CN1171949C - 改善的流动碳酸酯聚合物混合物 - Google Patents
改善的流动碳酸酯聚合物混合物 Download PDFInfo
- Publication number
- CN1171949C CN1171949C CNB008191557A CN00819155A CN1171949C CN 1171949 C CN1171949 C CN 1171949C CN B008191557 A CNB008191557 A CN B008191557A CN 00819155 A CN00819155 A CN 00819155A CN 1171949 C CN1171949 C CN 1171949C
- Authority
- CN
- China
- Prior art keywords
- rubber
- weight
- side chain
- polymer blend
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
- C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
- C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
- C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
实施例 | 1* | 2* | 3* | 4* | 5* | 6* | 7* | 8* | 9* | 10* | 11* | 12* | 13* |
混合组合物 | |||||||||||||
%PC-1 | 66 | 66 | 66 | 66 | 66 | 66 | 70 | 55 | 66 | 66 | 66 | 66 | 66 |
%ABS | 33.7 | 33.7 | 33.7 | 33.7 | 33.7 | 33.7 | 29.7 | 44.7 | 33.7 | 33.7 | 33.7 | 33.7 | 33.7 |
%Irganox 1076 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
%Lubril JK | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 | 0.1 |
PC成分 | |||||||||||||
MFR(300℃/1.2kg)g/10分钟 | 10 | 10 | 10 | 14 | 22 | 10 | 10 | 10 | 10 | 10 | 10 | 14 | 10 |
ABS成分 | |||||||||||||
%星形支链橡胶 | 14.8 | 15.9 | 15.6 | 15.6 | 15.6 | 17.1 | 17.1 | 17.1 | 9.4 | 7.6 | 10.6 | 10.6 | 0 |
%直链橡胶 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 0 | 9.4 | 7.6 | 4.6 | 4.6 | 22.1 |
%总的橡胶 | 14.8 | 15.9 | 15.6 | 15.6 | 15.6 | 17.1 | 17.1 | 17.1 | 18.8 | 15.2 | 15.2 | 15.2 | 22.1 |
%AN | 24 | 22.7 | 22.7 | 22.7 | 22.7 | 22.4 | 22.4 | 22.4 | 20.5 | 22.6 | 24.4 | 24.4 | 20.2 |
LAR | 2.08 | 2.50 | 2.65 | 2.65 | 2.65 | 2.35 | 2.35 | 2.35 | 2.92 | 1.99 | 2.33 | 2.33 | 3.50 |
MFR(230℃/3.8kg)g/10分钟 | 2.3 | 3 | 3.4 | 3.4 | 3.4 | 3.3 | 3.3 | 3.3 | 4.25 | 4.1 | 2.4 | 2.4 | 4.5 |
Mw | 149000 | 151000 | 150000 | 150000 | 150000 | 154000 | 154000 | 154000 | 140000 | 146000 | 153000 | 153000 | 139000 |
粒径(D43)微米 | 1.0 | 0.65 | 0.83 | 0.83 | 0.83 | 0.98 | 0.98 | 0.98 | 1.2 | 0.86 | 0.81 | 0.81 | 0.81 |
混合物性能 | |||||||||||||
张力 | |||||||||||||
拉伸模量MPa | 2482 | 2620 | 2551 | 2482 | 2551 | 2758 | 2689 | 2413 | 2344 | 2413 | 2482 | 2758 | 2482 |
断裂时的伸长率% | 127 | 119 | 129 | 103 | 85 | 124 | 123 | 122 | 59 | 125 | 132 | 123 | 120 |
拉伸断裂kPa | 53090 | 53779 | 59295 | 49642 | 48263 | 57226 | 57916 | 48953 | 45850 | 55158 | 56537 | 50332 | 50332 |
屈服时的伸长率% | 4.8 | 5 | 5 | 4.9 | 4.9 | 4.7 | 5 | 4.7 | 4.8 | 4.9 | 4.8 | 4.7 | 5.0 |
拉伸屈服kPa | 56537 | 59295 | 61363 | 58605 | 61363 | 59984 | 61363 | 56537 | 55848 | 58605 | 58605 | 58605 | 58605 |
抗弯性 | |||||||||||||
弯曲模量MPa | 2482 | 2620 | 2689 | 2551 | 2689 | 2827 | 2896 | 2551 | 2413 | 2620 | 2551 | 2620 | 2482 |
