CN115522017A - Corrosion and wear resistant method for high-voltage electric power fittings - Google Patents

Corrosion and wear resistant method for high-voltage electric power fittings Download PDF

Info

Publication number
CN115522017A
CN115522017A CN202110707278.2A CN202110707278A CN115522017A CN 115522017 A CN115522017 A CN 115522017A CN 202110707278 A CN202110707278 A CN 202110707278A CN 115522017 A CN115522017 A CN 115522017A
Authority
CN
China
Prior art keywords
hardware fitting
treatment
molded product
drying
electric power
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202110707278.2A
Other languages
Chinese (zh)
Inventor
杨辉兵
蔡红军
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Huayu Power Fittings Co ltd
Original Assignee
Jiangsu Huayu Power Fittings Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Huayu Power Fittings Co ltd filed Critical Jiangsu Huayu Power Fittings Co ltd
Priority to CN202110707278.2A priority Critical patent/CN115522017A/en
Publication of CN115522017A publication Critical patent/CN115522017A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/18Hardening; Quenching with or without subsequent tempering
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/36Successively applying liquids or other fluent materials, e.g. without intermediate treatment
    • B05D1/38Successively applying liquids or other fluent materials, e.g. without intermediate treatment with intermediate treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/002Pretreatement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/02Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by baking
    • B05D3/0218Pretreatment, e.g. heating the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/04Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases
    • B05D3/0406Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to gases the gas being air
    • B05D3/0413Heating with air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B05D7/16Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies using synthetic lacquers or varnishes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/544No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/52Two layers
    • B05D7/54No clear coat specified
    • B05D7/546No clear coat specified each layer being cured, at least partially, separately
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/56General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering characterised by the quenching agents
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/68Temporary coatings or embedding materials applied before or during heat treatment
    • C21D1/70Temporary coatings or embedding materials applied before or during heat treatment while heating or quenching
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/002Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working by rapid cooling or quenching; cooling agents used therefor
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/04Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11Oxides
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/12Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
    • C23C4/134Plasma spraying
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/64Carburising
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/60Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes
    • C23C8/62Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using solids, e.g. powders, pastes only one element being applied
    • C23C8/64Carburising
    • C23C8/66Carburising of ferrous surfaces
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D15/00Electrolytic or electrophoretic production of coatings containing embedded materials, e.g. particles, whiskers, wires

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Plasma & Fusion (AREA)
  • Electrochemistry (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The invention discloses an anticorrosion and wear-resistant method for a high-voltage electric power fitting, which comprises the following steps: quenching the hardware fitting molded product; electroplating the hardware fitting formed product after quenching treatment; performing paint spraying treatment on the electroplated hardware fitting formed product; performing surface coating treatment on the hardware fitting formed product subjected to paint spraying treatment; and drying and air-compressing the hardware fitting molded product subjected to surface coating treatment, and detecting the surface state. The invention discloses an anticorrosion and wear-resistant method for a high-voltage electric power fitting, which has the advantages that: the electric power fitting forms a protective layer by adopting a plurality of surface treatment procedures such as quenching treatment, electroplating treatment, paint spraying treatment, coating treatment, surface coating treatment, drying, air compression and the like, so that the corrosion resistance of the surface of the electric power fitting is improved, the chemical and mechanical properties are stable, and the economic benefit and the safety benefit are remarkably improved. The wear resistance of the electric power fitting is greatly improved through the treatment of multiple processes, the safety of the electric power fitting is improved, and the service life of the electric power fitting is prolonged.

