CN115305599A - Manufacturing process of cloth for ultraviolet-proof stain-resistant fabric curtain - Google Patents
Manufacturing process of cloth for ultraviolet-proof stain-resistant fabric curtain Download PDFInfo
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- CN115305599A CN115305599A CN202210943340.2A CN202210943340A CN115305599A CN 115305599 A CN115305599 A CN 115305599A CN 202210943340 A CN202210943340 A CN 202210943340A CN 115305599 A CN115305599 A CN 115305599A
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- resistant fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 96
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- 239000011248 coating agent Substances 0.000 claims abstract description 28
- 239000000835 fiber Substances 0.000 claims abstract description 27
- 238000000576 coating method Methods 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 16
- ASYVNKJNTGRTHC-UHFFFAOYSA-N 2-hydroxybenzoic acid;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.OC(=O)C1=CC=CC=C1O ASYVNKJNTGRTHC-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 13
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 13
- 241001330002 Bambuseae Species 0.000 claims abstract description 13
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims abstract description 13
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 13
- 239000011425 bamboo Substances 0.000 claims abstract description 13
- 150000002148 esters Chemical class 0.000 claims abstract description 12
- 229920000728 polyester Polymers 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 11
- 229920005989 resin Polymers 0.000 claims abstract description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- JGFBRKRYDCGYKD-UHFFFAOYSA-N dibutyl(oxo)tin Chemical compound CCCC[Sn](=O)CCCC JGFBRKRYDCGYKD-UHFFFAOYSA-N 0.000 claims abstract description 8
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011787 zinc oxide Substances 0.000 claims abstract description 8
- -1 salicylic acid ester compounds Chemical class 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims description 19
- 238000009987 spinning Methods 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 239000003292 glue Substances 0.000 claims description 4
- 229920000058 polyacrylate Polymers 0.000 claims description 4
- 230000000844 anti-bacterial effect Effects 0.000 claims description 3
- 238000002074 melt spinning Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 150000003902 salicylic acid esters Chemical class 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 238000002791 soaking Methods 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 13
- 239000000654 additive Substances 0.000 abstract description 6
- 230000000996 additive effect Effects 0.000 abstract description 6
- 230000005855 radiation Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 238000012545 processing Methods 0.000 abstract description 3
- 230000003197 catalytic effect Effects 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 230000004224 protection Effects 0.000 abstract description 2
- 239000004902 Softening Agent Substances 0.000 abstract 1
- 238000002834 transmittance Methods 0.000 description 8
- 210000003491 skin Anatomy 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 5
- 239000011487 hemp Substances 0.000 description 5
- 244000025254 Cannabis sativa Species 0.000 description 4
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 4
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 4
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 4
- 235000009120 camo Nutrition 0.000 description 4
- 235000005607 chanvre indien Nutrition 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- 229920000297 Rayon Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000019612 pigmentation Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 241000185686 Apocynum venetum Species 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000007999 Nuclear Proteins Human genes 0.000 description 1
- 108010089610 Nuclear Proteins Proteins 0.000 description 1
- 206010040844 Skin exfoliation Diseases 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000006750 UV protection Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010835 comparative analysis Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000035618 desquamation Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000006552 photochemical reaction Methods 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47H—FURNISHINGS FOR WINDOWS OR DOORS
- A47H23/00—Curtains; Draperies
- A47H23/02—Shapes of curtains; Selection of particular materials for curtains
- A47H23/08—Selection of particular materials
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0068—Polymeric granules, particles or powder, e.g. core-shell particles, microcapsules
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0086—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
- D06N3/0088—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/14—Properties of the materials having chemical properties
- D06N2209/146—Soilproof, soil repellent
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1678—Resistive to light or to UV
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention provides a manufacturing process of cloth for an ultraviolet-proof stain-resistant fabric curtain, which comprises the steps of treating and processing dimensional polyester chips, bamboo fibers, organic resin, inorganic nano zinc oxide, inorganic nano titanium oxide, a softening agent and a coupling agent, and treating the processed materials by using a finishing liquid to finally obtain the fabric with a stain-resistant effect. Salicylic acid bisphenol A ester with radiation protection effect is obtained by reacting salicylic acid ester compounds with dibutyltin oxide with catalytic action, and is used as an ultraviolet-proof additive. And finally, coating the ultraviolet-proof additive salicylic acid bisphenol A ester on the stain-resistant fabric by a coating method to form an ultraviolet-proof film on the stain-resistant fabric, and finally preparing the ultraviolet-proof stain-resistant fabric which is used for curtain cloth and can effectively prevent ultraviolet rays from damaging human bodies.
