CN115895336A - Preparation method of stationery printing sweat-resistant heat transfer ink - Google Patents
Preparation method of stationery printing sweat-resistant heat transfer ink Download PDFInfo
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- CN115895336A CN115895336A CN202211654913.6A CN202211654913A CN115895336A CN 115895336 A CN115895336 A CN 115895336A CN 202211654913 A CN202211654913 A CN 202211654913A CN 115895336 A CN115895336 A CN 115895336A
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Abstract
The invention relates to the field of printing ink, in particular to a preparation method of stationery printing sweat-resistant heat transfer ink; ternary chlorine vinegar, thermoplastic acrylic acid, pigment, wetting dispersant, leveling assistant, antistatic agent, rheological assistant, filler, ethyl acetate, n-propyl acetate, n-butyl acetate and isopropanol are adopted to prepare the stationery printing sweat-resistant heat transfer ink; the stationery printing sweat-resistant heat transfer ink prepared by the invention has the advantages that the pigment is firmly attached, and the problems of fading and the like when meeting sweat are not easy to occur; the patterns printed by the sweat-resistant heat transfer ink for stationery printing prepared by the invention have the advantages of sweat resistance, ink drop resistance, delamination resistance and the like.
Description
Technical Field
The invention relates to the field of printing ink, in particular to a preparation method of stationery printing sweat-resistant heat transfer ink.
Background
With the increasing stationery market, students and office staff pursue writing pens more and more. In case sweat in the hand erodes the printing pattern of pen-holder, not only influence the product image, also reduce the experience to the user simultaneously. Therefore, a heat transfer ink with sweat resistance can be widely accepted in the market.
CN201611050466.8: the invention discloses a high-adhesion printing ink binder and a preparation method thereof, wherein the high-adhesion printing ink binder takes microcrystalline cellulose dissolved in ionic liquid as a base material, polyacrylonitrile electrostatic spinning fiber as an additive and a plasticizer as an auxiliary additive, and utilizes active hydroxyl on the surface of the microcrystalline cellulose to form a hydrogen bond with strong electronegative nitrogen atoms in a molecular chain structure of the polyacrylonitrile electrostatic spinning fiber so as to further obtain a cross-linked structure, thereby obtaining the high-adhesion printing ink binder; the preparation method comprises five stages of preparation of spinning solution, electrostatic spinning, dissolution of microcrystalline cellulose, preparation of an electrostatic spinning fiber-microcrystalline cellulose mixture, preparation of a high-adhesion printing ink binder and the like; the T-shaped peel strength of the high-adhesion printing ink binder can exceed 3MPa after the binder is dried for 24 hours at the temperature of 45 to 55 ℃; the preparation method of the high-adhesion printing ink binder is simple and meets the environmental protection requirement of sustainable development.
CN201811520119.6: the invention discloses high-adhesion printing ink which adopts the technical scheme that the high-adhesion printing ink comprises the following components in parts by weight: 20-30 parts of chlorinated polypropylene resin, 10-20 parts of polyacrylic resin, 9-24 parts of organic solvent, 1-5 parts of inorganic filler, 0.2-1.0 part of modifier, 0.1-0.5 part of cosolvent and 1-5 parts of disperse dye; the solvent is formed by mixing diethylene glycol, thiodiglycol and ethyl acetate according to a mass ratio of 1; the grain diameter of the used inorganic filler is less than or equal to 10 mu m. The printing ink disclosed by the invention does not need to be doped with graphene, and is low in cost and high in adhesion fastness. The invention correspondingly discloses a preparation method of the high-adhesion printing ink, and the printing ink prepared by the method has the advantages of strong adhesion and smoothness after film forming.