Description

Corrosion and wear resistant method for high-voltage electric power fittings
Technical Field
The invention relates to the technical field of electric power fittings, in particular to an anti-corrosion and wear-resistant method for a high-voltage electric power fitting.
Background
Metal accessories made of iron or aluminum, which are widely used in power transmission lines, are collectively called as electric power fittings. Electric power fittings are of various kinds and have different applications, for example, various wire clamps for installing wires, various suspension loops for forming insulator strings, various crimping tubes and repairing tubes for connecting wires, various spacers on split wires, and the like, and various wire drawing fittings for towers and the size of the protection wires are related and need to be matched with each other. Most hardware fittings need to bear larger pulling force during operation, and some hardware fittings need to ensure good electrical contact at the same time, which is related to the safety of a lead or a tower, and even if one hardware fitting is damaged, a line fault can be caused. Therefore, the quality, correct use and installation of the electric power fitting have certain influence on the safe power transmission of the line.
When carrying out surface treatment to electric power fitting is erect to electric wire netting at present, have following problem: when carrying out surface treatment to electric power fitting and spraying paint, current only to its surface to electric power fitting sprays paint, will appear the condition that the lacquer painting cracks and drops after using a period after spraying paint, can lead to electric power fitting surface to lead to electric power fitting when using like this, the problem of oxidation corrosion appears in the place that the lacquer painting drops easily to reduce electric power fitting's life.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides an anticorrosion and wear-resistant method for a high-voltage electric power fitting, which adopts multiple surface treatment procedures such as quenching treatment, electroplating treatment, paint spraying treatment, coating treatment, surface coating treatment, drying, air compression and the like, so that the surface layer of the electric power fitting has better anticorrosion and wear-resistant effects.
The invention provides an anticorrosion and wear-resistant method for a high-voltage electric power fitting, which comprises the following steps:
(1) Quenching the hardware fitting molded product;
(2) Electroplating the hardware fitting molded product after quenching treatment;
(3) Performing paint spraying treatment on the hardware fitting molded product after the electroplating treatment;
(4) Performing surface coating treatment on the hardware fitting molded product subjected to the paint spraying treatment;
(5) And drying and air-compressing the hardware fitting molded product subjected to surface coating treatment, and detecting the surface state.
Further, the quenching treatment method in the step (1) is as follows:
a. the following materials are prepared according to mass percentage: 67% of carbon black powder, 8% of sodium carbonate, 4% of barium carbonate, 1% of calcium carbonate, 10% of sodium chloride and 10% of sodium hydroxide, and fully mixing the carbon black powder, the sodium carbonate, the barium carbonate, the calcium carbonate, the sodium chloride and the sodium hydroxide to obtain a quenching agent;
b. cleaning the wear-resistant part of the hardware fitting molded product, coating a layer of quenching agent with the thickness of 1-2 mm, naturally drying, drying at 100-200 ℃, coating a layer of protective agent on the surface of the quenching agent layer after drying, and naturally drying, wherein the protective agent is a high-temperature oxidation-resistant decarburized coating with the thickness of 0.5mm;
c. after the treatment of the step b, heating the hardware fitting in a quenching furnace at 1000-1500 ℃ until the hardware fitting is fully austenitized, heating and preserving the heat of a single piece for 2-3 min/mm, carburizing by quenching and heating, then putting into quenching oil for quenching, cooling to room temperature and taking out;
d. and tempering the quenched hardware at 200-220 ℃.
Further, the electroplating treatment method in the step (2) is as follows:
a. polishing, derusting and cleaning the surface of the hardware fitting molded product;
b. preparing an electroplating solution, wherein the electroplating solution comprises the following components in parts by weight: 10-20 parts of nano chromium oxide, 10-20 parts of fluoboric acid, 2-6 parts of sodium dodecyl sulfate, 2-5 parts of nano aluminum nitride, 25-40 parts of sodium phosphate, 1-3 parts of dibutyltin diacetate, 1-3 parts of complexing agent, 1-2 parts of buffering agent, 1-2 parts of ethane and 100-300 parts of deionized water;