强度kPa | 88942 | 91700 | 95148 | 90321 | 94458 | 95837 | 98595 | 89632 | 86874 | 92390 | 90321 | 92390 | 88942 |
热量 | |||||||||||||
于1.82MPa,℃时的DTUL | 106.1 | 104.4 | 107.2 | 107.8 | 104.4 | 105.6 | 110.6 | 101.1 | 105.0 | 107.8 | 106.7 | 105.0 | 105.6 |
缺口Izod | |||||||||||||
-23℃,J/m | 646 | 582 | 657 | 593 | 464 | 619 | 630 | 790 | 625 | 614 | 630 | 630 | 571 |
-29℃,J/m | 502 | 416 | 416 | 326 | 165 | 427 | 459 | 464 | 491 | 470 | 539 | 480 | 379 |
-40℃,J/m | 518 | 438 | 459 | 518 | 496 | 475 | 374 | ||||||
-45℃,J/m | 475 | 480 | 454 | 480 | |||||||||
DBTT | <-45 | -40 | -35 | -32 | -18 | -38 | -38 | -35 | <-45 | -45 | <-45 | -45 | -45 |
落镖冲击 | |||||||||||||
23℃最大能量, | 54.2 | 53.1 | 53.1 | 50.8 | 48.6 | 56.5 | 58.8 | 46.3 | 48.6 | 49.7 | 55.4 | 53.1 | 46.3 |
23℃总能量,J | 59.9 | 58.8 | 57.6 | 55.4 | 53.1 | 62.1 | 63.3 | 52.0 | 55.4 | 59.9 | 59.9 | 58.8 | 53.1 |
-29℃最大能量,J | 52.0 | 53.1 | 54.2 | 49.7 | 54.2 | 55.4 | 57.6 | 44.1 | 50.8 | 54.2 | 53.1 | 48.6 | 49.7 |
-29℃总能量,J | 66.7 | 67.8 | 63.3 | 57.6 | 62.1 | 65.5 | 65.5 | 53.1 | 58.9 | 68.9 | 65.5 | 62.1 | 64.4 |
模制后的PC Mw | 28400 | 27900 | 28700 | 26700 | 23100 | 28300 | 28600 | 28200 | 27900 | 28500 | 28700 | 26800 | 25900 |
粘度 | - | ||||||||||||
MFR(230℃/3.8kg)g/10分钟 | 2.6 | 3 | 2.42 | 3.03 | 5 | 2.35 | 2.26 | 2.56 | 3.3 | 2.9 | 2.5 | 3 | 3.4 |
实施例 | 14 | 15 | 16 |
混合组合物 | |||
%PC-2 | 41.9 | 41.7 | 40.9 |
%PC-3 | 5.9 | 5.9 | 5.8 |
%PC-4 | 11.9 | 11.9 | 11.7 |
%ABS | 39.9 | 39.8 | 38.9 |
%MBS | 2.0 | ||
%Irganox 1076 | 0.2 | 0.2 | 0.2 |
%Lubril JK | 0.1 | 0.1 | |
%GMS | 0.3 | 0.3 | |
ABS成分 | |||
%星形支链橡胶 | 7.6 | 7.6 | 7.6 |
%直链橡胶 | 7.6 | 7.6 | 7.6 |
%总橡胶 | 15.2 | 15.2 | 15.2 |
%AN | 22.6 | 22.6 | 22.6 |
LAR | 1.99 | 1.99 | 1.99 |
MFR(230℃/3.8kg),g/10分钟 | 4.1 | 4.1 | 4.1 |
Mw | 146000 | 146000 | 146000 |
粒径(D43),微米 | 0.86 | 0.86 | 0.86 |
混合物性能 | |||
张力 | |||
拉伸模量MPa | 2100 | ||
断裂时的伸长率% | 46.5 | ||
拉伸断裂kPa | 45 | ||
拉伸屈服kPa | 57 | ||
抗弯性 | |||
弯曲模量MPa | 2700 | 2700 | 2600 |
热量 | |||
于1.82MPa,℃时的DTUL | 97.4 | 97.1 | 99.6 |
缺口Izod | |||
23℃,J/m | 582 | 566 | 560 |
-25℃,J/m | 471 | ||
-40℃,J/m | 197 | 155 | 373 |
模制后的PC Mw | 23,600 | ||
粘度 | |||
MFR(230℃/3.8kg),g/10分钟 | 5.9 | 5.9 | 5.8 |
Claims (42)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/512,567 | 2000-02-24 | ||
US09/512,567 US6380303B1 (en) | 2000-02-24 | 2000-02-24 | Flow carbonate polymer blends |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1434842A CN1434842A (zh) | 2003-08-06 |
CN1171949C true CN1171949C (zh) | 2004-10-20 |
Family
ID=24039646
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008191557A Expired - Fee Related CN1171949C (zh) | 2000-02-24 | 2000-12-15 | 改善的流动碳酸酯聚合物混合物 |
Country Status (12)
Country | Link |
---|---|
US (1) | US6380303B1 (zh) |
