CN116072944A - Single-stack megawatt fuel cell - Google Patents

Single-stack megawatt fuel cell Download PDF

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Publication number
CN116072944A
CN116072944A CN202211565708.2A CN202211565708A CN116072944A CN 116072944 A CN116072944 A CN 116072944A CN 202211565708 A CN202211565708 A CN 202211565708A CN 116072944 A CN116072944 A CN 116072944A
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CN
China
Prior art keywords
groups
connectors
connector
fuel cell
megawatt
Prior art date
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Pending
Application number
CN202211565708.2A
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Chinese (zh)
Inventor
常景彩
石涌
张伟
韩新宇
张连海
王勇
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Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd
Shandong University
Original Assignee
Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd
Shandong University
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Application filed by Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd, Shandong University filed Critical Qingda Low Carbon Green Hydrogen Industrial Technology Research Institute Qingdao Co ltd
Priority to CN202211565708.2A priority Critical patent/CN116072944A/en
Publication of CN116072944A publication Critical patent/CN116072944A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • H01M8/2483Details of groupings of fuel cells characterised by internal manifolds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/24Grouping of fuel cells, e.g. stacking of fuel cells
    • H01M8/2465Details of groupings of fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The invention relates to a single-stack megawatt fuel cell, which comprises connectors and single cells positioned between two groups of oppositely arranged connectors, wherein flow passages on the surfaces of the two groups of connectors are mutually vertical, and sealing materials connected to the connectors are arranged between the adjacent two groups of single cells: the two groups of connectors which are arranged oppositely and the single cells in the connectors form a group of battery units together, and a plurality of groups of battery units are stacked to form a fuel cell stack. The metal connector is used as a matrix, and structures such as membrane electrodes, sealing layers, diaphragms and the like which are difficult to mold in the single cells are embedded in the metal connector, so that the lattice arrangement is formed, the redundancy of the number of small stacks under the high-power stacks is avoided, the complex waterway design, circuit design and gas circuit design are avoided, the unnecessary energy loss is avoided, and the occupied space of the fuel cell can be reduced.

Description

Single-stack megawatt fuel cell
Technical Field
The invention relates to the technical field of fuel cells, in particular to a single-stack megawatt fuel cell.
Background
The statements in this section merely provide background information related to the present disclosure and may not necessarily constitute prior art.
Solid Oxide Fuel Cells (SOFCs) convert chemical energy in fuel directly into electrical energy by electrochemical reactions, whereas Solid Oxide Electrolytic Cells (SOECs) convert electrical energy into hydrogen energy by electrochemical reactions, a technology that is contrary to SOFCs. PEM fuel cells are one technique for converting hydrogen energy into electrical energy, as opposed to PEM electrolysis cells. These four technologies are considered as the most potential hydrogen-to-electricity conversion technologies in the new era. The most classical structures of these three technologies are similar, all being similar to a "sandwich" structure, i.e. a metal-interconnect-anode-electrolyte-cathode-metal-interconnect structure.
In such a structure, since both the anode and cathode of the solid oxide cell (electrolytic cell) and the electrolyte material are metal oxide ceramic materials, the popularization of the SOFC (SOEC) in large scale and large power will be limited by the sintering of the ceramic materials. PEM fuel cells (cells) are also plagued by membrane electrodes, proton membranes, etc. and are difficult to scale, so that the large-scale and high-power requirements are usually met by adopting a mode of small-sized stacks connected in series-parallel, which can affect the layout design of the final fuel cell and lead to larger occupied space.
Disclosure of Invention
In order to solve the technical problems in the background technology, the invention provides a single-stack megawatt fuel cell, which utilizes the good ductility of a metal connector to design and produce a square connector with a large size, a plurality of single cells are arranged in the connector, after the single cells are arranged, sealing materials are filled in the arrangement gaps of the single cells, and then the other half of the metal connector is attached to the sealing materials to compress the single cells to complete the assembly of the single cells. The single-chip cells are arranged like a lattice arrangement of a plurality of cells like a large-scale cell stackThe cells are arranged in sequence to form a large-scale electric pile. The effective area of the single small battery is 100cm 2 Calculating that the area of the single large battery can reach 2500cm 2 (5*5 series) in a 100-piece single cell stack, the effective catalytic area was 250000cm 2 At 4W/cm 2 The stack may reach the megawatt level. While avoiding excessive stack length, more rows of cells, such as 6*6, 5*6, 8 x 8, 10 x 10, etc., may be used.
