CN115124883A - High-resistance thermal transfer ribbon containing UV material and preparation method thereof - Google Patents
High-resistance thermal transfer ribbon containing UV material and preparation method thereof Download PDFInfo
- Publication number
- CN115124883A CN115124883A CN202210840851.1A CN202210840851A CN115124883A CN 115124883 A CN115124883 A CN 115124883A CN 202210840851 A CN202210840851 A CN 202210840851A CN 115124883 A CN115124883 A CN 115124883A
- Authority
- CN
- China
- Prior art keywords
- thermal transfer
- resin
- ink
- transfer ribbon
- resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/08—Printing inks based on natural resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/103—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds of aldehydes, e.g. phenol-formaldehyde resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
The invention relates to a high-resistance thermal transfer ribbon containing UV materials and a preparation method thereof, wherein an ink layer comprises the following raw materials in percentage by weight: 10-20% of resin binder, 10-25% of pigment, 0.1-1% of dispersing agent, 5-10% of UV resin, 0.3-0.5% of UV curing agent and 50-70% of solvent. The ink disclosed by the invention is coated on a base material to prepare a carbon ribbon, and the transferred print is cured by irradiation of a UV lamp, so that the adhesive force, solvent resistance and wear resistance of the thermal transfer carbon ribbon can be remarkably improved, and the problems of insufficient adhesion force of the handwriting and poor solvent resistance and wear resistance in the practical application process of the print are effectively solved.
Description
Technical Field
The invention belongs to the technical field of thermal transfer ribbons, and particularly relates to a high-resistance thermal transfer ribbon containing a UV material and a preparation method thereof.
Background
In the middle of the twentieth century, with the rapid development of industrial production and the rapid popularization and application of polymer materials, the thermal transfer ribbon rapidly occupies a place in the printing industry due to the advantages of wide substrate adaptability, wide application range, clear printing and the like. However, with the continuous expansion of the thermal transfer application field, the increasing variety of transfer materials and the wide variety of use environments, the requirements of customers on the print after transfer are further increased, for example, the print is required to have very high solvent resistance (ethanol resistance, gasoline resistance and the like) and friction resistance. However, the wear resistance and alcohol resistance of the existing various carbon belts are 20-200 times, and the gasoline resistance is only 1-20 times, so that the industrial requirements cannot be met.
Therefore, it is necessary to research a high-resistance thermal transfer ribbon containing a UV material to improve the high wear resistance and solvent resistance of the print, so as to meet the needs of the industry for products.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provide a high-resistance thermal transfer ribbon containing a UV material, which can obviously improve the solvent resistance (ethanol resistance, gasoline resistance and the like), friction resistance and other properties of the print of the ribbon, wherein the print resists ethanol and gasoline for more than 500 times and resists gasoline for more than 200 times.
The invention also provides a preparation method of the high-resistance thermal transfer ribbon containing the UV material,
in order to achieve the purpose, the invention adopts the following technical scheme:
the ink for the high-resistance thermal transfer ribbon comprises the following raw materials in percentage by weight: 10-20% of resin binder, 10-25% of pigment, 0.1-1% of dispersing agent, 5-10% of UV resin, 0.3-0.5% of UV curing agent and 50-70% of solvent.
Further, the resin binder is one or a mixture of more than two of polyester resin, polyacrylic resin, EVA resin, polyurethane resin, phenolic resin, rosin resin and the like.
More preferably, the pigment is carbon black or the like.
Specifically, the dispersant is one or a mixture of more than two of dispersants BYK111, BYK-AT204, BYK-104S and the like.
Specifically, the UV resin is one or a mixture of more than two of polyurethane acrylate, polyester acrylate, modified epoxy acrylate and the like.
Specifically, the UV curing agent is one or a mixture of two or more of curing agents 184, 819, TPO, and the like.
Further, the solvent is one or a mixture of two or more of toluene, butanone, absolute ethyl alcohol, ethyl acetate, isopropanol and the like, and toluene and butanone are preferred.
