CN116409947A - High-performance self-leveling cement and preparation method thereof - Google Patents
High-performance self-leveling cement and preparation method thereof Download PDFInfo
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- CN116409947A CN116409947A CN202310193289.2A CN202310193289A CN116409947A CN 116409947 A CN116409947 A CN 116409947A CN 202310193289 A CN202310193289 A CN 202310193289A CN 116409947 A CN116409947 A CN 116409947A
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- 239000004568 cement Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 31
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000002893 slag Substances 0.000 claims abstract description 21
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 15
- 239000003245 coal Substances 0.000 claims abstract description 14
- 239000010440 gypsum Substances 0.000 claims abstract description 14
- 229910052602 gypsum Inorganic materials 0.000 claims abstract description 14
- 238000010791 quenching Methods 0.000 claims abstract description 13
- 230000000171 quenching effect Effects 0.000 claims abstract description 13
- 239000002689 soil Substances 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 11
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 5
- 239000003469 silicate cement Substances 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims abstract description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid group Chemical group C(CC(O)(C(=O)O)CC(=O)O)(=O)O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 150000004683 dihydrates Chemical class 0.000 claims description 8
- 229920005646 polycarboxylate Polymers 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 4
- 239000011398 Portland cement Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 230000003068 static effect Effects 0.000 claims description 3
- 238000009423 ventilation Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 7
- 238000010276 construction Methods 0.000 description 7
- 239000004570 mortar (masonry) Substances 0.000 description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000005997 Calcium carbide Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000002910 solid waste Substances 0.000 description 2
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CQBLUJRVOKGWCF-UHFFFAOYSA-N [O].[AlH3] Chemical compound [O].[AlH3] CQBLUJRVOKGWCF-UHFFFAOYSA-N 0.000 description 1
- OBNDGIHQAIXEAO-UHFFFAOYSA-N [O].[Si] Chemical compound [O].[Si] OBNDGIHQAIXEAO-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 238000004380 ashing Methods 0.000 description 1
- 230000000740 bleeding effect Effects 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 229910001678 gehlenite Inorganic materials 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000007885 magnetic separation Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/14—Cements containing slag
- C04B7/147—Metallurgical slag
- C04B7/153—Mixtures thereof with other inorganic cementitious materials or other activators
- C04B7/21—Mixtures thereof with other inorganic cementitious materials or other activators with calcium sulfate containing activators
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
- C04B40/0046—Premixtures of ingredients characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B7/00—Hydraulic cements
- C04B7/36—Manufacture of hydraulic cements in general
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
- C04B2103/14—Hardening accelerators
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention relates to high-performance self-leveling cement, which comprises the following components in parts by weight: 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of high collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent; the invention adopts water quenching blast furnace granulated slag, iron tailings, carbide slag, coal gangue and high collar soil to replace cement clinker, thereby achieving the purposes of protecting environment, saving resources and developing low-carbon economy; the high-performance self-leveling water prepared by the method has good rheological property, can be used in the fields of quick ground repair and the like, can greatly reduce the mixing proportion of clinker in high-performance early strength cement, and has remarkable economic effect.
Description
Technical Field
The invention belongs to the technical fields of building material production and industrial solid waste resource utilization, and particularly relates to high-performance early-strength self-leveling cement and a preparation method thereof.
Background
For a long time, cement is used as an important cementing material and is widely applied to civil construction, water conservancy, national defense and other projects.
The cement-based self-leveling mortar is a ground leveling decorative material prepared by taking special cement, ordinary Portland cement and gypsum as cementing materials and adding fillers and various additives, can quickly and efficiently level the ground, has the characteristics of good leveling property, high early strength, easiness in laying, high construction speed, short construction period and the like, is widely applied to industrial plants, parking lots, public grounds and the like, and is also a decorative material of modern buildings, and has great market potential. At present, domestic cement-based self-leveling mortar mainly has the problems of low early strength, surface ashing, wear resistance, shrinkage cracking caused by chemical reaction shrinkage and the like.
The technical staff in the field are dedicated to developing a preparation method of high-performance self-leveling cement, so that the prepared self-leveling cement has good rheological property, high early strength, proper setting time, strong wear resistance and good shrinkage performance, the cement-based self-leveling cement is guaranteed to have effective operation time, construction can be performed quickly and efficiently, the setting speed is high, and the purposes of recycling, production cost saving, quick input and use and construction cost saving are achieved.
Disclosure of Invention
The invention provides a cement-based self-leveling agent which has good rheological property, high early strength, proper setting time, strong wear resistance and good shrinkage performance, ensures that cement-based self-leveling has effective operation time, can perform construction quickly and efficiently, has good setting speed, and achieves the purposes of recycling, saving production cost, quick application and construction cost saving.
In order to achieve the aim, the high-performance self-leveling cement comprises 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of high collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent in parts by weight.
The early strength agent is prepared by mixing 50-60% of iron tailings, 30-40% of carbide slag and 10-15% of coal gangue, carrying out static pressure molding, placing the mixture in a kiln with a ventilation facility, heating the mixture to 750-850 ℃ at a constant temperature of 10 ℃/min, taking out and naturally cooling the mixture, wherein the coal gangue is the coal gangue subjected to vector burning treatment, and the coal gangue subjected to vector burning treatment can discharge vulcanized gas, so that the problem of incomplete reaction caused by cracking in the firing process of the early strength agent is avoided.
C in the Portland cement clinker 3 The S content is 70-85%, the gypsum is natural dihydrate gypsum, the water reducer is a polycarboxylate water reducer, and the dispersing agent is citric acid.
The iron tailings are residues left after iron ore is subjected to magnetic separation to obtain iron ore fine powder, and the residues are rich in chemical compositions such as ferric oxide, silicon dioxide, aluminum oxide, calcium oxide, sodium oxide and the like.
The calcium carbide slag is waste slag which takes calcium hydroxide as a main component after calcium carbide is hydrolyzed to obtain acetylene gas, has the solid content of 12.0 percent, belongs to national class II industrial solid waste, and is directly used as an adhesive for static pressure molding because of the high calcium content to provide calcium on one hand and the high water content on the other hand.
The activity of the gangue is low, and calcination is an effective means for exciting the activity of the gangue, and aims to make each particle in the microstructure of the gangue generate intense thermal motion by utilizing high temperature, remove cations such as calcium, magnesium, iron and the like, reselect interstitial positions, so that silicon oxygen tetrahedrons and aluminum oxygen trigones cannot be fully polymerized into long chains, and a large number of breaking points of free ends are formed. The particles can no longer be arranged according to a certain rule to form a structure in a thermodynamically unstable state.
The invention also aims to provide a preparation method of the high-performance self-leveling cement, which comprises the steps of placing silicate cement clinker, water quenching blast furnace granulated slag, an early strength agent and high collar soil into a cement mill for grinding until the specific surface area is more than 450m 2 And (3) adding the water reducer and the dispersing agent into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
The invention has outstanding substantive characteristics and remarkable progress that:
1. the early strength agent is realized by the modified gehlenite generated in a sintering system, the hydration reaction is rapid, and the structure of a hydration product is compact, so that the system has the advantage of high early strength;
2. according to the early strength agent, the iron tailings are used as a main body, the carbide slag is used as an alkali activator, the coal gangue is used as a dry system to add Mg element, and the modified geilite is generated through an activation reaction;
3. the early strength agent raw material system contains a large amount of iron phases and Mg elements, so that the viscosity of a liquid phase can be reduced, silicate phases can be generated in advance, the calcination temperature of clinker of the system is low, and the emission of greenhouse gases can be greatly reduced;
4. the invention adopts water quenching blast furnace granulated slag, iron tailings, carbide slag, coal gangue and high collar soil to replace cement clinker, thereby achieving the purposes of protecting environment, saving resources and developing low-carbon economy; the cement clinker has low carbon, early strength, rapid hardening and continuous increase of later strength, greatly reduces the mixing proportion of the cement clinker in the high-performance self-leveling cement, and has obvious economic effect;
5. the mortar slurry structure prepared by the high-performance self-leveling cement has good suspension property, high fluidity, no layering, no bleeding, no segregation, high mortar strength, high bonding strength, good water retention and specific surface area of cement more than 450m 2 And the powder fineness is high, so that the strength of the cement is improved.
Detailed Description
The present invention will be described in further detail by way of examples, but the scope of the present invention is not limited to the above description;
the early strength agents used in the following examples are shown in the following table:
mixing and static-pressure molding iron tailings, carbide slag and coal gangue, placing the mixture in a kiln with ventilation facilities, heating the mixture to 800 ℃ at 10 ℃/min, keeping the temperature for 2 hours, and taking out the mixture for natural cooling to obtain the coal gangue, wherein the coal gangue is the coal gangue subjected to vector burning treatment;
example 1
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 1, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 Adding 0.1 part of polycarboxylate water reducer and 0.06 part of citric acid into a cement mill, and obtaining the high-performance self-contained mixed material from the head of the cement millLeveling the cement.
Example 2
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 1, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 And (3) adding 0.15 part of the polycarboxylate water reducer and 0.08 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 3
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 2, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 And (3) adding 0.1 part of the polycarboxylate water reducer and 0.06 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 4
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 2, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 And (3) adding 0.15 part of the polycarboxylate water reducer and 0.08 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 5
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 3, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 And (3) adding 0.1 part of the polycarboxylate water reducer and 0.06 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 6
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 3, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 Adding 0.15 part of polycarboxylate water reducer and 0.08 part of citric acid into a cement mill, and obtaining the final productThe mixed material from the head is the high-performance self-leveling cement.
Table 1 high performance self-leveling cement performance test table
Table 2 high performance self-leveling cement workability table
The high-performance self-leveling cement prepared in the embodiment cases 1-6 is used for preparing self-leveling mortar, and the self-leveling mortar with good fluidity, high 24h strength, high wear resistance and high bonding performance can be obtained.
Claims (5)
1. The high-performance self-leveling cement is characterized by comprising the following components in parts by weight: 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of higher collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent.
2. The high performance self-leveling cement of claim 1, wherein: the early strength agent is prepared by mixing 50-60% of iron tailings, 30-40% of carbide slag and 10-15% of coal gangue, performing static pressure molding, placing the mixture in a kiln with ventilation facilities, heating the mixture to 750-850 ℃ at 10 ℃/min, keeping the temperature for 2 hours, and taking out and naturally cooling the mixture, wherein the coal gangue is the coal gangue subjected to vector burning treatment.
3. The high performance self-leveling cement of claim 1, wherein: c in Portland cement clinker 3 The S content is 70-85%.
4. The high performance self-leveling cement of claim 1, wherein: the gypsum is natural dihydrate gypsum, the water reducing agent is a polycarboxylate water reducing agent, and the dispersing agent is citric acid.
5. A method for preparing the high-performance self-leveling cement according to any one of claims 1 to 4, which is characterized in that: the silicate cement clinker, the granulated slag of the water quenching blast furnace, the early strength agent and the high collar soil are put into a cement mill to be ground until the specific surface area is more than 450m 2 And (3) adding the water reducer and the dispersing agent into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
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---|---|---|---|---|
CN1238312A (en) * | 1998-06-08 | 1999-12-15 | 曹龙 | High-efficiency cement |
CN101337779A (en) * | 2008-07-11 | 2009-01-07 | 南京师范大学 | Additive of composite portland cement and producing method thereof |
CN102701694A (en) * | 2012-05-17 | 2012-10-03 | 同济大学 | Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof |
CN103664026A (en) * | 2013-11-25 | 2014-03-26 | 武汉理工大学 | Concrete-used modifier of metakaolin base slurry state and preparation method thereof |
CN104876627A (en) * | 2014-09-22 | 2015-09-02 | 河北工程大学 | Method for preparing aerated concrete from gangue and iron tailings |
WO2018166221A1 (en) * | 2017-03-17 | 2018-09-20 | 山东大学 | System and method for co-treating organic wastewater and industrial solid waste |
-
2023
- 2023-03-03 CN CN202310193289.2A patent/CN116409947A/en active Pending
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---|---|---|---|---|
CN1238312A (en) * | 1998-06-08 | 1999-12-15 | 曹龙 | High-efficiency cement |
CN101337779A (en) * | 2008-07-11 | 2009-01-07 | 南京师范大学 | Additive of composite portland cement and producing method thereof |
CN102701694A (en) * | 2012-05-17 | 2012-10-03 | 同济大学 | Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof |
CN103664026A (en) * | 2013-11-25 | 2014-03-26 | 武汉理工大学 | Concrete-used modifier of metakaolin base slurry state and preparation method thereof |
CN104876627A (en) * | 2014-09-22 | 2015-09-02 | 河北工程大学 | Method for preparing aerated concrete from gangue and iron tailings |
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Title |
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