CN1173125A - Lipstick overcoat compositions comprising silicone oil and silica dioxide - Google Patents

Lipstick overcoat compositions comprising silicone oil and silica dioxide Download PDF

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Publication number
CN1173125A
CN1173125A CN 95197447 CN95197447A CN1173125A CN 1173125 A CN1173125 A CN 1173125A CN 95197447 CN95197447 CN 95197447 CN 95197447 A CN95197447 A CN 95197447A CN 1173125 A CN1173125 A CN 1173125A
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group
compositions
composition
volatile
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L.E.德里施斯勒
T.E.拉比
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Procter and Gamble Co
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Procter and Gamble Co
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    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/896Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/897Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/25Silicon; Compounds thereof
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89Polysiloxanes
    • A61K8/891Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02Preparations containing skin colorants, e.g. pigments
    • A61Q1/04Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06Lipsticks

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a composition which when applied over a lipstick composition prevents transference of the lipstick to objects such as cups, glasses and other table wear coming in contact with the lips. The composition extends the time between re-applications of said lipstick and adds luster and shine to the lips while providing the user with good skin feel properties.

Description

The lipstick overcoat compositions that contains silicone oil and silicon dioxide
Invention field
The present invention relates to a kind of compositions, it is applied on a kind of lip composition in case lip pomade is transferred to as teacup, glass with other with tableware that lip contacts on.Therefore, the present invention has prolonged the service time of this lip pomade, has increased the gloss and the light of lip, with seasonal user the advantages of good skin sensation is arranged.
Background of invention
This area has a kind of lip pomade converted products very famous, and its primary purpose is to delay abrasion, strengthens anti-speckle and shifts, and improve the gloss of this lip pomade.These lip pomade products refer to overcoat herein, have used different polymer fluids and film technique, for example, be mixed in the acrylic compounds film former in the overcoat, as CSI company " Sealed with a Kiss ", be dissolved in a kind of lip pomade surface volatile solvent that is sprinkled upon, in the alcohol.This product has solid character, makes lip surface have dry and the viscous sense.And, find that these protective polymer layers in the beginning a few minutes of using, when volatile solvent begins to vaporize, have viscosity.
Above-mentioned alternative overcoat product is mentioned in hentriaconta-day in August, 1993 disclosed Japanese patent application flat 5 (1993)-221829, the overcoat of being mentioned it is said in the persistency of dressing effect, curbs aspect such as normal complexion application properties and improves to some extent.This overcoat contains silicon dioxide powder and/or the alumina powder of 0.2%-25%, the PFPE of 75%-99.8%, and its general molecular formula: In the formula, R 1To R 5Be fluorine atom independently, perfluoro alkyl group or oxidation perfluoro alkyl group; P, the value of q and r is at least 0; Wherein the PFPE molecular weight is about 500-10000, and P, Q, R can equate but can not be zero.Mentioned herein to preferred PFPE product available on the market be known as Fomblin HC-04, HC-25 and the HC-R that Italian Montefluosu of Milano produces.These products have extraordinary smooth and lubricated sense when using.Yet because its surface energy is low, when contact saliva, when coffee, drinking water etc., fluoridizing liquid runs off from lip soon, stays the sandy dried silicon dioxide layer of one deck at lip.Along with PFPE more and more runs off from lip, above-mentioned relatively poor lip sense obviously increases, and PFPE is very expensive, has therefore directly increased the retail price of final products.
Releasing the new product that appears on the market in Japan by Kose and Shiseido recently is the compositions that contains siloxanes and hydrocarbon ils, and the compositions that wherein is applied to lip can prolong the service life of lip pomade, and has the sealing effectiveness of protection lip.Found that also these two kinds of products have relatively poor skin sense, and do not had tangible wear-resisting income.
Summary of the invention
