CN116121603A - Siliconized steel aluminum material - Google Patents
Siliconized steel aluminum material Download PDFInfo
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- CN116121603A CN116121603A CN202310055996.5A CN202310055996A CN116121603A CN 116121603 A CN116121603 A CN 116121603A CN 202310055996 A CN202310055996 A CN 202310055996A CN 116121603 A CN116121603 A CN 116121603A
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- 239000000463 material Substances 0.000 title claims abstract description 29
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 26
- 239000010959 steel Substances 0.000 title claims abstract description 26
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 24
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 20
- 239000002103 nanocoating Substances 0.000 claims abstract description 29
- 239000000758 substrate Substances 0.000 claims abstract description 20
- 229910021332 silicide Inorganic materials 0.000 claims abstract description 16
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011159 matrix material Substances 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 8
- -1 polysiloxane Polymers 0.000 claims abstract description 8
- 229910000838 Al alloy Inorganic materials 0.000 claims abstract description 7
- 229910000975 Carbon steel Inorganic materials 0.000 claims abstract description 7
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000010962 carbon steel Substances 0.000 claims abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 7
- 229920001709 polysilazane Polymers 0.000 claims abstract description 7
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 229920006217 cellulose acetate butyrate Polymers 0.000 claims abstract description 4
- 229910052681 coesite Inorganic materials 0.000 claims abstract description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims abstract description 4
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 4
- 229920000570 polyether Polymers 0.000 claims abstract description 4
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 4
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 4
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 4
- 229910052682 stishovite Inorganic materials 0.000 claims abstract description 4
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 4
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 4
- 229910052905 tridymite Inorganic materials 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 33
- 239000011248 coating agent Substances 0.000 claims description 29
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- LKTZODAHLMBGLG-UHFFFAOYSA-N alumanylidynesilicon;$l^{2}-alumanylidenesilylidenealuminum Chemical compound [Si]#[Al].[Si]#[Al].[Al]=[Si]=[Al] LKTZODAHLMBGLG-UHFFFAOYSA-N 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 238000005475 siliconizing Methods 0.000 claims description 6
- 239000004519 grease Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 239000012670 alkaline solution Substances 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000003449 preventive effect Effects 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 229910052727 yttrium Inorganic materials 0.000 claims description 3
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 238000004383 yellowing Methods 0.000 abstract description 12
- 229910052751 metal Inorganic materials 0.000 description 22
- 239000002184 metal Substances 0.000 description 22
- 239000010410 layer Substances 0.000 description 16
- 230000000052 comparative effect Effects 0.000 description 8
- 238000010411 cooking Methods 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000004075 alteration Effects 0.000 description 2
- 239000011247 coating layer Substances 0.000 description 2
- 230000036541 health Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 238000007792 addition Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/16—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers in which all the silicon atoms are connected by linkages other than oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/02—Alloys based on aluminium with silicon as the next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0806—Silver
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0812—Aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0881—Titanium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
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- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a siliconized steel aluminum material, which comprises the following components: the matrix is carbon steel or aluminum alloy; a nanocoating comprising the following components: 35-42 parts of n-butyl acetate, 7-9 parts of cellulose acetate butyrate, 10-20 parts of polysilazane solution with the mass concentration of 20-35%, 3-8 parts of polyether modified polysiloxane, 2-3 parts of 3-aminopropyl triethoxysilane, 3-8 parts of thermoplastic acrylic ester, 2-10 parts of PMMA coated nano silver and 5-10 parts of nano alumina sol; 5-8 parts of SiO2 coated nano aluminum powder and 5-8 parts of calcium carbonate coated nano titanium powder; and the silicide layer is etched into the substrate, and the surface of the substrate is modified to obtain the silicide layer. The nano coating is etched into steel or aluminum to modify the matrix and generate a silicide layer, and has the characteristics of no yellowing caused by burning, easy cleaning and scratch resistance.
Description
Technical Field
The invention relates to the technical field of nano coating materials, in particular to a siliconized steel aluminum material.
Background
The application of a cover layer protection on a metal surface is a major means of protecting the metal from corrosion, i.e. a coating treatment of the metal. The coating serves to isolate the metal from the surrounding air and prevent or reduce corrosion. The cover layer also has a certain functionality.
However, in the coating process, the coating belongs to an organic coating, so that the binding force between the coating and metal is poor, the metal surface needs to be pretreated before coating, the coating layer on the metal surface can improve the adhesive force of the coating on the metal surface, and the metal coating quality is ensured.
In the related art, people fry food with a metal product pot. However, the metal pan has the problems of easy food sticking, burning and other phenomena, and the health of human body is endangered. For example, woks are mainly used for frying or frying food, but may also be used for steaming, stewing, frying and other different cooking methods. And after the frying pan finishes cooking, the residual grease and dirt in the inner cavity of the frying pan are troublesome to clean, and particularly the phenomenon of yellowing caused by high temperature occurs at a local position, so that great inconvenience is brought to a user, and the experience is poor.
Disclosure of Invention
The present invention aims to solve at least one of the technical problems existing in the prior art. Therefore, the invention provides the siliconized steel aluminum material, which has the characteristics of no yellowing caused by burning, easy cleaning and scratch resistance.
According to an embodiment of the invention, a steel aluminum silicide material comprises:
the matrix is carbon steel or aluminum alloy;
a nanocoating comprising the following components: 35-42 parts of n-butyl acetate, 7-9 parts of cellulose acetate butyrate, 10-20 parts of polysilazane solution with the mass concentration of 20-35%, 3-8 parts of polyether modified polysiloxane, 2-3 parts of 3-aminopropyl triethoxysilane, 3-8 parts of thermoplastic acrylic ester, 2-10 parts of PMMA coated nano silver and 5-10 parts of nano alumina sol; 5-8 parts of SiO2 coated nano aluminum powder and 5-8 parts of calcium carbonate coated nano titanium powder;
the silicide layer is used for etching the nano coating into the matrix and modifying the surface of the matrix to obtain the nano coating;
the siliconized steel aluminum material is a siliconized layer obtained by the following preparation method:
cleaning: washing a substrate by using an alkaline solution, and then washing and drying the substrate by using water;
coating: uniformly coating the nano coating on the substrate after washing and drying, and drying after coating to obtain a substrate with the nano coating on the surface;
siliconizing: the substrate with the nano coating coated on the surface obtained after coating is heated to 500-550 ℃ and the pressure is: and curing for 15-50 min at 10 Pa-150 Pa to obtain the silicide layer.
The engine case positioning tool for the chain saw has the following beneficial effects: the nano coating is etched into steel or aluminum to modify the matrix and generate a silicide layer, and has the characteristics of no yellowing caused by burning, easy cleaning and scratch resistance.
According to the siliconized steel-aluminum material, the pressure intensity in siliconizing is as follows: 75Pa to 85Pa.
According to the steel aluminum silicide material, the solvent of the polysilazane solution is one or a combination of more than one of dibutyl ether, toluene and xylene.
According to the siliconized steel aluminum material, the thickness of the nano coating is 10-15 mu m.
According to the siliconized steel-aluminum material, the thickness of the siliconized layer is 0.2-0.35 mm.
According to the steel aluminum silicide material provided by the invention, the silicide layer is one or a combination of more than one of zinc fluosilicate, sodium fluosilicate, ammonium fluosilicate, magnesium fluosilicate, potassium fluosilicate and calcium fluosilicate.
According to the siliconized steel aluminum material, the aluminum alloy material comprises the following components: silicon: 0.2-1.5%, iron: 0.1-0.3%, manganese 0.5-1.5%, yttrium: 0.005-0.025%, cerium: 0.02-0.10%, nano silver 0.2-2%, aluminum powder 0.2-2%, titanium powder 0.2-2%, and the balance of aluminum and unavoidable impurities.
According to the siliconized steel-aluminum material, the carbon steel material comprises the following components: 0.06-0.15% of carbon, 0.15-0.30% of silicon, 0.65-1.30% of manganese, less than or equal to 0.02% of phosphorus, less than or equal to 0.02% of sulfur, 0.005-0.075% of chromium, 3-10% of rust preventive grease, and the balance of iron and unavoidable impurities.
Additional aspects and advantages of the invention will be set forth in part in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention.
