CN117756087A - Preparation method of negative electrode material for sodium ion battery and potassium ion battery - Google Patents
Preparation method of negative electrode material for sodium ion battery and potassium ion battery Download PDFInfo
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- CN117756087A CN117756087A CN202311715224.6A CN202311715224A CN117756087A CN 117756087 A CN117756087 A CN 117756087A CN 202311715224 A CN202311715224 A CN 202311715224A CN 117756087 A CN117756087 A CN 117756087A
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- negative electrode
- electrode material
- washing
- ion battery
- gluconate
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- 239000007773 negative electrode material Substances 0.000 title claims abstract description 18
- 229910001414 potassium ion Inorganic materials 0.000 title claims abstract description 18
- 229910001415 sodium ion Inorganic materials 0.000 title claims abstract description 18
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 title claims abstract description 17
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 title claims abstract description 16
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000005406 washing Methods 0.000 claims abstract description 30
- 238000002156 mixing Methods 0.000 claims abstract description 20
- 239000000463 material Substances 0.000 claims abstract description 16
- 229920002472 Starch Polymers 0.000 claims abstract description 11
- 235000019698 starch Nutrition 0.000 claims abstract description 11
- 239000008107 starch Substances 0.000 claims abstract description 11
- 238000010000 carbonizing Methods 0.000 claims abstract description 10
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims abstract description 7
- 229940050410 gluconate Drugs 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims description 36
- 239000002243 precursor Substances 0.000 claims description 36
- 239000011812 mixed powder Substances 0.000 claims description 18
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 16
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 10
- 238000001816 cooling Methods 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 238000000227 grinding Methods 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 9
- 239000000843 powder Substances 0.000 claims description 9
- 230000001681 protective effect Effects 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052786 argon Inorganic materials 0.000 claims description 8
- 239000001307 helium Substances 0.000 claims description 8
- 229910052734 helium Inorganic materials 0.000 claims description 8
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 8
- 229910052754 neon Inorganic materials 0.000 claims description 8
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 8
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 7
- 235000011478 zinc gluconate Nutrition 0.000 claims description 7
- 239000011670 zinc gluconate Substances 0.000 claims description 7
- 229960000306 zinc gluconate Drugs 0.000 claims description 7
- 239000004227 calcium gluconate Substances 0.000 claims description 6
- 229960004494 calcium gluconate Drugs 0.000 claims description 6
- 235000013927 calcium gluconate Nutrition 0.000 claims description 6
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 claims description 6
- 239000001755 magnesium gluconate Substances 0.000 claims description 6
- 229960003035 magnesium gluconate Drugs 0.000 claims description 6
- 235000015778 magnesium gluconate Nutrition 0.000 claims description 6
- IAKLPCRFBAZVRW-XRDLMGPZSA-L magnesium;(2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanoate;hydrate Chemical compound O.[Mg+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O IAKLPCRFBAZVRW-XRDLMGPZSA-L 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 238000005554 pickling Methods 0.000 claims description 6
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- 230000014759 maintenance of location Effects 0.000 abstract description 4
- 238000003763 carbonization Methods 0.000 abstract description 3
- 239000002253 acid Substances 0.000 abstract description 2
- 239000010406 cathode material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 239000010405 anode material Substances 0.000 description 12
- 238000001000 micrograph Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 229910021385 hard carbon Inorganic materials 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000003575 carbonaceous material Substances 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 229940032147 starch Drugs 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000011229 interlayer Substances 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Battery Electrode And Active Subsutance (AREA)
Abstract
The invention discloses a preparation method of a negative electrode material for a sodium ion battery and a potassium ion battery, which comprises the following steps of: mixing the materials, preheating, washing and carbonizing to obtain the cathode material. The negative electrode material is prepared by taking starch and gluconate as main raw materials through simple mixing, preheating treatment, acid washing and high-temperature carbonization, has the advantages of high gram capacity, high first efficiency and high capacity retention rate, and can be applied to sodium ion or potassium ion batteries.