The invention provides a high-resistance thermal transfer printing carbon tape containing the UV material and the ink, wherein the carbon tape comprises a base film, a back coating and an ink layer which are sequentially coated on the surface of the base film. The ink layer thickness is required to be 1 to 2 μm.
The invention also provides a preparation method of the high-resistance thermal transfer ribbon containing the UV material, which comprises the following steps:
1) weighing the components in proportion, uniformly mixing the resin binder and the solvent, heating to 80-100 ℃ to fully dissolve, and cooling to room temperature to obtain a resin solution;
2) adding a pigment and a dispersing agent into the resin liquid obtained in the step 1), and uniformly grinding to obtain common thermal transfer ink;
3) adding UV resin and UV curing agent into the common thermal transfer printing ink obtained in the step 2), and uniformly stirring to obtain the high-resistance thermal transfer printing ink for the carbon ribbon;
4) and (3) coating the ink prepared in the step 3) on a base film (preferably a PET base film with the thickness of 4.5 microns) containing a back coating by using coating equipment to obtain the high-resistance thermal transfer ribbon containing the UV material.
In the method for preparing the high-resistance thermal transfer ribbon containing the UV material, a material dissolving kettle and a sand mill are required in the ink preparation process, and the material dissolving time is generally 1-3 h. The carbon ribbon is prepared by coating and drying by a coating machine. The back coating formulation may be prepared using techniques conventional in the art.
Compared with the prior art, the invention has the following beneficial effects:
1) according to the invention, the carbon ribbon made of the UV resin material is added, and the adhesion, solvent resistance and wear resistance of the thermal transfer carbon ribbon can be obviously improved after the transfer print is irradiated and cured by a UV lamp, so that the problems of insufficient adhesion of the writing, poor solvent resistance and wear resistance and the like in the practical application process of the print are effectively solved;
2) the invention provides a high-resistance thermal transfer ribbon containing a UV material, which can remarkably improve the solvent resistance (ethanol resistance, gasoline resistance and the like) and the friction resistance and the like of the print of the ribbon, wherein the print resists ethanol and gasoline for more than 500 times and gasoline for more than 200 times; the wear resistance and the solvent resistance are several times or even ten times of those of the existing like products;
3) the preparation method of the high-resistance thermal transfer ribbon of the UV material adopts a one-time coating mode, reduces the production cost and the influence on equipment and environment, has simple preparation method conditions, is simple and convenient to operate, and is easy to industrially popularize and use.
Detailed Description
The technical solution of the present invention is further described in detail with reference to the following examples, but the scope of the present invention is not limited thereto.
In the following examples, unless otherwise specified, all of them are general commercial products that can be directly purchased. The purchase information of the selected part of the raw materials is given as follows:
polyester resin, korean SK group ES420, a proxy of kagao, kaoya chemical technology ltd;
polyacrylic acid resin, Guangzhou City communications commercial and trade Co., Ltd, DSM Dismann NeoCryl B-814;
polyurethane resin, Luoyangjiming chemical Co., Ltd JM-1016
EVA resin: dupont EVA 150, usa;
the UV resin is a product of Saduoma company in America; urethane acrylate CN2258, polyester acrylate CN2200, modified epoxy acrylate CN 118;
dispersants (BYK 111, BYK-AT204, BYK-104S): products of bike chemical china ltd;
UV curing agent (184, 819, TPO): basf, germany;
in the following examples, the formulation of the back coating can be carried out by conventional techniques in the art, for example, the back coating can be prepared from a synthetic resin disclosed in patent CN201010276825.8 and a back coating solution prepared from the synthetic resin, and the thickness of the back coating is 0.2-0.3 μm. The ink layer thickness is 1-2 μm.
Example 1
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 4% of polyester resin, 3% of EVA resin, 3% of polyurethane resin, 10% of pigment carbon black, 0.1% of dispersant BYK-104S, 10% of polyurethane acrylate, 0.5% of TPO, 50.2% of butanone and 19.2% of toluene.
