CN115702693B - Sweet cigarette containing slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper and preparation method thereof - Google Patents
Sweet cigarette containing slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper and preparation method thereof Download PDFInfo
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- CN115702693B CN115702693B CN202110937304.0A CN202110937304A CN115702693B CN 115702693 B CN115702693 B CN 115702693B CN 202110937304 A CN202110937304 A CN 202110937304A CN 115702693 B CN115702693 B CN 115702693B
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- sweet
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- sweetener
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- 235000009508 confectionery Nutrition 0.000 title claims abstract description 137
- 235000019504 cigarettes Nutrition 0.000 title claims abstract description 64
- 238000013270 controlled release Methods 0.000 title claims abstract description 59
- 238000002360 preparation method Methods 0.000 title claims abstract description 43
- 238000012546 transfer Methods 0.000 title claims abstract description 41
- 235000003599 food sweetener Nutrition 0.000 claims abstract description 97
- 239000003765 sweetening agent Substances 0.000 claims abstract description 97
- 239000000463 material Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 57
- 239000011159 matrix material Substances 0.000 claims abstract description 47
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical compound CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims abstract description 46
- 239000012754 barrier agent Substances 0.000 claims abstract description 37
- 239000000796 flavoring agent Substances 0.000 claims abstract description 29
- 235000019634 flavors Nutrition 0.000 claims abstract description 29
- 238000013268 sustained release Methods 0.000 claims abstract description 24
- 239000001087 glyceryl triacetate Substances 0.000 claims abstract description 23
- 235000013773 glyceryl triacetate Nutrition 0.000 claims abstract description 23
- 230000002459 sustained effect Effects 0.000 claims abstract description 23
- 229960002622 triacetin Drugs 0.000 claims abstract description 23
- 239000000243 solution Substances 0.000 claims description 158
- 239000000126 substance Substances 0.000 claims description 78
- 238000003756 stirring Methods 0.000 claims description 77
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 57
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 48
- 239000002253 acid Substances 0.000 claims description 48
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 40
- 230000008569 process Effects 0.000 claims description 39
- 238000007639 printing Methods 0.000 claims description 36
- 238000002156 mixing Methods 0.000 claims description 33
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 32
- 239000003921 oil Substances 0.000 claims description 30
- 235000019198 oils Nutrition 0.000 claims description 30
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 25
- 239000002981 blocking agent Substances 0.000 claims description 20
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 19
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 19
- 235000015165 citric acid Nutrition 0.000 claims description 19
- 239000001630 malic acid Substances 0.000 claims description 19
- 235000011090 malic acid Nutrition 0.000 claims description 19
- 150000001720 carbohydrates Chemical class 0.000 claims description 18
- 229930006000 Sucrose Natural products 0.000 claims description 16
- 239000004310 lactic acid Substances 0.000 claims description 16
- 235000014655 lactic acid Nutrition 0.000 claims description 16
- 239000005720 sucrose Substances 0.000 claims description 16
- FTLYMKDSHNWQKD-UHFFFAOYSA-N (2,4,5-trichlorophenyl)boronic acid Chemical compound OB(O)C1=CC(Cl)=C(Cl)C=C1Cl FTLYMKDSHNWQKD-UHFFFAOYSA-N 0.000 claims description 14
- 229930091371 Fructose Natural products 0.000 claims description 14
- 239000005715 Fructose Substances 0.000 claims description 14
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 14
- 239000003995 emulsifying agent Substances 0.000 claims description 14
- 229940085605 saccharin sodium Drugs 0.000 claims description 14
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 claims description 13
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 claims description 13
- UDIPTWFVPPPURJ-UHFFFAOYSA-M Cyclamate Chemical compound [Na+].[O-]S(=O)(=O)NC1CCCCC1 UDIPTWFVPPPURJ-UHFFFAOYSA-M 0.000 claims description 12
- 239000000625 cyclamic acid and its Na and Ca salt Substances 0.000 claims description 12
- 229960001462 sodium cyclamate Drugs 0.000 claims description 12
- WBZFUFAFFUEMEI-UHFFFAOYSA-M Acesulfame k Chemical compound [K+].CC1=CC(=O)[N-]S(=O)(=O)O1 WBZFUFAFFUEMEI-UHFFFAOYSA-M 0.000 claims description 11
- 239000004384 Neotame Substances 0.000 claims description 11
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 11
- 239000004376 Sucralose Substances 0.000 claims description 11
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 11
- 229960004998 acesulfame potassium Drugs 0.000 claims description 11
- 235000010358 acesulfame potassium Nutrition 0.000 claims description 11
- 239000000619 acesulfame-K Substances 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 11
- 235000019412 neotame Nutrition 0.000 claims description 11
- HLIAVLHNDJUHFG-HOTGVXAUSA-N neotame Chemical compound CC(C)(C)CCN[C@@H](CC(O)=O)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 HLIAVLHNDJUHFG-HOTGVXAUSA-N 0.000 claims description 11
- 108010070257 neotame Proteins 0.000 claims description 11
- 235000019408 sucralose Nutrition 0.000 claims description 11
- BAQAVOSOZGMPRM-QBMZZYIRSA-N sucralose Chemical compound O[C@@H]1[C@@H](O)[C@@H](Cl)[C@@H](CO)O[C@@H]1O[C@@]1(CCl)[C@@H](O)[C@H](O)[C@@H](CCl)O1 BAQAVOSOZGMPRM-QBMZZYIRSA-N 0.000 claims description 11
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 claims description 10
- 229920002472 Starch Polymers 0.000 claims description 10
- 230000004888 barrier function Effects 0.000 claims description 10
- 239000008101 lactose Substances 0.000 claims description 10
- 239000008107 starch Substances 0.000 claims description 10
- 235000019698 starch Nutrition 0.000 claims description 10
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 9
- 235000011054 acetic acid Nutrition 0.000 claims description 9
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 claims description 9
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 claims description 9
- 239000008103 glucose Substances 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 7
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- 108010011485 Aspartame Proteins 0.000 claims description 6
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 229920002125 Sokalan® Polymers 0.000 claims description 6
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000000605 aspartame Substances 0.000 claims description 6
- 235000010357 aspartame Nutrition 0.000 claims description 6
