CN115446049A - Economical waste paint bucket cleaning process - Google Patents

Economical waste paint bucket cleaning process Download PDF

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Publication number
CN115446049A
CN115446049A CN202210997140.5A CN202210997140A CN115446049A CN 115446049 A CN115446049 A CN 115446049A CN 202210997140 A CN202210997140 A CN 202210997140A CN 115446049 A CN115446049 A CN 115446049A
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China
Prior art keywords
waste paint
steel slag
solution
paint bucket
cleaning process
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CN202210997140.5A
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Chinese (zh)
Inventor
周丹
王文涛
胡历
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Baowu Huanke Wuhan Metal Resources Co ltd
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Baowu Huanke Wuhan Metal Resources Co ltd
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Priority to CN202210997140.5A priority Critical patent/CN115446049A/en
Publication of CN115446049A publication Critical patent/CN115446049A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B08CLEANING
    • B08BCLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B9/00Cleaning hollow articles by methods or apparatus specially adapted thereto 
    • B08B9/08Cleaning containers, e.g. tanks
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/261Alcohols; Phenols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/263Ethers

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Mechanical Engineering (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an economical waste paint bucket cleaning process, which comprises the steps of soaking steel slag tailings in a water tank to obtain a steel slag tailings soaking solution, wherein the pH value is 11-13; adding alkali into the obtained steel slag tailing soaking solution to increase the pH value to be more than 13; mixing the obtained soaking solution, diethylene glycol, propylene glycol and sodium polyacrylate to prepare a cleaning solution; placing a waste paint bucket in cleaning fluid to be heated and stirred; taking out the waste paint after the waste paint is stripped and sending the waste paint to a briquetting workshop; the cleaning solution is prepared by treating and compounding the steel slag tailings in the solid waste resources of the steel mill, the residual waste paint after the waste paint bucket is dumped is economically and effectively removed through a specific cleaning process, and the quality of briquettes returned to the steel mill is ensured; the invention also provides a resource utilization method for the steel slag tailings.

