CN115893459A - Preparation method of multifunctional water-soluble nano magnesium hydroxide stock solution - Google Patents

Preparation method of multifunctional water-soluble nano magnesium hydroxide stock solution Download PDF

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Publication number
CN115893459A
CN115893459A CN202211638944.2A CN202211638944A CN115893459A CN 115893459 A CN115893459 A CN 115893459A CN 202211638944 A CN202211638944 A CN 202211638944A CN 115893459 A CN115893459 A CN 115893459A
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water
solution
magnesium
stock solution
sodium hydroxide
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郭强
张朋
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Shandong Waterside New Material Technology Co ltd
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Shandong Waterside New Material Technology Co ltd
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Abstract

The invention provides a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution, which is characterized in that magnesium salt is mixed with water at the temperature of 20-30 ℃ for hydrolysis, sodium hydroxide is mixed with water at the temperature of 20-30 ℃ for full stirring, then the two solutions are mixed and stirred to obtain a suspension, then a dispersing agent is dissolved in water and added into the suspension, the suspension is stirred to obtain a clear liquid, the mass concentration of the sodium hydroxide at normal temperature and normal pressure is 1-10%, the mixing is to pour the sodium hydroxide solution into the magnesium salt solution and stir the solution while slowly pouring, the dispersing agent solution is mainly sodium bicarbonate, and the mass concentration of the sodium bicarbonate at normal temperature and normal pressure is 1-20%. The invention has the advantages that: the product is pure water-soluble magnesium hydroxide stock solution, is transparent clear liquid with the pH value close to neutral, is easy to add and absorb, and can be directly or indirectly applied to daily necessities, cosmetics, disinfection and sterilization products, foods, health-care foods and medicines.