CN201510851148.0: the invention discloses high-adhesion printing ink which is prepared from the following raw materials in parts by mass: 52-68 parts of polyester modified methyl phenyl silicone resin, 25-40 parts of titanium dioxide, 2.2-5.2 parts of barium sulfate, 1.5-6 parts of xylene, 1.5-6 parts of cyclohexanone, 1.3-6.5 parts of hexamethoxy methyl melamine resin, 3238 parts of octyl phenol polyoxyethylene ether, 3238 parts of zxft, 3262 parts of modified chlorinated polypropylene, 0.5-1 part of a silane coupling agent, 0.5-2 parts of a dispersing agent, 0.5-1 part of polyether modified siloxane and 0.5-1 part of an organic silicon defoaming agent. The invention selects polyester modified methyl phenyl silicone resin as the binder, which not only has excellent thermal stability of methyl phenyl silicone resin, but also has better flexibility of linear polyester. The titanium dioxide is selected as the pigment, and the titanium dioxide not only has high covering power, high whiteness and strong mechanical strength, but also has excellent heat resistance, high-temperature color retention and low heat conductivity. The polyether modified siloxane is selected as the leveling agent, so that the rheological property of the ink liquid can be adjusted, and the ink coating can be complete and smooth in surface and good in gloss when dried to form a film.
The transfer ink prepared by the above patent and the prior art can meet the process requirement of heat transfer, but the pattern is not sweat-resistant.
Disclosure of Invention
In order to solve the problems, the invention provides a preparation method of the sweat-resistant heat transfer ink for stationery printing, which comprises the following operation steps:
mixing 15-20 parts of ternary chlorine vinegar and 20-35 parts of thermoplastic acrylic acid according to the mass parts, stirring for 60-90min, adding 10-30 parts of pigment, 0.5-1.5 parts of wetting dispersant, 0.5-1.5 parts of leveling assistant, 0.5-1.5 parts of trihydroxyethyl methyl quaternary ammonium methyl sulfate, 0.5-2 parts of rheological assistant, 2-8 parts of filler, 10-15 parts of ethyl acetate, 15-25 parts of n-propyl acetate, 5-10 parts of n-butyl acetate and 5-8 parts of isopropanol, and continuously stirring for 30-40min to obtain the sweat-resistant heat transfer ink for stationery printing.
Preferably, in order to improve the sweat resistance and the antistatic property of the sweat resistance heat transfer ink, the technical scheme is further optimized, and the operation steps are as follows:
mixing 15-20 parts of ternary chlorine vinegar and 20-35 parts of thermoplastic acrylic acid according to the mass parts, stirring for 60-90min, adding 10-30 parts of pigment, 0.5-1.5 parts of wetting dispersant, 0.5-1.5 parts of leveling assistant, 0.5-1.5 parts of sweat-resistant antistatic agent, 0.5-2 parts of rheological assistant, 2-8 parts of filler, 10-15 parts of ethyl acetate, 15-25 parts of n-propyl acetate, 5-10 parts of n-butyl acetate and 5-8 parts of isopropanol, and continuously stirring for 30-40min to obtain the stationery printing sweat-resistant heat transfer ink.
Preferably, the stirring device is a sealed stirring device, and the rotating speed is 500-1000rpm.
Preferably, the pigment is PY180 yellow or PR254 or PR170 or phthalocyanine blue or titanium dioxide or carbon black.
Preferably, the wetting dispersant is B0K-F-501 or B0K-F-502 or B0K-F-505 or B0K-F-508 or B0K-F-512.
Preferably, the leveling assistant is B0K-L-301, B0K-L-302, B0K-L-303, B0K-L-305, B0K-L-307, B0K-L-308, B0K-L-309 or B0K-L-310.
Preferably, the rheological additive is BYK163 or BYK333 or BYK310 or BYK306.
Preferably, the filler is calcium carbonate or aluminum hydroxide or barium sulfate.
Preferably, the preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: according to the weight parts, 0.03-0.5 part of perfluoropolyether diol, 5-10 parts of 2-acryloxyethyl isocyanate, 0.05-1.5 parts of dibutyltin dilaurate and 150-200 parts of DMF are added into a closed high-pressure reactor, nitrogen is introduced for protection, and the reaction is carried out for 0.5-2 hours at 67-77 ℃;
s2: and then adding 30-40 parts of trihydroxyethyl methyl quaternary ammonium methyl sulfate and 0.05-1.5 parts of dibutyltin dilaurate, continuously reacting for 0.5-1.5h, then adding 0.01-0.2 part of aminated cage type polysilsesquioxane and 1-3 parts of triethylamine, continuously reacting for 20-40 min, and distilling to remove DMF to obtain the sweat-resistant liquid antistatic agent.
