CN117004321A - Water-in-water paint with enamel coating and preparation method thereof - Google Patents

Water-in-water paint with enamel coating and preparation method thereof Download PDF

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Publication number
CN117004321A
CN117004321A CN202310519886.XA CN202310519886A CN117004321A CN 117004321 A CN117004321 A CN 117004321A CN 202310519886 A CN202310519886 A CN 202310519886A CN 117004321 A CN117004321 A CN 117004321A
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CN
China
Prior art keywords
parts
water
enamel coating
coating
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202310519886.XA
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Chinese (zh)
Inventor
林传登
陈春潮
林家钧
林孟尧
林孟庆
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Minyuan Building Materials Technology Co ltd
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Shandong Minyuan Building Materials Technology Co ltd
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Filing date
Publication date
Application filed by Shandong Minyuan Building Materials Technology Co ltd filed Critical Shandong Minyuan Building Materials Technology Co ltd
Priority to CN202310519886.XA priority Critical patent/CN117004321A/en
Publication of CN117004321A publication Critical patent/CN117004321A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18Fireproof paints including high temperature resistant paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

Abstract

The invention provides a water-in-water coating with an enamel coating and a preparation method thereof, and relates to the technical field of coating production. The water-in-water paint with the enamel coating comprises water-in-water paint and an enamel coating, wherein the enamel coating is arranged on the surface of the water-in-water paint, and the water-in-water paint comprises the following raw materials in parts by mass: 1-5 parts of bentonite, 30-50 parts of a brilliant nest partner, 4-10 parts of propylene glycol, 0.5-2 parts of a bactericide, 5-12 parts of a film forming auxiliary agent, 100-200 parts of 619 emulsion, 1-5 parts of a thickener, 1-3 parts of a 95 multifunctional auxiliary agent, 0.1-1 part of a defoaming agent, 50-100 parts of color stone chips and 300-400 parts of 80-129 mesh snow flower. The enamel coating is added on the surface of the water-in-water coating, so that the water-in-water coating is isolated from the external environment, the finished product has excellent performances such as high-temperature stability, corrosion resistance, wear resistance and the like, the durability and chemical property of the coating can be improved, the service life and the application range of the coating are prolonged, and meanwhile, the hardness touch of the enamel coating is more close to that of marble, so that the similarity of the finished product and the marble is improved.

