CN116042301A - Water-based metal processing liquid - Google Patents

Water-based metal processing liquid Download PDF

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Publication number
CN116042301A
CN116042301A CN202211654597.2A CN202211654597A CN116042301A CN 116042301 A CN116042301 A CN 116042301A CN 202211654597 A CN202211654597 A CN 202211654597A CN 116042301 A CN116042301 A CN 116042301A
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China
Prior art keywords
agent
percent
water
aqueous
metalworking fluid
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CN202211654597.2A
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Chinese (zh)
Inventor
耿伟
冒素兰
杨明生
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Changzhou Longbang Lubrication Technology Co ltd
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Changzhou Longbang Lubrication Technology Co ltd
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Priority to CN202211654597.2A priority Critical patent/CN116042301A/en
Publication of CN116042301A publication Critical patent/CN116042301A/en
Priority to CN202310924572.8A priority patent/CN116875365A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00Lubricating compositions containing more than 10% water
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/062Oxides; Hydroxides; Carbonates or bicarbonates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/087Boron oxides, acids or salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/40Fatty vegetable or animal oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22Heterocyclic nitrogen compounds
    • C10M2215/223Five-membered rings containing nitrogen and carbon only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/02Unspecified siloxanes; Silicones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04Detergent property or dispersant property
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/28Anti-static
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/20Metal working
    • C10N2040/22Metal working with essential removal of material, e.g. cutting, grinding or drilling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/10Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention belongs to the field of metal processing liquids, and in particular relates to a high-performance fully-synthetic aqueous metal processing liquid which consists of a pH regulator, an antirust agent, a complexing agent, an oiliness agent, a defoaming agent and water, has good lubricating, cooling, corrosion-resistant performance, antistatic performance and permeability, is safe and environment-friendly, has long service life, can be recycled for a long time, and is particularly suitable for rough grinding processing of bearings.

