CN115449263A - Green environment-friendly water-soluble fluorescent ink - Google Patents

Green environment-friendly water-soluble fluorescent ink Download PDF

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Publication number
CN115449263A
CN115449263A CN202211118387.1A CN202211118387A CN115449263A CN 115449263 A CN115449263 A CN 115449263A CN 202211118387 A CN202211118387 A CN 202211118387A CN 115449263 A CN115449263 A CN 115449263A
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CN
China
Prior art keywords
fluorescent ink
friendly water
counterfeiting
green environment
green
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202211118387.1A
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Chinese (zh)
Inventor
刘大颖
丁琳
滕俊杰
王冉冉
马文哲
石军
邓思林
罗兰海
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Tianjin Agricultural University
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Tianjin Agricultural University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tianjin Agricultural University filed Critical Tianjin Agricultural University
Priority to CN202211118387.1A priority Critical patent/CN115449263A/en
Publication of CN115449263A publication Critical patent/CN115449263A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/50Sympathetic, colour changing or similar inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/16Writing inks

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses green and environment-friendly water-soluble fluorescent ink which is prepared from kitchen garbage such as fruit peels and vegetable bits and the like serving as raw materials by a microwave oven or an oven at a high temperature, and is safe, green, environment-friendly and pollution-free. The green environment-friendly water-soluble fluorescent ink also has a fluorescent invisible anti-counterfeiting function.

Description

Green environment-friendly water-soluble fluorescent ink
Technical Field
The invention belongs to the field of fluorescence anti-counterfeiting, and particularly relates to green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink and related application thereof.
Background
Fluorescence is a common phenomenon in nature. When a normal temperature substance is irradiated by incident light (usually ultraviolet) with a certain wavelength, the light energy is absorbed and enters an excited state, then the excited state is de-excited and the time is very short (10) -8 Second) transmissionVisible light with various colors and different intensities (usually, the wavelength is in the visible light region and is longer than the wavelength of incident light), and when the ultraviolet light stops irradiating, the light-emitting phenomenon also disappears immediately. Light with this property is fluorescence [1 ]]. The fluorescence characteristics of substances are related to various factors, and the fluorescence phenomenon is widely applied to various fields.
The criminal cases such as forged documents, critics, bills and the like are in a high trend, and the forging criminal behaviors seriously damage the good trust of the social public on the state organs, further damage the normal public management activities of the state organs and seriously threaten the state safety and the property safety of people. Therefore, the research on a novel environment-friendly anti-counterfeiting technology is of great significance.
There are many security technologies, and those related to fluorescence are paper and printing inks. Fluorescent ink technology is mature at present and is one of the most important means for printing banknotes. Now, the abuse of fluorescent agents causes environmental pollution. Therefore, the development of the green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink has extremely important significance.
Disclosure of Invention
Aiming at the defects in the prior art and the other defects, the inventor of the application invents a preparation method and application of green and environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink through a great deal of creative research work. The product is prepared by taking kitchen garbage such as fruit peels, vegetable heads and the like as raw materials and performing high-temperature preparation in a microwave oven or an oven, has good water solubility, is green, environment-friendly and pollution-free, has a hidden anti-counterfeiting function, and is suitable for various writing, pictures and the like. To achieve the above and other objects, the present invention provides the following solutions.
In the first aspect of the invention, a preparation method of green and environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink is provided.
In a preferred embodiment, the raw material is selected from lemon peel, mango peel, citrus peel:
in a preferred embodiment, the product of the present invention can be used to write hot words, graffiti strokes, etc.
In a second aspect of the invention, a green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink is provided, which is green, environment-friendly and pollution-free.
In a third aspect of the invention, there is provided the use of the product of the invention in covert security applications. In a preferred embodiment, the technique is a fluorescence technique.
The green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink has the following outstanding technical advantages:
1. the invention takes kitchen garbage such as fruit peel, vegetable head and the like as raw materials, changes waste into valuable and accords with the concept of environmental protection and sustainable development.
2. The raw materials of the invention are taken from the family in life, no professional chemical reagent is needed, the invention is safe and green, and the public can operate.
3. The product of the invention has fluorescent invisible anti-counterfeiting function.
Drawings
FIG. 1 is a technical route for preparing green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink.
FIG. 2 shows that the green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink is prepared from lemon peel, mango peel and orange peel.
FIG. 3 shows the effect of writing simple Chinese characters such as "one, two, three, you are good" with the green environmental protection water-soluble invisible anti-counterfeiting fluorescent ink of the invention.
FIG. 4 shows the hot word writing effect of the green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink.
FIG. 5 shows the effect of the green, environment-friendly, water-soluble, invisible and anti-counterfeiting fluorescent ink painting simple strokes.
Detailed Description
Crushing kitchen garbage such as fruit peel and vegetable head in a juice extractor; then putting the smashed residues into a container, and putting the container into a microwave oven to be fired for 20-40 minutes; grinding the solid treated by the high temperature treatment of the microwave oven, adding a certain amount of water, stirring and soaking, filtering by using a filter screen, and taking the filtrate for later use. The fluorescent light is observed by illuminating with a currency detecting lamp. The prepared fluorescent ink is used for writing and drawing.
FIG. 1 shows a technical route for preparing green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink by taking specific raw materials as examples. It is noted that the starting materials are used herein for ease of understanding only, and one skilled in the art can make necessary modifications to the technical route for these particular starting materials to make other fluorescent inks useful in the present invention.
While the invention has been described in conjunction with specific embodiments thereof, it will be understood that they have been presented by way of illustration and description, but not limitation. Those skilled in the art, having the benefit of this disclosure, may effect numerous modifications to the specific embodiments disclosed herein without departing from the spirit and scope of the invention as defined by the appended claims. The scope of the invention is defined by the appended claims, and all changes that come within the meaning and range of equivalency of the claims are intended to be embraced therein.
The present invention will be further described with reference to the following examples. In the following examples, specific preparation routes are provided to illustrate the preparation of the product of the invention and its specific application as an ink. The examples are provided only to illustrate how the invention may be carried out and are not intended to be limiting in any way. Those skilled in the art can use the specific examples given below to give a reverse example.
Unless otherwise indicated in the context of the present application, the technical terms and abbreviations used in the present application have the conventional meaning known to those skilled in the art.
The skilled in the art can prepare the green environment-friendly water-soluble invisible anti-counterfeiting fluorescent ink according to the ideas and the synthesis methods provided by the specification, which is not described herein again.

