CN1164694C - Composite compounding agent for amphiphilic active pigment - Google Patents

Composite compounding agent for amphiphilic active pigment Download PDF

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Publication number
CN1164694C
CN1164694C CNB02114799XA CN02114799A CN1164694C CN 1164694 C CN1164694 C CN 1164694C CN B02114799X A CNB02114799X A CN B02114799XA CN 02114799 A CN02114799 A CN 02114799A CN 1164694 C CN1164694 C CN 1164694C
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CN
China
Prior art keywords
pigment
compounding agent
composite compounding
amphiphilic
active pigment
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Expired - Fee Related
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CNB02114799XA
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Chinese (zh)
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CN1362455A (en
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吴雯菲
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Individual
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Individual
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Priority to CNB02114799XA priority Critical patent/CN1164694C/en
Publication of CN1362455A publication Critical patent/CN1362455A/en
Priority to PCT/CN2003/000097 priority patent/WO2003064542A1/en
Application granted granted Critical
Publication of CN1164694C publication Critical patent/CN1164694C/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/06—Artists' paints

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention discloses a composite compounding agent for an amphiphilic active pigment. The composite compounding agent is prepared from the following components: 5.5 to 9 wt% of non-ionic surfactant, 8.5 to 12 wt% of ionic surfactant, 3 to 5 wt% of propanediol, 2 to 6 wt% of glycerol, 13 to 20 wt% of sodium alginate, 1 to 2 wt% of fatty acid sodium, 3.5 to 6 wt% of antioxidant, 2 to 4 wt% of defoaming agent, 2 to 4 wt% of polyvinyl alcohol, 2 to 7 wt% of preservative, 2 to 6 wt% of active CaCO3 and 28 to 35 wt% of alkali solution whose mass percentage concentration is 10%. When the composite compounding agent for an amphiphilic active pigment of the present invention is used, an amphiphilic active pigment has amphiphilic regulating performance; the composite compounding agent for an amphiphilic active pigment can be correspondingly mixed with various kinds of pigment powder, cosolvents and auxiliary agents to be prepared into Chinese painting pigments, watercolor painting pigments, gouache pigments, oil painting pigments, etc.

Description

Composite compounding agent for amphiphilic active pigment
Technical field
The present invention relates to a kind of pigment ingredients.
Background technology
Traditional Chinese painting pigment, majority are natural mineral matter pigment, though its essential quality problem is little, its physique wetting ability is relatively poor, thereby use and to have precipitation often, need multiple times of filtration, divide the color that dyes just can be beautiful.So both time-consuming, waste pigment again.And China's pipe dress pigment mass is relatively poor, be very easy to dry and hard, the other powder is adorned Chinese pigment, normally used glue, its colloid film-forming properties is unsatisfactory, makes Chinese painting colour be difficult to reach the luminance brightness of watercolor, pigment, propylene, oil colour all the time, if brightness is improved, and the hydrophilic power that changes its physique, the just necessary dispersiveness that changes its film-formation result and pigment particles.
Many artists attempted sneaking into gouache color, watercolors, acrylic paints with Chinese painting, but found that their intermiscibilities are bad, and promptly affinity is poor, when utilization, did not reach the pigment effect of anticipation.
If with Chinese painting colour and watercolors mixing oil paint, find that promptly pigment is separation phenomenon, poor because of lipophilicity, so they are immiscible, thereby need a kind of amphiphatic blender to remove to change state of interface, regulate the oil loving feature of particle surface.
Summary of the invention
The invention provides a kind of pigment ingredients that can be used for the combination of various oiliness, water-based paint powder, solvent.
Composite compounding agent for amphiphilic active pigment of the present invention is made up of following component in percentage by weight: nonionogenic tenside 5.5-9%, ionic surface active agent 8.5-12%, propylene glycol 3-5%, glycerine 2-6%, sodium alginate 13-20%, sodium soap 1-2%, antioxidant 3.5-6%, defoamer 2-4%, polyvinyl alcohol 2-4%, sanitas 2-7%, active CaCO 32-6%, mass percent concentration are 10% alkaline solution 28-35%.
In order to make pigment have insect protected and deodorization functions, in above-mentioned ingredients, add the fennel volatile oil of 1-3%.
Adopt composite compounding agent for amphiphilic active pigment of the present invention, not only have parents and concoct performance, can be used for various pigment powder, solubility promoter, auxiliary agent, corresponding cooperation, make Chinese painting colour, watercolors, gouache color, oil colour etc.
Embodiment
Embodiment 1
Composite compounding agent for amphiphilic active pigment, form by following components in weight percentage: alkylphenol polyoxyethylene 7.5%, alpha-sulfo fatty acid methyl ester sodium salt (MES) 10.5%, propylene glycol 4.5%, glycerine 5%, sodium alginate 16%, sodium soap 1.5%, 2,6 di tert butyl 4 methyl phenol (BHT) 4.5%, organosilicon breast body 3.5%, polyvinyl alcohol 3%, sanitas 5%, active CaCO 32%, mass percent concentration is 10% NaOH solution 35%, fennel volatile oil 2%.
In mentioned component, alkylphenol polyoxyethylene is a nonionogenic tenside, and it makes pigment-dispersing good; The molecular structural formula of alpha-sulfo fatty acid methyl ester sodium salt (MES) is as follows:
It is one to contain the ionogenic surfactant of hydrophilic radical and lipophilic group, make two kinds of different pigment obtain uniform dispersion system, improve chroma-luminance, for example Chinese pigments system wetting ability is bad, sediment is big, or Chinese painting color allots now with other immiscible pigment and separates, and solves with regard to available MES.Propylene glycol is as wetting Agent for Printing Inks; Glycerine is as anti-skinning; Sodium alginate improves viscosity and makes the film softness as softening agent, promotes the adhesive attraction of pigment to attachment, increases the toughness of film; Sodium soap can improve the binding surface affinity, prevents to wear out; Organosilicon breast body has the froth breaking effect; 2,6 di tert butyl 4 methyl phenol (BHT) is an antioxidant, prevents mummification, delays oxypolymerization; Polyvinyl alcohol is reinforced paper, prevents that color from fading, and strengthens the ageing resistance of paintings; NaOH solution is as the PH alkalescence of regulating solvent; Fennel volatile oil makes pigment have insect protected, deodorization functions; Sanitas is methyl esters, propyl ester, NaN 3Mixed and got in 3: 1: 1 by weight percentage.
Described above-mentioned ingredients of present embodiment and various pigment are used, and make pigment have advantages such as parents' performance.It mixes with the weight proportion of Chinese painting colour powder with 1.1: 5, can allot the traditional Chinese painting pigment hydrophilic, that lipophilicity is good.
Embodiment 2
The composite compounding agent for amphiphilic active pigment of embodiment 1 gained is hereinafter to be referred as the A agent;
Weight percent is 72% active CaCO 3, 23% ZnO and 5% fennel powder mixture be designated hereinafter simply as the B agent;
With above-mentioned A agent, B agent and organic or inorganic pigment powder by weight mix at 1.1: 1: 5 watercolors and by 1.1: 3.5: 5 blended gouache colors.
Embodiment 3
The composite compounding agent for amphiphilic active pigment of embodiment 1 gained is hereinafter to be referred as the A agent;
Weight percent is that the fennel essential oil mixture of 6% hydrocarbon ethyl cellulose, 85% vinylformic acid and 9% is designated hereinafter simply as the C agent;
With above-mentioned A agent, C agent and organic or inorganic pigment powder by weight mix at 1.1: 2: 5 acrylic paints.
Embodiment 4
The composite compounding agent for amphiphilic active pigment of embodiment 1 gained is hereinafter to be referred as the A agent;
Weight percent is the fennel essential oil mixture of 76% linseed oil, 15% turps and 9%, is designated hereinafter simply as the D agent;
With above-mentioned A agent, D agent and organic or inorganic pigment powder by weight mix at 1.1: 2: 5 oil colour.
Parents' pigment combinations ingredients of the present invention is not limited only to above-mentioned use, and it can also be to be mixed with regeneration pigment at 1.1: 5 with weight proportion with the reclaiming waste material powder.Grind into powders such as the air-dry melon skin of reclaiming waste material, beans, tea grounds, flower.The color of regeneration pigment is mainly from the intrinsic colour of above-mentioned reclaiming waste material powder., color and luster is beautiful.

Claims (5)

1, a kind of composite compounding agent for amphiphilic active pigment is characterized in that: it is made up of following component in percentage by weight: alkylphenol polyoxyethylene 5.5-9%, alpha-sulfo fatty acid methyl ester sodium salt 8.5-12%, propylene glycol 3-5%, glycerine 2-6%, sodium alginate 13-20%, sodium soap 1-2%, antioxidant 3.5-6%, defoamer 2-4%, polyvinyl alcohol 2-4%, sanitas 2-7%, active CaCO 32-6%, mass percent concentration are 10% alkaline solution 28-35%.
2, by the described composite compounding agent for amphiphilic active pigment of claim 1, it is characterized in that: the fennel volatile oil that in described composite compounding, also has 1-3%.
3, by claim 1 or 2 described composite compounding agent for amphiphilic active pigment, it is characterized in that: described antioxidant is 2,6 di tert butyl 4 methyl phenol (BHT).
4, by claim 1 or 2 described composite compounding agent for amphiphilic active pigment, it is characterized in that: described defoamer is the organosilicon breast.
5, by claim 1 or 2 described composite compounding agent for amphiphilic active pigment, it is characterized in that: described sanitas is methyl esters, propyl ester, NaN 33: 1: 1 by weight percentage mixture.
CNB02114799XA 2002-01-29 2002-01-29 Composite compounding agent for amphiphilic active pigment Expired - Fee Related CN1164694C (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CNB02114799XA CN1164694C (en) 2002-01-29 2002-01-29 Composite compounding agent for amphiphilic active pigment
PCT/CN2003/000097 WO2003064542A1 (en) 2002-01-29 2003-01-29 Amphilic active pigment compounding agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB02114799XA CN1164694C (en) 2002-01-29 2002-01-29 Composite compounding agent for amphiphilic active pigment

Publications (2)

Publication Number Publication Date
CN1362455A CN1362455A (en) 2002-08-07
CN1164694C true CN1164694C (en) 2004-09-01

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CN (1) CN1164694C (en)
WO (1) WO2003064542A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100445956C (en) * 2004-12-24 2008-12-24 鸿富锦精密工业（深圳）有限公司 Device and method for debugging interconnection bus of peripheral devices

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100411887C (en) * 2004-12-17 2008-08-20 深圳市深蓝德精细化工科技有限公司 Drawing pen
CN101845246B (en) * 2010-06-10 2012-01-18 宋健 Easily scrubbed graffiti art watercolor paint and preparation method
CN102286223B (en) * 2011-06-21 2015-04-22 宁波工程学院 Pigment composition for drawing of children and preparation method thereof
CN102417747A (en) * 2011-11-07 2012-04-18 吴江市冰心文教用品有限公司 Production method of traditional Chinese painting pigment
CN103160152B (en) * 2011-12-14 2015-07-29 苏州欢颜电气有限公司 The red gouache color of a kind of fast-drying type and production method thereof
CN105017829A (en) * 2015-06-30 2015-11-04 河南行知专利服务有限公司 Biological environmental-friendly pigment used for artistic designing
CN105907147A (en) * 2016-05-03 2016-08-31 南阳理工学院 Photocatalyst containing oil paint and preparation method thereof
CN110713740A (en) * 2018-07-11 2020-01-21 刘静琳 Environment-friendly fen-flavor pigment
CN110577763B (en) * 2019-09-17 2021-09-24 华东理工大学 Oil painting pigment with lasting fragrance and preparation method thereof

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5991162A (en) * 1982-11-15 1984-05-25 Fuji Photo Film Co Ltd Production of aqueous pigment dispersion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100445956C (en) * 2004-12-24 2008-12-24 鸿富锦精密工业（深圳）有限公司 Device and method for debugging interconnection bus of peripheral devices

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CN1362455A (en) 2002-08-07

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