c. after the electroplating solution is stirred for 20-40 minutes, the hardware molding product is immersed into the electroplating solution, and the temperature of the electroplating solution is 45-60 ℃.
Further, the painting treatment method in the step (3) is as follows: preheating the hardware fitting forming product before spraying paint on the hardware fitting forming product, so that the surface temperature of the hardware fitting forming product is 50-80 ℃; putting the hardware fitting molded product into a spraying process room for spraying; spraying water-based paint on the surface of the hardware fitting molded product to form a uniform water-based paint film on the surface of the hardware fitting molded product to obtain the membrane-formed hardware fitting molded product, wherein the thickness of the water-based paint film is 0.1-1mm, and the mass percent of water in the water-based paint is 10-50%; drying the water-based paint in a drying oven for 1 to 2 hours to ensure that the mass percent of water in the water-based paint is 5 to 20 percent; controlling the sprayed hardware fitting molded product after film formation to enter a drying box for drying treatment to obtain a dried hardware fitting molded product; blowing the dried hardware fitting molded product in a blowing process to obtain a pretreated hardware fitting molded product; wherein the air speed of the air blowing is that the air speed of the tangent plane on the surface of the hardware fitting forming product is more than or equal to 10m/s, and the air blowing is hot air at the temperature of 80-100 ℃.
Further, the coating treatment method of the step (4) is as follows: the preparation of the coating material comprises the following steps: weighing 100-200kg of silicon dioxide, 120-150kg of zinc oxide and 60-70kg of zirconium dioxide, grinding and uniformly mixing 100-150kg of aluminum oxide powder and 20-30kg of yttrium oxide powder, putting into a solvent for stirring, heating to 300-600 ℃ under the protection of inert gas, boiling for 1-2 hours, and naturally cooling to room temperature to obtain a gel material; coating the prepared gel material on an electric power fitting forming product by a plasma spraying method to form a gel coating with the thickness of 0.1-0.3 mm; .
Further, the drying processing method in the step (5) is as follows: and (3) drying the hardware fitting molded product coated with the gel coating in a drying and pressurizing machine at the drying temperature of 20-30 ℃ for 12-24 hours, pressurizing every 2 hours in the drying process, and pressurizing to ensure that the surface of the hardware fitting molded product is uniform.
Further, the appearance detection method of the step (5) is as follows: and detecting the hardware fitting formed product after the surface treatment is finished through appearance detection equipment.
The invention provides an anticorrosion and wear-resistant method for a high-voltage electric power fitting, which has the advantages that: the electric power fitting forms a protective layer by adopting a plurality of surface treatment procedures such as quenching treatment, electroplating treatment, paint spraying treatment, coating treatment, surface coating treatment, drying, air compression and the like, so that the corrosion resistance of the surface of the electric power fitting is improved, the chemical and mechanical properties are stable, and the economic benefit and the safety benefit are remarkably improved. The wear-resisting property of the electric power fitting is greatly improved through the treatment of multiple processes, the safety of the electric power fitting is improved, and the service life of the electric power fitting is prolonged.
Detailed Description
The technical solution of the present invention will be clearly and completely described below with reference to the specific embodiments. The described embodiments are only some embodiments of the invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments of the present invention without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a corrosion-resistant and wear-resistant method for a high-voltage electric power fitting, which comprises the following steps:
(1) Quenching the hardware fitting molded product;
(2) Electroplating the hardware fitting molded product after quenching treatment;
(3) Performing paint spraying treatment on the hardware fitting molded product after the electroplating treatment;
(4) Performing surface coating treatment on the hardware fitting molded product subjected to the paint spraying treatment;
(5) And drying and air-compressing the hardware fitting molded product subjected to surface coating treatment, and detecting the surface state.
Example 1:
the quenching treatment method of the quenching treatment comprises the following steps:
