CN116463162A - Lubricating grease, raw material composition thereof, preparation method and application - Google Patents
Lubricating grease, raw material composition thereof, preparation method and application Download PDFInfo
- Publication number
- CN116463162A CN116463162A CN202310456064.1A CN202310456064A CN116463162A CN 116463162 A CN116463162 A CN 116463162A CN 202310456064 A CN202310456064 A CN 202310456064A CN 116463162 A CN116463162 A CN 116463162A
- Authority
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- China
- Prior art keywords
- parts
- oil
- agent
- diisocyanate
- extreme pressure
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000004519 grease Substances 0.000 title claims abstract description 50
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000002994 raw material Substances 0.000 title claims abstract description 16
- 230000001050 lubricating effect Effects 0.000 title abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 20
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 19
- 229910052982 molybdenum disulfide Inorganic materials 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 18
- 239000002199 base oil Substances 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims abstract description 18
- 239000013556 antirust agent Substances 0.000 claims abstract description 16
- 239000003755 preservative agent Substances 0.000 claims abstract description 16
- 239000010696 ester oil Substances 0.000 claims abstract description 15
- 230000002335 preservative effect Effects 0.000 claims abstract description 15
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 14
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 14
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 claims abstract description 4
- 150000003464 sulfur compounds Chemical group 0.000 claims abstract description 4
- 235000019198 oils Nutrition 0.000 claims description 17
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 11
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- -1 polyethylene Polymers 0.000 claims description 9
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 7
- 125000005442 diisocyanate group Chemical group 0.000 claims description 7
- 238000005461 lubrication Methods 0.000 claims description 7
- 229920013639 polyalphaolefin Polymers 0.000 claims description 7
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 6
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 claims description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 6
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 5
- 239000012964 benzotriazole Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 4
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 claims description 4
- WJUMWVJBOZKPPU-UHFFFAOYSA-N 2,3-bis(6-methylheptyl)-N-phenylaniline Chemical compound C(CCCCC(C)C)C=1C(=C(C=CC1)NC1=CC=CC=C1)CCCCCC(C)C WJUMWVJBOZKPPU-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims description 3
- 235000012343 cottonseed oil Nutrition 0.000 claims description 3
- 239000002385 cottonseed oil Substances 0.000 claims description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 claims description 2
- RUFPHBVGCFYCNW-UHFFFAOYSA-N 1-naphthylamine Chemical compound C1=CC=C2C(N)=CC=CC2=C1 RUFPHBVGCFYCNW-UHFFFAOYSA-N 0.000 claims description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 claims description 2
- 239000005057 Hexamethylene diisocyanate Substances 0.000 claims description 2
- 239000005058 Isophorone diisocyanate Substances 0.000 claims description 2
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 150000001412 amines Chemical group 0.000 claims description 2
- 125000003354 benzotriazolyl group Chemical class N1N=NC2=C1C=CC=C2* 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 claims description 2
- XJRAOMZCVTUHFI-UHFFFAOYSA-N isocyanic acid;methane Chemical compound C.N=C=O.N=C=O XJRAOMZCVTUHFI-UHFFFAOYSA-N 0.000 claims description 2
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims description 2
- AYLRODJJLADBOB-QMMMGPOBSA-N methyl (2s)-2,6-diisocyanatohexanoate Chemical compound COC(=O)[C@@H](N=C=O)CCCCN=C=O AYLRODJJLADBOB-QMMMGPOBSA-N 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 239000005077 polysulfide Substances 0.000 claims description 2
- 229920001021 polysulfide Polymers 0.000 claims description 2
- 150000008117 polysulfides Polymers 0.000 claims description 2