Claims (7)

1. The green environment-friendly water-soluble anti-counterfeiting fluorescent ink is characterized by being prepared from kitchen garbage such as fruit peels, vegetable heads and the like.
2. The green environment-friendly water-soluble anti-counterfeiting fluorescent ink according to claim 1, which is prepared from lemon peel, mango peel and orange peel by high-temperature treatment in a microwave oven or an oven.
3. The green environment-friendly water-soluble anti-counterfeiting fluorescent ink as claimed in claim 2, which is characterized by good water solubility.
4. The green environment-friendly water-soluble anti-counterfeiting fluorescent ink according to claim 3, which is green and environment-friendly without pollution and needs no chemical reagent.
5. The green environment-friendly water-soluble anti-counterfeiting fluorescent ink according to claim 4, characterized in that the green environment-friendly water-soluble anti-counterfeiting fluorescent ink is pollution-free and does not need any chemical reagent.
6. The product of claim 5, wherein the green environment-friendly water-soluble anti-counterfeiting fluorescent ink is anti-counterfeiting by a fluorescent technology, writing is traceless under normal sunlight, and fluorescent writing appears by using a currency detecting lamp or an ultraviolet lamp for irradiation.
7. The product of claim 5, wherein the product is used for writing and anti-counterfeiting of writing, drawing and the like.
CN202211118387.1A 2022-09-15 2022-09-15 Green environment-friendly water-soluble fluorescent ink Pending CN115449263A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202211118387.1A CN115449263A (en) 2022-09-15 2022-09-15 Green environment-friendly water-soluble fluorescent ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202211118387.1A CN115449263A (en) 2022-09-15 2022-09-15 Green environment-friendly water-soluble fluorescent ink

Publications (1)

Publication Number Publication Date
CN115449263A true CN115449263A (en) 2022-12-09

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202211118387.1A Pending CN115449263A (en) 2022-09-15 2022-09-15 Green environment-friendly water-soluble fluorescent ink

Country Status (1)

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CN (1) CN115449263A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105905884A (en) * 2016-04-23 2016-08-31 哈尔滨师范大学 Preparation method and application of fluorescence carbon quantum dots
CN106833630A (en) * 2017-01-22 2017-06-13 桂林碳谷科技有限公司 A kind of pH response types blue-fluorescence carbon quantum dot and its preparation method and application

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105905884A (en) * 2016-04-23 2016-08-31 哈尔滨师范大学 Preparation method and application of fluorescence carbon quantum dots
CN106833630A (en) * 2017-01-22 2017-06-13 桂林碳谷科技有限公司 A kind of pH response types blue-fluorescence carbon quantum dot and its preparation method and application

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中国材料研究学会组织编写: "《前沿新材料概论》", 中国铁道出版社有限公司, pages: 334 - 335 *

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