CN116178031A - Insulating layer castable for aluminum ash rotary kiln and preparation method thereof - Google Patents

Insulating layer castable for aluminum ash rotary kiln and preparation method thereof Download PDF

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Publication number
CN116178031A
CN116178031A CN202211685836.0A CN202211685836A CN116178031A CN 116178031 A CN116178031 A CN 116178031A CN 202211685836 A CN202211685836 A CN 202211685836A CN 116178031 A CN116178031 A CN 116178031A
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equal
castable
rotary kiln
granularity
insulating layer
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Inventor
马四凯
李洪波
李维锋
李勇伟
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Shanghai Xintaishan High Temperature Engineering Material Co ltd
Shanghai Lier Refractory Material Co ltd
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Shanghai Xintaishan High Temperature Engineering Material Co ltd
Shanghai Lier Refractory Material Co ltd
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Priority to CN202211685836.0A priority Critical patent/CN116178031A/en
Publication of CN116178031A publication Critical patent/CN116178031A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/08Producing shaped prefabricated articles from the material by vibrating or jolting
    • B28B1/087Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould
    • B28B1/0873Producing shaped prefabricated articles from the material by vibrating or jolting by means acting on the mould ; Fixation thereof to the mould the mould being placed on vibrating or jolting supports, e.g. moulding tables
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B11/00Apparatus or processes for treating or working the shaped or preshaped articles
    • B28B11/24Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
    • B28B11/243Setting, e.g. drying, dehydrating or firing ceramic articles
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/04Clay; Kaolin
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/131Inorganic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00Clay-wares
    • C04B33/02Preparing or treating the raw materials individually or as batches
    • C04B33/13Compounding ingredients
    • C04B33/132Waste materials; Refuse; Residues
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/66Monolithic refractories or refractory mortars, including those whether or not containing clay
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3217Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/44Metal salt constituents or additives chosen for the nature of the anions, e.g. hydrides or acetylacetonate
    • C04B2235/447Phosphates or phosphites, e.g. orthophosphate, hypophosphite
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74Physical characteristics
    • C04B2235/77Density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607Thermal properties, e.g. thermal expansion coefficient
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/60Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Ceramic Products (AREA)

Abstract

The invention discloses an insulating layer castable for an aluminum ash rotary kiln and a preparation method thereof, wherein the insulating layer castable comprises the following raw materials in percentage by mass: 36-73% of flint clay, 5-20% of bauxite, 1-10% of silica powder, 20-30% of 725 cement and 2-18% of Guangxi white mud; and the additive sodium tripolyphosphate accounts for 0.1 to 0.4 percent of the total mass of the raw materials. The heat-insulating layer castable has the advantages of low volume density, low heat conductivity and high refractoriness, and can obviously improve heat-insulating performance and reduce heat dissipation when used at the heat-insulating layer part of the aluminum ash rotary kiln, thereby bringing considerable economic benefit.

Description

Insulating layer castable for aluminum ash rotary kiln and preparation method thereof
Technical Field
The invention relates to the field of refractory materials, in particular to an insulating layer castable for an aluminum ash rotary kiln and a preparation method thereof.
Background
The aluminum ash is scum generated when molten aluminum is smelted in a casting furnace, is industrial waste which directly or indirectly damages the environment, and is a renewable resource which can be comprehensively utilized. The aluminum slag is treated by ash treatment complete equipment such as a rotary kiln, a cold ash cylinder, an ash sieving machine and the like, so that the burning loss of aluminum in the aluminum slag can be reduced, the aluminum in the slag can be recovered, and waste is changed into valuable. The rotary kiln has high efficiency and high mechanization degree, and is a common method for treating aluminum ash for large enterprises.
The traditional insulating layer castable for the aluminum ash rotary kiln has the characteristics of low porosity, high density and high heat conductivity, so that the shell of the rotary kiln is higher in temperature, quicker in heat dissipation and increased in energy consumption cost in use, and is contrary to the current energy conservation and consumption reduction. The aluminum ash rotary kiln heat insulation layer has the characteristics of moderate porosity, low volume density, low heat conductivity and high refractoriness, and can obviously improve heat insulation performance and reduce heat dissipation when being used at the heat insulation layer part of the aluminum ash rotary kiln, thereby bringing considerable economic benefit.
Disclosure of Invention
The invention aims to solve the defects of the technical problems, and provides an insulating layer castable for an aluminum ash rotary kiln and a preparation method thereof.
In order to solve the defects of the technical problems, the invention adopts the following technical scheme:
the invention discloses an insulating layer castable for an aluminum ash rotary kiln, which is characterized by comprising the following raw materials in parts by mass: 36-73% of flint clay, 5-20% of bauxite, 1-10% of silica powder, 20-30% of 725 cement and 2-18% of Guangxi white mud; sodium tripolyphosphate as an additive accounting for 0.1-0.4% of the total mass of the raw materials;
the flint clay contains more than or equal to 45% of aluminum oxide, less than or equal to 1.2% of ferric oxide, and the volume density of the flint clay is more than or equal to 2.5g/cm 3 The granularity is 5-3mm, 3-1mm, 1-0mm and more than or equal to 200 meshes respectively;
the alumina contains more than or equal to 60% of aluminum oxide by mass, and the granularity of the alumina is more than or equal to 325 meshes;
the silicon micro powder contains more than or equal to 95% of silicon dioxide and less than or equal to 1% of ferric oxide by mass, and the PH value is 5-8;
the 725 cement is cement with the label of 725, and contains more than or equal to 50% of aluminum oxide, less than or equal to 2.5% of ferric oxide and less than or equal to 8% of silicon dioxide by mass;
the Guangxi white clay is soft spherical refractory clay containing more than or equal to 31% of aluminum oxide and less than or equal to 55% of silicon dioxide.
More specifically, the insulating layer castable for the aluminum ash rotary kiln comprises the following raw materials in percentage by mass: 10-20% of flint clay with granularity of 5-3mm, 10-25% of flint clay with granularity of 3-1mm, 8-15% of flint clay with granularity of 1-0mm and 8-13% of flint clay with granularity of more than or equal to 200 meshes; 5-20% of bauxite with particle size of more than or equal to 325 meshes, 1-10% of silica micropowder, 20-30% of 725 cement and 2-18% of Guangxi white mud; and the additive sodium tripolyphosphate accounts for 0.1 to 0.4 percent of the total mass of the raw materials.
The invention relates to a preparation method of an insulating layer castable for an aluminum ash rotary kiln, which is characterized by comprising the following steps:
(1) The flint clay with granularity of 5-3mm, 3-1mm and 1-0mm is used as aggregate of the castable of the heat insulation layer, and other raw materials are powder materials;
(2) Firstly, adding all powder materials into a stirrer, and dry-mixing for at least 30 seconds; adding all aggregate, and continuously dry-mixing for at least 30 seconds; adding a proper amount of water, wet mixing for 120-180 seconds to uniformly stir the materials, and then vibrating and forming the materials on a vibrating table to prepare a strip-shaped sample;
(3) Naturally drying the sample at room temperature for 24 hours, demoulding, and drying at 105-110 ℃ for 20-30 hours to obtain the heat preservation castable.
Compared with the prior art, the invention has the following advantages:
the heat-insulating layer castable has the advantages of low volume density, low heat conductivity and high refractoriness, and can obviously improve heat-insulating performance and reduce heat dissipation when used at the heat-insulating layer part of the aluminum ash rotary kiln, thereby bringing considerable economic benefit.
Detailed Description
The invention is further illustrated by the following specific embodiments, which are intended to be illustrative of the invention and not limiting.
Example 1
The insulating layer castable for the aluminum ash rotary kiln comprises the following components in parts by mass: 15% of flint clay with granularity of 5-3mm, 15% of flint clay with granularity of 3-1mm, 12% of flint clay with granularity of 1-0mm, 12% of flint clay with granularity of more than or equal to 200 meshes, 12% of alumina with granularity of 325 meshes, 6% of silica powder, 26% of 725 cement and 3% of Guangxi white mud; an additive sodium tripolyphosphate accounting for 0.2% of the total mass of the raw materials;
the preparation method comprises the following steps:
(1) The flint clay with granularity of 5-3mm, 3-1mm and 1-0mm is used as aggregate of the castable of the heat insulation layer, and other raw materials are powder materials;
(2) Firstly, adding all powder materials into a stirrer, and dry-mixing for 30 seconds; adding all aggregate, and continuously dry-mixing for 30 seconds; adding a proper amount of water, wet mixing for 120 seconds to uniformly stir the materials, and vibrating the materials on a vibrating table for 60 seconds to form a strip sample with the thickness of 40mm multiplied by 160 mm;
(3) And naturally drying the sample at room temperature for 24 hours, demolding, and then preserving heat at 110 ℃ for 24 hours to obtain the heat preservation castable.
Example 2
The insulating layer castable for the aluminum ash rotary kiln comprises the following components in parts by mass: 15% of flint clay with granularity of 5-3mm, 25% of flint clay with granularity of 3-1mm, 8% of flint clay with granularity of 1-0mm and 8% of flint clay with granularity of more than or equal to 200 meshes; alumina with granularity of 325 meshes 10%, silicon micropowder 6%,725 cement 25% and Guangxi white mud 3%; an additive sodium tripolyphosphate accounting for 0.2% of the total mass of the raw materials; the preparation method is the same as in example 1.
Example 3
The insulating layer castable for the aluminum ash rotary kiln comprises the following components in parts by mass: 10% of flint clay with granularity of 5-3mm, 20% of flint clay with granularity of 3-1mm, 15% of flint clay with granularity of 1-0mm and 13% of flint clay with granularity of more than or equal to 200 meshes; alumina with granularity of 325 meshes is 8%, silica micropowder is 6%,725 cement is 25% and Guangxi white mud is 3%; an additive sodium tripolyphosphate accounting for 0.2% of the total mass of the raw materials; the preparation method is the same as in example 1.
Example 4
The insulating layer castable for the aluminum ash rotary kiln comprises the following components in parts by mass: 20% of flint clay with granularity of 5-3mm, 10% of flint clay with granularity of 3-1mm, 10% of flint clay with granularity of 1-0mm and 10% of flint clay with granularity of more than or equal to 200 meshes; alumina with granularity of 325 meshes 10%, silica micropowder 5%,725 cement 20% and Guangxi white mud 15%; an additive sodium tripolyphosphate accounting for 0.3 percent of the total mass of the raw materials; the preparation method is the same as in example 1.
The insulating layer castable obtained in examples 1 to 4 was examined, and the results are shown in Table 1.
Table 1 test results of the insulation castable of examples 1 to 4
Figure BDA0004020976870000051
As can be seen from Table 1, compared with the existing scheme, the volume density of the castable for the heat preservation layer prepared by the invention is lower than 1.5g/cm 3 The heat conductivity coefficient is lower than 0.7W/(m.K) at 1000 ℃, and the shell temperature of the rotary kiln is lower than 30-40 ℃ in the prior art in actual use, thus having considerable economic benefit.

Claims (7)

1. The insulating layer castable for the aluminum ash rotary kiln is characterized by comprising the following raw materials in percentage by mass: 36-73% of flint clay, 5-20% of bauxite, 1-10% of silica powder, 20-30% of 725 cement and 2-18% of Guangxi white mud; and the additive sodium tripolyphosphate accounts for 0.1 to 0.4 percent of the total mass of the raw materials.
2. The castable for the heat insulation layer for the aluminum ash rotary kiln according to claim 1, wherein the flint clay contains more than or equal to 45% of aluminum oxide, less than or equal to 1.2% of ferric oxide, and has a volume density of more than or equal to 2.5g/cm 3 The granularity is 5-3mm, 3-1mm, 1-0mm and more than or equal to 200 meshes respectively.
3. The castable for the heat insulation layer for the aluminum ash rotary kiln according to claim 1, wherein the alumina contains more than or equal to 60% by mass of aluminum oxide, and the granularity of the alumina is more than or equal to 325 meshes; the silicon micropowder contains more than or equal to 95% of silicon dioxide and less than or equal to 1% of ferric oxide by mass, and the PH value is 5-8.
4. The castable for the insulating layer for the aluminum ash rotary kiln according to claim 1, wherein 725 cement is cement with a label of 725, and contains more than or equal to 50% of aluminum oxide, less than or equal to 2.5% of ferric oxide and less than or equal to 8% of silicon dioxide by mass.
5. The castable for the heat insulation layer for the aluminum ash rotary kiln according to claim 1, wherein the Guangxi white clay is soft spherical refractory clay containing more than or equal to 31% of aluminum oxide and less than or equal to 55% of silicon dioxide.
6. The castable for the heat insulation layer for the aluminum ash rotary kiln according to claim 1, wherein flint clay with the granularity of 5-3mm is 10-20%, flint clay with the granularity of 3-1mm is 10-25%, flint clay with the granularity of 1-0mm is 8-15%, and flint clay with the granularity of more than or equal to 200 meshes is 8-13%; 5-20% of bauxite with particle size of more than or equal to 325 meshes, 1-10% of silica micropowder, 20-30% of 725 cement and 2-18% of Guangxi white mud; and the additive sodium tripolyphosphate accounts for 0.1 to 0.4 percent of the total mass of the raw materials.
7. The method for preparing the insulating layer castable for the aluminum ash rotary kiln according to any one of claims 1 to 6, characterized by comprising the following steps:
(1) The flint clay with granularity of 5-3mm, 3-1mm and 1-0mm is used as aggregate of the castable of the heat insulation layer, and other raw materials are powder materials;
(2) Firstly, adding all powder materials into a stirrer, and dry-mixing for at least 30 seconds; adding all aggregate, and continuously dry-mixing for at least 30 seconds; adding a proper amount of water, wet mixing for 120-180 seconds to uniformly stir the materials, and then vibrating and forming the materials on a vibrating table to prepare a strip-shaped sample;
(3) Naturally drying the sample at room temperature for 24 hours, demoulding, and drying at 105-110 ℃ for 20-30 hours to obtain the heat preservation castable.
CN202211685836.0A 2022-12-27 2022-12-27 Insulating layer castable for aluminum ash rotary kiln and preparation method thereof Pending CN116178031A (en)

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Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591180A (en) * 2008-05-30 2009-12-02 北京通达耐火技术股份有限公司 A kind of preparation method of light alkali-resistant refractory castable
CN102976771A (en) * 2012-11-16 2013-03-20 宜兴天霸非金属材料有限公司 High temperature resistant lightweight heat insulation castables
CN103468239A (en) * 2013-09-24 2013-12-25 淄博嘉丰矿业有限公司 Low-density high-strength ceramsite proppant prepared from flint clay as raw material and preparation method thereof
CN104193354A (en) * 2014-08-08 2014-12-10 上海利尔耐火材料有限公司 Permanent layer casting material of tundish and preparation method of permanent layer casting material
CN105503209A (en) * 2015-12-16 2016-04-20 武汉科技大学 Mullite light heat-insulation brick based on flint clay and preparation method of brick
CN105645936A (en) * 2016-01-11 2016-06-08 武汉科技大学 High-aluminum hollow sphere light-weight castable and preparation method thereof
CN107344857A (en) * 2017-06-20 2017-11-14 长兴兴鹰新型耐火建材有限公司 A kind of high-strength low heat conductivity fire resisting energy-conservation castable and preparation method thereof
CN107573098A (en) * 2017-09-01 2018-01-12 武汉钢铁有限公司 A kind of lightweight castable for sintering ignition furnace
CN108117400A (en) * 2017-11-17 2018-06-05 济源市耐火炉业有限公司 Light weight alumina refractory brick and preparation method thereof
CN110511044A (en) * 2018-05-21 2019-11-29 济源市涟源炉业有限公司 A kind of antiseepage castable and preparation method thereof
CN111978090A (en) * 2020-09-04 2020-11-24 沈阳绿冶新材科技有限公司 Aluminum-silicon light refractory castable and preparation method thereof
CN114292118A (en) * 2022-02-23 2022-04-08 上海利尔耐火材料有限公司 Long-life castable for waste incinerator and preparation method thereof

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101591180A (en) * 2008-05-30 2009-12-02 北京通达耐火技术股份有限公司 A kind of preparation method of light alkali-resistant refractory castable
CN102976771A (en) * 2012-11-16 2013-03-20 宜兴天霸非金属材料有限公司 High temperature resistant lightweight heat insulation castables
CN103468239A (en) * 2013-09-24 2013-12-25 淄博嘉丰矿业有限公司 Low-density high-strength ceramsite proppant prepared from flint clay as raw material and preparation method thereof
CN104193354A (en) * 2014-08-08 2014-12-10 上海利尔耐火材料有限公司 Permanent layer casting material of tundish and preparation method of permanent layer casting material
CN105503209A (en) * 2015-12-16 2016-04-20 武汉科技大学 Mullite light heat-insulation brick based on flint clay and preparation method of brick
CN105645936A (en) * 2016-01-11 2016-06-08 武汉科技大学 High-aluminum hollow sphere light-weight castable and preparation method thereof
CN107344857A (en) * 2017-06-20 2017-11-14 长兴兴鹰新型耐火建材有限公司 A kind of high-strength low heat conductivity fire resisting energy-conservation castable and preparation method thereof
CN107573098A (en) * 2017-09-01 2018-01-12 武汉钢铁有限公司 A kind of lightweight castable for sintering ignition furnace
CN108117400A (en) * 2017-11-17 2018-06-05 济源市耐火炉业有限公司 Light weight alumina refractory brick and preparation method thereof
CN110511044A (en) * 2018-05-21 2019-11-29 济源市涟源炉业有限公司 A kind of antiseepage castable and preparation method thereof
CN111978090A (en) * 2020-09-04 2020-11-24 沈阳绿冶新材科技有限公司 Aluminum-silicon light refractory castable and preparation method thereof
CN114292118A (en) * 2022-02-23 2022-04-08 上海利尔耐火材料有限公司 Long-life castable for waste incinerator and preparation method thereof

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