Description
Technical Field
The invention relates to the field of cloth processing, in particular to a manufacturing process of cloth for an ultraviolet-proof stain-resistant fabric curtain.
Background
Preventing ultraviolet rays from damaging human bodies is being paid more and more attention by consumers. Ultraviolet rays in the solar spectrum not only cause the color fading and embrittlement of textiles, but also cause the sunburn and aging of human skin, generate melanin and color spots, and further induce canceration to harm human health.
The ultraviolet rays have the most significant effect on the skin and eyes of the human body. The absorption of ultraviolet light by the skin is related to its wavelength. The shorter the wavelength, the less deep the skin is penetrated, and the less melanin pigmentation after irradiation; the longer the wavelength, the greater the penetration depth into the skin and the greater the pigmentation after irradiation. The photon flow with higher energy level can cause the denaturation of nuclear protein and some enzymes in the cell due to the action of photochemical reaction.
The curtain is made of cloth, hemp, yarn, aluminum sheet, wood chip, metal material, etc. and has the functions of shading sun, insulating heat and regulating indoor light. The cloth curtain is divided into cotton gauze, polyester fabric, polyester-cotton blended fabric, cotton-hemp blended fabric, non-woven fabric and the like according to the material, different materials, textures, colors, patterns and the like are integrated to form cloth curtains with different styles, and the cloth curtains are matched with indoor design curtains with different styles.
Therefore, after UV irradiation, a latency period of 6-8 hours is required before cell changes and symptoms including dry and painful skin, wrinkled epidermis, and even blistering and desquamation occur. The curtain has the functions of preventing direct irradiation of sunlight and ultraviolet rays and protecting a human body from excessive ultraviolet radiation, but part of fabrics of the curtain cloth do not have the function of ultraviolet prevention and cannot effectively protect the safety of indoor personnel.
Disclosure of Invention
In order to solve the technical problems, the invention provides a manufacturing process of the anti-ultraviolet stain-resistant fabric for the curtain, and the prepared stain-resistant fabric is subjected to anti-ultraviolet treatment by a coating method, so that the fabric of the fabric for the curtain not only has a good stain-resistant effect, but also can effectively prevent ultraviolet rays from penetrating through the fabric and directly irradiating human bodies.
In order to achieve the purpose, the invention adopts the technical scheme that:
the manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain is characterized in that the raw materials for preparing the ultraviolet-proof stain-resistant fabric comprise the following components in parts by weight: 100 parts of fiber-grade polyester chips, 5-15 parts of bamboo fibers, 1.0-1.5 parts of salicylate compounds, 0.5-0.7 part of dibutyltin oxide, 8-9 parts of chlorobenzene, 4-6 parts of organic resin, 6-9 parts of inorganic nano zinc oxide, 2-4 parts of inorganic nano titanium oxide, 2-5 parts of a softener, 5-8 parts of a coupling agent and 50-60 parts of a coating agent;
the preparation method of the ultraviolet-proof stain-resistant fabric comprises the following steps:
s1: adding the fiber-grade polyester chips, the bamboo fibers, the organic resin, the inorganic nano zinc oxide, the inorganic nano titanium oxide, the softener and the coupling agent into a grinder to be ground, putting the ground mixed particles into a high-speed stirrer to be stirred for 18-24min at the stirring speed of 300-330rpm, uniformly stirring, and carrying out melt spinning by a spinning machine to obtain spinning fibers;
s2: spinning the spinning fibers obtained in the step S1 into grey cloth, and placing the grey cloth into an antibacterial finishing agent for sterilization and disinfection, wherein the bath ratio is 1.5:15, soaking at high temperature for 1-2h, and drying, washing and drying to obtain the stain-resistant fabric;
s3: fully reacting the salicylic acid ester compound and dibutyltin oxide according to the weight part ratio of 2.10;
s4: and (2) crushing the salicylic acid bisphenol A ester obtained in the step (S2), adding the crushed salicylic acid bisphenol A ester into the coating agent in parts by weight, coating the surface of the stain-resistant fabric obtained in the step (S2) with an ultraviolet-proof coating by using a coater, drying the coated stain-resistant fabric by using a dryer, and performing heat treatment on the surface of the coating by using a drying oven to form an ultraviolet-proof film on the surface layer of the stain-resistant fabric, thereby preparing the ultraviolet-proof stain-resistant fabric.