a. the following materials are prepared according to mass percent: 67% of carbon black powder, 8% of sodium carbonate, 4% of barium carbonate, 1% of calcium carbonate, 10% of sodium chloride and 10% of sodium hydroxide, and fully mixing the carbon black powder, the sodium carbonate, the barium carbonate, the calcium carbonate, the sodium chloride and the sodium hydroxide to obtain a quenching agent;
b. cleaning the wear-resistant part of the hardware fitting molded product, coating a layer of quenching agent with the thickness of 1mm, naturally drying, drying at 100 ℃, coating a layer of protective agent on the surface of the quenching agent layer after drying, and naturally drying, wherein the protective agent is a high-temperature oxidation-resistant decarburized coating with the thickness of 0.5mm;
c. after the treatment of the step b, heating the hardware fitting in a 1000 ℃ quenching furnace until the hardware fitting is fully austenitized, keeping the temperature of the single piece for 2min/mm, carburizing by quenching and heating, then putting into quenching oil for quenching, cooling to room temperature and taking out;
d. and tempering the hardware after quenching at 200 ℃.
The electroplating treatment method comprises the following steps:
a. polishing, derusting and cleaning the surface of the hardware fitting molded product;
b. preparing an electroplating solution, wherein the electroplating solution comprises the following components in parts by weight: 10 parts of nano chromium oxide, 10 parts of fluoboric acid, 2 parts of sodium dodecyl sulfate, 2 parts of nano aluminum nitride, 25 parts of sodium phosphate, 1 part of dibutyltin diacetate, 1 part of complexing agent, 1 part of buffering agent, 1 part of ethane and 100 parts of deionized water;
c. after the plating solution was stirred for 20 minutes, the hardware molded article was immersed in the plating solution at a temperature of 45 ℃.
The painting treatment method comprises the following steps: preheating the hardware fitting molded product before spraying paint on the hardware fitting molded product, so that the surface temperature of the hardware fitting molded product is 50 ℃; putting the hardware fitting molded product into a spraying process room for spraying; spraying a water-based coating on the surface of the hardware fitting molded product to form a uniform water-based coating film on the surface of the hardware fitting molded product to obtain a film-formed hardware fitting molded product, wherein the thickness of the water-based coating film is 0.1mm, and the mass percentage of water in the water-based coating is 10%; drying the mixture in a drying oven for 1 hour to ensure that the mass percent of water in the water-based paint is 5 percent; controlling the sprayed hardware fitting molded product after film formation to enter a drying box for drying treatment to obtain a dried hardware fitting molded product; blowing the dried hardware fitting molded product in a blowing process to obtain a pretreated hardware fitting molded product; the wind speed of the blowing wind enables the wind speed of the surface tangent plane of the hardware fitting forming product to be more than or equal to 10m/s, and the blowing wind is hot wind at the temperature of 80 ℃.
The coating treatment method comprises the following steps: the preparation of the coating material comprises the following steps: weighing 100kg of silicon dioxide, 120kg of zinc oxide and 60kg of zirconium dioxide, grinding and mixing the silicon dioxide, the 120kg of aluminum oxide powder and the 20kg of yttrium oxide powder uniformly, putting the mixture into a solvent for stirring, heating to 300 ℃ under the protection of inert gas, boiling for 1 hour, and naturally cooling to room temperature to obtain a gel material; coating the prepared gel material on an electric power fitting formed product by a plasma spraying method to form a gel coating with the thickness of 0.1; .
The drying treatment method comprises the following steps: and (3) drying the hardware molding product coated with the gel coating in a drying and pressurizing machine at the drying temperature of 20 ℃ for 12 hours, pressurizing every 2 hours in the drying process, and pressurizing to ensure that the surface of the hardware molding product is uniform.
The appearance detection method comprises the following steps: and detecting the hardware fitting formed product after the surface treatment is finished through appearance detection equipment.
Example 2: the quenching treatment method comprises the following steps:
a. the following materials are prepared according to mass percent: 67% of carbon black powder, 8% of sodium carbonate, 4% of barium carbonate, 1% of calcium carbonate, 10% of sodium chloride and 10% of sodium hydroxide, and fully mixing the carbon black powder, the sodium carbonate, the barium carbonate, the calcium carbonate, the sodium chloride and the sodium hydroxide to obtain a quenching agent;