Description
Technical Field
The invention relates to the technology in the field of cathodes, in particular to a preparation method of a cathode material for sodium ion batteries and potassium ion batteries.
Background
In recent years, environmental problems are increasingly raised due to carbon emissions from fossil energy consumption, and the development of renewable energy sources such as solar energy, wind energy, tidal energy and the like on a large scale has become a global important consensus for advancing energy consumption structures toward low carbonization and cleaning. Since the commercialization of SONY in the 90 th century, lithium ion batteries have been widely used in the fields of mobile electronic devices, electric vehicles, and the like. With the increasingly wide application of lithium ion batteries, lithium resources with insufficient reserves in the crust will not meet the increasing huge demand, so the development of other battery technologies capable of effectively replacing lithium ion batteries in the energy storage field is urgent. Sodium and potassium resources are very abundant and distributed uniformly, and sodium, potassium and lithium are the same main group elements and have similar chemical properties, so that the development of sodium ion and potassium ion batteries can be used for referencing the successful experience of lithium ion batteries.
The most promising materials for large scale negative electrodes for sodium and potassium ion batteries are hard carbon materials. The microstructure of the hard carbon is short-range ordered micro-regions stacked by curved graphite-like sheets, and the random stacking of each micro-region leaves more nano holes. Because it tends to have a larger interlayer spacing (typically greater than 0.37 nm), more nanopores, and more defect sites, more sodium or potassium ions can be stored, with higher specific capacity. The performance of the hard carbon material on sodium ion or potassium ion batteries is still in the development stage, and physicochemical indexes such as granularity, specific surface, ash content and interlayer spacing are also limiting the capacity and first effect of the hard carbon material. Therefore, there is a need to propose a new solution to the above-mentioned problems.
Disclosure of Invention
In view of the above, the present invention aims at overcoming the drawbacks of the prior art, and its main objective is to provide a method for preparing a negative electrode material for sodium ion battery and potassium ion battery, wherein the prepared negative electrode material has the advantages of high gram capacity, high first efficiency and high capacity retention rate.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
the preparation method of the negative electrode material for the sodium ion battery and the potassium ion battery comprises the following steps:
(1) Mixing materials: starch and gluconate are mixed according to the mass ratio of 1: mixing the materials in the proportion of (0.5-1.5) in a stirrer to obtain mixed powder;
(2) Preheating: placing the mixed powder obtained in the step (1) into a crucible, then placing the crucible into a muffle furnace, heating to 200-400 ℃ at a heating rate of 5-10 ℃/min under the atmosphere of protective gas, and preserving heat for 2-3h to obtain a precursor;
(3) Washing: washing the precursor obtained in the step (2) for 3-8 times by using pickling solution, washing with water until the pH value is neutral, and drying to obtain a pickled precursor;
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1000-1300 ℃ at a heating rate of 5-15 ℃/min under the atmosphere of protective gas, preserving heat for 2-4h, cooling to room temperature, and grinding into powder to obtain the negative electrode material.
As a preferred scheme, the gluconate is one or more of magnesium gluconate, zinc gluconate and calcium gluconate.
As a preferable scheme, the shielding gas is one or more of nitrogen, argon, helium and neon.
As a preferable scheme, the pickling solution is one or a mixture of more of sulfuric acid, hydrochloric acid, nitric acid and phosphoric acid.
Compared with the prior art, the invention has obvious advantages and beneficial effects, and in particular, the technical scheme can be as follows:
the negative electrode material is prepared by taking starch and gluconate as main raw materials through simple mixing, preheating treatment, acid washing and high-temperature carbonization, has the advantages of high gram capacity, high first efficiency and high capacity retention rate, and can be applied to sodium ion or potassium ion batteries.
