CN116945444A - Preparation process of basalt fiber reinforced PVC composite material - Google Patents

Preparation process of basalt fiber reinforced PVC composite material Download PDF

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Publication number
CN116945444A
CN116945444A CN202310880966.8A CN202310880966A CN116945444A CN 116945444 A CN116945444 A CN 116945444A CN 202310880966 A CN202310880966 A CN 202310880966A CN 116945444 A CN116945444 A CN 116945444A
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CN
China
Prior art keywords
basalt fiber
pressing
fiber reinforced
mold
die
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Application number
CN202310880966.8A
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Chinese (zh)
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CN116945444B (en
Inventor
杜现国
刘雪莹
汪关文
王平
王俊强
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Feicheng Sanhe Engineering Material Co ltd
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Feicheng Sanhe Engineering Material Co ltd
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Priority to CN202310880966.8A priority Critical patent/CN116945444B/en
Priority claimed from CN202310880966.8A external-priority patent/CN116945444B/en
Publication of CN116945444A publication Critical patent/CN116945444A/en
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Publication of CN116945444B publication Critical patent/CN116945444B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/36Moulds for making articles of definite length, i.e. discrete articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2027/00Use of polyvinylhalogenides or derivatives thereof as moulding material
    • B29K2027/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2309/00Use of inorganic materials not provided for in groups B29K2303/00 - B29K2307/00, as reinforcement

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)

Abstract

The preparation process of basalt fiber reinforced PVC composite material adopts a pressed compact sintering process to prepare a basalt fiber reinforced PVC composite material sample, and comprises the following steps: s1, filling basalt fiber materials and PVC powder materials into a die cavity of a pressing die according to a set mixing proportion; s2, introducing working gas into a die cavity of the pressing die through an air inlet channel of the pressing die, and vibrating and mixing basalt fiber materials and PVC powder materials under the blowing of the working gas until the basalt fiber materials and the PVC powder materials are uniformly mixed; and S3, applying pressure to a die cavity of a pressing die through a pressure head, pressing the uniformly mixed basalt fiber material and PVC powder material into a green body, and sintering the green body into a basalt fiber reinforced PVC composite material sample. The process of the invention does not need to adopt special equipment such as a ball mill or a three-dimensional stirrer to carry out long-time mixing operation, realizes rapid and uniform mixing, and does not damage fiber materials.

