CN115226712B - Compound agricultural synergist containing olive oil and preparation method and application thereof - Google Patents
Compound agricultural synergist containing olive oil and preparation method and application thereof Download PDFInfo
- Publication number
- CN115226712B CN115226712B CN202210528051.6A CN202210528051A CN115226712B CN 115226712 B CN115226712 B CN 115226712B CN 202210528051 A CN202210528051 A CN 202210528051A CN 115226712 B CN115226712 B CN 115226712B
- Authority
- CN
- China
- Prior art keywords
- oil
- polyoxyethylene ether
- agricultural synergist
- based component
- olive oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004006 olive oil Substances 0.000 title claims abstract description 37
- 235000008390 olive oil Nutrition 0.000 title claims abstract description 37
- 150000001875 compounds Chemical class 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title abstract description 13
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 51
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 51
- 239000003921 oil Substances 0.000 claims abstract description 27
- 235000019198 oils Nutrition 0.000 claims abstract description 27
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims abstract description 18
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 16
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 10
- 239000003899 bactericide agent Substances 0.000 claims abstract description 10
- 239000004009 herbicide Substances 0.000 claims abstract description 10
- 239000002917 insecticide Substances 0.000 claims abstract description 8
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- 239000003240 coconut oil Substances 0.000 claims abstract description 7
- 235000019864 coconut oil Nutrition 0.000 claims abstract description 7
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 239000004359 castor oil Substances 0.000 claims abstract description 6
- 235000019438 castor oil Nutrition 0.000 claims abstract description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims abstract description 6
- 239000003760 tallow Substances 0.000 claims abstract description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 5
- 239000008158 vegetable oil Substances 0.000 claims abstract description 5
- YXHVCZZLWZYHSA-UHFFFAOYSA-N (Z)-6-[8-pentadecenyl]salicylic acid Natural products CCCCCCC=CCCCCCCCC1=CC=CC(O)=C1C(O)=O YXHVCZZLWZYHSA-UHFFFAOYSA-N 0.000 claims abstract description 4
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims abstract description 4
- YXHVCZZLWZYHSA-FPLPWBNLSA-N Ginkgoic acid Chemical compound CCCCCC\C=C/CCCCCCCC1=CC=CC(O)=C1C(O)=O YXHVCZZLWZYHSA-FPLPWBNLSA-N 0.000 claims abstract description 4
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims abstract description 4
- 235000010445 lecithin Nutrition 0.000 claims abstract description 4
- 239000000787 lecithin Substances 0.000 claims abstract description 4
- 229940067606 lecithin Drugs 0.000 claims abstract description 4
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims abstract description 4
- 229940073769 methyl oleate Drugs 0.000 claims abstract description 4
- TVFWYUWNQVRQRG-UHFFFAOYSA-N 2,3,4-tris(2-phenylethenyl)phenol Chemical compound C=1C=CC=CC=1C=CC1=C(C=CC=2C=CC=CC=2)C(O)=CC=C1C=CC1=CC=CC=C1 TVFWYUWNQVRQRG-UHFFFAOYSA-N 0.000 claims abstract description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims abstract description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims abstract description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims abstract description 3
- 235000019482 Palm oil Nutrition 0.000 claims abstract description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims abstract description 3
- 235000005687 corn oil Nutrition 0.000 claims abstract description 3
- 239000002285 corn oil Substances 0.000 claims abstract description 3
- YHAIUSTWZPMYGG-UHFFFAOYSA-L disodium;2,2-dioctyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCCCC(C([O-])=O)(C(C([O-])=O)S(O)(=O)=O)CCCCCCCC YHAIUSTWZPMYGG-UHFFFAOYSA-L 0.000 claims abstract description 3
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 3
- 150000004702 methyl esters Chemical class 0.000 claims abstract description 3
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 3
- 239000002480 mineral oil Substances 0.000 claims abstract description 3
- 229940049964 oleate Drugs 0.000 claims abstract description 3
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims abstract description 3
- 239000002540 palm oil Substances 0.000 claims abstract description 3
- 239000000600 sorbitol Substances 0.000 claims abstract description 3
- 239000003549 soybean oil Substances 0.000 claims abstract description 3
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000575 pesticide Substances 0.000 claims description 29
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 8
- 230000000895 acaricidal effect Effects 0.000 claims description 7
- 239000000642 acaricide Substances 0.000 claims description 7
- 230000002363 herbicidal effect Effects 0.000 claims description 7
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 4
- 229920000053 polysorbate 80 Polymers 0.000 claims description 4
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 claims description 3
- FBKRJCSYOMDOKB-UHFFFAOYSA-N 2,3,4-triphenylphenol Chemical compound C=1C=CC=CC=1C1=C(C=2C=CC=CC=2)C(O)=CC=C1C1=CC=CC=C1 FBKRJCSYOMDOKB-UHFFFAOYSA-N 0.000 claims description 2
- 239000003814 drug Substances 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 4