In order to achieve the above purpose, the present invention adopts the following technical scheme:
the first aspect of the invention provides a single-stack megawatt fuel cell, comprising a connector and single cells arranged between two groups of connectors which are oppositely arranged, wherein flow channels on the surfaces of the two groups of connectors are mutually perpendicular, and sealing materials connected to the connectors are arranged between two adjacent groups of single cells: the two groups of connectors which are arranged oppositely and the single cells in the connectors form a group of battery units together, and a plurality of groups of battery units are stacked to form a fuel cell stack.
The unit cells in each group of battery units are arranged on the connector in a lattice arrangement mode.
The connector is made of metal.
The connector is rectangular, and the surface is equipped with the multiunit battery cell installation position of arranging side by side, and every battery cell installation position surface of group has the runner, and every battery cell installation position both ends are equipped with respectively by runner intercommunication's first medium import and first medium export.
The first medium inlet and the first medium outlet are respectively positioned at two parallel side edges of the rectangular connecting body, and the other two parallel side edges are provided with a second medium inlet and a second medium outlet.
After the single battery is fixed by the two groups of connectors, one side is a gas side connector, the other side is an air side connector, a flow channel in the gas side connector forms a gas flow channel, and a flow channel in the air side connector forms an air flow channel.
After the single battery is fixed by the two groups of connectors, the flow channels on the two groups of connectors are mutually perpendicular at 90 degrees.
The flow passage in the gas side connector is communicated with the first medium inlet and the first medium outlet of the gas side connector.
The flow passage in the air-side connector communicates the first medium inlet and the first medium outlet of the air-side connector.
After the single battery is fixed by the two groups of connectors, the second medium inlet and the second medium outlet of the gas side connector are correspondingly connected with the first medium inlet and the first medium outlet of the air side connector respectively.
The multiple groups of single cells are uniformly arranged on each group of single cell installation positions, one side of a membrane electrode of each single cell is connected with an air side connector, the other side of the membrane electrode of each single cell is connected with a fuel gas side connector, and sealing materials are filled between two adjacent groups of single cells to form a sealing piece.
Compared with the prior art, the above technical scheme has the following beneficial effects:
1. the metal connector is used as a matrix, and structures such as membrane electrodes, sealing layers, diaphragms and the like which are difficult to mold in the single cells are embedded in the metal connector, so that the lattice arrangement is formed, the redundancy of the number of small stacks under the high-power stacks is avoided, the complex waterway design, circuit design and gas circuit design are avoided, the unnecessary energy loss is avoided, and the occupied space of the fuel cell can be reduced.
2. The connectors on two sides of the single cells relatively rotate by 90 degrees, the channels are mutually crossed by matching with the gas circuit design, and the sealing materials are matched to prevent the fuel gas and the air (oxygen) from being mixed, so that each group of single cells can be well supplied with the fuel gas and the air (oxygen), and the fuel gas and the air (oxygen) can be prevented from entering and exiting from the same side, and the risks of explosion and the like caused by the generation of gas flow mixing are avoided.
3. The effective area of the single small battery is 100cm 2 Calculating to obtain a group of battery units with an area of 2500cm 2 (5*5 series) an effective catalytic area of 250000cm calculated on a single cell stack formed by stacking 100 cells 2 At 4W/cm 2 The stack may reach the megawatt level.
4. The gas-liquid flow between different single batteries is communicated by virtue of a sealing path formed between a runner of a connector and a sealing material, the structure is like that the gas-liquid flow between different electric piles is connected by pipelines, and the electric pile connector is made of metal, belongs to a natural good conductor and can serve as a circuit connection between the electric piles, so that the method can greatly reduce the pipeline connection and the circuit connection between the traditional electric piles and avoid unnecessary energy loss.
Drawings
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the invention.
FIG. 1 is a schematic plan view of a metal connector in a fuel cell according to one or more embodiments of the present invention;
FIG. 2 is a schematic diagram of a partial side view of a metal connector in a fuel cell according to one or more embodiments of the present invention;
fig. 3 is a schematic view of a partial cross-sectional structure of a single cell in a fuel cell according to one or more embodiments of the present invention;
fig. 4 is a schematic view of an assembled structure of a single cell in a fuel cell according to one or more embodiments of the present invention;
in the figure: 1 side screw fixing holes; 2 corner screw fixing holes; 3, a fuel gas inlet; 4 trapezoid flow channels; 5 inner core set screw holes; 6, an air inlet; 7, a fuel gas outlet; 8, an air outlet; 9 trapezoid gas-liquid flow passages; 10 a first gas-liquid inlet and outlet; 11, a second gas-liquid inlet and outlet; 12 fuel gas flow passages; 13 gas side metal connector; 14 air flow channels; 15 air side metal connectors; a 16 cell membrane electrode layer or seal layer; 17 air side connector; 18 membrane electrode; 19 a seal; 20 gas side connector.
Detailed Description
The invention will be further described with reference to the drawings and examples.
It should be noted that the following detailed description is exemplary and is intended to provide further explanation of the invention. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.
It is noted that the terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of exemplary embodiments according to the present invention. As used herein, the singular is also intended to include the plural unless the context clearly indicates otherwise, and furthermore, it is to be understood that the terms "comprises" and/or "comprising" when used in this specification are taken to specify the presence of stated features, steps, operations, devices, components, and/or combinations thereof.
As described in the background art, the current fuel cell adopts a structure similar to a sandwich structure, namely, a metal connector-anode-electrolyte-cathode-metal connector structure, and the structure is limited by the materials of internal parts and is difficult to be large-scale, and a small-sized pile series-parallel connection mode is adopted to cope with the requirement of large scale and high power, so that more space is occupied.
Therefore, the following examples provide a single-stack megawatt fuel cell, which utilizes the good ductility of the metal connector to design and produce a square connector with a wide size, a plurality of single cells are arranged in the connector, after the single cells are arranged, sealing materials are filled in the arrangement gaps of the single cells, and then the other half of the metal connector is pressed against the sealing materials to complete the assembly of the single cells. The single-chip battery is arranged like a lattice arrangement of a plurality of batteries, and the batteries are sequentially arranged to form a large-scale electric pile like the large-scale electric pile. The effective area of the single small battery is 100cm 2 Calculating that the area of the single large battery can reach 2500cm 2 (5*5 series) in a 100-piece single cell stack, the effective catalytic area was 250000cm 2 At 4W/cm 2 The stack may reach the megawatt level. While avoiding excessive stack length, more rows of cells, such as 6*6, 5*6, 8 x 8, 10 x 10, etc., may be used.
Embodiment one:
as shown in fig. 1-4, a single-stack megawatt fuel cell includes a connector and a single cell located between two sets of connectors arranged oppositely, the flow channels on the surfaces of the two sets of connectors are mutually perpendicular, and sealing materials connected on the connectors are arranged between two adjacent sets of single cells: the two groups of connectors which are arranged oppositely and the single cells in the connectors form a group of battery units together, and a plurality of groups of battery units are stacked to form a fuel cell stack.
The unit cells in each group of battery units are arranged on the connector in a lattice arrangement mode.
The connector is made of metal.
The connector is rectangular, and the surface is equipped with multiunit battery cell installation position that arranges side by side, and every battery cell installation position surface of group has runner (trapezoidal runner 4), and every battery cell installation position both ends are equipped with respectively by the first medium import and the first medium export of trapezoidal runner 4 intercommunication.
The first medium inlet and the first medium outlet are respectively positioned at two opposite side edges of the rectangular connecting body, and the second medium inlet and the second medium outlet are arranged at the other two opposite side edges.
The cross section of the flow channel has various shapes such as trapezium, square, semicircle, triangle, etc., the performance of the flow field with the trapezium cross section is best according to the prior art, and the processing cost of the trapezium cross section is lowest in the machining, so the cross section of the flow channel is selected to be trapezium, namely, the trapezium flow channel 4 in the embodiment.
In the embodiment, the connector is square, and corner screw fixing holes 2 are formed in four corners and used for forming fasteners when a plurality of groups of battery units are stacked; an inner core fixing screw hole 5 is arranged between the installation positions of the adjacent two groups of single battery installation positions and is used for penetrating through the two groups of connecting bodies through fasteners to fix the single battery therein.
After the single battery is fixed by the two groups of connectors, the flow channels on the two groups of connectors are mutually perpendicular at 90 degrees, and as an example in fig. 4, the membrane electrode 18 is clamped between the gas side connector 20 and the air side connector 17 at the bottom, and a sealing piece 19 is arranged between the adjacent membrane electrodes 18.
The structure is as follows:
the first medium inlet and the first medium outlet communicated with the trapezoid flow passage 4 in the gas side connector 20 are a gas inlet 3 and a gas outlet 7 respectively, the first medium inlet and the first medium outlet are positioned at two parallel edges of the rectangular connector, and the second medium inlet and the second medium outlet respectively arranged at the other two parallel edges are an air inlet 6 and an air outlet 8 respectively.
The second medium inlet and the second medium outlet communicated with the trapezoid flow passage 4 in the air side connector 17 are an air inlet 6 and an air outlet 8 respectively, and the other two groups of parallel edges are a fuel gas inlet 3 and a fuel gas outlet 7 respectively.
The flow passages on the two groups of connectors in the structure are intersected with each other, so that the lower surface of each group of membrane electrode 18 flows through fuel gas, the upper surface flows through air (oxygen), the flow direction is intersected to be 90 degrees, the fuel gas which is introduced through the fuel gas inlet 3 and the fuel gas outlet 7 on the left side and the right side of the fuel gas side connector is blocked by the sealing piece 19 and cannot enter the upper layer area of the membrane electrode 18, and the air (oxygen) which is introduced through the air inlet 6 and the air outlet 8 on the upper side and the lower side of the fuel gas side connector is blocked by the sealing piece 19 and cannot enter the lower layer area of the membrane electrode 18.
In the structure, the connectors on two sides of the single cells relatively rotate by 90 degrees, the channels are mutually crossed by matching with the gas circuit design, and the sealing materials are matched to prevent fuel gas and air (oxygen) from being mixed, so that each group of single cells can be well supplied with fuel gas and air (oxygen), and the fuel gas and air (oxygen) can be prevented from entering and exiting from the same side, and the risks of explosion and the like caused by air flow mixing are avoided.
As shown in fig. 2, the two ends of the trapezoid runner 4 are provided with a first gas-liquid inlet and a first gas-liquid outlet 10, the first gas-liquid inlet and outlet 10 is communicated with a first medium inlet and a first medium outlet, when the connector is positioned on the gas side, the first gas-liquid inlet and outlet 10 is communicated with the gas inlet 3 and the gas outlet 7, and when the connector is positioned on the air side, the first gas-liquid inlet and outlet 10 is communicated with the air inlet 6 and the air outlet 8.
Fig. 2 is a schematic side view of a part of a connecting body, and in this embodiment, the air outlet 8 forms a trapezoid gas-liquid flow passage 9, which is rectangular ellipse-shaped and penetrates the connecting body, in the view angle shown in fig. 2.
The flow channels of fuel gas, air (oxygen) and the like in the connectors are all through, so that gas and liquid can enter different single cells simultaneously after a plurality of groups of connectors are stacked.
As shown in fig. 3, two metal connectors are combined together in a relatively crossed manner, and a partial side view schematic diagram of the membrane electrode is sandwiched therebetween, the flow channels of the metal connectors are crossed with each other and are not in the same direction, the air flow channel 14 is located at the position of the trapezoid flow channel 4 in fig. 1, that is, after the trapezoid flow channel on the air side connector is communicated with the air inlets and outlets 6 and 8, the air flow channel 14 shown in fig. 3 is formed, and correspondingly, the first air inlet and outlet 10 in fig. 2 corresponds to the position of the second air inlet and outlet 11 in fig. 3.
As shown in fig. 4, a plurality of groups of single cells are uniformly arranged on each group of single cell mounting positions, the membrane electrodes 18 of the single cells are connected with the air side metal connector 17 positioned at the top, and sealing materials filled between two adjacent groups of single cells form a sealing piece 19.
The single cells on each group of connectors are arranged in parallel, so that the single cells form array arrangement on the connectors, the single cells are clamped and fixed by the two groups of connectors to form a group of battery units, and a plurality of groups of battery units are stacked to form a complete fuel cell.
In this embodiment, a square connector with a large size is designed and produced, and a plurality of single cells are arranged in the connector, as shown in fig. 4. After the single cells are arranged, the sealing material is filled in the arrangement gaps of the single cells. And then the other half of the metal connector is pressed against the sealing material to complete the assembly of the single cell. The single-cell is thus mounted like a lattice arrangement of multiple cells, as is the case with a large-scale stack. The cells are orderly arranged to form a large-scale electric pile, and the effective area of each small cell is 100cm 2 Calculating that the area of the single large battery can reach 2500cm 2 (5*5 series) in a 100-piece single cell stack, the effective catalytic area was 250000cm 2 At 4W/cm 2 The stack may reach the megawatt level. While avoiding excessive stack length, more rows of cells, such as 6*6, 5*6, 8 x 8, 10 x 10, etc., may be used.
The structure can realize the large-scale and high-power product single-pile landing of technical products such as SOFC (SOEC), PEM fuel cells (electrolytic cells) and the like.
The adopted metal connector realizes the single-stack megawatt level, takes the easily-formed metal connector as a matrix, embeds the structures such as membrane electrodes, sealing layers, diaphragms and the like which are not easily formed therein, forms lattice arrangement, avoids the redundancy of the number of small stacks under the high-power stacks, avoids complex waterway design, circuit design and gas circuit design, and avoids unnecessary energy loss.
Shan Dui has advantages such as temperature uniformity and convenient control than a plurality of piles.
The single-cell stack is more stable than the single-cell stack with the traditional large single-cell stack, the risk of lowering the yield of key materials of the large single-cell is unavoidable while the large single-cell is pursued, and the single-cell method with the lattice small single-cell is pursued, so that the yield of products can be well controlled.
The gas-liquid communication between different small batteries depends on the sealing path communication formed between the flow channels of the connecting bodies and the sealing materials,
after entering one side of the battery, the fuel gas (liquid) passes through the fuel gas flow channel, and after the reaction of the first small module, the fuel gas (liquid) enters the next small module through the sealing flow channel formed between the connecting body and the sealing material, so that the common reaction result of a plurality of modules is realized.
The air-side flow passage is the same as the fuel flow passage in the flow manner, but the flow passage directions of the two flow passages intersect.
The structure is connected between different electric piles by pipelines, and the electric pile connector is made of metal, belongs to natural good conductors and can serve as circuit connection between the electric piles, so that the method can greatly reduce the pipeline connection and circuit connection between the traditional electric piles and avoid unnecessary energy loss.
In the traditional pile design scheme, if megawatt level is to be realized on the premise that key core materials cannot be made large, n small piles are required to be connected in series and parallel, and gas paths, waterways and circuit connection among the small piles become very complex. And the temperature between the electric pile and the electric pile is difficult to uniformly regulate and control, which is unfavorable for the whole service life and efficiency of the product.
The above description is only of the preferred embodiments of the present invention and is not intended to limit the present invention, but various modifications and variations can be made to the present invention by those skilled in the art. Any modification, equivalent replacement, improvement, etc. made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. A single stack megawatt fuel cell characterized in that: including the connector and be located the battery cell between two sets of connectors of relative arrangement, the runner on two sets of connector surfaces is mutually perpendicular, has the sealing material of connection on the connector between two adjacent battery cells: the two groups of connectors which are arranged oppositely and the single cells in the connectors form a group of battery units together, and a plurality of groups of battery units are stacked to form a fuel cell stack.
2. A single stack megawatt fuel cell as defined in claim 1, wherein: the connector is made of metal.
3. A single stack megawatt fuel cell as defined in claim 1, wherein: the connector is rectangular, a plurality of groups of single battery installation positions are arranged on the surface of the connector in parallel, the surface of each group of single battery installation positions is provided with a flow channel, and two ends of each group of single battery installation positions are respectively provided with a first medium inlet and a first medium outlet which are communicated by the flow channels.
4. A single stack megawatt fuel cell as in claim 3 wherein: the first medium inlet and the first medium outlet are respectively positioned at two parallel side edges of the rectangular connecting body, and the other two parallel side edges are provided with a second medium inlet and a second medium outlet.
5. A single stack megawatt fuel cell as defined in claim 4, wherein: after the single battery is fixed by the two groups of connectors, one side is a gas side connector, the other side is an air side connector, a flow channel in the gas side connector forms a gas flow channel, and a flow channel in the air side connector forms an air flow channel.
6. A single stack megawatt fuel cell as defined in claim 4, wherein: after the single battery is fixed by the two groups of connectors, the flow channels on the two groups of connectors are mutually perpendicular at 90 degrees.
7. A single stack megawatt fuel cell as defined in claim 5, wherein: the runner in the gas side connector is communicated with the first medium inlet and the first medium outlet of the gas side connector.
8. A single stack megawatt fuel cell as defined in claim 5, wherein: the flow passage in the air side connector communicates with the first medium inlet and the first medium outlet of the air side connector.
9. A single stack megawatt fuel cell as defined in claim 5, wherein: after the single battery is fixed by the two groups of connectors, the second medium inlet and the second medium outlet of the gas side connector are correspondingly connected with the first medium inlet and the first medium outlet of the air side connector respectively.
10. A single stack megawatt fuel cell as defined in claim 1, wherein: the multiple groups of single cells are uniformly arranged on each group of single cell installation positions, one side of a membrane electrode of each single cell is connected with an air side connector, the other side of the membrane electrode of each single cell is connected with a fuel gas side connector, and sealing materials are filled between two adjacent groups of single cells to form a sealing piece.
CN202211565708.2A 2022-12-07 2022-12-07 Single-stack megawatt fuel cell Pending CN116072944A (en)

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CN115036549A (en) * 2022-05-24 2022-09-09 江苏精瓷智能传感技术研究院有限公司 High power solid oxide fuel cell/electrolyser system
CN115051012A (en) * 2022-07-11 2022-09-13 同济大学 Multi-section multi-chamber megawatt fuel cell stack
CN115172836A (en) * 2022-07-11 2022-10-11 同济大学 Single-section multi-chamber megawatt fuel cell stack

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