As a preferred technical scheme of the invention: in step S4, the drying temperature of the dryer is 80-85 degrees, the drying time is 30-35min, the heat treatment temperature of the oven is 130-135 degrees, and the heat treatment time is 20-25min.
As a preferred technical scheme of the invention: the applicator in step S4 is a suspended hanging knife.
As a preferred technical scheme of the invention: the organic resin is organic silicon.
As a preferred technical scheme of the invention: the coating agent is polyacrylate coating glue.
Compared with the prior art, the invention has the beneficial effects that:
the bamboo fiber fabric with good ultraviolet-proof effect is selected as the raw material of the fabric, after processing, the bamboo fiber fabric has a stain-resistant effect and effectively prevents dust from adhering, and the bamboo fiber fabric with good ultraviolet-proof effect is further subjected to ultraviolet-proof treatment by a coating method, so that more than 95% of ultraviolet rays can be absorbed and isolated, and the damage to a human body can be effectively prevented.
Detailed Description
The present invention will be described in further detail with reference to specific embodiments below:
the invention provides a manufacturing process of cloth for an ultraviolet-proof stain-resistant fabric curtain, which comprises the following raw materials in parts by weight: 100 parts of fiber-grade polyester chips, 5-15 parts of bamboo fibers, 1.0-1.5 parts of salicylate compounds, 0.5-0.7 part of dibutyltin oxide, 8-9 parts of chlorobenzene, 4-6 parts of organic resin, 6-9 parts of inorganic nano zinc oxide, 2-4 parts of inorganic nano titanium oxide, 2-5 parts of a softener, 5-8 parts of a coupling agent and 50-60 parts of a coating agent;
the preparation method of the ultraviolet-proof stain-resistant fabric comprises the following steps:
s1: adding the fiber-grade polyester chips, the bamboo fibers, the organic resin, the inorganic nano zinc oxide, the inorganic nano titanium oxide, the softener and the coupling agent in parts by weight into a crusher for crushing, putting the crushed mixed particles into a high-speed stirrer for stirring at the stirring speed of 300-330rpm for 18-24min, and after uniformly stirring, carrying out melt spinning by a spinning machine to obtain spinning fibers;
s2: spinning the spinning fibers obtained in the step S1 into grey cloth, and putting the grey cloth into an antibacterial finishing agent for sterilization and disinfection, wherein the bath ratio is 1.5:15, soaking at high temperature for 1-2h, and drying, washing and drying to obtain the stain-resistant fabric;
s3: fully reacting the salicylic acid ester compound and dibutyltin oxide according to the weight part ratio of 2.10;
s4: and (2) crushing the salicylic acid bisphenol A ester obtained in the step (S2), adding the crushed salicylic acid bisphenol A ester into the coating agent in parts by weight, coating the surface of the stain-resistant fabric obtained in the step (S2) with an ultraviolet-proof coating by using a coater, drying the stain-resistant fabric coated by the coating by using a dryer, and performing heat treatment on the surface of the coating by using a drying oven to form an ultraviolet-proof film on the surface layer of the stain-resistant fabric, so that the ultraviolet-proof stain-resistant fabric is prepared, and has the effects of resisting bacteria and preventing mildew.
In step S4, the drying temperature of the dryer is 80-85 degrees, the drying time is 30-35min, the heat treatment temperature of the oven is 130-135 degrees, and the heat treatment time is 20-25min.
The organic resin is organic silicon. The coating agent is polyacrylate coating glue.
The invention processes and processes dimensional polyester chips, bamboo fibers, organic resin, inorganic nano zinc oxide, inorganic nano titanium oxide, a softener and a coupling agent, and then processes the processed products through a finishing liquid, thereby finally obtaining the fabric with the stain resistant effect.
Salicylic acid bisphenol A ester with radiation protection effect is obtained by reacting salicylic acid ester compounds with dibutyltin oxide with catalytic action, and is used as an ultraviolet-proof additive.
And finally, coating the anti-ultraviolet additive salicylic acid bisphenol A ester on the stain-resistant fabric by a coating method to form an anti-ultraviolet film on the stain-resistant fabric, and finally preparing the anti-ultraviolet stain-resistant fabric which is used for curtain cloth and can effectively prevent ultraviolet rays from damaging human bodies.
Among the influences of fiber raw materials and structures on the ultraviolet resistance:
the ultraviolet light transmittance test is carried out by selecting cotton, wool, silk, terylene, viscose and other woven fabrics which are not dyed and have close technological parameters, different fiber fabrics have great influence on the ultraviolet light transmittance, the ultraviolet light transmittance of wool fabrics is the lowest (8.6%), and the ultraviolet light transmittance of viscose fabrics is the highest (27.3%). It is noted that the thickness of the wool fabric in the test is almost 2 times that of the other fabrics, since wool fabrics of the same thickness as the other swatches are not found, and therefore, in the comparative analysis, the average value of the uv transmittance is corrected by the thickness and the coverage, and the corrected average value of the uv transmittance is lower for silk fabrics and polyester fabrics (16.8% and 15.3%), while the uv transmittance for cotton fabrics and viscose fabrics is higher (26.9% and 26.0%).
The hemp fiber has a unique pectin inclined hole structure; a ditch-shaped cavity and a plurality of pores on the tube wall are arranged between the ramie and the apocynum venetum fibers; the hemp fiber has a slender hollow cavity in the center and is connected with a plurality of cracks and small holes which are longitudinally distributed on the surface of the fiber. Due to the structural reasons, the fibrilia not only has good water absorption, but also has good elimination effect on sound waves and light waves, thereby having stronger ultraviolet-proof function.
The ultraviolet radiation blocking agent or the ultraviolet-proof additive is used together with the hemp fiber. The ultraviolet radiation transmittance of the fabric woven by the ultraviolet-proof polyester fiber is about 1/15 of that of cotton fabric and 1/6 of that of common polyester fabric.
Therefore, the bamboo fiber fabric is low in price and good in ultraviolet-proof effect and is made of the raw material of the fabric, and the ultraviolet-proof effect of the fabric can be further improved.
The invention adopts a coating method to coat the fabric with bamboo fiber as raw material, an anti-ultraviolet additive, namely salicylic acid bisphenol A ester, is added into a coating agent, and the coating agent adopts polyacrylate coating glue.
The salicylic acid bisphenol A ester is an ultraviolet absorbent, can absorb ultraviolet rays with the wavelength of less than 350nm, improves the weather resistance of the product, and can effectively absorb harmful short-wave ultraviolet rays.
The coating agent is added with a proper amount of ultraviolet screening agent, namely salicylic acid bisphenol A grease, the surface of the fabric is coated by a coater (such as a suspension scraper, a rotary screen and the like), and then a layer of film, namely an ultraviolet-proof film, is formed on the surface of the fabric through drying and necessary heat treatment.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the present invention in any way, but any modifications or equivalent variations made according to the technical spirit of the present invention are within the scope of the present invention as claimed.
Claims (5)
1. The manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain is characterized in that the raw materials for preparing the ultraviolet-proof stain-resistant fabric comprise the following components in parts by weight: 100 parts of fiber-grade polyester chips, 5-15 parts of bamboo fibers, 1.0-1.5 parts of salicylate compounds, 0.5-0.7 part of dibutyltin oxide, 8-9 parts of chlorobenzene, 4-6 parts of organic resin, 6-9 parts of inorganic nano zinc oxide, 2-4 parts of inorganic nano titanium oxide, 2-5 parts of a softener, 5-8 parts of a coupling agent and 50-60 parts of a coating agent;
the preparation method of the ultraviolet-proof stain-resistant fabric comprises the following steps:
s1: adding the fiber-grade polyester chips, the bamboo fibers, the organic resin, the inorganic nano zinc oxide, the inorganic nano titanium oxide, the softener and the coupling agent in parts by weight into a crusher for crushing, putting the crushed mixed particles into a high-speed stirrer for stirring at the stirring speed of 300-330rpm for 18-24min, and after uniformly stirring, carrying out melt spinning by a spinning machine to obtain spinning fibers;
s2: spinning the spinning fibers obtained in the step S1 into grey cloth, and putting the grey cloth into an antibacterial finishing agent for sterilization and disinfection, wherein the bath ratio is 1.5:15, soaking at high temperature for 1-2h, and drying, washing and drying to obtain the stain-resistant fabric;
s3: fully reacting the salicylic acid ester compound and dibutyltin oxide according to the weight part ratio of 2.10;
s4: and (2) crushing the salicylic acid bisphenol A ester obtained in the step (S2), adding the crushed salicylic acid bisphenol A ester into the coating agent in parts by weight, coating the surface of the stain-resistant fabric obtained in the step (S2) with an ultraviolet-proof coating by using a coater, drying the coated stain-resistant fabric by using a dryer, and performing heat treatment on the surface of the coating by using a drying oven to form an ultraviolet-proof film on the surface layer of the stain-resistant fabric, thereby preparing the ultraviolet-proof stain-resistant fabric.
2. The manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain as claimed in claim 1, characterized in that: in step S4, the drying temperature of the dryer is 80-85 degrees, the drying time is 30-35min, the heat treatment temperature of the oven is 130-135 degrees, and the heat treatment time is 20-25min.
3. The manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain as claimed in claim 1, is characterized in that: the applicator in step S4 is a suspended hanging knife.
4. The manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain as claimed in claim 1, characterized in that: the organic resin is organic silicon.
5. The manufacturing process of the cloth for the ultraviolet-proof stain-resistant fabric curtain as claimed in claim 1, is characterized in that: the coating agent is polyacrylate coating glue.
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| CN202210943340.2A CN115305599A (en) | 2022-08-08 | 2022-08-08 | Manufacturing process of cloth for ultraviolet-proof stain-resistant fabric curtain |
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| CN202210943340.2A CN115305599A (en) | 2022-08-08 | 2022-08-08 | Manufacturing process of cloth for ultraviolet-proof stain-resistant fabric curtain |
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|---|---|---|---|---|
| CN102952337A (en) * | 2012-11-15 | 2013-03-06 | 合肥会通新材料有限公司 | Modified bamboo fiber reinforced polypropylene composite material and preparation method thereof |
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| WO2021243940A1 (en) * | 2020-06-04 | 2021-12-09 | 席梦思床褥家具（苏州）有限公司 | Antibacterial and anti-mite organic cotton composite fiber fabric and processing technology therefor |
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| CN102952337A (en) * | 2012-11-15 | 2013-03-06 | 合肥会通新材料有限公司 | Modified bamboo fiber reinforced polypropylene composite material and preparation method thereof |
| CN109505024A (en) * | 2018-11-26 | 2019-03-22 | 福建凤竹纺织科技股份有限公司 | A kind of antibacterial ultraviolet-resistannanofiber line fabric and preparation method thereof |
| WO2021243940A1 (en) * | 2020-06-04 | 2021-12-09 | 席梦思床褥家具（苏州）有限公司 | Antibacterial and anti-mite organic cotton composite fiber fabric and processing technology therefor |
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Application publication date: 20221108 |