b. cleaning the wear-resistant part of the hardware fitting molded product, coating a layer of quenching agent with the thickness of 1.5mm, naturally drying, drying at 150 ℃, coating a layer of protective agent on the surface of the quenching agent layer after drying, and naturally drying, wherein the protective agent is a high-temperature oxidation-resistant decarburization coating with the thickness of 0.5mm;
c. after the treatment of the step b, heating the hardware fitting in a quenching furnace at 1200 ℃ until the hardware fitting is fully austenitized, heating and preserving heat for a single piece for 2.5min/mm, carburizing by quenching and heating, then putting into quenching oil for quenching, cooling to room temperature and taking out;
d. and tempering the quenched hardware at 210 ℃.
The electroplating treatment method comprises the following steps:
a. polishing, derusting and cleaning the surface of the hardware fitting molded product;
b. preparing an electroplating solution, wherein the electroplating solution comprises the following components in parts by weight: 15 parts of nano chromium oxide, 15 parts of fluoboric acid, 4 parts of sodium dodecyl sulfate, 4 parts of nano aluminum nitride, 30 parts of sodium phosphate, 2 parts of dibutyltin diacetate, 2 parts of complexing agent, 1.5 parts of buffering agent, 1.5 parts of ethane and 150 parts of deionized water;
c. after stirring the plating solution for 30 minutes, the hardware molding product is immersed into the plating solution at the temperature of 50 ℃.
The painting treatment method comprises the following steps: preheating the hardware fitting forming product before spraying paint on the hardware fitting forming product, so that the surface temperature of the hardware fitting forming product is 60 ℃; putting the hardware fitting molded product into a spraying process room for spraying; spraying a water-based coating on the surface of the hardware fitting molded product to form a uniform water-based coating film on the surface of the hardware fitting molded product to obtain a film-formed hardware fitting molded product, wherein the thickness of the water-based coating film is 0.5mm, and the mass percentage of water in the water-based coating is 35%; drying the mixture in a drying oven for 1.5 hours to ensure that the mass percent of water in the water-based paint is 10 percent; controlling the sprayed hardware fitting formed product after film forming to enter a drying box for drying treatment to obtain a dried hardware fitting formed product; blowing the dried hardware fitting formed product in a blowing process to obtain a pretreated hardware fitting formed product; the wind speed of the blowing wind enables the wind speed of the surface tangent plane of the hardware fitting forming product to be more than or equal to 10m/s, and the blowing wind is hot wind at 90 ℃.
The coating treatment method comprises the following steps: the preparation of the coating material comprises the following steps: weighing 150kg of silicon dioxide, 120-150kg of zinc oxide and 65kg of zirconium dioxide, grinding and mixing the silicon dioxide, the zinc oxide and the zirconium dioxide with 120kg of aluminum oxide powder and 25kg of yttrium oxide powder uniformly, putting the mixture into a solvent for stirring, heating to 400 ℃ under the protection of inert gas, boiling for 1.5 hours, and naturally cooling to room temperature to obtain a gel material; coating the prepared gel material on an electric power fitting forming product by a plasma spraying method to form a gel coating with the thickness of 0.2 mm; .
The drying treatment method comprises the following steps: and (3) drying the hardware fitting molded product coated with the gel coating in a drying and pressurizing machine at the drying temperature of 25 ℃ for 18 hours, pressurizing every 2 hours in the drying process, and pressurizing to ensure that the surface of the hardware fitting molded product is uniform.
The appearance detection method comprises the following steps: and detecting the hardware formed product subjected to surface treatment by using appearance detection equipment.
Example 3: the quenching treatment method comprises the following steps:
a. the following materials are prepared according to mass percentage: 67% of carbon black powder, 8% of sodium carbonate, 4% of barium carbonate, 1% of calcium carbonate, 10% of sodium chloride and 10% of sodium hydroxide, and fully mixing the carbon black powder, the sodium carbonate, the barium carbonate, the calcium carbonate, the sodium chloride and the sodium hydroxide to obtain a quenching agent;