Detailed Description
The following are specific embodiments of the present invention, and the technical solutions of the present invention will be further described with reference to the embodiments, but the present invention is not limited to these embodiments.
The application of a cover layer protection on the metal surface is the primary means of preventing corrosion of the metal, i.e. the coating process of the metal. The coating serves to isolate the metal from the surrounding air and prevent or reduce corrosion. The cover layer also has a certain functionality. However, in the coating process, the coating belongs to an organic coating, so that the binding force between the coating and metal is poor, the metal surface needs to be pretreated before coating, the coating layer on the metal surface can improve the adhesive force of the coating on the metal surface, and the metal coating quality is ensured.
In the related art, people fry food with a metal product pot. However, the metal pan has the problems of easy food sticking, burning and other phenomena, and the health of human body is endangered. For example, woks are mainly used for frying or frying food, but may also be used for steaming, stewing, frying and other different cooking methods. And after the frying pan finishes cooking, the residual grease and dirt in the inner cavity of the frying pan are troublesome to clean, and particularly the phenomenon of yellowing caused by high temperature occurs at a local position, so that great inconvenience is brought to a user, and the experience is poor.
Therefore, the invention provides the siliconized steel aluminum material which comprises a matrix, a nano coating and a siliconized layer between the nano coating and the matrix, wherein the matrix is carbon steel or aluminum alloy, the nano coating is etched into the matrix, and the surface of the matrix is modified to obtain the siliconized layer. Specifically, the nanocoating comprises the following components: 35-42 parts of n-butyl acetate, 7-9 parts of cellulose acetate butyrate, 10-20 parts of polysilazane solution with the mass concentration of 20-35%, 3-8 parts of polyether modified polysiloxane, 2-3 parts of 3-aminopropyl triethoxysilane, 3-8 parts of thermoplastic acrylic ester, 2-10 parts of PMMA coated nano silver and 5-10 parts of nano alumina sol; 5-8 parts of SiO2 coated nano aluminum powder and 5-8 parts of calcium carbonate coated nano titanium powder.
Further, the steel aluminum silicide material is prepared by the following preparation method:
cleaning: washing a substrate by using an alkaline solution, and then washing and drying the substrate by using water;
coating: uniformly coating the nano coating on the substrate after washing and drying, and drying after coating to obtain a substrate with the nano coating on the surface;
siliconizing: the substrate with the nano coating coated on the surface obtained after coating is heated to 500-550 ℃ and the pressure is: and curing for 15-50 min at 10 Pa-150 Pa to obtain the silicide layer.
After the nano coating is etched into steel or aluminum, the substrate is modified and a silicide layer is generated, so that the nano coating has the characteristics of no yellowing caused by burning, easy cleaning and scratch resistance.
Preferably, the pressure in silicidation is: 75Pa to 85Pa.
In some embodiments, the solvent of the polysilazane solution is one or a combination of more of dibutyl ether, toluene, and xylene.
Preferably, the thickness of the nano-coating is 10 μm to 15 μm.
Preferably, the thickness of the silicide layer is 0.2mm to 0.35mm. And the silicide layer is one or a combination of more than one of zinc fluosilicate, sodium fluosilicate, ammonium fluosilicate, magnesium fluosilicate, potassium fluosilicate and calcium fluosilicate.
In some embodiments, the aluminum alloy material comprises the following composition: silicon: 0.2-1.5%, iron: 0.1-0.3%, manganese 0.5-1.5%, yttrium: 0.005-0.025%, cerium: 0.02-0.10%, nano silver 0.2-2%, aluminum powder 0.2-2%, titanium powder 0.2-2%, and the balance of aluminum and unavoidable impurities.
In some embodiments, the carbon steel material comprises the following composition: 0.06-0.15% of carbon, 0.15-0.30% of silicon, 0.65-1.30% of manganese, less than or equal to 0.02% of phosphorus, less than or equal to 0.02% of sulfur, 0.005-0.075% of chromium, 3-10% of rust preventive grease, and the balance of iron and unavoidable impurities.