EP (1) | EP1268666B1 (zh) |
JP (1) | JP4965044B2 (zh) |
KR (1) | KR100680328B1 (zh) |
CN (1) | CN1171949C (zh) |
AU (1) | AU2001222665A1 (zh) |
BR (1) | BR0017116B1 (zh) |
CA (1) | CA2398807C (zh) |
DE (1) | DE60009573T2 (zh) |
MX (1) | MXPA02008269A (zh) |
TW (1) | TWI242582B (zh) |
WO (1) | WO2001062851A1 (zh) |
Families Citing this family (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10152317A1 (de) * | 2001-10-26 | 2003-05-08 | Bayer Ag | Mineralverstärkte schlagzähmodifizierte Polycarbonat-Blends |
DE10204524A1 (de) * | 2002-02-05 | 2003-08-07 | Bayer Ag | Zusammensetzungen enthaltend Polycarbonat |
US6930150B2 (en) * | 2002-08-29 | 2005-08-16 | Taylor Made Golf Company, Inc. | Method for making polymer mixtures and compositions thereof |
DE102004019932A1 (de) * | 2004-04-21 | 2005-11-17 | Basf Ag | Extrudierte Folie oder Platte mit verbesserter Zähigkeit |
CN1312101C (zh) * | 2004-10-15 | 2007-04-25 | 上海吴泾化工有限公司 | 提高醋酸高锰酸钾试验时间的醋酸精制方法 |
KR100615909B1 (ko) * | 2004-11-24 | 2006-08-28 | 제일모직주식회사 | 내화학성과 내충격성이 우수한 폴리카보네이트 수지조성물 |
KR100870106B1 (ko) * | 2006-03-21 | 2008-11-25 | 제일모직주식회사 | 메틸메타크릴레이트-아크릴로니트릴-부타디엔-스티렌공중합체 수지를 이용한 광디스크 |
US8486135B2 (en) | 2006-06-01 | 2013-07-16 | Abbott Cardiovascular Systems Inc. | Implantable medical devices fabricated from branched polymers |
US8262723B2 (en) * | 2007-04-09 | 2012-09-11 | Abbott Cardiovascular Systems Inc. | Implantable medical devices fabricated from polymer blends with star-block copolymers |
US20110159293A1 (en) * | 2009-12-31 | 2011-06-30 | Cheil Industries Inc. | Polycarbonate Resin Composition and Molded Product Using the Same |
US20110308761A1 (en) * | 2010-06-17 | 2011-12-22 | Air Products And Chemicals, Inc. | Regenerator, regeneration process, and liquid polymer mixture for a regenerator |
KR101144112B1 (ko) * | 2010-07-20 | 2012-05-24 | 전남대학교산학협력단 | 아크릴로니트릴 부타디엔 스티렌 소재의 내충격 물성 예측 방법 |
KR101362888B1 (ko) * | 2011-12-29 | 2014-02-14 | 제일모직주식회사 | 텔레비젼 하우징 및 그 제조방법 |
EP2657294A1 (de) | 2012-04-27 | 2013-10-30 | Bayer MaterialScience AG | Verarbeitungsstabile PC/ABS-Zusammensetzungen |
KR20140086767A (ko) * | 2012-12-28 | 2014-07-08 | 제일모직주식회사 | 텔레비전 하우징 및 그 제조방법 |
US10053597B2 (en) | 2013-01-18 | 2018-08-21 | Basf Se | Acrylic dispersion-based coating compositions |
EP3431511A1 (en) * | 2017-07-19 | 2019-01-23 | ARLANXEO Deutschland GmbH | Star-branched diene rubber |
CN111954687B (zh) | 2018-03-28 | 2022-12-27 | 科思创知识产权两合公司 | 用于生产具有提高的光泽度的模制品的组合物和热塑性模塑料 |
CN109796736B (zh) * | 2018-12-25 | 2021-05-18 | 金发科技股份有限公司 | 一种聚碳酸酯组合物及其制备方法和应用 |
US11834537B2 (en) | 2020-03-31 | 2023-12-05 | Lg Chem, Ltd. | Carboxylic acid modified-nitrile based copolymer latex and latex composition for dip-forming comprising the copolymer latex and article formed by the composition |