Description

Economical waste paint bucket cleaning process
Technical Field
The invention relates to a waste paint bucket cleaning process.
Background
According to the latest national catalog of dangerous wastes, waste oil barrels and waste paint barrels are containers containing or directly infected with dangerous wastes, and belong to dangerous wastes. At present, after a waste paint bucket enters a factory, waste paint is firstly poured into a collecting pool and then is put on a compression packer to be pressed into a pressing block for packing and outputting. But most waste paint bucket back, waste paint is the semi-solid state already, can't pour out completely, mainly leans on to extrude waste paint when flattening on the baling press, and this kind of method not only can harm the baling press belt, leads to the belt to glue unable rotation and influences production, still can influence the briquetting and return the production quality behind the steelworks.
How effectively get rid of the waste paint bucket economically and empty remaining waste paint after, guarantee to return the quality of steelmaking mill briquetting and become the problem that waits for immediate solution.
Disclosure of Invention
The invention aims to prepare a cleaning solution by treating and compounding steel slag tailings in solid waste resources of a steel mill, economically and effectively remove waste paint remained after a waste paint bucket is dumped through a specific cleaning process, and ensure the quality of briquettes returned to the steel mill; the invention also aims to provide a resource utilization method for the steel slag tailings.
In order to achieve the purpose, the technical scheme is as follows:
an economical waste paint bucket cleaning process comprises the following steps:
(1) Soaking the steel slag tailings in a water tank to obtain a steel slag tailings soaking solution, wherein the pH value is 11-13;
(2) Adding alkali into the obtained steel slag tailing soaking solution to increase the pH value to be more than 13;
(3) Mixing the soak solution obtained in the step (2), diethylene glycol, propylene glycol and sodium polyacrylate to prepare a cleaning solution;
(4) Placing a waste paint bucket in cleaning fluid to be heated and stirred; and taking out the waste paint after the waste paint is stripped and sending the waste paint to a briquetting workshop.
According to the scheme, the mass ratio of the steel slag tailings to the water in the step 1 is 1:3, 1 ton of steel slag tailings is soaked in a water pool with the size of 3 cubic meters for 7 days, and then the steel slag tailings soaking liquid is obtained, wherein the pH value is 11-13.
According to the scheme, the alkali in the step 2 is caustic soda flakes, sodium carbonate or other chemical reagents for increasing the pH value.
According to the scheme, the step 3 comprises the following steps in parts by weight:
100 parts of a soaking solution; 3-8 parts of diethylene glycol; 1-5 parts of propylene glycol; 1-5 parts of sodium polyacrylate.
According to the scheme, the step 4 is kept at the temperature of 70-90 ℃ and stirred for 35-45min.
According to the scheme, the method also comprises the step of filtering the cleaning solution after the step 4 and then refluxing the cleaning solution to the water pool in the step 1 for repeated use.
The steel slag tailings in the solid waste resources of the steel mill are composed of a large amount of oxides, can be made into high alkalinity after simple treatment, is doped with proper flake caustic soda and a surfactant, and can be prepared into a cleaning solution capable of cleaning paint impurities remained in a waste paint bucket according to a specific proportion. The cleaning liquid obtained by the invention can slowly soften the adhesive force between the waste paint adhered to the barrel and the surface of the barrel in a high-temperature environment, and can effectively separate the waste paint through continuous mechanical stirring.
Compared with the prior art, the invention has the following beneficial effects:
1) The main components of the steel slag tailings are CaO, mgO and other minerals, and after the steel slag tailings are fully soaked, the PH value of the solution can reach 11-13, so that the steel slag tailings have the effect of recycling solid waste resources of a steel mill. Meanwhile, the use of alkali is reduced, and the cost is saved.
2) The process utilizes the fact that the adhesive force between the waste paint adhered on the barrel and the surface of the barrel can be slowly softened under the environment of high temperature and strong alkali, and the waste paint can be effectively separated through continuous mechanical stirring.
3) Diethylene glycol and propylene glycol are surface dispersing active agents, and the adhesion force between the waste paint and the barrel surface can be eliminated in a speeded-up manner in the constant-temperature stirring process.
4) The sodium polyacrylate can soften the waste paint and flocculate the dust particles in the immersion liquid, so that the cleanness of the oil drum after cleaning is ensured.
Drawings
FIG. 1: the invention relates to a waste paint bucket cleaning process flow chart.
Detailed Description
The following examples further illustrate the technical solutions of the present invention, but should not be construed as limiting the scope of the present invention.
In one embodiment, an economical waste paint bucket cleaning process is provided, as shown in fig. 1:
(1) Soaking the steel slag tailings in a water tank to obtain a steel slag tailing soaking liquid, wherein the pH value is 11-13;
(2) Adding alkali into the obtained steel slag tailing soaking solution to increase the pH value to be more than 13;
(3) Mixing the soak solution obtained in the step (2), diethylene glycol, propylene glycol and sodium polyacrylate to prepare a cleaning solution;
(4) Placing a waste paint bucket in cleaning fluid to be heated and stirred; taking out the waste paint after the waste paint is stripped and sending the waste paint to a briquetting workshop;
specifically, the mass ratio of the steel slag tailings to the water in the step 1 is 1:3, and after one ton of the steel slag tailings is soaked in a water pool with the size of 3 cubic meters for 7 days, a steel slag tailing soaking solution is obtained, and the pH value is 11-13.
Specifically, the alkali in step 2 can be caustic soda flakes, sodium carbonate or other chemical agents for raising the pH value.
Specifically, the step 3 comprises the following components in parts by weight:
100 parts of soaking solution; 3-8 parts of diethylene glycol; 1-5 parts of propylene glycol; 1-5 parts of sodium polyacrylate.
Specifically, in the step 4, the mixture is stirred for 35-45min at the temperature of 70-90 ℃.
And filtering the cleaning solution after the step 4, and then refluxing the cleaning solution to the water pool in the step 1 for reuse.
Table 1 shows the raw material ratios and process parameters of the examples.
TABLE 1
Figure BDA0003805834610000031
The above description is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, many modifications and changes can be made without departing from the inventive concept of the present invention, and these modifications and changes are within the protection scope of the present invention.

Claims (6)

1. An economical waste paint bucket cleaning process is characterized by comprising the following steps:
(1) Soaking the steel slag tailings in a water tank to obtain a steel slag tailings soaking solution, wherein the pH value is 11-13;
(2) Adding alkali into the obtained steel slag tailing soaking solution to increase the pH value to be more than 13;
(3) Mixing the soak solution obtained in the step (2), diethylene glycol, propylene glycol and sodium polyacrylate to prepare a cleaning solution;
(4) Placing a waste paint bucket in cleaning fluid to be heated and stirred; and taking out the waste paint after the waste paint is stripped and sending the waste paint to a briquetting workshop.
2. The economic waste paint bucket cleaning process as claimed in claim 1, wherein the mass ratio of the steel slag tailings to the water in the step 1 is 1:3, and after 1 ton of the steel slag tailings is soaked in a 3 cubic meter water pool for 7 days, a steel slag tailings soaking solution is obtained, and the pH value is 11-13.
3. The economical waste paint bucket cleaning process of claim 1, wherein in step 2, the alkali is flake alkali, soda ash or other chemical agent for raising pH value.
4. The economic waste paint bucket cleaning process as set forth in claim 1, wherein the step 3 comprises the following steps in parts by weight:
100 parts of a soaking solution; 3-8 parts of diethylene glycol; 1-5 parts of propylene glycol; 1-5 parts of sodium polyacrylate.
5. The economical waste paint bucket cleaning process as claimed in claim 1, wherein the stirring in step 4 is carried out at 70-90 ℃ for 35-45min.
6. The economical waste paint bucket cleaning process of claim 1 further comprising filtering the cleaning solution after step 4 and returning the filtered cleaning solution to the water basin of step 1 for reuse.
CN202210997140.5A 2022-08-19 2022-08-19 Economical waste paint bucket cleaning process Pending CN115446049A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210997140.5A CN115446049A (en) 2022-08-19 2022-08-19 Economical waste paint bucket cleaning process

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Application Number Priority Date Filing Date Title
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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1831052A (en) * 2005-03-11 2006-09-13 佛山市顺德区汉达精密电子科技有限公司 Paint remover and method for removing paint from surface of plastic articles
CN104231717A (en) * 2014-10-17 2014-12-24 景丽 Oil paint stripping agent and preparation method thereof
CN104327580A (en) * 2014-10-12 2015-02-04 青岛康泰鑫环保科技有限公司 High-efficiency paint remover
CN106540525A (en) * 2016-11-25 2017-03-29 江西理工大学 A kind of collaboration is using CO in slag and the stable waste gas of waste water2Method and device
WO2018090428A1 (en) * 2016-11-15 2018-05-24 姚佑灿 Cleaning agent for removing paint on plastic surface and preparation method thereof
CN215918597U (en) * 2021-07-14 2022-03-01 惠州Tcl环境科技有限公司 Resourceful combined treatment device for alkaline waste stripping liquid and waste paint bucket

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1831052A (en) * 2005-03-11 2006-09-13 佛山市顺德区汉达精密电子科技有限公司 Paint remover and method for removing paint from surface of plastic articles
CN104327580A (en) * 2014-10-12 2015-02-04 青岛康泰鑫环保科技有限公司 High-efficiency paint remover
CN104231717A (en) * 2014-10-17 2014-12-24 景丽 Oil paint stripping agent and preparation method thereof
WO2018090428A1 (en) * 2016-11-15 2018-05-24 姚佑灿 Cleaning agent for removing paint on plastic surface and preparation method thereof
CN106540525A (en) * 2016-11-25 2017-03-29 江西理工大学 A kind of collaboration is using CO in slag and the stable waste gas of waste water2Method and device
CN215918597U (en) * 2021-07-14 2022-03-01 惠州Tcl环境科技有限公司 Resourceful combined treatment device for alkaline waste stripping liquid and waste paint bucket

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