We are bright to relate to a kind of compositions that contains non-volatile siloxane fluid He about 25% thickening agent of about 1%-of the about 10-1000cs of about 99% viscosity of about 75%-.
The molecular formula of the above-mentioned non-volatile siloxane fluid correspondence of mentioning is:
Figure A9519744700051
In the formula, R1 and R6 can be independently from by hydroxyl terminal groups, have in the group that low alkyl group end group that carbon chain length is about C1-C6 and composition thereof formed and choose; R2-R5 can be independently from being about the low-grade alkyl group of C1-C6 by having carbon chain length, the fluoroalkyl group, phenyl group is chosen in the group that aminoalkyl groups and composition thereof is formed.
Therefore, one of purpose of the present invention be lost to for fear of lip pomade from lip with object that lip contacts on and a kind of overcoat of providing is formed.Another object of the present invention is to prolong each pot life of using of lip pomade.A purpose provides a kind of compositions it has not only improved the gloss and the light of the lip composition that is used for lip again, and has strengthened use and wear-resisting characteristics that consumer is pursued.Used these purposes all embody in the more cheap product of a kind of corresponding product of mentioning than this area.
Detailed Description Of The Invention
A. non-volatile siloxane fluid
The nonvolatile siloxanes that the present invention relates to has following molecular formula: In the formula, end group R1 and R6 can be independently from by oh group, have in the group that low-grade alkyl group that carbon chain length is about C1-C6 and composition thereof formed and choose the preferable methyl group.Non-end group R2, R3, R4 and R5 can be independently from being about the low-grade alkyl group of C1-C6 by having carbon chain length, the fluoroalkyl group, phenyl group is chosen in the group that aminoalkyl group and composition thereof is formed.The non-volatile siloxane fluid of being carried is at 25 ℃, under the atmospheric pressure, and the about 10cs-1000cs of viscosity, preferred about 50cs-500cs, the about 75%-99% of non-volatile siloxane content described in the said compositions, preferably about 90%-99%, most preferably from about 90%-95%.
Known siloxanes fluids with non-end group (R2, R3, R4 and R5) comprises the side chain with carbon chain length C1-C6 and the low-grade alkyl group of straight chain in this area.Have relative non-lipophilic final products in order to obtain among the present invention, the chain length of preferred C1-C6 is short as far as possible.Therefore, be methyl group at the non-end group of this most preferred alkyl.The non-volatile siloxane fluid that contains these non-end groups available on the market comprises the 200 Fluids of Dow Corning Corporation's production and the SF-96 series that General Electric Co. Limited produces.
The siloxanes fluids that has the non-end group that comprises the fluoroalkyl group among the present invention also of great use.Yet, but preferably fluorine atom is linked on the alkyl group with C3-C8 chain length, and wherein, fluorine atom is linked on the described alkyl group of silicon/carbon bond more than or equal to three carbon atoms.Non-volatile siloxane fluid with this type of non-end group available on the market comprises the SF-1153 series that 1265Fluid is serial and General Electric Co. Limited produces that Dow Corning Corporation produces, 1265 Fluid series most preferably, most preferably those viscosity are about 100-350cs.
At this, it also is useful containing the siloxanes fluids that comprises allylic non-end group, and useful especially allyl group is a phenyl group, and the siloxanes fluids that the pi-allyl of particularly suitable available on the market replaces is 556 series of Dow Corning Corporation.
Above-mentioned non-end group also comprises the aminoalkyl groups of forming siloxanes such as polymethyl siloxane with amino functional base, and its structure is:
Figure A9519744700061
In the formula, X is the number of repeat unit on the polymer chain, and y is a methyl group length, and y is greater than 2, but less than about 10; (2<y<10).The poly-aminopropyl methylsiloxane that Dow Corning Corporation produces is a kind of useful especially siloxanes fluids.
Preferred non-volatile siloxane can be from by dimethicone among the present invention, the phenyl dimethicone, and phenyl front three polysiloxanes, fluorosilicone is chosen in the group that amino silicone and composition thereof is formed.
B. thickening agent
For to obtain a kind of overcoat compositions that satisfied viscosity is arranged, prevent to run off from lip immediately after it from using among the present invention, above-mentioned non-volatile siloxane fluid needs to combine with a kind of thickening agent.Used amount of thickener index is about the 1%-25% of compositions, preferred about 1%-10%, 5%-10% most preferably from about, preferred thickening can be from the organic/inorganic thickening agent, fumed silica, fumedization titanium is chosen in the group that calcine aluminium oxide and composition thereof is formed, preferred fumed silica.
Because fumed silica in these compositionss with itself and with the cross-linked network of siloxane polymerization chain formation hydrogen bonded, contain fumed silica in the cosmetic composition usually.These silicon dioxide are geometric form or the certain granules size are arranged, and when mixing with non-volatile silicon dioxide fluid, can obtain a kind of compositions with better skin sense, and it can prevent that skin from producing chiltern sense or friction sense during use.Fumed silica useful in this present invention can be by hydrophobic silicon dioxide, chooses in the group that hydrophilic silicon dioxide and composition thereof is formed.Most preferred hydrophilic fumed silica comprises the theAerosol Series as the disclosed Degussa of the merchandise news list company production of supplier in the list of references.Most preferred hydrophobic fumed silica is mentioned in the information list as above-mentioned supplier, also is the Aerosols that has handled through organic substance that Degussa produces.Aerosil R974 is most preferred hydrophobic fumed silica.
C. nonessential composition
This compositions further comprises nonessential composition, and it is added to above-mentioned composition makes product have the advantages that many consumers are pursued.Described nonessential composition comprises the normally used composition that makes it have the specific dressing effect of being pursued of those cosmetics.Also comprise other in addition as antiseptic and stabilizing agent, it keeps the material integrity of the integral body of product, and said nonessential component comprises wetting agent, occlusive agent, flavoring agent, spice, coloring agent and other common used compositions.
Volatile fluid is useful especially nonessential composition, it has reduced the initial viscosity of colloid siloxanes overcoat, therefore, improved easily the use degree of compositions in lip pomade, because volatile fluid volatilizees from compositions after use, the viscosity of compositions rises rapidly, gives lip comfortable lubricated sense.Described volatile fluid is from by volatile hydrocarbon, chooses in the group that volatile siloxane and composition thereof is formed.This compositions can comprise about 1%-50%, preferred 1%-25%, the most preferably volatile fluid of 1%-10%.The preferred volatile hydrocarbon fluid comprises Fancol ID, the Permethyl 99A of obtainable example such as Permethyl Corporation, and its corresponding molecular formula is:
CH 3(CH 2) 10CH 3
The preferred volatile siloxanes fluids comprises having three, four and the poly-cyclohexyl methyl siloxanes of five-membered ring structure, and corresponding molecular formula is:
Figure A9519744700081
In the formula, x is about 3-6, and described volatile siloxane comprises 244 Fluid of Dow Corning Corporation, 344Fluid and 345 Fluid.Preferably use the fumed silica powder with the volatile fluid gelling.
D. example
Composition Example compositions (wt.%)
???#1 ??#2 ??#3 ??#4 ????#5 ???#6 ???#7 ???#8 ????#9 ??#10 ???#11
500cs dimethicone fluid (1) ???95.0 ???95.0 ??93.5
50cs dimethicone fluid (1) ??92.5 ????82.0 ???95.0 ???95.0 ????92.5
10cs dimethicone fluid (1) ??90.0 ???85.0
300cs fluorosilicone fluid (2) ??95.0
Hydrophilic fumed silica powder (3) ??10.0 ???4.0 ???4.9 ????2.5 ??2.0
Hydrophobic fumed silica powder (4) ???5.0 ??7.5 ??5.0 ????9.0 ???4.4 ????5.0 ??3.0 ???10.0
Fancol ID (5) ????9.0
Tospcarl organosilicon ball (6) ???2.0 ???5.0
The red #6 barium color lake (7) of D﹠C ???0.1
Propyl parabene ???0.5
Propylene carbonate ??0.1 ????1.5
Total amount (wt.%) ?100 ??100 ?100 ?100 ????100 ?100 ???100 ??100 ????100 ????100 ????100
(1) Tospearl 3120A (7) Cardre of Permethyl 99A (6) the Toshiba silicones production of Aerosil R974 (5) the Permethyl Corp. production of Aerosil 200 (4) the Degussa Corp. production of DOW CORNING 200 Fluid (2) DOW CORNING 1265 Fluid (3) Degussa Corp. production, the Chronosphere that Inc. produces
E. manufacturing process
Hybrid silicone fluid and thickening agent in container, mixture stirs, and then it is passed through a three-roll rolling machine at least four times, component is mixed fully, and pulverize all clusters of grains, and mixture can be packed or store then, preferably is sealed in the container.
F. using method
This compositions is being used by the lip surface of one deck lip pomade covering at least, can be moving by the phase attrition of any way such as lip, and finger tip, lip pomade commonly used is coated with device, and this product is applied to above-mentioned lip surface equably.