Description

Water-in-water paint with enamel coating and preparation method thereof
Technical Field
The invention relates to the technical field of paint production, in particular to a water-in-water paint with enamel coating and a preparation method thereof.
Background
The academic name of the water-in-water multicolor paint is liquid stone, and the common name is the water-in-water multicolor paint. The paint is produced to meet the current development of building exterior wall paint market, is prepared from modified resin developed by high technology and pigment with good stability, is full-water-based and one-time sprayed colorful granite paint, has more vivid and durable color, and is the best product for replacing exterior wall granite.
The traditional water-in-water paint has the problems of low hardness, easy scratch, no high temperature resistance, easy corrosion and the like, cannot meet the development requirements of the modern manufacturing industry, has poor weather resistance, is subjected to wind blowing, sun drying and rain for a long time, can appear whitened and fall off to influence the attractiveness, and is influenced by the material of the paint, and the paint is similar to marble in appearance, but has far difference from marble in hardness, so that the touch feeling is cheaper.
Disclosure of Invention
Aiming at the defects of the prior art, the invention provides the water-in-water paint with the enamel coating and the preparation method thereof, which solve the problems of low hardness, easy scratching, no high temperature resistance, easy corrosion and poor weather resistance, and simultaneously, the enamel coating is added on the surface of the paint to enable the touch feeling to be more similar to that of marble raw materials.
In order to achieve the above purpose, the invention is realized by the following technical scheme: the water-in-water paint with the enamel coating comprises water-in-water paint and the enamel coating, wherein the enamel coating is arranged on the surface of the water-in-water paint, and the water-in-water paint comprises the following raw materials in parts by mass: 1-5 parts of bentonite, 30-50 parts of a brilliant nest partner, 4-10 parts of propylene glycol, 0.5-2 parts of a bactericide, 5-12 parts of a film forming auxiliary agent, 100-200 parts of 619 emulsion, 1-5 parts of a thickener, 1-3 parts of a 95 multifunctional auxiliary agent, 0.1-1 part of a defoaming agent, 50-100 parts of color stone chips, 300-400 parts of 80-129 mesh snow white, 5-10 parts of 80-120 green ash and 0.5-2 parts of a mildew preventive.
Preferably, the water-in-water paint comprises the following raw materials in parts by mass: 3 parts of bentonite, 40 parts of a brilliant nest partner, 8 parts of propylene glycol, 1.5 parts of a bactericide, 10 parts of a film forming auxiliary agent, 180 parts of 619 emulsion, 3 parts of a thickener, 1.5 parts of a 95 multifunctional auxiliary agent, 0.5 part of a defoaming agent, 71 parts of colored stone chips, 343 parts of 80-129 mesh snowflake white, 7.5 parts of 80-120 green ash and 1 part of a mildew inhibitor.
Preferably, the enamel coating comprises the following raw materials in parts by mass: 1269 parts of emulsion 934.6 parts, 46.7 parts of film forming additive, 18.7 parts of thickener, 5 parts of waterproof agent, 2 parts of anti-discoloration agent and 3 parts of reinforcing agent.
Preferably, the colored stone chips are obtained by crushing and processing stone materials and firing at a high temperature of 2000 ℃.
Preferably, the enamel coating has a surface hardness of more than 3H.
Preferably, the water-in-water paint with the enamel coating is applied to buildings, artware, furniture, automobile manufacturing and ship manufacturing.
Meanwhile, the invention also provides a preparation method of the water-in-water paint with the enamel coating, which comprises the following steps:
firstly, mixing bentonite, a brilliant nest partner, propylene glycol, a bactericide, a film-forming auxiliary agent, 619 emulsion, a thickener, a 95 multifunctional auxiliary agent, a defoaming agent, colored stone chips, 80-129 mesh snow white, 80-120 gray and a mildew preventive in proportion, and stirring and mixing at a high speed to obtain the water-in-water coating;
mixing 1269 emulsion, a film forming auxiliary agent, a thickening agent, a waterproof agent, an anti-discoloration agent and an enhancer in proportion, and stirring and mixing at a high speed to obtain enamel paint;
and thirdly, coating the enamel coating on the surface of the water-in-water coating, and forming an enamel coating after curing, namely forming the water-in-water coating with the enamel coating.
Preferably, the coating method of the enamel paint comprises spraying, spraying and knife coating.
Preferably, the enamel coating is polished after being cured, so that the smoothness is improved.
The invention provides a water-in-water paint with an enamel coating and a preparation method thereof. The beneficial effects are as follows:
according to the invention, the enamel coating is added on the surface of the water-in-water coating, so that the water-in-water coating is isolated from the external environment, so that the finished product has excellent performances such as high-temperature stability, corrosion resistance, wear resistance and the like, the durability and chemical properties of the coating can be improved, and the service life and application range of the coating are prolonged; meanwhile, the hardness touch sense of the enamel coating is closer to that of marble, so that the similarity of a finished product and the marble is improved, the appearance and the touch sense of the enamel coating are similar to those of the marble, and the quality of the product is improved.
