CN115505844A - Die forging and soft nitriding method for mine car wheel - Google Patents

Die forging and soft nitriding method for mine car wheel Download PDF

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Publication number
CN115505844A
CN115505844A CN202211158413.3A CN202211158413A CN115505844A CN 115505844 A CN115505844 A CN 115505844A CN 202211158413 A CN202211158413 A CN 202211158413A CN 115505844 A CN115505844 A CN 115505844A
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die forging
furnace
die
forging
mine car
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CN115505844B (en
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田仲华
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Mengyin Junhua Hydraulic Machinery Co.,Ltd.
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Mengyin Jinhua Machinery Co ltd
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21JFORGING; HAMMERING; PRESSING METAL; RIVETING; FORGE FURNACES
    • B21J5/00Methods for forging, hammering, or pressing; Special equipment or accessories therefor
    • B21J5/02Die forging; Trimming by making use of special dies ; Punching during forging
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D9/00Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
    • C21D9/34Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for tyres; for rims
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/001Ferrous alloys, e.g. steel alloys containing N
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • C22C38/24Ferrous alloys, e.g. steel alloys containing chromium with vanadium
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24Nitriding
    • C23C8/26Nitriding of ferrous surfaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Heat Treatment Of Articles (AREA)

Abstract

The invention discloses a die forging and soft nitriding method for a mine car wheel, which specifically comprises the following steps: (1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, forging the steel into a die forging blank, and removing oxide skin on the surface of the die forging blank; (2) Preheating a die forging die, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die; (3) After the blank is taken out of the die forging die, the blank is subjected to tempering treatment in a heat treatment furnace and is quenched and tempered to obtain a semi-finished product of the mine car wheel; (4) Placing the semi-finished product of the mine car wheel after quenching and tempering in a nitriding furnace for soft nitriding; (5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging the product out of the furnace; (6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel. The invention relates to the technical field of processing of mine car wheels, and particularly provides a die forging and soft nitriding method for a mine car wheel.