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 2
- 239000000194 fatty acid Substances 0.000 abstract description 2
- 229930195729 fatty acid Natural products 0.000 abstract description 2
- -1 sorbitan fatty acid ester Chemical class 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 description 19
- 238000012360 testing method Methods 0.000 description 17
- 241000196324 Embryophyta Species 0.000 description 14
- 239000000203 mixture Substances 0.000 description 12
- 238000009472 formulation Methods 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000011835 investigation Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 231100000674 Phytotoxicity Toxicity 0.000 description 6
- 235000009754 Vitis X bourquina Nutrition 0.000 description 6
- 235000012333 Vitis X labruscana Nutrition 0.000 description 6
- 240000006365 Vitis vinifera Species 0.000 description 6
- 235000014787 Vitis vinifera Nutrition 0.000 description 6
- 239000002671 adjuvant Substances 0.000 description 6
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000005730 Azoxystrobin Substances 0.000 description 5
- 239000005906 Imidacloprid Substances 0.000 description 5
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical group CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 description 5
- 230000001276 controlling effect Effects 0.000 description 5
- 229940056881 imidacloprid Drugs 0.000 description 5
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 5
- 239000000375 suspending agent Substances 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 239000005653 Bifenazate Substances 0.000 description 4
- 244000012254 Canarium album Species 0.000 description 4
- 235000009103 Canarium album Nutrition 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 4
- 244000299507 Gossypium hirsutum Species 0.000 description 4
- 241000488583 Panonychus ulmi Species 0.000 description 4
- 240000000111 Saccharum officinarum Species 0.000 description 4
- 235000007201 Saccharum officinarum Nutrition 0.000 description 4
- VHLKTXFWDRXILV-UHFFFAOYSA-N bifenazate Chemical compound C1=C(NNC(=O)OC(C)C)C(OC)=CC=C1C1=CC=CC=C1 VHLKTXFWDRXILV-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 230000000295 complement effect Effects 0.000 description 4
- 230000003902 lesion Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- GJUABKCEXOMRPQ-UHFFFAOYSA-N 1-[(2,5-dimethoxyphenyl)diazenyl]naphthalen-2-ol Chemical compound COC1=CC=C(OC)C(N=NC=2C3=CC=CC=C3C=CC=2O)=C1 GJUABKCEXOMRPQ-UHFFFAOYSA-N 0.000 description 3
- 241001600408 Aphis gossypii Species 0.000 description 3
- 241000207199 Citrus Species 0.000 description 3
- 241000238631 Hexapoda Species 0.000 description 3
- 241000233679 Peronosporaceae Species 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 235000020971 citrus fruits Nutrition 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 244000025254 Cannabis sativa Species 0.000 description 2
- 244000075634 Cyperus rotundus Species 0.000 description 2
- 239000005562 Glyphosate Substances 0.000 description 2
- 240000007817 Olea europaea Species 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 2
- 229940097068 glyphosate Drugs 0.000 description 2
- ZEKANFGSDXODPD-UHFFFAOYSA-N glyphosate-isopropylammonium Chemical group CC(C)N.OC(=O)CNCP(O)(O)=O ZEKANFGSDXODPD-UHFFFAOYSA-N 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000000361 pesticidal effect Effects 0.000 description 2
- 230000003405 preventing effect Effects 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012747 synergistic agent Substances 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 1
- 244000080767 Areca catechu Species 0.000 description 1
- 241000234653 Cyperus Species 0.000 description 1
- 235000016854 Cyperus rotundus Nutrition 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 230000001094 effect on targets Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/54—1,3-Diazines; Hydrogenated 1,3-diazines
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P13/00—Herbicides; Algicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P3/00—Fungicides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/02—Acaricides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01P—BIOCIDAL, PEST REPELLANT, PEST ATTRACTANT OR PLANT GROWTH REGULATORY ACTIVITY OF CHEMICAL COMPOUNDS OR PREPARATIONS
- A01P7/00—Arthropodicides
- A01P7/04—Insecticides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Agronomy & Crop Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Insects & Arthropods (AREA)
- Toxicology (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The application discloses a compound agricultural synergist containing olive oil, and a preparation method and application thereof. The compound agricultural synergist consists of olive oil, an oil-based component and a surfactant; the oil-based component is at least one of soybean oil, corn oil, coconut oil, palm oil, rosin-based vegetable oil, methyl oleate, fatty acid methyl ester, coconut oil methyl ester, mineral oil, lecithin, ginkgolic acid; the surfactant is at least one selected from fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene ether, tristyrylphenol polyoxyethylene ether, tallow amine polyoxyethylene ether, sorbitan fatty acid ester, sorbitol polyoxyethylene ether oleate and sodium dioctyl sulfosuccinate. The compound agricultural synergist can be widely used for the synergism of various herbicides, insecticides and bactericides, is mainly used for the barrel mixing synergism of various medicaments, and is environment-friendly, safe and efficient.