US11873391B2 (en) | 2020-03-31 | 2024-01-16 | Lg Chem, Ltd. | Carboxylic acid modified-nitrile based copolymer latex and latex composition for dip-forming comprising the copolymer latex and article formed by the composition |
CN114656769B (zh) * | 2022-03-30 | 2024-05-14 | 上海金发科技发展有限公司 | 一种pc/abs树脂合金及其制备方法和应用 |
Family Cites Families (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL104015C (zh) | 1953-10-16 | |||
BE570531A (zh) | 1957-08-22 | |||
US3243481A (en) | 1962-01-08 | 1966-03-29 | Dow Chemical Co | Process for making graft copolymers of vinyl aromatic compounds and stereospecific rubbers |
BE627652A (zh) | 1962-01-29 | |||
BE638995A (zh) | 1962-07-16 | |||
US3281383A (en) | 1962-08-09 | 1966-10-25 | Phillips Petroleum Co | Branched polymers prepared from monolithium-terminated polymers and compounds having at least three reactive sites |
DE1570336A1 (de) | 1965-02-24 | 1969-08-14 | Huels Chemische Werke Ag | Verfahren zur definierten Erhoehung des Molekulargewichtes ungesaettigter polymerer Kohlenwasserstoffe |
US3668162A (en) | 1968-11-25 | 1972-06-06 | Phillips Petroleum Co | Treating polybutadiene |
US3787510A (en) | 1969-02-03 | 1974-01-22 | Phillips Petroleum Co | Multifunctional polymerization initiators |
US3668263A (en) | 1970-01-19 | 1972-06-06 | Lithium Corp | Organolithium polymerization initiators and use thereof in polymerization processes |
US3660535A (en) | 1970-09-23 | 1972-05-02 | Dow Chemical Co | Process for the production of alkenyl aromatic polymers containing a reinforcing polymer therein |
US4183877A (en) | 1975-05-12 | 1980-01-15 | Asahi Kasei Kogyo Kabushiki Kaisha | High-impact polystyrene composition and production thereof |
FR2313389A1 (fr) | 1975-06-06 | 1976-12-31 | Anvar | Nouveaux amorceurs de polymerisation organolithiens bi-fonctionnels et leurs applications, en particulier pour l'obtention d'elastomeres thermoplastiques |
US4156069A (en) | 1976-04-02 | 1979-05-22 | Allied Chemical Corporation | Bisphenol-A/terephthalate/carbonate melt processable copolymers |
US4182818A (en) | 1977-08-15 | 1980-01-08 | The Dow Chemical Company | Polyfunctional lithium containing initiator |
US4260731A (en) | 1978-09-11 | 1981-04-07 | Mitsubishi Chemical Industries, Ltd. | Aromatic polyester-polycarbonate |
US4239863A (en) | 1979-06-28 | 1980-12-16 | The Dow Chemical Company | Process for the polymerization of acrylonitrile-butadiene-styrene resins |
US4340690A (en) | 1980-05-27 | 1982-07-20 | The Goodyear Tire & Rubber Company | Cyclic organo carbonate and sulfite coupling agents for living polymers of conjugated dienes |