- 150000003852 triazoles Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 2
- KEQFTVQCIQJIQW-UHFFFAOYSA-N N-Phenyl-2-naphthylamine Chemical compound C=1C=C2C=CC=CC2=CC=1NC1=CC=CC=C1 KEQFTVQCIQJIQW-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- BVEGNPSFKQMTQZ-UHFFFAOYSA-N calcium;1,2-di(nonyl)naphthalene Chemical compound [Ca].C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 BVEGNPSFKQMTQZ-UHFFFAOYSA-N 0.000 claims 1
- YMJSVUHZZIXMAK-UHFFFAOYSA-N calcium;naphthalene Chemical compound [Ca].C1=CC=CC2=CC=CC=C21 YMJSVUHZZIXMAK-UHFFFAOYSA-N 0.000 claims 1
- 150000002632 lipids Chemical class 0.000 claims 1
- 229910000831 Steel Inorganic materials 0.000 description 4
- 230000002159 abnormal effect Effects 0.000 description 4
- 238000005299 abrasion Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- RAADJDWNEAXLBL-UHFFFAOYSA-N 1,2-di(nonyl)naphthalene Chemical compound C1=CC=CC2=C(CCCCCCCCC)C(CCCCCCCCC)=CC=C21 RAADJDWNEAXLBL-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- MKFUUBCXQNCPIP-UHFFFAOYSA-L calcium;2,3-di(nonyl)naphthalene-1-sulfonate Chemical compound [Ca+2].C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1.C1=CC=C2C(S([O-])(=O)=O)=C(CCCCCCCCC)C(CCCCCCCCC)=CC2=C1 MKFUUBCXQNCPIP-UHFFFAOYSA-L 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- VSVUSPDEPGDGSO-UHFFFAOYSA-N [S].CC(C)=C Chemical compound [S].CC(C)=C VSVUSPDEPGDGSO-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- CXYRUNPLKGGUJF-OZVSTBQFSA-M pamine Chemical compound [Br-].C1([C@@H](CO)C(=O)OC2C[C@@H]3[N+]([C@H](C2)[C@@H]2[C@H]3O2)(C)C)=CC=CC=C1 CXYRUNPLKGGUJF-OZVSTBQFSA-M 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/06—Metal compounds
- C10M2201/065—Sulfides; Selenides; Tellurides
- C10M2201/066—Molybdenum sulfide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/283—Esters of polyhydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/14—Containing carbon-to-nitrogen double bounds, e.g. guanidines, hydrazones, semicarbazones
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/22—Heterocyclic nitrogen compounds
- C10M2215/223—Five-membered rings containing nitrogen and carbon only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/046—Overbasedsulfonic acid salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/102—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon only in the ring
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/10—Semi-solids; greasy
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16N—LUBRICATING
- F16N2210/00—Applications
- F16N2210/04—Vehicles
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention relates to the technical field of lubricating grease, and discloses lubricating grease, a raw material composition thereof, a preparation method and application, wherein the raw material composition of the lubricating grease comprises the following components in parts by weight: 75 to 90 parts of base oil, 4 to 18 parts of thickening agent, 1 to 6 parts of extreme pressure agent, 0.1 to 5 parts of antirust agent, 1 to 6 parts of nano molybdenum disulfide, 0.1 to 2 parts of preservative and 0.1 to 2 parts of antioxidant; the base oil is selected from one or more of hydrocarbon oil and ester oil; the thickener is a bisureido thickener; the extreme pressure agent is a sulfur compound; the antirust agent is sulfonate. The lubricating grease disclosed by the invention is prepared from the lubricating grease raw material composition through processing. The lubricating grease provided by the invention has the characteristics of low friction coefficient, high extreme pressure property and high wear resistance.
Description
Technical Field
The invention relates to the technical field of lubricating grease, in particular to lubricating grease, a raw material composition thereof, a preparation method and application thereof.
Background
With the continuous development of new energy automobile industry and the increasingly stringent national requirements for environmental protection, the switching of automobile power sources is impermissible. The change of the power source of the new energy automobile puts higher requirements on the lubrication of automobile parts, and particularly, the noise generated by other parts is covered by no noise of a fuel engine under the low-speed condition, so that the lubricating grease with excellent lubricating performance is essential to improve the running smoothness of the automobile parts.
The automobile universal joint has the function of ensuring that the connected input shaft and output circumference transmit power within a certain angle change range, and is structurally divided into an inner ball cage and an outer ball cage, and the outer ball cage of the existing passenger automobile universal joint generally adopts an Rzeppa structure, so that the six-steel-ball structure can effectively transmit power and torque.
The existing universal joint grease has the defects of poor performance, high use temperature rise, peeling abrasion of the steel balls, abnormal operation sound and the like.
Disclosure of Invention
The invention aims to solve the problems of high use temperature, peeling abrasion of steel balls and abnormal operation noise of universal joint grease in the prior art, and provides grease, a raw material composition, a preparation method and application thereof.
In order to achieve the above object, the present invention provides, in one aspect, a grease raw material composition comprising, in parts by weight: 75 to 90 parts of base oil, 4 to 18 parts of thickening agent, 1 to 6 parts of extreme pressure agent, 0.1 to 5 parts of antirust agent, 1 to 6 parts of nano molybdenum disulfide, 0.1 to 2 parts of preservative and 0.1 to 2 parts of antioxidant; the base oil is selected from one or more of hydrocarbon oil and ester oil; the thickener is a bisureido thickener; the extreme pressure agent is a sulfur compound; the antirust agent is sulfonate.
The second aspect of the invention provides a grease which is prepared by processing a grease raw material composition comprising the grease.
The third aspect of the invention provides a method for preparing the grease of the invention, comprising:
(1) Preparing a base fat system containing a thickening agent by using part of the base oil and the raw materials of the thickening agent;
(2) Adding the antioxidant and the preservative;
(3) And adding the balance of the base oil, the extreme pressure agent, the antirust agent and the nano molybdenum disulfide, and uniformly mixing.
According to a fourth aspect of the invention, there is provided the use of a grease stock composition according to the invention and/or a grease prepared by a preparation method according to the invention in the lubrication of a universal joint, more preferably in the lubrication of an rzepa type universal joint.
Through the technical scheme, the lubricating grease can be well applied to universal joints, and the problems of peeling abrasion and abnormal operation noise of the steel balls are prevented.
Detailed Description
The endpoints and any values of the ranges disclosed herein are not limited to the precise range or value, and are understood to encompass values approaching those ranges or values. For numerical ranges, one or more new numerical ranges may be found between the endpoints of each range, between the endpoint of each range and the individual point value, and between the individual point value, in combination with each other, and are to be considered as specifically disclosed herein.
In one aspect, the present invention provides a grease composition comprising, in parts by weight: 75 to 90 parts of base oil, 4 to 18 parts of thickening agent, 1 to 6 parts of extreme pressure agent, 0.1 to 5 parts of antirust agent, 1 to 6 parts of nano molybdenum disulfide, 0.1 to 2 parts of preservative and 0.1 to 2 parts of antioxidant; the base oil is selected from one or more of hydrocarbon oil and ester oil; the thickener is a bisureido thickener; the extreme pressure agent is a sulfur compound; the antirust agent is sulfonate.
According to a particularly preferred embodiment of the invention, the composition comprises, in parts by weight: 80 to 85 parts of base oil, 5 to 15 parts of thickening agent, 1 to 3 parts of extreme pressure agent, 0.1 to 2 parts of antirust agent, 1 to 5 parts of nano molybdenum disulfide, 0.1 to 1 part of preservative and 0.1 to 1 part of antioxidant.
In the present invention, the hydrocarbon oil is optionally of a wide variety, and according to a preferred embodiment of the present invention, the hydrocarbon oil is selected from one or more of Polyalphaolefins (PAO), polyethylene, naphthenic oils, hydrogenated mineral oil oils, preferably PAO. With the foregoing preferred embodiment, low temperature performance can be improved.
According to a preferred embodiment of the invention, the hydrocarbon oil has a kinematic viscosity at 40 ℃ of 100-150 mm 2 And/s. With the above preferred embodiment, low-temperature running performance and transmission efficiency can be improved.
In the present invention, the ester type is optionally wide, and according to a preferred embodiment of the present invention, the ester oil is selected from one or more of decyl ester, pentaerythritol ester, and tris-hydroxy complex ester, preferably tris-hydroxy complex ester, and the foregoing preferred embodiment is adopted, so that the low temperature performance and the additive solubility can be improved.
According to a preferred embodiment of the invention, the ester oil has a kinematic viscosity at 40 ℃ of 50-80 mm 2 And/s. With the above preferred embodiment, low-temperature running performance and transmission efficiency can be improved.
According to a preferred embodiment of the present invention, the base oil is a mixture of hydrocarbon oil and ester oil, and the mass ratio of hydrocarbon oil to ester oil is (4-20): 1. with the above preferred embodiment, lubricity and additive solubility can be improved.
In the present invention, the bisureido thickener may be a conventional choice in the art, as long as the object of the present invention is achieved, and according to a preferred embodiment of the present invention, the bisureido thickener is prepared by reacting a monoamine with a diisocyanate. With the above preferred embodiment, the high-temperature use temperature of the grease can be increased.
In the present invention, the monoamine is selected from one or more of octadecylamine, hexadecylamine, dodecyl amine, octylamine, aniline, naphthylamine, p-toluidine and cyclohexylamine, preferably a mixture of cyclohexylamine and octylamine, and the mass ratio of cyclohexylamine to octylamine is (0.5-2): 1. with the above preferred embodiment, the shearing resistance of the grease can be improved.
In the present invention, the diisocyanate may be selected from a wide variety, and according to a preferred embodiment of the present invention, the diisocyanate is selected from one or more of toluene diisocyanate, isophorone diisocyanate, diphenylmethane diisocyanate, methane diisocyanate, hexamethylene diisocyanate, lysine diisocyanate, and preferably toluene diisocyanate. With the foregoing preferred embodiments, the dropping point of grease can be increased.
In the present invention, the extreme pressure agent may be selected from one or more of polysulfide, vulcanized cottonseed oil, triisobutene and vulcanized isobutylene, preferably, vulcanized isobutylene. By adopting the preferable embodiment, the polishing effect of the lubricating grease on parts can be improved, and the bearing capacity of the grease can be improved.
In the invention, the rust inhibitor is selected from one or more of high-base-number alkyl benzene sulfonate and high-base-number alkyl naphthalene sulfonate, preferably high-base-number dinonyl naphthalene sulfonate calcium. By adopting the preferable embodiment, the rust resistance of the lubricating grease can be improved, and meanwhile, the lubricating grease and the sulfur extreme pressure agent can play a synergistic effect in the friction process, and calcium sulfate microcrystals are generated on the surface of the friction pair to reduce the friction coefficient.
In the present invention, the nano molybdenum disulfide is not particularly required as long as the object of the present invention can be achieved, and according to a preferred embodiment of the present invention, the particle size of the nano molybdenum disulfide is 50 to 150nm. With the above preferred embodiment, the friction performance of the grease can be improved.
In the present invention, the antioxidant is selected from a wide variety, and according to a preferred embodiment of the present invention, the antioxidant is an amine antioxidant selected from one or more of diphenylamine and nphenylβnaphthylamine, preferably diphenylamine. With the above preferred embodiment, oxidation resistance can be improved.
In the present invention, the preservative is selected from one or more of benzotriazole derivatives and triazole, preferably benzotriazole, according to a preferred embodiment of the present invention. With the above preferred embodiment, the grease aging resistance can be improved.
The invention provides lubricating grease which is prepared from the lubricating grease raw material composition.
The lubricating grease provided by the invention has excellent lubricating performance and has the characteristics of low friction coefficient, high extreme pressure property and high wear resistance.
The invention provides a preparation method of lubricating grease, which comprises the following steps:
(1) Preparing a base fat system containing a thickening agent by using part of the base oil and the raw materials of the thickening agent;
(2) Adding the antioxidant and the preservative;
(3) And adding the balance of the base oil, the extreme pressure agent, the antirust agent and the nano molybdenum disulfide, and uniformly mixing.
According to a preferred embodiment of the present invention, the preparation method comprises:
(a) Mixing the monoamine, the diisocyanate and the hydrocarbon oil, and reacting to obtain a basic fat system;
(b) Adding the antioxidant and the preservative;
(c) Adding the ester oil, the extreme pressure agent, the antirust agent and the nano molybdenum disulfide, uniformly mixing and grinding.
According to a preferred embodiment of the present invention, the reaction conditions of step (a) comprise: the reaction temperature is 50-100 ℃, and the temperature is preferably raised to 160-180 ℃ after the reaction is completed and kept constant for 30-80 minutes.
According to a preferred embodiment of the present invention, the addition of antioxidants and preservatives in step (b) controls the temperature of the base fat system between 110 and 125 ℃. With the foregoing preferred embodiment, the antioxidant and preservative can be prevented from being lost by pyrolysis.
According to a preferred embodiment of the present invention, the addition of the ester oil, the extreme pressure agent, the rust inhibitor and the nano molybdenum disulfide in step (c) controls the temperature of the base fat system to 70-90 ℃. With the above preferred embodiment, the prevention of pyrolysis loss of the additive component can be improved.
The invention provides application of the lubricating grease raw material composition and/or the lubricating grease prepared by the preparation method in universal joint lubrication, and more preferably application in Rzeppa type universal joint lubrication.
The lubricating grease disclosed by the invention has excellent lubricating performance, can be well applied to universal joints, and can be used for preventing the problems of peeling abrasion and abnormal operation sound of steel balls.
The present invention will be described below by way of specific examples, but the scope of the present invention is not limited to the scope covered by the examples, and the test methods involved are as follows:
maximum no bite load: GB/T3142, test conditions: at room temperature, 1500rpm.
Sintering load: GB/T3142, test conditions: at room temperature, 1500rpm.
Coefficient of friction: NB/SH/T0721, test conditions: 80 ℃,2h,50Hz,1.0mm,200N, point contact.
Plaque diameter: SH/T0204, test conditions: 3992N, 75 ℃,1200rpm,60min.
Example 1
78 parts of PAO (kinematic viscosity at 40 ℃ C. Of 150 mm) 2 After the reaction of 2.70 parts of octylamine, 5.23 parts of toluene diisocyanate and 2.07 parts of cyclohexylamine is completed at 60 ℃, the temperature is raised to 170 ℃ and kept constant for 30min, 0.2 part of diphenylamine and 0.2 part of benzotriazole are added after the temperature is reduced to 120 ℃, 5.6 parts of trihydroxycomplex ester is added after the temperature is reduced to 80 ℃Viscosity of 62mm 2 S), 2 parts of sulfur isobutene, 2 parts of high-base-number dinonyl naphthalene sulfonate and 2 parts of molybdenum disulfide with the particle size of 100nm, and homogenizing by using a three-wheel mill after uniformly mixing to obtain lubricating grease.
Example 2
After the reaction of 76 parts of naphthenic oil, 2.50 parts of octadecylamine, 5.81 parts of toluene diisocyanate and 3.69 parts of cyclohexylamine is completed at 80 ℃, heating to 170 ℃ and keeping the temperature for 60 minutes, cooling to 120 ℃, adding 0.2 part of diisooctyl diphenylamine and 0.2 part of benzotriazole, cooling to 80 ℃, adding 6.1 parts of pentaerythritol ester, 1.5 parts of vulcanized cottonseed oil, 1 part of high-base number dinonyl naphthalene sulfonate and 3 parts of molybdenum disulfide with the particle size of 150nm, homogenizing by using a three-wheel mill after the temperature is reduced to 80 ℃, and obtaining the lubricating grease.
Example 3
After the reaction of 78 parts of PAO, 4.43 parts of dodecyl amine, 4.99 parts of toluene diisocyanate and 1.58 parts of cyclohexane is completed at the temperature of 60 ℃, the temperature is raised to 170 ℃ and kept constant for 30min, 0.2 part of diisooctyl diphenylamine and 0.2 part of benzotriazole are added after the temperature is reduced to 120 ℃, 6.6 parts of pentaerythritol ester, 1.5 parts of triisobutene sulfide, 1 part of high-base number calcium dodecyl benzene sulfonate and 1.5 parts of molybdenum disulfide with the particle size of 150nm are added after the temperature is reduced to 80 ℃, and the grease is obtained after the uniform mixing, the homogenization is carried out by using a three-wheel mill.
Example 4
The procedure of example 1 was followed except that sulfurized isobutylene was substituted for tricresyl phosphate. The results are shown in Table 1.
Example 5
The procedure of example 1 was followed except that high base number calcium dinonylnaphthalene sulfonate was substituted for barium petroleum sulfonate. The results are shown in Table 1.
Example 6
The procedure of example 1 was followed except that 2 parts of calcium dinonylnaphthalene sulfonate having a high base number was additionally added. The results are shown in Table 1.
Comparative example 1
The procedure of example 1 was followed except that isobutylene sulfide was not added, and the other conditions were the same as in example 1. The results are shown in Table 1.
Comparative example 2
The procedure of example 1 was followed except that high base number calcium dinonylnaphthalene sulfonate was not added, and the conditions were the same as in example 1. The results are shown in Table 1.
TABLE 1
| Maximum no-bite load P B /N | Sintering load P D /N | Coefficient of friction | Diameter of mill spot/mm | |
| Example 1 | 1373 | 4905 | 0.064 | 0.36 |
| Example 2 | 1177 | 3924 | 0.069 | 0.36 |
| Example 3 | 1177 | 4905 | 0.072 | 0.39 |
| Example 4 | 1236 | 3924 | 0.105 | 0.38 |
| Example 5 | 1177 | 3090 | 0.094 | 0.44 |
| Example 6 | 1079 | 3924 | 0.085 | 0.38 |
| Comparative example 1 | 736 | 2453 | 0.098 | 0.40 |
| Comparative example 2 | 981 | 3924 | 0.092 | 0.46 |
As can be seen from the results of Table 1, examples 1 to 3 using the grease composition of the present invention have better extreme pressure property and antiwear property, and at the same time exhibit lower friction coefficient and excellent overall performance.
The preferred embodiments of the present invention have been described in detail above, but the present invention is not limited thereto. Within the scope of the technical idea of the invention, a number of simple variants of the technical solution of the invention are possible, including combinations of the individual technical features in any other suitable way, which simple variants and combinations should likewise be regarded as being disclosed by the invention, all falling within the scope of protection of the invention.
Claims (10)
1. A grease raw material composition, characterized in that the composition comprises, in parts by weight: 75 to 90 parts of base oil, 4 to 18 parts of thickening agent, 1 to 6 parts of extreme pressure agent, 0.1 to 5 parts of antirust agent, 1 to 6 parts of nano molybdenum disulfide, 0.1 to 2 parts of preservative and 0.1 to 2 parts of antioxidant;
the base oil is selected from one or more of hydrocarbon oil and ester oil;
the thickener is a bisureido thickener;
the extreme pressure agent is a sulfur compound;
the antirust agent is sulfonate.
2. The composition of claim 1, wherein the composition comprises, in parts by weight: 80 to 85 parts of base oil, 5 to 15 parts of thickening agent, 1 to 3 parts of extreme pressure agent, 0.1 to 2 parts of antirust agent, 1 to 5 parts of nano molybdenum disulfide, 0.1 to 1 part of preservative and 0.1 to 1 part of antioxidant.
3. The composition according to claim 1 or 2, wherein,
the hydrocarbon oil is selected from one or more of polyalphaolefins, polyethylene, naphthenic oils, hydrogenated mineral oils, preferably polyalphaolefins; and/or
The ester oil is selected from one or more of decyl ester, pentaerythritol ester and trihydroxy complex ester, preferably trihydroxy complex ester; and/or
Preferably, the base oil is a mixture of hydrocarbon oil and ester oil, and the mass ratio of hydrocarbon oil to ester oil is (4-20): 1.
4. a composition according to any one of claims 1-3, wherein the nano molybdenum disulfide has a particle size of 50-150 nm; and/or
The antioxidant is an amine antioxidant, preferably one or more of diphenylamine, diisooctyl diphenylamine and N-phenyl beta naphthylamine, preferably diphenylamine; and/or
The preservative is selected from one or more of benzotriazole derivatives and triazole, preferably benzotriazole; and/or
The diureido thickener is prepared by reacting monoamine and diisocyanate;
preferably, the method comprises the steps of,
the monoamine is one or more of octadecylamine, hexadecylamine, dodecylamine, octylamine, aniline, naphthylamine, p-toluidine and cyclohexylamine, and is preferably a mixture of cyclohexylamine and octylamine; and/or
The diisocyanate is selected from one or more of toluene diisocyanate, isophorone diisocyanate, diphenylmethane diisocyanate, methane diisocyanate, hexamethylene diisocyanate and lysine diisocyanate, and preferably toluene diisocyanate.
5. The composition according to any one of claim 1 to 4, wherein,
the extreme pressure agent is selected from one or more of polysulfide, vulcanized cotton seed oil, vulcanized triisobutene and vulcanized isobutene, and is preferably vulcanized isobutene; and/or
The rust inhibitor is organic calcium sulfonate, preferably the organic calcium sulfonate is selected from one or more of high-base-number alkyl benzene calcium sulfonate and high-base-number alkyl naphthalene calcium sulfonate, preferably high-base-number dinonyl naphthalene calcium sulfonate.
6. A grease prepared from a grease raw material composition according to any one of claims 1 to 5.
7. A method of preparing a grease according to claim 6, comprising:
(1) Preparing a base fat system containing a thickening agent by using part of the base oil and the raw materials of the thickening agent;
(2) Adding the antioxidant and the preservative;
(3) And adding the balance of the base oil, the extreme pressure agent, the antirust agent and the nano molybdenum disulfide, and uniformly mixing.
8. The production method according to claim 7, wherein the production method comprises:
(a) Mixing the monoamine, the diisocyanate and the hydrocarbon oil, and reacting to obtain a basic fat system;
(b) Adding the antioxidant and the preservative;
(c) Adding the ester oil, the extreme pressure agent, the antirust agent and the nano molybdenum disulfide, uniformly mixing and grinding.
9. The method of claim 7 or 8, wherein the reaction conditions of step (a) comprise: the reaction temperature is 50-100 ℃, and the temperature is preferably raised to 160-180 ℃ after the reaction is completed and kept constant for 30-80 minutes; and/or
Adding an antioxidant and a preservative in the step (b) to control the temperature of the basic lipid system to be 110-125 ℃; and/or
In the step (c), ester oil, an extreme pressure agent, an antirust agent and nano molybdenum disulfide are added, and the temperature of the basic fat system is controlled to be 70-90 ℃.
10. Use of a grease composition according to any one of claims 1 to 5 and/or a grease according to claim 6 and/or a grease prepared by a method according to any one of claims 7 to 9 in the lubrication of a universal joint, more preferably in the lubrication of an rzepa type universal joint.
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