b. cleaning the wear-resistant part of the hardware fitting molded product, coating a layer of quenching agent with the thickness of 2mm, naturally drying, drying at 200 ℃, coating a layer of protective agent on the surface of the quenching agent layer after drying, and naturally drying, wherein the protective agent is a high-temperature oxidation-resistant decarburized coating with the thickness of 0.5mm;
c. after the treatment of the step b, heating the hardware fitting in a quenching furnace at 1500 ℃ until the hardware fitting is fully austenitized, heating and preserving heat for 3min/mm of a single piece, carburizing by quenching and heating, then putting into quenching oil for quenching, cooling to room temperature and taking out;
d. and (4) tempering the hardware after quenching at 220 ℃.
The electroplating treatment method comprises the following steps:
a. polishing, derusting and cleaning the surface of the hardware fitting molded product;
b. preparing an electroplating solution, wherein the electroplating solution comprises the following components in parts by weight: 20 parts of nano chromium oxide, 20 parts of fluoboric acid, 6 parts of sodium dodecyl sulfate, 5 parts of nano aluminum nitride, 40 parts of sodium phosphate, 3 parts of dibutyltin diacetate, 3 parts of complexing agent, 2 parts of buffering agent, 2 parts of ethane and 300 parts of deionized water;
c. after the plating solution was stirred for 40 minutes, the hardware molded article was immersed in the plating solution at a temperature of 60 ℃.
The paint spraying treatment method comprises the following steps: preheating the hardware fitting molded product before spraying paint on the hardware fitting molded product, so that the surface temperature of the hardware fitting molded product is 80 ℃; putting the hardware fitting molded product into a spraying process room for spraying; spraying a water-based coating on the surface of the hardware fitting molded product to form a uniform water-based coating film on the surface of the hardware fitting molded product, so as to obtain the membrane-formed hardware fitting molded product, wherein the thickness of the water-based coating film is 1mm, and the mass percentage of water in the water-based coating is 50%; drying the mixture in a drying oven for 2 hours to ensure that the mass percent of water in the water-based paint is 20%; controlling the sprayed hardware fitting formed product after film forming to enter a drying box for drying treatment to obtain a dried hardware fitting formed product; blowing the dried hardware fitting molded product in a blowing process to obtain a pretreated hardware fitting molded product; the wind speed of the blowing wind enables the wind speed of the surface tangent plane of the hardware fitting molded product to be more than or equal to 10m/s, and the blowing wind is hot wind at the temperature of 100 ℃.
The coating treatment method comprises the following steps: the preparation of the coating material comprises the following steps: weighing 200kg of silicon dioxide, 150kg of zinc oxide and 70kg of zirconium dioxide, grinding and mixing 150kg of aluminum oxide powder and 30kg of yttrium oxide powder uniformly, putting into a solvent for stirring, heating to 600 ℃ under the protection of inert gas, boiling for 2 hours, and naturally cooling to room temperature to obtain a gel material; coating the prepared gel material on an electric power fitting formed product by a plasma spraying method to form a gel coating with the thickness of 0.3 mm; .
The drying treatment method comprises the following steps: and (3) drying the hardware fitting molded product coated with the gel coating in a drying and pressurizing machine at the drying temperature of 30 ℃ for 24 hours, pressurizing every 2 hours in the drying process, and pressurizing to ensure that the surface of the hardware fitting molded product is uniform.
The appearance detection method comprises the following steps: and detecting the hardware fitting formed product after the surface treatment is finished through appearance detection equipment.
In summary, the anti-corrosion and wear-resistant method for the high-voltage electric power fitting provided by the invention has the advantages that: the electric power fitting forms a protective layer by adopting a plurality of surface treatment procedures such as quenching treatment, electroplating treatment, paint spraying treatment, coating treatment, surface coating treatment, drying, air compression and the like, so that the corrosion resistance of the surface of the electric power fitting is improved, the chemical and mechanical properties are stable, and the economic benefit and the safety benefit are remarkably improved. The wear resistance of the electric power fitting is greatly improved through the treatment of multiple processes, the safety of the electric power fitting is improved, and the service life of the electric power fitting is prolonged.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (7)