The preparation method of the high-resistance thermal transfer ribbon containing the UV material specifically comprises the following steps:
1) weighing the components in proportion, adding resin binders (polyester resin, EVA resin and polyurethane resin), butanone and toluene serving as solvents into a material dissolving kettle, uniformly mixing, heating to about 90 ℃ to fully dissolve, and cooling to room temperature to obtain resin liquid;
2) adding pigment carbon black and a dispersant BYK-104S into the resin liquid obtained in the step 1), and uniformly grinding by using a sand mill to obtain common thermal transfer printing ink;
3) adding a UV curing agent and UV resin into the ink obtained in the step 2), and uniformly stirring to obtain the ink containing the UV material for the high-resistance thermal transfer ribbon;
4) and (3) coating the ink prepared in the step (3) on a PET film containing a back coating and having a thickness of 4.5 microns by using a coating machine, and drying at 90-110 ℃ for 10-15 seconds to obtain the high-resistance thermal transfer ribbon containing the UV material.
Example 2
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 5% of polyester resin, 10% of polyurethane resin, 20% of pigment carbon black, BYK 1110.8% of dispersant, 5% of polyester acrylate, 5% of modified epoxy acrylate, 1840.3% of UV curing agent, 43.9% of butanone and 10% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 3
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 17% of polyester resin, 3% of EVA resin, 25% of pigment carbon black, a dispersant BYK-AT 2041%, 10% of UV resin urethane acrylate, 0.4% of UV curing agent TPO, 38% of butanone and 5.6% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 4
The high-resistance thermal transfer printing carbon ribbon containing the UV material comprises a PET film, and a back coating and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 18% of polyurethane resin, 15% of pigment carbon black, 5% of UV resin polyurethane acrylate, 5% of UV resin modified epoxy acrylate, 0.2% of UV curing agent TPO, 8190.1% of UV curing agent, 41.2% of butanone and 15% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 5
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 5% of polyacrylic resin, 8% of polyurethane resin, 11% of pigment carbon black, BYK 1110.5% of dispersant, 5% of UV resin polyurethane acrylate, 0.5% of UV curing agent TPO, 50% of butanone and 20% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 6
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 4% of polyester resin, 3% of EVA resin, 5% of phenolic resin, 17% of pigment carbon black, 2040.9% of dispersant BYK-AT, 8% of UV resin urethane acrylate, 1840.5% of UV curing agent, 42% of butanone and 19.6% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 7
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 4% of rosin resin, 2% of EVA resin, 8% of polyurethane resin, 15% of pigment carbon black, 0.8% of dispersant BYK-104S, 10% of UV resin polyester acrylate, 0.5% of UV curing agent TPO, 39.7% of butanone and 20% of toluene.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Example 8
The high-resistance thermal transfer ribbon containing the UV material comprises a PET film, and a back coating layer and an ink layer which are sequentially coated on the surface of the PET film. The ink layer is composed of the following raw materials in percentage by weight: 4% of polyester resin, 10% of polyurethane resin, 15% of pigment carbon black, BYK 1110.7% of dispersant, 10% of UV resin urethane acrylate, 8190.5% of UV curing agent and 59.8% of butanone.
The method for preparing the high-resistance thermal transfer ribbon containing the UV material is as described in example 1.
Comparative examples 1 to 8
Comparative examples 1 to 8 correspond to examples 1 to 8, respectively, with the difference that: the UV resin and the UV curing agent are not added, and the solvent is used for filling the mixture to 100 percent.
Performance test:
the carbon ribbons prepared in the above examples 1 to 8 were printed on a print by a bar printer, cured by UV light irradiation, and subjected to alcohol resistance, abrasion resistance, and other related performance tests. The carbon ribbons prepared in the comparative examples 1 to 8 are directly subjected to alcohol resistance, wear resistance and other related performance tests by a bar code printer and printed prints. The gasoline resistance and the alcohol resistance are tested by an alcohol abrasion resistance instrument A20-339, and the load is 500 g; the abrasion resistance is tested by a Liquidambar formosana JM-V paint film abrasion tester, and the load is 500 g. The test results are shown in table 1 below.