Claims (8)

1. a compositions that is applied to lip comprises:
A) a kind of non-volatile siloxane fluid accounts for 75%-99%, preferred 90%-99%, and 90%-95% most preferably, its viscosity is 10cs-1000cs, preferred 50cs-500cs;
B) fumed silica accounts for 1%-25%, preferred 1%-10%, most preferably 5%-10%.
2. the compositions of claim 1, wherein the fluidic molecular formula of non-volatile siloxane is:
Figure A9519744700021
In the formula, R1 and R6 can be independently from by hydroxyl terminal groups, have in the group that low alkyl group end group that carbon chain length is C1-C6 and composition thereof formed and choose the preferable methyl group; R2-R5 can be independently from being about the low-grade alkyl group of C1-C6 by having carbon chain length, the fluoroalkyl group, phenyl group is chosen in the group that aminoalkyl groups and composition thereof is formed; The low-grade alkyl group that preferably has carbon chain length C1-C6; The most preferable group.
3. the compositions of claim 2, wherein the non-volatile siloxane fluid can be from by dimethicone, the phenyl dimethicone, phenyl front three polysiloxanes, fluorosilicone is chosen in the group that amino silicone and composition thereof is formed; Preferred dimethicone.
4. the compositions of claim 1, wherein fumed silica can be chosen in the group that hydrophilic silicon dioxide and composition thereof is formed from by hydrophobic silicon dioxide.
5. the compositions of claim 1, comprise in addition 1%-50% from volatile hydrocarbon, the volatile fluid of choosing in volatile siloxane and composition thereof.
6. the compositions of claim 5, comprise 1%-25% from have three, four and the group formed of the SILIBIONE OIL 70047 V20 DC-21330 DC21330 of five-membered ring structure in the volatile siloxane chosen, corresponding molecular formula is:
Figure A9519744700022
X is 3-6 in the formula.
7. the compositions of claim 6 comprises the SILIBIONE OIL 70047 V20 DC-21330 DC21330 of 1%-10%.
8. a compositions comprises
A.75%-99% dimethicone, viscosity are 10cs-1000cs;
B.1%-25% hydrophobic fumed silica;
C.1%-10% SILIBIONE OIL 70047 V20 DC-21330 DC21330.
CN 95197447 1994-12-21 1995-11-28 Lipstick overcoat compositions comprising silicone oil and silica dioxide Pending CN1173125A (en)

Applications Claiming Priority (2)

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US36124694A 1994-12-21 1994-12-21
US08/361,246 1994-12-21

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JP (1) JPH10508867A (en)
CN (1) CN1173125A (en)
AU (1) AU4288996A (en)
CA (1) CA2208443A1 (en)
CO (1) CO4700279A1 (en)
WO (1) WO1996019185A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100366234C (en) * 2003-04-14 2008-02-06 宝洁公司 Anhydrous, transfer-resistant cosmetic lip compositions
EP2123257A2 (en) 2008-05-20 2009-11-25 Evonik Goldschmidt GmbH Stable high Vitamin C content polyol-in-oil emulsified system and its preparation
CN113647388A (en) * 2021-08-12 2021-11-16 广东莱雅新化工科技有限公司 Antibacterial and deodorant air freshener and preparation method thereof

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US6139823A (en) * 1995-11-07 2000-10-31 The Procter & Gamble Company Transfer resistant cosmetic compositions
US6071503A (en) * 1995-11-07 2000-06-06 The Procter & Gamble Company Transfer resistant cosmetic compositions
WO1997017057A1 (en) * 1995-11-07 1997-05-15 The Procter & Gamble Company Compositions and methods for improving the performance of long-wearing cosmetic products
US6406683B1 (en) 1995-11-07 2002-06-18 The Procter & Gamble Company Transfer resistant cosmetic compositions
EP0889711A1 (en) * 1996-01-16 1999-01-13 The Procter & Gamble Company Transfer-resistant lip compositions
KR100486950B1 (en) * 1996-08-26 2005-09-08 가부시키가이샤 시세이도 Lipstick composition
FR2756174B1 (en) * 1996-11-26 1998-12-18 Oreal COMPOSITION, IN PARTICULAR COSMETIC, COMPRISING AT LEAST ONE VOLATILE COMPOUND, AT LEAST ONE WAX AND AT LEAST ONE FLUOROSILICONE COMPOUND, AND USE OF SAID FLUOROSILICONE COMPOUND IN SUCH A COMPOSITION
JP2002087929A (en) * 2000-09-12 2002-03-27 Kose Corp Gel-like composition and cosmetic product comprising the same
US20030072780A1 (en) * 2001-09-06 2003-04-17 Ionita-Manzatu Mirela Cristina Fluid-to-powder compositions
WO2003086333A1 (en) * 2002-04-08 2003-10-23 The Procter & Gamble Company Anhydrous, single phase, transfer resistant cosmetic lip compositions
AU2004229576B2 (en) * 2003-04-14 2007-03-08 The Procter & Gamble Company Anhydrous, silicone modified flourinated polymers for transfer-resistant cosmetic lip compositions
JP5026728B2 (en) * 2006-04-03 2012-09-19 花王株式会社 Makeup cosmetics
FR2924929B1 (en) * 2007-12-13 2010-01-01 Oreal COSMETIC COMPOSITION COMPRISING PERLITE PARTICLES.
JP5719315B2 (en) 2010-02-05 2015-05-13 株式会社 資生堂 Makeup cosmetic and makeup kit containing the makeup cosmetic and topcoat agent
US20160198800A1 (en) * 2015-01-08 2016-07-14 Kimberly Anna O'NEILL High heel hydrogel grip pads
US11931447B2 (en) 2019-04-30 2024-03-19 Dow Global Technologies Llc Polymer/hydrophilic silica oil blend
US20210251855A1 (en) * 2020-02-19 2021-08-19 L'oréal Two-step reactive lip system

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JPS5470437A (en) * 1977-11-16 1979-06-06 Kobayashi Kose Co Lip overcoat
JPS6124512A (en) * 1984-07-13 1986-02-03 Kobayashi Kooc:Kk Overcoating for lipstick
EP0485012B1 (en) * 1990-11-08 1996-02-07 The Procter & Gamble Company Liquid antiperspirant composition
JP3098604B2 (en) * 1992-02-13 2000-10-16 株式会社コーセー Lipstick overcoat
JPH0624932A (en) * 1992-03-18 1994-02-01 Isehan:Kk Lip coat
JPH07196448A (en) * 1994-01-10 1995-08-01 Isehan:Kk Composition for suppressing spreading of rouge

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100366234C (en) * 2003-04-14 2008-02-06 宝洁公司 Anhydrous, transfer-resistant cosmetic lip compositions
EP2123257A2 (en) 2008-05-20 2009-11-25 Evonik Goldschmidt GmbH Stable high Vitamin C content polyol-in-oil emulsified system and its preparation
CN113647388A (en) * 2021-08-12 2021-11-16 广东莱雅新化工科技有限公司 Antibacterial and deodorant air freshener and preparation method thereof

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WO1996019185A1 (en) 1996-06-27
MX9704720A (en) 1997-10-31
AU4288996A (en) 1996-07-10
CA2208443A1 (en) 1996-06-27
EP0794759A1 (en) 1997-09-17
CO4700279A1 (en) 1998-12-29
JPH10508867A (en) 1998-09-02

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