CN115750040A - Novel integration device for efficiently removing SO2 and PM of ship - Google Patents
Novel integration device for efficiently removing SO2 and PM of ship Download PDFInfo
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- CN115750040A CN115750040A CN202211334504.8A CN202211334504A CN115750040A CN 115750040 A CN115750040 A CN 115750040A CN 202211334504 A CN202211334504 A CN 202211334504A CN 115750040 A CN115750040 A CN 115750040A
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- Prior art keywords
- washing
- washing liquid
- waste gas
- venturi scrubber
- tower
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- 230000010354 integration Effects 0.000 title claims abstract 8
- 238000005406 washing Methods 0.000 claims abstract description 102
- 239000007788 liquid Substances 0.000 claims abstract description 81
- 239000002912 waste gas Substances 0.000 claims abstract description 23
- 238000005201 scrubbing Methods 0.000 claims abstract description 21
- 238000003795 desorption Methods 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 6
- 238000004140 cleaning Methods 0.000 claims description 13
- 238000005192 partition Methods 0.000 claims description 10
- 238000004065 wastewater treatment Methods 0.000 claims description 7
- 238000009423 ventilation Methods 0.000 claims description 5
- 238000012806 monitoring device Methods 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 8
- 230000008569 process Effects 0.000 abstract description 7
- 238000005265 energy consumption Methods 0.000 abstract description 4
- 238000013461 design Methods 0.000 abstract description 3
- 238000009434 installation Methods 0.000 abstract description 3
- 239000007789 gas Substances 0.000 description 20
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- 238000005200 wet scrubbing Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- -1 alcohol amine Chemical class 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000006911 nucleation Effects 0.000 description 1
- 238000010899 nucleation Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 208000023504 respiratory system disease Diseases 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
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- Treating Waste Gases (AREA)
Abstract
The invention discloses aNovel ship SO 2 With the integration device of the high-efficient desorption of PM, the device sets up to two-layer, and the integration of venturi scrubber is inside traditional scrubbing tower, and will desorption PM washing liquid and desorption SO through ingenious design 2 The washing liquid runs in the washing tower completely and independently, thereby not only realizing PM and SO 2 The high-efficiency removal can obviously reduce the replacement period of the washing liquid, thereby saving water resources and water replenishing energy consumption. In the device, waste gas enters a washing tower from the upper part of the washing tower, PM is removed in a Venturi scrubber, and then the waste gas moves upwards along the outer layer of the washing tower to finish SO in the waste gas in a filler 2 And (4) removing, wherein the waste gas passes through the twice demisting device in the whole removing process, so that the waste gas is fully separated from the washing water. The venturi scrubber is integrated in the traditional washing tower, so that the volume of the washing tower cannot be obviously reduced, the appearance shape of the washing tower is more regular, and the installation convenience of the venturi scrubber on a ship is greatly improved.
Description
Technical Field
The invention relates to the technical field of tail gas purification of marine diesel engines, in particular to a novel marine SO 2 And a PM integrated removing device.
Background
With the rapid development of world trade, the amount of goods in and out of countries has increased dramatically, and maritime transportation is responsible for more than 90% of the goods in the world. Diesel engines are widely used as marine propulsion power plants due to their good performance. At present, the ship engine mainly takes inferior heavy oil as fuel, and the tail gas contains a large amount of SO 2 . International Maritime Organization (IMO) and environmental protection department of china for ship SO 2 Has strict limiting standards. In addition, the exhaust gas discharged by ships contains a large amount of PM, and the large amount of PM discharge can cause respiratory system diseases of human bodies and bring great harm to human health and marine ecology. Various scientific research institutions at home and abroad are dedicated to ship exhaust SO 2 And PM removal technical studies.
A great deal of research shows that wet scrubbing of SO from marine exhaust gas 2 And PM has certain removal effect. Due to SO 2 Has better solubility, SO the wet washing technology can realize SO 2 In the wet washing process, the washing liquid forms mist-like small droplets after being sprayed out from a nozzle, and the small droplets collide with PM particles in the exhaust gasThe nucleation of colliding with the condensation, finally gather, thereby realize the high-efficient desorption of PM, the desorption efficiency of the pure utilization traditional scrubbing tower PM is lower, it sets up the vice scrubbing tower to be generally adopting beside the main washing for the desorption efficiency that improves PM, thereby realize the high-efficient desorption of PM, but the setting of vice scrubbing tower can obviously increase the volume of scrubbing tower, the washing liquid after vice scrubbing tower takes off the granule is seriously polluted simultaneously, later with the washing liquid of serious pollution and comparatively overtightened desulfurization washing liquid mix together can obviously improve the replacement frequency of washing liquid, thereby increase the operation work energy consumption of washing system, because the boats and ships space is narrow and small, therefore small-size and energy-conserving washing system is vital to the green low carbon operation of boats and ships, many scholars have carried out research and design to boats and ships wet scrubbing system, but all have certain defect in the technology.
In the integrated device and method for desulfurization, denitrification and dust removal of ship with the application number of 202210202292.1, NO in ship exhaust gas is realized by an SNCR device x Then the SO in the ship exhaust gas is realized by washing 2 The high-efficiency removal of PM and the obvious problems in the application of the modified device, firstly, the temperature of the ship exhaust gas is low, and NO can not be realized by the SNCR technology x Secondly, the efficient removal of PM cannot be achieved in this patent by a simple scrubber alone.
In the patent of 202120951616.2, the comprehensive absorption tower is used to desulfurize, dedust and decarbonize the tail gas of ship, and the carbon dioxide analyzer separates out carbon dioxide and lean liquid from the decarbonized rich liquid to realize the separation of sulfur oxide, particle and CO in waste gas 2 The removal is efficient. The first liquid collecting section and the second liquid collecting section of the device cannot be completely separated in practical application, the first liquid collecting section and the second liquid collecting section are mixed, ship washing wastewater has a clear discharge standard, and the washed wastewater can be discharged outside only after being treated. In addition, the absorption liquid mixed by alcohol amine belongs to toxic liquid, and can be applied to ships in various aspectsEvaluation and CO 2 The desorption temperature of (2) is high and close to boiling, so that not only can a large amount of heat energy be required, but also a large amount of water resources can be consumed.
In summary, the existing ship SO 2 Has a plurality of problems with PM removing devices, develops a set of ship SO with small volume, low energy consumption and simple structure 2 And an integrated device for efficiently removing PM is necessary.
Disclosure of Invention
The invention provides a novel ship SO 2 And an integrated device for efficiently removing PM, and provides detailed composition, design principle and working flow of the device.
In the invention, SO is realized by utilizing a wet washing technology 2 And efficient removal of PM. The scrubbing tower is set to be two-layer, wherein the venturi scrubbing tower of PM desorption is installed in the inside of scrubbing tower, and diesel engine exhaust waste gas gets into the scrubbing tower from the inside of scrubbing tower from the top down, and waste gas gets rid of PM through the washing of venturi scrubber, then waste gas moves from the skin of scrubbing tower to down and on, passes through one-level defogging device, central authorities' baffle, packing layer and second grade defogging device in proper order, realizes SO 2 After the high-efficiency removal, the waste gas is finally discharged out of the washing tower from the upper part of the washing tower.
Novel ship SO of the invention 2 And the specific working process of the PM high-efficiency removal integrated device is as follows:
(1) The high-temperature exhaust gas discharged by a marine diesel engine moves downwards in a Venturi scrubber in a washing tower, a PM removing and washing spray device is installed in the Venturi scrubber, so that the exhaust gas can be efficiently removed in the Venturi scrubber, the exhaust gas discharged from the Venturi scrubber runs upwards on the outer layer of the washing tower, when the exhaust gas passes through a primary demisting device, a PM washing liquid is effectively separated from the exhaust gas, the exhaust gas continues to go upwards, the PM washing liquid passes through a filtering device below the Venturi scrubber, the PM washing liquid after filtering dregs is recycled to a Venturi nozzle again for carrying out the next working process, a density meter is installed on a PM washing liquid pipeline and used for monitoring the water quality of the PM washing liquid, when the density of the PM washing liquid is too high, part of the PM washing liquid is gradually discharged into a wastewater treatment device, and meanwhile, corresponding fresh liquid is supplied to the PM washing liquid pipeline.
(2) The waste gas passing through the first-stage demisting device continuously goes upward, passes through the ventilation cap above the clapboard, then goes upward to the packing layer above, and simultaneously SO 2 SO sprayed from cleaning solution spraying layer 2 The cleaning liquid also falls to the filling layer, and SO is completed in the filling layer 2 The removal process is performed when SO is shielded by the gas permeable cap 2 After the scrubbing liquid has fallen from the packing layer, SO 2 The cleaning solution only falls to the upper part of the clapboard, but not to the lower part of the clapboard and the SO above the clapboard 2 The washing liquid is transferred to SO again by a water pump 2 Washing the layer for the next cycle of SO 2 Removal of in SO 2 The washing liquid is transported to SO 2 SO can be detected by the sensor in the process of spraying the cleaning solution on the layer 2 The pH and density of the wash liquor are monitored and when conditions are not met, a portion of the SO is removed 2 The washing liquid is gradually discharged into the wastewater treatment device, and meanwhile, the water replenishing device supplies SO to the washing liquid 2 The washing liquid spraying layer supplies corresponding fresh liquid. Has removed SO 2 The waste gas continuously goes upwards to pass through a secondary demisting device, in the secondary demisting device, moisture in the waste gas is removed, and then SO 2 And discharging the exhaust gas after PM treatment from the upper part of the washing tower.
Compared with the prior art, the invention has the following advantages:
(1) In the invention, SO is removed 2 The washing liquid and the washing liquid for removing PM share one set of washing liquid supply system, but the two liquids are separated in the washing tower, because the PM washing liquid can remove a large amount of PM, SO 2 The scrubbing liquid is relatively clean even after multiple cycles, which significantly reduces SO 2 The frequency of the renewal of the washing liquid, at the same time, greatly reduces the clogging rate of the packing. And because the main effect of the PM washing liquid is the removal of PM, the washing liquid can be repeatedly washed for many times, so that the integral replacement and replacement frequency of the washing liquid can be greatly reduced, the water consumption of the system can be greatly reduced, and the energy consumption is obviously reduced accordingly.
(2) Install the venturi scrubber and make the outward appearance of scrubbing tower more regular in the scrubbing tower, obviously reduce the installation space of scrubbing tower to greatly promote its installation and maintenance convenience at boats and ships.
Drawings
FIG. 1 is SO according to the invention 2 And an integrated device for efficiently removing PM.
In FIG. 1, 1-two stage demisting device, 2-SO 2 Three-way electromagnetic valve for washing liquid, 3-SO 2 A cleaning solution spray layer, 4-filler, 5-exhaust gas ventilation cap, 6-residue discharge port, 7-liquid level meter, 8-filter screen, 9-Venturi scrubber, 10-primary demisting device, 11-SO 2 The device comprises a washing liquid sensor, 12-a washing liquid storage tank, 13-a wastewater treatment device, 14-a PM washing liquid three-way electromagnetic valve, 15-a density sensor, 16-a PM washing layer and 17-a middle partition plate.
Detailed Description
Exhaust gas discharged by a marine diesel engine enters the venturi scrubber 9 downwards from the inside of the washing tower, a PM washing liquid is sprayed in the venturi scrubber through the PM washing layer 16, small droplets of the PM washing liquid collide with particulate matters in the exhaust gas and are deposited, the particulate matters in the exhaust gas enter the PM washing liquid, the PM washing liquid falls on the filter screen 8, the washed PM washing liquid is filtered under the action of gravity, filtered residues are discharged from the residue discharge port 6, and then the washing liquid is refuted by a water pump and conveyed to the PM washing liquid washing layer again to remove PM, and the PM is sequentially circulated. In the circulation process of the PM washing liquid, the density sensor 15 monitors the state of the PM washing liquid, when the concentration of the PM washing liquid is too high, part of the PM washing liquid is discharged into the wastewater treatment device 13 through the PM washing liquid three-way electromagnetic valve 14, and meanwhile, fresh washing liquid is replenished to a PM washing liquid washing layer through the washing liquid storage tank 12.
The waste gas discharged from the Venturi scrubber goes upwards along the outer layer of the washing tower, the washing liquid in the waste gas is subjected to gas-liquid separation through the first-stage demisting device 10, then the waste gas goes upwards continuously to pass through the waste gas ventilation cap 5, then the waste gas passes through the filler 4 and the SO 2 Washing liquid is composed of SO 2 The cleaning solution sprays the layer 3 to spray SO in the waste gas 2 With SO 2 The washing liquid generates chemical reaction in the filler 4 to remove SO in the waste gas 2 And removing, then continuously ascending the waste gas, carrying out gas-liquid separation by a secondary demisting device 1, and then discharging the clean waste gas from the upper part of the washing tower. SO (SO) 2 After the washing liquid passes through the filler, it drops on the intermediate partition 17, and since the air-permeable cap 5 is installed 2 The cleaning solution will not fall below the intermediate partition 17, and the SO above the intermediate partition 17 2 The washing liquid is transferred to SO by a water pump 2 Washing the layer with a washing liquid to effect SO 2 In SO 2 In the process of washing liquid circulation, SO 2 Cleaning solution sensor 11 to SO 2 The density of the pH of the washing liquor is monitored, and when the density of the washing liquor is too high, part of the SO is obtained 2 Passing the washing liquid through SO 2 The washing liquid three-way electromagnetic valve 2 discharges into a wastewater treatment device 13, and the washing liquid storage tank 12 simultaneously discharges to SO 2 The washing liquid washing layer is supplemented with fresh washing liquid.
Claims (5)
1. Novel ship SO 2 And the integration device of the high-efficient desorption of PM, its characterized in that: the device comprises a first-stage demister, a second-stage demister, a PM washing layer and SO 2 Cleaning solution washing layer, venturi scrubber, filter screen, ventilation cap, filler, intermediate partition board, liquid level monitoring device, density sensor and SO 2 Cleaning solution sensor, SO 2 A cleaning solution three-way electromagnetic valve, a PM cleaning solution three-way electromagnetic valve, a cleaning solution storage tank and a wastewater treatment device.
2. Novel ship SO according to claim 1 2 And the integration device of the high-efficient desorption of PM, its characterized in that: the Venturi scrubber for removing PM is arranged in the scrubbing tower, the first-stage demisting device is arranged below the middle partition plate, and the second-stage demisting device is arranged above the middle partition plate.
3. Novel ship SO according to claim 1 2 And the integration device of the high-efficient desorption of PM, its characterized in that: the Venturi scrubber for removing the PM is arranged below the inner part of the washing tower and is close to the filter screen below.
4. Novel ship SO according to claim 1 2 And the integration device of the high-efficient desorption of PM, its characterized in that: SO is separated by an intermediate partition plate 2 Completely separating the scrubbing solution from the PM-removing scrubbing solution, SO after scrubbing 2 The removed washing liquid falls above the middle partition plate, so that the height of the washing liquid above the middle partition plate cannot exceed the waste gas ventilation cap.
5. Novel ship SO according to claim 1 2 And the integration device of the high-efficient desorption of PM, its characterized in that: PM removal and SO 2 The removal uses a common washing liquid storage tank and wastewater treatment device, PM removal and SO 2 Two independent circulation systems are used for the removal.
Priority Applications (1)
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CN202211334504.8A CN115750040A (en) | 2022-10-28 | 2022-10-28 | Novel integration device for efficiently removing SO2 and PM of ship |
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CN202211334504.8A CN115750040A (en) | 2022-10-28 | 2022-10-28 | Novel integration device for efficiently removing SO2 and PM of ship |
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CN202211334504.8A Pending CN115750040A (en) | 2022-10-28 | 2022-10-28 | Novel integration device for efficiently removing SO2 and PM of ship |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN117180975A (en) * | 2023-11-08 | 2023-12-08 | 中太海碳(上海)环保科技有限公司 | A integrative reaction unit for boats and ships tail gas treatment |
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