Description

Preparation method of multifunctional water-soluble nano magnesium hydroxide stock solution
Technical Field
The invention relates to the field of additive preparation, and in particular relates to a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution.
Background
The magnesium hydroxide has wide application range and can be used as food additives, rubber and plastic flame retardants, cleaning bactericides, antacids for medicines, gastric acid neutralizers and magnesium element supplements. However, magnesium hydroxide is a white crystal or powder, is poorly soluble in water, and is generally applied in a solid form. When used as a magnesium supplement, the magnesium supplement is applied in a liquid form instead of a solid, and is more easily absorbed by the living organism. In the field of magnesium supplementation of living organisms, the prior literature indicates that magnesium acts as an activator for at least 300 different enzyme systems in living organisms. The total magnesium content of a normal adult body is about 25g, wherein 60-65% of the magnesium is present in bones and teeth, and 27% of the magnesium is distributed in soft tissues.
Magnesium is the main cation in human cells in the medical field, is concentrated in mitochondria, is second to potassium and phosphorus, is second to sodium and calcium in extracellular fluid, and is an essential substance for basic biochemical reactions of various cells in vivo. Magnesium is the most important inorganic substance in the intercellular fluid system of a biological organism, and clinical medical experiments on human body functions show that magnesium plays an important role in controlling the activity of carbohydrate, fat and electrolyte conversion, cell permeability, neuromuscular excitability and division and transfer of phosphate by enzyme, and is an important factor for ensuring human health and preventing diseases. Based on the theory of the important role of magnesium for living organisms, a series of physical symptoms may be based on symptoms caused by insufficient magnesium:
1. central nervous system disorders manifested by anhedonia, depression, loss of appetite, disorientation and coma;
2. disorders of the skeletal muscle system manifested by muscle twitching, cramps, movement disorders, muscle atrophy;
3. cardiovascular diseases, i.e. arrhythmia, ischemia, hypertension, acute cardiac arrest;
4. gastrointestinal symptoms such as anorexia, diffuse abdominal pain, diarrhea, and obstipation;
however, most of magnesium element on the market exists in a solid form, a method for supplementing the magnesium element to people in time is lacked, and the absorption rate is low, so that a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution which has high biological absorption efficiency and can be combined with daily necessities to supplement the magnesium element in vivo is needed.
Disclosure of Invention
The invention aims to provide a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution, wherein a solution obtained by mixing a magnesium salt and a sodium hydroxide solution is easier to absorb by a human body, and the concentration of the magnesium salt can be adjusted from 1% to 30% according to the product requirement, so that the magnesium salt can be efficiently utilized.
In order to achieve the purpose of the invention, the invention adopts the technical scheme that:
a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution is characterized in that magnesium salts are mixed with water at the temperature of 20-30 ℃ for hydrolysis, sodium hydroxide is mixed with water at the temperature of 20-30 ℃ for full stirring, then the two solutions are mixed and stirred to obtain a suspension, then a dispersing agent is dissolved in water and added into the suspension, and the mixture is stirred to obtain a clear liquid.
As an improvement, the magnesium salt is a mixture of anhydrous magnesium chloride and magnesium chloride hexahydrate, the mass concentration of the mixture of the magnesium salt and water is 1-30%, and the reaction environment is at normal temperature and normal pressure.
As an improvement, the mass concentration of the sodium hydroxide at normal temperature and normal pressure is 1-10%, and the mixing is to pour the sodium hydroxide solution into the magnesium salt solution, and stirring is required to be carried out while slowly pouring.
As a modification, the dispersant solution is mainly sodium bicarbonate, and the mass concentration of the dispersant solution at normal temperature and normal pressure is 1-20%.
The beneficial effects of the invention are as follows: magnesium hydroxide and a salt solution obtained by mixing a magnesium salt and a sodium hydroxide solution are more convenient for absorption of living organisms, different products can be conveniently added and used by adjusting the mixing concentration ratio, and the final product is a pure water-soluble magnesium hydroxide stock solution, a transparent clear liquid with a pH value close to neutral, is easy to add and absorb, and can be directly or indirectly applied to daily necessities, cosmetics, disinfection and sterilization products, foods, health-care foods and medicine applications.
Drawings
FIG. 1 is a block diagram of a preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution.
Detailed Description
In order to make the content of the present invention more clearly understood, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention. In which like parts are designated by like reference numerals. It should be noted that the terms "front," "back," "left," "right," "upper" and "lower" used in the following description refer to directions in the drawings, and the terms "inner" and "outer" refer to directions toward and away from, respectively, the geometric center of a particular component.
As shown in fig. 1, a method for preparing a multifunctional water-soluble nano magnesium hydroxide stock solution is characterized in that magnesium salt is mixed with water at 20-30 ℃ for hydrolysis, sodium hydroxide is mixed with water at 20-30 ℃ and fully stirred, then the two solutions are mixed and stirred to obtain a suspension, then a dispersing agent is dissolved in water and added into the suspension, and the mixture is stirred to obtain a clear liquid. When the product is required to be added, the product can be diluted by mixing with water and can be directly or directly applied according to the requirements and characteristics of the product, so that the discomfort of taste organs caused by bitter taste and astringent taste is avoided.
The magnesium salt is a mixture of anhydrous magnesium chloride and magnesium chloride hexahydrate, the mass concentration of the mixture of the magnesium salt and water is 1-30%, and the reaction environment is at normal temperature and normal pressure. The mass concentration of the sodium hydroxide is 1-10% at normal temperature and normal pressure, and the mixing is to pour the sodium hydroxide solution into the magnesium salt solution, and to stir the sodium hydroxide solution while pouring the sodium hydroxide solution slowly. The dispersant solution is mainly sodium bicarbonate, and the mass concentration of the dispersant solution at normal temperature and normal pressure is 1-20%. The magnesium salt and the sodium hydroxide solution are mixed and react to obtain the magnesium hydroxide solution and the salt, and the magnesium hydroxide solution is more convenient for human body to absorb.
Example 1: 800 g of anhydrous magnesium chloride is dissolved in 800 ml of water at normal temperature for standby. 10 g of sodium hydroxide is dissolved in 100 ml of water at normal temperature for later use. 10 g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for standby. Slowly dripping sodium hydroxide solution into the magnesium salt hydrolysate, stirring, and separating out white precipitate to obtain suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 30% is obtained.
Example 2: 400 g of anhydrous magnesium chloride is dissolved in 800 ml of water at normal temperature for standby. 5g of sodium hydroxide is dissolved in 100 ml of water at normal temperature for standby. 5g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for standby. Slowly dripping the sodium hydroxide solution into the anhydrous magnesium chloride solution, stirring, and separating out white precipitate to obtain the suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 15% is obtained.
Example 3: 30 g of anhydrous magnesium chloride is dissolved in 800 ml of water at normal temperature for standby. 0.5 g of sodium hydroxide was dissolved in 100 ml of water at room temperature for further use. 0.5 g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for standby. Slowly dripping the sodium hydroxide solution into the anhydrous magnesium chloride solution, stirring, and separating out white precipitate to obtain the suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 1% is obtained.
Example 4: 800 g of magnesium chloride hexahydrate are dissolved in 400 ml of water at normal temperature for later use. 10 g of sodium hydroxide was dissolved in 100 ml of water at room temperature for further use. 10 g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for later use. Slowly dripping sodium hydroxide solution into magnesium chloride hexahydrate, stirring, and separating out white precipitate to obtain suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 30% is obtained.
Example 5: 400 g of magnesium chloride hexahydrate is dissolved in 400 ml of water at normal temperature for later use. 5g of sodium hydroxide is dissolved in 100 ml of water at normal temperature for standby. 5g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for standby. Slowly dripping the sodium hydroxide solution into the magnesium chloride hexahydrate solution, stirring, and separating out white precipitate to obtain a suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 15% is obtained.
Example 6: 40 g of magnesium chloride hexahydrate is dissolved in 400 ml of water at normal temperature for later use. 0.5 g of sodium hydroxide was dissolved in 100 ml of water at room temperature for further use. 0.5 g of sodium bicarbonate is dissolved in 100 ml of water at normal temperature for standby. Slowly dripping sodium hydroxide solution into magnesium chloride hexahydrate, stirring, and separating out white precipitate to obtain suspension. And (3) dripping the sodium bicarbonate solution into the suspension, and stirring until a clear water-soluble magnesium hydroxide stock solution with the mass concentration of 1% is obtained.
In the using process, the pure water-soluble magnesium hydroxide stock solution and the transparent clear liquid with the pH value close to neutral are easy to add and absorb, and can be directly or indirectly applied to daily necessities, cosmetics, disinfection and sterilization products, foods, health-care foods and medicines. The prepared high-concentration stock solution can be directly applied to the outside of an organism, the disinfection and sterilization effects are obvious, and if the stock solution is taken orally, the stock solution needs to be matched according to the actual conditions, so that the taste is prevented from being influenced by excessive bitter and astringent taste.
The preparation process of the stock solution is environment-friendly and harmless, no waste is generated, the whole production process is operated at normal temperature and normal pressure, the process is simple, the dispersibility and the stability are good, meanwhile, the storage and the transportation are convenient, and the use is safe and reliable. The stock solution is directly added into an application example in a liquid form, and can be used as a water-based flame retardant, a curing agent and a nutrition enhancer, so that the stock solution can be widely used as components of daily chemical products, disinfection and sterilization products, foods, health-care foods and medical products.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the present invention, and any modifications, equivalents and improvements made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (4)

1. A preparation method of a multifunctional water-soluble nano magnesium hydroxide stock solution is characterized in that magnesium salt is mixed with water at the temperature of 20-30 ℃ for hydrolysis, sodium hydroxide is mixed with water at the temperature of 20-30 ℃ for full stirring, then the two solutions are mixed and stirred to obtain a suspension, then a dispersing agent is dissolved in water and added into the suspension, and the mixture is stirred to obtain a clear liquid.
2. The method for preparing the multifunctional water-soluble nano magnesium hydroxide stock solution according to claim 1, wherein the magnesium salt is a mixture of anhydrous magnesium chloride and magnesium chloride hexahydrate, the mass concentration of the mixture of the magnesium salt and water is 1-30%, and the reaction environment is at normal temperature and normal pressure.
3. The method for preparing the multifunctional water-soluble nano magnesium hydroxide stock solution according to claim 1, wherein the mass concentration of the sodium hydroxide at normal temperature and normal pressure is 1-10%, and the mixing is performed by pouring the sodium hydroxide solution into the magnesium salt solution and stirring while slowly pouring.
4. The method for preparing the multifunctional water-soluble nano magnesium hydroxide stock solution as claimed in claim 1, wherein the dispersant solution is mainly sodium bicarbonate, and the mass concentration of the dispersant solution is 1 to 20 percent at normal temperature and normal pressure.
CN202211638944.2A 2022-12-20 2022-12-20 Preparation method of multifunctional water-soluble nano magnesium hydroxide stock solution Pending CN115893459A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2032470A1 (en) * 1989-05-05 1990-11-06 Andreas Meier Finely powdery magnesium hydroxide and a process for preparing thereof
CN1556034A (en) * 2004-01-09 2004-12-22 山东师范大学 Synthesis method of magnesium hydroxide nano pipe
WO2008041833A1 (en) * 2006-10-03 2008-04-10 Servicios Industriales Peñoles, S.A. De C.V. Method for producing stable, monodispersed, nanometric magnesium hydroxide and resulting product
CN101177289A (en) * 2007-11-05 2008-05-14 昆明理工大学 Method for preparing fibrous nano magnesium hydrate
CN102444395A (en) * 2010-09-20 2012-05-09 S.P.C.M.股份公司 Process for enhanced oil recovery using asp technique
CN102912623A (en) * 2011-08-02 2013-02-06 上海优先装饰材料有限公司 Novel water-soluble textile product flame retardant and preparation method thereof
WO2014167573A1 (en) * 2013-04-08 2014-10-16 Tata Chemicals Limited A redispersible magnesium hydroxide and a process for manufacturing the same
CN112390272A (en) * 2019-08-19 2021-02-23 唐苑雯 Water-soluble magnesium hydroxide fire retardant and preparation method thereof

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2032470A1 (en) * 1989-05-05 1990-11-06 Andreas Meier Finely powdery magnesium hydroxide and a process for preparing thereof
CN1556034A (en) * 2004-01-09 2004-12-22 山东师范大学 Synthesis method of magnesium hydroxide nano pipe
WO2008041833A1 (en) * 2006-10-03 2008-04-10 Servicios Industriales Peñoles, S.A. De C.V. Method for producing stable, monodispersed, nanometric magnesium hydroxide and resulting product
CN101177289A (en) * 2007-11-05 2008-05-14 昆明理工大学 Method for preparing fibrous nano magnesium hydrate
CN102444395A (en) * 2010-09-20 2012-05-09 S.P.C.M.股份公司 Process for enhanced oil recovery using asp technique
CN102912623A (en) * 2011-08-02 2013-02-06 上海优先装饰材料有限公司 Novel water-soluble textile product flame retardant and preparation method thereof
WO2014167573A1 (en) * 2013-04-08 2014-10-16 Tata Chemicals Limited A redispersible magnesium hydroxide and a process for manufacturing the same
CN112390272A (en) * 2019-08-19 2021-02-23 唐苑雯 Water-soluble magnesium hydroxide fire retardant and preparation method thereof

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
冯玉铖;马海宾;赵洪江;: "水热法可控合成纳米氢氧化镁", 神华科技, no. 06 *
苏明阳;徐竟一;: "分散剂对纳米氢氧化镁制备的影响", 当代化工, no. 03 *
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