- IAOZJIPTCAWIRG-QWRGUYRKSA-N aspartame Chemical compound OC(=O)C[C@H](N)C(=O)N[C@H](C(=O)OC)CC1=CC=CC=C1 IAOZJIPTCAWIRG-QWRGUYRKSA-N 0.000 claims description 6
- 229960003438 aspartame Drugs 0.000 claims description 6
- 238000005520 cutting process Methods 0.000 claims description 6
- 238000007646 gravure printing Methods 0.000 claims description 6
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 6
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 6
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 claims description 6
- 239000004584 polyacrylic acid Substances 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 238000004080 punching Methods 0.000 claims description 6
- 238000005096 rolling process Methods 0.000 claims description 6
- 229940081974 saccharin Drugs 0.000 claims description 6
- 235000019204 saccharin Nutrition 0.000 claims description 6
- CVHZOJJKTDOEJC-UHFFFAOYSA-N saccharin Chemical compound C1=CC=C2C(=O)NS(=O)(=O)C2=C1 CVHZOJJKTDOEJC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000901 saccharin and its Na,K and Ca salt Substances 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- 239000003549 soybean oil Substances 0.000 claims description 6
- 235000012424 soybean oil Nutrition 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 229920008347 Cellulose acetate propionate Polymers 0.000 claims description 5
- 229920001747 Cellulose diacetate Polymers 0.000 claims description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 5
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 5
- HVUMOYIDDBPOLL-XGKPLOKHSA-N [2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XGKPLOKHSA-N 0.000 claims description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 5
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 5
- 239000011118 polyvinyl acetate Substances 0.000 claims description 5
- 235000011078 sorbitan tristearate Nutrition 0.000 claims description 5
- -1 sucrose ester Chemical class 0.000 claims description 5
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 4
- IJCWFDPJFXGQBN-RYNSOKOISA-N [(2R)-2-[(2R,3R,4S)-4-hydroxy-3-octadecanoyloxyoxolan-2-yl]-2-octadecanoyloxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-RYNSOKOISA-N 0.000 claims description 4
- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 claims description 4
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 claims description 4
- 229920000223 polyglycerol Polymers 0.000 claims description 4
- WBHHMMIMDMUBKC-QJWNTBNXSA-M ricinoleate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC([O-])=O WBHHMMIMDMUBKC-QJWNTBNXSA-M 0.000 claims description 4
- 229940066675 ricinoleate Drugs 0.000 claims description 4
- FKOKUHFZNIUSLW-UHFFFAOYSA-N 2-Hydroxypropyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(C)O FKOKUHFZNIUSLW-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004090 dissolution Methods 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 claims description 3
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 3
- 229940093625 propylene glycol monostearate Drugs 0.000 claims description 3
- 244000061176 Nicotiana tabacum Species 0.000 claims 1
- 235000019605 sweet taste sensations Nutrition 0.000 abstract description 4
- 239000012730 sustained-release form Substances 0.000 abstract 1
- 238000005303 weighing Methods 0.000 description 37
- 241000208125 Nicotiana Species 0.000 description 10
- 230000000694 effects Effects 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- 210000000214 mouth Anatomy 0.000 description 5
- 230000000391 smoking effect Effects 0.000 description 5
- 238000003825 pressing Methods 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000000265 homogenisation Methods 0.000 description 3
- 210000002200 mouth mucosa Anatomy 0.000 description 3
- 238000001514 detection method Methods 0.000 description 2
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- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 210000004400 mucous membrane Anatomy 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- QOXOZONBQWIKDA-UHFFFAOYSA-N 3-hydroxypropyl Chemical group [CH2]CCO QOXOZONBQWIKDA-UHFFFAOYSA-N 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- 235000006679 Mentha X verticillata Nutrition 0.000 description 1
- 235000002899 Mentha suaveolens Nutrition 0.000 description 1
- 235000001636 Mentha x rotundifolia Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
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- 238000004945 emulsification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229940116364 hard fat Drugs 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004877 mucosa Anatomy 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
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- 210000003296 saliva Anatomy 0.000 description 1
- IJCWFDPJFXGQBN-BIFNRIDTSA-N sorbitan tristearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)[C@H]1OC[C@@H](O)[C@@H]1OC(=O)CCCCCCCCCCCCCCCCC IJCWFDPJFXGQBN-BIFNRIDTSA-N 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
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Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
- Fats And Perfumes (AREA)
Abstract
The invention provides a sweet cigarette containing a slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper and a preparation method thereof. The method comprises the following steps: 1. preparing a filter stick containing sustained and controlled release sweet essence; 2. preparing double-barrier agent transfer paper; 3. and preparing the sweet cigarette. According to the invention, the emulsified wall material matrix is used as a fat-soluble matrix, so that the problem that the water-soluble sweetener cannot be directly dissolved in the glyceryl triacetate is effectively solved, the filter stick with the sustained and controlled release sweet flavor is prepared, the transfer paper containing the double barrier agents is further combined on the basis, the sustained release and control of sweet taste are further improved, and finally the sweet cigarette with better taste and longer sweet feeling is prepared.
Description
Technical Field
The invention belongs to the technical field of tobacco flavors, and particularly relates to a filter tip with a slow-release and controlled-release sweet flavor and a double-barrier agent and a preparation method thereof.
Background
In the cigarette smoking process, when bitter substances generated by high-temperature combustion of tobacco shreds are combined with oral mucosa substances, the oral mucosa or throat mucosa is converged, and the oral mucosa or throat dryness can be generated by the mucosal convergence, so that negative feeling is brought to consumers. Sweetener works in contrast to the mucous membranes of the mouth or throat, which are manifested by mucous membrane dispersion, moist mouth and throat. Therefore, cigarettes that give a sweet feel to consumers during smoking are popular in the market and have also been a goal of the development of cigarette products that has been pursued.