Comparative example 1
Coating of stainless steel frying pan sold in market
TABLE 1
Examples 1-4 in Table 1 are all examples of the present invention, comparative example 1 is a commercially available product and is a comparative example of the present invention, and the coatings of examples 1-4 and comparative example 1 were subjected to performance tests, respectively, with the test results shown in Table 3 below, and Table 4 is the test results of aluminum steel silicide prepared in the examples of the nanocoating corresponding to Table 3.
The performance detection method and the standard are as follows:
adhesion force: measured according to the standard of GB/T9286-1998;
hardness: measured according to the GB/T6739-2006 standard:
water contact angle: measuring by a contact angle measuring instrument;
stain resistance: using oily mark strokes to be on the surface of the coating, standing for 2min, applying a certain vertical acting force on the surface by hands to wipe by using paper towels, and observing the handwriting residue condition; table 2 is an evaluation criterion of stain resistance;
TABLE 2
| Feeling strength | Wiping force | Oily pen handwriting | Stain resistance grade |
| Gently wipe without applying force | ＜1.0kg | No residue | Excellent and excellent properties |
| Wiping with little force | 1-1.5kg | No residue | Good quality |
| Forceful wiping | 1.5-5kg | No residue | Qualified product |
| Forceful wiping | 1.5-5kg | With residues | Failure to pass |
High temperature resistance and yellowing resistance: and (3) baking the sample in a high-temperature furnace at 350 ℃ for 2 hours, judging after the sample is cooled to room temperature, wherein the surface is generally blackish, reddish and yellowish after baking, namely DeltaL <0, deltaa >0 and Deltab >0, and when the visual judgment result meets the requirement, the chromatic aberration DeltaE <5 (overall chromatic aberration) and Deltab <2 (yellowing degree). Namely, when delta E is less than 5 and delta b is less than 2, the high-temperature yellowing resistance is excellent; otherwise, the high temperature yellowing resistance is not good.
TABLE 3 Table 3
Referring to Table 3, from the analysis of the test data of examples 1-4 and comparative example 1, the technical effect of example 3 on hydrophobicity was the worst among 4 groups of examples. However, as is clear from comparison of the test data of example 3 and comparative example 1, the technical solution of example 3 is significantly better than comparative example 1 in terms of both adhesion, hardness, etc., and also in terms of hydrophobicity, contamination resistance, high temperature resistance, yellowing resistance, etc. Therefore, the technical scheme of the invention has the technical effect obviously superior to that of the comparative example 1, and the nanoscale coating prepared by the technical scheme of the invention has obvious improvement on the aspects of adhesive force, hardness, hydrophobicity, pollution resistance, high-temperature resistance, yellowing resistance and the like, and can effectively solve the problems in the prior art.
TABLE 4 Table 4
After adjusting the curing temperature, curing pressure and curing time for examples 1-4 corresponding to Table 3, referring to Table 4, it is seen from an analysis of examples 1-4 that example 1 is the worst in hardness effect among 4 groups of examples.
Examples 2 and 3 have a better effect on hardness.
The embodiments herein are not exhaustive of the values of points in the technical scope of the invention claimed, and new technical solutions formed by equivalent substitution of single or multiple technical features in the technical solutions of the embodiments are also within the scope of the invention claimed, and all the parameters involved in the solutions of the invention are not mutually and non-replaceable unique combinations unless specifically stated.
The specific embodiments described herein are offered by way of example only to illustrate the spirit of the invention. Various modifications or additions to the described embodiments may be made by those skilled in the art to which the invention pertains or may be substituted in a similar manner without departing from the spirit of the invention or beyond the scope of the appended claims.
The present invention has been described in detail with reference to the embodiments, but the present invention is not limited to the embodiments, and various changes can be made within the knowledge of those skilled in the art without departing from the spirit of the present invention.
Claims (8)
1. A steel aluminum silicide material, comprising:
the matrix is carbon steel or aluminum alloy;
a nanocoating comprising the following components: 35-42 parts of n-butyl acetate, 7-9 parts of cellulose acetate butyrate, 10-20 parts of polysilazane solution with the mass concentration of 20-35%, 3-8 parts of polyether modified polysiloxane, 2-3 parts of 3-aminopropyl triethoxysilane, 3-8 parts of thermoplastic acrylic ester, 2-10 parts of PMMA coated nano silver and 5-10 parts of nano alumina sol; 5-8 parts of SiO2 coated nano aluminum powder and 5-8 parts of calcium carbonate coated nano titanium powder;
the silicide layer etches the nano coating into the substrate, and the surface of the substrate is modified to obtain the silicide layer;
the siliconized steel aluminum material is prepared by the following preparation method:
cleaning: washing a substrate by using an alkaline solution, and then washing and drying the substrate by using water;
coating: uniformly coating the nano coating on the substrate after washing and drying, and drying after coating to obtain a substrate with the nano coating on the surface;
siliconizing: the substrate with the nano coating coated on the surface obtained after coating is heated to 500-550 ℃ and the pressure is: and curing for 15-50 min at 10 Pa-150 Pa to obtain the silicide layer.
2. A steel aluminium silicide material as claimed in claim 1, wherein: the pressure in siliconizing is: 75Pa to 85Pa.
3. A steel aluminium silicide material as claimed in claim 1 or 2, wherein: the solvent of the polysilazane solution is one or a combination of more than one of dibutyl ether, toluene and xylene.
4. A steel aluminium silicide material as claimed in claim 1, wherein: the thickness of the nano coating is 10-15 mu m.
5. A steel aluminium silicide material as claimed in claim 1 or 4, wherein: the thickness of the silicide layer is 0.2 mm-0.35 mm.
6. A steel aluminium silicide material as claimed in claim 5, wherein: the siliconizing layer is one or a combination of more than one of zinc fluosilicate, sodium fluosilicate, ammonium fluosilicate, magnesium fluosilicate, potassium fluosilicate and calcium fluosilicate.
7. A steel aluminium silicide material as claimed in claim 1, wherein: the aluminum alloy material comprises the following components: silicon: 0.2-1.5%, iron: 0.1-0.3%, manganese 0.5-1.5%, yttrium: 0.005-0.025%, cerium: 0.02-0.10%, nano silver 0.2-2%, aluminum powder 0.2-2%, titanium powder 0.2-2%, and the balance of aluminum and unavoidable impurities.
8. A steel aluminium silicide material as claimed in claim 1, wherein: the carbon steel material comprises the following components: 0.06-0.15% of carbon, 0.15-0.30% of silicon, 0.65-1.30% of manganese, less than or equal to 0.02% of phosphorus, less than or equal to 0.02% of sulfur, 0.005-0.075% of chromium, 3-10% of rust preventive grease, and the balance of iron and unavoidable impurities.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103695883A (en) * | 2014-01-13 | 2014-04-02 | 马连众 | Environment-friendly type silicification agent for cold-rolled steel sheet and preparation method of environment-friendly type silicification agent |
| CN110250918A (en) * | 2019-07-19 | 2019-09-20 | 宁波百飞特厨具有限公司 | A kind of non-stick pan |
| CN110577852A (en) * | 2018-06-11 | 2019-12-17 | 河北津西钢板桩型钢科技有限公司 | component of H-shaped steel with antirust function |
| CN111995908A (en) * | 2020-07-20 | 2020-11-27 | 安徽金合科技有限公司 | Nanoscale coating for stainless steel wok |
| WO2022061410A1 (en) * | 2020-09-24 | 2022-03-31 | Nanokote Pty Ltd | Coating process |
-
2023
- 2023-01-18 CN CN202310055996.5A patent/CN116121603A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103695883A (en) * | 2014-01-13 | 2014-04-02 | 马连众 | Environment-friendly type silicification agent for cold-rolled steel sheet and preparation method of environment-friendly type silicification agent |
| CN110577852A (en) * | 2018-06-11 | 2019-12-17 | 河北津西钢板桩型钢科技有限公司 | component of H-shaped steel with antirust function |
| CN110250918A (en) * | 2019-07-19 | 2019-09-20 | 宁波百飞特厨具有限公司 | A kind of non-stick pan |
| CN111995908A (en) * | 2020-07-20 | 2020-11-27 | 安徽金合科技有限公司 | Nanoscale coating for stainless steel wok |
| WO2022061410A1 (en) * | 2020-09-24 | 2022-03-31 | Nanokote Pty Ltd | Coating process |
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