According to the invention, the colored stone chips are added into the water-in-water paint, so that the appearance of the water-in-water paint is more similar to that of marble, and the similarity between the water-in-water paint and real stone is improved.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Embodiment one:
the embodiment of the invention provides a water-in-water coating with an enamel coating, which comprises a water-in-water coating and an enamel coating, wherein the enamel coating is arranged on the surface of the water-in-water coating, and the water-in-water coating comprises the following raw materials in parts by mass: 1 part of bentonite, 30 parts of a brilliant nest partner, 4 parts of propylene glycol, 0.5 part of a bactericide, 5 parts of a film forming auxiliary agent, 100 parts of 619 emulsion, 1 part of a thickener, 1 part of a 95 multifunctional auxiliary agent, 0.1 part of a defoaming agent, 50 parts of colored stone chips, 300 parts of 80-129 mesh snowflake white, 5 parts of 80-120 green ash and 0.5 part of a mildew preventive.
By adding the enamel coating on the surface of the water-in-water coating, the water-in-water coating is isolated from the external environment, so that the finished product has excellent performances such as high-temperature stability, corrosion resistance, wear resistance and the like, the durability and chemical properties of the coating can be improved, and the service life and application range of the coating are prolonged; meanwhile, the hardness touch sense of the enamel coating is closer to that of marble, so that the similarity of a finished product and the marble is improved, the appearance and the touch sense of the enamel coating are similar to those of the marble, and the quality of the product is improved.
The enamel coating comprises the following raw materials in parts by mass: 1269 parts of emulsion 934.6 parts, 46.7 parts of film forming additive, 18.7 parts of thickener, 5 parts of waterproof agent, 2 parts of anti-discoloration agent and 3 parts of reinforcing agent.
The composition and thickness of the enamel coating should be adjusted according to the specific application and requirements of the coating to ensure the best performance and application effect.
the color stone chip is obtained by crushing stone and sintering at 2000 deg.C.
The colored stone chips are added into the water-in-water paint, so that the appearance of the water-in-water paint is more similar to that of marble, and the similarity between the water-in-water paint and real stone is improved.
The surface hardness of the enamel coating is more than 3H.
The surface hardness of the marble is between 2.5H and 5H, and the surface hardness of the water-in-water coating is close to the surface hardness of the marble through the coverage of the enamel coating, so that the physical property and the real touch feeling of the marble are improved.
The water-in-water paint with enamel coating is applied to building, artware, furniture, automobile manufacturing and ship manufacturing.
Under the coating of enamel coating, the application of water-in-water paint is more extensive.
Embodiment two:
unlike the above examples, in the examples of the present invention, the water-in-water paint comprises the following raw materials in parts by mass: 5 parts of bentonite, 50 parts of a brilliant nest partner, 10 parts of propylene glycol, 2 parts of a bactericide, 12 parts of a film forming auxiliary agent, 200 parts of 619 emulsion, 5 parts of a thickener, 3 parts of a 95 multifunctional auxiliary agent, 1 part of a defoamer, 100 parts of colored stone chips, 400 parts of 80-129 mesh snowflake white, 10 parts of 80-120 green ash and 2 parts of a mildew preventive.
Embodiment III:
unlike the above examples, in the examples of the present invention, the water-in-water paint comprises the following raw materials in parts by mass: 3 parts of bentonite, 40 parts of a brilliant nest partner, 8 parts of propylene glycol, 1.5 parts of a bactericide, 10 parts of a film forming auxiliary agent, 180 parts of 619 emulsion, 3 parts of a thickener, 1.5 parts of a 95 multifunctional auxiliary agent, 0.5 part of a defoaming agent, 71 parts of colored stone chips, 343 parts of 80-129 mesh snowflake white, 7.5 parts of 80-120 green ash and 1 part of a mildew inhibitor.
Embodiment four:
on the basis of the above embodiment, this embodiment provides a method for preparing a water-in-water paint with enamel coating, which includes the following steps:
firstly, mixing bentonite, a brilliant nest partner, propylene glycol, a bactericide, a film-forming auxiliary agent, 619 emulsion, a thickener, a 95 multifunctional auxiliary agent, a defoaming agent, colored stone chips, 80-129 mesh snow white, 80-120 gray and a mildew preventive in proportion, and stirring and mixing at a high speed to obtain the water-in-water coating;
mixing 1269 emulsion, a film forming auxiliary agent, a thickening agent, a waterproof agent, an anti-discoloration agent and an enhancer in proportion, and stirring and mixing at a high speed to obtain enamel paint;
and thirdly, coating the enamel coating on the surface of the water-in-water coating, and forming an enamel coating after curing, namely forming the water-in-water coating with the enamel coating.
The coating method of the enamel paint comprises spraying, spraying and knife coating.
And after the enamel coating is solidified, the surface of the enamel coating is polished, so that the smoothness is improved.
According to the preparation method in the fourth embodiment, the first, second and third embodiments are prepared according to different raw material ratios, and the first, second and third samples are obtained and compared with the marble-polished samples, respectively, and the three embodiments are different in similarity with the marble-polished samples.
Although embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that various changes, modifications, substitutions and alterations can be made therein without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (9)

1. The water-in-water paint with the enamel coating comprises water-in-water paint and the enamel coating, and is characterized in that the enamel coating is arranged on the surface of the water-in-water paint, and the water-in-water paint comprises the following raw materials in parts by mass: 1-5 parts of bentonite, 30-50 parts of a brilliant nest partner, 4-10 parts of propylene glycol, 0.5-2 parts of a bactericide, 5-12 parts of a film forming auxiliary agent, 100-200 parts of 619 emulsion, 1-5 parts of a thickener, 1-3 parts of a 95 multifunctional auxiliary agent, 0.1-1 part of a defoaming agent, 50-100 parts of color stone chips, 300-400 parts of 80-129 mesh snow white, 5-10 parts of 80-120 green ash and 0.5-2 parts of a mildew preventive.
2. The water-in-water paint with the enamel coating according to claim 1, wherein the water-in-water paint comprises the following raw materials in parts by mass: 3 parts of bentonite, 40 parts of a brilliant nest partner, 8 parts of propylene glycol, 1.5 parts of a bactericide, 10 parts of a film forming auxiliary agent, 180 parts of 619 emulsion, 3 parts of a thickener, 1.5 parts of a 95 multifunctional auxiliary agent, 0.5 part of a defoaming agent, 71 parts of colored stone chips, 343 parts of 80-129 mesh snowflake white, 7.5 parts of 80-120 green ash and 1 part of a mildew inhibitor.
3. A water-in-water paint with enamel coating according to any one of claims 1-2, wherein the enamel coating comprises the following raw materials in parts by mass: 1269 parts of emulsion 934.6 parts, 46.7 parts of film forming additive, 18.7 parts of thickener, 5 parts of waterproof agent, 2 parts of anti-discoloration agent and 3 parts of reinforcing agent.
4. A water-in-water paint with enamel coating according to any one of claims 1-2, wherein the colored stone chips are obtained by stone crushing and firing at 2000 ℃.
5. A water-in-water paint with enamel coating according to claim 1, wherein the enamel coating has a surface hardness of more than 3H.
6. A water-in-water paint with enamel coating according to claim 1, wherein the water-in-water paint with enamel coating is applied to construction, handicraft article, furniture, automobile manufacturing, ship manufacturing.
7. A method for preparing a water-in-water paint with enamel coating, which is characterized by comprising the following steps:
firstly, mixing bentonite, a brilliant nest partner, propylene glycol, a bactericide, a film-forming auxiliary agent, 619 emulsion, a thickener, a 95 multifunctional auxiliary agent, a defoaming agent, colored stone chips, 80-129 mesh snow white, 80-120 gray and a mildew preventive in proportion, and stirring and mixing at a high speed to obtain the water-in-water coating;
mixing 1269 emulsion, a film forming auxiliary agent, a thickening agent, a waterproof agent, an anti-discoloration agent and an enhancer in proportion, and stirring and mixing at a high speed to obtain enamel paint;
and thirdly, coating the enamel coating on the surface of the water-in-water coating, and forming an enamel coating after curing, namely forming the water-in-water coating with the enamel coating.
8. The method for preparing a water-in-water paint with enamel coating according to claim 7, wherein the method for coating enamel coating comprises spraying, thermal spraying and knife coating.
9. The method for preparing a water-in-water paint with enamel coating according to claim 7, wherein the enamel coating is polished to improve the smoothness after being cured.
CN202310519886.XA 2023-05-10 2023-05-10 Water-in-water paint with enamel coating and preparation method thereof Pending CN117004321A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310519886.XA CN117004321A (en) 2023-05-10 2023-05-10 Water-in-water paint with enamel coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202310519886.XA CN117004321A (en) 2023-05-10 2023-05-10 Water-in-water paint with enamel coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN117004321A true CN117004321A (en) 2023-11-07

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1493636A (en) * 2002-06-14 2004-05-05 ��������ķ������ Water based adhesive
WO2017028471A1 (en) * 2015-08-16 2017-02-23 上海大通涂料化工有限公司 Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof
CN110643245A (en) * 2019-10-16 2020-01-03 江苏久诺建材科技股份有限公司 Water-in-water multicolor paint
CN115975451A (en) * 2023-02-10 2023-04-18 山东青巢新型建材有限公司 Color-changeable water-in-water multicolor paint for interior wall and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1493636A (en) * 2002-06-14 2004-05-05 ��������ķ������ Water based adhesive
WO2017028471A1 (en) * 2015-08-16 2017-02-23 上海大通涂料化工有限公司 Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof
CN110643245A (en) * 2019-10-16 2020-01-03 江苏久诺建材科技股份有限公司 Water-in-water multicolor paint
CN115975451A (en) * 2023-02-10 2023-04-18 山东青巢新型建材有限公司 Color-changeable water-in-water multicolor paint for interior wall and preparation method thereof

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