The cigarette filter stick can directly contact the lips, and the cigarette filter stick directly senses sweet feeling when the cigarette is smoked, so that the cigarette filter stick becomes a main carrier for sweetening. The prior art has mostly prepared the tobacco sweetener as granules and placed in the filter stick. Such techniques require that the tobacco sweetener be first prepared into particles, then added to the filter stick, and then combined with the normal filter stick before and after. The process is complicated and costly, and the sweetening effect of this technique is not direct and undesirable because the portion in contact with the mouth is not a granular segment with sweetener, but a normal filter rod.
The sweetener is prepared into sweet essence and added into the triacetin, and the sweet essence is added into tows along with the triacetin in the rod making process, so that the whole filter rod can be made into tows with sweet feeling by preparing the sweet cigarette filter rod, and when a consumer sucks the sweet cigarette filter rod, the mouth can be directly contacted with the sweet essence to feel sweet feeling. Simple process, low cost and good sweetening effect, and can achieve the sweetening effect only by a small amount of sweetener. However, this technique has not yet been developed, mainly because the sweetener is water-soluble, but the glyceryl triacetate is not water-soluble, and such sweetener cannot be directly dissolved in the glyceryl triacetate. In addition, there has not been found a filter tip sweetened by a filter rod and a transfer paper together to achieve a better taste for sucking and a method for producing the same.
Disclosure of Invention
In order to solve the technical problems, the invention provides a sweet cigarette containing a slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper and a preparation method thereof. Aiming at the special requirements in the preparation process of the tobacco essence and the filter stick, the invention provides a filter tip with better sucking taste by simultaneously sweetening the filter stick and the transfer paper together. The filter tip prepared by the invention has good sweet effect.
The technical scheme provided by the invention is as follows:
the invention aims at providing a preparation method of a sweet cigarette containing a slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper, which comprises the following steps:
1. sustained and controlled release sweet essence for preparing filter stick
(1) Emulsifying a wall material by using an emulsifying agent to obtain a wall material matrix, and dissolving the wall material matrix in an ethanol water solution to obtain a wall material matrix solution;
(2) Preparing a sweetener solution;
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
(4) Mixing the solution I and glyceryl triacetate according to the mass ratio of 1:1-20, dispersing in the atmosphere with the pressure of 30-60Mpa, stirring at 13000-25000r/min and the dispersing time of 90-150min to obtain the sustained and controlled release sweet essence;
(5) Spraying the slow-release sweet flavor essence prepared in the first step on the tow with 10-30% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a forming cavity of a filter tip forming unit to form a tows strip containing sweet essence, and then wrapping forming paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor;
2. preparation of double Barrier transfer papers
(1) Preparation of Barrier A solution
Uniformly mixing the barrier agent A and 95% -100% (v/v) ethanol water solution according to a mass ratio of 1:1-20, wherein the stirring speed is 100-500r/min in the dissolving process, the stirring time is 0.5-2h, and the dissolving temperature is 35-55 ℃;
the blocking agent A is one or a mixture of more of epoxidized soybean oil, cellulose diacetate, cellulose acetate propionate, polyvinyl butyral, polyvinyl acetate and hydroxyethyl cellulose;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B solution;
dissolving the blocking agent B in 0% -20% (v/v) ethanol water solution, and uniformly mixing to obtain a blocking agent B solution;
the blocking agent B is one or a mixture of more of polyethylene glycol, polyvinyl alcohol, polyacrylic acid, hydroxypropyl methyl cellulose and hydroxypropyl cellulose;
(2.2) preparing sweet essence
Saccharide substances, sweetener and acid substances are mixed according to the mass ratio of 3-25:1 to 5:3-10 is dissolved in 0% -20% (v/v) ethanol water solution;
(2.3) dispersing the barrier agent B solution, the sweet essence and the gloss oil at high speed under high pressure to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step to prepare the sweet cigarette.
Further, the wall material in the first step is one or a mixture of more than one of sucrose ester, polyglycerol ricinoleate, vinyl acetate, monoglyceride and propylene glycol monostearate; the mass ratio of the wall material matrix to the ethanol water solution is 1:1-15, and the mass concentration of the ethanol water solution is 50% -70%; the stirring speed of the mixing is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
Further, the emulsifier in the first step is one or a mixture of several of Span60, span65, span80 and gluconate-SS, and the HLB value of the emulsifier is 3-6.
Further, the sweetener solution in the step one (2) is prepared by dissolving sugar substances, sweeteners and acid substances in an ethanol water solution with the mass concentration of 0-20%; wherein the mass ratio of the sugar substances to the sweetening agent to the acid substances is 3-25:1-5:3-10; the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol water solution is 1:1-20; the saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from one or more of saccharin, saccharin sodium, sodium cyclamate, aspartame, acesulfame potassium, sucralose and neotame; the acid substance is selected from one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid; the stirring speed is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h in the dissolving process.
Further, in the step one (3), the mass ratio of the sweetener solution to the wall material matrix solution is 1:1-20; stirring at a speed of 100-500r/min and a temperature of 25-55deg.C for 0.5-2h; the mixing method is to dropwise add sweetener solution into wall material matrix solution while stirring.
Further, the concentration of the ethanol water solution in the step two (2.1) is 0% -20%; the stirring speed of dissolution is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
Further, the concentration of the ethanol water solution in the step two (2.2) is 0% -20%; the stirring speed in the dissolving process is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
The saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from saccharin, saccharin sodium, sodium cyclamate, and sodium cyclamate aspartame, acesulfame potassium one or a mixture of more of sucralose and neotame; the acid substance is one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid.
Further, in the second step (2.3), the mass ratio of the barrier agent B solution to the sweet flavor and the gloss oil is 1-10:1-10:20-80, wherein the dispersion pressure is 30-60MPa, and the stirring speed is 13,000-25,000r/min.
Further, in the second step (3),
in the printing process of the base color and the blocking agent A, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4mpa;
in the controlled-release sweet photosensitive oil printing process, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4mpa.
It is a second object of the present invention to provide a filter prepared by the above method.