Description

Preparation process of basalt fiber reinforced PVC composite material
Technical Field
The invention relates to the technical field of basalt fiber reinforced PVC composite materials, in particular to a preparation process of a basalt fiber reinforced PVC composite material.
Background
Before the basalt fiber reinforced PVC composite material sample is manufactured by adopting a hot pressing method, special mixing equipment is required to mix basalt fibers and a PVC matrix, a ball mill or a three-dimensional mixer is most commonly used at present for carrying out the mixing operation, a large amount of alcohol is required to be used as a mixing medium for the mixing operation, and the basalt fibers are more easily damaged when being mechanically ball-milled or stirred for a longer time, so that the whole performance of the manufactured composite material is finally influenced.
Disclosure of Invention
In order to solve the problems of the background technology, the invention provides a preparation process of a basalt fiber reinforced PVC composite material, which realizes quick and uniform mixing and avoids damaging fiber materials in the process of manufacturing a basalt fiber reinforced PVC composite material sample by adopting a hot pressing method.
The technical scheme adopted by the invention is as follows:
the preparation process of basalt fiber reinforced PVC composite material adopts a pressed compact sintering process to prepare a basalt fiber reinforced PVC composite material sample, and comprises the following steps:
s1, charging
Filling basalt fiber materials and PVC powder materials into a die cavity of a pressing die according to a set mixing proportion;
s2, mixing materials
Introducing working gas into a die cavity of the pressing die through an air inlet channel of the pressing die, and vibrating and mixing the basalt fiber material and the PVC powder material under the blowing of the working gas until the basalt fiber material and the PVC powder material are uniformly mixed;
s3, pressing and sintering
And applying pressure to a die cavity of a pressing die through a pressure head, pressing the uniformly mixed basalt fiber material and PVC powder material into a green body, and sintering the green body into a basalt fiber reinforced PVC composite material sample.
According to the preparation process of the basalt fiber reinforced PVC composite material, in the step S3, pressure is applied to the die cavity of the pressing die through the pressure head, and the basalt fiber material and the PVC powder material are heated through the pressing die, so that the basalt fiber reinforced PVC composite material sample is obtained through hot pressing of the basalt fiber material and the PVC powder material.
According to the preparation process of the basalt fiber reinforced PVC composite material, the pressing die comprises the side die, the top die and the bottom die, the side die, the top die and the bottom die enclose the die cavity, the top die is connected with the pressing head and is arranged opposite to the bottom die, and the pressing head can drive the pressing head to move towards the bottom die to press the mixed material in the die cavity.
According to the preparation process of the basalt fiber reinforced PVC composite material, the air inlet channel penetrates through the side die, the air inlet of the air inlet channel is connected with an external air source pipeline, and the air outlet of the air inlet channel is inclined towards the bottom of the die cavity.
According to the preparation process of the basalt fiber reinforced PVC composite material, a plurality of air inlet channels are arranged along the circumferential direction of the side die, and the air inlet channels are uniformly distributed.
According to the preparation process of the basalt fiber reinforced PVC composite material, mild and/or heated high-pressure gas is introduced into the air inlet channel through the air source pipeline.
According to the preparation process of the basalt fiber reinforced PVC composite material, the bottom die is an elastic bottom die, and an elastic component is arranged below the elastic bottom die.
According to the preparation process of the basalt fiber reinforced PVC composite material, in the step S3, after the pressure is applied to the basalt fiber material and the PVC powder material in the die cavity of the pressing die through the pressure head, the air outlet of the air inlet channel is positioned outside the compressed die cavity.
According to the preparation process of the basalt fiber reinforced PVC composite material, the top die is provided with the air holes, and/or is made of an air permeable material.
According to the preparation process of the basalt fiber reinforced PVC composite material, in the step S1, the set mixing proportion is that basalt fiber materials and PVC powder materials are counted by volume=1 (2-40).
The beneficial effects are that:
according to the preparation process of the basalt fiber reinforced PVC composite material, provided by the invention, in the process of manufacturing the basalt fiber reinforced PVC composite material sample by adopting a hot pressing method, long-time mixing operation is not required by adopting special equipment such as a ball mill or a three-dimensional mixer, only working gas is directly introduced into a die cavity of a pressing die, and the basalt fiber material and the PVC powder material can be fully and uniformly vibrated and mixed under the blowing of the working gas by controlling the conditions such as a gas flow path, the temperature and the like, so that the rapid and uniform mixing is realized, and the fiber material is not damaged.
Drawings
Fig. 1 is a process schematic diagram of a preparation process of a basalt fiber reinforced PVC composite material according to an embodiment of the present invention.
Fig. 2 is a second process schematic diagram of a preparation process of a basalt fiber reinforced PVC composite material according to an embodiment of the present invention.
In the figure: a side die 1; a top die 2; a pressure head 3; a bottom die 4; an intake passage 5; an air source pipeline 6; an elastic member 7; and mixing the material 8.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention.
Example 1
Referring to fig. 1 and 2, fig. 1 and 2 are process schematic diagrams of a preparation process of a basalt fiber reinforced PVC composite material according to an embodiment of the present invention.
Specifically, the preparation process of the basalt fiber reinforced PVC composite material adopts a compact sintering process to prepare a basalt fiber reinforced PVC composite material sample, and comprises three steps of S1, loading, S2, mixing, S3 and pressing and sintering.
In step S1, basalt fiber material and PVC powder material are charged into the cavity of the pressing mold at a set mixing ratio, wherein the set mixing ratio is determined according to the sample requirement, and in general, basalt fiber material and PVC powder material may be represented by volume=1 (2 to 40), preferably=1 (10 to 30).
As shown in the figure, the pressing mold in this embodiment is a vertical mold, and includes a side mold 1, a top mold 2 and a bottom mold 4, where the side mold 1, the top mold 2 and the bottom mold 4 enclose a mold cavity, and the top mold 2 is connected with a pressing head 3 and is disposed opposite to the bottom mold 4, and can be driven by the pressing head 3 to move toward the bottom mold 4 to press the mixed material 8 in the mold cavity.
With continued reference to fig. 1 and 2, it can be seen that a plurality of air inlet channels 5 are provided through the side mold 1, preferably such that the plurality of air inlet channels 5 are uniformly distributed along the circumference of the side mold 1, the air inlet of the air inlet channels 5 is connected to an external air source pipe 6, and the air outlet of the air inlet channels 5 is inclined towards the bottom of the mold cavity. With this arrangement, in step S1, the basalt fiber material and the PVC powder material charged into the cavity of the pressing die may not be mixed in advance (or simply premixed) at all, so that the rapid and uniform and effective mixing is performed in the next step S2.
Specifically, in step S2, working gas is introduced into the cavity of the pressing mold through the air inlet channel 5 of the pressing mold, and the basalt fiber material and the PVC powder material are mixed by shaking under the blowing of the working gas until the basalt fiber material and the PVC powder material are uniformly mixed, wherein the working gas is a high-pressure gas at a low temperature and/or a high temperature, preferably a non-reactive gas such as nitrogen or argon, but not excluding optional compressed air, and is introduced into the air inlet channel 5 through the air source pipeline 6.
Considering the situation that the traditional pneumatic mixing mode is easy to generate uneven mixing when preparing the basalt fiber material and PVC powder material, the improved two-step method can be adopted when adopting the scheme of the embodiment to carry out pneumatic mixing of basalt fiber material and PVC powder material, when high-pressure gas is introduced through the air inlet channel 5, the first step is to fully mix basalt fiber material and PVC powder material for a period of time by introducing normal-temperature gas, so that the basalt fiber material and PVC powder material are fully and uniformly mixed in the airflow vibration process, and the second step is to introduce heated high-temperature gas to enable the basalt fiber material and PVC powder material to generate surface infiltration at high temperature, thereby reducing the separation of the basalt fiber material and PVC powder material in the sedimentation process after vibration, controlling the temperature of the high-temperature gas to be more than 120 ℃ and not more than 250 ℃ at most, so that the material just generates surface infiltration without obvious melting of PVC powder material.
The top mold 2 of this embodiment is preferably provided with ventilation holes, and the top mold 2 may be made of ventilation material, so as to ensure smooth mixing and subsequent pressing.
The next step is S3, pressing and sintering, specifically, applying pressure to a die cavity of a pressing die through a pressing head 3, pressing the uniformly mixed basalt fiber material and PVC powder material into a green body, and sintering the green body into a basalt fiber reinforced PVC composite sample.
In step S3, the basalt fiber reinforced PVC composite sample is preferably sintered by hot pressing, that is, the pressing mold itself has a heating function (not shown in the drawing), and when pressure is applied to the cavity of the pressing mold by the pressing head 3, the basalt fiber material and the PVC powder material are heated by the pressing mold, and the basalt fiber material and the PVC powder material are hot pressed into the basalt fiber reinforced PVC composite sample.
As further shown in fig. 1 and 2, the bottom die 4 in this embodiment is an elastic bottom die, and an elastic component 7 is disposed below the elastic bottom die, which is beneficial to playing a role of buffering in the pressurizing process and facilitating the demolding of the sample.
Preferably, in step S3, after the basalt fiber material and the PVC powder material in the cavity of the pressing mold are pressurized by the pressing head 3, the air outlet of the air inlet passage 5 is located outside the compressed cavity due to the movement of the top mold 2 and the bottom mold 4, and this design can reduce the influence of the pressing process on the air inlet passage 5.
Example 2
This example is another possible means proposed for the manner in which the basalt fiber-reinforced PVC composite sample of example 1 is sintered, in example 1, the pressing die itself has a heating function (not shown in the drawing), and when pressure is applied to the cavity of the pressing die by the pressing head 3, the basalt fiber material and the PVC powder material are also heated by the pressing die, and the basalt fiber material and the PVC powder material are hot-pressed into the basalt fiber-reinforced PVC composite sample.
The difference in this embodiment is that in the "press sintering" of step S3, the pressing mold itself is not used as a sintering mold any more, after the uniformly mixed basalt fiber material and PVC powder material are pressed into a green body by the pressing head 3, the green body is demolded from the pressing mold, and then the demolded green body is sintered into a basalt fiber reinforced PVC composite sample in another sintering apparatus (hot press furnace, vacuum sintering furnace, atmosphere sintering furnace, isostatic pressing sintering furnace, etc.).
The preparation process of the basalt fiber reinforced PVC composite material provided by the embodiment does not need to adopt special equipment such as a ball mill or a three-dimensional stirrer to carry out long-time mixing operation in the process of manufacturing the basalt fiber reinforced PVC composite material sample by adopting a hot pressing method, only needs to directly introduce working gas into a die cavity of a pressing die, can fully vibrate and uniformly mix the basalt fiber material and the PVC powder material under the blowing of the working gas by controlling the conditions such as a gas flow path, the temperature and the like, realizes quick and uniform mixing, does not damage the fiber material, and therefore has outstanding contribution in the aspect of efficiently preparing the basalt fiber reinforced PVC composite material or even similar composite material.
In the foregoing, only the preferred embodiments of the present invention are described, and any person skilled in the art should, within the scope of the present disclosure, be able to substitute or change the technical solution according to the present invention and the inventive concept thereof, and should be covered by the protection scope of the present invention.

Claims (10)

1. The preparation process of the basalt fiber reinforced PVC composite material adopts a compact sintering process to prepare a basalt fiber reinforced PVC composite material sample, and is characterized by comprising the following steps:
s1, charging
Filling basalt fiber materials and PVC powder materials into a die cavity of a pressing die according to a set mixing proportion;
s2, mixing materials
Working gas is introduced into a die cavity of the pressing die through an air inlet channel (5) of the pressing die, and basalt fiber materials and PVC powder materials are mixed in an oscillating way under the blowing of the working gas until the basalt fiber materials and the PVC powder materials are uniformly mixed;
s3, pressing and sintering
And applying pressure to a die cavity of a pressing die through a pressure head (3), pressing the uniformly mixed basalt fiber material and PVC powder material into a green body, and sintering the green body into a basalt fiber reinforced PVC composite material sample.
2. The process for preparing the basalt fiber reinforced PVC composite according to claim 1, wherein in the step S3, a pressure is applied to the cavity of the pressing mold by the pressing head (3), and the basalt fiber material and the PVC powder material are heated by the pressing mold, so that the basalt fiber material and the PVC powder material are hot-pressed into the basalt fiber reinforced PVC composite sample.
3. The process for preparing the basalt fiber reinforced PVC composite material according to claim 1, wherein the pressing mold comprises a side mold (1), a top mold (2) and a bottom mold (4), wherein the side mold (1), the top mold (2) and the bottom mold (4) enclose the mold cavity, the top mold (2) is connected with the pressing head (3) and is arranged opposite to the bottom mold (4), and the pressing head (3) can drive the pressing head to move towards the bottom mold (4) so as to press the mixed material (8) in the mold cavity.
4. A process for the preparation of a basalt fiber reinforced PVC composite according to claim 3, wherein the air inlet channel (5) is provided through the side mould (1) with its air inlet connected to an external air source duct (6) and its air outlet inclined towards the bottom of the mould cavity.
5. The process for preparing the basalt fiber reinforced PVC composite material according to claim 4, wherein a plurality of air inlet channels (5) are circumferentially arranged along the side mold (1), and the plurality of air inlet channels (5) are uniformly distributed.
6. A process for the preparation of a basalt fiber reinforced PVC composite according to claim 4, wherein a high pressure gas, which is at a temperature and/or heat, is introduced into the inlet channel (5) through the gas source conduit (6).
7. The process for preparing the basalt fiber reinforced PVC composite material according to claim 4, wherein the bottom die (4) is an elastic bottom die, and an elastic component (7) is arranged below the elastic bottom die.
8. The process for preparing the basalt fiber reinforced PVC composite material according to claim 4, wherein in the step S3, after the pressure is applied to the basalt fiber material and the PVC powder material in the cavity of the pressing mold by the pressure head (3), the air outlet of the air inlet channel (5) is positioned outside the compressed cavity.
9. A process for the preparation of a basalt fiber reinforced PVC composite according to claim 3, wherein the top mould (2) is provided with ventilation holes and/or wherein the top mould (2) is made of a ventilation material.
10. The process for preparing a basalt fiber reinforced PVC composite according to claim 9, wherein in step S1, the set mixing ratio is (2-40) of basalt fiber material and PVC powder material=1 by volume.
CN202310880966.8A 2023-07-18 Preparation process of basalt fiber reinforced PVC composite material Active CN116945444B (en)

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Application Number Priority Date Filing Date Title
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CN116945444B CN116945444B (en) 2024-05-31

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Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH081799A (en) * 1994-06-24 1996-01-09 Sumitomo Chem Co Ltd Production of fiber reinforced resin molding
CN1258598A (en) * 1998-12-28 2000-07-05 帝人株式会社 Method and apparatus for moulding fibre mixture
US20040145092A1 (en) * 2003-01-24 2004-07-29 Mccollum Robert P. Method of making a composite molded article
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WO2009121615A2 (en) * 2008-04-04 2009-10-08 Otto Bock Schaumsysteme Gmbh Method for producing a molded part and molding tool therefor
CN101906250A (en) * 2010-08-13 2010-12-08 东南大学 Basalt fiber reinforced wood-plastic composite material and preparation method thereof
EP2529916A1 (en) * 2011-06-01 2012-12-05 Greiner Perfoam GmbH Method for manufacturing a laminated moulded part
CN103802324A (en) * 2014-02-22 2014-05-21 许剑海 Composite material containing tool and manufacturing process thereof
CN104175569A (en) * 2014-07-21 2014-12-03 青岛顺益新材料科技有限公司 Method for manufacturing fiber reinforced thermoplastic composite materials
WO2015159050A2 (en) * 2014-04-17 2015-10-22 Far-Uk Ltd Manufacture of fibre-reinforced composite
CN106883534A (en) * 2017-04-07 2017-06-23 冷纯廷 The enhanced PVC board of fibre modification and its production technology
KR20170101143A (en) * 2016-02-26 2017-09-05 (주)네오유엠시 Menufacturing method for molded article using fiber reinforcerd plastic waste
CN108501280A (en) * 2018-05-09 2018-09-07 成都润信实业有限公司 A kind of high-precision Sheet Metal Forming Technology of basalt case lid
CN111662545A (en) * 2020-07-09 2020-09-15 四川拜赛特高新科技有限公司 Long basalt fiber reinforced thermoplastic resin composite master batch, and preparation method and application thereof
CN114603881A (en) * 2022-03-16 2022-06-10 广州科莱瑞迪医疗器材股份有限公司 Die pressing equipment and processing method for composite material

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH081799A (en) * 1994-06-24 1996-01-09 Sumitomo Chem Co Ltd Production of fiber reinforced resin molding
CN1258598A (en) * 1998-12-28 2000-07-05 帝人株式会社 Method and apparatus for moulding fibre mixture
US20040145092A1 (en) * 2003-01-24 2004-07-29 Mccollum Robert P. Method of making a composite molded article
DE102004014423A1 (en) * 2004-03-19 2005-10-06 Faurecia Innenraum Systeme Gmbh Vehicle airbag cover and interior cladding component manufacture involves heating and molding fiber carrier layer together with sheet of thermoplastic binder and more heat stable material
WO2009121615A2 (en) * 2008-04-04 2009-10-08 Otto Bock Schaumsysteme Gmbh Method for producing a molded part and molding tool therefor
CN101906250A (en) * 2010-08-13 2010-12-08 东南大学 Basalt fiber reinforced wood-plastic composite material and preparation method thereof
EP2529916A1 (en) * 2011-06-01 2012-12-05 Greiner Perfoam GmbH Method for manufacturing a laminated moulded part
CN103802324A (en) * 2014-02-22 2014-05-21 许剑海 Composite material containing tool and manufacturing process thereof
WO2015159050A2 (en) * 2014-04-17 2015-10-22 Far-Uk Ltd Manufacture of fibre-reinforced composite
CN104175569A (en) * 2014-07-21 2014-12-03 青岛顺益新材料科技有限公司 Method for manufacturing fiber reinforced thermoplastic composite materials
KR20170101143A (en) * 2016-02-26 2017-09-05 (주)네오유엠시 Menufacturing method for molded article using fiber reinforcerd plastic waste
CN106883534A (en) * 2017-04-07 2017-06-23 冷纯廷 The enhanced PVC board of fibre modification and its production technology
CN108501280A (en) * 2018-05-09 2018-09-07 成都润信实业有限公司 A kind of high-precision Sheet Metal Forming Technology of basalt case lid
CN111662545A (en) * 2020-07-09 2020-09-15 四川拜赛特高新科技有限公司 Long basalt fiber reinforced thermoplastic resin composite master batch, and preparation method and application thereof
CN114603881A (en) * 2022-03-16 2022-06-10 广州科莱瑞迪医疗器材股份有限公司 Die pressing equipment and processing method for composite material

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