In order to more clearly illustrate the structural features and efficacy of the present invention, the following detailed description of the invention is made with reference to the accompanying drawings and to the specific embodiments:
drawings
FIG. 1 is a scanning electron microscope image of the anode material prepared in example 1 of the present invention at different resolutions;
FIG. 2 is a scanning electron microscope image of the anode material prepared in example 2 of the present invention at different resolutions;
FIG. 3 is a scanning electron microscope image of the anode material prepared in example 3 of the present invention at different resolutions;
FIG. 4 is a scanning electron microscope image of the anode material prepared in example 4 of the present invention at different resolutions;
FIG. 5 is a scanning electron microscope image of the anode material prepared in example 5 of the present invention at different resolutions;
FIG. 6 is a scanning electron microscope image of the anode material prepared in example 6 of the present invention at different resolutions.
Detailed Description
The invention discloses a preparation method of a negative electrode material for a sodium ion battery and a potassium ion battery, which comprises the following steps:
(1) Mixing materials: starch and gluconate are mixed according to the mass ratio of 1: mixing (0.5-1.5) with magnesium gluconate, zinc gluconate and/or calcium gluconate to obtain mixed powder.
(2) Preheating: placing the mixed powder obtained in the step (1) into a crucible, then placing the crucible into a muffle furnace, heating to 200-400 ℃ at a heating rate of 5-10 ℃/min under the atmosphere of protective gas, and preserving heat for 2-3h to obtain a precursor; wherein the protective gas is one or more of nitrogen, argon, helium and neon.
(3) Washing: washing the precursor obtained in the step (2) for 3-8 times by using pickling solution, washing with water until the pH value is neutral, and drying to obtain a pickled precursor; the pickling solution is one or more of sulfuric acid, hydrochloric acid, nitric acid and phosphoric acid.
(4) Carbonizing: placing the precursor obtained in the step (3) in a crucible, heating to 1000-1300 ℃ at a heating rate of 5-15 ℃/min under the atmosphere of protective gas, preserving heat for 2-4 hours, cooling to room temperature, and grinding into powder to obtain a negative electrode material; wherein the protective gas is one or more of nitrogen, argon, helium and neon.
The following describes in detail specific embodiments.
Example 1
(1) Mixing materials: starch and magnesium gluconate are mixed according to the mass ratio of 1:1 are put into a stirrer to be uniformly mixed, thus obtaining mixed powder.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 400 ℃ at a heating rate of 10 ℃/min under the atmosphere of argon, and preserving heat for 2 hours to obtain the precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 3 times by using a mixed solution of nitric acid and sulfuric acid, washing with water until the pH value is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1000 ℃ at a heating rate of 10 ℃/min under the atmosphere of argon, preserving heat for 2 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
Example 2
(1) Mixing materials: starch and zinc gluconate are mixed according to the mass ratio of 1:1.5, and mixing the materials uniformly in a stirrer to obtain mixed powder.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 300 ℃ at a heating rate of 8 ℃/min under the atmosphere of nitrogen and argon, and preserving heat for 2 hours to obtain the precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 8 times by using hydrochloric acid, washing with water until the pH is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1200 ℃ at a heating rate of 10 ℃/min under the atmosphere of nitrogen and argon, preserving heat for 4 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
Example 3
(1) Mixing materials: starch and calcium gluconate are mixed according to the mass ratio of 1: mixing in a mixer to obtain mixed powder at a ratio of 0.5.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 400 ℃ at a heating rate of 5 ℃/min under the atmosphere of helium, and preserving heat for 3 hours to obtain a precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 5 times by using phosphoric acid, washing with water until the pH is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1300 ℃ at a heating rate of 5 ℃/min under the atmosphere of helium, preserving heat for 4 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
Example 4
(1) Mixing materials: starch, zinc gluconate and calcium gluconate are mixed according to the mass ratio of 1: mixing in a mixer to obtain mixed powder at a ratio of 0.8.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 200 ℃ at a heating rate of 6 ℃/min under the atmosphere of neon, and preserving heat for 3 hours to obtain the precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 6 times by using phosphoric acid, washing with water until the pH is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1300 ℃ at a heating rate of 15 ℃/min under the atmosphere of neon, preserving heat for 3.5 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
Example 5
(1) Mixing materials: starch and magnesium gluconate and zinc gluconate are mixed according to the mass ratio of 1:1.2, and uniformly mixing the materials in a stirrer to obtain mixed powder.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 350 ℃ at a heating rate of 8 ℃/min under the atmosphere of helium, and preserving heat for 3 hours to obtain a precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 8 times by using a mixed solution of hydrochloric acid and phosphoric acid, washing with water until the pH value is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) into a crucible, heating to 1300 ℃ at a heating rate of 12 ℃/min under the atmosphere of neon, preserving heat for 4 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
Example 6
(1) Mixing materials: the starch, magnesium gluconate, zinc gluconate and calcium gluconate are mixed according to the mass ratio of 1:1.4, and uniformly mixing the materials in a stirrer to obtain mixed powder.
(2) Preheating: and (3) placing the mixed powder obtained in the step (1) into a crucible, placing the crucible into a muffle furnace, heating to 380 ℃ at a heating rate of 6 ℃/min under the atmosphere of helium, and preserving heat for 3 hours to obtain a precursor.
(3) Washing: and (3) washing the precursor obtained in the step (2) for 8 times by using a mixed solution of hydrochloric acid and phosphoric acid, washing with water until the pH value is neutral, and drying to obtain the acid-washed precursor.
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1250 ℃ at a heating rate of 6 ℃/min under the atmosphere of neon, preserving heat for 3 hours, cooling to room temperature, and grinding into powder to obtain the anode material.
The negative electrode materials prepared in the above examples were subjected to performance test, and the test results are shown in table 1.
Table 1.
As can be seen from the table, the negative electrode material prepared by the preparation method provided by the invention has the advantages of high gram capacity, high first efficiency and high capacity retention rate, can be applied to sodium ion or potassium ion batteries, and has good specific volume value performance in the application of super capacitors.
The foregoing description is only a preferred embodiment of the present invention, and is not intended to limit the technical scope of the present invention, so any minor modifications, equivalent changes and modifications made to the above embodiments according to the technical principles of the present invention are still within the scope of the technical solutions of the present invention.
Claims (4)
1. A preparation method of a negative electrode material for a sodium ion battery and a potassium ion battery is characterized by comprising the following steps: the method comprises the following steps:
(1) Mixing materials: starch and gluconate are mixed according to the mass ratio of 1: mixing the materials in the proportion of (0.5-1.5) in a stirrer to obtain mixed powder;
(2) Preheating: placing the mixed powder obtained in the step (1) into a crucible, then placing the crucible into a muffle furnace, heating to 200-400 ℃ at a heating rate of 5-10 ℃/min under the atmosphere of protective gas, and preserving heat for 2-3h to obtain a precursor;
(3) Washing: washing the precursor obtained in the step (2) for 3-8 times by using pickling solution, washing with water until the pH value is neutral, and drying to obtain a pickled precursor;
(4) Carbonizing: and (3) placing the precursor obtained in the step (3) in a crucible, heating to 1000-1300 ℃ at a heating rate of 5-15 ℃/min under the atmosphere of protective gas, preserving heat for 2-4h, cooling to room temperature, and grinding into powder to obtain the negative electrode material.
2. The method for producing a negative electrode material for sodium ion batteries and potassium ion batteries according to claim 1, characterized in that: the gluconate is one or more of magnesium gluconate, zinc gluconate and calcium gluconate.
3. The method for producing a negative electrode material for sodium ion batteries and potassium ion batteries according to claim 1, characterized in that: the protective gas is one or more of nitrogen, argon, helium and neon.
4. The method for producing a negative electrode material for sodium ion batteries and potassium ion batteries according to claim 1, characterized in that: the pickling solution is one or more of sulfuric acid, hydrochloric acid, nitric acid and phosphoric acid.
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CN118099357A (en) * | 2024-04-22 | 2024-05-28 | 山东方诺新材料科技有限公司 | Sodium ion battery and preparation method thereof |
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