The invention has the beneficial effects that:
(1) The sweet essence prepared by the invention is a fat-soluble controlled-release sweet essence for cigarettes, can be added into triacetin to directly prepare a sweet filter stick, and widens the application range of the sweet essence;
(2) The emulsified wall material matrix is used as the fat-soluble matrix, so that the water-soluble sweetener is wrapped, the problem that the water-soluble sweetener cannot be directly dissolved in the glyceryl triacetate can be effectively solved, and the utilization effect of the sweetener is greatly improved;
(3) In the preparation process of the sweet glyceryl triacetate, a ultrasonic emulsification technology is adopted to uniformly mix the liquid slow-release mint essence and the glyceryl triacetate together, so that the uniform distribution of the sweet feel of the filter stick for cigarettes is ensured;
(4) The solvents adopted by the invention are water and ethanol, which are edible solvents, so that the invention is safer, and can combine the triacetin and the slow-release sweet essence, and the system is more uniform;
(5) The preparation method provided by the invention has the advantages of simple process, low cost and good sweetening effect, and the sweetening effect can be achieved only by a small amount of sweetener;
(6) The essence and the sweetener in the filter stick are mainly added into the glyceryl triacetate, saliva gradually contacts the filter stick in the process of smoking the cigarette by a consumer, and the essence is slowly and continuously dissolved and released, so that the comfort of smoking the cigarette is improved, and the harm of the cigarette to the human health is reduced;
(7) According to the invention, the filter tip with better sweet effect is prepared by respectively sweetening the filter stick and the transfer paper, the sweetening filter stick and the transfer paper cooperate, the transfer paper can not only effectively sweeten but also play a role in blocking the sweetener, the sweetening effect and the sucking taste are further improved, and the sweet feeling is more durable.
Detailed Description
The present invention will be further described with reference to the following specific examples, which should not be construed as limiting the scope of the invention.
A sweet cigarette containing a slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper and a preparation method thereof comprise the following steps:
1. preparation of filter stick containing sustained and controlled release sweet flavor
(1) Emulsifying a wall material by using an emulsifying agent to obtain a wall material matrix, and dissolving the wall material matrix in an ethanol water solution to obtain a wall material matrix solution;
(2) Preparing a sweetener solution;
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
(4) Mixing the solution I and glyceryl triacetate according to the mass ratio of 1:1-20, dispersing in the atmosphere with the pressure of 30-60Mpa, stirring at 13000-25000r/min and the dispersing time of 90-150min to obtain the sustained and controlled release sweet essence;
(5) Spraying the slow-release sweet flavor essence prepared in the first step on the tow with 10-30% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a forming cavity of a filter tip forming unit to form a tows strip containing sweet essence, and then wrapping forming paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor;
2. preparation of double Barrier transfer papers
(1) Preparation of Barrier A solution
Uniformly mixing the barrier agent A and 95% -100% (v/v) ethanol water solution according to a mass ratio of 1:1-20, wherein the stirring speed is 100-500r/min in the dissolving process, the stirring time is 0.5-2h, and the dissolving temperature is 35-55 ℃;
the blocking agent A is one or a mixture of more of epoxidized soybean oil, cellulose diacetate, cellulose acetate propionate, polyvinyl butyral, polyvinyl acetate and hydroxyethyl cellulose;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B solution;
dissolving the blocking agent B in 0% -20% (v/v) ethanol water solution, and uniformly mixing to obtain a blocking agent B solution;
the blocking agent B is one or a mixture of more of polyethylene glycol, polyvinyl alcohol, polyacrylic acid, hydroxypropyl methyl cellulose and hydroxypropyl cellulose;
(2.2) preparing sweet essence
Saccharide substances, sweetener and acid substances are mixed according to the mass ratio of 3-25:1 to 5:3-10 is dissolved in 0% -20% (v/v) ethanol water solution;
(2.3) dispersing the barrier agent B solution, the sweet essence and the gloss oil at high speed under high pressure to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step to prepare the sweet cigarette.
Further, the wall material in the first step is one or a mixture of more than one of sucrose ester, polyglycerol ricinoleate, vinyl acetate, monoglyceride and propylene glycol monostearate; the mass ratio of the wall material matrix to the ethanol water solution is 1:1-15, and the concentration of the ethanol water solution is 50% -70%; the stirring speed of the mixing is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
Further, the emulsifier in the first step is one or a mixture of several of Span60, span65, span80 and gluconate-SS, and the HLB value of the emulsifier is 3-6.
Further, the sweetener solution in the step one (2) is prepared by dissolving sugar substances, sweeteners and acid substances in an ethanol water solution with the mass concentration of 0-20%; wherein the mass ratio of the sugar substances to the sweetening agent to the acid substances is 3-25:1-5:3-10; the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol water solution is 1:1-20; the saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from one or more of saccharin, saccharin sodium, sodium cyclamate, aspartame, acesulfame potassium, sucralose and neotame; the acid substance is selected from one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid; the stirring speed is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h in the dissolving process.
Further, in the step one (3), the mass ratio of the sweetener solution to the wall material matrix solution is 1:1-20; stirring at a speed of 100-500r/min and a temperature of 25-55deg.C for 0.5-2h; the mixing method is to dropwise add sweetener solution into wall material matrix solution while stirring.
Further, the concentration of the ethanol aqueous solution in the step two (2.1) is 0% -20% (v/v); the stirring speed of dissolution is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
Further, the concentration of the ethanol aqueous solution in the step two (2.2) is 0% -20% (v/v); the stirring speed in the dissolving process is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
The saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from saccharin, saccharin sodium, sodium cyclamate, and sodium cyclamate aspartame, acesulfame potassium one or a mixture of more of sucralose and neotame; the acid substance is one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid.
Further, in the second step (2.3), the mass ratio of the barrier agent B solution to the sweet flavor and the gloss oil is 1-10:1-10:20-80, wherein the dispersion pressure is 30-60MPa, and the stirring speed is 13,000-25,000r/min.
Further, in the second step (3),
in the printing process of the base color and the blocking agent A, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4mpa;
in the controlled-release sweet photosensitive oil printing process, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4mpa.
In the invention, the ethanol concentration refers to volume fraction.
Example 1
1. Preparation of filter stick containing sustained and controlled release sweet flavor
(1) Preparation of wall Material matrix solution
(1) According to sucrose ester: polyglycerol ricinoleate = 4:1 (mass ratio) weighing 5kg of wall material;
(2) selecting Span60 as an emulsifier, and weighing Span60 g according to the weight ratio of wall material to the emulsifier of 10:1;
(3) according to the wall material matrix: 50% aqueous ethanol solution=1:1 (mass ratio) 5.5kg of 70% aqueous ethanol solution was weighed, mixed and stirred therein at a stirring speed of 300r/min and a temperature of 40 ℃ for 0.5h, to obtain a wall material matrix solution.
(2) Preparing a sweetener solution;
(1) the total weight of sucrose and fructose is weighed according to the mass ratio of 2:1 and 25kg, and the sucrose and the fructose are used as sugar substances.
(2) Weighing saccharin sodium and neotame together to obtain 1kg according to the mass ratio of 10:1, and using the saccharin sodium and neotame as sweetener.
(3) Weighing 3kg of total lactic acid, citric acid and malic acid according to the mass ratio of 1:5:8, and using the total lactic acid, citric acid and malic acid as acid substances.
(4) The following substances are prepared from the following substances: sweetener: acid = 25:1:3 (mass ratio) weighing the saccharide, the sweetener and the acid substances, wherein the total mass of the saccharide, the sweetener and the acid substances is 5kg, and weighing 5kg of 0% ethanol water solution (namely water solution) according to the mass ratio of the saccharide, the sweetener and the acid substances to the ethanol water solution of 1:1. And mixing and stirring for 0.5 hour at 25 ℃ at the stirring speed of 300rpm until the components are uniformly mixed to obtain the sweetener solution of the embodiment.
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
1kg of each of the wall material matrix solution and the sweetener solution was weighed according to the mass ratio of the wall material matrix solution to the sweetener=1:1, and the sweetener solution was dropwise added to the wall material matrix solution at 25 ℃ with stirring at 300rpm, and stirred for 0.5 hour to obtain the solution I of the present example.
(4) Mixing the solution I with glyceryl triacetate, and dispersing at high speed to obtain the sustained and controlled release sweet essence.
Weighing 2kg of each of the solution I and the glyceryl triacetate according to the mass ratio of the solution I to the glyceryl triacetate=1:1; the dispersion was carried out in an atmosphere under a pressure of 30MPa, the stirring speed was 13000r/min, and the dispersion time was 90min.
(5) Spraying the essence with the sustained and controlled release sweet taste on the tow with the mass of 10% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a molding cavity of a filter tip molding machine set to form a tows strip containing sweet essence, and wrapping molding paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor.
2. Preparation of double Barrier transfer papers
(1) Preparation of Barrier A-epoxidized Soybean oil solution
In example 1, epoxidized soybean oil was used as the barrier agent a. Uniformly stirring epoxidized soybean oil and 95% ethanol in a mass ratio of 1:1 at 35 ℃ at a stirring speed of 100r/min for 0.5h to obtain a barrier agent A solution;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B-polyethylene glycol solution;
polyethylene glycol was used as the blocking agent B in example 1. Dissolving polyethylene glycol in 0% ethanol water solution, stirring at a speed of 100r/min and a temperature of 25 ℃, and uniformly mixing to obtain a barrier agent B solution;
(2.2) preparing sweet essence
(1) Weighing 30kg of sucrose and fructose according to the mass ratio of 2:1, and using the sucrose and the fructose as sugar substances.
(2) Weighing saccharin sodium and neotame which are 1kg in total according to the mass ratio of 10:1, and using the saccharin sodium and neotame as sweetener.
(3) Weighing 3kg of total lactic acid, citric acid and malic acid according to the mass ratio of 1:5:8, and using the total lactic acid, citric acid and malic acid as acid substances.
(4) According to the sugar substances: sweetener: acid = 25:1:3 (mass ratio) weighing sugar substances (sucrose and fructose), sweetener (saccharin sodium, neotame) and acid substances (lactic acid, citric acid and malic acid), wherein the total mass of the sugar substances, the sweetener and the acid substances is 5kg, and weighing 0% ethanol water solution 5kg according to the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol water solution of 1:1. And mixing and stirring for 0.5 hour at 25 ℃ and stirring speed of 300rpm until the components are uniformly mixed, so as to obtain the sweet essence of the embodiment.
(2.3) adding a barrier agent B-polyethylene glycol solution, sweet essence and gloss oil according to a mass ratio of 1:1:20, performing high-speed dispersion and high-pressure homogenization treatment for 90min under the conditions of 30MPa of pressure and 13,000r/min of stirring speed to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing; the temperature of the oven is 140 ℃, the speed of the vehicle is 60m/min, and the roller pressure is 0.2MPa;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil; the temperature of the oven is 140 ℃, the speed of the vehicle is 60m/min, and the roller pressure is 0.2MPa;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step by adopting a conventional method to prepare the sweet cigarette.
Example 2
Preparation of sweet cigarette
1. Sustained and controlled release sweet essence for preparing filter stick
(1) Preparation of wall Material matrix solution
(1) According to the following steps: monoglyceride=3: 1 (mass ratio) weighing 2kg of wall material;
(2) span65: span: 80=1: 1 (mass ratio) is an emulsifier, and Span65 and Span80 are weighed according to the mass ratio of wall material to the emulsifier of 10:1 to be 200g in total;
(3) according to the wall material matrix: 60% aqueous ethanol solution=1:5 (mass ratio) 11kg of 70% aqueous ethanol solution was weighed, mixed and stirred therein at a stirring speed of 400r/min and a temperature of 35 ℃ for 1 hour to obtain a wall material matrix solution.
(2) Preparing a sweetener solution;
(1) weighing glucose, maltose and fructose according to the mass ratio of 2:1:1, and taking the total of 20kg as sugar substances.
