CN115449436B - Floor cleaning agent and preparation method thereof - Google Patents
Floor cleaning agent and preparation method thereof Download PDFInfo
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- CN115449436B CN115449436B CN202211059111.0A CN202211059111A CN115449436B CN 115449436 B CN115449436 B CN 115449436B CN 202211059111 A CN202211059111 A CN 202211059111A CN 115449436 B CN115449436 B CN 115449436B
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 10
- 238000002360 preparation method Methods 0.000 title abstract description 4
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 26
- 239000002738 chelating agent Substances 0.000 claims abstract description 21
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims abstract description 12
- 229930182490 saponin Natural products 0.000 claims abstract description 12
- 150000007949 saponins Chemical class 0.000 claims abstract description 12
- 239000000284 extract Substances 0.000 claims description 53
- -1 sucrose fatty acid ester Chemical class 0.000 claims description 25
- 229920002545 silicone oil Polymers 0.000 claims description 21
- 241000221079 Euphorbia <genus> Species 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 18
- 235000013399 edible fruits Nutrition 0.000 claims description 18
- 229930006000 Sucrose Natural products 0.000 claims description 17
- 244000153888 Tung Species 0.000 claims description 17
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 17
- 239000000194 fatty acid Substances 0.000 claims description 17
- 229930195729 fatty acid Natural products 0.000 claims description 17
- 239000005720 sucrose Substances 0.000 claims description 17
- 239000000022 bacteriostatic agent Substances 0.000 claims description 16
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 claims description 12
- 240000008384 Capsicum annuum var. annuum Species 0.000 claims description 12
- 239000003995 emulsifying agent Substances 0.000 claims description 12
- 241000411851 herbal medicine Species 0.000 claims description 12
- 229940116257 pepper extract Drugs 0.000 claims description 12
- 235000007650 Aralia spinosa Nutrition 0.000 claims description 6
- 241000949456 Zanthoxylum Species 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 2
- QPCDCPDFJACHGM-UHFFFAOYSA-N N,N-bis{2-[bis(carboxymethyl)amino]ethyl}glycine Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(=O)O)CCN(CC(O)=O)CC(O)=O QPCDCPDFJACHGM-UHFFFAOYSA-N 0.000 claims description 2
- 238000013329 compounding Methods 0.000 claims description 2
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 claims description 2
- 229960003330 pentetic acid Drugs 0.000 claims description 2
- LJCNRYVRMXRIQR-OLXYHTOASA-L potassium sodium L-tartrate Chemical compound [Na+].[K+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O LJCNRYVRMXRIQR-OLXYHTOASA-L 0.000 claims description 2
- 229940074439 potassium sodium tartrate Drugs 0.000 claims description 2
- 239000001509 sodium citrate Substances 0.000 claims description 2
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 claims description 2
- 235000011006 sodium potassium tartrate Nutrition 0.000 claims description 2
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims description 2
- 244000269722 Thea sinensis Species 0.000 claims 1
- 241001122767 Theaceae Species 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 9
- 239000006260 foam Substances 0.000 abstract description 9
- 231100000252 nontoxic Toxicity 0.000 abstract description 8
- 230000003000 nontoxic effect Effects 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 6
- 241001465754 Metazoa Species 0.000 abstract description 5
- 238000005202 decontamination Methods 0.000 abstract description 5
- 230000003588 decontaminative effect Effects 0.000 abstract description 5
- 239000003205 fragrance Substances 0.000 abstract description 4
- 239000000419 plant extract Substances 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 3
- 230000014759 maintenance of location Effects 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 238000005187 foaming Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 241000222122 Candida albicans Species 0.000 description 3
- 241000588724 Escherichia coli Species 0.000 description 3
- 241000191967 Staphylococcus aureus Species 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 229940095731 candida albicans Drugs 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 description 3
- 239000008782 xin-kang Substances 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 230000036556 skin irritation Effects 0.000 description 2
- 231100000475 skin irritation Toxicity 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 206010002198 Anaphylactic reaction Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 241000282412 Homo Species 0.000 description 1
- 206010020751 Hypersensitivity Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 241000589517 Pseudomonas aeruginosa Species 0.000 description 1
- 241000607142 Salmonella Species 0.000 description 1
- 240000001866 Vernicia fordii Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 208000026935 allergic disease Diseases 0.000 description 1
- 230000007815 allergy Effects 0.000 description 1
- 230000036783 anaphylactic response Effects 0.000 description 1
- 208000003455 anaphylaxis Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 235000020710 ginseng extract Nutrition 0.000 description 1
- 229930182470 glycoside Natural products 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the field of cleaning agents, in particular to a floor cleaning agent and a preparation method thereof. The composition comprises the following components in percentage by weight: 0.1 to 10 percent of natural nonionic surfactant, 0.1 to 10 percent of bacteriostat, 0.1 to 15 percent of chelating agent, 0.01 to 1 percent of auxiliary agent and the balance of water. The invention adopts the natural plant extracts for matching use, not only does not contain harmful chemical substances, is environment-friendly, and is nontoxic to human and animals, but also has the comprehensive effects of decontamination, sterilization, low-foam fragrance retention and the like, meets the use experience of floor cleaning, and adopts the tea saponin to not only improve the action effect of stains, but also has the characteristic of low foam.
Description
Technical Field
The invention relates to the field of cleaning agents, in particular to a floor cleaning agent and a preparation method thereof.
Background
With the improvement of domestic living standard, the higher the comfort level requirement of people on living environment. Especially, a large number of urban staff can independently rent rooms, leave work and return to a renting room, the 'free feet' of light entering a small room is prone to the first generation of young people, and the requirement for floor/carpet cleaning is no longer a simple clean water mopping. The new comprehensive requirements are: the floor can be decontaminated and sterilized, fragrance is naturally remained, the floor is antiskid, no water is needed for multiple times, and the floor is nontoxic and environment-friendly. While the floor cleaner objects currently on the market appear to be still older. This is not very desirable in terms of functional propaganda, product fragrance. Meanwhile, with the change of the earth environment, the types and the quantity of germs are more and more like common staphylococcus aureus, escherichia coli, pseudomonas aeruginosa, candida albicans, salmonella and the like. Thus, the need for freedom in light foot requires floor cleaners: can sterilize effectively, is natural and nontoxic, has natural smell, and has pleasant and safe use experience. The cleaning agent contains a surfactant component with stronger foaming performance, a large amount of foam is generated when the cleaning tool is rinsed after mopping, and the floor and the cleaning tool are required to be rinsed for a plurality of times until the foam disappears, so that more energy is consumed and water resource waste is caused.
Patent CN108192766a discloses a floor cleaner which has a good grease removal effect while having a faint scent, but has a certain pollution to the environment, and does not conform to the current green environmental protection theme. Thus, there is a need to develop an environmentally friendly floor cleaner that is non-toxic to humans and animals.
Disclosure of Invention
The application provides a floor cleaner which comprises the following components in percentage by weight: 0.1 to 10 percent of natural nonionic surfactant, 0.1 to 10 percent of bacteriostat, 0.1 to 15 percent of chelating agent, 0.01 to 1 percent of auxiliary agent and the balance of water.
Preferably, the floor cleaner comprises the following components in percentage by weight: 0.2 to 7 percent of natural nonionic surfactant, 0.5 to 5 percent of bacteriostat, 0.5 to 2 percent of chelating agent, 0.05 to 0.4 percent of auxiliary agent and the balance of water.
Preferably, the floor cleaner comprises the following components in percentage by weight: 0.2 to 3 percent of natural nonionic surfactant, 1 to 4 percent of bacteriostat, 1 to 2 percent of chelating agent, 0.1 to 0.2 percent of auxiliary agent and the balance of water.
As a preferable technical scheme, the natural nonionic surfactant is tea saponin with purity of 60% and is purchased from Wuhan Haishan technology Co.
Tea saponin is also called tea saponin, is a kind of glycoside compound extracted from tea seeds (tea seeds and tea seeds), and is a natural surfactant with good performance. The hydrophilic group is mainly composed of a stack of oxygen-containing groups, and the hydrophilic group is mainly used as a carbohydrate ligand and an ester ligand of saponin, the esters have the characteristic of low foam, and some esters can be used as defoamers even in specific fields. Which itself has a low foaming property as a surfactant.
As a preferable technical scheme, the bacteriostat is one of Chinese herbal medicine bacteriostat and inorganic bacteriostat.
Preferably, the antibacterial agent is a Chinese herbal medicine antibacterial agent, and the Chinese herbal medicine antibacterial agent is one or more selected from rhizoma paridis extract, folium Artemisiae Argyi extract, herba Euphorbiae Humifusae extract, pericarpium Zanthoxyli extract, glycyrrhrizae radix extract, folium Aleuropaea extract, radix Ginseng extract, rhizoma Ligustici extract, pericarpium Granati extract, and rhizoma Polygoni Cuspidati extract.