Description

Water-based metal processing liquid
Technical Field
The invention belongs to the field of metal working fluids, and particularly relates to a high-performance fully-synthetic water-based metal working fluid.
Background
The metal surface is subjected to a large cutting force during machining and has a relative movement, so that a large friction is generated between the tool and the workpiece surface, and between the tool and the chip. The presence of such friction phenomena generates a large amount of heat and aggravates wear of the tool and deterioration of the workpiece surface accuracy, and reduces the machining efficiency. In addition, the dual functions of shearing and friction exist in the machining process, so that larger heat is inevitably generated, if the heat cannot be taken away in time, high temperature is generated between the cutter and the workpiece, the cutter is softened, the hardness of the surface of the workpiece is even reduced, the cutter abrasion is increased, and the surface precision of the workpiece is affected. Moreover, accumulation of chips can be generated at high temperature, so that the machining precision of the workpiece is deviated. Machining chips generated during metal machining, if not removed from the machining area in time, may generate built-up chips and cause abrasion of the machined surface. Most metallic materials (e.g., iron and cast iron) rust quickly after contact with humid air and water, resulting in product rejection.
The metal working fluid mainly plays roles of lubrication and cooling, has the functions of rust prevention, cleaning and the like, so that friction is reduced, heat generated in a machining process can be taken away through the flushing function of the large-flow metal working fluid, and a good rust prevention function can be provided, so that the temperature of a cutter and a workpiece is reduced, the service life of the cutter is prolonged, the surface precision of a machined part is improved, and the machining efficiency is improved.
At present, many total synthetic metal working fluids in China are weak in rust prevention and lubrication, contain an environment-friendly carcinogenic substance nitrite, bring unnecessary economic loss to enterprise production, and bring a lot of hidden troubles to social environment. In addition, the metal working fluid has poor performance, so that large-scale equipment or some precise equipment is damaged, and serious economic loss is caused for enterprises.
Disclosure of Invention
In order to solve the technical problems, the invention aims to provide a high-performance fully-synthetic metal working fluid which consists of an antirust agent, an oiliness agent surfactant, a synthetic lubricant and the like and is specially designed for imported and domestic high-precision machining center equipment requiring high lubrication, cooling, cleaning and corrosion resistance.
In order to achieve the above purpose, the invention adopts the following technical scheme:
the aqueous metal working fluid consists of the following components in percentage by mass:
13.5 to 16.0 percent of pH regulator
4.1 to 5.3 percent of rust inhibitor
Complexing agent 0.1-0.3%
4.0 to 5.0 percent of oiliness agent
0.1 to 0.3 percent of defoaming agent
0.001 to 0.003 percent of colorant
The balance being water.
The pH regulator is prepared from monoethanolamine, triethanolamine and potassium hydroxide according to a mass ratio of 3.0-4.0: 10.0 to 11.0:0.5 to 1.0, and is used for adjusting the pH value of the aqueous processing liquid to 10 to 11.
The antirust agent is prepared from benzotriazole and boric acid according to the mass ratio of 0.1-0.3: 4.0 to 5.0.
The complexing agent is ethylenediamine tetraacetic acid.
The oily agent is vegetable oleic acid.
The defoaming agent is organic silicon.
The colorant is dye, the color of the metal processing liquid is regulated and controlled by strictly controlling and monitoring the adding proportion of the dye, and the concentration of the colorant is judged by the color of the processing liquid in use, so that the colorant is important to control the quality of products.
The invention also provides a preparation method of the aqueous metal working fluid, which comprises the following steps: mixing pH regulator, antirust agent and complexing agent, heating to 70deg.C, stirring and mixing to transparency, adding oily agent and stirring to transparency, adding defoamer, colorant and water, stirring to transparency, cooling to normal temperature, and packaging.
The specific gravity of the aqueous metal working fluid stock solution prepared by the method is 1.0-1.1 g/cm 3 (20 ℃) and a dynamic viscosity of 1.1 to 1.4mm 2 The copper plate corrosion was classified into 1a to 1b (100 ℃ C..times.3. 3 Hrs).
The aqueous metal working fluid is diluted and used for metal working, the concentration is generally 3-6%, and if special working requirements are met, the concentration can be properly increased. The preparation method comprises the following steps: the tap water is directly prepared by industrial tap water (for obtaining the best use performance, the recommended water hardness range is 50-150 ppm), and when the tap water is prepared, the tap water is firstly added into a liquid tank, and then the concentrated solution is added to the specified concentration while stirring (or beating and circulating) for recycling.
The aqueous metal working fluid of the present invention is suitable for the general cutting and grinding of cast iron, ferrous metals including stainless steel, ceramics, nichrome and the like, and is a dual-purpose synthetic water-soluble cutting oil. The processing equipment is an internal and external grinding machine, a plane, a centerless, a channel, a guide rail, a high-speed grinding machine, a lathe, a drilling machine, a milling machine and the like. The grinding machine is particularly suitable for grinding the bearing ring.
Compared with the prior art, the invention has the beneficial effects that: the lubricating performance is good, the service life of the cutting tool is prolonged, the abrasion in the processing process can be effectively reduced, and the surface smoothness of the workpiece is improved. The cooling performance is excellent, the cutting heat is fully taken away, the surface of the workpiece has strong adsorption capacity, and the workpiece is not annealed and burnt. Excellent corrosion resistance and excellent protection for the workpiece. Has good antistatic property and permeability, and has no bonding phenomenon to the grinding wheel. Safe and environment-friendly, long in service life and capable of being recycled for a long time. The method is particularly suitable for rough grinding of the bearing.
Detailed Description
The technical scheme of the invention is further described by the following specific embodiments. It will be appreciated by those skilled in the art that the examples are merely provided to aid in the understanding of the present invention and should not be construed as limiting the invention.
Example 1
Monoethanolamine 3.0
Triethanolamine 10
Potassium hydroxide 0.5
Boric acid 4.0
Benzotriazole 0.15
Ethylenediamine tetraacetic acid 0.3
Vegetable oleic acid 4.0
Organosilicon 0.15
Colorant 0.0015
The balance being water. Based on 100 parts of the total amount.
Heating monoethanolamine, triethanolamine, potassium hydroxide, boric acid, benzotriazole and ethylenediamine tetraacetic acid to 70 ℃, stirring until clear, adding vegetable oleic acid, stirring until transparent, adding organic silicon, colorant and water, stirring until transparent, cooling to room temperature, and filling.
Example 2
Monoethanolamine 3.5
Triethanolamine 11.0
Potassium hydroxide 0.7
Boric acid 4.5
Benzotriazole 0.2
Ethylenediamine tetraacetic acid 0.2
Oleic acid (vegetable oil acid) 4.5
Organosilicon 0.2
Colorant 0.002
The balance being water. Based on 100 parts of the total amount.
Heating monoethanolamine, triethanolamine, potassium hydroxide, boric acid, benzotriazole and ethylenediamine tetraacetic acid to 70 ℃, stirring until clear, adding vegetable oleic acid, stirring until transparent, adding organic silicon, colorant and water, stirring until transparent, cooling to room temperature, and filling.
Example 3
Monoethanolamine 3.5
Triethanolamine 10.5
Potassium hydroxide 1.0
Boric acid 4.0
Benzotriazole 0.3
Ethylenediamine tetraacetic acid 0.3
Oleic acid (vegetable oleic acid) 4.0
Organosilicon 0.1
Colorant 0.003
The balance being water. Based on 100 parts of the total amount. Heating monoethanolamine, triethanolamine, potassium hydroxide, boric acid, benzotriazole and ethylenediamine tetraacetic acid to 70 ℃, stirring until clear, adding vegetable oleic acid, stirring until transparent, adding organic silicon, colorant and water, stirring until transparent, cooling to room temperature, and filling.
The aqueous metal working fluids of examples 1 to 3 were added to industrial tap water to prepare a 5% strength dilution, and the properties of the aqueous metal working fluid stock solutions of examples 1 to 3 and the dilutions thereof were examined, with the results shown in the following table:
Figure BDA0004012053830000051
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Claims (8)

1. the aqueous metal working fluid is characterized by comprising the following components in percentage by mass:
13.5 to 16.0 percent of pH regulator, 4.1 to 5.3 percent of antirust agent, 0.1 to 0.3 percent of complexing agent, 4.0 to 5.0 percent of oiliness agent, 0.1 to 0.3 percent of defoamer, 0.001 to 0.003 percent of colorant and the balance of water.
2. The aqueous metalworking fluid of claim 1, wherein the pH adjuster is composed of monoethanolamine, triethanolamine and potassium hydroxide in a mass ratio of 3.0 to 4.0:10.0 to 11.0:0.5 to 1.0.
3. The aqueous metal working fluid according to claim 1, wherein the rust inhibitor comprises benzotriazole and boric acid in a mass ratio of 0.1-0.3: 4.0 to 5.0.
4. The aqueous metalworking fluid of claim 1 wherein the complexing agent is ethylenediamine tetraacetic acid.
5. The aqueous metalworking fluid of claim 1 wherein the oily agent is vegetable oleic acid.
6. The aqueous metalworking fluid of claim 1 wherein the defoamer is a silicone.
7. The aqueous metalworking fluid of claim 1 wherein the colorant is a dye.
8. A method for preparing an aqueous metalworking fluid according to claim 1, wherein the pH adjuster, the rust inhibitor and the complexing agent are mixed, heated to 70 ℃, stirred and mixed until transparent, the oiliness agent is added and stirred until transparent, the antifoaming agent, the coloring agent and the water are added and stirred until transparent, and then cooled to room temperature and filled.
CN202211654597.2A 2022-12-22 2022-12-22 Water-based metal processing liquid Pending CN116042301A (en)

Priority Applications (2)

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CN202211654597.2A CN116042301A (en) 2022-12-22 2022-12-22 Water-based metal processing liquid
CN202310924572.8A CN116875365A (en) 2022-12-22 2023-07-26 Water-based metal processing liquid

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Application Number Priority Date Filing Date Title
CN202211654597.2A CN116042301A (en) 2022-12-22 2022-12-22 Water-based metal processing liquid

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Application publication date: 20230502