(2) Weighing saccharin sodium and sodium cyclamate together to obtain 1kg according to the mass ratio of 10:1, and using as sweetener.
(5) Weighing 3kg of acetic acid, citric acid and malic acid according to the mass ratio of 1:5:8, and using the mixture as an acid substance.
(4) According to the sugar substances: sweetener: acid = 20:1:3 (mass ratio) weighing the saccharide, the sweetener and the acid substances, wherein the total mass of the saccharide, the sweetener and the acid substances is 1kg, and weighing 10kg of 10% ethanol water solution according to the mass ratio of the saccharide, the sweetener and the acid substances to the ethanol water solution of 1:10. Mixing and stirring for 1 hour at 30 ℃ and stirring speed of 400rpm until the components are uniformly mixed, and obtaining the sweetener solution of the embodiment.
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
1kg of wall material matrix solution and 5kg of sweetener solution are respectively weighed according to the mass ratio of the wall material matrix solution to the sweetener of 1:5, and the sweetener solution is dropwise added into the wall material matrix solution under the condition that the temperature is 30 ℃ and the stirring speed is 400rpm, and the solution I of the embodiment is obtained after stirring for 1 hour while adding.
(4) Mixing the solution I with glyceryl triacetate, and dispersing at high speed to obtain the sustained and controlled release sweet essence.
Weighing 1kg and 5kg of solution I and 5kg of glyceryl triacetate respectively according to the mass ratio of the solution I to the glyceryl triacetate=1:5; dispersing in 40Mpa atmosphere, stirring at 20000r/min, and dispersing for 120min.
(5) Spraying the essence with the sustained and controlled release sweet taste on the tow with the mass of 20% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a molding cavity of a filter tip molding machine set to form a tows strip containing sweet essence, and wrapping molding paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor.
2. Preparation of double Barrier transfer papers
(1) Preparation of Barrier A (cellulose diacetate and cellulose acetate propionate) solution
Example 2 cellulose diacetate was used: cellulose acetate propionate=1:3 (mass ratio) as barrier agent a. Uniformly stirring a barrier agent A and a 95% ethanol water solution in a mass ratio of 1:5 at 40 ℃ at a stirring speed of 300r/min for 1h to obtain a barrier agent A solution;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B (polyvinyl alcohol and polyacrylic acid) solution;
example 2 polyvinyl alcohol was selected: polyacrylic acid=1:1 (mass ratio) as barrier agent B. Dissolving the blocking agent B in 10% ethanol water solution, stirring at a speed of 300r/min and a temperature of 35 ℃, and uniformly mixing to obtain a blocking agent B solution;
(2.2) preparing sweet essence
(1) Weighing glucose, maltose and fructose according to the mass ratio of 2:1:1, and taking 30kg as sugar substances.
(2) Weighing saccharin sodium and sodium cyclamate together to obtain 1kg according to the mass ratio of 10:1, and using as sweetener.
(3) Weighing 3kg of acetic acid, citric acid and malic acid according to the mass ratio of 1:5:8, and using the mixture as an acid substance.
(4) According to the sugar substances: sweetener: acid = 20:1:3 (mass ratio) weighing sugar substances (glucose, maltose and fructose), sweetener (saccharin sodium, sodium cyclamate) and acid substances (acetic acid, citric acid and malic acid), wherein the total mass of the sugar substances, the sweetener and the acid substances is 1kg, and weighing 10kg of 10% ethanol aqueous solution according to the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol aqueous solution of 1:10. Mixing and stirring for 1 hour at 30 ℃ and stirring speed of 400rpm until the components are uniformly mixed, and obtaining the sweet essence of the embodiment.
(2.3) adding a barrier agent B (polyvinyl alcohol and polyacrylic acid) solution, sweet flavor and gloss oil according to a mass ratio of 5:5:40, performing high-speed dispersion and high-pressure homogenization treatment for 100min under the conditions of the pressure of 40MPa and the stirring speed of 20,000r/min to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing; the temperature of the oven is 150 ℃, the speed of the vehicle is 70m/min, and the roller pressing speed is 0.3mpa;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil; the temperature of the oven is 150 ℃, the speed of the vehicle is 70m/min, and the roller pressing speed is 0.3mpa;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step by adopting a conventional method to prepare the sweet cigarette.
Example 3
1. Preparation of filter stick containing sustained and controlled release sweet flavor
(1) Preparation of wall Material matrix solution
(1) Sucrose ester: propylene glycol mono hard fat = 1:1 (mass ratio) weighing 1kg of wall material;
(2) span80: gluconate-ss=2: 1 (mass ratio), weighing Span80 and Glucate-SS accounting for 50g according to the mass ratio of wall material to emulsifier of 20:1;
(3) according to the wall material matrix: 70% aqueous ethanol solution=1:15 (mass ratio) 15.75kg of 70% aqueous ethanol solution was weighed, mixed and stirred therein at a stirring speed of 500r/min and a temperature of 55 ℃ for 1 hour to obtain a wall material matrix solution.
(2) Preparing a sweetener solution;
(1) weighing 23kg of maltose, starch sugar and lactose according to the mass ratio of 2:1:2, and using the mixture as sugar substances.
(2) Weighing 1kg of acesulfame potassium and sucralose according to the mass ratio of 5:1, and using the acesulfame potassium and sucralose as a sweetener.
(3) Weighing 3kg of total lactic acid, citric acid and malic acid according to the mass ratio of 1:3:6, and using the total lactic acid, citric acid and malic acid as acid substances.
(4) According to the sugar substances: sweetener: acid = 23:1:2 (mass ratio) weighing the saccharide, the sweetener and the acid substances, wherein the total mass of the saccharide, the sweetener and the acid substances is 5kg, and weighing 5kg of 20% ethanol water solution according to the mass ratio of the saccharide, the sweetener and the acid substances to the ethanol water solution of 1:20. Mixing and stirring for 2 hours at 40 ℃ and stirring speed of 500rpm until the components are uniformly mixed, and obtaining the sweetener solution of the embodiment.