1. The method for preventing corrosion and abrasion of the high-voltage electric power fitting is characterized by comprising the following steps of:
(1) Quenching the hardware fitting molded product;
(2) Electroplating the hardware fitting formed product after quenching treatment;
(3) Performing paint spraying treatment on the hardware fitting molded product after the electroplating treatment;
(4) Performing surface coating treatment on the hardware fitting molded product subjected to the paint spraying treatment;
(5) And drying and air-compressing the hardware fitting molded product subjected to surface coating treatment, and detecting the surface state.
2. The corrosion and wear resistant method for high voltage electric power fittings according to claim 1, wherein the quenching treatment method in step (1) is as follows:
a. the following materials are prepared according to mass percent: 67% of carbon black powder, 8% of sodium carbonate, 4% of barium carbonate, 1% of calcium carbonate, 10% of sodium chloride and 10% of sodium hydroxide, and fully mixing the carbon black powder, the sodium carbonate, the barium carbonate, the calcium carbonate, the sodium chloride and the sodium hydroxide to obtain a quenching agent;
b. cleaning the wear-resistant part of the hardware fitting molded product, coating a layer of quenching agent with the thickness of 1-2 mm, naturally drying, drying at 100-200 ℃, coating a layer of protective agent on the surface of the quenching agent layer after drying, and naturally drying, wherein the protective agent is a high-temperature oxidation-resistant decarburized coating with the thickness of 0.5mm;
c. after the treatment of the step b, heating the hardware fitting in a quenching furnace at 1000-1500 ℃ until the hardware fitting is fully austenitized, keeping the temperature of the single piece for 2-3 min/mm, carburizing by quenching and heating, then putting into quenching oil for quenching, cooling to room temperature and taking out;
d. and tempering the hardware after quenching at 200-220 ℃.
3. The corrosion and wear resistant method for high voltage electric power fittings according to claim 1, wherein the electroplating treatment method of the step (2) is as follows:
a. polishing, derusting and cleaning the surface of the hardware fitting molded product;
b. preparing an electroplating solution, wherein the electroplating solution comprises the following components in parts by weight: 10-20 parts of nano chromium oxide, 10-20 parts of fluoboric acid, 2-6 parts of sodium dodecyl sulfate, 2-5 parts of nano aluminum nitride, 25-40 parts of sodium phosphate, 1-3 parts of dibutyltin diacetate, 1-3 parts of complexing agent, 1-2 parts of buffering agent, 1-2 parts of ethane and 100-300 parts of deionized water;
c. after the electroplating solution is stirred for 20-40 minutes, the hardware molding product is immersed into the electroplating solution, and the temperature of the electroplating solution is 45-60 ℃.
4. The corrosion and wear resistant method for high voltage electric power fittings according to claim 1, wherein the painting treatment method of the step (3) is as follows: preheating the hardware fitting forming product before spraying paint on the hardware fitting forming product, so that the surface temperature of the hardware fitting forming product is 50-80 ℃; putting the hardware fitting molded product into a spraying process room for spraying; spraying water-based paint on the surface of the hardware fitting molded product to form a uniform water-based paint film on the surface of the hardware fitting molded product to obtain the membrane-formed hardware fitting molded product, wherein the thickness of the water-based paint film is 0.1-1mm, and the mass percent of water in the water-based paint is 10-50%; drying the mixture in a drying oven for 1 to 2 hours to ensure that the mass percent of water in the water-based paint is 5 to 20 percent; controlling the sprayed hardware fitting molded product after film formation to enter a drying box for drying treatment to obtain a dried hardware fitting molded product; blowing the dried hardware fitting molded product in a blowing process to obtain a pretreated hardware fitting molded product; wherein the air speed of the air blowing is that the air speed of the tangential plane on the surface of the hardware fitting forming product is more than or equal to 10m/s, and the air blowing is hot air at the temperature of 80-100 ℃.
5. The corrosion and wear resistant method for high voltage electric power fittings according to claim 1, wherein the coating treatment method of the step (4) is as follows: the preparation of the coating material comprises the following steps: weighing 100-200kg of silicon dioxide, 120-150kg of zinc oxide and 60-70kg of zirconium dioxide, grinding and uniformly mixing 100-150kg of aluminum oxide powder and 20-30kg of yttrium oxide powder, putting into a solvent for stirring, heating to 300-600 ℃ under the protection of inert gas, boiling for 1-2 hours, and naturally cooling to room temperature to obtain a gel material; coating the prepared gel material on an electric power fitting forming product by a plasma spraying method to form a gel coating with the thickness of 0.1-0.3 mm; .
6. The corrosion and wear resistant method for high voltage electric power fittings according to claim 1, wherein the drying treatment method of the step (5) is as follows: and (3) drying the hardware fitting molded product coated with the gel coating in a drying and pressurizing machine at the drying temperature of 20-30 ℃ for 12-24 hours, pressurizing every 2 hours in the drying process, and pressurizing to ensure that the surface of the hardware fitting molded product is uniform.
7. The corrosion and wear resistant method for the high voltage electric power fittings according to claim 1, wherein the appearance detection method of the step (5) is as follows: and detecting the hardware formed product subjected to surface treatment by using appearance detection equipment.
CN202110707278.2A 2021-06-24 2021-06-24 Corrosion and wear resistant method for high-voltage electric power fittings Pending CN115522017A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110707278.2A CN115522017A (en) 2021-06-24 2021-06-24 Corrosion and wear resistant method for high-voltage electric power fittings

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202110707278.2A CN115522017A (en) 2021-06-24 2021-06-24 Corrosion and wear resistant method for high-voltage electric power fittings

Publications (1)

Publication Number Publication Date
CN115522017A true CN115522017A (en) 2022-12-27

Family

ID=84694497

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202110707278.2A Pending CN115522017A (en) 2021-06-24 2021-06-24 Corrosion and wear resistant method for high-voltage electric power fittings

Country Status (1)

Country Link
CN (1) CN115522017A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101547978A (en) * 2006-11-28 2009-09-30 威尔彻精密技术株式会社 Inorganic pigments composition having high hardness
CN106521344A (en) * 2016-12-14 2017-03-22 苏州富艾姆工业设备有限公司 Machining process of wear resisting piston rod for valve
CN106868448A (en) * 2017-01-23 2017-06-20 扬州大学 A kind of method that utilization paste carburizing improves transmission line hardware wearability
CN107747110A (en) * 2017-11-23 2018-03-02 四川精通机械科技有限公司 A kind of steel electro-plating method
US20190300975A1 (en) * 2018-04-02 2019-10-03 Lundtek, Inc. Metal Coating Method
CN110560341A (en) * 2019-08-28 2019-12-13 中车长江车辆有限公司 Steel pretreatment method
CN112695319A (en) * 2020-11-27 2021-04-23 上海宏挺紧固件制造有限公司 Countersunk self-drilling screw and processing method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101547978A (en) * 2006-11-28 2009-09-30 威尔彻精密技术株式会社 Inorganic pigments composition having high hardness
CN106521344A (en) * 2016-12-14 2017-03-22 苏州富艾姆工业设备有限公司 Machining process of wear resisting piston rod for valve
CN106868448A (en) * 2017-01-23 2017-06-20 扬州大学 A kind of method that utilization paste carburizing improves transmission line hardware wearability
CN107747110A (en) * 2017-11-23 2018-03-02 四川精通机械科技有限公司 A kind of steel electro-plating method
US20190300975A1 (en) * 2018-04-02 2019-10-03 Lundtek, Inc. Metal Coating Method
CN110560341A (en) * 2019-08-28 2019-12-13 中车长江车辆有限公司 Steel pretreatment method
CN112695319A (en) * 2020-11-27 2021-04-23 上海宏挺紧固件制造有限公司 Countersunk self-drilling screw and processing method thereof

Similar Documents

Publication Publication Date Title
CN109616259B (en) Manufacturing process of enameled wire with water-based insulating paint as insulating layer
CN107565478A (en) A kind of production technology of fireproof bus duct
CN107565479A (en) A kind of production technology of the bus duct of working stability
CN110846647A (en) Surface treatment process for aluminum alloy profile
CN115522017A (en) Corrosion and wear resistant method for high-voltage electric power fittings
CN109243694B (en) long-life enameled wire and production process thereof
CN108531921B (en) Surface galvanizing process for cable bridge
CN111755196B (en) High-corrosion-resistance iron-silicon-chromium alloy soft magnetic material and preparation method thereof
CN108950571B (en) Surface treatment process for wire and cable bridge
CN111101125B (en) Optical cable drawing method
CN109371285B (en) Steel core wire anti-corrosion alloy coating for overhead conductor and preparation method thereof
CN111575749A (en) Surface coating treatment process of high-strength fastener
CN112626434A (en) Preparation process of power insulator iron cap
CN113231287A (en) Manufacturing method of insulating anti-corrosion prestressed steel bar
CN111041182A (en) Chain machining process method
CN114843031B (en) Manufacturing method of antioxidant high-temperature-resistant aluminum electromagnetic wire
CN108264833B (en) High-temperature-resistant strong-acid-soaking-resistant graphene hot-dip galvanizing hanger coating and preparation method thereof
CN107779094A (en) A kind of air compressor machine surface-treated metal paint and preparation method thereof
KR100311804B1 (en) Fingerprint solution with excellent low temperature reactivity and corrosion resistance and manufacturing method of inner fingerprint steel sheet using the same
CN112095064A (en) Improved galvanizing process for electric power fitting
CN114214624A (en) Preparation method of steel material composite coating
CN117438142A (en) Antioxidant copper conductor for coaxial cable
JP3643544B2 (en) Surface-treated steel sheet excellent in workability and corrosion resistance of machined part and method for producing the same
CN113005383A (en) Galvanized steel pipe production process
CN116949363A (en) High-strength steel wire and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination