CN116495994A - Production process method of ultrathin electronic grade glass fiber cloth - Google Patents

Production process method of ultrathin electronic grade glass fiber cloth Download PDF

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Publication number
CN116495994A
CN116495994A CN202310397852.8A CN202310397852A CN116495994A CN 116495994 A CN116495994 A CN 116495994A CN 202310397852 A CN202310397852 A CN 202310397852A CN 116495994 A CN116495994 A CN 116495994A
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China
Prior art keywords
glass
glass fiber
fiber cloth
electronic grade
cleaning
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Pending
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CN202310397852.8A
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Chinese (zh)
Inventor
陈昞宬
刘振
王勤粟
唐艳
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Jiangsu Shenghong Electrical Equipment Co ltd
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Jiangsu Shenghong Electrical Equipment Co ltd
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Priority to CN202310397852.8A priority Critical patent/CN116495994A/en
Publication of CN116495994A publication Critical patent/CN116495994A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/02Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C03B37/022Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/02Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C03B37/03Drawing means, e.g. drawing drums ; Traction or tensioning devices
    • C03B37/035Drawing means, e.g. drawing drums ; Traction or tensioning devices having means for deflecting or stripping-off fibres or for removing defective parts
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/10Non-chemical treatment

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Glass Compositions (AREA)

Abstract

The invention relates to the technical field of glass fiber cloth, and discloses a production process method of ultrathin electronic grade glass fiber cloth, which comprises the following steps: s1, cleaning raw materials; s2, sun drying; s3, igniting and heating; s4, adding and mixing auxiliary materials: adding the reinforcing agent and the plant fiber pulp into the crucible, and continuously stirring through a stirring rod when the reinforcing agent and the plant fiber pulp are added, so that the reinforcing agent, the plant fiber pulp and the melted glass are fully mixed; s5, drawing, spinning, softening and feeding; s6, packaging and warehousing. According to the invention, the raw materials can be efficiently cleaned when the raw materials are selected and cleaned, so that the quality of the subsequent glass fiber cloth production is ensured, and the reinforcing agent and the plant fiber pulp are added in the production process, so that the glass fiber cloth has higher strength and is not easy to break, and meanwhile, the glass fiber cloth is subjected to corrosion prevention treatment after the production, so that the corrosion prevention performance of the glass fiber cloth can be improved, and the service life of the glass fiber cloth is prolonged.

Description

Production process method of ultrathin electronic grade glass fiber cloth
Technical Field
The invention relates to the technical field of glass fiber cloth, in particular to a production process method of ultrathin electronic grade glass fiber cloth.
Background
The glass fiber cloth is an inorganic nonmetallic material with excellent performance, has various kinds, and has the advantages of good insulativity, strong heat resistance, good corrosion resistance and high mechanical strength, but has the disadvantages of catalysis and poor wear resistance, and is mainly formed by adopting recycled waste glass as a raw material for secondary processing, so the cost is low.
The glass fiber cloth is a material with very wide application, is suitable for wall reinforcement and external wall heat preservation, and is a common building material.
The Chinese patent discloses a production process method (grant publication No. CN 109281039B) of ultrathin electronic-grade glass fiber cloth, and the tension of a warp beam is uniformly controlled in the whole sizing process of the patent technology, so that the tension of the cloth cover is uniform; the weaving process is reasonable, the weaving process is thinner than that of a commercial product by 0.022mm, the basis weight is 20.8g/m < 2 >, and the prepared electronic glass fiber cloth has high tearing strength; the cloth cover is flat and ultrathin.
However, this patent realizes tension control by sizing and desizing and treating with a silane coupling agent, but this patent fails to increase the strength of the glass fiber cloth, and is likely to break during use, resulting in damage and failure. Therefore, a person skilled in the art provides a production process method of an ultrathin electronic grade glass fiber cloth to solve the problems in the background art.
Disclosure of Invention
The invention aims to provide a production process method of ultrathin electronic grade glass fiber cloth, which aims to solve the problems in the background technology.
In order to achieve the above purpose, the present invention provides the following technical solutions:
the production process of the ultrathin electronic grade glass fiber cloth comprises the following steps:
s1, cleaning raw materials: firstly, selecting waste glass as a raw material, and placing the selected waste glass into a water tank for cleaning, wherein a stirrer is required to be used for stirring and cleaning in the cleaning process;
s2, sun-drying: taking out the cleaned waste glass from the water tank, and placing the waste glass under the sun for insolation;
s3, igniting and heating: putting the sun-dried glass into a crucible, heating the crucible to melt the glass, and enabling the temperature of the melted glass to reach 1100-1300 ℃;
s4, adding and mixing auxiliary materials: adding 30-50% of reinforcing agent and plant fiber pulp into a crucible, and continuously stirring by a stirring rod when adding, so that the reinforcing agent is fully mixed with the plant fiber pulp and melted glass;
s5, wire drawing, softening and wire feeding: the mixed liquid flows out from the bottom of the eye of the crucible, and is drawn and spun, after spinning, a softening agent needs to be sprayed on the surface of the liquid, and a filament body sprayed with the softening agent is wound on a roller for filament winding treatment;
s6, packaging and warehousing: and packaging and warehousing the filament body subjected to the filament winding post-treatment, thereby finishing.
As still further aspects of the invention: the sheet diameter of the waste glass selected in the step S1 is more than 3cm, and the waste glass does not comprise high-temperature, mercury, organic and brown glass.
As still further aspects of the invention: in the step S1, the cleaning is carried out once, and then the cleaned water is taken out and put into another clean water tank for cleaning again, and 4% of caustic soda is added into the other clean water tank.
As still further aspects of the invention: in the step S2, after the cleaned glass is taken out, the cleaned glass is clamped by a fixing clamp, the glass is placed towards the sun, and dust prevention treatment is carried out through a dust screen.
As still further aspects of the invention: in the step S3, the blast lamp needs to be preheated in advance when the glass is placed in the crucible, and a igniting rod needs to be used when the glass is melted.
As still further aspects of the invention: the reinforcing agent in the step S4 is any one or more of cationic polyacrylamide, butyl acrylate polymer and polyvinyl acetate.
As still further aspects of the invention: in the step S5, the wire needs to be pulled from outside to inside during wire drawing, so that the wire is not easy to break.
As still further aspects of the invention: the produced glass fiber yarns are soaked into the anti-corrosion solution in the step S5, the soaking time is 20min, and the glass fiber yarns are dried after being soaked.
As still further aspects of the invention: the preservative solution comprises the following solutions: 10-30% of formalin, 5-10% of carbolic acid, 20-30% of alcohol, 10-30% of glycerol and 60-70% of water.
As still further aspects of the invention: the packaging process in S6 needs to be registered, and the registration process is performed after the registration process, so as to facilitate subsequent searching.
Compared with the prior art, the invention has the beneficial effects that: according to the invention, the raw materials can be efficiently cleaned when the raw materials are selected and cleaned, so that the production quality of the subsequent glass fiber cloth is ensured, and the reinforcing agent and the plant fiber pulp are added in the production process, so that the produced glass fiber cloth has higher strength and is not easy to break, and meanwhile, the glass fiber cloth is subjected to corrosion prevention treatment after production, so that the corrosion prevention performance of the glass fiber cloth is improved, and the service life of the glass fiber cloth is prolonged.
Detailed Description
The technical solutions of the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is apparent that the described embodiments are only some embodiments of the present invention, not all embodiments. All other embodiments, which can be made by those skilled in the art based on the embodiments of the invention without making any inventive effort, are intended to be within the scope of the invention.
Example 1
The production process of the ultrathin electronic grade glass fiber cloth comprises the following steps:
s1, cleaning raw materials: firstly, selecting waste glass as a raw material, and placing the selected waste glass into a water tank for cleaning, wherein a stirrer is required to be used for stirring and cleaning in the cleaning process;
s1, the sheet diameter of the waste glass selected in the step S1 is more than 3cm, and the waste glass does not comprise high-temperature, mercury, organic and brown glass; in the step S1, the cleaning is carried out once, and then the cleaning is carried out in another clean water tank, and 4% caustic soda is added into the other clean water tank.
S2, sun-drying: taking out the cleaned waste glass from the water tank, and placing the waste glass under the sun for insolation;
s2, after the cleaned glass is taken out, the cleaned glass is clamped by a fixing clamp, the glass is placed towards the sun, and dust prevention treatment is carried out through a dust screen.
S3, igniting and heating: putting the sun-dried glass into a crucible, heating the crucible to melt the glass, and enabling the temperature of the melted glass to reach 1100-1300 ℃;
in S3, preheating a blast lamp in advance is needed when the glass is placed into the crucible, and a igniting rod is needed when the glass is melted.
S4, adding and mixing auxiliary materials: adding 30% of reinforcing agent and plant fiber pulp into a crucible, and continuously stirring by a stirring rod during the addition, so that the reinforcing agent is fully mixed with the plant fiber pulp and melted glass;
and S4, the reinforcing agent is any one or more of cationic polyacrylamide, butyl acrylate polymer and polyvinyl acetate.
S5, wire drawing, softening and wire feeding: the mixed liquid flows out from the bottom of the eye of the crucible, and is drawn and spun, after spinning, a softening agent needs to be sprayed on the surface of the liquid, and a filament body sprayed with the softening agent is wound on a roller for filament winding treatment;
s5, the wire is required to be pulled from outside to inside during wire drawing, so that the wire is not easy to break; in S5, the produced glass fiber yarns are soaked into the anti-corrosion solution for 20min, and are dried after being soaked; the preservative solution comprises the following solutions: 10% of formalin, 5% of carbolic acid, 20% of alcohol, 10% of glycerol and 60% of water.
S6, packaging and warehousing: packaging and warehousing the filament body subjected to filament winding post-treatment, thereby finishing;
it needs to be registered after packaging in S6 and recorded after registration for subsequent searching.
Example two
The production process of the ultrathin electronic grade glass fiber cloth comprises the following steps:
s1, cleaning raw materials: firstly, selecting waste glass as a raw material, and placing the selected waste glass into a water tank for cleaning, wherein a stirrer is required to be used for stirring and cleaning in the cleaning process;
s1, the sheet diameter of the waste glass selected in the step S1 is more than 3cm, and the waste glass does not comprise high-temperature, mercury, organic and brown glass; in the step S1, the cleaning is carried out once, and then the cleaning is carried out in another clean water tank, and 4% caustic soda is added into the other clean water tank.
S2, sun-drying: taking out the cleaned waste glass from the water tank, and placing the waste glass under the sun for insolation;
s2, after the cleaned glass is taken out, the cleaned glass is clamped by a fixing clamp, the glass is placed towards the sun, and dust prevention treatment is carried out through a dust screen.
S3, igniting and heating: putting the sun-dried glass into a crucible, heating the crucible to melt the glass, and enabling the temperature of the melted glass to reach 1100-1300 ℃;
in S3, preheating a blast lamp in advance is needed when the glass is placed into the crucible, and a igniting rod is needed when the glass is melted.
S4, adding and mixing auxiliary materials: adding 40% of reinforcing agent and plant fiber pulp into a crucible, and continuously stirring by a stirring rod when adding, so that the reinforcing agent is fully mixed with the plant fiber pulp and melted glass;
and S4, the reinforcing agent is any one or more of cationic polyacrylamide, butyl acrylate polymer and polyvinyl acetate.
S5, wire drawing, softening and wire feeding: the mixed liquid flows out from the bottom of the eye of the crucible, and is drawn and spun, after spinning, a softening agent needs to be sprayed on the surface of the liquid, and a filament body sprayed with the softening agent is wound on a roller for filament winding treatment;
s5, the wire is required to be pulled from outside to inside during wire drawing, so that the wire is not easy to break; in S5, the produced glass fiber yarns are soaked into the anti-corrosion solution for 20min, and are dried after being soaked; the preservative solution comprises the following solutions: formalin 20%, carbolic acid 7%, alcohol 25%, glycerin 20% and water 65%.
S6, packaging and warehousing: packaging and warehousing the filament body subjected to filament winding post-treatment, thereby finishing;
it needs to be registered after packaging in S6 and recorded after registration for subsequent searching.
Example III
The production process of the ultrathin electronic grade glass fiber cloth comprises the following steps:
s1, cleaning raw materials: firstly, selecting waste glass as a raw material, and placing the selected waste glass into a water tank for cleaning, wherein a stirrer is required to be used for stirring and cleaning in the cleaning process;
s1, the sheet diameter of the waste glass selected in the step S1 is more than 3cm, and the waste glass does not comprise high-temperature, mercury, organic and brown glass; in the step S1, the cleaning is carried out once, and then the cleaning is carried out in another clean water tank, and 4% caustic soda is added into the other clean water tank.
S2, sun-drying: taking out the cleaned waste glass from the water tank, and placing the waste glass under the sun for insolation;
s2, after the cleaned glass is taken out, the cleaned glass is clamped by a fixing clamp, the glass is placed towards the sun, and dust prevention treatment is carried out through a dust screen.
S3, igniting and heating: putting the sun-dried glass into a crucible, heating the crucible to melt the glass, and enabling the temperature of the melted glass to reach 1100-1300 ℃;
in S3, preheating a blast lamp in advance is needed when the glass is placed into the crucible, and a igniting rod is needed when the glass is melted.
S4, adding and mixing auxiliary materials: adding 50% of reinforcing agent and plant fiber pulp into a crucible, and continuously stirring by a stirring rod when adding, so that the reinforcing agent is fully mixed with the plant fiber pulp and melted glass;
and S4, the reinforcing agent is any one or more of cationic polyacrylamide, butyl acrylate polymer and polyvinyl acetate.
S5, wire drawing, softening and wire feeding: the mixed liquid flows out from the bottom of the eye of the crucible, and is drawn and spun, after spinning, a softening agent needs to be sprayed on the surface of the liquid, and a filament body sprayed with the softening agent is wound on a roller for filament winding treatment;
s5, the wire is required to be pulled from outside to inside during wire drawing, so that the wire is not easy to break; in S5, the produced glass fiber yarns are soaked into the anti-corrosion solution for 20min, and are dried after being soaked; the preservative solution comprises the following solutions: 30% of formalin, 10% of carbolic acid, 30% of alcohol, 30% of glycerol and 70% of water.
S6, packaging and warehousing: packaging and warehousing the filament body subjected to filament winding post-treatment, thereby finishing;
it needs to be registered after packaging in S6 and recorded after registration for subsequent searching.
The glass fiber cloths prepared in example one, example two and example three were subjected to strength and corrosion resistance tests, and the results are shown in table 1:
TABLE 1
Project Example 1 Example two Example III
Radial strength 135N/25mm 138N/25mm 137N/25mm
Weft strength 60N/25mm 63N/25mm 62N/25mm
Corrosion resistance No obvious corrosion phenomenon No obvious corrosion phenomenon No obvious corrosion phenomenon
As can be seen from Table 1, the reinforcing agent and the plant fiber slurry are added during the production process, so that the strength of the produced glass fiber cloth is higher, breakage is not easy to occur, and meanwhile, the glass fiber cloth is subjected to corrosion prevention treatment after production, so that the corrosion resistance of the glass fiber cloth can be improved, and the service life of the glass fiber cloth is prolonged.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present disclosure describes embodiments, not every embodiment is provided with a separate embodiment, and that this description is provided for clarity only, and that the disclosure is not limited to the embodiments described in detail below, and that the embodiments described in the examples may be combined as appropriate to form other embodiments that will be apparent to those skilled in the art.

Claims (10)

1. The production process method of the ultrathin electronic grade glass fiber cloth is characterized by comprising the following steps of:
s1, cleaning raw materials: firstly, selecting waste glass as a raw material, and placing the selected waste glass into a water tank for cleaning, wherein a stirrer is required to be used for stirring and cleaning in the cleaning process;
s2, sun-drying: taking out the cleaned waste glass from the water tank, and placing the waste glass under the sun for insolation;
s3, igniting and heating: putting the sun-dried glass into a crucible, heating the crucible to melt the glass, and enabling the temperature of the melted glass to reach 1100-1300 ℃;
s4, adding and mixing auxiliary materials: adding 30-50% of reinforcing agent and plant fiber pulp into a crucible, and continuously stirring by a stirring rod when adding, so that the reinforcing agent is fully mixed with the plant fiber pulp and melted glass;
s5, wire drawing, softening and wire feeding: the mixed liquid flows out from the bottom of the eye of the crucible, and is drawn and spun, after spinning, a softening agent needs to be sprayed on the surface of the liquid, and a filament body sprayed with the softening agent is wound on a roller for filament winding treatment;
s6, packaging and warehousing: and packaging and warehousing the filament body subjected to the filament winding post-treatment, thereby finishing.
2. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the sheet diameter of the waste glass selected in S1 is more than 3cm, and the waste glass does not comprise high-temperature, mercury, organic and brown glass.
3. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the step S1 is to take out the cloth after one time of cleaning, put the cloth into another clean water tank for cleaning again, and add 4% caustic soda into the other clean water tank.
4. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein in S2, after the cleaned glass is taken out, the cleaned glass is clamped by a fixing clamp, the glass is placed facing the sun, and dust-proof treatment is performed by a dust-proof net.
5. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein in S3, preheating of the burner is required in advance when the glass is put into the crucible, and a firing rod is required when the glass is melted.
6. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the reinforcing agent in S4 is any one or more of cationic polyacrylamide, butyl acrylate polymer and polyvinyl acetate.
7. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the step S5 is performed by drawing from outside to inside, so that the filaments are not easily broken.
8. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the step S5 is to soak the produced glass fiber yarn into an antiseptic solution for 20min, and then dry the glass fiber yarn after soaking.
9. The process for producing ultra-thin electronic grade fiberglass cloth of claim 8, wherein the anti-corrosive solution comprises the following solutions: 10-30% of formalin, 5-10% of carbolic acid, 20-30% of alcohol, 10-30% of glycerol and 60-70% of water.
10. The process for producing ultra-thin electronic grade glass fiber cloth according to claim 1, wherein the packaging in S6 requires registration and recording after registration for subsequent searching.
CN202310397852.8A 2023-04-14 2023-04-14 Production process method of ultrathin electronic grade glass fiber cloth Pending CN116495994A (en)

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CN202310397852.8A CN116495994A (en) 2023-04-14 2023-04-14 Production process method of ultrathin electronic grade glass fiber cloth

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Application Number Priority Date Filing Date Title
CN202310397852.8A CN116495994A (en) 2023-04-14 2023-04-14 Production process method of ultrathin electronic grade glass fiber cloth

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104628249A (en) * 2014-12-19 2015-05-20 江门市江海区金达玻璃文化有限公司 Glass fiber molding technique
CN108244093A (en) * 2018-04-10 2018-07-06 大连理工大学 A kind of insect specimen color preserving agent, preparation method and color-retention method
CN112390542A (en) * 2020-04-20 2021-02-23 河南光远新材料股份有限公司 Glass fiber antistatic impregnating compound and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104628249A (en) * 2014-12-19 2015-05-20 江门市江海区金达玻璃文化有限公司 Glass fiber molding technique
CN108244093A (en) * 2018-04-10 2018-07-06 大连理工大学 A kind of insect specimen color preserving agent, preparation method and color-retention method
CN112390542A (en) * 2020-04-20 2021-02-23 河南光远新材料股份有限公司 Glass fiber antistatic impregnating compound and preparation method thereof

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