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
1kg of wall material matrix solution and 10kg of sweetener solution are respectively weighed according to the mass ratio of the wall material matrix solution to the sweetener of 1:10, and the sweetener solution is dropwise added into the wall material matrix solution under the condition that the stirring speed is 500rpm at 40 ℃ while stirring for 2 hours, so that the solution I of the embodiment is obtained.
(4) Mixing the solution I with glyceryl triacetate, and dispersing at high speed to obtain the sustained and controlled release sweet essence.
Weighing 1kg and 20kg of solution I and 20kg of glyceryl triacetate respectively according to the mass ratio of the solution I to the glyceryl triacetate=1:20; the dispersion was carried out under 60MPa, the stirring speed was 25000r/min, and the dispersion time was 150min.
(5) Spraying and coating the essence with the sustained and controlled release sweet taste on the tow with the mass of 30% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a molding cavity of a filter tip molding machine set to form a tows strip containing sweet essence, and wrapping molding paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor.
2. Preparation of double Barrier transfer papers
(1) Preparation of Barrier A (polyvinyl acetate and hydroxyethyl cellulose) solution
Example 3 polyvinyl acetate was used: hydroxyethylcellulose=1:2 (mass ratio) as barrier agent a. Uniformly stirring a barrier agent A and 100% ethanol in a mass ratio of 1:20 at 55 ℃ at a stirring speed of 500r/min for 2 hours to obtain a barrier agent A solution;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B (hydroxypropyl methylcellulose and hydroxypropyl cellulose) solution;
example 3 hydroxypropyl methylcellulose was selected: hydroxypropyl cellulose=1:2 (mass ratio) as barrier agent B. Dissolving the blocking agent B in 20% ethanol water solution, stirring at 500r/min and 55 ℃, and uniformly mixing to obtain blocking agent B solution;
(2.2) preparing sweet essence
(1) And weighing 20kg of total maltose, starch sugar and lactose according to the mass ratio of 2:1:2, and using the total maltose, starch sugar and lactose as sugar substances.
(2) Weighing 1kg of acesulfame potassium and sucralose according to the mass ratio of 5:1, and using the acesulfame potassium and sucralose as a sweetener.
(3) Weighing 3kg of total lactic acid, citric acid and malic acid according to the mass ratio of 1:3:6, and using the total lactic acid, citric acid and malic acid as acid substances.
(4) According to the sugar substances: sweetener: acid = 23:1:2 (mass ratio) weighing sugar substances (maltose, starch sugar and lactose), sweetener (acesulfame potassium and sucralose) and acid substances (lactic acid, citric acid and malic acid), wherein the total mass of the sugar substances, the sweetener and the acid substances is 5kg, and weighing 20% ethanol water solution 5kg according to the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol water solution of 1:20. Mixing and stirring for 2 hours at 40 ℃ and stirring speed of 500rpm until the components are uniformly mixed, and obtaining the sweet essence of the embodiment.
(2.3) adding a barrier agent B (hydroxypropyl methyl cellulose and hydroxypropyl cellulose) solution, sweet flavor and gloss oil according to a mass ratio of 2:2:80, performing high-speed dispersion and high-pressure homogenization treatment for 150min under the conditions of 60MPa of pressure and 25,000r/min of stirring speed to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing; the temperature of the oven is 160 ℃, the speed of the vehicle is 70m/min, and the roller pressing speed is 0.3mpa;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil; the temperature of the oven is 160 ℃, the speed of the vehicle is 70m/min, and the roller pressing speed is 0.3mpa;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step by adopting a conventional method to prepare the sweet cigarette.
Example 4
Evaluation of sensory quality of cigarette
Cigarette sensory quality evaluation was performed on cigarette samples containing conventional filters and cigarette samples prepared from the filter sticks of examples 1 to 3 according to national standard GB5606.4-2005, and after 10 smokers evaluated the average score was as shown in table 1.
Table 1 evaluation results of suction evaluation
The results of the three examples compared with the comparative examples show that:
1. the fragrance is slightly lost.
2. Natural, comfortable and sweet feeling of promoting the production of body fluid can improve the comfort of the oral cavity. Thereby improving the scores of miscellaneous gases, stimulation and aftertaste and improving the overall smoking comfort of the cigarettes.
Example 5
Hazardous substance detection
The cigarette filters prepared in examples 1 to 3 were tested in comparison with cigarettes without wall material matrix and sweetener, and tested by the methods of ISO and GB, as shown in Table 2.
TABLE 2 routine detection of flue gases (Tar, nicotine, CO)
The present invention is not limited to the above-mentioned embodiments, but any modifications, equivalents, improvements and modifications within the scope of the invention will be apparent to those skilled in the art.