Table 1 results of imprint performance testing after curing of various examples by transfer printing:
the results in table 1 show: the carbon ribbon has the imprinting after transfer printing and curing, resists alcohol and rubbing for more than 500 times and resists gasoline for more than 200 times; the abrasion resistance and solvent resistance of the print are far superior to those of the comparative example and the existing product.
Claims (9)
1. The ink for the high-resistance thermal transfer ribbon is characterized by comprising the following raw materials in percentage by weight: 10-20% of resin binder, 10-25% of pigment, 0.1-1% of dispersing agent, 5-10% of UV resin, 0.3-0.5% of UV curing agent and 50-70% of solvent.
2. The ink for a highly resistant thermal transfer ribbon according to claim 1, wherein the resin binder is one or a mixture of two or more of a polyester resin, a polyacrylic resin, an EVA resin, a polyurethane resin, a phenolic resin, and a rosin resin.
3. The ink for a highly resistant thermal transfer ribbon according to claim 1, wherein the pigment is carbon black.
4. The ink for highly resistant thermal transfer ribbon as claimed in claim 1, wherein the dispersant is one or a mixture of two or more of dispersants BYK111, BYK-AT204 and BYK-104S.
5. The ink for a highly resistant thermal transfer ribbon according to claim 1, wherein the UV resin is one or a mixture of two or more of urethane acrylate, polyester acrylate, and modified epoxy acrylate.
6. The ink for highly durable thermal transfer ribbon according to claim 1, wherein the UV curing agent is one or a mixture of two or more of curing agents 184, 819 and TPO.
7. The ink for a highly resistant thermal transfer ribbon according to claim 1, wherein the solvent is one or a mixture of two or more of toluene, methyl ethyl ketone, absolute ethyl alcohol, ethyl acetate, and isopropyl alcohol.
8. A highly durable thermal transfer ribbon containing a UV-containing material with the ink according to any one of claims 1 to 7, comprising a base film, and a back coating layer and an ink layer sequentially coated on the surface of the base film.
9. The method for preparing the highly durable thermal transfer ribbon containing the UV material according to claim 8, comprising the steps of:
1) weighing the components in proportion, uniformly mixing the resin binder and the solvent, heating to 80-100 ℃ for dissolving, and cooling to room temperature to obtain a resin liquid;
2) adding a pigment and a dispersing agent into the resin liquid obtained in the step 1), and uniformly grinding to obtain common thermal transfer ink;
3) adding UV resin and UV curing agent into the common thermal transfer printing ink obtained in the step 2), and uniformly stirring to obtain the high-resistance thermal transfer printing ink for the carbon ribbon;
4) coating the ink prepared in the step 3) on a base film containing a back coating to obtain the high-resistance thermal transfer ribbon containing the UV material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210840851.1A CN115124883B (en) | 2022-07-18 | 2022-07-18 | High-resistance thermal transfer carbon belt containing UV material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210840851.1A CN115124883B (en) | 2022-07-18 | 2022-07-18 | High-resistance thermal transfer carbon belt containing UV material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN115124883A true CN115124883A (en) | 2022-09-30 |
| CN115124883B CN115124883B (en) | 2023-07-04 |
Family
ID=83383920
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210840851.1A Active CN115124883B (en) | 2022-07-18 | 2022-07-18 | High-resistance thermal transfer carbon belt containing UV material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115124883B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6225369B1 (en) * | 1999-05-19 | 2001-05-01 | Moltex Co., Ltd. | UV-curable, adhesive transfer ink |
| US20030020798A1 (en) * | 2000-08-02 | 2003-01-30 | Taylor Jeffrey F. | Radiation-curable thermal printing ink and ink ribbons and methods of making, using and printing using the same |
| CN104553385A (en) * | 2015-01-05 | 2015-04-29 | 鹏码实业(上海)有限公司 | Heat transfer printing colored tape capable of being used on band-shaped or card-shaped label and preparation method thereof |
| CN107400455A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | A kind of thermal transfer UV mould releases and preparation method thereof |
| CN109337532A (en) * | 2018-09-26 | 2019-02-15 | 上海乘鹰新材料有限公司 | A kind of release coating of super abrasive UV photocuring and preparation method thereof |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
-
2022
- 2022-07-18 CN CN202210840851.1A patent/CN115124883B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6225369B1 (en) * | 1999-05-19 | 2001-05-01 | Moltex Co., Ltd. | UV-curable, adhesive transfer ink |
| US20030020798A1 (en) * | 2000-08-02 | 2003-01-30 | Taylor Jeffrey F. | Radiation-curable thermal printing ink and ink ribbons and methods of making, using and printing using the same |
| CN104553385A (en) * | 2015-01-05 | 2015-04-29 | 鹏码实业(上海)有限公司 | Heat transfer printing colored tape capable of being used on band-shaped or card-shaped label and preparation method thereof |
| CN107400455A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | A kind of thermal transfer UV mould releases and preparation method thereof |
| CN109337532A (en) * | 2018-09-26 | 2019-02-15 | 上海乘鹰新材料有限公司 | A kind of release coating of super abrasive UV photocuring and preparation method thereof |
| CN111662592A (en) * | 2020-07-16 | 2020-09-15 | 焦作卓立膜材料有限责任公司 | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN115124883B (en) | 2023-07-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111662592B (en) | Antistatic flame-retardant thermal transfer printing ink for carbon ribbon and preparation method thereof | |
| TWI437051B (en) | Electrically conductive uv-curable ink | |
| JP5616044B2 (en) | Radiation curable ink composition and method for forming an image | |
| CN107286740B (en) | UV-LED offset printing ink and preparation method thereof | |
| JP3893262B2 (en) | Water-based photocurable resin composition, water-based ink, ink cartridge, recording unit, and ink jet recording apparatus | |
| CN100398613C (en) | Colored composition | |
| CN110746836B (en) | High-temperature steam resistant thermal transfer release agent and preparation method thereof | |
| US20080281036A1 (en) | Pigment Dispersion Composition, Use Thereof And Compound For Treating Pigment | |
| CN112976840B (en) | Heat transfer printing film for vehicle license plate and preparation method thereof | |
| CN113178128A (en) | High-temperature-resistant label for thermal transfer printing and preparation method thereof | |
| EP2404970A1 (en) | Infrared absorbing material, method for synthesizing same, coloring composition, ink, toner, printed material, image recording method and image information detecting method | |
| TW202020075A (en) | Optical fiber coating having color fixation capability, outer coating layer for optical fiber, optical fiber, and preparation methods thereof | |
| CN115011171A (en) | Special thermal transfer printing ink for high-temperature-resistant carbon ribbon production and preparation method thereof | |
| CN114736556B (en) | High-glossiness UV offset printing ink and preparation method thereof | |
| CN114055977B (en) | Process method for printing soft label on thermal sublimation color band | |
| CN109177540B (en) | Transfer printing print ultra-high temperature resistant carbon ribbon and preparation method thereof | |
| CN111845134A (en) | Water-based color-changeable thermal transfer ribbon and manufacturing method thereof | |
| CN115124883B (en) | High-resistance thermal transfer carbon belt containing UV material and preparation method thereof | |
| CN105172409A (en) | Preparation method for compounded thermal transfer ribbon | |
| CN110982338A (en) | Aqueous thermosetting printing ink | |
| CN116082883A (en) | Modified ink suitable for LED curing light source and preparation method thereof | |
| CN114312061B (en) | Wear-resistant heat transfer printing carbon belt applicable to multiple base materials and preparation method thereof | |
| CN117227347A (en) | Thermal transfer protective film for thermosensitive and preparation method thereof | |
| CN111518432A (en) | High-temperature-resistant UV (ultraviolet) curing printing ink | |
| CN116285498B (en) | High-temperature-resistant UV (ultraviolet) inkjet printing ink |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |