CN116463175A - Ceramic tile surface treating agent composition and preparation method thereof - Google Patents

Ceramic tile surface treating agent composition and preparation method thereof Download PDF

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Publication number
CN116463175A
CN116463175A CN202310352443.6A CN202310352443A CN116463175A CN 116463175 A CN116463175 A CN 116463175A CN 202310352443 A CN202310352443 A CN 202310352443A CN 116463175 A CN116463175 A CN 116463175A
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China
Prior art keywords
surface treating
tile surface
surfactant
thickener
composition according
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Pending
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CN202310352443.6A
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Chinese (zh)
Inventor
甘丽娜
胡浪滔
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Fujian Sanqing Paint Co ltd
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Fujian Sanqing Paint Co ltd
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Priority to CN202310352443.6A priority Critical patent/CN116463175A/en
Publication of CN116463175A publication Critical patent/CN116463175A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/10—Carbonates ; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2086—Hydroxy carboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707—Polyethers, e.g. polyalkyleneoxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Paints Or Removers (AREA)

Abstract

The application relates to the technical field of surface treatment agents, and particularly provides a tile surface treatment agent composition and a preparation method thereof. The ceramic tile surface treating agent composition comprises, by weight, 100% of the following raw material components, 2-10% of alkali, 0.5-3% of complexing agent, 0.1-2% of penetrating agent, 2-15% of surfactant, 0.5-3% of thickener, 0.3-4% of shaddock peel extract and the balance of water. The thickener is a copolymer of fatty alcohol polyoxyethylene ether acrylate and acrylic ester. The tile surface treating agent composition has a good cleaning treatment effect on greasy dirt on the surface of the tile, and the treated tile is good in adhesiveness after being coated with water-based paint.

Description

Ceramic tile surface treating agent composition and preparation method thereof
Technical Field
The application relates to the technical field of surface treatment agents, in particular to a ceramic tile surface treatment agent composition and a preparation method thereof.
Background
The water-based paint is an effective means for improving the beautiful appearance and the service life of the ceramic tile. However, the surface of the ceramic tile is difficult to be well adhered with water paint due to oil stains, soap scum and the like existing on the surface of the ceramic tile after the ceramic tile is used. In order to improve the adhesion of the aqueous coating to the tile surface, the tile surface must be treated with a treating agent. However, the existing treating agent is too alkaline to corrode the glazed surface of the ceramic tile, and the water-based paint is difficult to have higher adhesion after the treatment.
Disclosure of Invention
In order to solve the technical problem that the adhesive force of the water-based paint is still not high enough after the treatment agent is treated, the application provides a ceramic tile surface treatment agent composition and a preparation method thereof.
The application adopts the following technical scheme:
a ceramic tile surface treating agent composition comprises, by weight, 100% of the following raw material components, 2-10% of alkali, 0.5-3% of complexing agent, 0.1-2% of penetrating agent, 2-15% of surfactant, 0.5-3% of thickener, 0.3-4% of shaddock peel extract and the balance of water; the thickener has a structure represented by the following formula (1),
wherein R is 1 And R is 2 Independently selected from C1-C4 alkyl or hydrogen, R 3 Selected from C6-C24 alkyl, R 4 Selected from hydrogen or C1-C4 alkyl, n=6-20, a > 0, b > 0.
Preferably, the values of a and b satisfy: the value of b/a does not exceed 20%.
More preferably, the values of a and b satisfy: the value of b/a does not exceed 15%.
Preferably, the alkali is selected from one or more of sodium carbonate, sodium silicate, sodium hydroxide, potassium carbonate and potassium hydroxide.
Preferably, the complexing agent is selected from one or more of sodium gluconate, disodium EDTA, tetrasodium EDTA and diethylenetriamine pentacarboxylate.
Preferably, the penetrating agent has a structure represented by the following formula (2),
wherein m=2-5.
Preferably, the surfactant is one or more selected from nonionic surfactant, anionic surfactant, amphoteric surfactant and cationic surfactant.
More preferably, the surfactant contains at least the nonionic surfactant.
Preferably, the weight content of the shaddock peel extract is 0.5-2%.
The method for preparing a tile surface treating composition according to any one of the above embodiments, comprising: adding the alkali into the water, uniformly mixing, sequentially adding the complexing agent, the penetrating agent, the surfactant, the thickener and the shaddock peel extract, and uniformly mixing.
In summary, the present application has the following beneficial effects:
1. the thickener with the structure shown in the formula (1) is adopted in the application, and has a thickening function on the surface treatment agent composition, so that the water-based paint has a good adhesion effect on ceramic tiles after treatment, and the performance of the water-based paint is improved.
2. The penetrating agent with the structure shown in the formula (2) is further adopted in the application, so that the penetrating performance of the surface treatment agent composition is better, and the cleaning effect can be realized faster.
3. The addition of the shaddock peel extract to the surface treating agent composition in the present application was found to further improve the treating effect of the surface treating agent composition.
Drawings
FIG. 1 is a graph showing the results of a hundred-method test of the film of a tile-coating water-based paint after the tile surface treating agent composition of example 1 was treated.
FIG. 2 is a graph showing the results of a hundred-method test of the film of water-based paint applied to a tile after the tile surface treating agent composition of example 5 was applied.
FIG. 3 is a graph showing the results of a hundred-method test of the film of a tile-coated water-based paint after being treated with the tile surface treating agent composition of comparative example 1.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention will be described in detail below.
Throughout the specification, unless specifically indicated otherwise, the terms used herein should be understood as meaning as commonly used in the art. Accordingly, unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification will control.
In one aspect, the application provides a tile surface treatment agent composition, which comprises the following raw materials, by weight, 2-10% of alkali, 0.5-3% of complexing agent, 0.1-2% of penetrating agent, 2-15% of surfactant, 0.5-3% of thickener, 0.3-4% of shaddock peel extract and the balance of water;
the thickener has a structure represented by the following formula (1),
wherein R is 1 And R is 2 Independently selected from C1-C4 alkyl or hydrogen, R 3 Selected from C6-C24 alkyl, R 4 Selected from hydrogen or C1-C4 alkyl, n=6-20, a > 0, b > 0.
The thickener with the structure shown in the formula (1) can provide thickening effect, so that the surface treatment agent composition can be stably covered on the surface of the ceramic tile to be treated, and the applicant finds that the adhesiveness of the water-based paint on the ceramic tile after the ceramic tile is cleaned is higher.
The thickener represented by the formula (1) can be prepared as follows: monomer CH 2 ＝CR 1 CO(OCH 2 CH 2 ) n OR 3 With monomer CH 2 ＝CR 2 COOR 4 Adding the mixture into an organic solvent according to a certain molar ratio, uniformly mixing, adding an initiator, initiating polymerization reaction at a certain temperature, and removing the organic solvent to obtain the thickener R 1 、R 2 、R 3 、R 4 And n has the meaning given above.
In a preferred embodiment of the present application, the values of a and b above satisfy: the value of b/a does not exceed 20%. In a more preferred embodiment, the values of a and b above satisfy: the value of b/a does not exceed 15%. Further preferably, the value of b/a is not less than 5%, and for example, the value of b/a may be 5%, 5.5%, 6%, 6.5%, 7%, 7.5%, 8%, 8.5%, 9%, 9.5%, 10%, 10.5%, 11%, 11.5%, 12%, 12.5%, 13%, 13.5%, 14%, 14.5%, 5%, etc., without being limited to the above-exemplified ones.
In a preferred embodiment of the present application, the base is selected from one or more of sodium carbonate, sodium silicate, sodium hydroxide, potassium carbonate and potassium hydroxide. In this application, more preferably, when the alkali is selected from one or more of sodium carbonate, sodium silicate and potassium carbonate, the weight percentage of the alkali may be 5 to 10%, and when the alkali is selected from sodium hydroxide and/or potassium hydroxide, the weight percentage of the alkali may be 2 to 5%.
In a preferred embodiment of the present application, the complexing agent is selected from one or more of sodium gluconate, disodium EDTA, tetrasodium EDTA and diethylenetriamine pentacarboxylate. In the application, the complexing agent is used for complexing metal ions in some greasy dirt containing metal ions on the surface of the ceramic tile, so that the metal ions are prevented from being adsorbed on the surface of the ceramic tile which is cleaned.
In a preferred embodiment of the present application, the above-mentioned penetrant has a structure represented by the following formula (2),
wherein m=2-5.
The penetrant represented by formula (2) can be obtained by a ring-opening reaction of tertiary butanol and ethylene oxide.
The penetrant has the structure, the effect of the penetrant is better than that of the penetrant JFC on the market, three methyl groups in the structure of tertiary butyl of the penetrant shown in the formula (1) possibly face outwards, the penetrant has lower surface energy, and the penetrant can permeate better.
In a preferred embodiment of the present application, the surfactant is one or more selected from the group consisting of nonionic surfactants, anionic surfactants, amphoteric surfactants and cationic surfactants. For example, the nonionic surfactant may be AEO-9, AEO-15, peregal O, AEO-10, tween 60, tween 80, etc.; the anionic surfactant may be sodium dodecylbenzene sulfonate, sodium dodecylsulfate, sodium dodecylsulfonate, sodium dodecylcarboxylate, etc.; the amphoteric surfactant may be dodecyl ethoxy sulfobetaine, dodecyl dimethyl hydroxypropyl sulfobetaine, dodecyl dimethyl sulfopropyl betaine, etc.; the cationic surfactant may be octadecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium chloride, octadecyl benzyl dimethyl ammonium chloride, etc.
In a more preferred embodiment of the present application, the surfactant contains at least a nonionic surfactant. In the application, the surfactant can be a combination of nonionic surfactant and anionic surfactant, the weight ratio is 1:0.1-10, or a combination of nonionic surfactant and amphoteric surfactant, and the weight ratio is 1:0.1-10.
In a preferred embodiment of the present application, the weight content of the shaddock peel extract is 0.5-2%. The shaddock peel extract mainly contains naringin, and has a structure shown in the following formula (3).
The addition of shaddock peel extract to the tile treating composition of the present application found that the treatment was better, possibly related to the high polarity of phenolic hydroxyl groups and polyhydroxy groups in the naringin.
Another aspect of the present application proposes a method for preparing a tile surface treating agent composition according to any one of the above embodiments, comprising: adding alkali into water, mixing, sequentially adding complexing agent, penetrant, surfactant, thickener and pericarpium Citri Grandis extract, and mixing.
The technical scheme of the application is described in detail below with reference to examples and comparative examples.
Preparation example 1
Will CH 2 ＝CHCO(OCH 2 CH 2 ) 7.2 OR 3 (R 3 Is n-C 8 H 17 ) Adding the mixture and butyl methacrylate into butyl acetate which is 3 times of the weight of the monomer according to the molar ratio of 1:0.1, uniformly mixing, adding AIBN which is 1% of the weight of the monomer, introducing nitrogen, heating to 60 ℃ for polymerization reaction for 8 hours, and removing butyl acetate to obtain the thickener.
Preparation example 2
In preparation example 1, CH 2 ＝CHCO(OCH 2 CH 2 ) 7.2 OR 3 Adjusted to equimolar CH 2 ＝CHCO(OCH 2 CH 2 ) 13.6 OR 3 (R 3 Is n-C 12 H 25 ) The remaining steps remain unchanged.
Preparation example 3
Will CH 2 ＝CHCO(OCH 2 CH 2 ) 7.2 OR 3 (R 3 Is n-C 8 H 17 ) Adding the mixture and ethyl methacrylate into butyl acetate with the weight of 2.8 times of that of the monomer according to the molar ratio of 1:0.06, uniformly mixing, adding AIBN with the weight of 1% of that of the monomer, introducing nitrogen, heating to 60 ℃ for polymerization reaction for 8 hours, and removing butyl acetate to obtain the thickener.
Preparation example 4
Will CH 2 ＝CHCO(OCH 2 CH 2 ) 13.6 OR 3 (R 3 Is n-C 12 H 25 ) Adding the mixture into butyl acetate with the weight 2.8 times of the monomer according to the mol ratio of 1:0.1:0.05, uniformly mixing, and adding A with the weight 1% of the monomerAnd (3) under the condition of introducing nitrogen, heating to 60 ℃ for polymerization reaction for 8 hours, and removing butyl acetate to obtain the thickener.
Preparation example 5
In preparation example 4, CH 2 ＝CHCO(OCH 2 CH 2 ) 13.6 OR 3 (R 3 Is n-C 12 H 25 ) The molar ratio of the catalyst to butyl methacrylate and methyl methacrylate is adjusted to be 1:0.15:0.08, and the rest steps are kept unchanged.
Comparative preparation example 1
Will CH 2 ＝CHCO(OCH 2 CH 2 ) 13.6 OR 3 (R 3 Is n-C 12 H 25 ) Adding the mixture into butyl acetate with the weight of 2.8 times of that of the monomer, uniformly mixing, adding AIBN with the weight of 1% of that of the monomer, introducing nitrogen, heating to 60 ℃ for polymerization reaction for 8 hours, and removing butyl acetate to obtain the thickener.
Example 1
The tile surface treating agent composition comprises, by weight, 100% sodium carbonate, 2% sodium hydroxide, 1% sodium gluconate, 0.8% penetrant (CH 3 ) 3 CO(CH 2 CH 2 O) 2.7 H,3% AEO-9,5% sodium dodecyl benzene sulfonate, 1.5% thickener of preparation example 1, 2.2% shaddock peel extract, and the balance being water.
Example 2
The thickener in example 1 was replaced with an equal weight percentage of the thickener of preparation example 2.
Example 3
The thickener of example 1 was replaced with an equal weight percent of the thickener of preparation 3.
Example 4
The thickener in example 1 was replaced with an equal weight percent of the thickener of preparation example 4.
Example 5
The thickener in example 1 was replaced with an equal weight percent of the thickener of preparation example 5.
Comparative example 1
The thickener of example 1 was replaced with an equal weight percent of the thickener of comparative preparation 1.
Comparative example 2
The thickener of example 1 was replaced with an equal weight percentage of commercially available thickener RH-960.
Example 6
The tile surface treating agent composition comprises, by weight, 100% sodium carbonate, 2% sodium hydroxide, 1% sodium gluconate, 0.8% penetrant (CH 3 ) 3 CO(CH 2 CH 2 O) 2.7 H,3% AEO-9,5% sodium dodecyl benzene sulfonate, 0.6% thickener of preparation example 2, 1.5% shaddock peel extract, and the balance being water.
Example 7
In example 5, the thickener of preparation 2 was adjusted to 1% content, the water content was correspondingly reduced, and the rest of the procedure remained unchanged.
Comparative example 3
In example 5, the penetrant was replaced with equal weight percent of penetrant JFC, the rest of the procedure remaining unchanged.
Comparative example 4
In example 5, the water content was increased without the addition of the pomelo peel extract, and the rest of the steps remained unchanged.
Performance testing
Clean tile of 1.2mX0.6m was coated with a layer of greasy dirt (composed of 20wt% vegetable oil, 15wt% stearic acid, 5wt% commercially available soap, 5wt% granular sugar, 55% dust) to a thickness of 100.+ -. 10 μm, and placed at 150 ℃ for 2 hours, cut into small tiles of 10cm X5 cm, and placed in an outdoor ventilation and sunshade environment for 10 days.
And (3) testing small tiles: the tile treating agent coated on the small tile is soaked for 1 hour, washed clean with clear water and dried, then water-based tile glass paint (Sanqing company) is coated on the surface of the clean small tile, the film thickness is 30+/-2 mu m, whether obvious shrinkage cavity and other poor wetting conditions occur on the film layer is observed, and the adhesive force of the film layer is tested by adopting a hundred-grid method after 48 hours. If a significant wetting failure such as shrinkage cavity occurs, this means that the greasy dirt at the location is not removed. Each tile surface treating agent tested 20 tiles and judged the number of tiles without wetting failure, with little wetting failure and significant wetting failure. Clear water soaking was used as a blank. The results are shown in Table 1 below, where adhesion ratings were 1-5, 5 was most optimal, and 1 was the worst.
TABLE 1
From the results shown in Table 1, the tile surface treatment composition of the present application had a good cleaning effect on tile surfaces, and the cleaned tile surfaces had good adhesion after being coated with the aqueous coating.
The present embodiment is merely illustrative of the present application and is not intended to be limiting, and those skilled in the art, after having read the present specification, may make modifications to the present embodiment without creative contribution as required, but is protected by patent laws within the scope of the claims of the present application.

Claims (10)

1. The ceramic tile surface treating agent composition is characterized by comprising the following raw material components, by weight, 2-10% of alkali, 0.5-3% of complexing agent, 0.1-2% of penetrating agent, 2-15% of surfactant, 0.5-3% of thickener, 0.3-4% of shaddock peel extract and the balance of water;
the thickener has a structure represented by the following formula (1),
（1）
wherein R is 1 And R is 2 Independently selected from C1-C4 alkyl or hydrogen, R 3 Selected from C6-C24 alkyl, R 4 Selected from hydrogen or C1-C4 alkyl, n=6-20, a > 0, b > 0.
2. The tile surface treating composition according to claim 1, wherein the values of a and b satisfy: the value of b/a does not exceed 20%.
3. The tile surface treating composition according to claim 2, wherein the values of a and b satisfy: the value of b/a does not exceed 15%.
4. The tile surface treating composition according to claim 1, wherein the base is selected from one or more of sodium carbonate, sodium silicate, sodium hydroxide, potassium carbonate and potassium hydroxide.
5. The tile surface treating composition according to claim 1, wherein the complexing agent is selected from one or more of sodium gluconate, disodium EDTA, tetrasodium EDTA and diethylenetriamine pentacarboxylate.
6. The tile surface treating agent composition according to claim 1, wherein the penetrating agent has a structure represented by the following formula (2),
（2）
wherein m=2-5.
7. The tile surface treating composition according to claim 1, wherein the surfactant is selected from one or more of nonionic surfactant, anionic surfactant, amphoteric surfactant and cationic surfactant.
8. The tile surface treating composition according to claim 7, wherein said surfactant comprises at least said nonionic surfactant.
9. The tile surface treating composition according to claim 1, wherein the shaddock peel extract is contained in an amount of 0.5 to 2% by weight.
10. A method of preparing a tile surface treating composition according to any one of claims 1 to 9, comprising: adding the alkali into the water, uniformly mixing, sequentially adding the complexing agent, the penetrating agent, the surfactant, the thickener and the shaddock peel extract, and uniformly mixing.
CN202310352443.6A 2023-04-04 2023-04-04 Ceramic tile surface treating agent composition and preparation method thereof Pending CN116463175A (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117066081A (en) * 2023-10-18 2023-11-17 山西赛科德科技有限公司 Coating method of non-oriented silicon steel thin strip self-adhesive coating

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN117066081A (en) * 2023-10-18 2023-11-17 山西赛科德科技有限公司 Coating method of non-oriented silicon steel thin strip self-adhesive coating
CN117066081B (en) * 2023-10-18 2023-12-29 山西赛科德科技有限公司 Coating method of non-oriented silicon steel thin strip self-adhesive coating

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