Preferably, the Chinese herbal medicine bacteriostat is a humifuse euphorbia herb extract, a green pepper extract and a tung tree leaf extract, and the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:0.5-1.5.
Preferably, the Chinese herbal medicine bacteriostat is a humifuse euphorbia herb extract, a green pepper extract and a tung tree leaf extract, and the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:1.
The invention selects Chinese herbal medicines as raw materials, has low cost, no pungent peculiar smell and obvious sterilization and bacteriostasis effects, does not contain harmful chemical substances such as phosphorus and the like, is environment-friendly and nontoxic to human and animals, does not contain ethanol, avoids the risk of anaphylaxis to the ethanol and skin irritation, and has natural faint scent of Chinese herbal medicine extract and pleasant trust experience in use; particularly, when three specific Chinese herbal medicine bacteriostats are adopted as main bacteriostasis components of the system, the compatibility with the used natural nonionic surfactant tea saponin is good, and the bacteriostasis performance of the tea saponin can be promoted, especially when the weight ratio of the humifuse euphorbia herb extract, the green pepper extract and the tung oil tree leaf extract is 1:1:0.5-1.5, the bacteriostasis to escherichia coli, staphylococcus aureus and candida albicans is good.
As a preferable technical scheme, the chelating agent is at least one of an amino carboxylic acid compound, an organic amino phosphonic acid compound, sodium citrate, ammonium citrate and potassium sodium tartrate.
Preferably, the chelating agent is an amino carboxylic acid compound, and the amino carboxylic acid compound is at least one of amino triacetic acid, ethylenediamine tetraacetic acid and diethylenetriamine pentaacetic acid.
Preferably, the chelating agent is aminotriamine.
As a preferable technical scheme, the auxiliary agent is the compounding of silicone oil and fruit acid.
Silicone oil and fruit acid are added into the system, so that the effects of defoaming and skid resistance can be achieved, meanwhile, the thickening effect is achieved, and the stability of the system is improved.
Preferably, the weight ratio of the silicone oil to the fruit acid is 1:1-3;
preferably, the weight ratio of the silicone oil to the fruit acid is 1:2.
As a preferable technical scheme, the floor cleaner also comprises an emulsifier sucrose fatty acid ester, wherein the addition amount of the sucrose fatty acid ester is 20-30wt% of the content of the natural nonionic surfactant.
When the sucrose fatty acid ester serving as an emulsifier is added into the system, the stability of the whole system is improved, and adverse phenomena such as flocculation are avoided, so that the decontamination effect of the cleanser is ensured.
Preferably, the sucrose fatty acid ester is added in an amount of 25wt% of the natural nonionic surfactant content.
In another aspect, the present application provides a method of preparing a floor cleaner comprising the steps of: and sequentially adding the required weight parts of natural nonionic surfactant, the bacteriostatic agent, the chelating agent, the auxiliary agent and the emulsifying agent into water, and uniformly stirring to obtain the floor cleaner.
The invention has the following beneficial effects: 1) The invention adopts the natural plant extracts for matching use, not only does not contain harmful chemical substances, is environment-friendly, and is nontoxic to human and animals, but also has the comprehensive effects of decontamination, sterilization, low foam, natural fragrance retention of plants and the like, and meets the use experience of floor cleaning; 2) The tea saponin adopted in the invention is natural and nontoxic, has good decontamination effect and antibacterial effect, and has the characteristic of low foam compared with common surfactants; 3) The plant extract is used as the bactericide, so that the bactericide is not only free of irritant peculiar smell, but also environment-friendly, nontoxic to human and animals, especially free of ethanol, free of risk of ethanol allergy and free of skin irritation, and the Chinese herbal medicine extract has natural faint scent, has pleasant trust experience in use, and particularly has an excellent antibacterial effect; 4) The silicone oil, the fruit acid and the like added in the product formula not only stabilize the product properties, but also play the functions of low foam property, wettability and the like, and compared with the common cleaning products, the cleaning products do not need to be washed with water for many times, and are more time-saving and environment-friendly.
Detailed Description
Example 1
The embodiment 1 of the invention provides a floor cleaner, which comprises the following components in percentage by weight: 1.5% of natural nonionic surfactant, 2.5% of bacteriostat, 1.5% of chelating agent, 0.15% of auxiliary agent and the balance of water.
The natural nonionic surfactant is tea saponin with purity of 60%, and is purchased from the mountain of the Wuhan mountain of the China company.
The bacteriostatic agent is a Chinese herbal medicinal bacteriostatic agent, and the Chinese herbal medicinal bacteriostatic agent is a humifuse euphorbia herb extract, a green pepper extract and a tung tree leaf extract, wherein the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:1.
The humifuse euphorbia herb extract is SH-01, and is purchased from Shaanxi Xinkang biotechnology Co., ltd; the green pricklyash peel extract is HY-236, and is purchased from Shaanxi Haoyang Biotechnology Co., ltd; the tung tree leaf extract was purchased from sienna tenuifolia biotechnology limited.
The chelating agent is aminotriamine.
The auxiliary agent is a compound of silicone oil and fruit acid, and the weight ratio of the silicone oil to the fruit acid is 1:2.
The silicone oil is dimethyl silicone oil with a viscosity (25 ℃ cp) of 500, and is purchased from Guangzhou Hetai chemical industry trade company.
The fruit acid was purchased from Hebei's source biotechnology Co.
The floor cleaner also comprises an emulsifier sucrose fatty acid ester, wherein the addition amount of the sucrose fatty acid ester is 25 weight percent of the content of the natural nonionic surfactant.
The sucrose fatty acid ester is SE-13G, and is purchased from Guangxi Gaotong food technology Co.
In another aspect, the present embodiment provides a method for preparing a floor cleaner, including the steps of: and sequentially adding the required weight parts of natural nonionic surfactant, the bacteriostatic agent, the chelating agent, the auxiliary agent and the emulsifying agent into water, and uniformly stirring to obtain the floor cleaner.
Example 2
The embodiment 2 of the invention provides a floor cleaner which comprises the following components in percentage by weight: 0.5% of natural nonionic surfactant, 1% of bacteriostat, 1% of chelating agent, 0.1% of auxiliary agent and the balance of water.
The natural nonionic surfactant is tea saponin with purity of 60%, and is purchased from the mountain of the Wuhan mountain of the China company.
The bacteriostatic agent is a Chinese herbal medicinal bacteriostatic agent, and the Chinese herbal medicinal bacteriostatic agent is a humifuse euphorbia herb extract, a green pepper extract and a tung tree leaf extract, wherein the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:0.5.
The humifuse euphorbia herb extract is SH-01, and is purchased from Shaanxi Xinkang biotechnology Co., ltd; the green pricklyash peel extract is HY-236, and is purchased from Shaanxi Haoyang Biotechnology Co., ltd; the tung tree leaf extract was purchased from sienna tenuifolia biotechnology limited.
The chelating agent is aminotriamine.
The auxiliary agent is a compound of silicone oil and fruit acid, and the weight ratio of the silicone oil to the fruit acid is 1:1.
The silicone oil is dimethyl silicone oil with a viscosity (25 ℃ cp) of 500, and is purchased from Guangzhou Hetai chemical industry trade company.
The fruit acid was purchased from Hebei's source biotechnology Co.
The floor cleaner also comprises an emulsifier sucrose fatty acid ester, wherein the addition amount of the sucrose fatty acid ester is 30 weight percent of the content of the natural nonionic surfactant.
The sucrose fatty acid ester is SE-13G, and is purchased from Guangxi Gaotong food technology Co.
In another aspect, the present embodiment provides a method for preparing a floor cleaner, including the steps of: and sequentially adding the required weight parts of natural nonionic surfactant, the bacteriostatic agent, the chelating agent, the auxiliary agent and the emulsifying agent into water, and uniformly stirring to obtain the floor cleaner.
Example 3
The embodiment 3 of the invention provides a floor cleaner, which comprises the following components in percentage by weight: 3% of natural nonionic surfactant, 4% of bacteriostat, 2% of chelating agent, 0.2% of auxiliary agent and the balance of water.
The natural nonionic surfactant is tea saponin with purity of 60%, and is purchased from the mountain of the Wuhan mountain of the China company.
The bacteriostatic agent is a Chinese herbal medicinal bacteriostatic agent, and the Chinese herbal medicinal bacteriostatic agent is a humifuse euphorbia herb extract, a green pepper extract and a tung tree leaf extract, wherein the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:1.5.
The humifuse euphorbia herb extract is SH-01, and is purchased from Shaanxi Xinkang biotechnology Co., ltd; the green pricklyash peel extract is HY-236, and is purchased from Shaanxi Haoyang Biotechnology Co., ltd; the tung tree leaf extract was purchased from sienna tenuifolia biotechnology limited.
The chelating agent is aminotriamine.
The auxiliary agent is a compound of silicone oil and fruit acid, and the weight ratio of the silicone oil to the fruit acid is 1:3.
The silicone oil is dimethyl silicone oil with a viscosity (25 ℃ cp) of 500, and is purchased from Guangzhou Hetai chemical industry trade company.
The fruit acid was purchased from Hebei's source biotechnology Co.
The floor cleaner also comprises an emulsifier sucrose fatty acid ester, wherein the addition amount of the sucrose fatty acid ester is 20wt% of the content of the natural nonionic surfactant.
The sucrose fatty acid ester is SE-13G, and is purchased from Guangxi Gaotong food technology Co.
In another aspect, the present embodiment provides a method for preparing a floor cleaner, including the steps of: and sequentially adding the required weight parts of natural nonionic surfactant, the bacteriostatic agent, the chelating agent, the auxiliary agent and the emulsifying agent into water, and uniformly stirring to obtain the floor cleaner.
Comparative example 1
The invention provides a floor cleaner in comparative example 1, and the specific implementation mode is the same as example 1, wherein the Chinese herbal medicine bacteriostat is humifuse euphorbia herb extract, green pricklyash peel extract and tung tree leaf extract, and the weight ratio of the humifuse euphorbia herb extract, green pricklyash peel extract to the tung tree leaf extract is 1:1:0.1.
Comparative example 2
The invention provides a floor cleaner in comparative example 2, and the specific implementation mode is the same as example 1, wherein the auxiliary agent is a compound of silicone oil and fruit acid, and the weight ratio of the silicone oil to the fruit acid is 0.5:2.
Comparative example 3
Comparative example 3 of the present invention provides a floor cleaner, which is different from example 1 in that the floor cleaner further comprises an emulsifier sucrose fatty acid ester, wherein the added amount of the sucrose fatty acid ester is 10wt% of the content of the natural nonionic surfactant.
Performance testing
All the products obtained in the examples and comparative examples were diluted 100 times by volume and subjected to the following performance tests.
1. Antibacterial performance: the bacteriostasis rate against E.coli, staphylococcus aureus and Candida albicans was tested according to standard QB/T2738.
2. Decontamination performance: the soil release performance was tested according to standard QB/T4532.
3. Foaming properties: the initial foam height is tested according to standard GB/T13173, the higher the height the better the foaming properties, and conversely the lower the foaming properties, i.e.the low foamability.
The test results are shown in Table 1.
TABLE 1
Claims (4)
1. A floor cleaner, comprising the following components in percentage by weight: 0.2 to 7 percent of natural nonionic surfactant, 0.5 to 5 percent of bacteriostat, 0.5 to 2 percent of chelating agent, 0.05 to 0.4 percent of auxiliary agent, and the balance of emulsifying agent sucrose fatty acid ester and water; the natural nonionic surfactant is tea saponin, and the addition amount of the sucrose fatty acid ester is 20-30wt% of the content of the natural nonionic surfactant;
the bacteriostatic agent is a Chinese herbal medicine bacteriostatic agent;
the Chinese herbal medicine bacteriostat is a humifuse euphorbia herb extract, a green pricklyash peel extract and a tung tree leaf extract; the weight ratio of the humifuse euphorbia herb extract to the green pepper extract to the tung tree leaf extract is 1:1:0.5 or 1:1:1;
the auxiliary agent is the compounding of silicone oil and fruit acid;
the weight ratio of the silicone oil to the fruit acid is 1:1-3.
2. A floor cleaning agent according to claim 1 wherein the chelating agent is at least one of an amino carboxylic acid compound, an organic amino phosphonic acid compound, sodium citrate, ammonium citrate, potassium sodium tartrate.
3. A floor cleaning agent according to claim 1 wherein the chelating agent is an amino carboxylic acid compound which is at least one of amino triacetic acid, ethylenediamine tetraacetic acid, diethylenetriamine pentaacetic acid.
4. A method of preparing a floor cleaner according to any one of claims 1 to 3, comprising the steps of: sequentially adding the natural nonionic surfactant, the bacteriostatic agent, the chelating agent, the auxiliary agent and the emulsifying agent in the required weight percentage into water, and uniformly stirring to obtain the floor cleaning agent.
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