Description
Technical Field
The application belongs to the field of pesticide synergistic additives and plant protection, and particularly relates to a compound agricultural synergist containing olive oil, and a preparation method and application thereof.
Background
The pesticide tank mixing auxiliary agent is added into pesticide liquid together with pesticide products when the pesticide is used, is an auxiliary agent product for the prior mixing, and achieves the aim of improving the pesticide effect by improving the adhesion, spreading or penetration of the pesticide liquid on a target. The agricultural synergist on the current market mainly comprises organic silicon, is popular due to excellent permeation, spreading and expanding performances, but has the following defects: firstly, the problem of phytotoxicity is serious; secondly, the mixing property is poor, flocculation reaction is easy to occur in the mixed liquid, and the drug effect is reduced; thirdly, the fruit surface and vegetables are polluted, the plant surface and the vegetable are not decomposed after being permeated into the plant body, the residue is high, and crops and the environment are polluted.
The olive oil belongs to woody vegetable oil, is directly cold pressed from fresh olive fruits, does not undergo heating and chemical treatment, retains natural nutritional ingredients, is considered as the most suitable fat for human nutrition in the fat discovered so far, and is used as an agricultural synergist raw material, so that the safety is high, the residue in organisms is low, and the environmental pollution is small.
Disclosure of Invention
Aiming at the defects existing in the prior art, the application aims to provide the compound agricultural synergistic additive containing olive oil and the preparation method thereof, which improve the effective utilization rate of pesticides, can improve the pesticide effect by more than 35%, reduce the dosage of pesticides and improve the economic benefit compared with the conventional pesticides.
In order to achieve the above purpose, the technical scheme adopted by the application is as follows:
in a first aspect, the application provides a compound agricultural synergist, which consists of olive oil, an oil-based component and a surfactant;
the oil-based component is at least one of soybean oil, corn oil, coconut oil, palm oil, rosin-based vegetable oil, methyl oleate, fatty acid methyl ester, coconut oil methyl ester, mineral oil, lecithin, ginkgolic acid;
the surfactant is at least one selected from fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene ether, tristyrylphenol polyoxyethylene ether, tallow amine polyoxyethylene ether, sorbitan fatty acid ester, sorbitol polyoxyethylene ether oleate and sodium dioctyl sulfosuccinate.
In the compound agricultural synergist, the mass sum of the olive oil and the oil-based component can be 15% -35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 5: (5-30).
Preferably, the mass sum of the olive oil and the oil-based component can be 25% -35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component may be 10: (15-40).
The compound agricultural synergist can be specifically any one of the following b 1) to b 3):
b1 The mass sum of the olive oil and the oil-based component is 25% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:15;
b2 The mass sum of the olive oil and the oil-based component is 25% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:40, a step of performing a;
b3 The mass sum of the olive oil and the oil-based component is 35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:25.
in the compound agricultural synergist, the fatty alcohol-polyoxyethylene ether can be linear fatty alcohol-polyoxyethylene ether or branched fatty alcohol-polyoxyethylene ether;
the surfactant is any one of the following a 1) to a 5):
a1 Mass ratio of 30): 20:25 branched fatty alcohol-polyoxyethylene ether, linear fatty alcohol-polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a2 Mass ratio of 15): 25:35, a triphenylphenol polyoxyethylene ether, an alkylphenol polyoxyethylene ether, and dioctyl sodium sulfosuccinate;
a3 Mass ratio of 30): 10:25 castor oil polyoxyethylene ether, linear fatty alcohol polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a4 20 mass ratio): 30:25 polyoxyethylene sorbitan monooleate, branched fatty alcohol polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a5 20 mass ratio): 20:25, linear fatty alcohol polyoxyethylene ether, tallow amine polyoxyethylene ether, and dioctyl sodium sulfosuccinate.
In a second aspect, the application provides a method for preparing the compound agricultural synergist according to any one of the above, comprising the following steps: the components of the compound agricultural synergist are mixed according to a proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the compound agricultural synergist.
In a third aspect, the application provides the use of any of the above-described formulated agricultural potentiators as a tank mix potentiator in the preparation of a pesticide.
In the above application, the pesticide may be at least one of herbicide, insecticide, bactericide and acaricide.
As an example, the herbicide is glyphosate isopropylamine salt aqueous solution.
As an example, the pesticide is an imidacloprid suspension.
As an example, the bactericide is azoxystrobin suspension agent.
As an example, the acaricide is a bifenazate suspending agent.
In a third aspect, the application provides a pesticide comprising the formulated agricultural synergist of any one of the above.
Among the above pesticides, the pesticide may be at least one of herbicide, insecticide, bactericide and acaricide.
The application has the advantages that:
1. the universality is good. Can be widely used for the synergism of various herbicides, insecticides and bactericides, and is mainly used for the tank mix synergism of various medicaments.
2. Green, environment-friendly, safe and efficient. The components of the synergistic agent are all green and environment-friendly materials, and the synergistic agent is safe to people and environment in the processing and using processes and has remarkable synergistic effect.
Detailed Description
The following detailed description of the application is provided in connection with the accompanying drawings that are presented to illustrate the application and not to limit the scope thereof. The examples provided below are intended as guidelines for further modifications by one of ordinary skill in the art and are not to be construed as limiting the application in any way.
The experimental methods used in the following examples are all conventional methods unless otherwise specified; the materials, reagents and the like used, unless otherwise specified, are all commercially available.
Example 1
The embodiment is used for explaining the preparation of the agricultural synergist.
Weighing, in terms of mass percent, 10% of olive oil (Canarium album agricultural development Co., ltd.), 15% of coconut oil (Cocois import and export trade Co., ltd. In the sea, south China sea), 30% of AC3003 (branched fatty alcohol polyoxyethylene ether, lianghong New Material science and technology Co., ltd.), 20% of AEO-7 (straight-chain fatty alcohol polyoxyethylene ether, jiangsu sea-Ann petrochemical Co., ltd.), and 70% of fast T (dioctyl sodium sulfosuccinate, ehrlich chemical Co., ltd. In the Weifang, utility Co., ltd.) to make up 100%. The raw materials are mixed according to a certain proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the agricultural synergist.
Example 2
The embodiment is used for explaining the preparation of the agricultural synergist.
Weighing, in mass percent, 5% of olive oil (Cannon olive branch agricultural development Co., ltd.), 20% of ND-60 (Colophony vegetable oil, fujian Norde Biotechnology Co., ltd.), 15% of No. 601 (triphenylphosphine polyoxyethylene ether, jiangsu province sea-ampere petrochemical plant), 25% of OP-10 (alkylphenol polyoxyethylene ether, jiangsu province sea-ampere petrochemical plant), and 70% of fast T (dioctyl sodium sulfosuccinate, ehrlich chemical Co., ltd. In the city of Weifang) to complement 100%. The raw materials are mixed according to a certain proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the agricultural synergist.
Example 3
The embodiment is used for explaining the preparation of the agricultural synergist.
The preparation method comprises the steps of weighing, by mass, 10% of olive oil (Canarium album agriculture development Co., ltd.), 25% of lecithin (Anqing, ming's biological engineering Co., ltd.), 30% of EL-36 (Castor oil polyoxyethylene ether, jiangsu sea-ampere petrochemical plant, ltd.), 10% of AEO-3 (straight-chain fatty alcohol polyoxyethylene ether, jiangsu sea-ampere petrochemical plant, jiangsu sea-ampere oil polyoxyethylene ether, lev's sea-ampere petrochemical plant, ltd.), and 70% of fast T (dioctyl sodium sulfosuccinate, emilite chemical Co., ltd., areca., mitsu, co., ltd.) to complement 100%. The raw materials are mixed according to a certain proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the agricultural synergist.
Example 4
The embodiment is used for explaining the preparation of the agricultural synergist.
