CN1164435A - Concentrating and discharging method for wet fume-extracting desulfurizing absorption liquor raw material - Google Patents
Concentrating and discharging method for wet fume-extracting desulfurizing absorption liquor raw material Download PDFInfo
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- CN1164435A CN1164435A CN 97104539 CN97104539A CN1164435A CN 1164435 A CN1164435 A CN 1164435A CN 97104539 CN97104539 CN 97104539 CN 97104539 A CN97104539 A CN 97104539A CN 1164435 A CN1164435 A CN 1164435A
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Abstract
The invention provides a concentration discharging method of raw meal of wet flue gas desulphurization absorption liquid. A division chamber arranged at a side arm of an absorption liquid cylinder of a flue gas desulphurization device adopting the wet lime-gypsum method is used to discharge the raw meal of absorption liquid in the absorption liquid raw meal cylinder out of the system after concentration. The invention is characterized in that the concentration of the drawn raw meal is mensurated consecutively, so that the drawn raw meal is discharged out of the system or cycled in the division chamber in a set range; the concentration of the absorption liquid raw meal inside the absorption liquid raw meal cylinder is also detected, so that the air flux which supplies for an air lift tube arranged on the division chamber is increased or decreased according to the detected value so as to adjust the concentration of the absorption liquid raw meal. Thus, the gypsum as concentrated raw meal with stable concentration can be discharged with the amount of the concentrated raw meal matching that of sulfur removal amount, and the raw meal concentration inside the absorption liquid raw meal cylinder can be easily adjusted.
Description
The gypsum composition with absorption liquor raw material that the present invention relates in the wet type lime stone-gypsum method flue gas desulfurization equipment concentrates the method that discharge the back.
An example of the concentrating and discharging method of the absorption liquor raw material in the now used wet type lime stone-gypsum method flue gas desulfurization equipment can be specified with Fig. 5.
In device shown in Figure 5, the smoke evacuation AA that will be untreated is fed to 101 li on absorption tower from smoke evacuation inlet 105, and is desulfurized after absorption liquor raw material CC from injection spray pipe 108 spreadings contacts, and is discharged from as handling smoke evacuation BB from smoke evacuation outlet 106.Be blown into from the air HH of air-blaster 110 output from air dispersion device 112 in the absorption liquor raw material CC in the absorption liquor raw material groove cylinder 102, make the sulfite oxidation that generates through desulfurization and form gypsum, and in order to prevent the sedimentation of gypsum and other solid material, to be stirred with mixer 111, will with the SO that absorbs
2The gypsum of amount phase weighing is discharged as dense raw material DD.The mode of discharging from pipeline 107 (it be by circulating pump 103 absorption liquor raw material CC is promoted and be scattered in 101 li on absorption tower with) feed fluid cyclone separator 104 behind the extraction part absorption liquor raw material CC, form dense raw material DD and discharge, and rare raw material EE is turned back to 102 li in absorption liquor raw material groove cylinder from liquid cyclone separator 104 bottoms.Symbol 109 among Fig. 5 is absorbent groove cylinders that absorbent FF such as the lime stone of the amount that matches with the amount of discharging as gypsum and water GG supply with absorption liquor raw material groove cylinder 102 usefulness.
And, the inventor once proposed the concentrating and discharging method of more economical, easy absorption liquor raw material, and it is enrichment region (cutting apart the chamber) is set in the absorption liquor raw material groove cylinder of flue gas desulfurization equipment, gypsum deposition is concentrated and discharges (Japanese patent gazette spy opens flat 7-308539 number) at this enrichment region.
In order to concentrate the solid state component of absorption liquor raw material, adopt the method for the prior art of liquid cyclone separator that following described problem is arranged.That is, under the occasion of flue gas desulfurization equipment,, usually need to handle the raw material of certain flow with the liquid cyclone separator though make the amount of gypsum change of generation by the change of exhaust gas desulfurization amount.Like this, when the concentration of the dense raw material that tail off, discharge when desulfurization amount reduced, the treatment facility of follow-up dense raw material will cause poor dewatering etc. as making gypsum dehydration and carrying out the processing time lengthening just of the equipment of Separation of Solid and Liquid.Many when the desulfurization quantitative change, when the concentration of the dense raw material of discharge increases, makes for fear of above-mentioned concentration reduction the delivery flow of dense raw material to dwindle, have in the liquid cyclone separator, to cause superfluous concentrating and problems such as generation obstruction.For this reason, adopt some changes, the dense raw material that a part is concentrated to turn back to the method in the absorption liquor raw material groove cylinder, the quality of managing dense raw material corresponding to load.That is, handle the superfluous useless amount of processing under few occasion in smoke evacuation.
In addition, in the absorption liquor raw material groove cylinder of flue gas desulfurization equipment, the thickener method of (cutting apart the chamber) is set, must adjusts flow according to the change of raw material concentration with above-mentioned.Under this occasion, if flow does not very have special problem at most, but when flow tailed off, the sedimentation in pipeline of heavy gypsum caused pipeline blockage.
When making in the absorption liquor raw material groove cylinder raw material concentration, the reasons such as change owing to desulfurization load became when low, the gypsum scale takes place in positions such as the wall on absorption tower and the groove inside wall of cylinder, make the insufficient growth of particle of gypsum, and only generate the particulate of gypsum, because concentrating, the sedimentation in thickener can not carry out, thereby the discharge that just can not be well on, the gypsum concentration in the absorption liquor raw material is risen, this situation will make absorption liquid circulating pump damaged (wearing and tearing).And when bringing up to a certain degree concentration, grow up and carry out violent concentrating owing to gypsum particle, this just makes the concentration of absorption liquor raw material reduce on the contrary, thereby the amplitude of fluctuation of concentration is increased.For this reason, the absorption liquor raw material concentration in the absorption liquor raw material groove cylinder must be held in to a certain degree concentration level.
The present invention makes for the problem that solves above-mentioned prior art existence, the concentrating and discharging method that provides a kind of wet type flue gas desulfurization to absorb raw material is provided, it can with desulfurization amount mutually the gypsum of weighing discharge as the dense raw material that form concentration stabilize, and can easily adjust raw material concentration in the absorption liquor raw material groove cylinder.
The 1st scheme of the concentrating and discharging method of the wet type flue gas desulfurization absorption raw material of the present invention of making in order to achieve the above object is to be provided with to cut apart the chamber on the sidewall of the poor cylinder of absorption liquor raw material of wet type lime stone-gypsum method flue gas desulfurization equipment, this top of cutting apart the chamber be provided with absorption liquor raw material groove cylinder in the air stalk that is communicated with, sidewall is provided with the opening that is communicated with raw material in the absorption liquor raw material groove cylinder, the bottom is provided with the pipe arrangement that is communicated with the raw material drawing pump, after concentrating, absorption liquor raw material in this chamber of cutting apart makes absorption liquor raw material groove cylinder is discharged in the method outside the system, it is characterized in that: measure the raw material concentration of extracting out continuously with above-mentioned raw material drawing pump, after the concentration of extracting raw material out reached capping concentration, the raw material that then begin to be extracted out by above-mentioned raw material drawing pump were discharged to outside the system; When the concentration of extracting raw material out reaches the setting least concentration, stop outside system, to discharge above-mentioned extraction raw material, make it to the above-mentioned indoor circulation of cutting apart.The 2nd scheme that the wet type flue gas desulfurization of having done of the present invention absorbs the concentrating and discharging method of raw material is on the basis of the 1st scheme, detect the concentration of the absorption liquor raw material in the absorption liquor raw material groove cylinder, corresponding to this detected value the air mass flow that supplies in the above-mentioned air stalk is increased and decreased, thereby above-mentionedly cut apart indoor and absorption liquor raw material amount that be discharged from and regulate flowing into.
The present invention is provided with in the absorption liquor raw material groove cylinder of wet type lime stone-gypsum method flue gas desulfurization equipment cuts apart the chamber, the indoor absorption liquor raw material that makes is concentrated cutting apart, when discharging the raw material that concentrate, the raw material concentration of extracting out from the chamber of cutting apart does not reach under the situation of normal concentration, it is intactly turned back to circulates after cutting apart the chamber, if when concentrating the back, then outside system, discharge above normal concentration.That is, the present invention discharges the raw material of concentration more than normal concentration off and on, can near with desulfurization amount mutually the absorption liquor raw material of weighing be discharged to outside the system as the raw material that form concentration stabilize.Even in that time of not discharging raw material, owing to also circulating, thereby can not produce the problem of gypsum sedimentation.
Though the raw material concentration of discharging is different because of the structure of the last handling process of the operating condition of desulfurizer, raw material, get 50~70 weight % usually for well, 50~60 weight % preferably are because the easiest processing in this case.
And, preferred forms of the present invention is to detect the concentration of the absorption liquor raw material in the absorption liquor raw material groove cylinder, make according to this detected value and to supply to the above-mentioned air mass flow of cutting apart in the air stalk set on the chamber and increase and decrease, cut apart the indoor absorption liquor raw material amount or the absorption liquor raw material amount of discharge thereby regulate to flow into, just the absorption liquor raw material concentration in the absorption liquor raw material groove cylinder can be remained in the concentration range of regulation thus.Though the concentration of absorption liquor raw material is taken in 15~30 weight % scopes just can keep stable status preferably because of the operating condition of desulfurizer is different usually.
Adopt method of the present invention, can be from the absorption liquor raw material groove cylinder that absorption liquor raw material is acutely being flowed because of mixer and bubbling air, by the chamber of cutting apart that is arranged in the absorption liquor raw material groove cylinder, can discharge the absorption liquor raw material that is condensed into high concentration in weighing ground mutually with desulfurization amount, because inadequate raw material repetitive cycling is indoor to cutting apart concentrating, up to the concentration that is condensed into necessity, thereby can not discharge the raw material that are concentrated lavishly.
Again because by detecting the concentration of the absorption liquor raw material in the absorption liquor raw material groove cylinder, regulate the air capacity that is blown in the air stalk according to this detected value, control the amount of cutting apart indoor absorption liquor raw material that flow into, adjust thereby raw material are concentrated speed, thereby have and to keep certain effect to the absorption liquid concentration in the absorption liquor raw material groove cylinder.
Fig. 1 is the schematic diagram of an example of the expression apparatus structure of implementing the inventive method,
Fig. 2 is the amplification profile diagram of the structure of cutting apart chamber 13 in the presentation graphs 1,
Fig. 3 is the schematic diagram of another example of the expression apparatus structure of implementing the inventive method,
Fig. 4 is the SO in the untreated smoke evacuation of representing among the embodiment 2
2The variation chart of change in concentration and absorption liquor raw material concentration corresponding with it,
Fig. 5 is the schematic diagram of an example of the concentrating and discharging method of the absorption liquor raw material in the wet type flue gas desulfurization equipment before the expression.
Below, specific embodiments of the invention are described, can more clearly understand effect of the present invention thus.
(embodiment 1)
Fig. 1 and Fig. 2 represent an example of embodiments of the present invention.Fig. 1 is the schematic diagram of an example of the expression apparatus structure of implementing the inventive method.Desulfurization treatment system in the device shown in Figure 1 is made of following part, that is, from the untreated smoke evacuation A that smoke evacuation inlet 5 imports, carry out the smoke evacuation outlet 6 of the absorption tower 1 of wet type desulfurizing, the processing smoke evacuation B that will be desulfurized discharging, the absorption liquid bath cylinder 2 that is arranged on 1 bottom, absorption tower, from absorb liquid bath cylinder 2 with absorption liquor raw material C be promoted to circulating pump 3 in the absorption tower 1, by pipe arrangement 7 the absorption liquor raw material C that are raised be dispensed onto injection spray pipe 8 in the absorption tower 1, the SO that neutralizes and absorbed
2Alkaline absorbent F and water G mixes and absorption liquid bath cylinder 9, the absorbent pump 22 of modulation absorbent raw material, carry and be used for the SO that oxidation absorbed
2Air H air-blaster 10, make from the mixer 11 that the air H of air-blaster 10 input is distributed to air dispersion device 12 the absorption liquor raw material C in the absorption liquor raw material groove cylinder 2, the sedimentation of gypsum in the absorption liquid that prevents to be generated by oxidation is used.
On the sidewall of absorption liquor raw material groove cylinder 2, be provided with make that gypsum concentrates cut apart chamber 13, also be provided with from cutting apart the drawing pump 4 that chamber 13 is extracted dense raw material out, the densimeter (raw material densimeter) 17 that the raw material concentration of being extracted out by this drawing pump 4 is detected, make through the raw material of densimeter 17 mensuration concentration and supply with the control valve 19 that the destination is chosen in discharge line 21 sides, with it is chosen in to the control valve 20 of cutting apart the circulation of chamber 13 sides, control the accommodometer 18 of the switch motion of above-mentioned control valve 19 and 20 according to the detection signal of densimeter 17.
Fig. 2 is the amplification profile diagram that the structure of chamber 13 is cut apart in expression.Be provided with opening 14 on the chamber 13 cutting apart, it is that the absorption liquor raw material C that the air H that is discharged by mixer 11 and air dispersion device 12 in the absorption liquor raw material groove cylinder 2 is being stirred tempestuously flows into the opening of cutting apart in the chamber 13, be provided with air stalk 15 on the top of cutting apart chamber 13, its front end is that opening is in absorption liquor raw material groove cylinder 2, cut apart 13 bottoms, chamber and be connected, also be connected with the return pipeline of drawing that makes concentrated inadequate raw material circulation from drawing pump 4 with above-mentioned drawing pump 4.The pipeline that is connecting air supply H midway at air stalk 15.In the bottom of cutting apart chamber 13, forms the dead band in order to prevent to pile up because of gypsum, be provided with the angle of repose of considering gypsum (though different because of environment, get under this occasion 40~60 spend about) constriction, be preferably formed as the shape of easy discharge raw material.
Use this structure, use the device of specification shown in the table 1, carried out the smoke evacuation Processing Test according to the condition shown in the table 2.SO among its result, the processing smoke evacuation B
2Concentration is 100~130ppm, and the temperature of handling smoke evacuation B is 48 ° of degree.And the discharge of raw material per hour is average about 4 times, and the opening time of each control valve 19 is about 10 minutes, raw material concentration average out to 57~60 weight % that are discharged from (the concentration width of cloth is 50~65 weight %).
Table 1
Project specifications |
Absorption tower 1 cross dimensions 1m * 1m height 10m absorption liquor raw material groove 2 dimension width 2m, length 2m, it is 0.4m * 0.4m height 1m opening 14 height 0.01m that height 3m is cut apart the chamber the widest part of 13 sections, width 0.1m constriction from the height half, be that the 0.5m place |
Table 2
The project condition |
Per hour 10000m of the smoke evacuation A treating capacity that is untreated
3N ????????????????????SO
298 ℃ of absorption liquor raw material C of concentration 1000ppm temperature flow is 170m per hour
3Concentration 20 weight % air dispersion devices 12 air mass flows are 500m per hour
3Air stalk 15 air mass flows are 0.5m per hour
3Absorption liquor raw material groove cylinder horizontal |
(embodiment 2)
Fig. 3 represents the 2nd example of embodiment of the present invention.This embodiment is being changed from cutting apart chamber 13 extraction systems in the apparatus structure of embodiment shown in Figure 11, here omitting with the part of Fig. 1 repetition, Fig. 3 its specific structure partly is illustrated.The structure of this example is to detect the concentration of the absorption liquor raw material C in the absorption liquor raw material groove cylinder 2 with densimeter 23, by concentration adjustment meter 24 these detectable concentrations of management and setting concentration, deviation corresponding to concentration makes control valve 25 actions, thereby regulates the flow of the air H that is blown into 15 li of air stalks.
Except make from the extraction system of cutting apart chamber 13 shown in Figure 3, all the other all use the device with embodiment 1 same size, as illustrated in fig. 4 except making the SO among the smoke evacuation A that is untreated
2Outside the concentration changes with time, all the other operate the Processing Test of discharging fume with embodiment 1 such condition.Consequently handle the SO among the smoke evacuation B
2Concentration is corresponding to the SO of the smoke evacuation A that is untreated that imports
2Concentration and become 40~130ppm, the temperature of handling smoke evacuation B is 48 ℃.In addition, according to the raw material concentration in the absorption liquor raw material groove cylinder 2, by making the flow that imports 15 li of air stalks at 0.1~0.5m per hour
3Between change, remain between 19~21 weight % with just making the concentration stabilize that absorbs the interior absorption liquor raw material C of raw material groove cylinder 2.
Claims (2)
1. wet type flue gas desulfurization absorbs the concentrating and discharging method of raw material, it is to be provided with to cut apart the chamber on the sidewall of the absorption liquor raw material groove cylinder of wet type lime stone-gypsum method flue gas desulfurization equipment, this top of cutting apart the chamber be provided with absorption liquor raw material groove cylinder in the air stalk that is communicated with, sidewall is provided with the opening that is communicated with raw material in the absorption liquor raw material groove cylinder, the bottom is provided with the pipe arrangement that is communicated with the raw material drawing pump, cut apart at this and indoorly to be discharged to outside the system after absorption liquor raw material in the absorption liquor raw material groove cylinder is concentrated, it is characterized in that: measure the raw material concentration of extracting out continuously with above-mentioned raw material drawing pump, after the raw material concentration of extracting out reached capping concentration, the raw material that then begin to be extracted out by above-mentioned raw material drawing pump were discharged to outside the system; When extraction raw material concentration reaches the setting least concentration, stop outside system, to discharge above-mentioned extraction raw material, make it to the above-mentioned indoor circulation of cutting apart.
2. wet type flue gas desulfurization as claimed in claim 1 absorbs the concentrating and discharging method of raw material, it is characterized in that: the concentration that detects the absorption liquor raw material in the absorption liquor raw material groove cylinder, corresponding to this detected value the air mass flow that supplies in the above-mentioned air stalk is increased and decreased, thereby above-mentionedly cut apart indoor and absorption liquor raw material amount that be discharged from and regulate flowing into.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP070159/96 | 1996-03-26 | ||
JP8070159A JPH09253443A (en) | 1996-03-26 | 1996-03-26 | Concentration-discharge method for wet type flue-gas desulfurization absorption liquid slurry |
Publications (2)
Publication Number | Publication Date |
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CN1164435A true CN1164435A (en) | 1997-11-12 |
CN1084216C CN1084216C (en) | 2002-05-08 |
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CN97104539A Expired - Fee Related CN1084216C (en) | 1996-03-26 | 1997-03-25 | Concentrating and discharging method for wet fume-extracting desulfurizing absorption liquor raw material |
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JP (1) | JPH09253443A (en) |
CN (1) | CN1084216C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100531864C (en) * | 2004-03-18 | 2009-08-26 | 国际壳牌研究有限公司 | Process for treating a loaded solvent stream having a time-varying concentration of contaminant |
EP3170547A4 (en) * | 2014-07-17 | 2018-01-24 | Mitsubishi Hitachi Power Systems, Ltd. | Flue gas desulfurization apparatus and method of operating same |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN104597206A (en) * | 2014-12-31 | 2015-05-06 | 聚光科技(杭州)股份有限公司 | Continuous flue gas emission monitoring system and continuous flue gas emission monitoring method |
CN106178163B (en) * | 2016-07-01 | 2019-02-01 | 翁炳焕 | AIDS biological cell immunization therapy instrument |
JP6526278B1 (en) * | 2018-03-23 | 2019-06-05 | 三菱日立パワーシステムズ株式会社 | Exhaust gas desulfurization system |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS55134631A (en) * | 1979-04-05 | 1980-10-20 | Mitsubishi Heavy Ind Ltd | Circulation of absorbent in exhaust gas treating apparatus |
JPS5922574A (en) * | 1982-07-29 | 1984-02-04 | ヤマハ株式会社 | Production of wood club head for golf |
JPH02819A (en) * | 1988-01-26 | 1990-01-05 | Nippon Mining Co Ltd | Light signal distributor |
US5209905A (en) * | 1990-12-14 | 1993-05-11 | Mitsubishi Jukogyo Kabushiki Kaisha | Wet-type exhaust gas desulfurization system having a means for supplying air |
-
1996
- 1996-03-26 JP JP8070159A patent/JPH09253443A/en active Pending
-
1997
- 1997-03-25 CN CN97104539A patent/CN1084216C/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100531864C (en) * | 2004-03-18 | 2009-08-26 | 国际壳牌研究有限公司 | Process for treating a loaded solvent stream having a time-varying concentration of contaminant |
EP3170547A4 (en) * | 2014-07-17 | 2018-01-24 | Mitsubishi Hitachi Power Systems, Ltd. | Flue gas desulfurization apparatus and method of operating same |
Also Published As
Publication number | Publication date |
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CN1084216C (en) | 2002-05-08 |
JPH09253443A (en) | 1997-09-30 |
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