Preferably, the molecular weight of the perfluoropolyether diol is 1000 to 1500.
The reaction mechanism is as follows:
perfluoropolyether diol and 2-acryloxyethyl isocyanate firstly generate reaction, then excessive 2-acryloxyethyl isocyanate continuously reacts with trihydroxyethyl methyl quaternary ammonium methyl sulfate, aminated caged polysilsesquioxane and acryloxy are subjected to addition reaction and combined together to obtain the antistatic agent with sweat resistance, so that the durability of the antistatic is improved.
The technical effects are as follows:
compared with the prior art, the preparation method of the sweat-resistant heat transfer ink for stationery printing has the following remarkable effects:
1. the prepared stationery printing sweat-resistant heat transfer ink enables the pigment to be firmly attached and is not easy to fade;
2. the prepared stationery printing sweat-resistant heat transfer ink has good dispersion stability, so that the ink is uniform in color and luster;
3. the prepared stationery printing sweat-resistant heat transfer ink increases the adhesion fastness of the pigment on the surface of a printing substrate and the dispersion stability of the pigment in an ink system;
4. the patterns printed by the sweat-resistant heat transfer ink for stationery printing prepared by the invention have the advantages of sweat resistance, ink drop resistance, delamination resistance and the like.
Drawings
FIG. 1 is an adhesion detection instrument;
FIG. 2 is a graph showing the adhesion trend of 1-12 h.
Detailed Description
The technical solutions of the present invention will be described in detail below in order to clearly understand the technical features, objects, and advantages of the present invention, but the present invention is not limited to the practical scope of the present invention.
Example 1
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 15kg of ternary chlorine vinegar and 20kg of thermoplastic acrylic acid, stirring for 60min, adding 10kg of pigment, 0.5kg of wetting dispersant, 0.5kg of leveling aid, 0.5kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate, 0.5kg of rheological aid, 2kg of filler, 10kg of ethyl acetate, 15kg of n-propyl acetate, 5kg of n-butyl acetate and 5kg of isopropanol, and continuously stirring for 30min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 500rpm.
The pigment is PY180 yellow.
The wetting dispersant is B0K-F-501.
The leveling auxiliary agent is B0K-L-301.
The rheological additive is BYK163.
The filler is calcium carbonate.
Example 2
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 16kg of ternary chlorine vinegar and 25kg of thermoplastic acrylic acid, stirring for 70min, adding 15kg of pigment, 0.8kg of wetting dispersant, 0.8kg of leveling aid, 0.8kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate, 1kg of rheological aid, 4kg of filler, 12kg of ethyl acetate, 18kg of n-propyl acetate, 6kg of n-butyl acetate and 6kg of isopropanol, and continuously stirring for 35min to obtain the sweat-resistant heat transfer ink for stationery printing.
The stirring equipment is sealed stirring equipment, and the rotating speed is 600rpm.
The pigment is PR254.
The wetting dispersant is B0K-F-502.
The leveling auxiliary agent is B0K-L-302.
The rheological additive is BYK333.
The filler is aluminum hydroxide.
Example 3
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 18kg of ternary chlorine vinegar and 30kg of thermoplastic acrylic acid, stirring for 80min, adding 25kg of pigment, 1.2kg of wetting dispersant, 1.2kg of leveling aid, 1.2kg of sweat-resistant antistatic agent, 1.5kg of rheological aid, 6kg of filler, 14kg of ethyl acetate, 22kg of n-propyl acetate, 8kg of n-butyl acetate and 7kg of isopropanol, and continuously stirring for 35min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 900rpm.
The pigment is PR170.
The wetting dispersant is B0K-F-505.
The leveling auxiliary agent is B0K-L-303.
The rheological additive is BYK310.
The filler is aluminum hydroxide.
The preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: adding 0.4kg of perfluoropolyether diol, 9kg of 2-acryloyloxyethyl isocyanate, 1.2kg of dibutyltin dilaurate and 180kg of DMF (dimethyl formamide) into a sealed high-pressure reactor, introducing nitrogen for protection, and reacting at 75 ℃ for 1.5h;
s2: then 38kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate and 1.2kg of dibutyltin dilaurate are added for continuous reaction for 1.2h, 0.15kg of aminated cage type polysilsesquioxane and 2kg of triethylamine are added for continuous reaction for 35min, and DMF is distilled off to obtain the sweat-resistant antistatic agent.
The molecular weight of the perfluoropolyether diol is 1500.
Example 4
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
20kg of ternary chlorine vinegar and 35kg of thermoplastic acrylic acid are mixed and stirred for 90min, 30kg of pigment, 1.5kg of wetting dispersant, 1.5kg of leveling aid, 1.5kg of sweat-resistant antistatic agent, 2kg of rheological aid, 8kg of filler, 15kg of ethyl acetate, 25kg of n-propyl acetate, 10kg of n-butyl acetate and 8kg of isopropanol are added, and the mixture is continuously stirred for 40min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 1000rpm.
The pigment is carbon black.
The wetting dispersant is B0K-F-512.
The leveling auxiliary agent is B0K-L-310.
The rheological additive is BYK306.
The filler is barium sulfate.
The preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: adding 0.5kg of perfluoropolyether diol, 10kg of 2-acryloyloxyethyl isocyanate, 1.5kg of dibutyltin dilaurate and 200kg of DMF (dimethyl formamide) into a sealed high-pressure reactor, introducing nitrogen for protection, and reacting at 77 ℃ for 2h;
s2: then adding 40kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate and 1.5kg of dibutyltin dilaurate, continuing to react for 1.5h, then adding 0.2kg of aminated cage type polysilsesquioxane and 3kg of triethylamine, continuing to react for 40min, and distilling to remove DMF to obtain the sweat-resistant antistatic agent.
The molecular weight of the perfluoropolyether diol is 1500.
Comparative example 1
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 15kg of ternary chlorine vinegar and 20kg of thermoplastic acrylic acid, stirring for 60min, adding 10kg of pigment, 0.5kg of wetting dispersant, 0.5kg of leveling aid, 0.5kg of rheological aid, 2kg of filler, 10kg of ethyl acetate, 15kg of n-propyl acetate, 5kg of n-butyl acetate and 5kg of isopropanol, and continuously stirring for 30min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 500rpm.
The pigment is PY180 yellow.
The wetting dispersant is B0K-F-501.
The leveling auxiliary agent is B0K-L-301.
The rheological additive is BYK163.
The filler is calcium carbonate.
Comparative example 2
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 15kg of ternary chlorine vinegar and 20kg of thermoplastic acrylic acid, stirring for 60min, adding 10kg of pigment, 0.5kg of wetting dispersant, 0.5kg of leveling aid, 0.5kg of sweat-resistant antistatic agent, 0.5kg of rheological aid, 2kg of filler, 10kg of ethyl acetate, 15kg of n-propyl acetate, 5kg of n-butyl acetate and 5kg of isopropanol, and continuously stirring for 30min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 500rpm.
The pigment is PY180 yellow.
The wetting dispersant is B0K-F-501.
The leveling auxiliary agent is B0K-L-301.
The rheological additive is BYK163.
The filler is calcium carbonate.
The preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: adding 0.03kg of perfluoropolyether diol, 5kg of 2-acryloyloxyethyl isocyanate, 0.05kg of dibutyltin dilaurate and 150kg of DMF (dimethyl formamide) into a sealed high-pressure reactor, introducing nitrogen for protection, and reacting at 67 ℃ for 0.5h;
s2: and then 30kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate is added to continue the reaction for 0.5h, 0.01kg of aminated cage type polyshemisiloxane and 1kg of triethylamine are added to continue the reaction for 20 min, and DMF is removed by distillation to obtain the sweat-resistant antistatic agent.
The molecular weight of the perfluoropolyether diol is 1000.
Comparative example 3
A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 15kg of ternary chlorine vinegar and 20kg of thermoplastic acrylic acid, stirring for 60min, adding 10kg of pigment, 0.5kg of wetting dispersant, 0.5kg of leveling aid, 0.5kg of sweat-resistant antistatic agent, 0.5kg of rheological aid, 2kg of filler, 10kg of ethyl acetate, 15kg of n-propyl acetate, 5kg of n-butyl acetate and 5kg of isopropanol, and continuously stirring for 30min to obtain the stationery printing sweat-resistant heat transfer ink.
The stirring equipment is sealed stirring equipment, and the rotating speed is 500rpm.
The pigment is PY180 yellow.
The wetting dispersant is B0K-F-501.
The leveling auxiliary agent is B0K-L-301.
The rheological additive is BYK163.
The filler is calcium carbonate.
The preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: adding 0.03kg of perfluoropolyether diol, 5kg of 2-acryloyloxyethyl isocyanate, 0.05kg of dibutyltin dilaurate and 150kg of DMF (dimethyl formamide) into a sealed high-pressure reactor, introducing nitrogen for protection, and reacting at 67 ℃ for 0.5h;
s2: then 30kg of trihydroxyethyl methyl quaternary ammonium methyl sulfate and 0.05kg of dibutyltin dilaurate are added for continuous reaction for 0.5h, 1kg of triethylamine is added for continuous reaction for 20 min, and DMF is removed by distillation to obtain the sweat-resistant antistatic agent.
The molecular weight of the perfluoropolyether diol is 1000.
The inks prepared in the above examples and comparative examples were subjected to an analytical test according to the test method with reference to QB/T2024-2012, the test results of which are shown in the following table:
| color/grade | Viscosity of the solution | Fineness of fineness | Coloring power/%) | 8h adhesion/%) | Initial drying/mm/30 s | Solvent residue total amount/mg/square meter | Benzene solvent residual quantity/mg/square meter | |
| Example 1 | 5 | 20.8 | 17 | 99 | 93.9 | 30.6 | 5.8 | Undetected |
| Example 2 | 5 | 21.3 | 17 | 99 | 94.2 | 31.4 | 5.6 | Not detected out |
| Example 3 | 5 | 22.0 | 15 | 100 | 95.1 | 33.5 | 5.0 | Not detected out |
| Example 4 | 5 | 21.7 | 16 | 100 | 94.6 | 32.3 | 5.3 | Undetected |
| Comparative example 1 | 4 | 13.7 | 25 | 95 | 90.3 | 21.6 | 8.6 | 2.6 |
| Comparative example 2 | 4 | 14.5 | 23 | 96 | 91.2 | 22.8 | 7.3 | 2.1 |
| Comparative example 3 | 4 | 15.1 | 22 | 97 | 91.9 | 24.1 | 7.1 | 1.9 |
As described above, it is obvious to those skilled in the art that other various changes and modifications can be made based on the technical solution and the technical idea of the present invention, and all such changes and modifications should fall within the protection scope of the claims of the present invention.
Claims (10)
1. A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing and stirring 15-20 parts of ternary chlorine vinegar and 20-35 parts of thermoplastic acrylic acid for 60-90min according to the mass parts, adding 10-30 parts of pigment, 0.5-1.5 parts of wetting dispersant, 0.5-1.5 parts of leveling assistant, 0.5-1.5 parts of trihydroxyethyl methyl quaternary ammonium methyl sulfate, 0.5-2 parts of rheological assistant, 2-8 parts of filler, 10-15 parts of ethyl acetate, 15-25 parts of n-propyl acetate, 5-10 parts of n-butyl acetate and 5-8 parts of isopropanol, and continuously stirring for 30-40min to obtain the sweat-resistant heat transfer ink for stationery printing.
2. A preparation method of stationery printing sweat-resistant heat transfer ink comprises the following operation steps:
mixing 15-20 parts of ternary chlorine vinegar and 20-35 parts of thermoplastic acrylic acid according to the mass parts, stirring for 60-90min, adding 10-30 parts of pigment, 0.5-1.5 parts of wetting dispersant, 0.5-1.5 parts of leveling assistant, 0.5-1.5 parts of sweat-resistant antistatic agent, 0.5-2 parts of rheological assistant, 2-8 parts of filler, 10-15 parts of ethyl acetate, 15-25 parts of n-propyl acetate, 5-10 parts of n-butyl acetate and 5-8 parts of isopropanol, and continuously stirring for 30-40min to obtain the stationery printing sweat-resistant heat transfer ink.
3. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, wherein the method comprises the following steps: the stirring equipment is sealed stirring equipment, and the rotating speed is 500-1000rpm.
4. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, wherein the method comprises the following steps: the pigment is PY180 yellow or PR254 or PR170 or phthalocyanine blue or titanium dioxide or carbon black.
5. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, wherein the method comprises the following steps: the wetting dispersant is B0K-F-501 or B0K-F-502 or B0K-F-505 or B0K-F-508 or B0K-F-512.
6. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, characterized in that: the leveling auxiliary agent is B0K-L-301 or B0K-L-302 or B0K-L-303 or B0K-L-305 or B0K-L-307 or B0K-L-308 or B0K-L-309 or B0K-L-310.
7. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, characterized in that: the rheological additive is BYK163 or BYK333 or BYK310 or BYK306.
8. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 1 or 2, wherein the method comprises the following steps: the filler is calcium carbonate or aluminum hydroxide or barium sulfate.
9. The method for preparing the sweat-resistant heat transfer ink for stationery printing according to claim 2, wherein the method comprises the following steps: the preparation method of the sweat-resistant antistatic agent comprises the following steps:
s1: according to the weight parts, 0.03-0.5 part of perfluoropolyether diol, 5-10 parts of 2-acryloxyethyl isocyanate, 0.05-1.5 parts of dibutyltin dilaurate and 150-200 parts of DMF are added into a closed high-pressure reactor, nitrogen is introduced for protection, and the reaction is carried out for 0.5-2 hours at 67-77 ℃;
s2: and then adding 30-40 parts of trihydroxyethyl methyl quaternary ammonium methyl sulfate and 0.05-1.5 parts of dibutyltin dilaurate, continuously reacting for 0.5-1.5h, then adding 0.01-0.2 part of aminated cage type polysilsesquioxane and 1-3 parts of triethylamine, continuously reacting for 20-40 min, and distilling to remove DMF to obtain the sweat-resistant liquid antistatic agent.
10. The method for preparing the stationery printing sweat-resistant heat transfer ink according to claim 9, wherein: the molecular weight of the perfluoropolyether diol is 1000-1500.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752342A (en) * | 2017-03-06 | 2017-05-31 | 宁波瑞联特油墨有限公司 | A kind of ABS mouldings pad-transfer printing ink and its preparation technology |
| CN109294328A (en) * | 2018-10-10 | 2019-02-01 | 玉溪接装纸制造有限公司 | A kind of gravure ink binder and preparation method thereof suitable for tipping paper of aluminizing |
-
2022
- 2022-12-22 CN CN202211654913.6A patent/CN115895336A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106752342A (en) * | 2017-03-06 | 2017-05-31 | 宁波瑞联特油墨有限公司 | A kind of ABS mouldings pad-transfer printing ink and its preparation technology |
| CN109294328A (en) * | 2018-10-10 | 2019-02-01 | 玉溪接装纸制造有限公司 | A kind of gravure ink binder and preparation method thereof suitable for tipping paper of aluminizing |
Non-Patent Citations (1)
| Title |
|---|
| 宋小平: "《纺织染整助剂生产工艺与技术》", 北京：科学技术文献出版社, pages: 388 - 389 * |
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