CN117210119A - Water-based UV preprinting gloss oil - Google Patents
Water-based UV preprinting gloss oil Download PDFInfo
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- CN117210119A CN117210119A CN202311352343.XA CN202311352343A CN117210119A CN 117210119 A CN117210119 A CN 117210119A CN 202311352343 A CN202311352343 A CN 202311352343A CN 117210119 A CN117210119 A CN 117210119A
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- water
- gloss oil
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 20
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 claims abstract description 24
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 15
- 239000004417 polycarbonate Substances 0.000 claims abstract description 15
- 150000002009 diols Chemical class 0.000 claims abstract description 13
- JVYDLYGCSIHCMR-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)butanoic acid Chemical compound CCC(CO)(CO)C(O)=O JVYDLYGCSIHCMR-UHFFFAOYSA-N 0.000 claims abstract description 9
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 claims abstract description 9
- KCWDJXPPZHMEIK-UHFFFAOYSA-N isocyanic acid;toluene Chemical class N=C=O.N=C=O.CC1=CC=CC=C1 KCWDJXPPZHMEIK-UHFFFAOYSA-N 0.000 claims abstract description 9
- NDWUBGAGUCISDV-UHFFFAOYSA-N 4-hydroxybutyl prop-2-enoate Chemical compound OCCCCOC(=O)C=C NDWUBGAGUCISDV-UHFFFAOYSA-N 0.000 claims abstract description 8
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000013530 defoamer Substances 0.000 claims abstract description 8
- 239000012975 dibutyltin dilaurate Substances 0.000 claims abstract description 8
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000000080 wetting agent Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 6
- VLGNTAHJZQOHJE-UHFFFAOYSA-N (6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)-phenylmethanone Chemical compound OC1(C(C(=O)C2=CC=CC=C2)C=CC=C1)C VLGNTAHJZQOHJE-UHFFFAOYSA-N 0.000 claims abstract description 3
- -1 ester diol Chemical class 0.000 claims abstract description 3
- 229920000909 polytetrahydrofuran Polymers 0.000 claims abstract description 3
- 239000002994 raw material Substances 0.000 claims abstract description 3
- 238000006243 chemical reaction Methods 0.000 claims description 35
- 238000003756 stirring Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 10
- XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- INJAHHABQHQOMY-UHFFFAOYSA-N 2-(dihydroxymethyl)butanoic acid Chemical compound CCC(C(O)O)C(O)=O INJAHHABQHQOMY-UHFFFAOYSA-N 0.000 claims description 4
- LBTOSGHVABTIRX-UHFFFAOYSA-N oxolane-2,3-diol Chemical compound OC1CCOC1O LBTOSGHVABTIRX-UHFFFAOYSA-N 0.000 claims description 2
- 238000004806 packaging method and process Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000000123 paper Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 238000001816 cooling Methods 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001815 facial effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000002966 varnish Substances 0.000 description 2
- 239000004970 Chain extender Substances 0.000 description 1
- 241000510097 Megalonaias nervosa Species 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011087 paperboard Substances 0.000 description 1
Landscapes
- Polyurethanes Or Polyureas (AREA)
Abstract
The application belongs to the field of packaging printing materials, and particularly relates to water-based UV preprinting gloss oil. The water-based UV preprinting gloss oil is characterized by comprising the following raw materials in parts by mass: 135-193 parts of polycarbonate diol, 21-65 parts of polytetrahydrofuran ester diol, 25-36 parts of dimethylol butyric acid, 10-40 parts of 1, 4-cyclohexanedimethanol, 156-215 parts of hydrogenated phenylmethane diisocyanate, 0.01-0.2 part of dibutyltin dilaurate, 0.01-0.03 part of 4-methoxyphenol, 39-63 parts of 4-hydroxybutyl acrylate, 27-39 parts of triethylamine, 0.3-1 part of organosilicon defoamer, 0.5-1.8 parts of alcohol alkoxy chemical wetting agent, 0.05-0.3 part of vinyl-terminated organosilicon, 18-30 parts of 2-hydroxy-2-methylbenzophenone photoinitiator and 15-27 parts of diphenyl (2, 4, 6-trimethylbenzoyl) phosphine oxide photoinitiator. The beneficial effects are that: the water-based UV preprinting gloss oil can be mixed and dissolved with water and ethanol, is resistant to friction at 180 ℃ and free of scratch and decoloration, is difficult to adhere after being solidified and dried, can be quickly stacked and piled, is convenient for subsequent binding processing, and has good water resistance.
Description
Technical Field
The application belongs to the field of packaging printing materials, and particularly relates to water-based UV preprinting gloss oil.
Background
The traditional corrugated board is formed by facial tissue and paper in a core paper box, the surface of the corrugated board is uneven due to a hollow structure, a washboard phenomenon can be generated at a place with inconsistent pressure during corrugated board processing, excessive moisture is left by applying pressure box colloid to the corrugated core paper in the mounting process, and the technical properties such as flat pressing strength, wear resistance, adhesive strength and the like of the paper box are difficult to meet the requirements of high-grade commodities on packaging. The corrugated paper adopting the preprinting varnish and the preprinting process can ensure the integrity of the paperboard performance, has good protection effect on commodities, and can well protect the shape of the corrugated paper due to small die cutting compression of the corrugated paper.
In the corrugated board production process by adopting the preprinting process, in order to thoroughly dry the adhesive in the corrugated board, the corrugated board needs to be subjected to high-temperature drying and mounting processes at 160-220 ℃, and in the high-temperature baking process, the color and pattern of the printed matter need to be protected from color change. Meanwhile, in the secondary processing process of the tile line, paper products are easy to scrape and scratch, equipment and the like, and patterns printed on the facial tissues are easy to infiltrate and change due to the fact that a large amount of water is contained in the adhesive used for multi-layer compounding.
Disclosure of Invention
In view of the above, the present application provides an aqueous UV preprinting varnish.
The water-based UV preprinting gloss oil is characterized by comprising the following raw materials in parts by mass: 135-193 parts of polycarbonate diol, 21-65 parts of polytetrahydrofuran ester diol, 25-36 parts of dimethylol butyric acid, 10-40 parts of 1, 4-cyclohexanedimethanol, 156-215 parts of hydrogenated phenylmethane diisocyanate, 0.01-0.2 part of dibutyltin dilaurate, 0.01-0.03 part of 4-methoxyphenol, 39-63 parts of 4-hydroxybutyl acrylate, 27-39 parts of triethylamine, 0.3-1 part of organosilicon defoamer, 0.5-1.8 parts of alcohol alkoxy chemical wetting agent, 0.05-0.3 part of vinyl-terminated organosilicon, 18-30 parts of 2-hydroxy-2-methylbenzophenone photoinitiator and 15-27 parts of diphenyl (2, 4, 6-trimethylbenzoyl) phosphine oxide photoinitiator.
The molecular weight of the polycarbonate diol is 1000.
The molecular weight of the tetrahydrofurane diol is 500.
The 1, 4-cyclohexanedimethanol is an internal plasticization heat-resistant chain extender, and can improve the heat resistance and friction resistance of gloss oil.
The hydrogenated phenyl methane diisocyanate provides a smooth polymerization reaction.
The vinyl-terminated organosilicon contains unsaturated vinyl-terminated groups, can react with the preprinted gloss oil during UV curing of the preprinted gloss oil, can improve scratch resistance and hydrophobicity of the gloss oil, and is durable in scratch resistance and hydrophobicity and not easy to migrate due to the participation in curing polymerization.
The preparation method of the aqueous UV preprinting gloss oil is characterized by comprising the following steps:
(1) Heating the reaction kettle to 61+/-2 ℃, adding 135-193 parts of polycarbonate dihydric alcohol, 25-36 parts of dimethylol butyric acid and 10-40 parts of 1, 4-cyclohexanedimethanol into the reaction kettle, and uniformly stirring;
(2) After the dihydroxymethyl butyric acid is fully dissolved and dispersed in the polycarbonate diol, 156-215 parts of hydrogenated phenyl methane diisocyanate is added into a reaction kettle, and the mixture is stirred for 10min, and then the temperature of the reaction kettle is raised to 73+/-2 ℃; reacting for 30min;
(3) Heating the reaction kettle to 93+/-2 ℃, adding 0.01-0.2 part of dibutyltin dilaurate, and reacting for 2 hours;
(4) Dropwise adding 39-63 parts of 4-hydroxybutyl acrylate dissolved with 0.01-0.03 parts of 4-methoxyphenol to the reaction kettle at 73+/-2 ℃ for 30min, and preserving the heat for 1h;
(5) Cooling the temperature of the reaction kettle to 40+/-2 ℃, adding 27-39 parts of triethylamine, stirring for 30min, adding 0.3-1 part of organosilicon defoamer, 0.5-1.8 parts of alcohol alkoxy chemical wetting agent, 0.05-0.3 part of vinyl-terminated organosilicon, 18-30 parts of 2-hydroxy-2-methyl propiophenone photoinitiator and 15-27 parts of diphenyl (2, 4, 6-trimethyl benzoyl) phosphine oxide photoinitiator, stirring uniformly, and discharging.
Compared with the prior art, the application has the beneficial effects that: the water-based UV preprinting gloss oil can be mixed and dissolved with water and ethanol, is resistant to friction at 180 ℃ and free of scratch and decoloration, is difficult to adhere after being solidified and dried, can be quickly stacked and piled, is convenient for subsequent binding processing, and has good water resistance.
Description of the embodiments
The present application is further described below in conjunction with the examples in order to facilitate an understanding of the above objects, features of the arrangement and advantageous effects by those skilled in the art.
Example 1
The preparation method of the water-based UV preprinting gloss oil comprises the following steps:
(1) Heating the reaction kettle to 61+/-2 ℃, adding 135 parts of polycarbonate diol, 25 parts of dimethylol butyric acid and 10 parts of 1, 4-cyclohexanedimethanol into the reaction kettle, and uniformly stirring;
(2) After the dimethylolbutyric acid is fully dissolved and dispersed in the polycarbonate diol, 156 parts of hydrogenated phenyl methane diisocyanate is added into a reaction kettle, and the mixture is stirred for 10min, and then the temperature of the reaction kettle is raised to 73+/-2 ℃; reacting for 30min;
(3) Heating the reaction kettle to 93+/-2 ℃, adding 0.01 part of dibutyltin dilaurate, and reacting for 2 hours;
(4) Cooling the reaction kettle to 73+/-2 ℃, dropwise adding 39 parts of 4-hydroxybutyl acrylate dissolved with 0.01 part of 4-methoxyphenol, finishing dripping for 30min, and preserving heat for 1h;
(5) The temperature of the reaction kettle is raised to 40+/-2 ℃, 27 parts of triethylamine is added, after stirring for 30min, 0.3 part of organosilicon defoamer, 0.5 part of alcohol alkoxy chemical wetting agent, 0.05 part of vinyl-terminated organosilicon, 18 parts of 2-hydroxy-2-methyl propiophenone photoinitiator and 15 parts of diphenyl (2, 4, 6-trimethyl benzoyl) phosphine oxide photoinitiator are added, and after stirring uniformly, the materials are discharged.
Through application test: the aqueous UV preprinting gloss oil is free from decolorization by friction at 180 ℃, is free from adhesion after being accumulated after being solidified and dried, and is free from deformation of patterns of water drops on the UV preprinting coating.
Example 2
The preparation method of the water-based UV preprinting gloss oil comprises the following steps:
(1) Heating the reaction kettle to 61+/-2 ℃, adding 161 parts of polycarbonate diol, 31 parts of dimethylol butyric acid and 32 parts of 1, 4-cyclohexanedimethanol into the reaction kettle, and uniformly stirring;
(2) After the dihydroxymethyl butyric acid is fully dissolved and dispersed in the polycarbonate diol, 195 parts of hydrogenated phenyl methane diisocyanate is added into a reaction kettle, and the mixture is stirred for 10min, and then the temperature of the reaction kettle is raised to 73+/-2 ℃; reacting for 30min;
(3) Heating the reaction kettle to 93+/-2 ℃, adding 0.05 part of dibutyltin dilaurate, and reacting for 2 hours;
(4) Cooling the reaction kettle to 73+/-2 ℃, dropwise adding 53 parts of 4-hydroxybutyl acrylate dissolved with 0.02 part of 4-methoxyphenol, finishing dripping for 30min, and preserving heat for 1h;
(5) The temperature of the reaction kettle is raised to 40+/-2 ℃, 33 parts of triethylamine is added, after stirring for 30min, 0.7 part of organosilicon defoamer, 0.9 part of alcohol alkoxy chemical wetting agent, 0.1 part of vinyl-terminated organosilicon, 23 parts of 2-hydroxy-2-methyl propiophenone photoinitiator and 21 parts of diphenyl (2, 4, 6-trimethyl benzoyl) phosphine oxide photoinitiator are added, and after stirring uniformly, the materials are discharged.
Through application test: the aqueous UV preprinting gloss oil is rubbed at 180 ℃ without scratch for decoloration, is accumulated without adhesion after solidification and drying, and the patterns of water drops on the UV preprinting coating are not deformed.
Example 3
The preparation method of the water-based UV preprinting gloss oil comprises the following steps:
(1) Heating the reaction kettle to 61+/-2 ℃, adding 193 parts of polycarbonate diol, 36 parts of dimethylol butyric acid and 40 parts of 1, 4-cyclohexanedimethanol into the reaction kettle, and uniformly stirring;
(2) After the dihydroxymethyl butyric acid is fully dissolved and dispersed in the polycarbonate diol, 215 parts of hydrogenated phenyl methane diisocyanate is added into a reaction kettle, and the mixture is stirred for 10min, and then the temperature of the reaction kettle is raised to 73+/-2 ℃; reacting for 30min;
(3) Heating the reaction kettle to 93+/-2 ℃, adding 0.2 part of dibutyltin dilaurate, and reacting for 2 hours;
(4) Cooling the reaction kettle to 73+/-2 ℃, dropwise adding 63 parts of 4-hydroxybutyl acrylate dissolved with 0.03 part of 4-methoxyphenol, finishing dripping for 30min, and preserving heat for 1h;
(5) The temperature of the reaction kettle is raised to 40+/-2 ℃, 39 parts of triethylamine is added, after stirring for 30min, 0.8 part of organosilicon defoamer, 1.8 parts of alcohol alkoxy chemical wetting agent, 0.3 part of vinyl-terminated organosilicon, 30 parts of 2-hydroxy-2-methyl propiophenone photoinitiator and 27 parts of diphenyl (2, 4, 6-trimethyl benzoyl) phosphine oxide photoinitiator are added, and after stirring uniformly, the materials are discharged.
Through application test: the aqueous UV preprinting gloss oil is rubbed at 180 ℃ without scratch for decoloration, is accumulated without adhesion after solidification and drying, and the patterns of water drops on the UV preprinting coating are not deformed.
The above specific examples are further illustrative of the technical solution and the advantageous effects of the present application, and are not limiting to the embodiments.
Claims (4)
1. The water-based UV preprinting gloss oil is characterized by comprising the following raw materials in parts by mass: 135-193 parts of polycarbonate diol, 21-65 parts of polytetrahydrofuran ester diol, 25-36 parts of dimethylol butyric acid, 10-40 parts of 1, 4-cyclohexanedimethanol, 156-215 parts of hydrogenated phenylmethane diisocyanate, 0.01-0.2 part of dibutyltin dilaurate, 0.01-0.03 part of 4-methoxyphenol, 39-63 parts of 4-hydroxybutyl acrylate, 27-39 parts of triethylamine, 0.3-1 part of organosilicon defoamer, 0.5-1.8 parts of alcohol alkoxy chemical wetting agent, 0.05-0.3 part of vinyl-terminated organosilicon, 18-30 parts of 2-hydroxy-2-methylbenzophenone photoinitiator and 15-27 parts of diphenyl (2, 4, 6-trimethylbenzoyl) phosphine oxide photoinitiator.
2. The aqueous UV preprinting oil according to claim 1, wherein the polycarbonate diol has a molecular weight of 1000.
3. The aqueous UV preprinting oil according to claim 1, wherein the tetrahydrofurane diol has a molecular weight of 500.
4. The aqueous UV preprinting oil of claim 1, which is prepared by the steps of:
(1) Heating the reaction kettle to 61+/-2 ℃, adding 135-193 parts of polycarbonate dihydric alcohol, 25-36 parts of dimethylol butyric acid and 10-40 parts of 1, 4-cyclohexanedimethanol into the reaction kettle, and uniformly stirring;
(2) After the dihydroxymethyl butyric acid is fully dissolved and dispersed in the polycarbonate diol, 156-215 parts of hydrogenated phenyl methane diisocyanate is added into a reaction kettle, and the mixture is stirred for 10min, and then the temperature of the reaction kettle is raised to 73+/-2 ℃; reacting for 30min;
(3) Heating the reaction kettle to 93+/-2 ℃, adding 0.01-0.2 part of dibutyltin dilaurate, and reacting for 2 hours;
(4) Dropwise adding 39-63 parts of 4-hydroxybutyl acrylate dissolved with 0.01-0.03 parts of 4-methoxyphenol to the reaction kettle at 73+/-2 ℃ for 30min, and preserving the heat for 1h;
(5) The temperature of the reaction kettle is raised to 40+/-2 ℃, 27-39 parts of triethylamine is added, after stirring for 30min, 0.3-1 part of organosilicon defoamer, 0.5-1.8 parts of alcohol alkoxy chemical wetting agent, 0.05-0.3 part of vinyl-terminated organosilicon, 18-30 parts of 2-hydroxy-2-methyl propiophenone photoinitiator and 15-27 parts of diphenyl (2, 4, 6-trimethyl benzoyl) phosphine oxide photoinitiator are added, and after fully stirring uniformly, the materials are discharged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311352343.XA CN117210119A (en) | 2023-10-19 | 2023-10-19 | Water-based UV preprinting gloss oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202311352343.XA CN117210119A (en) | 2023-10-19 | 2023-10-19 | Water-based UV preprinting gloss oil |
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| CN117210119A true CN117210119A (en) | 2023-12-12 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202311352343.XA Pending CN117210119A (en) | 2023-10-19 | 2023-10-19 | Water-based UV preprinting gloss oil |
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Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009161710A (en) * | 2008-01-10 | 2009-07-23 | Dic Corp | Surface printing mat ink composition for laminated film |
| CN101967341A (en) * | 2010-09-29 | 2011-02-09 | 中国科学院长春应用化学研究所 | Waterborne wear-resisting ultraviolet-cured glazing oil and preparation method thereof |
| CN102070981A (en) * | 2010-12-02 | 2011-05-25 | 广州慧谷化学有限公司 | Ultraviolet curing paint and preparation method and application thereof |
| CN102649895A (en) * | 2012-05-18 | 2012-08-29 | 中国印刷科学技术研究所 | Ultraviolet light-heat dual-curing gloss oil, and preparation method and application thereof |
| CN103074802A (en) * | 2013-01-24 | 2013-05-01 | 陕西科技大学 | Preparation method for ultraviolet curing water-based paper varnish |
| CN103756552A (en) * | 2014-01-14 | 2014-04-30 | 汕头市龙湖昌丰化工有限公司 | UV (Ultraviolet) impressing gloss oil and preparation method thereof |
| CN104387552A (en) * | 2014-11-24 | 2015-03-04 | 鹤山雅图仕印刷有限公司 | Biodegradable UV (ultraviolet)-curable resin as well as preparation method and application thereof in coating material for paper |
| CN104558499A (en) * | 2013-10-23 | 2015-04-29 | 湖南岁丰新材料科技发展有限公司 | UV-curable elastic polyurethane acrylate emulsion and synthesis method thereof |
| CN105505195A (en) * | 2015-12-30 | 2016-04-20 | 中物功能材料研究院有限公司 | Waterborne ultraviolet curing gloss oil and preparation method thereof |
| JP2017042956A (en) * | 2015-08-25 | 2017-03-02 | 協立化学産業株式会社 | Method for manufacturing laminate |
| CN107619622A (en) * | 2017-08-02 | 2018-01-23 | 洋紫荆油墨(中山)有限公司 | A kind of glass water resistance UV gloss oil and preparation method thereof |
| CN108795259A (en) * | 2018-05-12 | 2018-11-13 | 湖南辰砾新材料有限公司 | A kind of waterborne organic silicon is modified UV woodcare paints and preparation method thereof |
| CN113278326A (en) * | 2021-06-25 | 2021-08-20 | 东莞新能德科技有限公司 | Printing ink and preparation method and curing method thereof |
| CN115418161A (en) * | 2022-09-22 | 2022-12-02 | 江西晨光新材料股份有限公司 | Ultraviolet-curing antifogging high-transparency display screen coating composition and preparation method thereof |
| WO2023049857A1 (en) * | 2021-09-24 | 2023-03-30 | Materia, Inc. | Hybrid compositions comprising olefinic compositions and resin compositions polymerizable by addition or condensation polymerization reactions |
-
2023
- 2023-10-19 CN CN202311352343.XA patent/CN117210119A/en active Pending
Patent Citations (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2009161710A (en) * | 2008-01-10 | 2009-07-23 | Dic Corp | Surface printing mat ink composition for laminated film |
| CN101967341A (en) * | 2010-09-29 | 2011-02-09 | 中国科学院长春应用化学研究所 | Waterborne wear-resisting ultraviolet-cured glazing oil and preparation method thereof |
| CN102070981A (en) * | 2010-12-02 | 2011-05-25 | 广州慧谷化学有限公司 | Ultraviolet curing paint and preparation method and application thereof |
| CN102649895A (en) * | 2012-05-18 | 2012-08-29 | 中国印刷科学技术研究所 | Ultraviolet light-heat dual-curing gloss oil, and preparation method and application thereof |
| CN103074802A (en) * | 2013-01-24 | 2013-05-01 | 陕西科技大学 | Preparation method for ultraviolet curing water-based paper varnish |
| CN104558499A (en) * | 2013-10-23 | 2015-04-29 | 湖南岁丰新材料科技发展有限公司 | UV-curable elastic polyurethane acrylate emulsion and synthesis method thereof |
| CN103756552A (en) * | 2014-01-14 | 2014-04-30 | 汕头市龙湖昌丰化工有限公司 | UV (Ultraviolet) impressing gloss oil and preparation method thereof |
| CN104387552A (en) * | 2014-11-24 | 2015-03-04 | 鹤山雅图仕印刷有限公司 | Biodegradable UV (ultraviolet)-curable resin as well as preparation method and application thereof in coating material for paper |
| JP2017042956A (en) * | 2015-08-25 | 2017-03-02 | 協立化学産業株式会社 | Method for manufacturing laminate |
| CN105505195A (en) * | 2015-12-30 | 2016-04-20 | 中物功能材料研究院有限公司 | Waterborne ultraviolet curing gloss oil and preparation method thereof |
| CN107619622A (en) * | 2017-08-02 | 2018-01-23 | 洋紫荆油墨(中山)有限公司 | A kind of glass water resistance UV gloss oil and preparation method thereof |
| CN108795259A (en) * | 2018-05-12 | 2018-11-13 | 湖南辰砾新材料有限公司 | A kind of waterborne organic silicon is modified UV woodcare paints and preparation method thereof |
| CN113278326A (en) * | 2021-06-25 | 2021-08-20 | 东莞新能德科技有限公司 | Printing ink and preparation method and curing method thereof |
| WO2023049857A1 (en) * | 2021-09-24 | 2023-03-30 | Materia, Inc. | Hybrid compositions comprising olefinic compositions and resin compositions polymerizable by addition or condensation polymerization reactions |
| CN115418161A (en) * | 2022-09-22 | 2022-12-02 | 江西晨光新材料股份有限公司 | Ultraviolet-curing antifogging high-transparency display screen coating composition and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 王光彬等: "《涂料与涂装技术》", vol. 1, 31 August 1994, 北京：国防工业出版社, pages: 239 * |
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