Claims (10)
1. The preparation method of the sweet cigarette containing the slow-release sweet essence filter tip and the double-barrier transfer paper is characterized by comprising the following steps of:
1. preparation of filter stick containing sustained and controlled release sweet flavor
(1) Emulsifying a wall material by using an emulsifying agent to obtain a wall material matrix, and dissolving the wall material matrix in an ethanol water solution to obtain a wall material matrix solution;
(2) Preparing a sweetener solution;
(3) Mixing a wall material matrix solution and a sweetener solution to obtain a solution I;
(4) Mixing the solution I and glyceryl triacetate according to the mass ratio of 1:1-20, dispersing in the atmosphere with the pressure of 30-60Mpa, stirring at 13000-25000r/min and the dispersing time of 90-150min to obtain the sustained and controlled release sweet essence;
(5) Spraying the slow-release sweet flavor essence prepared in the first step on the tow with 10-30% of the mass of the tow for cigarettes, and then sizing;
(6) Sending the tows into a forming cavity of a filter tip forming unit to form a tows strip containing sweet essence, and then wrapping forming paper;
(7) Cutting to obtain the tobacco filter stick with the sustained and controlled release sweet flavor;
2. preparation of double Barrier transfer papers
(1) Preparation of Barrier A solution
Uniformly mixing the barrier agent A and 95% -100% (v/v) ethanol water solution according to a mass ratio of 1:1-20, wherein the stirring speed is 100-500r/min in the dissolving process, the stirring time is 0.5-2h, and the dissolving temperature is 35-55 ℃;
the blocking agent A is one or a mixture of more of epoxidized soybean oil, cellulose diacetate, cellulose acetate propionate, polyvinyl butyral, polyvinyl acetate and hydroxyethyl cellulose;
(2) Preparation of controlled Release sweet photosensitive oil
(2.1) preparing a barrier agent B solution;
dissolving the blocking agent B in 0% -20% (v/v) ethanol water solution, and uniformly mixing to obtain a blocking agent B solution;
the blocking agent B is one or a mixture of more of polyethylene glycol, polyvinyl alcohol, polyacrylic acid, hydroxypropyl methyl cellulose and hydroxypropyl cellulose;
(2.2) preparing sweet essence
Saccharide substances, sweetener and acid substances are mixed according to the mass ratio of 3-25:1 to 5:3-10 is dissolved in 0% -20% (v/v) ethanol water solution;
(2.3) dispersing the barrier agent B solution, the sweet essence and the gloss oil at high speed under high pressure to obtain the controlled-release sweet photosensitive oil;
(3) Preparing transfer paper for cigarettes;
the printing process is that the gravure printing process is coated on the surface of the base paper, and the printing process flow is as follows:
(3.1) base color and barrier agent a printing;
(3.2) pearlescent printing;
(3.3) printing by using the controlled-release sweet photosensitive oil;
(3.4) gilding;
(3.5) slitting;
(3.6) punching;
3. preparation of sweet cigarette
And (3) rolling the filter stick prepared in the first step and the transfer paper prepared in the second step to prepare the sweet cigarette.
2. The method for preparing the sweet cigarette containing the slow-release and controlled-release sweet flavor filter tip and the double-barrier transfer paper according to claim 1, which is characterized in that: the wall material in the first step is one or a mixture of more of sucrose ester, polyglycerol ricinoleate, vinyl acetate, monoglyceride and propylene glycol monostearate; the mass ratio of the wall material matrix to the ethanol water solution is 1:1-15, and the mass concentration of the ethanol water solution is 50% -70%; the stirring speed of the mixing is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
3. The method for preparing the sweet cigarette containing the slow-release and controlled-release sweet flavor filter tip and the double-barrier transfer paper according to claim 1, which is characterized in that: the emulsifier in the first step is one or a mixture of several of Span60, span65, span80 and Glucate-SS, and the HLB value of the emulsifier is 3-6.
4. The method for preparing a sweet cigarette containing a slow-release and controlled-release sweet flavor filter tip and double-barrier transfer paper according to claim 1, wherein the sweetener solution in the step one (2) is prepared by dissolving sugar substances, sweeteners and acid substances in an ethanol water solution with the mass concentration of 0-20%; wherein the mass ratio of the sugar substances to the sweetening agent to the acid substances is 3-25:1-5:3-10; the mass ratio of the total mass of the sugar substances, the sweetener and the acid substances to the ethanol water solution is 1:1-20; the saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from one or more of saccharin, saccharin sodium, sodium cyclamate, aspartame, acesulfame potassium, sucralose and neotame; the acid substance is selected from one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid; the stirring speed is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h in the dissolving process.
5. The method for preparing a sweet cigarette containing a slow-release and controlled-release sweet flavor filter tip and double-barrier transfer paper according to claim 1, wherein the mass ratio of the sweetener solution to the wall material matrix solution in the step one (3) is 1:1-20; stirring at a speed of 100-500r/min and a temperature of 25-55deg.C for 0.5-2h; the mixing method is to dropwise add sweetener solution into wall material matrix solution while stirring.
6. The method for preparing a sweet cigarette containing a slow-release sweet flavor filter tip and double barrier transfer paper according to claim 1, wherein the concentration of the ethanol aqueous solution in the second step (2.1) is 0% -20%; the stirring speed of dissolution is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h.
7. The method for preparing a sweet cigarette containing a slow-release sweet flavor filter tip and double barrier transfer paper according to claim 1, wherein the concentration of the ethanol aqueous solution in the second step (2.2) is 0% -20%; the stirring speed in the dissolving process is 100-500r/min, the temperature is 25-55 ℃, and the stirring time is 0.5-2h;
the saccharide is selected from one or more of glucose, fructose, sucrose, maltose, starch sugar and lactose; the sweetener is selected from saccharin, saccharin sodium, sodium cyclamate, and sodium cyclamate aspartame, acesulfame potassium one or a mixture of more of sucralose and neotame; the acid substance is one or a mixture of several of lactic acid, acetic acid, citric acid and malic acid.
8. The method for preparing the sweet cigarette containing the slow-release and controlled-release sweet flavor filter tip and the double-barrier transfer paper according to claim 1, wherein the mass ratio of the barrier B solution to the sweet flavor to the gloss oil in the step two (2.3) is 1-10:1-10:20-80, wherein the dispersion pressure is 30-60MPa, and the stirring speed is 13,000-25,000r/min.
9. The method for preparing a sweet cigarette containing a slow and controlled release sweet flavor filter tip and double barrier transfer paper according to claim 1, wherein in the second step (3),
in the printing process of the base color and the blocking agent A, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4MPa;
in the controlled-release sweet photosensitive oil printing process, the temperature of an oven is 140-160 ℃, the speed of the oven is 60-80m/min, and the pressure of a plate roller is 0.2-0.4MPa.
10. A sweet cigarette containing a slow-release and controlled-release sweet essence filter tip and double-barrier transfer paper is characterized in that: a method according to any one of claims 1 to 9.
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| US20050172976A1 (en) * | 2002-10-31 | 2005-08-11 | Newman Deborah J. | Electrically heated cigarette including controlled-release flavoring |
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| US5913311A (en) * | 1995-08-04 | 1999-06-22 | Mitsubishi Rayon Co., Ltd. | Cigarette filter and filter material therefor |
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