Weighing, in terms of mass percent, 10% of olive oil (Canarium album agriculture development Co., ltd.), 15% of methyl oleate (Soviet's Fengshi Biotechnology Co., ltd.), 20% of Tween-80 (polyoxyethylene sorbitan monooleate, jiangsu sea An petrochemical Co., ltd.), 30% of AC3003 (branched fatty alcohol polyoxyethylene ether, lian Ling New Material science and technology Co., ltd.), and 70% of fast T (dioctyl sodium sulfosuccinate, emilite chemical Co., ltd. In the city of Weifang) to complement 100%. The raw materials are mixed according to a certain proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the agricultural synergist.
Example 5
The embodiment is used for explaining the preparation of the agricultural synergist.
The preparation method comprises the steps of weighing, in percentage by mass, 10% of olive oil (Canarium album agriculture development Co., ltd.), 25% of ginkgolic acid (Chengdu Li Pu biotechnology Co., ltd.), 20% of AEO-3 (straight-chain fatty alcohol polyoxyethylene ether, jiangsu sea-ampere petrochemical plant, boliphatic amine polyoxyethylene ether), 20% of 1815# (Boseki fatty alcohol polyoxyethylene ether, jiangsu sea-ampere petrochemical plant, ltd.) and 70% of fast T (dioctyl sodium sulfosuccinate, emilite chemical Co., ltd., of Fangsu, city) to complement 100%. The raw materials are mixed according to a certain proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the agricultural synergist.
Example 6
The agricultural synergists prepared in examples 1 to 5 are applied in crop herbicides:
test time: 2019, 7, 11 days
Test site: zhanjiang agricultural reclamation sugarcane garden
Control object: rhizoma Cyperi (Cyperus rotundus L.)
Control agent: 480g/l glyphosate isopropylamine salt solution (Zhejiang Xinan chemical company Co., ltd.)
The investigation method comprises the following steps: 5 points are randomly taken from each cell, and each point is 1/4m 2 Weed plants were investigated 5 days, 10 days, and 20 days after application, respectively, and the control effect was calculated.
The formula of the control effect calculation is as follows:
wherein: PT-number of residual grass (or fresh weight) in the agent treatment zone;
ck—number of live grass (or fresh weight) in the control blank.
TABLE 1 synergistic effects of agricultural synergistic adjuvants on glyphosate control of sugarcane Cyperus rotundus in sugarcane fields
From Table 1, the synergistic adjuvant has obvious synergistic effect on the herbicide glyphosate to prevent and remove weed nutgrass flatsedge in sugarcane fields.
Example 7
The agricultural synergists prepared in examples 1 to 5 were used in agricultural pesticides:
test time: 2019 8, 15
Test site: experimental farm for cotton research institute of Henan Anyang China academy of agricultural sciences
Control object: cotton aphid
Control agent: 350g/l imidacloprid suspension (Nanjing Huazhou pharmaceutical Co., ltd.)
The investigation method comprises the following steps: before the pesticide is applied, 25 cotton fixed plants are randomly extracted in the middle 2 rows of each cell to hold cards, the wingless aphid number on the whole cotton seedling is investigated, the residual insect number on the cotton plants held by the cards in each cell is investigated 1 day after the pesticide is applied, the prevention effect is calculated, and meanwhile the pesticide damage condition is observed.
TABLE 2 synergistic action of agricultural synergistic adjuvant on imidacloprid for controlling cotton aphids
| Name of the name | Usage amount (ml/mu) | Radix of predrug outlet | Number of live insects 1 day after administration | Preventing and controlling effects, percent |
| Example 1+ formulation | 30+8 | 230 | 20 | 91.5 |
| Example 2+ formulation | 30+8 | 240 | 26 | 90.8 |
| Example 3+ formulation | 30+8 | 220 | 18 | 92.4 |
| Example 4+ formulation | 30+8 | 270 | 22 | 92.7 |
| Example 5+ formulation | 30+8 | 260 | 25 | 91.6 |
| 350g/l imidacloprid suspension | 8 | 280 | 42 | 85.4 |
As shown in Table 2, the synergistic additive has obvious synergistic effect on controlling cotton aphids by using imidacloprid as an insecticide.
Safety investigation and observation during test period, all the test reagents are safe to cotton growth and have no phytotoxicity.
Example 8
The agricultural synergist prepared in examples 1-5 is applied to a crop bactericide:
test time: 2019, 9 and 10 days
Test site: grape base of Jinbaowan planting and raising professional cooperation in Chenghai region of Shanzhi
Control object: downy mildew of grape
Control agent: 25% azoxystrobin suspension agent (Jiangsu Chang Long Nong chemical Co., ltd.)
The investigation method comprises the following steps: and (3) randomly investigating 10 current-year new vines in each district 7 days after the pesticide application, investigating all leaves from top to bottom, recording the leaf numbers of each stage of diseases and the total leaf numbers according to the following grading method, and simultaneously calculating the control effect.
Severity of illness classification criteria: level 0: no disease spots;
stage 1: the area of the lesion accounts for 5% or less of the whole leaf area;
3 stages: the area of the lesion accounts for 6% -25% of the whole leaf area;
5 stages: the area of the lesion accounts for 26% -50% of the whole leaf area;
7 stages: the area of the lesion accounts for 51% -75% of the whole leaf area;
stage 9: the area of the disease spots accounts for more than 76% of the whole leaf area;
safety investigation and impact on other organisms: the effect of each treatment of the agent on grape growth and on other diseases was observed on the first day and several days after each spray.
TABLE 3 synergistic Effect of agricultural synergistic adjuvants on azoxystrobin control of grape downy mildew
| Name of the name | Usage amount (ml/mu) | Leaf disease rate, percent | Index of disease state, percent | Preventing and controlling effects, percent |
| Example 1+ formulation | 30+50 | 2.54 | 2.31 | 86.42 |
| Example 2+ formulation | 30+50 | 3.01 | 2.94 | 82.78 |
| Example 3+ formulation | 30+50 | 2.75 | 2.67 | 84.14 |
| Example 4+ formulation | 30+50 | 2.67 | 2.43 | 85.84 |
| Example 5+ formulation | 30+50 | 2.92 | 2.83 | 83.24 |
| 25% azoxystrobin suspending agent | 50 | 8.71 | 5.22 | 67.12 |
From Table 3, the synergistic adjuvant has obvious synergistic effect on the prevention and treatment of grape downy mildew by the bactericide azoxystrobin.
Safety investigation and observation during the test period show that each treatment agent does not cause phytotoxicity to grape stems and leaves.
Example 9
The agricultural synergist prepared in examples 1 to 5 is applied to the acaricide of crops:
test time: 2019 8 month 22 day
Test site: hunan Shimen citrus garden
Control object: orange red spider
Control agent: 43% Bifenazate suspending agent (Jiangsu Fengshan group Co., ltd.)
The investigation method comprises the following steps: the citrus leaves in each test cell are marked by 5 fixed points according to 5 azimuth marks in east, south, west and north, 2 plants are investigated in each cell, and all the living insects in each plant are investigated. The control effect of each medicament on citrus red spiders is investigated and calculated 7 days, 14 days and 21 days after the medicament, and meanwhile, the phytotoxicity condition is observed.
The formula of the control effect calculation is as follows:
table 4 synergistic effect of agricultural co-agents on bifenazate to control citrus red spider
From Table 4, the synergistic adjuvant has obvious synergistic effect on controlling citrus red spider by using bifenazate.
Safety investigation and observation during test period, all the test reagents are safe to citrus growth and fruits, and no phytotoxicity phenomenon occurs.
The test result shows that the compound synergist containing olive oil has obviously better control effect on targets than single pesticide when being mixed with pesticide barrels such as herbicide, insecticide, bactericide, acaricide and the like.
Safety investigation and observation during test period, all the test reagents are safe to the growth of crops or cash crops, and no phytotoxicity phenomenon occurs.
Experimental results show that when the compound synergist containing olive oil is mixed with a pesticide barrel for use, compared with a single agent, the compound synergist containing olive oil has the advantages of obviously improving the control effect on a target, having obvious synergistic effect, being less in environmental pollution and safe for crop growth, and being an ideal synergist for green prevention and control.
The present application is described in detail above. It will be apparent to those skilled in the art that the present application can be practiced in a wide range of equivalent parameters, concentrations, and conditions without departing from the spirit and scope of the application and without undue experimentation. While the application has been described with respect to specific embodiments, it will be appreciated that the application may be further modified. In general, this application is intended to cover any variations, uses, or adaptations of the application following, in general, the principles of the application and including such departures from the present disclosure as come within known or customary practice within the art to which the application pertains. The application of some of the basic features may be done within the scope of the claims.
Claims (9)
1. A compound agricultural synergist comprises olive oil, oil-based components and a surfactant;
the oil-based component is at least one of soybean oil, corn oil, coconut oil, palm oil, rosin-based vegetable oil, methyl oleate, fatty acid methyl ester, coconut oil methyl ester, mineral oil, lecithin, ginkgolic acid;
the surfactant is at least three selected from branched chain fatty alcohol polyoxyethylene ether, linear chain fatty alcohol polyoxyethylene ether, castor oil polyoxyethylene ether, alkylphenol polyoxyethylene ether, tristyrylphenol polyoxyethylene ether, tallow amine polyoxyethylene ether, sorbitol polyoxyethylene ether oleate and sodium dioctyl sulfosuccinate;
the mass sum of the olive oil and the oil-based component is 15% -35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 5: (5-30).
2. The compounded agricultural synergist according to claim 1, characterized in that: the mass sum of the olive oil and the oil-based component is 25% -35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10: (15-40).
3. The compounded agricultural synergist according to any one of claims 1-2, characterized in that: the compound agricultural synergist is any one of the following b 1) to b 3):
b1 The mass sum of the olive oil and the oil-based component is 25% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:15;
b2 The mass sum of the olive oil and the oil-based component is 25% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:40, a step of performing a;
b3 The mass sum of the olive oil and the oil-based component is 35% of the total mass of the compound agricultural synergist;
the mass ratio of the olive oil to the oil-based component is 10:25.
4. the compounded agricultural synergist according to any one of claims 1-2, characterized in that: the surfactant is any one of the following a 1) to a 5):
a1 Mass ratio of 30): 20:25 branched fatty alcohol-polyoxyethylene ether, linear fatty alcohol-polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a2 Mass ratio of 15): 25:35, a triphenylphenol polyoxyethylene ether, an alkylphenol polyoxyethylene ether, and dioctyl sodium sulfosuccinate;
a3 Mass ratio of 30): 10:25 castor oil polyoxyethylene ether, linear fatty alcohol polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a4 20 mass ratio): 30:25 polyoxyethylene sorbitan monooleate, branched fatty alcohol polyoxyethylene ether and dioctyl sodium sulfosuccinate;
a5 20 mass ratio): 20:25, linear fatty alcohol polyoxyethylene ether, tallow amine polyoxyethylene ether, and dioctyl sodium sulfosuccinate.
5. The method for preparing the compound agricultural synergist of any one of claims 1-2, comprising the following steps: the components of the compound agricultural synergist are mixed according to a proportion, heated to 45 ℃, stirred for 10 minutes until transparent and uniform, and filtered to obtain the compound agricultural synergist.
6. Use of the compounded agricultural synergist of any one of claims 1-4 as a tank mix synergist for pesticides to prepare pesticides.
7. The use according to claim 6, characterized in that: the pesticide is at least one of herbicide, insecticide, bactericide and acaricide.
8. A pesticide comprising the formulated agricultural synergist of any one of claims 1-4.
9. A pesticide as set forth in claim 8, characterized in that: the pesticide is at least one of herbicide, insecticide, bactericide and acaricide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210528051.6A CN115226712B (en) | 2022-05-16 | 2022-05-16 | Compound agricultural synergist containing olive oil and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210528051.6A CN115226712B (en) | 2022-05-16 | 2022-05-16 | Compound agricultural synergist containing olive oil and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115226712A CN115226712A (en) | 2022-10-25 |
| CN115226712B true CN115226712B (en) | 2023-10-27 |
Family
ID=83668273
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210528051.6A Active CN115226712B (en) | 2022-05-16 | 2022-05-16 | Compound agricultural synergist containing olive oil and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115226712B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355288A (en) * | 2013-07-19 | 2013-10-23 | 江苏省农业科学院 | Anti-photooxidation plant oil spray adjuvant used for insecticidal pesticide preparation and its use method |
| CN108041099A (en) * | 2017-12-04 | 2018-05-18 | 薛银福 | A kind of pesticide synergistic agent |
| CN108294007A (en) * | 2017-12-27 | 2018-07-20 | 青岛奥迪斯生物科技有限公司 | A kind of bactericidal composition containing fluorine azoles bacterium aniline, Fluoxastrobin |
| CN108812706A (en) * | 2018-08-10 | 2018-11-16 | 武汉埃格瑞生物工程技术有限公司 | A kind of agricultural builder of olive oil and its preparation method and application for killing pest |
| CN112293412A (en) * | 2020-11-02 | 2021-02-02 | 吉林省农业科学院 | Pesticide synergist and preparation method and application thereof |
| CN113519516A (en) * | 2021-08-26 | 2021-10-22 | 安徽省圣丹生物化工有限公司 | Propanil emulsifiable concentrate herbicide and preparation method thereof |
| WO2023104096A1 (en) * | 2021-12-07 | 2023-06-15 | 中科睿极(深圳)医学科技有限公司 | Porous microcarrier and preparation method therefor |
-
2022
- 2022-05-16 CN CN202210528051.6A patent/CN115226712B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355288A (en) * | 2013-07-19 | 2013-10-23 | 江苏省农业科学院 | Anti-photooxidation plant oil spray adjuvant used for insecticidal pesticide preparation and its use method |
| CN108041099A (en) * | 2017-12-04 | 2018-05-18 | 薛银福 | A kind of pesticide synergistic agent |
| CN108294007A (en) * | 2017-12-27 | 2018-07-20 | 青岛奥迪斯生物科技有限公司 | A kind of bactericidal composition containing fluorine azoles bacterium aniline, Fluoxastrobin |
| CN108812706A (en) * | 2018-08-10 | 2018-11-16 | 武汉埃格瑞生物工程技术有限公司 | A kind of agricultural builder of olive oil and its preparation method and application for killing pest |
| CN112293412A (en) * | 2020-11-02 | 2021-02-02 | 吉林省农业科学院 | Pesticide synergist and preparation method and application thereof |
| CN113519516A (en) * | 2021-08-26 | 2021-10-22 | 安徽省圣丹生物化工有限公司 | Propanil emulsifiable concentrate herbicide and preparation method thereof |
| WO2023104096A1 (en) * | 2021-12-07 | 2023-06-15 | 中科睿极(深圳)医学科技有限公司 | Porous microcarrier and preparation method therefor |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115226712A (en) | 2022-10-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN110037014B (en) | Compound synergist containing lecithin and D-limonene and preparation method and application thereof | |
| CN106259458A (en) | A kind of pesticide yield-increasing compositions containing jasmonic and (-)-methyl cis-2-pent-2'-enyl-3-oxocyclopentylacetate | |
| CN102017879B (en) | Effective method suitable for preventing and killing weed for clover seedling | |
| CN112314622A (en) | Application of composition containing fosthiazate and amino-oligosaccharin in prevention and treatment of root-knot nematodes | |
| CN115226712B (en) | Compound agricultural synergist containing olive oil and preparation method and application thereof | |
| JP3203479B2 (en) | Soil conditioner | |
| CN108812707B (en) | Thrips killing plant essential oil composition, preparation and application thereof | |
| CN117958268A (en) | Mite-killing composition and application thereof | |
| CN112514903B (en) | Pesticide composition containing fenpyroximate and application thereof | |
| CN111449077B (en) | Metiram compound bactericide and application thereof | |
| CN103651597B (en) | Containing the agricultural chemicals and its production and use of acalypha copperleaf and Derris ellipta extract | |
| CN103918659A (en) | Pesticide composite including tolfenpyrad and fluazinam and preparation method and application of pesticide composite | |
| CN108402061B (en) | Biopesticide composition for preventing and treating tea geometrid | |
| CN103734168B (en) | Insecticidal pesticide formulation containing biopesticide-rotenone | |
| CN102696682B (en) | Wanlongmycin dimethomorph suspending agent, preparation method thereof and application | |
| CN115590038B (en) | Tobacco mosaic virus nucleic acid interferon dispersible oil suspending agent and application thereof | |
| CN109336679A (en) | A kind of Weed removal medicinal fertilizer composition of Glufosinate-ammoniumpesticideng and its preparation method and application | |
| CN104255734B (en) | The composition pesticide of a kind of containing chlorfenapyr and fluazinam | |
| CN114747571B (en) | Cebai triene diol emulsifiable powder and preparation method and application thereof | |
| CN107980777A (en) | A kind of bactericidal composition containing bromothalonil and eugenol | |
| CN107494559A (en) | Prevent and treat Pesticidal combination of citrus leaf-miner and application thereof | |
| CN109744252B (en) | Synergistic composition for preventing and treating citrus mites | |
| CN105379739A (en) | Compound composition of bifenazate and foliage fertilizer | |
| CN117598328A (en) | Eucalyptus oil-containing composite herbicide and preparation method thereof | |
| CN116138270A (en) | Bactericidal composition for preventing and controlling gray mold and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |