCCCCCCCOP(=O)OCCCCCCCC CYXGBTZYTXLVDN-UHFFFAOYSA-N 0.000 description 2
- JRFBLFCZOPUKBM-UHFFFAOYSA-N 2-(1-naphthalen-1-ylnaphthalen-2-yl)oxyethanol Chemical group OCCOC1=C(C2=CC=CC=C2C=C1)C1=CC=CC2=CC=CC=C12 JRFBLFCZOPUKBM-UHFFFAOYSA-N 0.000 description 2
- IYAZLDLPUNDVAG-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-(2,4,4-trimethylpentan-2-yl)phenol Chemical compound CC(C)(C)CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 IYAZLDLPUNDVAG-UHFFFAOYSA-N 0.000 description 2
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 description 2
- PPYWEGBDKQIRKU-UHFFFAOYSA-N 2-[6-(9H-fluoren-1-yl)naphthalen-2-yl]oxyethanol Chemical compound OCCOC=1C=C2C=CC(=CC2=CC=1)C1=CC=CC=2C3=CC=CC=C3CC1=2 PPYWEGBDKQIRKU-UHFFFAOYSA-N 0.000 description 2
- FHZQOYSKWUJKDZ-UHFFFAOYSA-N 2-[6-[9-[6-(2-hydroxyethoxy)naphthalen-2-yl]fluoren-9-yl]naphthalen-2-yl]oxyethanol Chemical compound C1=C(OCCO)C=CC2=CC(C3(C4=CC=CC=C4C4=CC=CC=C43)C3=CC4=CC=C(C=C4C=C3)OCCO)=CC=C21 FHZQOYSKWUJKDZ-UHFFFAOYSA-N 0.000 description 2
- 125000001622 2-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C(*)C([H])=C([H])C2=C1[H] 0.000 description 2
- DUUKZBGYNMHUHO-UHFFFAOYSA-N 253MC0P0YV Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)COCC(O)CO DUUKZBGYNMHUHO-UHFFFAOYSA-N 0.000 description 2
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 2
- VSAWBBYYMBQKIK-UHFFFAOYSA-N 4-[[3,5-bis[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-2,4,6-trimethylphenyl]methyl]-2,6-ditert-butylphenol Chemical compound CC1=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)C(C)=C1CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VSAWBBYYMBQKIK-UHFFFAOYSA-N 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 229920001651 Cyanoacrylate Polymers 0.000 description 2
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- ARIWANIATODDMH-UHFFFAOYSA-N Lauric acid monoglyceride Natural products CCCCCCCCCCCC(=O)OCC(O)CO ARIWANIATODDMH-UHFFFAOYSA-N 0.000 description 2
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 2
- GWFGDXZQZYMSMJ-UHFFFAOYSA-N Octadecansaeure-heptadecylester Natural products CCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC GWFGDXZQZYMSMJ-UHFFFAOYSA-N 0.000 description 2
- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 2
- 229930182556 Polyacetal Natural products 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 150000001339 alkali metal compounds Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 125000003828 azulenyl group Chemical group 0.000 description 2
- 150000007514 bases Chemical class 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical class CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- PASDCCFISLVPSO-UHFFFAOYSA-N benzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1 PASDCCFISLVPSO-UHFFFAOYSA-N 0.000 description 2
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 2
- 229940073608 benzyl chloride Drugs 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 125000005619 boric acid group Chemical class 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical class [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- OSPSWZSRKYCQPF-UHFFFAOYSA-N dibutoxy(oxo)phosphanium Chemical compound CCCCO[P+](=O)OCCCC OSPSWZSRKYCQPF-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- LXCYSACZTOKNNS-UHFFFAOYSA-N diethoxy(oxo)phosphanium Chemical compound CCO[P+](=O)OCC LXCYSACZTOKNNS-UHFFFAOYSA-N 0.000 description 2
- XFUSKHPBJXJFRA-UHFFFAOYSA-N dihexyl hydrogen phosphite Chemical compound CCCCCCOP(O)OCCCCCC XFUSKHPBJXJFRA-UHFFFAOYSA-N 0.000 description 2
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 2
- XMQYIPNJVLNWOE-UHFFFAOYSA-N dioctyl hydrogen phosphite Chemical compound CCCCCCCCOP(O)OCCCCCCCC XMQYIPNJVLNWOE-UHFFFAOYSA-N 0.000 description 2
- ASMQGLCHMVWBQR-UHFFFAOYSA-M diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)([O-])OC1=CC=CC=C1 ASMQGLCHMVWBQR-UHFFFAOYSA-M 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- YQEMORVAKMFKLG-UHFFFAOYSA-N glycerine monostearate Natural products CCCCCCCCCCCCCCCCCC(=O)OC(CO)CO YQEMORVAKMFKLG-UHFFFAOYSA-N 0.000 description 2
- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- IVQOVYWBHRSGJI-UHFFFAOYSA-N hexyl 4-methylbenzenesulfonate Chemical compound CCCCCCOS(=O)(=O)C1=CC=C(C)C=C1 IVQOVYWBHRSGJI-UHFFFAOYSA-N 0.000 description 2
- 150000004678 hydrides Chemical class 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 150000004679 hydroxides Chemical class 0.000 description 2
- 230000000415 inactivating effect Effects 0.000 description 2
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 2
- 229910052740 iodine Inorganic materials 0.000 description 2
- 229940070765 laurate Drugs 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical compound CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 description 2
- 239000006082 mold release agent Substances 0.000 description 2
- 125000004593 naphthyridinyl group Chemical group N1=C(C=CC2=CC=CN=C12)* 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- WTBAHSZERDXKKZ-UHFFFAOYSA-N octadecanoyl chloride Chemical compound CCCCCCCCCCCCCCCCCC(Cl)=O WTBAHSZERDXKKZ-UHFFFAOYSA-N 0.000 description 2
- NKBWPOSQERPBFI-UHFFFAOYSA-N octadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCCCC NKBWPOSQERPBFI-UHFFFAOYSA-N 0.000 description 2
- KCRLWVVFAVLSAP-UHFFFAOYSA-N octyl dihydrogen phosphite Chemical compound CCCCCCCCOP(O)O KCRLWVVFAVLSAP-UHFFFAOYSA-N 0.000 description 2
- 229940049964 oleate Drugs 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 239000013307 optical fiber Substances 0.000 description 2
- 239000005304 optical glass Substances 0.000 description 2
- 125000002971 oxazolyl group Chemical group 0.000 description 2
- CHJUOCDSZWMLRU-UHFFFAOYSA-N oxo(dipropoxy)phosphanium Chemical compound CCCO[P+](=O)OCCC CHJUOCDSZWMLRU-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- PXDJXZJSCPSGGI-UHFFFAOYSA-N palmityl palmitate Chemical compound CCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC PXDJXZJSCPSGGI-UHFFFAOYSA-N 0.000 description 2
- 125000005561 phenanthryl group Chemical group 0.000 description 2
- 239000002530 phenolic antioxidant Substances 0.000 description 2
- VCAFTIGPOYBOIC-UHFFFAOYSA-N phenyl dihydrogen phosphite Chemical compound OP(O)OC1=CC=CC=C1 VCAFTIGPOYBOIC-UHFFFAOYSA-N 0.000 description 2
- CMPQUABWPXYYSH-UHFFFAOYSA-N phenyl phosphate Chemical compound OP(O)(=O)OC1=CC=CC=C1 CMPQUABWPXYYSH-UHFFFAOYSA-N 0.000 description 2
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical compound OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 2
- 150000003003 phosphines Chemical class 0.000 description 2
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 2
- 150000003009 phosphonic acids Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 150000003016 phosphoric acids Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920006324 polyoxymethylene Polymers 0.000 description 2
- 229920001955 polyphenylene ether Polymers 0.000 description 2
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 2
- XAEFZNCEHLXOMS-UHFFFAOYSA-M potassium benzoate Chemical compound [K+].[O-]C(=O)C1=CC=CC=C1 XAEFZNCEHLXOMS-UHFFFAOYSA-M 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 2
- 229940093625 propylene glycol monostearate Drugs 0.000 description 2
- 125000001042 pteridinyl group Chemical group N1=C(N=CC2=NC=CN=C12)* 0.000 description 2
- 125000000561 purinyl group Chemical group N1=C(N=C2N=CNC2=C1)* 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- LKUNXBRZDFMZOK-UHFFFAOYSA-N rac-1-monodecanoylglycerol Chemical compound CCCCCCCCCC(=O)OCC(O)CO LKUNXBRZDFMZOK-UHFFFAOYSA-N 0.000 description 2
- GHBFNMLVSPCDGN-UHFFFAOYSA-N rac-1-monooctanoylglycerol Chemical compound CCCCCCCC(=O)OCC(O)CO GHBFNMLVSPCDGN-UHFFFAOYSA-N 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 229950011392 sorbitan stearate Drugs 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- VDZOOKBUILJEDG-UHFFFAOYSA-M tetrabutylammonium hydroxide Chemical compound [OH-].CCCC[N+](CCCC)(CCCC)CCCC VDZOOKBUILJEDG-UHFFFAOYSA-M 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 2
- WGKLOLBTFWFKOD-UHFFFAOYSA-N tris(2-nonylphenyl) phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(OC=1C(=CC=CC=1)CCCCCCCCC)OC1=CC=CC=C1CCCCCCCCC WGKLOLBTFWFKOD-UHFFFAOYSA-N 0.000 description 2
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 2
- 229940124543 ultraviolet light absorber Drugs 0.000 description 2
- 125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 2
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- SLHYOPBSTLVPFZ-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 2-ethylhexyl hydrogen phosphite Chemical compound CCCCC(CC)COP(O)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C SLHYOPBSTLVPFZ-UHFFFAOYSA-N 0.000 description 1
- SXJSETSRWNDWPP-UHFFFAOYSA-N (2-hydroxy-4-phenylmethoxyphenyl)-phenylmethanone Chemical compound C=1C=C(C(=O)C=2C=CC=CC=2)C(O)=CC=1OCC1=CC=CC=C1 SXJSETSRWNDWPP-UHFFFAOYSA-N 0.000 description 1
- DNISEZBAYYIQFB-PHDIDXHHSA-N (2r,3r)-2,3-diacetyloxybutanedioic acid Chemical compound CC(=O)O[C@@H](C(O)=O)[C@H](C(O)=O)OC(C)=O DNISEZBAYYIQFB-PHDIDXHHSA-N 0.000 description 1
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- XCPFSALHURPPJE-UHFFFAOYSA-N (3,5-ditert-butyl-4-hydroxyphenyl) propanoate Chemical compound CCC(=O)OC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 XCPFSALHURPPJE-UHFFFAOYSA-N 0.000 description 1
- GPFJHNSSBHPYJK-UHFFFAOYSA-N (3-methylphenyl) hydrogen carbonate Chemical compound CC1=CC=CC(OC(O)=O)=C1 GPFJHNSSBHPYJK-UHFFFAOYSA-N 0.000 description 1
- ARVUDIQYNJVQIW-UHFFFAOYSA-N (4-dodecoxy-2-hydroxyphenyl)-phenylmethanone Chemical compound OC1=CC(OCCCCCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 ARVUDIQYNJVQIW-UHFFFAOYSA-N 0.000 description 1
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 1
- HCNHNBLSNVSJTJ-UHFFFAOYSA-N 1,1-Bis(4-hydroxyphenyl)ethane Chemical compound C=1C=C(O)C=CC=1C(C)C1=CC=C(O)C=C1 HCNHNBLSNVSJTJ-UHFFFAOYSA-N 0.000 description 1
- OWEYKIWAZBBXJK-UHFFFAOYSA-N 1,1-Dichloro-2,2-bis(4-hydroxyphenyl)ethylene Chemical compound C1=CC(O)=CC=C1C(=C(Cl)Cl)C1=CC=C(O)C=C1 OWEYKIWAZBBXJK-UHFFFAOYSA-N 0.000 description 1
- 125000001399 1,2,3-triazolyl group Chemical group N1N=NC(=C1)* 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- 125000004504 1,2,4-oxadiazolyl group Chemical group 0.000 description 1
- 125000001376 1,2,4-triazolyl group Chemical group N1N=C(N=C1)* 0.000 description 1
- QFMZQPDHXULLKC-UHFFFAOYSA-N 1,2-bis(diphenylphosphino)ethane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)CCP(C=1C=CC=CC=1)C1=CC=CC=C1 QFMZQPDHXULLKC-UHFFFAOYSA-N 0.000 description 1
- ODDSXTDNXBAVPQ-UHFFFAOYSA-N 1,2-dihydroxypropyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(O)C(C)O ODDSXTDNXBAVPQ-UHFFFAOYSA-N 0.000 description 1
- 125000001781 1,3,4-oxadiazolyl group Chemical group 0.000 description 1
- VNQNXQYZMPJLQX-UHFFFAOYSA-N 1,3,5-tris[(3,5-ditert-butyl-4-hydroxyphenyl)methyl]-1,3,5-triazinane-2,4,6-trione Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CN2C(N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C(=O)N(CC=3C=C(C(O)=C(C=3)C(C)(C)C)C(C)(C)C)C2=O)=O)=C1 VNQNXQYZMPJLQX-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- YPFDHNVEDLHUCE-UHFFFAOYSA-N 1,3-propanediol Substances OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 1
- 229940035437 1,3-propanediol Drugs 0.000 description 1
- UAXNXOMKCGKNCI-UHFFFAOYSA-N 1-diphenylphosphanylethyl(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)C(C)P(C=1C=CC=CC=1)C1=CC=CC=C1 UAXNXOMKCGKNCI-UHFFFAOYSA-N 0.000 description 1
- ARIWANIATODDMH-AWEZNQCLSA-N 1-lauroyl-sn-glycerol Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)CO ARIWANIATODDMH-AWEZNQCLSA-N 0.000 description 1
- 125000001637 1-naphthyl group Chemical group [H]C1=C([H])C([H])=C2C(*)=C([H])C([H])=C([H])C2=C1[H] 0.000 description 1
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- WZUNUACWCJJERC-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)(CO)CO WZUNUACWCJJERC-UHFFFAOYSA-N 0.000 description 1
- RVNAQNUKCZKJCP-UHFFFAOYSA-N 2,3-dihydroxypropyl 12-hydroxyoctadecanoate Chemical compound CCCCCCC(O)CCCCCCCCCCC(=O)OCC(O)CO RVNAQNUKCZKJCP-UHFFFAOYSA-N 0.000 description 1
- LRZBIPQJHILPJI-UHFFFAOYSA-N 2,3-dihydroxypropyl 2-(2,3-dihydroxypropyl)octadecanoate Chemical compound CCCCCCCCCCCCCCCCC(CC(O)CO)C(=O)OCC(O)CO LRZBIPQJHILPJI-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- HJZJMARGPNJHHG-UHFFFAOYSA-N 2,6-dimethyl-4-propylphenol Chemical compound CCCC1=CC(C)=C(O)C(C)=C1 HJZJMARGPNJHHG-UHFFFAOYSA-N 0.000 description 1
- GJDRKHHGPHLVNI-UHFFFAOYSA-N 2,6-ditert-butyl-4-(diethoxyphosphorylmethyl)phenol Chemical compound CCOP(=O)(OCC)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 GJDRKHHGPHLVNI-UHFFFAOYSA-N 0.000 description 1
- JLZIIHMTTRXXIN-UHFFFAOYSA-N 2-(2-hydroxy-4-methoxybenzoyl)benzoic acid Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1C(O)=O JLZIIHMTTRXXIN-UHFFFAOYSA-N 0.000 description 1
- LEVFXWNQQSSNAC-UHFFFAOYSA-N 2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-hexoxyphenol Chemical compound OC1=CC(OCCCCCC)=CC=C1C1=NC(C=2C=CC=CC=2)=NC(C=2C=CC=CC=2)=N1 LEVFXWNQQSSNAC-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- WXHVQMGINBSVAY-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 WXHVQMGINBSVAY-UHFFFAOYSA-N 0.000 description 1
- QSRJVOOOWGXUDY-UHFFFAOYSA-N 2-[2-[2-[3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoyloxy]ethoxy]ethoxy]ethyl 3-(3-tert-butyl-4-hydroxy-5-methylphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C)=CC(CCC(=O)OCCOCCOCCOC(=O)CCC=2C=C(C(O)=C(C)C=2)C(C)(C)C)=C1 QSRJVOOOWGXUDY-UHFFFAOYSA-N 0.000 description 1
- UOGUFKQDHYUPFF-UHFFFAOYSA-N 2-[2-cyclohexyl-4-(9h-fluoren-1-yl)phenoxy]ethanol Chemical compound OCCOC1=CC=C(C=2C3=C(C4=CC=CC=C4C3)C=CC=2)C=C1C1CCCCC1 UOGUFKQDHYUPFF-UHFFFAOYSA-N 0.000 description 1
- DIGVBSRERRMQGF-UHFFFAOYSA-N 2-[2-tert-butyl-4-(9h-fluoren-1-yl)phenoxy]ethanol Chemical compound C1=C(OCCO)C(C(C)(C)C)=CC(C=2C3=C(C4=CC=CC=C4C3)C=CC=2)=C1 DIGVBSRERRMQGF-UHFFFAOYSA-N 0.000 description 1
- BPZIYBJCZRUDEG-UHFFFAOYSA-N 2-[3-(1-hydroxy-2-methylpropan-2-yl)-2,4,8,10-tetraoxaspiro[5.5]undecan-9-yl]-2-methylpropan-1-ol Chemical compound C1OC(C(C)(CO)C)OCC21COC(C(C)(C)CO)OC2 BPZIYBJCZRUDEG-UHFFFAOYSA-N 0.000 description 1
- ZSSVCEUEVMALRD-UHFFFAOYSA-N 2-[4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C1=NC(C=2C(=CC(C)=CC=2)C)=NC(C=2C(=CC(C)=CC=2)C)=N1 ZSSVCEUEVMALRD-UHFFFAOYSA-N 0.000 description 1
- HCAUPHOHHNOCLW-UHFFFAOYSA-N 2-[4-(9h-fluoren-1-yl)-2-methylphenoxy]ethanol Chemical compound C1=C(OCCO)C(C)=CC(C=2C3=C(C4=CC=CC=C4C3)C=CC=2)=C1 HCAUPHOHHNOCLW-UHFFFAOYSA-N 0.000 description 1
- AIFZYIWZIDCFDV-UHFFFAOYSA-N 2-[4-(9h-fluoren-1-yl)-2-phenylphenoxy]ethanol Chemical compound OCCOC1=CC=C(C=2C3=C(C4=CC=CC=C4C3)C=CC=2)C=C1C1=CC=CC=C1 AIFZYIWZIDCFDV-UHFFFAOYSA-N 0.000 description 1
- NDZVXLXMMKMELQ-UHFFFAOYSA-N 2-[4-(9h-fluoren-1-yl)-2-propan-2-ylphenoxy]ethanol Chemical compound C1=C(OCCO)C(C(C)C)=CC(C=2C3=C(C4=CC=CC=C4C3)C=CC=2)=C1 NDZVXLXMMKMELQ-UHFFFAOYSA-N 0.000 description 1
- MDOBPGJMVOGJQP-UHFFFAOYSA-N 2-[4-(9h-fluoren-1-yl)phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1=CC=CC2=C1CC1=CC=CC=C21 MDOBPGJMVOGJQP-UHFFFAOYSA-N 0.000 description 1
- CKPPCRXSDMAOOO-UHFFFAOYSA-N 2-[5-(9H-fluoren-1-yl)naphthalen-2-yl]oxyethanol Chemical compound OCCOC=1C=C2C=CC=C(C2=CC1)C1=CC=CC=2C3=CC=CC=C3CC12 CKPPCRXSDMAOOO-UHFFFAOYSA-N 0.000 description 1
- HXEWWQYSYQOUSD-UHFFFAOYSA-N 2-[5-ethyl-5-(hydroxymethyl)-1,3-dioxan-2-yl]-2-methylpropan-1-ol Chemical compound CCC1(CO)COC(C(C)(C)CO)OC1 HXEWWQYSYQOUSD-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- XKZGIJICHCVXFV-UHFFFAOYSA-N 2-ethylhexyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCC(CC)CCCC)OC1=CC=CC=C1 XKZGIJICHCVXFV-UHFFFAOYSA-N 0.000 description 1
- OPJWPPVYCOPDCM-UHFFFAOYSA-N 2-ethylhexyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC OPJWPPVYCOPDCM-UHFFFAOYSA-N 0.000 description 1
- ZVTDEEBSWIQAFJ-KHPPLWFESA-N 2-hydroxypropyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(C)O ZVTDEEBSWIQAFJ-KHPPLWFESA-N 0.000 description 1
- BHIZVZJETFVJMJ-UHFFFAOYSA-N 2-hydroxypropyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(C)O BHIZVZJETFVJMJ-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 2-phenyl-1h-imidazole Chemical compound C1=CNC(C=2C=CC=CC=2)=N1 ZCUJYXPAKHMBAZ-UHFFFAOYSA-N 0.000 description 1
- WJQOZHYUIDYNHM-UHFFFAOYSA-N 2-tert-Butylphenol Chemical compound CC(C)(C)C1=CC=CC=C1O WJQOZHYUIDYNHM-UHFFFAOYSA-N 0.000 description 1
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 1
- AIBRSVLEQRWAEG-UHFFFAOYSA-N 3,9-bis(2,4-ditert-butylphenoxy)-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP1OCC2(COP(OC=3C(=CC(=CC=3)C(C)(C)C)C(C)(C)C)OC2)CO1 AIBRSVLEQRWAEG-UHFFFAOYSA-N 0.000 description 1
- PZRWFKGUFWPFID-UHFFFAOYSA-N 3,9-dioctadecoxy-2,4,8,10-tetraoxa-3,9-diphosphaspiro[5.5]undecane Chemical compound C1OP(OCCCCCCCCCCCCCCCCCC)OCC21COP(OCCCCCCCCCCCCCCCCCC)OC2 PZRWFKGUFWPFID-UHFFFAOYSA-N 0.000 description 1
- XNVYSHNTOAAJBU-UHFFFAOYSA-N 3-(1-naphthalen-1-ylnaphthalen-2-yl)oxypropan-1-ol Chemical group OCCCOC1=C(C2=CC=CC=C2C=C1)C1=CC=CC2=CC=CC=C12 XNVYSHNTOAAJBU-UHFFFAOYSA-N 0.000 description 1
- FJDLQLIRZFKEKJ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanamide Chemical compound CC(C)(C)C1=CC(CCC(N)=O)=CC(C(C)(C)C)=C1O FJDLQLIRZFKEKJ-UHFFFAOYSA-N 0.000 description 1
- KNBGFOYMHHZQCZ-UHFFFAOYSA-N 3-[6-(9H-fluoren-1-yl)naphthalen-2-yl]oxypropan-1-ol Chemical compound C1C2=CC=CC=C2C3=CC=CC(=C31)C4=CC5=C(C=C4)C=C(C=C5)OCCCO KNBGFOYMHHZQCZ-UHFFFAOYSA-N 0.000 description 1
- RXNYJUSEXLAVNQ-UHFFFAOYSA-N 4,4'-Dihydroxybenzophenone Chemical compound C1=CC(O)=CC=C1C(=O)C1=CC=C(O)C=C1 RXNYJUSEXLAVNQ-UHFFFAOYSA-N 0.000 description 1
- VWGKEVWFBOUAND-UHFFFAOYSA-N 4,4'-thiodiphenol Chemical compound C1=CC(O)=CC=C1SC1=CC=C(O)C=C1 VWGKEVWFBOUAND-UHFFFAOYSA-N 0.000 description 1
- DHTRVBNLGWVSKJ-UHFFFAOYSA-N 4-(1-naphthalen-1-ylnaphthalen-2-yl)oxybutan-1-ol Chemical group C1=CC=C2C(=C1)C=CC=C2C3=C(C=CC4=CC=CC=C43)OCCCCO DHTRVBNLGWVSKJ-UHFFFAOYSA-N 0.000 description 1
- NZGQHKSLKRFZFL-UHFFFAOYSA-N 4-(4-hydroxyphenoxy)phenol Chemical compound C1=CC(O)=CC=C1OC1=CC=C(O)C=C1 NZGQHKSLKRFZFL-UHFFFAOYSA-N 0.000 description 1
- RQCACQIALULDSK-UHFFFAOYSA-N 4-(4-hydroxyphenyl)sulfinylphenol Chemical compound C1=CC(O)=CC=C1S(=O)C1=CC=C(O)C=C1 RQCACQIALULDSK-UHFFFAOYSA-N 0.000 description 1
- SJCHYUQURUSBIO-UHFFFAOYSA-N 4-(benzotriazol-2-yloxy)octan-2-ol Chemical compound C1=CC=CC2=NN(OC(CC(C)O)CCCC)N=C21 SJCHYUQURUSBIO-UHFFFAOYSA-N 0.000 description 1
- BATCUENAARTUKW-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)-diphenylmethyl]phenol Chemical compound C1=CC(O)=CC=C1C(C=1C=CC(O)=CC=1)(C=1C=CC=CC=1)C1=CC=CC=C1 BATCUENAARTUKW-UHFFFAOYSA-N 0.000 description 1
- UMPGNGRIGSEMTC-UHFFFAOYSA-N 4-[1-(4-hydroxyphenyl)-3,3,5-trimethylcyclohexyl]phenol Chemical compound C1C(C)CC(C)(C)CC1(C=1C=CC(O)=CC=1)C1=CC=C(O)C=C1 UMPGNGRIGSEMTC-UHFFFAOYSA-N 0.000 description 1
- IJWIRZQYWANBMP-UHFFFAOYSA-N 4-[2-(4-hydroxy-3-propan-2-ylphenyl)propan-2-yl]-2-propan-2-ylphenol Chemical compound C1=C(O)C(C(C)C)=CC(C(C)(C)C=2C=C(C(O)=CC=2)C(C)C)=C1 IJWIRZQYWANBMP-UHFFFAOYSA-N 0.000 description 1
- PVFQHGDIOXNKIC-UHFFFAOYSA-N 4-[2-[3-[2-(4-hydroxyphenyl)propan-2-yl]phenyl]propan-2-yl]phenol Chemical compound C=1C=CC(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 PVFQHGDIOXNKIC-UHFFFAOYSA-N 0.000 description 1
- FUNGASCEZWMVBA-UHFFFAOYSA-N 4-[6-[9-[6-(4-hydroxybutoxy)naphthalen-2-yl]fluoren-9-yl]naphthalen-2-yl]oxybutan-1-ol Chemical compound OCCCCOC=1C=C2C=CC(=CC2=CC=1)C1(C2=CC=CC=C2C=2C=CC=CC1=2)C1=CC2=CC=C(C=C2C=C1)OCCCCO FUNGASCEZWMVBA-UHFFFAOYSA-N 0.000 description 1
- 125000004801 4-cyanophenyl group Chemical group [H]C1=C([H])C(C#N)=C([H])C([H])=C1* 0.000 description 1
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- YVPZFPKENDZQEJ-UHFFFAOYSA-N 4-propylcyclohexan-1-ol Chemical compound CCCC1CCC(O)CC1 YVPZFPKENDZQEJ-UHFFFAOYSA-N 0.000 description 1
- 125000002373 5 membered heterocyclic group Chemical group 0.000 description 1
- UWSMKYBKUPAEJQ-UHFFFAOYSA-N 5-Chloro-2-(3,5-di-tert-butyl-2-hydroxyphenyl)-2H-benzotriazole Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O UWSMKYBKUPAEJQ-UHFFFAOYSA-N 0.000 description 1
- CQPPWLHLNWUIGX-UHFFFAOYSA-N 5-[9-(6-hydroxynaphthalen-1-yl)fluoren-9-yl]naphthalen-2-ol Chemical compound Oc1ccc2c(cccc2c1)C1(c2ccccc2-c2ccccc12)c1cccc2cc(O)ccc12 CQPPWLHLNWUIGX-UHFFFAOYSA-N 0.000 description 1
- 125000004070 6 membered heterocyclic group Chemical group 0.000 description 1
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 1
- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 description 1
- FBMKRJLPKSEGPX-UHFFFAOYSA-N 9h-fluorene;naphthalen-1-ol Chemical compound C1=CC=C2C(O)=CC=CC2=C1.C1=CC=C2CC3=CC=CC=C3C2=C1 FBMKRJLPKSEGPX-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- VOWWYDCFAISREI-UHFFFAOYSA-N Bisphenol AP Chemical compound C=1C=C(O)C=CC=1C(C=1C=CC(O)=CC=1)(C)C1=CC=CC=C1 VOWWYDCFAISREI-UHFFFAOYSA-N 0.000 description 1
- HTVITOHKHWFJKO-UHFFFAOYSA-N Bisphenol B Chemical compound C=1C=C(O)C=CC=1C(C)(CC)C1=CC=C(O)C=C1 HTVITOHKHWFJKO-UHFFFAOYSA-N 0.000 description 1
- GIXXQTYGFOHYPT-UHFFFAOYSA-N Bisphenol P Chemical compound C=1C=C(C(C)(C)C=2C=CC(O)=CC=2)C=CC=1C(C)(C)C1=CC=C(O)C=C1 GIXXQTYGFOHYPT-UHFFFAOYSA-N 0.000 description 1
- SDDLEVPIDBLVHC-UHFFFAOYSA-N Bisphenol Z Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)CCCCC1 SDDLEVPIDBLVHC-UHFFFAOYSA-N 0.000 description 1
- RDVHHDNIJMZOIV-UHFFFAOYSA-N C(C)(C)(C)C1=C(OC2(OCC3(CO2)COC(OC3)(P(=O)=O)OC2=C(C=C(C=C2C(C)(C)C)C)C(C)(C)C)P(=O)=O)C(=CC(=C1)C)C(C)(C)C Chemical compound C(C)(C)(C)C1=C(OC2(OCC3(CO2)COC(OC3)(P(=O)=O)OC2=C(C=C(C=C2C(C)(C)C)C)C(C)(C)C)P(=O)=O)C(=CC(=C1)C)C(C)(C)C RDVHHDNIJMZOIV-UHFFFAOYSA-N 0.000 description 1
- GGCDQHOMAXJOTJ-UHFFFAOYSA-N CCCCCCCCCCCCCC(=O)OCC(O)COCC(O)CO Chemical compound CCCCCCCCCCCCCC(=O)OCC(O)COCC(O)CO GGCDQHOMAXJOTJ-UHFFFAOYSA-N 0.000 description 1
- LKUNXBRZDFMZOK-GFCCVEGCSA-N Capric acid monoglyceride Natural products CCCCCCCCCC(=O)OC[C@H](O)CO LKUNXBRZDFMZOK-GFCCVEGCSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- QSJXEFYPDANLFS-UHFFFAOYSA-N Diacetyl Chemical group CC(=O)C(C)=O QSJXEFYPDANLFS-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical class [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- KLDXJTOLSGUMSJ-JGWLITMVSA-N Isosorbide Chemical compound O[C@@H]1CO[C@@H]2[C@@H](O)CO[C@@H]21 KLDXJTOLSGUMSJ-JGWLITMVSA-N 0.000 description 1
- FDBMBOYIVUGUSL-UHFFFAOYSA-N OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C Chemical compound OP(O)OP(O)O.C(C)(C)(C)C1=C(C(=CC(=C1)C)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1C(C)(C)C)C)C(C)(C)C FDBMBOYIVUGUSL-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical class [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical class [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 description 1
- LWZFANDGMFTDAV-BURFUSLBSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O LWZFANDGMFTDAV-BURFUSLBSA-N 0.000 description 1
- NENOAJSZZPODGJ-OIMNJJJWSA-N [(2r)-2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octanoate Chemical compound CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NENOAJSZZPODGJ-OIMNJJJWSA-N 0.000 description 1
- MBKVMGGUKWIVDS-UHFFFAOYSA-N [1-[2-(hydroxymethyl)naphthalen-1-yl]naphthalen-2-yl]methanol Chemical group C1=CC=C2C(C3=C4C=CC=CC4=CC=C3CO)=C(CO)C=CC2=C1 MBKVMGGUKWIVDS-UHFFFAOYSA-N 0.000 description 1
- GHKFHTVXSMGGJZ-UHFFFAOYSA-N [2,3-bis(2,4-ditert-butylphenyl)-4-phenylphenyl]phosphonic acid Chemical compound CC(C)(C)c1ccc(c(c1)C(C)(C)C)-c1c(ccc(c1-c1ccc(cc1C(C)(C)C)C(C)(C)C)P(O)(O)=O)-c1ccccc1 GHKFHTVXSMGGJZ-UHFFFAOYSA-N 0.000 description 1
- YPFLEIIDUKZWFB-UHFFFAOYSA-N [2,4-bis(2,4-ditert-butylphenyl)-3-phenylphenyl]phosphonic acid Chemical compound CC(C)(C)c1ccc(-c2ccc(c(-c3ccc(cc3C(C)(C)C)C(C)(C)C)c2-c2ccccc2)P(O)(O)=O)c(c1)C(C)(C)C YPFLEIIDUKZWFB-UHFFFAOYSA-N 0.000 description 1
- BKZCZANSHGDPSH-KTKRTIGZSA-N [3-(2,3-dihydroxypropoxy)-2-hydroxypropyl] (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)COCC(O)CO BKZCZANSHGDPSH-KTKRTIGZSA-N 0.000 description 1
- OGELJRHPEZALCC-UHFFFAOYSA-N [3-(2,3-dihydroxypropoxy)-2-hydroxypropyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCC(O)COCC(O)CO OGELJRHPEZALCC-UHFFFAOYSA-N 0.000 description 1
- LZGAFUNRMOUFFI-UHFFFAOYSA-N [3-(2-cyano-3,3-diphenylprop-2-enoyl)oxyphenyl] 2-cyano-3,3-diphenylprop-2-enoate Chemical compound C=1C=CC=CC=1C(C=1C=CC=CC=1)=C(C#N)C(=O)OC(C=1)=CC=CC=1OC(=O)C(C#N)=C(C=1C=CC=CC=1)C1=CC=CC=C1 LZGAFUNRMOUFFI-UHFFFAOYSA-N 0.000 description 1
- VSVVZZQIUJXYQA-UHFFFAOYSA-N [3-(3-dodecylsulfanylpropanoyloxy)-2,2-bis(3-dodecylsulfanylpropanoyloxymethyl)propyl] 3-dodecylsulfanylpropanoate Chemical compound CCCCCCCCCCCCSCCC(=O)OCC(COC(=O)CCSCCCCCCCCCCCC)(COC(=O)CCSCCCCCCCCCCCC)COC(=O)CCSCCCCCCCCCCCC VSVVZZQIUJXYQA-UHFFFAOYSA-N 0.000 description 1
- RABVYVVNRHVXPJ-UHFFFAOYSA-N [3-(hydroxymethyl)-1-adamantyl]methanol Chemical compound C1C(C2)CC3CC1(CO)CC2(CO)C3 RABVYVVNRHVXPJ-UHFFFAOYSA-N 0.000 description 1
- OCKWAZCWKSMKNC-UHFFFAOYSA-N [3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC OCKWAZCWKSMKNC-UHFFFAOYSA-N 0.000 description 1
- IQXDUKXUDQPOBC-UHFFFAOYSA-N [3-octadecanoyloxy-2-[[3-octadecanoyloxy-2,2-bis(octadecanoyloxymethyl)propoxy]methyl]-2-(octadecanoyloxymethyl)propyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COCC(COC(=O)CCCCCCCCCCCCCCCCC)(COC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC IQXDUKXUDQPOBC-UHFFFAOYSA-N 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- DCBNMBIOGUANTC-UHFFFAOYSA-N [5-[(5-benzoyl-4-hydroxy-2-methoxyphenyl)methyl]-2-hydroxy-4-methoxyphenyl]-phenylmethanone Chemical compound COC1=CC(O)=C(C(=O)C=2C=CC=CC=2)C=C1CC(C(=CC=1O)OC)=CC=1C(=O)C1=CC=CC=C1 DCBNMBIOGUANTC-UHFFFAOYSA-N 0.000 description 1
- MWLZCJIESXBSHQ-UHFFFAOYSA-N [6-[9-[6-(hydroxymethoxy)naphthalen-2-yl]fluoren-9-yl]naphthalen-2-yl]oxymethanol Chemical compound OCOC=1C=C2C=CC(=CC2=CC=1)C1(C2=CC=CC=C2C=2C=CC=CC1=2)C1=CC2=CC=C(C=C2C=C1)OCO MWLZCJIESXBSHQ-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 125000000641 acridinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3C=C12)* 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005233 alkylalcohol group Chemical group 0.000 description 1
- 229920005603 alternating copolymer Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000002178 anthracenyl group Chemical group C1(=CC=CC2=CC3=CC=CC=C3C=C12)* 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- ITHZDDVSAWDQPZ-UHFFFAOYSA-L barium acetate Chemical compound [Ba+2].CC([O-])=O.CC([O-])=O ITHZDDVSAWDQPZ-UHFFFAOYSA-L 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- UCVMQZHZWWEPRC-UHFFFAOYSA-L barium(2+);hydrogen carbonate Chemical compound [Ba+2].OC([O-])=O.OC([O-])=O UCVMQZHZWWEPRC-UHFFFAOYSA-L 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 description 1
- 125000004619 benzopyranyl group Chemical group O1C(C=CC2=C1C=CC=C2)* 0.000 description 1
- 125000004196 benzothienyl group Chemical group S1C(=CC2=C1C=CC=C2)* 0.000 description 1
- 125000004541 benzoxazolyl group Chemical group O1C(=NC2=C1C=CC=C2)* 0.000 description 1
- NDKBVBUGCNGSJJ-UHFFFAOYSA-M benzyltrimethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)CC1=CC=CC=C1 NDKBVBUGCNGSJJ-UHFFFAOYSA-M 0.000 description 1
- ZDZHCHYQNPQSGG-UHFFFAOYSA-N binaphthyl group Chemical group C1(=CC=CC2=CC=CC=C12)C1=CC=CC2=CC=CC=C12 ZDZHCHYQNPQSGG-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- MUCRFDZUHPMASM-UHFFFAOYSA-N bis(2-chlorophenyl) carbonate Chemical compound ClC1=CC=CC=C1OC(=O)OC1=CC=CC=C1Cl MUCRFDZUHPMASM-UHFFFAOYSA-N 0.000 description 1
- ZFVMWEVVKGLCIJ-UHFFFAOYSA-N bisphenol AF Chemical compound C1=CC(O)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(O)C=C1 ZFVMWEVVKGLCIJ-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- FLLNLJJKHKZKMB-UHFFFAOYSA-N boron;tetramethylazanium Chemical compound [B].C[N+](C)(C)C FLLNLJJKHKZKMB-UHFFFAOYSA-N 0.000 description 1
- OCWYEMOEOGEQAN-UHFFFAOYSA-N bumetrizole Chemical compound CC(C)(C)C1=CC(C)=CC(N2N=C3C=C(Cl)C=CC3=N2)=C1O OCWYEMOEOGEQAN-UHFFFAOYSA-N 0.000 description 1
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 1
- QDHFHIQKOVNCNC-UHFFFAOYSA-N butane-1-sulfonic acid Chemical compound CCCCS(O)(=O)=O QDHFHIQKOVNCNC-UHFFFAOYSA-N 0.000 description 1
- ZWRWUGGYDBHANL-UHFFFAOYSA-N butyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCC)OC1=CC=CC=C1 ZWRWUGGYDBHANL-UHFFFAOYSA-N 0.000 description 1
- ZOAIGCHJWKDIPJ-UHFFFAOYSA-M caesium acetate Chemical compound [Cs+].CC([O-])=O ZOAIGCHJWKDIPJ-UHFFFAOYSA-M 0.000 description 1
- FJDQFPXHSGXQBY-UHFFFAOYSA-L caesium carbonate Chemical compound [Cs+].[Cs+].[O-]C([O-])=O FJDQFPXHSGXQBY-UHFFFAOYSA-L 0.000 description 1
- 229910000024 caesium carbonate Inorganic materials 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 239000004301 calcium benzoate Substances 0.000 description 1
- 235000010237 calcium benzoate Nutrition 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- HZQXCUSDXIKLGS-UHFFFAOYSA-L calcium;dibenzoate;trihydrate Chemical compound O.O.O.[Ca+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 HZQXCUSDXIKLGS-UHFFFAOYSA-L 0.000 description 1
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- BLUMOBPWAAOPOY-UHFFFAOYSA-M cesium;benzoate Chemical compound [Cs+].[O-]C(=O)C1=CC=CC=C1 BLUMOBPWAAOPOY-UHFFFAOYSA-M 0.000 description 1
- WLZGEDNSZCPRCJ-UHFFFAOYSA-M cesium;octadecanoate Chemical compound [Cs+].CCCCCCCCCCCCCCCCCC([O-])=O WLZGEDNSZCPRCJ-UHFFFAOYSA-M 0.000 description 1
- 125000000259 cinnolinyl group Chemical group N1=NC(=CC2=CC=CC=C12)* 0.000 description 1
- 239000008395 clarifying agent Substances 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 125000000392 cycloalkenyl group Chemical group 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- GLOQRSIADGSLRX-UHFFFAOYSA-N decyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCCCC)OC1=CC=CC=C1 GLOQRSIADGSLRX-UHFFFAOYSA-N 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229940099371 diacetylated monoglycerides Drugs 0.000 description 1
- PNOXNTGLSKTMQO-UHFFFAOYSA-L diacetyloxytin Chemical compound CC(=O)O[Sn]OC(C)=O PNOXNTGLSKTMQO-UHFFFAOYSA-L 0.000 description 1
- 125000004988 dibenzothienyl group Chemical group C1(=CC=CC=2SC3=C(C21)C=CC=C3)* 0.000 description 1
- QLVWOKQMDLQXNN-UHFFFAOYSA-N dibutyl carbonate Chemical compound CCCCOC(=O)OCCCC QLVWOKQMDLQXNN-UHFFFAOYSA-N 0.000 description 1
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- ZXDVQYBUEVYUCG-UHFFFAOYSA-N dibutyltin(2+);methanolate Chemical compound CCCC[Sn](OC)(OC)CCCC ZXDVQYBUEVYUCG-UHFFFAOYSA-N 0.000 description 1
- FYIBPWZEZWVDQB-UHFFFAOYSA-N dicyclohexyl carbonate Chemical compound C1CCCCC1OC(=O)OC1CCCCC1 FYIBPWZEZWVDQB-UHFFFAOYSA-N 0.000 description 1
- NMAKPIATXQEXBT-UHFFFAOYSA-N didecyl phenyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OC1=CC=CC=C1 NMAKPIATXQEXBT-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical class OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- WZPMZMCZAGFKOC-UHFFFAOYSA-N diisopropyl hydrogen phosphate Chemical compound CC(C)OP(O)(=O)OC(C)C WZPMZMCZAGFKOC-UHFFFAOYSA-N 0.000 description 1
- SMBQBQBNOXIFSF-UHFFFAOYSA-N dilithium Chemical class [Li][Li] SMBQBQBNOXIFSF-UHFFFAOYSA-N 0.000 description 1
- REKWWOFUJAJBCL-UHFFFAOYSA-L dilithium;hydrogen phosphate Chemical compound [Li+].[Li+].OP([O-])([O-])=O REKWWOFUJAJBCL-UHFFFAOYSA-L 0.000 description 1
- OXDOANYFRLHSML-UHFFFAOYSA-N dimethoxyphosphorylbenzene Chemical compound COP(=O)(OC)C1=CC=CC=C1 OXDOANYFRLHSML-UHFFFAOYSA-N 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- MKZVQIIAAIPNGH-UHFFFAOYSA-N dioctyl phenyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OC1=CC=CC=C1 MKZVQIIAAIPNGH-UHFFFAOYSA-N 0.000 description 1
- IJNMJRMPMZHRQQ-UHFFFAOYSA-N diphenylmethanone trihydrate Chemical compound O.O.O.O=C(C1=CC=CC=C1)C1=CC=CC=C1 IJNMJRMPMZHRQQ-UHFFFAOYSA-N 0.000 description 1
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 1
- KCIDZIIHRGYJAE-YGFYJFDDSA-L dipotassium;[(2r,3r,4s,5r,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl] phosphate Chemical class [K+].[K+].OC[C@H]1O[C@H](OP([O-])([O-])=O)[C@H](O)[C@@H](O)[C@H]1O KCIDZIIHRGYJAE-YGFYJFDDSA-L 0.000 description 1
- PXGLYSITKOROKV-UHFFFAOYSA-N dipropoxyphosphorylbenzene Chemical compound CCCOP(=O)(OCCC)C1=CC=CC=C1 PXGLYSITKOROKV-UHFFFAOYSA-N 0.000 description 1
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 1
- TYJOJLOWRIQYQM-UHFFFAOYSA-L disodium;phenyl phosphate Chemical compound [Na+].[Na+].[O-]P([O-])(=O)OC1=CC=CC=C1 TYJOJLOWRIQYQM-UHFFFAOYSA-L 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- HJJZFSVYWJHHFE-UHFFFAOYSA-N docosanoic acid;propane-1,2-diol Chemical compound CC(O)CO.CCCCCCCCCCCCCCCCCCCCCC(O)=O HJJZFSVYWJHHFE-UHFFFAOYSA-N 0.000 description 1
- MCPKSFINULVDNX-UHFFFAOYSA-N drometrizole Chemical compound CC1=CC=C(O)C(N2N=C3C=CC=CC3=N2)=C1 MCPKSFINULVDNX-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 125000002541 furyl group Chemical group 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- RZRNAYUHWVFMIP-HXUWFJFHSA-N glycerol monolinoleate Natural products CCCCCCCCC=CCCCCCCCC(=O)OC[C@H](O)CO RZRNAYUHWVFMIP-HXUWFJFHSA-N 0.000 description 1
- 229940049654 glyceryl behenate Drugs 0.000 description 1
- 229940080812 glyceryl caprate Drugs 0.000 description 1
- 229940074046 glyceryl laurate Drugs 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 125000004356 hydroxy functional group Chemical group O* 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 125000002883 imidazolyl group Chemical group 0.000 description 1
- 125000003453 indazolyl group Chemical group N1N=C(C2=C1C=CC=C2)* 0.000 description 1
- 125000003406 indolizinyl group Chemical group C=1(C=CN2C=CC=CC12)* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 125000000904 isoindolyl group Chemical group C=1(NC=C2C=CC=CC12)* 0.000 description 1
- XUGNVMKQXJXZCD-UHFFFAOYSA-N isopropyl palmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC(C)C XUGNVMKQXJXZCD-UHFFFAOYSA-N 0.000 description 1
- 125000002183 isoquinolinyl group Chemical group C1(=NC=CC2=CC=CC=C12)* 0.000 description 1
- 229960002479 isosorbide Drugs 0.000 description 1
- 125000000842 isoxazolyl group Chemical group 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- ACKFDYCQCBEDNU-UHFFFAOYSA-J lead(2+);tetraacetate Chemical compound [Pb+2].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O ACKFDYCQCBEDNU-UHFFFAOYSA-J 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- XIXADJRWDQXREU-UHFFFAOYSA-M lithium acetate Chemical compound [Li+].CC([O-])=O XIXADJRWDQXREU-UHFFFAOYSA-M 0.000 description 1
- 229940031993 lithium benzoate Drugs 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- HGPXWXLYXNVULB-UHFFFAOYSA-M lithium stearate Chemical compound [Li+].CCCCCCCCCCCCCCCCCC([O-])=O HGPXWXLYXNVULB-UHFFFAOYSA-M 0.000 description 1
- LDJNSLOKTFFLSL-UHFFFAOYSA-M lithium;benzoate Chemical compound [Li+].[O-]C(=O)C1=CC=CC=C1 LDJNSLOKTFFLSL-UHFFFAOYSA-M 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
- 239000011654 magnesium acetate Substances 0.000 description 1
- 235000011285 magnesium acetate Nutrition 0.000 description 1
- 229940069446 magnesium acetate Drugs 0.000 description 1
- QWDJLDTYWNBUKE-UHFFFAOYSA-L magnesium bicarbonate Chemical compound [Mg+2].OC([O-])=O.OC([O-])=O QWDJLDTYWNBUKE-UHFFFAOYSA-L 0.000 description 1
- 229910000022 magnesium bicarbonate Inorganic materials 0.000 description 1
- 239000002370 magnesium bicarbonate Substances 0.000 description 1
- 235000014824 magnesium bicarbonate Nutrition 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 1
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 235000019359 magnesium stearate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- JGIZKLDQCIOYLH-UHFFFAOYSA-L magnesium;phenyl phosphate Chemical compound [Mg+2].[O-]P([O-])(=O)OC1=CC=CC=C1 JGIZKLDQCIOYLH-UHFFFAOYSA-L 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000005499 meniscus Effects 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- ADFPJHOAARPYLP-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;styrene Chemical compound COC(=O)C(C)=C.C=CC1=CC=CC=C1 ADFPJHOAARPYLP-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- YJFCFSVVFTZXBL-UHFFFAOYSA-N o-[3-henicosanethioyloxy-2,2-bis(henicosanethioyloxymethyl)propyl] henicosanethioate Chemical compound CCCCCCCCCCCCCCCCCCCCC(=S)OCC(COC(=S)CCCCCCCCCCCCCCCCCCCC)(COC(=S)CCCCCCCCCCCCCCCCCCCC)COC(=S)CCCCCCCCCCCCCCCCCCCC YJFCFSVVFTZXBL-UHFFFAOYSA-N 0.000 description 1
- QJXZDBOIVBLYSJ-UHFFFAOYSA-N o-[3-heptadecanethioyloxy-2,2-bis(heptadecanethioyloxymethyl)propyl] heptadecanethioate Chemical compound CCCCCCCCCCCCCCCCC(=S)OCC(COC(=S)CCCCCCCCCCCCCCCC)(COC(=S)CCCCCCCCCCCCCCCC)COC(=S)CCCCCCCCCCCCCCCC QJXZDBOIVBLYSJ-UHFFFAOYSA-N 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- OTLDLKLSNZMTTA-UHFFFAOYSA-N octahydro-1h-4,7-methanoindene-1,5-diyldimethanol Chemical compound C1C2C3C(CO)CCC3C1C(CO)C2 OTLDLKLSNZMTTA-UHFFFAOYSA-N 0.000 description 1
- AXRSHKZFNKUGQB-UHFFFAOYSA-N octyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC)OC1=CC=CC=C1 AXRSHKZFNKUGQB-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- LYTNHSCLZRMKON-UHFFFAOYSA-L oxygen(2-);zirconium(4+);diacetate Chemical compound [O-2].[Zr+4].CC([O-])=O.CC([O-])=O LYTNHSCLZRMKON-UHFFFAOYSA-L 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000001792 phenanthrenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3C=CC12)* 0.000 description 1
- 125000004934 phenanthridinyl group Chemical group C1(=CC=CC2=NC=C3C=CC=CC3=C12)* 0.000 description 1
- 125000004625 phenanthrolinyl group Chemical group N1=C(C=CC2=CC=C3C=CC=NC3=C12)* 0.000 description 1
- 125000001791 phenazinyl group Chemical group C1(=CC=CC2=NC3=CC=CC=C3N=C12)* 0.000 description 1
- SMIZARYCGYRDGF-UHFFFAOYSA-N phenyl dipropan-2-yl phosphite Chemical compound CC(C)OP(OC(C)C)OC1=CC=CC=C1 SMIZARYCGYRDGF-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 239000004300 potassium benzoate Substances 0.000 description 1
- 235000010235 potassium benzoate Nutrition 0.000 description 1
- 229940103091 potassium benzoate Drugs 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 229940026235 propylene glycol monolaurate Drugs 0.000 description 1
- 125000003373 pyrazinyl group Chemical group 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- 125000002098 pyridazinyl group Chemical group 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 125000002294 quinazolinyl group Chemical group N1=C(N=CC2=CC=CC=C12)* 0.000 description 1
- 125000002943 quinolinyl group Chemical group N1=C(C=CC2=CC=CC=C12)* 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000012488 sample solution Substances 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229940100515 sorbitan Drugs 0.000 description 1
- 229950006451 sorbitan laurate Drugs 0.000 description 1
- 235000011067 sorbitan monolaureate Nutrition 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 229950004959 sorbitan oleate Drugs 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 239000001589 sorbitan tristearate Substances 0.000 description 1
- 235000011078 sorbitan tristearate Nutrition 0.000 description 1
- 229960004129 sorbitan tristearate Drugs 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229940114926 stearate Drugs 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- WJMMDJOFTZAHHS-UHFFFAOYSA-L strontium;carbonic acid;carbonate Chemical compound [Sr+2].OC([O-])=O.OC([O-])=O WJMMDJOFTZAHHS-UHFFFAOYSA-L 0.000 description 1
- RXSHXLOMRZJCLB-UHFFFAOYSA-L strontium;diacetate Chemical compound [Sr+2].CC([O-])=O.CC([O-])=O RXSHXLOMRZJCLB-UHFFFAOYSA-L 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- CXVGEDCSTKKODG-UHFFFAOYSA-N sulisobenzone Chemical compound C1=C(S(O)(=O)=O)C(OC)=CC(O)=C1C(=O)C1=CC=CC=C1 CXVGEDCSTKKODG-UHFFFAOYSA-N 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- LVEOKSIILWWVEO-UHFFFAOYSA-N tetradecyl 3-(3-oxo-3-tetradecoxypropyl)sulfanylpropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCC LVEOKSIILWWVEO-UHFFFAOYSA-N 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 description 1
- 125000003831 tetrazolyl group Chemical group 0.000 description 1
- 125000004627 thianthrenyl group Chemical group C1(=CC=CC=2SC3=CC=CC=C3SC12)* 0.000 description 1
- 125000001544 thienyl group Chemical group 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
- YJGJRYWNNHUESM-UHFFFAOYSA-J triacetyloxystannyl acetate Chemical compound [Sn+4].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O YJGJRYWNNHUESM-UHFFFAOYSA-J 0.000 description 1
- 125000004306 triazinyl group Chemical group 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 description 1
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
- CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
- QOQNJVLFFRMJTQ-UHFFFAOYSA-N trioctyl phosphite Chemical compound CCCCCCCCOP(OCCCCCCCC)OCCCCCCCC QOQNJVLFFRMJTQ-UHFFFAOYSA-N 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- AJHKJOCIGPIJFZ-UHFFFAOYSA-N tris(2,6-ditert-butylphenyl) phosphite Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1OP(OC=1C(=CC=CC=1C(C)(C)C)C(C)(C)C)OC1=C(C(C)(C)C)C=CC=C1C(C)(C)C AJHKJOCIGPIJFZ-UHFFFAOYSA-N 0.000 description 1
- QEDNBHNWMHJNAB-UHFFFAOYSA-N tris(8-methylnonyl) phosphite Chemical compound CC(C)CCCCCCCOP(OCCCCCCCC(C)C)OCCCCCCCC(C)C QEDNBHNWMHJNAB-UHFFFAOYSA-N 0.000 description 1
- QQBLOZGVRHAYGT-UHFFFAOYSA-N tris-decyl phosphite Chemical compound CCCCCCCCCCOP(OCCCCCCCCCC)OCCCCCCCCCC QQBLOZGVRHAYGT-UHFFFAOYSA-N 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- IFNXAMCERSVZCV-UHFFFAOYSA-L zinc;2-ethylhexanoate Chemical compound [Zn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O IFNXAMCERSVZCV-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Abstract
According to the present invention, there can be provided a thermoplastic resin comprising 22 to 49 mol% of a structural unit (a) derived from a diol represented by the following general formula (1A), 40 to 75 mol% of a structural unit (B) derived from a diol represented by the following general formula (2A), and 0 to 15 mol% of a structural unit (C) derived from a diol represented by the following general formula (3A), based on the total amount (100 mol%) of the structural units in the resin.
Description
Technical Field
The present invention relates to a thermoplastic resin and an optical lens comprising the same. More particularly, the present invention relates to a polycarbonate resin and an optical lens comprising the same.
Background
As a material of an optical lens used in an optical system of various cameras such as a camera, a film-integrated camera, a video camera, and the like, an optical glass or an optical resin is used. The optical glass is excellent in heat resistance, transparency, dimensional stability, chemical resistance, etc., but has problems of high material cost, poor molding processability, and low productivity.
On the other hand, an optical lens made of an optical resin has an advantage that mass production can be performed by injection molding, and as a high refractive index material for a camera lens, polycarbonate, polyester carbonate, polyester resin, or the like is used.
When an optical resin is used as an optical lens, it is required to have heat resistance, transparency, low water absorption, chemical resistance, low birefringence, moist heat resistance, and the like in addition to optical characteristics such as refractive index and abbe number. In particular, in recent years, optical lenses having a high refractive index and high heat resistance have been demanded, and various resins have been developed (patent documents 1 to 5).
In addition, thermoplastic resins using 2,2 '-bis (2-hydroxyethoxy) -1,1' -binaphthyl as a raw material have excellent optical characteristics and are useful as various optical materials (patent document 6). However, due to the expansion of various molding processes and use environments, it is required to increase the birefringence in the lens surface.
In recent years, development of resins having a high refractive index has been demanded due to the thinness, shortness and smallness of the articles. In general, when the refractive index of the optical material is high, a lens element having the same refractive index can be realized with a surface having a smaller curvature, and thus the amount of aberration generated by the surface can be reduced. As a result, the number of lenses can be reduced, the decentering sensitivity of the lenses can be reduced, and the thickness of the lenses can be reduced, thereby realizing weight reduction.
In addition, in general, in an optical system of a camera, aberration correction is performed by combining a plurality of concave lenses and convex lenses. That is, for chromatic aberration generated by the convex lens, chromatic aberration is synthetically canceled by combining the convex lens with a concave lens having chromatic aberration of opposite sign. At this time, the concave lens is required to have high dispersion (i.e., low abbe number).
Therefore, a resin for an optical lens having a high refractive index and a low abbe number has been developed. For example, patent document 7 discloses that a copolymer of a bisphenol a type polycarbonate structural unit and a structural unit represented by the following formula (E) improves the refractive index. In the example of patent document 7, it is described that the refractive index reaches 1.62 to 1.64 and the abbe number reaches 23 to 26. Such an increase in refractive index is thought to be due to the structural unit represented by formula (E).
Further, patent document 8 discloses a copolymer of a polycarbonate resin having a structural unit having a fluorene structure and bisphenol a. Examples of this document describe refractive indices up to 1.616 to 1.636. The structural unit disclosed in this document is different from the formula (E).
As described above, polycarbonate resins and optical lenses having a high refractive index and a low abbe number have not been provided yet.
In recent years, a polycarbonate resin and an optical lens having a small absolute value of birefringence strength and a small in-plane birefringence have been demanded.
Prior art literature
Patent literature
Patent document 1: japanese patent laid-open publication No. 2018-2893
Patent document 2: japanese patent application laid-open No. 2018-2894
Patent document 3: japanese patent application laid-open No. 2018-2895
Patent document 4: japanese patent laid-open No. 2018-59074
Patent document 5: WO2017/078073
Patent document 6: WO2014/073496
Patent document 7: international publication No. 2007/142149
Patent document 8: japanese patent laid-open No. 6-25398
Disclosure of Invention
Technical problem to be solved by the invention
The technical problems to be solved by the invention are as follows: provided are a thermoplastic resin which has excellent optical characteristics such as refractive index, abbe number and haze and also has excellent birefringence in a lens surface, and an optical lens using the same. Moreover, the technical problems to be solved by the invention are as follows: provided are a polycarbonate resin having a high refractive index and a low Abbe number, and having a small absolute value of birefringence strength and a small in-plane birefringence, and an optical lens using the same.
Technical scheme for solving technical problems
The inventors of the present invention have conducted intensive studies to solve the above-mentioned problems, and as a result, have found that: the present invention has been completed by adding a diol compound having a specific structure in a specific amount to obtain a thermoplastic resin having excellent optical characteristics such as refractive index, abbe number and haze and also excellent birefringence in the lens surface. It was also found that: the above technical problems can be solved by the following polycarbonate resin and optical lens, and the present invention has been completed.
That is, the present invention includes the following means.
<1> A thermoplastic resin comprising, relative to the total amount (100 mol%) of structural units in the resin, 22 to 49 mol% of structural units (A) derived from a diol represented by the following general formula (1A), 40 to 75 mol% of structural units (B) derived from a diol represented by the following general formula (2A), and 0 to 15 mol% of structural units (C) derived from a diol represented by the following general formula (3A),
In the general formula (1A), R a、Rb、Raa and R bb are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
A and b each independently represent an integer of 0 to 10,
In the general formula (2A), R c and R d are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 30 carbon atoms which may have a substituent, a heteroaryl group having 6 to 30 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
C and d each independently represent an integer of 0 to 10,
In the general formula (3A), R e and R f are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
E and f each independently represent an integer of 0 to 10.
<2> The thermoplastic resin according to the above <1>, wherein the proportion of the structural unit (A) derived from the diol represented by the above general formula (1A) is 24 to 47 mol%, the proportion of the structural unit (B) derived from the diol represented by the above general formula (2A) is 45 to 70 mol%, and the proportion of the structural unit (C) derived from the diol represented by the above general formula (3A) is 0 to 8 mol%, based on the total amount (100 mol%) of the structural units in the resin.
<3> The thermoplastic resin according to the above <1> or <2>, wherein the diol represented by the above general formula (1) comprises a diol represented by the following structural formula,
<4> The thermoplastic resin according to any one of the above <1> to <3>, wherein the diol represented by the above general formula (2A) comprises at least one of the diols represented by the following structural formulas,
<5> The thermoplastic resin according to any one of the above <1> to <4>, wherein the diol represented by the above general formula (3A) comprises a diol represented by the following structural formula,
<6> The thermoplastic resin according to any one of the above <1> to <5>, wherein the thermoplastic resin is a polycarbonate resin.
<7> The thermoplastic resin according to any one of the above <1> to <6>, wherein the thermoplastic resin further comprises a structural unit derived from at least one monomer selected from the group consisting of,
In the above formula, R 1 and R 2 each independently represent a hydrogen atom, a methyl group or an ethyl group, and R 3 and R 4 each independently represent a hydrogen atom, a methyl group, an ethyl group or an alkylene glycol having 2 to 5 carbon atoms.
<8> The thermoplastic resin according to any one of <1> to <7>, wherein the thermoplastic resin has an in-lens-surface birefringence of 1 to 21.
<9> The thermoplastic resin according to any one of <1> to <8>, wherein the weight average molecular weight (Mw) of the thermoplastic resin in terms of polystyrene is 10,000 ~ 100,000.
<10> The thermoplastic resin according to any one of <1> to <9>, wherein the refractive index (nD) of the thermoplastic resin is 1.650 to 1.695.
<11> The thermoplastic resin according to any one of <1> to <10>, wherein the thermoplastic resin has an Abbe number (. Nu.) of 16.0 to 21.0.
<12> The thermoplastic resin according to any one of <1> to <11>, wherein the glass transition temperature of the thermoplastic resin is 130 to 190 ℃.
<13> The thermoplastic resin according to any one of <1> to <12>, wherein the thermoplastic resin has a melt volume flow rate (MVR) of 20 to 55.
<14> The thermoplastic resin according to any one of <1> to <13>, wherein the thermoplastic resin has a haze of 0.01 to 1.00.
<15> An optical member comprising the thermoplastic resin according to any one of the above <1> to <14 >.
<16> An optical lens comprising the thermoplastic resin according to any one of the above <1> to <14 >.
<17> An optical film comprising the thermoplastic resin according to any one of the above <1> to <14 >.
<18> A polycarbonate resin comprising a structural unit represented by the following general formula (1B), a structural unit represented by the following general formula (2B) and a structural unit represented by the following general formula (3B),
The proportion of the structural unit represented by the following general formula (1B) is 1 mol% or more and less than 10 mol%,
The proportion of the structural unit represented by the following general formula (2B) is 10 to 60 mol%,
The proportion of the structural unit represented by the following general formula (3B) is 5 to 80 mol%,
In the general formula (1B), X represents an alkylene group having 1 to 4 carbon atoms, and a and B each independently represent an integer of 1 to 10;
In the general formula (2B), Y represents an alkylene group having 1 to 4 carbon atoms, and c and d each independently represent an integer of 1 to 10;
in the general formula (3B),
Z represents an alkylene group having 1 to 4 carbon atoms,
R 1~R6 each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, a cycloalkoxy group having 5 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an aryloxy group having 6 to 20 carbon atoms,
E and f each independently represent an integer of 0 to 5.
<19> The polycarbonate resin as described in <18> above, wherein,
The proportion of the structural unit represented by the above general formula (1B) is 2 to 9 mol%,
The proportion of the structural unit represented by the general formula (2B) is 20 to 60 mol%,
The proportion of the structural unit represented by the general formula (3B) is 30 to 70 mol%.
<20> An optical lens comprising the polycarbonate resin according to <18> or <19 >.
Effects of the invention
According to the present invention, it is possible to provide a thermoplastic resin excellent in optical characteristics such as refractive index, abbe number and haze and also excellent in-plane birefringence, and an optical lens comprising the same. Further, according to the present invention, there can be provided a polycarbonate resin having a high refractive index and a low abbe number, and having a small absolute value of birefringence and a small in-plane birefringence, and an optical lens comprising the same.
Detailed Description
The present invention will be described in detail by way of examples, and the like, but the present invention is not limited to the examples, and the like, and can be modified to any method without significantly departing from the scope of the present invention.
First embodiment
< Thermoplastic resin >
The first embodiment of the present invention is a thermoplastic resin comprising 22 to 49 mol% of a structural unit (a) derived from a diol represented by the following general formula (1A), 40 to 75 mol% of a structural unit (B) derived from a diol represented by the following general formula (2A), and 0 to 15 mol% of a structural unit (C) derived from a diol represented by the following general formula (3A), based on the total amount (100 mol%) of the structural units in the resin.
[ Structural Unit (A) derived from a diol represented by the general formula (1A) ]
In the general formula (1A), R a、Rb、Raa and R bb are each independently selected from a hydrogen atom, a halogen atom (fluorine atom, chlorine atom, bromine atom or iodine atom), an alkyl group having 1 to 20 carbon atoms (preferably an alkyl group having 1 to 6 carbon atoms) which may have a substituent, an alkoxy group having 1 to 20 carbon atoms (preferably an alkoxy group having 1 to 6 carbon atoms) which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms (preferably a cycloalkyl group having 5 to 10 carbon atoms) which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms (preferably a cycloalkoxy group having 5 to 10 carbon atoms) which may have a substituent, an aryl group having 6 to 20 carbon atoms (preferably an aryl group having 6 to 12 carbon atoms) which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms (preferably a heteroaryl group having 6 to 12 carbon atoms) which may have a heterocyclic atom selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms (preferably a c≡c) which may have a substituent, and an aryloxy group having a c≡c h.
Preferably, R a and R b each independently represent a hydrogen atom, a methyl group, an ethyl group or a phenyl group, and R aa and R bb each independently represent a hydrogen atom or a phenyl group.
R h in the above-mentioned-C.ident.C-R h represents an aryl group having 6 to 20 carbon atoms (preferably an aryl group having 6 to 12 carbon atoms) which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms (preferably a heteroaryl group having 6 to 12 carbon atoms) which contains 1 or more hetero ring atoms selected from O, N and S and may have a substituent.
X independently represents an alkylene group having 1 to 5 carbon atoms (preferably an alkylene group having 1 to 3 carbon atoms, more preferably an ethylene group) which may have a substituent.
A and b each independently represent an integer of 0 to 10, preferably an integer of 1 to 3, and more preferably 1.
In the present specification, examples of the substituent "which may have a substituent" include halogen, cyano, alkyl having 1 to 20 carbon atoms, and aryl having 6 to 12 carbon atoms.
In one embodiment of the present invention, the structural unit (A) derived from the diol represented by the above general formula (1A) is
When used as an optical lens, it is preferable because of good balance between refractive index and Abbe number.
The above structural units are derived from BPEF (9, 9-bis [4- (2-hydroxyethoxy) phenyl ] fluorene) represented by the following structural formula and OPPFL (9, 9-bis [4- (2-hydroxyethoxy) -3-phenylphenyl ] fluorene) represented by the following structural formula, respectively, and in the present invention, commercially available products or synthetic products may be used.
[ Structural Unit (B) derived from a diol represented by the general formula (2A) ]
In the general formula (2A), R c and R d are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 30 carbon atoms which may have a substituent, a heteroaryl group having 6 to 30 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
C and d each independently represent an integer of 0 to 10.
R c and R d in the general formula (2A) are each independently preferably a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkoxy group having 1 to 4 carbon atoms, or an aryl group having 6 to 30 carbon atoms, more preferably an aryl group having 6 to 20 carbon atoms, and still more preferably an aryl group having 6 to 14 carbon atoms. It is preferable that at least one of R c and R d in the general formula (2A) is an aryl group having 6 to 20 carbon atoms, more preferably an aryl group having 6 to 14 carbon atoms, and particularly preferably both of R c and R d are aryl groups having 6 to 14 carbon atoms or 6 to 12 carbon atoms.
R c and R d may be the same or different and may be selected from a monocyclic or polycyclic aryl group having 6 to 30 carbon atoms or a monocyclic or polycyclic heterocyclic aryl group having 5 to 36 ring atoms, wherein 1,2, 3 or 4 ring atoms of the heterocyclic aryl group are selected from nitrogen, sulfur and oxygen, and the other ring atoms are carbon. Wherein the mono-or polycyclic aryl group and the mono-or polycyclic heteroaryl group may be unsubstituted.
R c and R d are each selected from the group described below. That is to say,
Azulene group (azulenyl);
an unsubstituted indenyl group, or an indenyl group which may be substituted with 2, 3, 4 or 5 substituents selected from phenyl groups and polycyclic aryl groups which may be bonded to each other by a single bond, may be directly condensed with each other and/or may be condensed with a saturated or unsaturated 4 to 10 membered ring monocyclic or bicyclic hydrocarbon ring and have 2, 3 or 4 benzene rings;
Unsubstituted phenyl;
Phenyl which may be substituted by 1 or 2 CN groups;
Phenyl which may be substituted by 2, 3,4 or 5 substituents selected from phenyl and polycyclic aryl groups which may be bonded to each other by a single bond, may be condensed directly with each other and/or may be condensed with saturated or unsaturated 4 to 10 membered ring monocyclic or bicyclic hydrocarbon rings and have 2, 3 or 4 benzene rings;
Polycyclic aryl groups which may be directly condensed with each other and/or may be condensed with saturated or unsaturated 4-to 10-membered monocyclic or bicyclic hydrocarbon rings and which have 2,3 or 4 benzene rings may be unsubstituted or substituted with 1 or 2 substituents selected from phenyl groups and polycyclic aryl groups having 2 or 3 benzene rings, 2 or 3 of the benzene rings may be bonded to each other by a single bond, may be directly condensed with each other and/or may be condensed with saturated 4-to 10-membered monocyclic or bicyclic hydrocarbon rings, and the benzene rings of polycyclic aryl groups may be unsubstituted or have 1 or 2 substituents R a.
In addition, R c and R d may be each selected from the following group. That is to say,
Unsubstituted phenyl, or phenyl which may be substituted by 1,2, 3, 4 or 5 phenyl groups;
phenyl substituted with 1 or 2 CN groups;
phenyl substituted with 1 or 2 polycyclic aryl groups selected from biphenyl, naphthyl, fluorenyl, anthracyl, phenanthryl, and pyrenyl, and further substituted with 1 phenyl group;
Unsubstituted naphthyl, or naphthyl substituted with 1 or 2 substituents selected from CN, phenyl, polycyclic aryl selected from biphenyl, naphthyl, fluorenyl, anthracenyl, phenanthrenyl, and pyrenyl;
A biphenyl group; a triphenyl group; tetraphenyl; phenanthryl; pyrenyl; 9H-fluorenyl; dibenzo [ a, e ] [8] cycloalkenyl, perylene, and 9,9' -spirodi [ 9H-fluorene ] groups.
Among them, R c and R d are preferably selected from phenyl, 2-cyanophenyl, 3-cyanophenyl, 4-cyanophenyl, 2-naphthyl, 1-naphthyl and 9-naphthyl.
In addition, R c and R d may be each selected from the following groups. That is to say,
A heteroaromatic monocyclic group of 5 or 6 ring atoms having 1,2,3 or 4 nitrogen atoms, or having 1 oxygen atom and 0, 1,2 or 3 nitrogen atoms, or having 1 sulfur atom and 0, 1,2 or 3 nitrogen atoms, the other ring atoms being carbon atoms;
A heteroaromatic polycyclic group having the above aromatic monocyclic ring and 1,2,3, 4 or 5 additional aromatic rings selected from the group consisting of phenyl and heteroaromatic monocyclic rings, the (hetero) aromatic rings of the polycyclic heteroaryl group being bonded to each other by covalent bonds, being condensed directly with each other, and/or being condensed with a saturated or unsaturated 4-to 10-membered monocyclic hydrocarbon ring; and
A heteroaromatic polycyclic group having: a heterocyclic ring containing at least 1 saturated or partially unsaturated 5-or 6-membered ring containing 1 or 2 heteroatoms selected from oxygen, sulfur and nitrogen as ring atoms; and 1, 2,3, 4 or 5 further aromatic rings selected from phenyl and the above heteroaromatic monocyclic rings, at least 1 further of the above aromatic rings being directly condensed with a saturated or partially unsaturated 5-or 6-membered heterocyclic group, the other further aromatic rings of the polycyclic heteroaryl aromatic rings being bonded to each other by covalent bonds or being directly condensed with each other and/or being condensed with a saturated or unsaturated 4-to 10-membered mono-or bi-cyclic hydrocarbon ring.
In addition, R c and R d may be each selected from the following groups. That is to say, furyl, thienyl, pyrrolyl, imidazolyl, pyrazolyl, 1,2, 3-triazolyl, 1,2, 4-triazolyl, tetrazolyl, oxazolyl, isoxazolyl, 1,3, 4-oxadiazolyl, 1,2, 4-oxadiazolyl, pyridyl, pyrazinyl, pyridazinyl, pyrimidinyl, triazinyl, benzofuranyl, dibenzofuranyl, benzothienyl, dibenzothienyl, thianthrenyl, naphthofuranyl, furo [3,2-b ] furanyl, furo [2,3-b ] furanyl, furo [3,4-b ] furanyl, oxazolyl (oxanthrenyl), indolyl, isoindolyl, carbazolyl, indolizinyl, benzopyrazolyl, benzimidazolyl, benzoxazolyl, benzo [ cd ] indolyl, 1H-benzo [ g ] indolyl, quinolinyl, isoquinolinyl, acridinyl, phenazinyl, quinazolinyl, quinoxalinyl phenoxazinyl, benzo [ b ] [1,5] naphthyridinyl, cinnolinyl, 1, 5-naphthyridinyl, 1, 8-naphthyridinyl, phenylpyrrolyl, naphthyridinyl, bipyridinyl, phenylpyridinyl, naphthyridinyl, pyrido [4,3-b ] indolyl, pyrido [3,2-g ] quinolinyl, pyrido [2,3-b ] [1,8] naphthyridinyl, pyrrolo [3,2-b ] pyridinyl, pteridinyl (pteridinyl), purinyl (purinyl), 9H-xanthenyl (xanthenyl), 2H-benzopyranyl, phenanthridinyl, phenanthrolinyl, furo [3,2-f ] [1] benzofuranyl, furo [2,3-f ] [1] benzofuranyl, furo [3,2-g ] quinolinyl, furo [2,3-g ] pyrrolyl, benzoo [3, 3-g ] benzopyranyl, benzoo [3,2-g ] pyrrolyl, benzopyrrolyl (xanthenyl), benzo [ g ] quinoxalinyl, benzo [ f ] quinoxalinyl and benzo [ h ] isoquinolinyl.
X in the general formula (2A) is independently preferably an alkylene group having 2 to 4 carbon atoms, more preferably an alkylene group having 2 or 3 carbon atoms, particularly preferably an ethylene group.
In the general formula (2A), c and d are each independently preferably an integer of 1 to 6, more preferably an integer of 1 to 4, and particularly preferably 2 or 3.
The diol represented by the above general formula (2A) preferably contains at least one of the diols represented by the following structural formulas.
[ Structural Unit (C) derived from a diol represented by the general formula (3A) ]
In the general formula (3A), R e and R f are each independently selected from a hydrogen atom, a halogen atom (fluorine atom, chlorine atom, bromine atom or iodine atom), an alkyl group having 1 to 20 carbon atoms (preferably an alkyl group having 1 to 6 carbon atoms) which may have a substituent, an alkoxy group having 1 to 20 carbon atoms (preferably an alkoxy group having 1 to 6 carbon atoms) which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms (preferably a cycloalkyl group having 5 to 10 carbon atoms) which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms (preferably a cycloalkoxy group having 5 to 10 carbon atoms) which may have a substituent, an aryl group having 6 to 20 carbon atoms (preferably an aryl group having 6 to 12 carbon atoms) which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms (preferably a heteroaryl group having 6 to 12 carbon atoms) which may have 1 or more hetero atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms (preferably a C.ident.6 to 20 carbon atoms) which may have a substituent, and a C. h aryl group having C.ident.,
Preferably, R e and R f each independently represent a hydrogen atom or a phenyl group.
R h in the above-mentioned-C.ident.C-R h represents an aryl group having 6 to 20 carbon atoms (preferably an aryl group having 6 to 12 carbon atoms) which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms (preferably a heteroaryl group having 6 to 12 carbon atoms) which contains 1 or more hetero ring atoms selected from O, N and S and may have a substituent.
X independently represents an alkylene group having 1 to 5 carbon atoms (preferably an alkylene group having 1 to 3 carbon atoms, more preferably an ethylene group) which may have a substituent.
E and f each independently represent an integer of 0 to 10, preferably an integer of 1 to 3, more preferably 1.
In one embodiment of the present invention, it is particularly preferable that the diol represented by the above general formula (3A) is NOLE (9, 9-bis [6- (2-hydroxyethoxy) -2-naphthyl ] fluorene) represented by the following structural formula, and in the present invention, a commercially available product or a synthetic product may be used.
One embodiment of the present invention is a thermoplastic resin containing 22 to 49 mol% (preferably 22 to 47 mol%, more preferably 26 to 45 mol%) of a structural unit (a) derived from a diol represented by the above general formula (1A), 40 to 75 mol% (preferably 45 to 70 mol%, more preferably 40 to 65 mol%) of a structural unit (B) derived from a diol represented by the above general formula (2A), and 0 to 15 mol% (preferably 0 to 8 mol%, more preferably 0 to 6 mol%) of a structural unit (C) derived from a diol represented by the above general formula (3A) with respect to the total amount (100 mol%) of the structural units in the resin.
The thermoplastic resin according to one embodiment of the present invention may be a polyester resin, a polycarbonate resin, a polyester carbonate resin, an epoxy resin, a polyurethane resin, a polyacrylate resin, a polymethacrylate resin, or the like, but is not particularly limited, and is preferably a polycarbonate resin, a polyester resin, or a polyester carbonate resin, and more preferably a polycarbonate resin.
In the thermoplastic resin according to an embodiment of the present invention, the proportion of the total of the structural units (a), (B) and (C) in the total of the structural units is preferably 80 to 100 mol%, more preferably 90 to 100 mol%, and particularly preferably 100 mol% of the total of the structural units.
That is, the thermoplastic resin according to one embodiment of the present invention may contain, in addition to the structural units (a) to (C), structural units derived from an aliphatic dihydroxy compound and/or structural units derived from an aromatic dihydroxy compound, which are generally used as structural units of a polycarbonate resin and/or a polyester carbonate resin, within a range that does not impair the effects of the present invention.
Specifically, examples of the aliphatic dihydroxy compound include various compounds, particularly 1, 4-cyclohexanedimethanol, tricyclodecanedimethanol, 1, 3-adamantanedimethanol, 2-bis (4-hydroxycyclohexyl) -propane, 3, 9-bis (2-hydroxy-1, 1-dimethylethyl) -2,4,8, 10-tetraoxaspiro [5.5] undecane, 2- (5-ethyl-5-hydroxymethyl-1, 3-dioxane-2-yl) -2-methylpropan-1-ol, isosorbide, 1, 3-propanediol, 1, 4-butanediol, 1, 6-hexanediol, and the like.
Examples of the aromatic dihydroxy compound include various compounds, particularly 2, 2-bis (4-hydroxyphenyl) propane (bisphenol A), bis (4-hydroxyphenyl) methane, 1-bis (4-hydroxyphenyl) ethane, 2-bis (4-hydroxy-3, 5-dimethylphenyl) propane, 4' -dihydroxybiphenyl, bis (4-hydroxyphenyl) cycloalkane, bis (4-hydroxyphenyl) oxide, bis (4-hydroxyphenyl) sulfide, bis (4-hydroxyphenyl) sulfone, bis (4-hydroxyphenyl) sulfoxide, bis (4-hydroxyphenyl) ketone, diphenoxyglycolfluorene and the like.
The thermoplastic resin according to one embodiment of the present invention also preferably further contains a structural unit derived from at least one monomer selected from the following monomer groups.
In the above formula, R 1 and R 2 each independently represent a hydrogen atom, a methyl group or an ethyl group, and R 3 and R 4 each independently represent a hydrogen atom, a methyl group, an ethyl group or an alkylene glycol having 2 to 5 carbon atoms.
In the polycarbonate resin according to a preferred embodiment of the present invention, alcohol compounds such as phenol compounds that are produced as by-products during production, unreacted and residual diol components or carbonic acid diester may be present as impurities.
Since alcohol compounds such as phenol compounds and carbonic acid diesters as impurities also cause a decrease in strength after forming a molded article and an odor, the content of these compounds is preferably as small as possible.
The content of the remaining phenolic compound is preferably 3000 mass ppm or less, more preferably 1000 mass ppm or less, and particularly preferably 300 mass ppm or less, based on 100 mass% of the polycarbonate resin.
The content of the residual diol component is preferably 1000 mass ppm or less, more preferably 100 mass ppm or less, and particularly preferably 10 mass ppm or less, based on 100 mass% of the polycarbonate resin.
The content of the residual carbonic acid diester is preferably 1000 mass ppm or less, more preferably 100 mass ppm or less, and particularly preferably 10 mass ppm or less, based on 100 mass% of the polycarbonate resin.
In particular, the content of the compounds such as phenol and tert-butylphenol is preferably small, and these compounds are preferably within the above-mentioned range.
The content of the remaining phenolic compound in the polycarbonate resin can be measured by a method of analyzing the phenolic compound extracted from the polycarbonate resin by using gas chromatography.
The content of the alcohol compound remaining in the polycarbonate resin can also be measured by a method of analyzing the alcohol compound extracted from the polycarbonate resin by using gas chromatography.
The content of the diol component and the carbonic acid diester remaining in the polycarbonate resin can also be measured by extracting these compounds from the polycarbonate resin and analyzing them by gas chromatography.
The content of the by-product alcohol compound such as the phenol compound, the diol component and the carbonic acid diester can be reduced to an undetectable level, but may be contained in a small amount within a range that does not impair the effect from the viewpoint of productivity. In addition, if the amount is small, the plasticity can be improved when the resin is melted.
The content of each of the residual phenolic compound, diol component and carbonic acid diester may be, for example, 0.01 mass ppm or more, 0.1 mass ppm or more, or 1 mass ppm or more with respect to 100 mass ppm of the polycarbonate resin.
The content of the remaining alcohol compound may be, for example, 0.01 mass ppm or more, 0.1 mass ppm or more, or 1 mass ppm or more with respect to 100 mass% of the polycarbonate resin.
The content of the by-product alcohol compound such as the phenol compound, the diol component, and the carbonic acid diester in the polycarbonate resin can be adjusted to the above range by appropriately adjusting the polycondensation conditions, the setting of the apparatus, and the like. In addition, the conditions of the extrusion process after polycondensation may be adjusted.
For example, the residual amount of the by-product alcohol compound such as the phenol compound is related to the type of carbonic acid diester used in the polymerization of the polycarbonate resin, the polymerization temperature, the polymerization pressure, and the like. By adjusting these conditions, the residual amount of the by-product alcohol compound such as the phenol compound can be reduced.
For example, when a polycarbonate resin is produced using a dialkyl carbonate such as diethyl carbonate, the molecular weight tends to be less likely to increase, and the content of a by-product alkyl alcohol compound tends to increase because a low molecular weight polycarbonate is formed. Such an alkyl alcohol has high volatility, and once it remains in the polycarbonate resin, the moldability of the resin tends to be deteriorated. In addition, when the residual amount of the by-product alcohol compound such as the phenol compound is large, there is a possibility that a problem of odor generation occurs during resin molding or a cleavage reaction of the resin skeleton occurs during compounding, resulting in a decrease in molecular weight. Accordingly, the content of the by-product alcohol compound remaining in the obtained polycarbonate resin is preferably 3000 mass ppm or less with respect to the polycarbonate resin (100 mass%). The content of the remaining alcohol compound is preferably 3000 mass ppm or less, more preferably 1000 mass ppm or less, and particularly preferably 300 mass ppm or less, based on 100 mass% of the polycarbonate resin.
< Physical Properties of thermoplastic resin >
(1) Refractive index (nD)
In one embodiment of the present invention, one of the characteristics of the thermoplastic resin is a high refractive index, preferably 1.650 to 1.695, more preferably 1.660 to 1.690, particularly preferably 1.662 to 1.689. In the present invention, the refractive index can be measured by the method described in examples described below.
(2) Abbe number (v)
In one embodiment of the present invention, the thermoplastic resin has an Abbe number of preferably 16.0 to 21.0, more preferably 16.3 to 20.5, particularly preferably 16.6 to 20.2. In the present invention, the Abbe number can be measured by the method described in examples described below.
(3) Glass transition temperature (Tg)
In one embodiment of the present invention, one of the characteristics of the thermoplastic resin is high heat resistance, and the glass transition temperature (Tg) is preferably 130 to 190 ℃, more preferably 135 to 180 ℃, particularly preferably 140 to 165 ℃. In the present invention, the glass transition temperature can be measured by the method described in examples described below.
(4) Weight average molecular weight (Mw) in terms of polystyrene
In one embodiment of the present invention, the weight average molecular weight of the thermoplastic resin in terms of polystyrene is preferably 10,000 ~ 100,000, more preferably 20,000 ~ 70,000, particularly preferably 30,000 ~ 60,000.
(5) Melt volume flow Rate (MVR)
In one embodiment of the present invention, the thermoplastic resin preferably has a melt volume flow rate (MVR) of 20 to 55, more preferably 25 to 50, particularly preferably 30 to 45. In the present invention, the melt volume flow rate (MVR) can be measured by the method described in examples described below.
(6) Haze degree
In one embodiment of the present invention, the haze of the thermoplastic resin is preferably 0.01 to 1.00, more preferably 0.05 to 0.50, and particularly preferably 0.10 to 0.30. In the present invention, haze can be measured by the method described in examples described below.
(7) Internal birefringence of lens face
In one embodiment of the present invention, the thermoplastic resin preferably has an in-lens-surface birefringence of 1 to 21, more preferably 2 to 15, and particularly preferably 2 to 13. In the present invention, the transparent in-plane birefringence can be measured by the method described in examples described below.
< Thermoplastic resin composition >
Another embodiment of the present invention is a thermoplastic resin composition containing the above thermoplastic resin and an additive. The thermoplastic resin composition of the present embodiment may be used in combination with a resin other than the thermoplastic resin of the present invention containing the above-mentioned structural units (a), (B) and (C) within a range that does not impair the intended effects of the present embodiment. The resin is not particularly limited, and examples thereof include at least one resin selected from the group consisting of polycarbonate resins, polyester carbonate resins, (meth) acrylic resins, polyamide resins, polystyrene resins, cycloolefin resins, acrylonitrile-butadiene-styrene copolymer resins, vinyl chloride resins, polyphenylene ether resins, polysulfone resins, polyacetal resins, and methyl methacrylate-styrene copolymer resins. These resins may be used in various known products, and may be added to the thermoplastic resin composition singly or in combination of two or more.
[ Antioxidant ]
The thermoplastic resin composition preferably contains an antioxidant as the above additive.
The antioxidant preferably contains at least one of a phenolic antioxidant and a phosphite antioxidant.
Examples of the phenolic antioxidants include 1,3, 5-tris (3, 5-di-t-butyl-4-hydroxyphenylmethyl) -2,4, 6-trimethylbenzene, 1,3, 5-tris (3, 5-di-t-butyl-4-hydroxybenzyl) -1,3, 5-triazine-2, 4,6- (1H, 3H, 5H) -trione, 4' - (1-methylpropanoyl-3-ylidene) tris (6-t-butylm-cresol), 6' -di-t-butyl-4, 4' -butylidenemethyl phenol, 3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate octadecyl ester, pentaerythritol-tetrakis [3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate ], 3, 9-bis {2- [3- (3-t-butyl-4-hydroxy-5-methylphenyl) propionyloxy ] -1, 1-dimethylethyl } -2,4,8, 10-tetraoxaspiro [5.5] undecyl ] pentaerythritol-tetrakis [3- (3, 5-di-t-butyl-4-hydroxyphenyl) propionate ] pentaerythritol-tetrakis [3, 5-di-t-butyl-4-hydroxyphenyl ] propionate.
Examples of the phosphite-based antioxidant include 2-ethylhexyl diphenyl phosphite, isodecyl diphenyl phosphite, triisodecyl phosphite, triphenyl phosphite, 3, 9-bis (octadecylacyloxy) -2,4,8, 10-tetraoxa-3, 9-diphosphaspiro [5.5] undecane, 3, 9-bis (2, 6-di-tert-butyl-4-methylphenoxy) -2,4,8, 10-tetraoxa-3, 9-diphosphaspiro [5.5] undecane, 2' -methylenebis (4, 6-di-tert-butylphenyl) 2-ethylhexyl phosphite, tris (2, 4-di-tert-butylphenyl) phosphite, tris (nonylphenyl) phosphite, and tetra-C12-15 alkyl (propane-2, 2-diylbis (4, 1-phenylene)) bisphosphite, and 3, 9-bis (2, 6-di-tert-butyl-4-methylphenoxy) -2,4,8, 10-tetraoxa-3, 9-diphosphaspiro [5.5] undecane are preferable.
As the antioxidant, only any one of the above-mentioned may be used, or a mixture of two or more kinds may be used.
In the present invention, 5, 7-di-t-butyl-3- (3, 4-dimethylphenyl) -3H-benzofuran-2-one may be used as an antioxidant other than a phenol-based antioxidant and a phosphite-based antioxidant.
The antioxidant is preferably contained in the thermoplastic resin composition in an amount of 1 to 3000 ppm by weight based on the total weight of the resin composition. The content of the antioxidant in the thermoplastic resin composition is more preferably 50 to 2500 ppm by weight, still more preferably 100 to 2000 ppm by weight, particularly preferably 150 to 1500 ppm by weight, still more preferably 200 to 1500 ppm by weight.
[ Release agent ]
The thermoplastic resin composition preferably contains a release agent as the above additive.
Examples of the release agent include ester compounds, for example, fatty acid glycerides such as monoglycerides and diglycerides of glycerin fatty acid, glycol fatty acid esters such as propylene glycol fatty acid esters and sorbitan fatty acid esters, higher alcohol fatty acid esters, full esters of aliphatic polyhydric alcohols and aliphatic carboxylic acids, and mono fatty acid esters. When an ester of an aliphatic polyol and an aliphatic carboxylic acid is used as the release agent, any of a monoester, a full ester, and the like may be used, and for example, an ester other than the full ester such as a monoester may be used.
Specific examples of the release agent include the following.
That is, sorbitan fatty acid esters such as sorbitan stearate, sorbitan laurate, sorbitan oleate, sorbitan trioleate, sorbitan tribehenate, sorbitan stearate, sorbitan tristearate, and sorbitan caprylate;
propylene glycol fatty acid esters such as propylene glycol monostearate, propylene glycol monooleate, propylene glycol monobehenate, propylene glycol monolaurate and propylene glycol monopalmitate;
Higher alcohol fatty acid esters such as stearyl stearate;
Glycerol fatty acid ester monoglycerides including glycerol monostearate, glycerol mono-hydroxystearate and glycerol mono-12-hydroxystearate, glycerol monooleate, glycerol monobehenate, glycerol monocaprylate, glycerol monocaprate, monoglycerides such as glycerol monolaurate, glycerol mono/distearate, glycerol mono/dibuch, glycerol mono/dioleate and glycerol mono/diglycerol esters such as glycerol mono/dioleate;
acetylated monoglycerides of glycerol fatty acid esters such as diacetyl monolaurate;
Organic acid monoglycerides such as citric acid fatty acid monoglyceride, succinic acid fatty acid monoglyceride, diacetyl tartaric acid fatty acid monoglyceride, and the like;
Polyglyceryl fatty acid esters such as diglyceryl stearate, diglyceryl laurate, diglyceryl oleate, diglyceryl monostearate, diglyceryl monolaurate, diglyceryl monomyristate, diglyceryl monooleate, tetraglyceryl stearate, decaglyceryl laurate, decaglyceryl oleate, polyglyceryl polyricinoleate, and the like.
Among them, glycerol monostearate is preferable as the release agent.
The release agent is preferably contained in the thermoplastic resin composition in an amount of 1 to 5000 ppm by weight based on the total weight of the resin composition. The content of the release agent in the thermoplastic resin composition is more preferably 50 to 4000 ppm by weight, still more preferably 100 to 3500 ppm by weight, particularly preferably 500 to 13000 ppm by weight, still more preferably 1000 to 2500 ppm by weight.
[ Other additives ]
In addition to the above-mentioned antioxidant and release agent, other additives may be added to the thermoplastic resin composition. Examples of the additives that may be contained in the thermoplastic resin composition include complexing agents, catalyst deactivators, heat stabilizers, plasticizers, fillers, ultraviolet absorbers, rust inhibitors, dispersants, defoamers, leveling agents, flame retardants, lubricants, dyes, pigments, bluing agents, nucleating agents, clarifying agents, and the like.
The content of the antioxidant and the additive other than the release agent in the thermoplastic resin composition is preferably 10 to 5.0 wt%, more preferably 100 to 2.0 wt%, still more preferably 1000 to 1.0 wt%, but is not limited thereto.
The above additives may adversely affect the transmittance, and therefore are preferably excessively added, for example, the total amount added is within the above range.
In the method for producing a thermoplastic resin composition of the present invention, the catalyst may be removed or deactivated after completion of the polymerization reaction in order to maintain thermal stability and hydrolytic stability, but it is not necessarily deactivated. In order to deactivate the catalyst, a method of deactivating the catalyst by adding a known acidic substance may be suitably carried out. Esters such as butyl benzoate are particularly suitable for use as the acidic substance; aromatic sulfonic acids such as p-toluenesulfonic acid; aromatic sulfonates such as butyl p-toluenesulfonate and hexyl p-toluenesulfonate; phosphoric acids such as phosphorous acid, phosphoric acid, and phosphonic acid; phosphites such as triphenyl phosphite, monophenyl phosphite, diphenyl phosphite, diethyl phosphite, di-n-propyl phosphite, di-n-butyl phosphite, di-n-hexyl phosphite, dioctyl phosphite, and monooctyl phosphite; phosphate esters such as triphenyl phosphate, diphenyl phosphate, monophenyl phosphate, dibutyl phosphate, dioctyl phosphate, and monooctyl phosphate; phosphonic acids such as diphenylphosphonic acid, dioctylphosphonic acid, dibutylphosphonic acid, and the like; phosphonates such as diethyl phenylphosphonate; phosphines such as triphenylphosphine and bis (diphenylphosphine) ethane; boric acids such as boric acid and phenylboric acid; aromatic sulfonates such as tetrabutylphosphonium dodecylbenzenesulfonate; organic halides such as stearoyl chloride, benzoyl chloride and p-toluenesulfonyl chloride; alkyl sulfates such as dimethyl sulfate; organic halides such as benzyl chloride, and the like. From the viewpoints of the effect of the inactivating agent, stability against resin, and the like, p-toluene or butyl sulfonate or tetrabutylphosphonium dodecylbenzenesulfonate is particularly preferable. These deactivators are used in an amount of 0.01 to 50 mol, preferably 0.3 to 20 mol, based on the amount of the catalyst. When the amount is less than 0.01 times by mol, the deactivation effect is insufficient, which is not preferable. When the amount is more than 50 times by mole based on the amount of the catalyst, the heat resistance of the resin is lowered, and the molded article is liable to be colored, which is not preferable.
The kneading of the deactivator may be performed immediately after completion of the polymerization reaction, or may be performed after granulating the polymerized resin. In addition, other additives other than the deactivator may be added by the same method.
< Optical Member >
The thermoplastic resin or thermoplastic resin composition (hereinafter simply referred to as "resin composition") of the present invention can be applied to an optical member. In one embodiment of the present invention, there is provided an optical member containing the resin composition of the present invention. In one embodiment of the present invention, the optical member includes, but is not limited to, an optical disc, a transparent conductive substrate, an optical card, a sheet, a film, an optical fiber, a lens, a prism, an optical film, a base, an optical filter, a hard coat film, and the like. The resin composition of the present invention is particularly suitable for producing a thin optical member because it has high flowability and can be molded by a casting method. In a preferred embodiment of the present invention, the optical member manufactured using the resin composition of the present invention may be an optical lens. In another preferred embodiment of the present invention, the optical member manufactured using the resin composition of the present invention may be an optical film.
When an optical member containing the resin composition of the present invention is produced by injection molding, it is preferable to mold it under the conditions of a cylinder temperature of 260 to 350℃and a mold temperature of 90 to 170 ℃. More preferably, the molding is performed at a cylinder temperature of 270 to 320℃and a mold temperature of 100 to 160 ℃. When the barrel temperature is higher than 350 ℃, cracking and coloring of the resin composition occur; when the temperature is less than 260 ℃, the melt viscosity increases, which tends to cause difficulty in molding. Further, when the mold temperature is higher than 170 ℃, it is easy to cause difficulty in removing a molded article made of the resin composition from the mold. On the other hand, when the mold temperature is lower than 90 ℃, the resin is cured prematurely in the mold at the time of molding, resulting in difficulty in controlling the shape of the molded sheet or in sufficiently transferring the shape attached to the mold.
< Optical lens >
In one embodiment of the present invention, the resin composition can be applied to an optical lens. The optical lens produced using the resin composition of the present invention has a high refractive index and excellent heat resistance, and therefore can be used in the field of conventional expensive high refractive index glass lenses such as telescopes, binoculars, television projectors, and the like, and is therefore extremely useful.
For example, in the lens of a smart phone, it is possible to mold a lens from a thermoplastic resin containing the structural units (A), (B) and (C), or a lens from a thermoplastic resin containing a thermoplastic resin derived from the structural units (A), (B) and (C)
Resin molded lens stacks of structural units of any one of the above formulas, in which R 1 and R 2 each independently represent a hydrogen atom, a methyl group or an ethyl group, and R 3 and R 4 each independently represent a hydrogen atom, a methyl group, an ethyl group or an alkylene glycol having 2 to 5 carbon atoms, are used as lens units.
The optical lens of the present invention can be realized by using an aspherical lens form as needed. Since the aspherical lens can realize substantially zero spherical aberration with one lens, it is not necessary to combine a plurality of spherical lenses to eliminate spherical aberration, and it is possible to reduce the weight and the molding cost. Therefore, an aspherical lens is useful as an optical lens, particularly as a camera lens.
Further, since the optical lens of the present invention has high molding fluidity, it is particularly useful as a material for thin, small and complex optical lenses. The thickness of the center portion is preferably 0.05 to 3.0mm, more preferably 0.05 to 2.0mm, and still more preferably 0.1 to 2.0mm, as a specific lens size. The diameter is preferably 1.0 to 20.0mm, more preferably 1.0 to 10.0mm, and still more preferably 3.0 to 10.0mm. In addition, a meniscus lens having a convex surface and a concave surface is preferable as the shape.
The optical lens of the present invention may be molded by any method such as mold molding, cutting, grinding, laser processing, electric discharge processing, etching, and the like. Among them, mold molding is more preferable in terms of manufacturing cost.
< Optical film >
In one embodiment of the present invention, the resin composition can be applied to an optical film. In particular, the optical film produced using the polycarbonate resin of the present invention is excellent in transparency and heat resistance, and therefore can be suitably used for a film for a liquid crystal substrate, an optical memory card, and the like.
In order to avoid the contamination of foreign matter into the optical film as much as possible, the molding environment is of course also required to be a low-dust environment, preferably 6 or less, more preferably 5 or less.
Second embodiment
< Polycarbonate resin >
The second embodiment of the present invention is a polycarbonate resin containing a structural unit represented by the following general formula (1B), a binaphthyl derivative unit represented by the following general formula (2B), and a fluorene derivative unit represented by the following general formula (3B).
In the general formula (1B), X represents an alkylene group having 1 to 4 carbon atoms, and a and B each independently represent an integer of 1 to 10;
In the general formula (2B), Y represents an alkylene group having 1 to 4 carbon atoms, and c and d each independently represent an integer of 1 to 10;
In the general formula (3B), Z represents an alkylene group having 1 to 4 carbon atoms, R 1~R6 each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, a cycloalkoxy group having 5 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aryloxy group having 6 to 20 carbon atoms, and e and f each independently represent an integer of 0 to 5.
The polycarbonate resin of the present invention is preferably substantially composed of structural units represented by the general formulae (1B) to (3B). In the present specification, "substantially consist of" means that the polycarbonate resin of the present invention may contain other structural units within a range that does not impair the effects of the present invention. For example, in the structural unit of the polycarbonate resin of the present invention, the structural unit represented by the general formulae (1B) to (3B) is preferably 90% or more, more preferably 95% or more, and still more preferably 98% or more.
In the polycarbonate resin of the present invention, the proportion of the structural unit represented by the general formula (1B) is 1 mol% or more and less than 10 mol%, the proportion of the structural unit represented by the general formula (2B) is 10 to 60 mol%, and the proportion of the structural unit represented by the general formula (3B) is 5 to 80 mol%. In addition, since a resin having a small absolute value of the birefringence strength and a small birefringence index in the lens surface can be obtained, the ratio of the structural unit represented by the general formula (1B) is preferably 2 to 9 mol%, the ratio of the structural unit represented by the general formula (2B) is preferably 20 to 60 mol%, the ratio of the structural unit represented by the general formula (3B) is preferably 30 to 70 mol%, the ratio of the structural unit represented by the general formula (1B) is particularly preferably 3 to 8 mol%, the ratio of the structural unit represented by the general formula (2B) is preferably 30 to 60 mol%, and the ratio of the structural unit represented by the general formula (3B) is preferably 40 to 60 mol%.
The polycarbonate resin of the present invention is not particularly limited as to how the structural units represented by the general formulae (1B) to (3B) are contained in the resin. In one embodiment of the present invention, the polycarbonate resin may contain a copolymer containing structural units represented by the general formulae (1B) to (3B), or may be a ternary resin containing a homopolymer formed of each structural unit. Or may be a blend of a copolymer comprising structural units represented by the general formulae (1B) and (2B) and a homopolymer comprising structural units represented by the general formula (3B), or may be a blend of a copolymer comprising structural units represented by the general formulae (1B) and (2B) and a copolymer comprising structural units represented by the general formulae (1B) and (3B).
The polycarbonate resin of the present invention may comprise any of random, block and alternating copolymer structures.
The polycarbonate resin of the present invention preferably has a weight average molecular weight (Mw) of 20,000 ~ 200,000 in terms of polystyrene. The weight average molecular weight (Mw) in terms of polystyrene is more preferably 25,000 ~ 120,000, still more preferably 28,000 ~ 55,000, particularly preferably 30,000 ~ 45,000.
When the Mw is less than 20,000, the molded body becomes brittle, and is thus not preferable; if the Mw exceeds 200,000, the melt viscosity increases, which is not preferable because the resin after production is difficult to take out and the fluidity is poor, and injection molding is difficult to achieve in a molten state.
The refractive index (nD) of the polycarbonate resin of the present invention at 23℃and a wavelength of 589nm is preferably 1.635 to 1.695, more preferably 1.640 to 1.690, still more preferably 1.645 to 1.685, and particularly preferably 1.650 to 1.680. The polycarbonate resin of the present invention has a high refractive index (nD) and is suitable for use as an optical lens material. The refractive index may be measured by Abbe refractometer according to JIS B7071-2: 2018 was measured on a film having a thickness of 0.1 mm.
The Abbe number (. Nu.) of the polycarbonate resin of the present invention is preferably 24 or less, more preferably 22 or less, and still more preferably 21 or less. Abbe numbers can be calculated based on refractive indices of 486nm, 589nm, 656nm at 23℃using the following formulas.
ν=(nD-1)/(nF-nC)
ND: refractive index at wavelength 589nm
NC: refractive index at 656nm
NF: refractive index at wavelength 486nm
The melt volume flow rate (MVR) of the polycarbonate resin of the present invention is preferably 10 to 100, more preferably 30 to 100, particularly preferably 30 to 50. In the present invention, MVR can be measured by the method described in examples described below.
The polycarbonate resin of the present invention preferably has a birefringence strength of-0.6 to +0.7, more preferably-0.5 to +0.5, and particularly preferably-0.3 to +0.3. In the present invention, the birefringence intensity can be measured by the method described in examples described below.
The in-plane birefringence of the polycarbonate resin of the present invention is preferably 0.1 to 15, more preferably 1 to 10, and particularly preferably 2 to 7. In the present invention, the in-plane birefringence of the lens can be measured by the method described in examples described below.
The haze of the polycarbonate resin of the present invention is preferably 0.05 to 3.00, more preferably 0.10 to 2.00. In the present invention, haze can be measured by the method described in examples described below.
The polycarbonate resin of the present invention can be blended with other resins for the production of molded articles. Examples of the other resin include polyamide, polyacetal, polycarbonate, modified polyphenylene ether, polyethylene terephthalate, polybutylene terephthalate, and the like.
The polycarbonate resin of the present invention may further contain an antioxidant, a mold release agent, an ultraviolet absorber, a fluidity improver, a crystallization nucleating agent, a reinforcing agent, a dye, an antistatic agent, an antibacterial agent, and the like.
Examples of the molding method include, but are not limited to, compression molding, injection molding, roll processing, extrusion molding, and stretching.
When the polycarbonate resin of the present invention is used for injection molding, the glass transition temperature (Tg) is preferably 90 to 180 ℃, more preferably 95 to 175 ℃, still more preferably 100 to 170 ℃, still more preferably 130 to 170 ℃, particularly preferably 135 to 150 ℃. When Tg is lower than 90 ℃, the use temperature range becomes narrow, and thus is not preferable. When the temperature exceeds 180 ℃, the melting temperature of the resin increases, and cracking and coloring of the resin easily occur, so that it is not preferable. When the glass transition temperature of the resin is too high, in the general-purpose mold temperature controller, the difference between the mold temperature and the glass transition temperature of the resin increases. Therefore, in applications requiring strict surface accuracy for products, it is difficult to use a resin having an excessively high glass transition temperature, which is not preferable. In addition, from the viewpoint of molding fluidity and molding heat resistance, the lower limit value of Tg is preferably 130 ℃, more preferably 135 ℃, and the upper limit value of Tg is preferably 160 ℃, more preferably 150 ℃.
The amount of residual phenol contained in the polycarbonate resin of the present invention is preferably 500ppm or less, more preferably 300ppm or less, and still more preferably 50ppm or less.
The amount of residual diphenyl carbonate (DPC) contained in the polycarbonate resin of the present invention is preferably 200ppm or less, more preferably 100ppm or less, and still more preferably 50ppm or less.
< Method for producing polycarbonate resin >
The polycarbonate resin having the structural units represented by the general formulae (1B) to (3B) of the present invention can be produced by reacting a compound represented by the following general formulae (4B) to (6B) with a carbonate precursor such as a carbonic acid diester as a dihydroxy component. Specifically, the catalyst is produced by reacting a compound represented by the general formulae (4B) to (6B) with a carbonate precursor such as a carbonic acid diester in the presence of a basic compound catalyst, a transesterification catalyst, or a mixed catalyst containing both, or by a melt polycondensation method in the absence of a catalyst.
In the general formula (4B), X represents an alkylene group having 1 to 4 carbon atoms, and a and B each independently represent an integer of 1 to 10;
In the general formula (5B), Y represents an alkylene group having 1 to 4 carbon atoms, and c and d each independently represent an integer of 1 to 10;
In the general formula (6B), Z represents an alkylene group having 1 to 4 carbon atoms, R 1~R6 each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, a cycloalkoxy group having 5 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, or an aryloxy group having 6 to 20 carbon atoms, and e and f each independently represent an integer of 0 to 5.
The compound of the general formula (4B) may be 9, 9-bis (hydroxy (poly) alkoxynaphthyl) fluorene. Examples of the compound of the general formula (4) include 9, 9-bis [6- (1-hydroxy methoxy) naphthalen-2-yl ] fluorene, 9-bis [6- (2-hydroxy ethoxy) naphthalen-2-yl ] fluorene, 9-bis [6- (3-hydroxy propoxy) naphthalen-2-yl ] fluorene, and 9, 9-bis [6- (4-hydroxy butoxy) naphthalen-2-yl ] fluorene. Of these, 9-bis [6- (2-hydroxyethoxy) naphthalen-2-yl ] fluorene is preferable. These compounds may be used alone or in combination of two or more.
In the production of the compound of the general formula (4B), a compound having either one of a and B as an impurity of 0 may be produced as an impurity. The content of such impurities in the monomer containing the compound of the general formula (4B) as a main component is preferably 1000ppm or less, more preferably 500ppm or less, further preferably 200ppm or less, particularly preferably 100ppm or less in total. Besides these impurities, fluorenone, which is one of the raw materials, may be contained as an impurity. The fluorenone content in the monomer containing the compound of the general formula (4B) as a main component is preferably 1000ppm or less, more preferably 100ppm or less, further preferably 50ppm or less, particularly preferably 10ppm or less. Fluorenone contained in a monomer containing a compound of the general formula (4B) as a main component may remain in the resin after polymerization. The smaller the fluorenone content, the better the hue of the resin, and thus is preferable. Further, although not an impurity, the total of the compounds having a and B different from each other (i.e., a+.b) in the general formula (4B) in the monomer containing the compound of the general formula (4B) as a main component is preferably 50ppm or less, more preferably 20ppm or less.
The compound of the general formula (4B) can be produced by various synthetic methods. For example, as described in Japanese patent No. 5442800, 9-bis (hydroxynaphthalene) fluorene is produced by a method of reacting fluorenones with hydroxynaphthalene in the presence of hydrogen chloride gas and mercapto carboxylic acid, (b) a method of reacting 9-fluorenones with hydroxynaphthalene in the presence of an acid catalyst (and alkyl mercaptan), (c) a method of reacting fluorenones with hydroxynaphthalene in the presence of hydrochloric acid and mercaptans (mercapto carboxylic acid, etc.), and (d) a method of reacting fluorenones with hydroxynaphthalene in the presence of sulfuric acid and mercaptans (mercapto carboxylic acid, etc.), and crystallizing by a crystallization solvent composed of hydrocarbons and polar solvents. For example, 9-bis [6- (2-hydroxyethoxy) naphthyl ] fluorene can be obtained by reacting 9, 9-bis [ 6-hydroxynaphthyl ] fluorene with 2-chloroethanol under alkaline conditions.
Examples of the dihydroxy compound represented by general formula (5B) include 2,2 '-bis (1-hydroxymethyl) -1,1' -binaphthyl, 2 '-bis (2-hydroxyethoxy) -1,1' -binaphthyl, 2 '-bis (3-hydroxypropoxy) -1,1' -binaphthyl, 2 '-bis (4-hydroxybutoxy) -1,1' -binaphthyl and the like. Among them, 2 '-bis (2-hydroxyethoxy) -1,1' -binaphthyl (hereinafter sometimes abbreviated as "BHEBN") is preferable. These compounds may be used alone or in combination of two or more.
When the compound of the general formula (5B) is produced, a compound having either one of c and d of 0 may be produced as an impurity. The content of such impurities in the monomer containing the compound of the general formula (5B) as a main component is preferably 1000ppm or less, more preferably 500ppm or less, further preferably 200ppm or less, particularly preferably 100ppm or less in total. Further, although not an impurity, the compounds of the general formula (5B) in which c and d are different (i.e., c+.d) are preferably 50ppm or less, more preferably 20ppm or less in total, in the monomer containing the compound of the general formula (5B) as a main component.
Examples of the dihydroxy compound represented by general formula (6B) include 9, 9-bis [4- (2-hydroxyethoxy) phenyl ] fluorene (hereinafter, abbreviated as "BPEF" in some cases), 9-bis [4- (2-hydroxyethoxy) -3-methylphenyl ] fluorene, 9-bis [4- (2-hydroxyethoxy) -3-tert-butylphenyl ] fluorene, 9-bis [4- (2-hydroxyethoxy) -3-isopropylphenyl ] fluorene, 9-bis [4- (2-hydroxyethoxy) -3-cyclohexylphenyl ] fluorene, 9-bis [4- (2-hydroxyethoxy) -3-phenylphenyl ] fluorene (hereinafter, abbreviated as "BPPEF" in some cases), and the like. Among them, 9-bis [4- (2-hydroxyethoxy) phenyl ] fluorene and 9, 9-bis [4- (2-hydroxyethoxy) -3-phenylphenyl ] fluorene are preferable. These compounds may be used alone or in combination of two or more.
When the compound of the general formula (6B) is produced, a compound having either one of e and f of 0 may be produced as an impurity. The content of such impurities in the monomer containing the compound of the general formula (6B) as a main component is preferably 1000ppm or less, more preferably 500ppm or less, further preferably 200ppm or less, particularly preferably 100ppm or less in total. Further, although not an impurity, the compounds having e and f different from each other (that is, e.noteq.f) in the general formula (6B) are preferably 50ppm or less, more preferably 20ppm or less in total in the monomer containing the compound of the general formula (6B) as a main component.
Examples of the aromatic dihydroxy compound which may be used in combination other than the above include bisphenol A, bisphenol AP, bisphenol AF, bisphenol B, bisphenol BP, bisphenol C, bisphenol E, bisphenol F, bisphenol G, bisphenol M, bisphenol S, bisphenol P, bisphenol PH, bisphenol TMC, bisphenol Z, and the like.
Examples of the carbonic acid diester used in the present invention include diphenyl carbonate, ditolyl carbonate, bis (chlorophenyl) carbonate, m-tolyl carbonate, dimethyl carbonate, diethyl carbonate, dibutyl carbonate, dicyclohexyl carbonate and the like. Among them, diphenyl carbonate is particularly preferable. The diphenyl carbonate is preferably used in a proportion of 0.97 to 1.20 mol, more preferably 0.98 to 1.10 mol, based on 1 mol of the total of the dihydroxy compounds.
Among the transesterification catalysts, alkali metal compounds, alkaline earth metal compounds, nitrogen-containing compounds, and the like are particularly exemplified as the basic compound catalyst.
Examples of the alkali metal compound used in the present invention include organic acid salts, inorganic salts, oxides, hydroxides, hydrides, alkoxides, and the like of alkali metals. Specifically, sodium hydroxide, potassium hydroxide, cesium hydroxide, lithium hydroxide, sodium hydrogencarbonate, sodium carbonate, potassium carbonate, cesium carbonate, lithium carbonate, sodium acetate, potassium acetate, cesium acetate, lithium acetate, sodium stearate, potassium stearate, cesium stearate, lithium stearate, sodium borohydride, sodium benzoborate, sodium benzoate, potassium benzoate, cesium benzoate, lithium benzoate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, dilithium hydrogen phosphate, disodium phenylphosphate, disodium salt, dipotassium salt, cesium salt or dilithium salt of bisphenol a, sodium salt, potassium salt, cesium salt or lithium salt of phenol, and the like can be used.
Examples of the alkaline earth metal compound include organic acid salts, inorganic salts, oxides, hydroxides, hydrides, alkoxides, and the like of the alkaline earth metal compound. Specifically, magnesium hydroxide, calcium hydroxide, strontium hydroxide, barium hydroxide, magnesium bicarbonate, calcium bicarbonate, strontium bicarbonate, barium bicarbonate, magnesium carbonate, calcium carbonate, strontium carbonate, barium carbonate, magnesium acetate, calcium acetate, strontium acetate, barium acetate, magnesium stearate, calcium benzoate, magnesium phenylphosphate, and the like can be used.
Examples of the nitrogen-containing compound include quaternary ammonium hydroxides, salts thereof, amines, and the like. Specific examples thereof include quaternary ammonium hydroxides having an alkyl group, an aryl group, and the like, such as tetramethylammonium hydroxide, tetraethylammonium hydroxide, tetrapropylammonium hydroxide, tetrabutylammonium hydroxide, and trimethylbenzylammonium hydroxide; tertiary amines such as triethylamine, dimethylbenzylamine and triphenylamine; secondary amines such as diethylamine and dibutylamine; primary amines such as propylamine and butylamine; imidazoles such as 2-methylimidazole, 2-phenylimidazole, and benzimidazole; or an alkali or basic salt such as ammonia, tetramethylammonium borohydride, tetrabutylammonium tetraphenylborate, or tetraphenylammonium tetraphenylborate.
As the transesterification catalyst, salts of zinc, tin, zirconium, lead, etc. are preferably used, and these compounds may be used alone or in combination.
Specific examples of the transesterification catalyst include zinc acetate, zinc benzoate, zinc 2-ethylhexanoate, tin (II) chloride, tin (IV) chloride, tin (II) acetate, tin (IV) acetate, dibutyltin dilaurate, dibutyltin oxide, dibutyldimethoxytin, zirconium acetylacetonate, zirconium oxyacetate, zirconium tetrabutoxide, lead (II) acetate, and lead (IV) acetate.
These catalysts may be used in a proportion of 1X 10 -9~1×10-3 mol, preferably 1X 10 -7~1×10-4 mol, based on 1 mol of the total dihydroxy compounds.
The melt polycondensation method is a method of performing melt polycondensation while removing by-products by transesterification under normal pressure or reduced pressure using the above raw materials and a catalyst.
In the melt polycondensation of the component system of the present invention, it is desirable that the compounds represented by the general formulae (4B) to (6B) and the carbonic acid diester are melted in a reaction vessel and then reacted in a state where the by-product monohydroxy compound is retained. In order to achieve the retention, the reaction device may be closed, or pressure control such as pressure reduction or pressure increase may be performed. The reaction time in this step is 20 minutes to 240 minutes, preferably 40 minutes to 180 minutes, and particularly preferably 60 minutes to 150 minutes. In this case, if distilled off immediately after the formation of the by-product monohydroxy compound, the content of the high molecular weight product of the finally obtained polycarbonate resin is reduced. However, if the by-product monohydroxy compound is allowed to remain in the reaction vessel for a certain period of time, the content of the high molecular weight product of the finally obtained polycarbonate resin is large.
The melt polycondensation reaction may be carried out continuously or batchwise. The reaction apparatus used in the reaction may be a vertical apparatus including an anchor type stirring blade, MAXBLEND stirring blade, ribbon type stirring blade, or the like, a horizontal apparatus including a paddle blade, a lattice blade, a spectacle type blade, or the like, or an extruder type apparatus including a screw. In addition, it is preferable to use a reaction apparatus in which these reaction apparatuses are appropriately combined in consideration of the viscosity of the polymer.
In the method for producing a polycarbonate resin used in the present invention, after the polymerization reaction is completed, the catalyst may be removed or deactivated in order to maintain thermal stability and hydrolytic stability. A method of inactivating the catalyst by adding a known acidic substance can be preferably performed. Specific examples of the acidic substance include esters such as butyl benzoate and aromatic sulfonic acids such as p-toluenesulfonic acid; aromatic sulfonates such as butyl p-toluenesulfonate and hexyl p-toluenesulfonate; phosphoric acids such as phosphorous acid, phosphoric acid, and phosphonic acid; phosphites such as triphenyl phosphite, monophenyl phosphite, diphenyl phosphite, diethyl phosphite, di-n-propyl phosphite, di-n-butyl phosphite, di-n-hexyl phosphite, dioctyl phosphite, and monooctyl phosphite; phosphate esters such as triphenyl phosphate, diphenyl phosphate, monophenyl phosphate, dibutyl phosphate, dioctyl phosphate, and monooctyl phosphate; phosphonic acids such as diphenylphosphonic acid, dioctylphosphonic acid, dibutylphosphonic acid, and the like; phosphonates such as diethyl phenylphosphonate; phosphines such as triphenylphosphine and bis (diphenylphosphino) ethane; boric acids such as boric acid and phenylboric acid; aromatic sulfonates such as tetrabutylphosphonium dodecylbenzenesulfonate; organic halides such as stearoyl chloride, benzoyl chloride and p-toluenesulfonyl chloride; alkyl sulfuric acid such as dimethyl sulfuric acid; organic halides such as benzyl chloride, and the like. Among them, butyl p-toluenesulfonate and tetrabutylphosphonium dodecylbenzenesulfonate are particularly preferably used. These deactivators are used in an amount of 0.01 to 50 mol per mol of the catalyst, preferably 0.3 to 20 mol per mol of the catalyst. When the amount is less than 0.01 times by mole, the deactivation effect may be insufficient, which is not preferable. In addition, when the amount of the catalyst is more than 50 times by mol, the heat resistance of the resin tends to be low, and the molded article tends to be colored, which is not preferable.
After the deactivation of the catalyst, a step of devolatilizing and removing the low boiling point compounds in the polymer at a pressure of 0.1 to 1mmHg and a temperature of 200 to 350 ℃ may be provided. In this step, a horizontal type apparatus or a thin film evaporator having stirring paddles excellent in surface renewal such as paddle blades, lattice blades, and spectacle blades can be preferably used.
The polycarbonate resin of the present invention preferably contains as little foreign matter as possible, and is preferably obtained by filtering a molten raw material, filtering a catalyst liquid, or the like. The mesh size of the filter is preferably 5 μm or less, more preferably 1 μm or less. The resin produced is preferably filtered by a polymer filter. The mesh size of the polymer filter is preferably 100 μm or less, more preferably 30 μm or less. The step of collecting the resin pellets is, of course, required to be a low-dust environment, and is preferably 6 or less, more preferably 5 or less.
In another embodiment of the present invention, in the case of producing a polycarbonate resin containing structural units represented by the general formulae (1B) to (3B), a copolymer containing structural units represented by the general formulae (1B) to (3B) may be produced using compounds represented by the general formulae (4B) to (6B), or a ternary resin containing homopolymers of the respective structural units may be produced by polymerizing the compounds represented by the general formulae (4B) to (6B). Alternatively, the copolymer containing the structural units represented by the general formulae (1B) and (2B) may be blended after polymerization with the homopolymer containing the structural unit represented by the general formula (3B), or the copolymer containing the structural units represented by the general formulae (1B) and (2B) may be blended after polymerization with the copolymer containing the structural units represented by the general formulae (1B) and (3B).
< Optical molded body >
The polycarbonate resin of the present invention can be used to produce an optical molded article. The molding can be performed by any method such as injection molding, compression molding, extrusion molding, or solution casting. The polycarbonate resin of the present invention is excellent in moldability and heat resistance, and therefore can be used particularly advantageously in an optical lens requiring injection molding. In molding, the polycarbonate resin of the present invention may be used by mixing with other resins such as other polycarbonate resins and polyester resins. In addition, additives such as antioxidants, processing stabilizers, light stabilizers, polymeric metal deactivators, flame retardants, slip agents, antistatic agents, surfactants, antibacterial agents, mold release agents, ultraviolet absorbers, plasticizers, and compatibilizers may be blended.
Examples of the antioxidant include triethylene glycol-bis [3- (3-tert-butyl-5-methyl-4-hydroxyphenyl) propionate ], 1, 6-hexanediol-bis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], pentaerythritol-tetrakis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], octadecyl-3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate, 1,3, 5-trimethyl-2, 4, 6-tris (3, 5-di-tert-butyl-4-hydroxybenzyl) benzene, N, N-hexamethylenebis (3, 5-di-tert-butyl-4-hydroxy-hydrocinnamamide), 3, 5-di-tert-butyl-4-hydroxy-benzylphosphonate-diethyl ester, tris (3, 5-di-tert-butyl-4-hydroxybenzyl) isocyanurate, 3, 9-bis {1, 1-dimethyl-2- [ β - (3-tert-butyl-4-hydroxy-5-methylphenyl) propionyloxy ] ethyl } -2,4,8, 10-tetraoxaspiro (5.5) undecane, 5, 7-di-tert-butyl-3- (3, 4-dimethylphenyl) -3H-benzofuran-2-one, 3, 9-bis (2, 6-di-tert-butyl-4-methylphenoxy) -2,4,8, 10-tetraoxa-3, 9-diphospho spiro [5.5] undecane, and the like. Of these, pentaerythritol-tetrakis [3- (3, 5-di-tert-butyl-4-hydroxyphenyl) propionate ], 5, 7-di-tert-butyl-3- (3, 4-dimethylphenyl) -3H-benzofuran-2-one and 3, 9-bis (2, 6-di-tert-butyl-4-methylphenoxy) -2,4,8, 10-tetraoxa-3, 9-diphosphaspiro [5.5] undecane are particularly preferably used. The content of the antioxidant in the polycarbonate resin is preferably 0.001 to 0.3 parts by weight, more preferably 0.05 to 0.2 parts by weight, relative to 100 parts by weight of the polycarbonate resin.
Examples of the processing stabilizer include a phosphorus-based processing heat stabilizer, a sulfur-based processing heat stabilizer, and the like. Examples of the phosphorus-based processing heat stabilizer include phosphorous acid, phosphoric acid, phosphonic acid, and esters thereof. Specific examples thereof include triphenyl phosphite, tris (nonylphenyl) phosphite, tris (2, 4-di-t-butylphenyl) phosphite, tris (2, 6-di-t-butylphenyl) phosphite, tridecyl phosphite, trioctyl phosphite, trioctadecyl phosphite, didecyl monophenyl phosphite, dioctyl monophenyl phosphite, diisopropyl monophenyl phosphite, monobutyl diphenyl phosphite, monodecyl diphenyl phosphite, monooctyl diphenyl phosphite, bis (2, 6-di-t-butyl-4-methylphenyl) pentaerythritol diphosphite, 2-methylenebis (4, 6-di-t-butylphenyl) octyl phosphite, bis (nonylphenyl) pentaerythritol diphosphite bis (2, 4-dicumylphenyl) pentaerythritol diphosphite, bis (2, 4-di-tert-butylphenyl) pentaerythritol diphosphite, distearyl pentaerythritol diphosphite, tributyl phosphate, triethyl phosphate, trimethyl phosphate, triphenyl phosphate, diphenyl mono-o-diphenyl phosphate, dibutyl phosphate, dioctyl phosphate, diisopropyl phosphate, dimethyl phenylphosphonate, diethyl phenylphosphonate, dipropyl phenylphosphonate, tetrakis (2, 4-di-tert-butylphenyl) -4,4' -biphenylene diphosphonate, tetrakis (2, 4-di-tert-butylphenyl) -4,3' -biphenylene diphosphonate, tetrakis (2, 4-di-tert-butylphenyl) -3,3' -biphenylene diphosphonate, bis (2, 4-di-t-butylphenyl) -4-phenyl-phenylphosphonate, bis (2, 4-di-t-butylphenyl) -3-phenyl-phenylphosphonate, and the like. The content of the phosphorus-based processing heat stabilizer in the polycarbonate resin is preferably 0.001 to 0.2 parts by weight based on 100 parts by weight of the polycarbonate resin.
Examples of the heat stabilizer for the sulfur-based processing include pentaerythritol-tetrakis (3-laurylthiopropionate), pentaerythritol-tetrakis (3-myristylthiopropionate), pentaerythritol-tetrakis (3-stearylthiopropionate), dilauryl-3, 3' -thiodipropionate, dimyristyl-3, 3' -thiodipropionate, distearyl-3, 3' -thiodipropionate, and the like. The content of the sulfur-based processing heat stabilizer in the polycarbonate resin is preferably 0.001 to 0.2 parts by weight relative to 100 parts by weight of the polycarbonate resin.
The release agent is preferably composed of an ester of an alcohol and a fatty acid in an amount of 90% by weight or more. Specific examples of the ester of an alcohol and a fatty acid include an ester of a monohydric alcohol and a fatty acid, and a partial ester or a full ester of a polyhydric alcohol and a fatty acid. The ester of a monohydric alcohol and a fatty acid is preferably an ester of a monohydric alcohol having 1 to 20 carbon atoms and a saturated fatty acid having 10 to 30 carbon atoms. The partial or full ester of a polyol and a fatty acid is preferably a partial or full ester of a polyol having 1 to 25 carbon atoms and a saturated fatty acid having 10 to 30 carbon atoms.
Specifically, examples of esters of monohydric alcohols and saturated fatty acids include stearyl stearate, palmityl palmitate, butyl stearate, methyl laurate, and isopropyl palmitate. Examples of the partial or full ester of a polyhydric alcohol and a saturated fatty acid include a partial or full ester of dipentaerythritol such as glyceryl monostearate, diglyceryl stearate, glyceryl tristearate, sorbitan monostearate, glyceryl behenate, glyceryl caprate, glyceryl laurate, pentaerythritol monostearate, pentaerythritol tetrastearate, pentaerythritol tetrasonanoate, propylene glycol monostearate, diphenyl diphenoate, sorbitol monostearate, 2-ethylhexyl stearate, dipentaerythritol hexastearate, and the like. The content of the release agent is preferably in the range of 0.005 to 2.0 parts by weight, more preferably in the range of 0.01 to 0.6 parts by weight, and even more preferably in the range of 0.02 to 0.5 parts by weight, relative to 100 parts by weight of the polycarbonate resin.
The ultraviolet absorber is preferably at least one ultraviolet absorber selected from the group consisting of benzotriazole-based ultraviolet absorbers, benzophenone-based ultraviolet absorbers, triazine-based ultraviolet absorbers, cyclic imido ester-based ultraviolet absorbers and cyanoacrylate-based ultraviolet absorbers. That is, any one of the ultraviolet absorbers described below may be used alone, or two or more may be used in combination.
Examples of the benzotriazole-based ultraviolet absorber include 2- (2-hydroxy-5-methylphenyl) benzotriazole, 2- (2-hydroxy-5-tert-octylphenyl) benzotriazole, 2- (2-hydroxy-3, 5-di-tert-pentylphenyl) phenylbenzotriazole, 2- (2-hydroxy-3-tert-butyl-5-methylphenyl) -5-chlorobenzotriazole, 2 '-methylenebis [4- (1, 3-tetramethylbutyl) -6- (2N-benzotriazol-2-yl) phenol ], 2- (2-hydroxy-3, 5-di-tert-butylphenyl) benzotriazole, 2- (2-hydroxy-3, 5-di-tert-butylphenyl) -5-chlorobenzotriazole, 2- (2-hydroxy-3, 5-di-tert-pentylphenyl) benzotriazole, 2- (2-hydroxy-5-tert-octylphenyl) benzotriazole, 2- (2-hydroxy-5-tert-butylphenyl) benzotriazole, 2- (2-hydroxy-4-octyloxy) benzotriazole, 2' -bis- [2, 5-di-tert-butylphenyl ] benzotriazole, 2- (2-hydroxy-3, 5-di-tert-butylphenyl) benzotriazole, and 2- (2-hydroxy-3, 5-di-tert-butylphenyl) benzotriazole.
Examples of the benzophenone-based ultraviolet light absorber include 2, 4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2-hydroxy-4-benzyloxy-benzophenone, 2-hydroxy-4-methoxy-5-sulfobenzophenone, 2-hydroxy-4-methoxy-5-sulfoacid trihydrate benzophenone, 2 '-dihydroxy-4-methoxybenzophenone, 2',4 '-tetrahydroxybenzophenone, 2' -dihydroxy-4, 4 '-dimethoxybenzophenone, 2' -dihydroxy-4, 4 '-dimethoxy-5-sulfosodium benzophenone, bis (5-benzoyl-4-hydroxy-2-methoxyphenyl) methane, 2-hydroxy-4-n-dodecoxybenzophenone, and 2-hydroxy-4-methoxy-2' -carboxybenzophenone.
Examples of the triazine ultraviolet light absorber include 2- (4, 6-diphenyl-1, 3, 5-triazin-2-yl) -5- [ (hexyl) oxy ] phenol and 2- (4, 6-bis (2, 4-dimethylphenyl) -1,3, 5-triazin-2-yl) -5- [ (octyl) oxy ] phenol.
As the cyclic iminoester-based ultraviolet absorber, examples thereof include 2,2 '-bis (3, 1-benzoxazin-4-one), 2' -p-phenylenebis (3, 1-benzoxazin-4-one), 2 '-m-phenylenebis (3, 1-benzoxazin-4-one), 2' - (4, 4 '-diphenylene) bis (3, 1-benzoxazin-4-one), 2' - (2, 6-naphthalene) bis (3, 1-benzoxazin-4-one) 2,2'- (1, 5-naphthalene) bis (3, 1-benzoxazin-4-one), 2' - (2-methyl-p-phenylene) bis (3, 1-benzoxazin-4-one), 2'- (2-nitro-p-phenylene) bis (3, 1-benzoxazin-4-one), 2' - (2-chloro-p-phenylene) bis (3, 1-benzoxazin-4-one), and the like.