Description

Die forging and soft nitriding method for mine car wheel
Technical Field
The invention relates to the technical field of processing of mine car wheels, in particular to a die forging and soft nitriding method for a mine car wheel.
Background
The mine car is a standard or narrow-gauge railway conveying vehicle for conveying bulk materials such as ores, waste rocks and coal in mines and is generally pulled by a locomotive or a winch. The mine car is mainly used for track transportation of underground roadways, shafts and the ground of mines. Mine car wheels are important components of mine cars, which have higher requirements for strength and durability.
The existing mine wheel is mainly produced by adopting a casting mode, and then is subjected to heat treatment after casting processing. Although the mineral vehicle wheel produced by casting has the advantages of low cost and the like, the problems of insufficient strength and durability of the product exist at the same time, the quality problems of air holes, sand holes and the like are inevitably generated in the metal casting process, the density of the cast product is low, the existing mineral vehicle wheel is insufficient in strength and durability, the damage and the replacement are frequent, and even safety accidents are caused.
Nitrocarburizing is also known as nitrocarburizing or ferritic nitrocarburizing. Is a chemical surface heat treatment process for simultaneously permeating nitrogen and carbon atoms into the surface of a steel piece under the action of high temperature. In order to shorten the nitriding period and to make the nitriding process not limited by steel grade, the soft nitriding process was developed on the basis of the low-temperature nitriding process in the last twenty years. The soft nitriding is substantially low-temperature carbonitriding mainly involving nitriding, and steel is not only permeated with nitrogen atoms but also with a small amount of carbon atoms, and the treatment results are called soft nitriding because the hardness of the carburized layer is lower and the brittleness is smaller than that of the aforementioned general gaseous nitrogen.
Gas soft nitriding, which is one of the soft nitriding methods, is low-temperature nitrogen and carbon co-cementation in an atmosphere containing carbon and nitrogen atoms, and common co-cementation media include urea, formamide and triethanolamine, which undergo a thermal decomposition reaction at a soft nitriding temperature to produce activated carbon and nitrogen atoms. The active carbon and nitrogen atoms are absorbed by the surface of the workpiece and permeate into the surface layer of the workpiece through diffusion, so that a carbonitriding layer mainly containing nitrogen is obtained.
Disclosure of Invention
Aiming at the situation, in order to make up for the existing defects, the invention provides a die forging and soft nitriding method for a mine car wheel, which effectively solves the technical problems of improving the strength and durability of the product by combining a novel die forging processing mode and soft nitriding.
The invention provides the following technical scheme: the invention relates to a die forging and tufftriding method for a mine car wheel, which specifically comprises the following steps:
(1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, forging the steel into a die forging blank, and removing oxide skin on the surface of the die forging blank;
(2) Preheating a die forging die, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die;
(3) After the wheel is taken out of the die forging die, tempering the wheel in a heat treatment furnace to carry out quenching and tempering to obtain a semi-finished product of the mine wheel so as to inhibit the formation of network carbides inside the wheel and eliminate internal stress, so that a good internal structure of the wheel is obtained and the toughness of the wheel is improved;
(4) Placing the semi-finished product of the mine car wheel after the quenching and tempering treatment in a nitriding furnace, vacuumizing the nitriding furnace to a vacuum degree of 22-28 pa, introducing nitrogen gas for filling protective gas, introducing an ethanol solution, keeping introducing the nitrogen until the temperature in the nitriding furnace reaches 260-350 ℃, stopping supplying the nitrogen, introducing dried ammonia gas, continuously heating the nitriding furnace, controlling the temperature of the nitriding furnace to be at the soft nitriding treatment temperature, and entering a nitriding heat preservation stage;
(5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging the product out of the furnace;
(6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel.
Further, the steel for soft nitriding in the step (1) comprises the following components: c, by mass percent: 0.25 to 035%, si:0.1 to 0.2%, mn:0.8 to 1.2%, cr:2.5 to 5.0%, N:0.03 to 0.05%, P:0.01 to 0.03%, S:0.005 to 0.015%, al:0.01 to 0.06%, V:0.05 to 0.1 percent, and the balance of Fe and inevitable impurities, wherein the sum of the mass percent of the components is 100 percent.
Further, the initial forging temperature in the heating furnace in the step (1) is 1250-1350 ℃, the annealing temperature is 1300-1400 ℃, and the annealing heat preservation time is 30-40 min.
Further, the preheating temperature of the die forging die in the step (2) is 220-260 ℃.
Further, the tempering frequency in the step (3) is 2 times, the primary tempering is 480 ℃ for 5 hours, and the secondary tempering is 500 ℃ for 6 hours.
Further, the temperature of the tufftriding treatment in the step (4) is 560-620 ℃, and the tufftriding heat preservation time is as follows: 100 to 150 minutes.
Further, the dripping speed of the ethanol solution in the step (4) is 50-100 d/min.
The invention with the structure has the following beneficial effects: according to the die forging and tufftriding method for the mine car wheel, disclosed by the invention, the die forging forming and tufftriding treatment methods are combined, so that the density, the strength and the durability of the product are effectively improved, the product is uniform inside and outside, and the performance is consistent; the product quality is stable, and the use and maintenance cost can be greatly reduced.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The invention provides the following technical scheme: the invention relates to a die forging and soft nitriding method for a mine car wheel, which specifically comprises the following steps:
(1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, wherein the steel is forged into a die forging blank, the initial forging temperature in the heating furnace is 1250-1350 ℃, the annealing temperature is 1300-1400 ℃, the annealing heat preservation time is 30-40 min, and oxide skin on the surface of the die forging blank is removed, and the steel for the soft nitriding treatment comprises the following components: c, by mass percent: 0.25%, si:0.1%, mn:0.8%, cr:2.5%, N:0.03%, P:0.01%, S:0.005%, al:0.01%, V:0.05 percent, and the balance of Fe and inevitable impurities, wherein the sum of the mass percent of the components is 100 percent;
(2) Preheating a die forging die, wherein the preheating temperature of the die forging die is 220-260 ℃, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die;
(3) Taking the wheel out of the die forging die and then carrying out tempering treatment in a heat treatment furnace for tempering to obtain a semi-finished product of the mine wheel, wherein the technical scheme of 2 times of tempering is adopted, the primary tempering is 480 ℃ for 5 hours, and the secondary tempering is 500 ℃ for 6 hours, so that the formation of network carbides in the wheel is inhibited and the internal stress is eliminated, and the good internal structure of the wheel is obtained and the toughness of the wheel is improved;
(4) Placing the semi-finished product of the mine car wheel after the quenching and tempering treatment in a nitriding furnace, vacuumizing the nitriding furnace to a vacuum degree of 22-28 pa, introducing nitrogen gas for filling protective gas, introducing an ethanol solution, keeping the dropping speed of the ethanol solution at 50-100 d/min, introducing nitrogen until the temperature in the nitriding furnace reaches 260-350 ℃, stopping supplying nitrogen, introducing dried ammonia gas, continuously heating the nitriding furnace, controlling the temperature of the nitriding furnace to be 560-620 ℃ at the tufftride treatment temperature, and keeping the tufftride temperature for a tufftride heat preservation time: 100-150 minutes;
(5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging the product out of the furnace;
(6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel.
Example 2
The invention provides the following technical scheme: the invention relates to a die forging and soft nitriding method for a mine car wheel, which specifically comprises the following steps:
(1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, wherein the steel is forged into a die forging blank, the initial forging temperature in the heating furnace is 1250-1350 ℃, the annealing temperature is 1300-1400 ℃, the annealing heat preservation time is 30-40 min, and oxide skin on the surface of the die forging blank is removed, and the steel for the soft nitriding treatment comprises the following components: c:0.3%, si:0.15%, mn:1.0%, cr:3.75%, N:0.04%, P:0.02%, S:0.01%, al:0.035%, V:0.075%, and the balance of Fe and inevitable impurities, wherein the sum of the mass percentages of the components is 100%;
(2) Preheating a die forging die, wherein the preheating temperature of the die forging die is 220-260 ℃, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die;
(3) Taking the wheel out of the die forging die and then carrying out tempering treatment in a heat treatment furnace for tempering to obtain a semi-finished product of the mine wheel, wherein the technical scheme of 2 times of tempering is adopted, the primary tempering is 480 ℃ for 5 hours, and the secondary tempering is 500 ℃ for 6 hours, so that the formation of network carbides in the wheel is inhibited and the internal stress is eliminated, and the good internal structure of the wheel is obtained and the toughness of the wheel is improved;
(4) Placing the semi-finished product of the mine car wheel after the quenching and tempering treatment in a nitriding furnace, vacuumizing the nitriding furnace to a vacuum degree of 22-28 pa, introducing nitrogen gas for filling protective gas, introducing an ethanol solution, keeping the dropping speed of the ethanol solution at 50-100 d/min, introducing nitrogen until the temperature in the nitriding furnace reaches 260-350 ℃, stopping supplying nitrogen, introducing dried ammonia gas, continuously heating the nitriding furnace, controlling the temperature of the nitriding furnace to be 560-620 ℃ at the tufftride treatment temperature, and keeping the tufftride temperature for a tufftride heat preservation time: 100-150 minutes;
(5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging the product out of the furnace;
(6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel.
Example 3
The invention provides the following technical scheme: the invention relates to a die forging and soft nitriding method for a mine car wheel, which specifically comprises the following steps:
(1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, wherein the steel is forged into a die forging blank, the initial forging temperature in the heating furnace is 1250-1350 ℃, the annealing temperature is 1300-1400 ℃, the annealing heat preservation time is 30-40 min, and oxide skin on the surface of the die forging blank is removed, and the steel for the soft nitriding treatment comprises the following components: c, by mass percent: 035%, si:0.2%, mn:1.2%, cr:5.0%, N:0.05%, P:0.03%, S:0.015%, al:0.06%, V:0.1 percent, and the balance of Fe and inevitable impurities, wherein the sum of the mass percent of the components is 100 percent;
(2) Preheating a die forging die, wherein the preheating temperature of the die forging die is 220-260 ℃, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die;
(3) Taking the wheel out of the die forging die and then carrying out tempering treatment in a heat treatment furnace for tempering to obtain a semi-finished product of the mine wheel, wherein the technical scheme of 2 times of tempering is adopted, the primary tempering is 480 ℃ for 5 hours, and the secondary tempering is 500 ℃ for 6 hours, so that the formation of network carbides in the wheel is inhibited and the internal stress is eliminated, and the good internal structure of the wheel is obtained and the toughness of the wheel is improved;
(4) Placing the semi-finished product of the mine car wheel after the quenching and tempering treatment in a nitriding furnace, vacuumizing the nitriding furnace to a vacuum degree of 22-28 pa, introducing nitrogen gas for filling protective gas, introducing an ethanol solution, keeping the dropping speed of the ethanol solution at 50-100 d/min, introducing nitrogen until the temperature in the nitriding furnace reaches 260-350 ℃, stopping supplying nitrogen, introducing dried ammonia gas, continuously heating the nitriding furnace, controlling the temperature of the nitriding furnace to be 560-620 ℃ at the tufftride treatment temperature, and keeping the tufftride temperature for a tufftride heat preservation time: 100-150 minutes;
(5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging the product out of the furnace;
(6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Furthermore, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (7)

1. The die forging and soft nitriding method for the mine car wheel is characterized by comprising the following steps:
(1) Placing the steel for the soft nitriding treatment in a heating furnace for forging, forging the steel into a die forging blank, and removing oxide skin on the surface of the die forging blank;
(2) Preheating a die forging die, transferring a die forging blank with surface oxide skin removed into a forging press, and performing die forging through the die forging die;
(3) After the blank is taken out of the die forging die, the blank is subjected to tempering treatment in a heat treatment furnace and is quenched and tempered to obtain a semi-finished product of the mine car wheel;
(4) Placing the semi-finished product of the mine car wheel after the quenching and tempering treatment in a nitriding furnace, vacuumizing the nitriding furnace to a vacuum degree of 22-28 pa, introducing nitrogen gas for filling protective gas, introducing an ethanol solution, keeping introducing the nitrogen until the temperature in the nitriding furnace reaches 260-350 ℃, stopping supplying the nitrogen, introducing dried ammonia gas, continuously heating the nitriding furnace, controlling the temperature of the nitriding furnace to be at the soft nitriding treatment temperature, and entering a nitriding heat preservation stage;
(5) Filling nitrogen into the furnace, cooling to below 280 ℃, opening a furnace door, and discharging a product out of the furnace;
(6) And removing burrs of the discharged product to obtain a finished product of the mine car wheel.
2. The die forging and tufftriding method for mine vehicle wheels as claimed in claim 1, wherein said tufftriding steel material of step (1) comprises the following components: c, by mass percent: 0.25 to 035%, si:0.1 to 0.2%, mn:0.8 to 1.2%, cr:2.5 to 5.0%, N:0.03 to 0.05%, P:0.01 to 0.03%, S:0.005 to 0.015%, al:0.01 to 0.06%, V:0.05 to 0.1 percent, and the balance of Fe and inevitable impurities, wherein the sum of the mass percent of the components is 100 percent.
3. The die forging and soft nitriding method for the mine wheel according to claim 1, wherein the initial forging temperature in the heating furnace in the step (1) is 1250-1350 ℃, the annealing temperature is 1300-1400 ℃, and the annealing holding time is 30-40 min.
4. The die forging and tufftriding method for mine car wheels as claimed in claim 1, wherein said die forging preheating temperature in step (2) is 220-260 ℃.
5. The die forging and tufftriding process for mine vehicle wheels as claimed in claim 1, wherein said tempering of step (3) is performed 2 times, wherein the first tempering is performed at 480 ℃ for 5 hours, and wherein the second tempering is performed at 500 ℃ for 6 hours.
6. The die forging and tufftriding method for mine vehicle wheels as claimed in claim 1, wherein the tufftriding temperature in step (4) is 560-620 ℃, the tufftriding holding time is as follows: 100 to 150 minutes.
7. The die forging and tufftriding method for mine vehicle wheels as claimed in claim 1, wherein the dropping speed of the ethanol solution in the step (4) is 50-100 d/min.
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CN104131248A (en) * 2013-05-01 2014-11-05 大同特殊钢株式会社 Nitrocarburized crankshaft and method of manufacturing the same
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