US4340691A (en) | 1980-05-27 | 1982-07-20 | The Goodyear Tire & Rubber Company | Linear organo carbonate coupling agents for living polymers of conjugated dienes |
US4529791A (en) | 1981-01-28 | 1985-07-16 | The Dow Chemical Company | Interfacial polycarbonate preparation by adding additional solvent |
US4677162A (en) | 1983-04-15 | 1987-06-30 | Mobay Corporation | Polycarbonate blends having low gloss |
US4572819A (en) | 1983-08-24 | 1986-02-25 | The Dow Chemical Company | Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled |
US4585825A (en) | 1983-09-30 | 1986-04-29 | The Dow Chemical Company | Monovinylidene aromatic polymer resins having added amounts of high molecular weight polymer |
US4666987A (en) | 1985-02-22 | 1987-05-19 | The Dow Chemical Company | In-mold polymerization of vinyl aromatic compound |
US4940752A (en) * | 1988-12-19 | 1990-07-10 | Polysar Financial Services S.A. | Styrenic polycarbonate alloys |
US5087663A (en) * | 1989-03-08 | 1992-02-11 | The Dow Chemical Company | Molding compositions with methyl (meth)acrylate-butadiene-styrene graft copolymers |
US5290842A (en) * | 1991-09-03 | 1994-03-01 | Avery Dennison Corporation | Pressure-sensitive adhesives based on preferentially tackified immiscible elastomers |
JP3152709B2 (ja) * | 1991-12-18 | 2001-04-03 | 日本エラストマー株式会社 | ゴム変性耐衝撃性樹脂組成物及びその製造方法 |
JP3336685B2 (ja) * | 1993-06-17 | 2002-10-21 | 日本エラストマー株式会社 | ゴム変性耐衝撃性スチレン系樹脂組成物及びその製造方法 |
JP3336686B2 (ja) * | 1993-06-18 | 2002-10-21 | 日本エラストマー株式会社 | 耐衝撃性スチレン系樹脂組成物及びその製造方法 |
JP2993338B2 (ja) * | 1993-10-18 | 1999-12-20 | 住友化学工業株式会社 | ゴム変性ポリスチレン樹脂組成物、その製造方法及び射出成形品 |
US5508359A (en) | 1993-11-22 | 1996-04-16 | The Dow Chemical Company | Blends of high MW branched polycarbonate with a lower MW polycarbonate |
TW377367B (en) * | 1994-06-21 | 1999-12-21 | Asahi Kasei Corp | Aromatic polycarbonate-styrene polymer resin composition |
US5804673A (en) | 1997-01-09 | 1998-09-08 | The Dow Chemical Compny | Blend of branched and linear carbonate polymer resins |
WO1998051737A1 (en) * | 1997-05-15 | 1998-11-19 | General Electric Company | Aromatic polycarbonate resin composition for molding |
JP2001139765A (ja) * | 1999-11-11 | 2001-05-22 | Nippon Elastomer Kk | ポリカーボネート樹脂/abs系樹脂組成物 |
-
2000
- 2000-02-24 US US09/512,567 patent/US6380303B1/en not_active Expired - Fee Related
- 2000-12-15 BR BRPI0017116-6A patent/BR0017116B1/pt not_active IP Right Cessation
- 2000-12-15 AU AU2001222665A patent/AU2001222665A1/en not_active Abandoned
- 2000-12-15 CA CA2398807A patent/CA2398807C/en not_active Expired - Fee Related
- 2000-12-15 CN CNB008191557A patent/CN1171949C/zh not_active Expired - Fee Related
- 2000-12-15 DE DE60009573T patent/DE60009573T2/de not_active Expired - Lifetime
- 2000-12-15 JP JP2001562628A patent/JP4965044B2/ja not_active Expired - Fee Related
- 2000-12-15 MX MXPA02008269A patent/MXPA02008269A/es active IP Right Grant
- 2000-12-15 EP EP00986425A patent/EP1268666B1/en not_active Expired - Lifetime
- 2000-12-15 WO PCT/US2000/034064 patent/WO2001062851A1/en active IP Right Grant
- 2000-12-15 KR KR1020027011088A patent/KR100680328B1/ko not_active IP Right Cessation
-
2001
- 2001-01-10 TW TW090100565A patent/TWI242582B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
KR20020089361A (ko) | 2002-11-29 |
KR100680328B1 (ko) | 2007-02-09 |
BR0017116A (pt) | 2003-01-14 |
TWI242582B (en) | 2005-11-01 |
AU2001222665A1 (en) | 2001-09-03 |
EP1268666A1 (en) | 2003-01-02 |
JP2003524053A (ja) | 2003-08-12 |
EP1268666B1 (en) | 2004-03-31 |
MXPA02008269A (es) | 2004-06-29 |
CA2398807A1 (en) | 2001-08-30 |
CN1434842A (zh) | 2003-08-06 |
CA2398807C (en) | 2010-04-27 |
DE60009573D1 (de) | 2004-05-06 |
WO2001062851A1 (en) | 2001-08-30 |
US6380303B1 (en) | 2002-04-30 |
BR0017116B1 (pt) | 2010-08-24 |
JP4965044B2 (ja) | 2012-07-04 |
DE60009573T2 (de) | 2004-12-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1171949C (zh) | 改善的流动碳酸酯聚合物混合物 | |
EP1222218B1 (en) | Improved mass polymerized rubber-modified monovinylidene aromatic copolymer compositions | |
CN1171130A (zh) | 基于接枝共聚物和嵌段共聚物的热塑性模塑组合物 | |
CN1153811C (zh) | 具有改进的性能稳定性的聚合物组合物 | |
CN1404506A (zh) | 具有改良的可加工性和高光泽度的abs-模塑组合物 | |
CN1898329A (zh) | 聚碳酸酯树脂组合物以及具有该组合物的模制品 | |
CN1085997C (zh) | 聚碳酸酯树脂组合物 | |
CN1164681C (zh) | 改进流动性的碳酸酯聚合物共混料 | |
CN1235970C (zh) | 热塑性模塑组合物 | |
EP1141120B1 (en) | Improved rubber modified monovinylidene aromatic polymer compositions | |
CN101050299A (zh) | 一种基于连续本体法的abs聚合物与聚碳酸酯合金的制备方法 | |
CN1170862C (zh) | 苯乙烯系树脂组合物及其制造方法 | |
CN100335557C (zh) | 透明橡胶改质聚苯乙烯系树脂 | |
JPH0686565B2 (ja) | 艶消しされたポリカーボネート系樹脂組成物の製造方法 | |
CN1269898C (zh) | 透明橡胶改质苯乙烯系树脂 | |
JPH1025399A (ja) | ポリカーボネート/abs樹脂組成物 | |
JPH07149846A (ja) | ゴム変性スチレン系樹脂組成物 | |
JPH10147703A (ja) | 熱可塑性樹脂組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: STYRON EUROPE SHARES GMBH Free format text: FORMER OWNER: STYRON LLC Effective date: 20110826 Owner name: STYRON LLC Effective date: 20110826 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20110826 Address after: Horgen Switzerland Patentee after: Styron Europe Co.,Ltd. Address before: michigan Patentee before: Styron LLC Effective date of registration: 20110826 Address after: michigan Patentee after: Styron LLC Address before: michigan Patentee before: Dow Global Technologies Inc. |
|
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20041020 Termination date: 20111215 |