CN116024470B - Magnesium-silver alloy and preparation method and application thereof - Google Patents
Magnesium-silver alloy and preparation method and application thereof Download PDFInfo
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- CN116024470B CN116024470B CN202211545907.7A CN202211545907A CN116024470B CN 116024470 B CN116024470 B CN 116024470B CN 202211545907 A CN202211545907 A CN 202211545907A CN 116024470 B CN116024470 B CN 116024470B
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- magnesium
- silver alloy
- alloy
- silver
- treatment
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- 229910001316 Ag alloy Inorganic materials 0.000 title claims abstract description 39
- SJCKRGFTWFGHGZ-UHFFFAOYSA-N magnesium silver Chemical compound [Mg].[Ag] SJCKRGFTWFGHGZ-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000011777 magnesium Substances 0.000 claims abstract description 66
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 62
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 62
- 239000010405 anode material Substances 0.000 claims abstract description 10
- 230000002902 bimodal effect Effects 0.000 claims abstract description 8
- 229910045601 alloy Inorganic materials 0.000 claims description 47
- 239000000956 alloy Substances 0.000 claims description 47
- 238000007670 refining Methods 0.000 claims description 36
- 238000003723 Smelting Methods 0.000 claims description 35
- 239000000243 solution Substances 0.000 claims description 33
- 239000007788 liquid Substances 0.000 claims description 29
- 229910052709 silver Inorganic materials 0.000 claims description 29
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 27
- 239000004332 silver Substances 0.000 claims description 27
- 239000012298 atmosphere Substances 0.000 claims description 25
- 230000001681 protective effect Effects 0.000 claims description 24
- 239000002994 raw material Substances 0.000 claims description 24
- 239000006104 solid solution Substances 0.000 claims description 22
- 238000002844 melting Methods 0.000 claims description 18
- 230000008018 melting Effects 0.000 claims description 18
- 238000000034 method Methods 0.000 claims description 18
- 238000004321 preservation Methods 0.000 claims description 9
- 238000000265 homogenisation Methods 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 3
- 238000003825 pressing Methods 0.000 claims description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 8
- 239000001257 hydrogen Substances 0.000 abstract description 8
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 8
- 238000007086 side reaction Methods 0.000 abstract description 6
- 239000011159 matrix material Substances 0.000 abstract description 4
- 230000000903 blocking effect Effects 0.000 abstract description 2
- 230000001808 coupling effect Effects 0.000 abstract description 2
- 239000007772 electrode material Substances 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 238000001125 extrusion Methods 0.000 description 17
- 239000002245 particle Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000003795 chemical substances by application Substances 0.000 description 13
- 238000010791 quenching Methods 0.000 description 11
- 230000000171 quenching effect Effects 0.000 description 11
- 239000002893 slag Substances 0.000 description 11
- 229910000861 Mg alloy Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000005498 polishing Methods 0.000 description 7
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000005266 casting Methods 0.000 description 5
- 239000003792 electrolyte Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 229910004261 CaF 2 Inorganic materials 0.000 description 3
- 239000012300 argon atmosphere Substances 0.000 description 3
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 3
- 229910001626 barium chloride Inorganic materials 0.000 description 3
- 238000003754 machining Methods 0.000 description 3
- 239000007773 negative electrode material Substances 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- 229910052770 Uranium Inorganic materials 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
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- Manufacture And Refinement Of Metals (AREA)
Abstract
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CN202211545907.7A CN116024470B (en) | 2022-12-05 | 2022-12-05 | Magnesium-silver alloy and preparation method and application thereof |
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CN202211545907.7A CN116024470B (en) | 2022-12-05 | 2022-12-05 | Magnesium-silver alloy and preparation method and application thereof |
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CN116024470A CN116024470A (en) | 2023-04-28 |
CN116024470B true CN116024470B (en) | 2024-06-14 |
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Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE307393B (en) * | 1966-01-12 | 1969-01-07 | Asea Ab | |
EP1873846A4 (en) * | 2005-03-23 | 2013-04-03 | Pionics Co Ltd | Negative electrode active material particle for lithium secondary battery, negative electrode and methods for producing those |
KR20100033563A (en) * | 2008-09-22 | 2010-03-31 | 지성중공업 주식회사 | Air - magnesium battery |
US8709127B2 (en) * | 2010-02-12 | 2014-04-29 | GM Global Technology Operations LLC | Porous dendritic platinum tubes as fuel cell electrocatalysts |
CN103190031B (en) * | 2011-08-02 | 2015-05-13 | 一般社团法人铃魏 | Magnesium metal-air battery |
JP6032018B2 (en) * | 2012-01-19 | 2016-11-24 | 日産自動車株式会社 | Injection metal-air battery |
JP6099257B2 (en) * | 2013-02-07 | 2017-03-22 | 国立研究開発法人物質・材料研究機構 | Magnesium-based alloy thin plate and foil material and method for producing them |
WO2014205553A1 (en) * | 2013-06-28 | 2014-12-31 | Boom Energy Inc. | Anode element for electrochemical reactions |
JP2015046368A (en) * | 2013-08-29 | 2015-03-12 | 古河電池株式会社 | Magnesium battery |
JP6161589B2 (en) * | 2013-12-16 | 2017-07-12 | 木ノ本伸線株式会社 | Joining material, joining structure of magnesium (Mg) alloy material and filler material, joining method by fusion welding of magnesium (Mg) alloy material, magnesium (Mg) alloy material joining structure, and magnesium (Mg) alloy material joining Manufacturing method of structure |
JP5847283B1 (en) * | 2014-12-03 | 2016-01-20 | 充 吉川 | Magnesium-air battery with multiple cells |
US10752515B2 (en) * | 2015-03-23 | 2020-08-25 | Council Of Scientific & Industrial Research | Lithium-substituted magnesium ferrite material based hydroelectric cell and process for preparation thereof |
JP2017168226A (en) * | 2016-03-14 | 2017-09-21 | 株式会社倉元製作所 | Magnesium battery and method for manufacturing the same |
CN111793760B (en) * | 2020-07-17 | 2021-10-26 | 广东省科学院新材料研究所 | Anode alloy material for magnesium air battery, preparation method thereof and battery |
CN113718147B (en) * | 2021-07-19 | 2022-06-03 | 南通大学 | Multi-element alloy anode material for magnesium air battery and preparation method thereof |
-
2022
- 2022-12-05 CN CN202211545907.7A patent/CN116024470B/en active Active
Non-Patent Citations (1)
Title |
---|
镁空气电池用Mg-0.5Bi-0.5Ag合金挤压态的组织特性与放电性能研究;冯瑨等;轻合金加工技术;20220629;第50卷(第4期);第44页、1 试验方法 * |
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Inventor after: Cheng Weili Inventor after: Feng Jin Inventor after: ShangGuan Feier Inventor after: Shi Jiaoyan Inventor after: Wang Linxin Inventor after: Zhao Fanxu Inventor after: Cai Chenyang Inventor before: Feng Jin Inventor before: Cheng Weili Inventor before: ShangGuan Feier Inventor before: Shi Jiaoyan Inventor before: Wang Linxin Inventor before: Zhao Fanxu Inventor before: Cai Chenyang |
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