Examples of the cyanoacrylate-based ultraviolet absorber include 1, 3-bis [ (2 ' -cyano-3 ',3' -diphenylacryloyl) oxy ] -2, 2-bis [ (2-cyano-3, 3-diphenylacryloyl) oxy ] methyl) propane and 1, 3-bis [ (2-cyano-3, 3-diphenylacryloyl) oxy ] benzene.
The content of the ultraviolet absorber is preferably 0.01 to 3.0 parts by weight, more preferably 0.02 to 1.0 parts by weight, and still more preferably 0.05 to 0.8 parts by weight, based on 100 parts by weight of the polycarbonate resin. When the amount is within the above range, sufficient weather resistance can be imparted to the polycarbonate resin for the intended use.
The polycarbonate resin of the present invention has a high refractive index and a low abbe number. In addition to the optical lens, the optical lens can be advantageously used as a molding for optical use as a structural material or a functional material for optical components such as transparent conductive substrates, optical disks, liquid crystal panels, optical cards, sheets, films, optical fibers, connectors, vapor deposited plastic mirrors, and displays, which are used for liquid crystal displays, organic EL displays, solar cells, and the like.
The surface of the optical molded body may be provided with a coating such as an antireflection layer or a hard coat layer, if necessary. The antireflection layer may be a single layer or a plurality of layers, and may be organic or inorganic, but is preferably inorganic. Specifically, oxides or fluorides such as silicon oxide, aluminum oxide, zirconium oxide, titanium oxide, cerium oxide, magnesium oxide, and magnesium fluoride can be exemplified.
< Optical lens >
The optical lens produced using the polycarbonate resin of the present invention has a high refractive index, a low abbe number, a small absolute value of birefringence strength, and a small in-plane birefringence, and therefore can be used in the field of conventional expensive high refractive index glass lenses such as telescopes, binoculars, and television projectors, and is therefore extremely useful. If necessary, it is preferable to use an aspherical lens. Since the aspherical lens can realize substantially zero spherical aberration by 1 lens, there is no need to eliminate spherical aberration by combining a plurality of spherical lenses, and the weight and production cost can be reduced. Therefore, an aspherical lens is useful as an optical lens, particularly as a camera lens.
The optical lens may be molded by any method such as injection molding, compression molding, injection compression molding, or the like. According to the present invention, an aspherical lens having a high refractive index and low birefringence, which is technically difficult to process in terms of glass lenses, can be more easily obtained.
In order to avoid the contamination of foreign matter into the optical lens as much as possible, the molding environment must be a low-dust environment, and it is preferably 6 or less, more preferably 5 or less.
(Optical film)
The optical film produced using the polycarbonate resin of the present invention is excellent in transparency and heat resistance, and therefore is suitable for use as a film for a liquid crystal substrate, an optical memory card, or the like.
In order to avoid the contamination of the optical film with foreign matters as much as possible, the molding environment must be a low-dust environment, and it is preferably 6 or less, more preferably 5 or less.
Examples
The following examples and comparative examples of the present invention are shown together to explain the summary of the invention in detail, but the present invention is not limited to these examples. The measurement values in the examples were measured by the following methods and apparatuses.
1) Refractive index (nD):
According to JIS B7071-2: 2018, molding a polycarbonate resin to obtain a V-shaped block as a test piece. The refractive index was measured at 23℃by a refractive index meter (KPR-3000 manufactured by Shimadzu corporation).
2) Abbe number (v)
The refractive indices of 486nm, 589nm and 656nm at 23℃were measured using a refractive index meter using the same test piece (V-block) as that used for the refractive index measurement, and Abbe numbers were calculated using the following formulas.
Refractive index meter: KPR-3000 manufactured by Shimadzu corporation
ν=(nD-1)/(nF-nC)
ND: refractive index at wavelength 589nm
NC: refractive index at 656nm
NF: refractive index at wavelength 486nm
3) Intensity of birefringence
Test piece molding
The obtained resin was extrusion molded to obtain a film test piece having a thickness of 100. Mu.m.
And (3) a forming machine: PULAENG-EXTRUDER
The molding conditions are as follows: barrel temperature 260 ℃, roller temperature Tg+10deg.C
Determination of the birefringence:
the film test piece was stretched to measure the birefringence at 450 nm.
Measurement device: JASCO ellipsometer (Spectroellipsometer) M-220
Measurement conditions: measurement was performed using a film stretched 1.5 times
The birefringence strength is the ratio of the birefringence of the resulting resin at 450nm to the birefringence of the polycarbonate (homopolymer) derived from BPEF at 450 nm.
4) Glass transition temperature (Tg)
The measurement was performed according to JIS K7121-1987 by using a differential scanning calorimeter with a temperature-raising program of 10℃per minute.
Differential thermal scanning calorimeter: X-DSC7000 manufactured by Hitachi technology science, kagao, co., ltd
5) Weight average molecular weight
The weight average molecular weight of the obtained resin was measured by Gel Permeation Chromatography (GPC), and calculated by conversion with standard polystyrene. The apparatus, column and measurement conditions are shown below.
GPC apparatus: tosoh Co., ltd., HLC-8420GPC
Column: tosoh co., ltd. TSKgel SuperHM-mx3 roots
Tosoh co., ltd. TSKgel guardcolumn SuperH-h×1 root
Tosoh Co., ltd. TSKgel SuperH-RC. Times.1 root
A detector: RI detector
Standard polystyrene: tosoh Co., ltd., standard polystyrene kit PStQuick C
Sample solution: 0.2% by mass tetrahydrofuran solution
Eluent: tetrahydrofuran (THF)
Eluent flow rate: 0.6mL/min
Column temperature: 40 DEG C
6) Melt volume flow Rate (MVR)
The obtained resin was dried under vacuum at 120℃for 4 hours and measured in accordance with JIS K7210.
Measurement device: melt index instrument T-111 manufactured by Toyo refiner of Kagaku Co., ltd
Measurement conditions: the measurement was performed under a load of 2160g at a temperature of 260 ℃.
The operation is as follows: MVR (unit: cm 3/10 min) was calculated based on the amount of resin extruded every 10 minutes from a standard die set at the bottom of the barrel.
7) Internal birefringence of lens face
Test piece molding
The obtained resin was injection molded to obtain a concave lens test piece having a diameter of 4.5mm and a center thickness of 0.2 mm.
And (3) a forming machine: SUMITOMO SHIDEMAG SE EV
The molding conditions are as follows: barrel temperature 280 ℃, die temperature Tg-15 ℃, injection speed 40mm/s, VP pressure 70MPa (position 2.3 mm), pressure maintaining 65MPa×1s+55MPa×1.5s
Determination of the birefringence in a lens face
The retardation of the concave lens test piece obtained as described above was measured.
Measurement device: photonic Lattice Co., ltd. WPA-100
The data processing method comprises the following steps: the value of the birefringence in the lens surface was determined from the retardation average using software "PA/WPA View" manufactured by Photonic Lattice co., ltd.
8) Haze degree
The obtained resin was molded to a thickness of 3mm, and measured in accordance with JIS K-7136.
Measuring instrument: spectral haze meter SH7000 manufactured by Nippon electric color industry Co., ltd
Example 1A
As a raw material, 9391.9g (15.9 mol) of 9, 9-bis [4- (2-hydroxyethoxy) -3-phenylphenyl ] fluorene (hereinafter sometimes abbreviated as "OPPFL") represented by the following structural formula, 1457.7g (2.7 mol) of 9, 9-bis [6- (2-hydroxyethoxy) -2-naphthyl ] fluorene (hereinafter sometimes abbreviated as "NOLE") represented by the following structural formula, 5700.0g (15.2 mol) of 2,2 '-bis (2-hydroxyethoxy) -1,1' -binaphthyl (hereinafter sometimes abbreviated as "BNE") represented by the following structural formula, 7450g (hereinafter sometimes abbreviated as "DPC") and 12 ml (3.0X10 -4 mol) of an aqueous sodium bicarbonate solution (2.5X10 -2 mol, namely 10X 10 ﹣6 mol relative to 1 mol of the total dihydroxy compound) were charged into a 50 liter reactor equipped with a stirrer and a distillation apparatus, and after the nitrogen gas was replaced with nitrogen gas, the nitrogen gas was stirred at 700℃under a temperature of 200℃under a heating atmosphere. After confirming that the raw material was completely dissolved 20 minutes after the start of heating, the mixture was stirred under this condition for 80 minutes. Then, the degree of decompression was adjusted to 200Torr for 20 minutes, and the reaction was kept at 200℃for 10 minutes under 200Torr to carry out transesterification. The temperature was raised to 215℃for 30 minutes, and the pressure was reduced to 180Torr. Then adjusted to 230℃and 150Torr in 40 minutes. Then adjusted to 120Torr for another 10 minutes. And then adjusted to 100Torr, 240℃for 10 minutes. Then, the polymerization was carried out at 240℃for 30 minutes under 1Torr with a temperature of 1Torr being adjusted to 1Torr for 50 minutes. After the completion of the reaction, nitrogen was introduced into the reaction system in the reactor to pressurize the reaction system, and the produced polycarbonate resin was pelletized and extracted to obtain a polycarbonate resin. Physical properties of the obtained resin are shown in table 2.
Examples 2A to 4A and comparative examples 1A to 8A
A polycarbonate resin was obtained in the same manner as in example 1A, except that the raw materials shown in table 1 were used. Physical properties of the obtained resin are shown in table 2.
TABLE 1
/>
TABLE 2
The 3mmt can be molded, but the strength of the molded thin-wall lens is insufficient
Example 1B
As a raw material, 1690g (3.14 mol) of 9, 9-bis (6- (2-hydroxyethoxy) naphthalen-2-yl ] fluorene (BNEF), 6170g (16.5 mol) of 2,2 '-bis (2-hydroxyethoxy) -1,1' -Binaphthyl (BNE), 4760g (10.9 mol) of 9, 9-bis (4- (2-hydroxyethoxy) phenyl ] fluorene (BPEF), 8390g (14.2 mol) of 9, 9-bis (4- (2-hydroxyethoxy) -3-phenylphenyl ] fluorene (BPPEF), 10000g (46.7 mol) of diphenyl carbonate (DPC) and 16ml (4.0X10 -4 mol) of an aqueous sodium bicarbonate solution of 2.5X10 -2 mol/liter, i.e., 8.9X10 -6 mol relative to the total 1 mol of dihydroxyl compound were charged into a 50L reactor equipped with a stirrer and a distillation device under nitrogen atmosphere of 760mmHg, heating to 180deg.C for 30min, stirring for 120 min, regulating vacuum to 200mmHg, heating to 200deg.C at 60deg.C/hr, maintaining at 200deg.C for 20min, reacting, heating to 230deg.C at 75deg.C/hr for 10min, maintaining at the temperature, regulating pressure reduction to below 1mmHg, heating to 245 deg.C at 60deg.C/hr, stirring for 30min, introducing nitrogen into the reaction system, pressurizing, granulating, and extracting, a polycarbonate resin was obtained. The physical properties of the obtained resin are shown in Table 3.
TABLE 3
Example 2B, comparative examples 1B to 3B
A polycarbonate resin was obtained in the same manner as in example 1B, except that the raw materials shown in table 4 were used. Physical properties of the obtained polycarbonate resin are shown in table 3.
TABLE 4
/>
Claims (20)
1. A thermoplastic resin characterized in that:
The resin contains, relative to 100 mol% of the total amount of structural units in the resin, 22 to 49 mol% of structural units (A) derived from a diol represented by the following general formula (1A), 40 to 75 mol% of structural units (B) derived from a diol represented by the following general formula (2A), and 0 to 15 mol% of structural units (C) derived from a diol represented by the following general formula (3A),
In the general formula (1A), R a、Rb、Raa and R bb are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
A and b each independently represent an integer of 0 to 10,
In the general formula (2A), R c and R d are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 30 carbon atoms which may have a substituent, a heteroaryl group having 6 to 30 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
C and d each independently represent an integer of 0 to 10,
In the general formula (3A), R e and R f are each independently selected from a hydrogen atom, a halogen atom, an alkyl group having 1 to 20 carbon atoms which may have a substituent, an alkoxy group having 1 to 20 carbon atoms which may have a substituent, a cycloalkyl group having 5 to 20 carbon atoms which may have a substituent, a cycloalkoxy group having 5 to 20 carbon atoms which may have a substituent, an aryl group having 6 to 20 carbon atoms which may have a substituent, a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S, an aryloxy group having 6 to 20 carbon atoms which may have a substituent, and-C.ident.C-R h,
R h represents an aryl group having 6 to 20 carbon atoms which may have a substituent or a heteroaryl group having 6 to 20 carbon atoms which may have a substituent and contains 1 or more hetero ring atoms selected from O, N and S,
X each independently represents an alkylene group having 1 to 5 carbon atoms which may have a substituent,
E and f each independently represent an integer of 0 to 10.
2. The thermoplastic resin of claim 1 wherein:
The proportion of the structural unit (A) derived from the diol represented by the general formula (1A) is 24 to 47 mol%, the proportion of the structural unit (B) derived from the diol represented by the general formula (2A) is 45 to 70 mol%, and the proportion of the structural unit (C) derived from the diol represented by the general formula (3A) is 0 to 8 mol%, based on 100 mol% of the total amount of the structural units in the resin.
3. The thermoplastic resin according to claim 1 or 2, wherein:
the dihydric alcohol shown in the general formula (1A) comprises dihydric alcohol shown in the following structural formula,
4. A thermoplastic resin according to any one of claims 1 to 3, wherein:
The diol represented by the general formula (2A) contains at least one of the diols represented by the following structural formulas,
5. The thermoplastic resin according to any one of claims 1 to 4, wherein:
the diol represented by the general formula (3A) comprises a diol represented by the following structural formula,
6. The thermoplastic resin according to any one of claims 1 to 5, wherein:
The thermoplastic resin is a polycarbonate resin.
7. The thermoplastic resin according to any one of claims 1 to 6, wherein:
The thermoplastic resin further comprises structural units derived from at least one monomer selected from the group of monomers,
In the above formula, R 1 and R 2 each independently represent a hydrogen atom, a methyl group or an ethyl group, and R 3 and R 4 each independently represent a hydrogen atom, a methyl group, an ethyl group or an alkylene glycol having 2 to 5 carbon atoms.
8. The thermoplastic resin according to any one of claims 1 to 7, wherein:
the thermoplastic resin has a birefringence of 1 to 21 in the lens surface.
9. The thermoplastic resin according to any one of claims 1 to 8, wherein:
The weight average molecular weight (Mw) of the thermoplastic resin in terms of polystyrene is 10,000 ~ 100,000.
10. The thermoplastic resin according to any one of claims 1 to 9, characterized in that:
the refractive index (nD) of the thermoplastic resin is 1.650-1.695.
11. The thermoplastic resin according to any one of claims 1 to 10, characterized in that:
the Abbe number (v) of the thermoplastic resin is 16.0 to 21.0.
12. The thermoplastic resin according to any one of claims 1 to 11, characterized in that:
The glass transition temperature of the thermoplastic resin is 130-190 ℃.
13. The thermoplastic resin according to any one of claims 1 to 12, characterized in that:
The thermoplastic resin has a melt volume flow rate (MVR) of 20 to 55.
14. The thermoplastic resin according to any one of claims 1 to 13, characterized in that:
the thermoplastic resin has a haze of 0.01 to 1.00.
15. An optical component, characterized by:
A thermoplastic resin according to any one of claims 1 to 14.
16. An optical lens, characterized by:
A thermoplastic resin according to any one of claims 1 to 14.
17. An optical film, characterized in that:
A thermoplastic resin according to any one of claims 1 to 14.
18. A polycarbonate resin characterized in that:
Comprising a structural unit represented by the following general formula (1B), a structural unit represented by the following general formula (2B) and a structural unit represented by the following general formula (3B),
The proportion of the structural unit represented by the following general formula (1B) is 1 mol% or more and less than 10 mol%,
The proportion of the structural unit represented by the following general formula (2B) is 10 to 60 mol%,
The proportion of the structural unit represented by the following general formula (3B) is 5 to 80 mol%,
In the general formula (1B), X represents an alkylene group having 1 to 4 carbon atoms, and a and B each independently represent an integer of 1 to 10;
In the general formula (2B), Y represents an alkylene group having 1 to 4 carbon atoms, and c and d each independently represent an integer of 1 to 10;
in the general formula (3B),
Z represents an alkylene group having 1 to 4 carbon atoms,
R 1~R6 each independently represents a hydrogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 20 carbon atoms, a cycloalkoxy group having 5 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms or an aryloxy group having 6 to 20 carbon atoms,
E and f each independently represent an integer of 0 to 5.
19. The polycarbonate resin of claim 18, wherein:
the proportion of the structural unit represented by the general formula (1B) is 2 to 9 mol%,
The proportion of the structural unit represented by the general formula (2B) is 20 to 60 mol%,
The proportion of the structural unit represented by the general formula (3B) is 30 to 70 mol%.
20. An optical lens, characterized by:
A polycarbonate resin according to claim 18 or 19.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2021-184822 | 2021-11-12 | ||
JP2022018448 | 2022-02-09 | ||
JP2022-018448 | 2022-02-09 | ||
PCT/JP2022/041824 WO2023085339A1 (en) | 2021-11-12 | 2022-11-10 | Thermoplastic resin and optical lens including same |
Publications (1)
Publication Number | Publication Date |
---|---|
CN118215702A true CN118215702A (en) | 2024-06-18 |
Family
ID=91450985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202280074108.8A Pending CN118215702A (en) | 2021-11-12 | 2022-11-10 | Thermoplastic resin and optical lens comprising the same |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN118215702A (en) |
-
2022
- 2022-11-10 CN CN202280074108.8A patent/CN118215702A/en active Pending
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111094389B (en) | Polycarbonate resin, method for producing same, and optical lens | |
JP7298669B2 (en) | POLYCARBONATE RESIN, MANUFACTURING METHOD THEREOF, AND OPTICAL LENS | |
US10711100B2 (en) | Dihydroxy compound | |
CN108329464B (en) | Polycarbonate resin, process for producing the same, and optical molded article | |
CN110461942B (en) | Polycarbonate resin composition and optical lens using same | |
JP7176535B2 (en) | POLYCARBONATE RESIN COMPOSITION, METHOD FOR MANUFACTURING SAME, AND OPTICAL LENS | |
JP6908026B2 (en) | A polycarbonate copolymer, an optical lens and a film using the same, and a method for producing the copolymer. | |
CN115516005A (en) | Polycarbonate resin, and optical lens and optical film using same | |
CN118215702A (en) | Thermoplastic resin and optical lens comprising the same | |
WO2023085339A1 (en) | Thermoplastic resin and optical lens including same | |
CN118201981A (en) | Polycarbonate resin, and optical lens and optical film using same | |
CN117337312A (en) | Thermoplastic resin and optical lens comprising the same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |