CN116409947A - High-performance self-leveling cement and preparation method thereof - Google Patents

High-performance self-leveling cement and preparation method thereof Download PDF

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Publication number
CN116409947A
CN116409947A CN202310193289.2A CN202310193289A CN116409947A CN 116409947 A CN116409947 A CN 116409947A CN 202310193289 A CN202310193289 A CN 202310193289A CN 116409947 A CN116409947 A CN 116409947A
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parts
cement
leveling
performance self
early strength
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赵龑
魏兴
夏举佩
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • C04B7/153Mixtures thereof with other inorganic cementitious materials or other activators
    • C04B7/21Mixtures thereof with other inorganic cementitious materials or other activators with calcium sulfate containing activators
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/0028Aspects relating to the mixing step of the mortar preparation
    • C04B40/0039Premixtures of ingredients
    • C04B40/0046Premixtures of ingredients characterised by their processing, e.g. sequence of mixing the ingredients when preparing the premixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/10Accelerators; Activators
    • C04B2103/14Hardening accelerators
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to high-performance self-leveling cement, which comprises the following components in parts by weight: 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of high collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent; the invention adopts water quenching blast furnace granulated slag, iron tailings, carbide slag, coal gangue and high collar soil to replace cement clinker, thereby achieving the purposes of protecting environment, saving resources and developing low-carbon economy; the high-performance self-leveling water prepared by the method has good rheological property, can be used in the fields of quick ground repair and the like, can greatly reduce the mixing proportion of clinker in high-performance early strength cement, and has remarkable economic effect.

Description

High-performance self-leveling cement and preparation method thereof
Technical Field
The invention belongs to the technical fields of building material production and industrial solid waste resource utilization, and particularly relates to high-performance early-strength self-leveling cement and a preparation method thereof.
Background
For a long time, cement is used as an important cementing material and is widely applied to civil construction, water conservancy, national defense and other projects.
The cement-based self-leveling mortar is a ground leveling decorative material prepared by taking special cement, ordinary Portland cement and gypsum as cementing materials and adding fillers and various additives, can quickly and efficiently level the ground, has the characteristics of good leveling property, high early strength, easiness in laying, high construction speed, short construction period and the like, is widely applied to industrial plants, parking lots, public grounds and the like, and is also a decorative material of modern buildings, and has great market potential. At present, domestic cement-based self-leveling mortar mainly has the problems of low early strength, surface ashing, wear resistance, shrinkage cracking caused by chemical reaction shrinkage and the like.
The technical staff in the field are dedicated to developing a preparation method of high-performance self-leveling cement, so that the prepared self-leveling cement has good rheological property, high early strength, proper setting time, strong wear resistance and good shrinkage performance, the cement-based self-leveling cement is guaranteed to have effective operation time, construction can be performed quickly and efficiently, the setting speed is high, and the purposes of recycling, production cost saving, quick input and use and construction cost saving are achieved.
Disclosure of Invention
The invention provides a cement-based self-leveling agent which has good rheological property, high early strength, proper setting time, strong wear resistance and good shrinkage performance, ensures that cement-based self-leveling has effective operation time, can perform construction quickly and efficiently, has good setting speed, and achieves the purposes of recycling, saving production cost, quick application and construction cost saving.
In order to achieve the aim, the high-performance self-leveling cement comprises 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of high collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent in parts by weight.
The early strength agent is prepared by mixing 50-60% of iron tailings, 30-40% of carbide slag and 10-15% of coal gangue, carrying out static pressure molding, placing the mixture in a kiln with a ventilation facility, heating the mixture to 750-850 ℃ at a constant temperature of 10 ℃/min, taking out and naturally cooling the mixture, wherein the coal gangue is the coal gangue subjected to vector burning treatment, and the coal gangue subjected to vector burning treatment can discharge vulcanized gas, so that the problem of incomplete reaction caused by cracking in the firing process of the early strength agent is avoided.
C in the Portland cement clinker 3 The S content is 70-85%, the gypsum is natural dihydrate gypsum, the water reducer is a polycarboxylate water reducer, and the dispersing agent is citric acid.
The iron tailings are residues left after iron ore is subjected to magnetic separation to obtain iron ore fine powder, and the residues are rich in chemical compositions such as ferric oxide, silicon dioxide, aluminum oxide, calcium oxide, sodium oxide and the like.
The calcium carbide slag is waste slag which takes calcium hydroxide as a main component after calcium carbide is hydrolyzed to obtain acetylene gas, has the solid content of 12.0 percent, belongs to national class II industrial solid waste, and is directly used as an adhesive for static pressure molding because of the high calcium content to provide calcium on one hand and the high water content on the other hand.
The activity of the gangue is low, and calcination is an effective means for exciting the activity of the gangue, and aims to make each particle in the microstructure of the gangue generate intense thermal motion by utilizing high temperature, remove cations such as calcium, magnesium, iron and the like, reselect interstitial positions, so that silicon oxygen tetrahedrons and aluminum oxygen trigones cannot be fully polymerized into long chains, and a large number of breaking points of free ends are formed. The particles can no longer be arranged according to a certain rule to form a structure in a thermodynamically unstable state.
The invention also aims to provide a preparation method of the high-performance self-leveling cement, which comprises the steps of placing silicate cement clinker, water quenching blast furnace granulated slag, an early strength agent and high collar soil into a cement mill for grinding until the specific surface area is more than 450m 2 And (3) adding the water reducer and the dispersing agent into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
The invention has outstanding substantive characteristics and remarkable progress that:
1. the early strength agent is realized by the modified gehlenite generated in a sintering system, the hydration reaction is rapid, and the structure of a hydration product is compact, so that the system has the advantage of high early strength;
2. according to the early strength agent, the iron tailings are used as a main body, the carbide slag is used as an alkali activator, the coal gangue is used as a dry system to add Mg element, and the modified geilite is generated through an activation reaction;
3. the early strength agent raw material system contains a large amount of iron phases and Mg elements, so that the viscosity of a liquid phase can be reduced, silicate phases can be generated in advance, the calcination temperature of clinker of the system is low, and the emission of greenhouse gases can be greatly reduced;
4. the invention adopts water quenching blast furnace granulated slag, iron tailings, carbide slag, coal gangue and high collar soil to replace cement clinker, thereby achieving the purposes of protecting environment, saving resources and developing low-carbon economy; the cement clinker has low carbon, early strength, rapid hardening and continuous increase of later strength, greatly reduces the mixing proportion of the cement clinker in the high-performance self-leveling cement, and has obvious economic effect;
5. the mortar slurry structure prepared by the high-performance self-leveling cement has good suspension property, high fluidity, no layering, no bleeding, no segregation, high mortar strength, high bonding strength, good water retention and specific surface area of cement more than 450m 2 And the powder fineness is high, so that the strength of the cement is improved.
Detailed Description
The present invention will be described in further detail by way of examples, but the scope of the present invention is not limited to the above description;
the early strength agents used in the following examples are shown in the following table:
Figure SMS_1
mixing and static-pressure molding iron tailings, carbide slag and coal gangue, placing the mixture in a kiln with ventilation facilities, heating the mixture to 800 ℃ at 10 ℃/min, keeping the temperature for 2 hours, and taking out the mixture for natural cooling to obtain the coal gangue, wherein the coal gangue is the coal gangue subjected to vector burning treatment;
example 1
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 1, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 Adding 0.1 part of polycarboxylate water reducer and 0.06 part of citric acid into a cement mill, and obtaining the high-performance self-contained mixed material from the head of the cement millLeveling the cement.
Example 2
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 1, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 And (3) adding 0.15 part of the polycarboxylate water reducer and 0.08 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 3
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 2, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 And (3) adding 0.1 part of the polycarboxylate water reducer and 0.06 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 4
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 2, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 And (3) adding 0.15 part of the polycarboxylate water reducer and 0.08 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 5
45 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 10 parts of early strength agent No. 3, 10 parts of high collar soil and 10 parts of dihydrate gypsum are mixed and put into a cement mill together until the specific surface area is more than 450m 2 And (3) adding 0.1 part of the polycarboxylate water reducer and 0.06 part of the citric acid into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
Example 6
40 parts of silicate clinker, 25 parts of granulated slag of a water quenching blast furnace, 20 parts of early strength agent No. 3, 10 parts of high collar soil, 5 parts of dihydrate gypsum are mixed and put into a cement mill together to be ground until the specific surface area is more than 450m 2 Adding 0.15 part of polycarboxylate water reducer and 0.08 part of citric acid into a cement mill, and obtaining the final productThe mixed material from the head is the high-performance self-leveling cement.
Table 1 high performance self-leveling cement performance test table
Figure SMS_2
Table 2 high performance self-leveling cement workability table
Figure SMS_3
The high-performance self-leveling cement prepared in the embodiment cases 1-6 is used for preparing self-leveling mortar, and the self-leveling mortar with good fluidity, high 24h strength, high wear resistance and high bonding performance can be obtained.

Claims (5)

1. The high-performance self-leveling cement is characterized by comprising the following components in parts by weight: 40-50 parts of silicate cement clinker, 25 parts of water quenching blast furnace granulated slag, 10-20 parts of early strength agent, 10 parts of higher collar soil, 5-10 parts of gypsum, 0.1-0.15 part of water reducer and 0.06-0.08 part of dispersing agent.
2. The high performance self-leveling cement of claim 1, wherein: the early strength agent is prepared by mixing 50-60% of iron tailings, 30-40% of carbide slag and 10-15% of coal gangue, performing static pressure molding, placing the mixture in a kiln with ventilation facilities, heating the mixture to 750-850 ℃ at 10 ℃/min, keeping the temperature for 2 hours, and taking out and naturally cooling the mixture, wherein the coal gangue is the coal gangue subjected to vector burning treatment.
3. The high performance self-leveling cement of claim 1, wherein: c in Portland cement clinker 3 The S content is 70-85%.
4. The high performance self-leveling cement of claim 1, wherein: the gypsum is natural dihydrate gypsum, the water reducing agent is a polycarboxylate water reducing agent, and the dispersing agent is citric acid.
5. A method for preparing the high-performance self-leveling cement according to any one of claims 1 to 4, which is characterized in that: the silicate cement clinker, the granulated slag of the water quenching blast furnace, the early strength agent and the high collar soil are put into a cement mill to be ground until the specific surface area is more than 450m 2 And (3) adding the water reducer and the dispersing agent into a cement mill, and obtaining the high-performance self-leveling cement from the mixed material from the head of the cement mill.
CN202310193289.2A 2023-03-03 2023-03-03 High-performance self-leveling cement and preparation method thereof Pending CN116409947A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1238312A (en) * 1998-06-08 1999-12-15 曹龙 High-efficiency cement
CN101337779A (en) * 2008-07-11 2009-01-07 南京师范大学 Additive of composite portland cement and producing method thereof
CN102701694A (en) * 2012-05-17 2012-10-03 同济大学 Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof
CN103664026A (en) * 2013-11-25 2014-03-26 武汉理工大学 Concrete-used modifier of metakaolin base slurry state and preparation method thereof
CN104876627A (en) * 2014-09-22 2015-09-02 河北工程大学 Method for preparing aerated concrete from gangue and iron tailings
WO2018166221A1 (en) * 2017-03-17 2018-09-20 山东大学 System and method for co-treating organic wastewater and industrial solid waste

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1238312A (en) * 1998-06-08 1999-12-15 曹龙 High-efficiency cement
CN101337779A (en) * 2008-07-11 2009-01-07 南京师范大学 Additive of composite portland cement and producing method thereof
CN102701694A (en) * 2012-05-17 2012-10-03 同济大学 Non-calcined desulfurization gypsum hydraulic compound gel system and quick steam-curing process thereof
CN103664026A (en) * 2013-11-25 2014-03-26 武汉理工大学 Concrete-used modifier of metakaolin base slurry state and preparation method thereof
CN104876627A (en) * 2014-09-22 2015-09-02 河北工程大学 Method for preparing aerated concrete from gangue and iron tailings
WO2018166221A1 (en) * 2017-03-17 2018-09-20 山东大学 System and method for co-treating organic wastewater and industrial solid waste

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张伟: "《高性能水泥基材料应用技术》", 31 August 2017, 中国建材工业出版社, pages: 157 *

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