CN115093778A - Water-based sealant coating and preparation method thereof - Google Patents

Water-based sealant coating and preparation method thereof Download PDF

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Publication number
CN115093778A
CN115093778A CN202210657209.XA CN202210657209A CN115093778A CN 115093778 A CN115093778 A CN 115093778A CN 202210657209 A CN202210657209 A CN 202210657209A CN 115093778 A CN115093778 A CN 115093778A
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water
sealant coating
percent
cosolvent
drier
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CN115093778B (en
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戴润达
陈鹏
王鑫博
胡广瑞
陈刚
林东
吴锡忠
周自强
王博
张利勇
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China Railway Hi Tech Industry Corp Ltd
China Railway Shanhaiguan Bridge Group Co Ltd
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China Railway Hi Tech Industry Corp Ltd
China Railway Shanhaiguan Bridge Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20Diluents or solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09FNATURAL RESINS; FRENCH POLISH; DRYING-OILS; OIL DRYING AGENTS, i.e. SICCATIVES; TURPENTINE
    • C09F9/00Compounds to be used as driers, i.e. siccatives

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a water-based sealant coating and a preparation method thereof, wherein the coating comprises the following components: 40-60% of water-based alkyd resin, 0.1-0.5% of defoaming agent, 0.1-0.6% of base material wetting agent, 0.2-0.8% of thickening agent, 0.5-1.5% of water-based drier, 0.5-1.0% of pH regulator and 35.6-58.6% of cosolvent; the preparation method comprises the following steps: mixing part of cosolvent and water-based alkyd resin, stirring for 10-15 minutes at a speed of 500-600 r/min, uniformly stirring, sequentially adding a defoaming agent, a base material wetting agent, a thickening agent and a water-based drier, stirring for 10-15 minutes, adding a pH regulator, adding the rest cosolvent, adjusting the construction viscosity, filtering with 200-mesh filter cloth, and packaging. The method solves the problems that the appearance quality of a paint film is influenced by the residual cutting fluid of the high manganese steel frog casting when the production efficiency is improved and the complexity and the incompleteness of the process of wiping the cutting fluid of the high manganese steel frog casting by water are solved; the paint has the advantages of simple construction, high paint film gloss, excellent adhesive force, water resistance and artificial weather aging resistance.

Description

Water-based sealant coating and preparation method thereof
Technical Field
The invention belongs to the technical field of coating, and particularly relates to a water-based sealant coating and a preparation method thereof.
Background
The high manganese steel frog is alloy steel with high manganese and carbon contents, has high strength and good impact toughness, and can be quickly hardened under the action of impact load after heat treatment, so that the surface has good smoothness and wear resistance. The high manganese steel frog products need to be coated with a layer of protective varnish before leaving a factory to ensure that the high manganese steel frog products are not corroded and have good appearance, and the coating used for the high manganese steel frog products on the market at present is a solvent-based coating basically, contains a large amount of volatile organic compounds (VOC for short), has large influence on the environment and human health, and has large risks in operation and storage.
Based on the problems caused by the solvent-based coating for the high manganese steel frog product, the high manganese steel frog product starts to use the water-based coating, the water-based coating takes water as a diluent, the volatile organic compound content is less, the cleaning is easy, the influence on the environment and the human health is small, and the operation and the storage are safe. However, in the process of using the water-based paint for the high manganese steel frog product, the high manganese steel frog has a whitish mark locally, the white matter disappears in the process of brushing the water-based paint, but the white mark appears again after the water-based paint film is dried, and the special water-based varnish for the high manganese steel frog can not cover the mark, so that the high manganese steel frog product after painting is directly unattractive.
The substance for generating the whitening mark is cutting fluid (modified water glass), mainly contains silicon dioxide and sodium oxide, is easy to dissolve in water, and has poor water resistance. The high manganese steel frog casting needs to be separated from the casting system by an electric spark cutting technology, and cutting fluid (modified water glass) is used in the process. Since spark is splashed in the electric spark cutting process, cutting liquid is splashed to other parts, and therefore white marks appear at and around the cutting part. The water paint takes water as a diluent, when the water paint is brushed, cutting fluid is dissolved in the water paint, white marks disappear, and after the water is evaporated, the remained substances form a white mark to appear on the surface of the frog casting.
Aiming at the characteristic that the modified water glass is easy to dissolve in water, the modified water glass is erased after being sprayed with water on the surface of a casting with white marks, but the modified water glass after being dissolved in water is colorless and transparent, so that whether the modified water glass is completely removed or not is difficult to know, and the erasing difficulty is high at complex parts such as slits. Further analysis shows that the solution of the modified water glass after being dissolved in water is alkaline, and in the process of water evaporation and drying, the high manganese steel frog casting is in an alkaline environment, so that the high manganese steel frog casting is corroded to a certain degree. The occurrence of the phenomenon seriously hinders the popularization and application of the water-based varnish.
In order to better eliminate the influence of the modified water glass on the application of the water-based paint on the surface of the manganese fork casting, a sealing agent is developed, and the modified water glass is dissolved and coated in a sealing agent coating by utilizing a physical sealing principle, so that the modified water glass is well isolated from water in subsequent water-based varnish.
Disclosure of Invention
The invention aims to solve the problems of high VOC content, storage and safety of high manganese steel frog products caused by using solvent-based coatings, and the problem that residual cutting fluid on the surface of a high manganese steel frog casting cannot be covered by directly using water-based coatings.
The technical scheme of the invention is as follows: according to one aspect of the invention, the invention discloses a water-based sealant coating which is prepared from the following raw materials in percentage by weight:
the water-based alkyd resin comprises the following components in percentage by weight: 40 to 60 percent of the total weight of the steel,
the defoaming agent is as follows: 0.1 to 0.5 percent,
the base material wetting agent comprises the following components in percentage by weight: 0.1 to 0.6 percent,
the thickener comprises the following components in percentage by weight: 0.2 to 0.8 percent,
the water-based drier comprises the following components in percentage by weight: 0.5 to 1.5 percent,
the PH regulator is in proportion: 0.5 to 1.0 percent,
the cosolvent ratio is as follows: 35.6 to 58.6 percent.
Furthermore, the water-based alkyd resin is 3AK0235Y from the same chemical industry, and the solid content is 70-75%.
Still further, the defoamer is at least one of BYK 028, dygao TEGO 810W, or TEGO 902W aqueous defoamer.
Still further, the substrate wetting agent is at least one or more of TEGO Twin4100, BYK346, or TEGO 280.
Still further, the thickener is a polyurethane type thickener of at least one or more of OMG 0434 or OMG 0620.
Furthermore, the aqueous drier is an aqueous cobalt drier of Tongde chemical WD 016.
Further, the pH regulator is one or more of triethylamine, triethanolamine or N, N-dimethylethanolamine.
Further, the cosolvent is one or more of absolute ethyl alcohol, isopropanol or D40 solvent oil.
According to another aspect of the invention, the invention discloses a preparation method of the water-based sealant coating, which comprises the following steps: mixing 60-80% of the total weight of the cosolvent with the waterborne alkyd resin, stirring the mixed solution for 10-15 minutes by setting a rotating speed of 500-600 r/min through a stirrer, uniformly stirring, sequentially adding the defoamer, the base material wetting agent, the thickening agent and the waterborne drier, stirring for 10-15 minutes, adding the pH regulator, finally adding the rest cosolvent to adjust the construction viscosity, and filtering and packaging through 200-mesh filter cloth.
Compared with the prior art, the invention has the following beneficial effects:
(1) the aqueous sealant coating disclosed by the invention effectively seals the residual cutting fluid on the surface of the high manganese steel frog, so that the complexity and the incompleteness of the process of wiping the cutting fluid by water are solved, the production and construction efficiency is effectively improved, and the problem that the appearance quality of a paint film is influenced by the residual cutting fluid of a high manganese steel frog casting is solved;
(2) the water-based sealant coating has excellent drying, rust prevention and construction performances;
(3) the water-based sealant coating disclosed by the invention is matched with the water-based varnish special for the high manganese steel frog, so that the integral VOC (volatile organic compounds) in the construction process is reduced, and meanwhile, the water-based varnish has a great pushing effect on the application of the water-based varnish in the field of high manganese steel frog.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are a part of the embodiments of the present invention, but not all of the embodiments.
According to one aspect of the invention, the invention discloses a water-based sealant coating which is prepared from the following raw materials in percentage by weight:
the water-based alkyd resin comprises the following components in percentage by weight: 40 to 60 percent of the total weight of the steel,
the defoaming agent is as follows: 0.1 to 0.5 percent,
the base material wetting agent comprises the following components in percentage by weight: 0.1 to 0.6 percent,
the thickener comprises the following components in percentage by weight: 0.2 to 0.8 percent,
the water-based drier comprises the following components in percentage by weight: 0.5 to 1.5 percent,
the PH regulator is in proportion: 0.5 to 1.0 percent,
the cosolvent ratio is as follows: 35.6 to 58.6 percent.
Furthermore, the waterborne alkyd resin is 3AK0235Y in the chemical industry of Tongde, and the solid content is 70-75%.
Still further, the defoamer is at least one of BYK 028, dygao TEGO 810W, or TEGO 902W aqueous defoamer.
Further, the substrate wetting agent is at least one or more of TEGO Twin4100, BYK346, or TEGO 280.
Still further, the thickener is a polyurethane-type thickener that is at least one or more of OMG 0434 or OMG 0620.
Furthermore, WD016 of the same chemical industry is an aqueous cobalt drier.
Further, the pH regulator is one or more of triethylamine, triethanolamine or N, N-dimethylethanolamine.
Further, the cosolvent is one or more of absolute ethyl alcohol, isopropanol or D40 solvent oil.
It is noted that the above mentioned names of materials relate to the manufacturer and type of the material, which are readily available in the art and are known in the art. In the specific implementation of the technical scheme of the invention, the end point values of the range symbols-' are all in the value range.
The invention also discloses a preparation method of the water-based sealant coating, which comprises the following steps: mixing 60-80% of the total weight of the cosolvent with the waterborne alkyd resin, stirring the mixed solution for 10-15 minutes at a rotation speed of 500-600 r/min by a stirrer, uniformly stirring, sequentially adding the defoamer, the base material wetting agent, the thickening agent and the waterborne drier, stirring for 10-15 minutes, adding the pH regulator, finally adding the rest cosolvent to adjust the construction viscosity, filtering by a 200-mesh filter cloth, and packaging.
The first embodiment is as follows: the invention relates to a water-based sealant coating and a preparation method thereof, wherein the preparation method comprises the following steps:
the construction of the invention is as follows: after the structural surface is subjected to oil cleaning and soot blowing, the sealant can be coated on the structural surface in a mode of air spraying or brushing, the sealant is uniformly coated, and the thickness of the sealant is 15 microns. And the subsequent coating construction or transportation can be carried out only by keeping good ventilation and drying at the temperature of more than 10 ℃ for 3 hours. The water-based sealant coating formula comprises: 40% of water-based alkyd resin (solid content 72%, 3AK20W in Tongde chemical industry), 43.2% of isopropanol, 0.3% of defoamer TEGO 810W, 0.6% of base material wetting agent BYK346, 0.3% of thickener OMG 0434, 0.2% of OMG 0620, 0.6% of water-based drier WD016, 0.6% of N, N-dimethylethanolamine and 14.2% of cosolvent D40 solvent oil.
The preparation method comprises the following steps: mixing cosolvent isopropanol and water-based alkyd resin, stirring the mixed solution for 10-15 minutes by setting a rotating speed of 500-600 r/min through a stirrer, uniformly stirring, sequentially adding a defoaming agent TEGO 810W, a base material wetting agent BYK346, a thickening agent OMG 0434 and a water-based drier chemical WD016, stirring for 10-15 minutes, adding N, N-dimethylethanolamine, finally adding cosolvent D40 solvent oil to adjust the construction viscosity, and filtering and packaging through 200-mesh filter cloth.
The prepared aqueous sealant coating is sprayed on a test board which is degreased and derusted, and a paint film is subjected to performance test after being maintained in a constant temperature and humidity chamber for one week, and the results are shown in the following table 1:
TABLE 1
Figure BDA0003688626890000051
Figure BDA0003688626890000061
The second embodiment is as follows: the invention relates to a water-based sealant coating and a preparation method thereof, wherein the preparation method comprises the following steps:
the formula of the water-based sealant comprises: 50% of water-based alkyd resin (solid content 72%, 3AK20W in Tongde chemical industry), 28.8% of isopropanol, 0.4% of defoamer TEGO 810W, 0.5% of base material wetting agent BYK346, 0.2% of thickener OMG 0434 and 0.2% of OMG 0620, 0.9% of water-based drier WD016, 0.3% of PH regulator N, N-dimethylethanolamine, 0.4% of triethylamine and 18.3% of cosolvent D40 solvent oil.
The preparation method comprises the following steps: mixing cosolvent isopropanol and water-based alkyd resin, stirring the mixed solution for 10-15 minutes by setting a rotating speed of 500-600 r/min through a stirrer, uniformly stirring, sequentially adding a defoaming agent TEGO 810W, a base material wetting agent BYK346, a thickening agent OMG 0434 and a water-based drier chemical WD016, stirring for 10-15 minutes, adding a pH regulator N, N-dimethylethanolamine, finally adding cosolvent D40 solvent oil to adjust the construction viscosity, and filtering and packaging through 200-mesh filter cloth.
The prepared aqueous sealant coating was sprayed on a test board which was degreased and rust-removed, and a paint film was subjected to a performance test after being maintained in a constant temperature and humidity chamber for one week, with the results shown in table 2 below:
TABLE 2
Figure BDA0003688626890000071
The third concrete embodiment: the invention relates to a water-based sealant coating and a preparation method thereof, wherein the preparation method comprises the following steps:
the formula of the water-based sealant comprises: 58% of water-based alkyd resin (solid content 72%, 3AK20W in Tongde chemical industry), 15.2% of isopropanol, 0.5% of defoamer TEGO 810W, 0.3% of base material wetting agent BYK346, 0.1% of thickener OMG 0434 and 0.1% of OMG 0620, 1.4% of water-based drier WD016, 0.3% of PH regulator N, N-dimethylethanolamine, 0.6% of triethylamine and 23.5% of D40 solvent oil.
The preparation method comprises the following steps: mixing cosolvent isopropanol and water-based alkyd resin, stirring the mixed solution for 10-15 minutes by setting a rotating speed of 500-600 r/min through a stirrer, uniformly stirring, sequentially adding a defoaming agent TEGO 810W, a base material wetting agent BYK346, a thickening agent OMG 0434 and a water-based drier chemical WD016, stirring for 10-15 minutes, adding a pH regulator N, N-dimethylethanolamine, finally adding cosolvent D40 solvent oil to adjust the construction viscosity, and filtering and packaging through 200-mesh filter cloth.
The prepared aqueous sealant coating was sprayed on a test board which was degreased and rust-removed, and after maintaining for one week in a constant temperature and humidity chamber, the paint film was subjected to a performance test, and the results are shown in table 3 below:
TABLE 3
Figure BDA0003688626890000081
The water-based sealant coating disclosed by the invention has good sealing property on residual manganese fork casting cutting fluid, and meanwhile, a paint film prepared from the sealant has excellent performances such as impact property, gloss, adhesive force, water resistance and the like, and by matching with the water-based varnish for the high manganese steel frog, the VOC (volatile organic compound) in the whole construction process is reduced, and the water-based varnish has great significance in promoting the water-based varnish to be used in the field of the high manganese steel frog.
The foregoing description of specific embodiments of the present invention has been presented. It is to be understood that the present invention is not limited to the specific embodiments described above, and that various changes or modifications may be made by one skilled in the art within the scope of the appended claims without affecting the spirit of the invention. The embodiments and features of the embodiments of the present application may be combined with each other arbitrarily without conflict.

Claims (9)

1. The water-based sealant coating is characterized by comprising the following raw materials in percentage by weight:
the proportion of the water-based alkyd resin is as follows: 40 to 60 percent of the total weight of the steel,
the defoaming agent is as follows: 0.1 to 0.5 percent,
the base material wetting agent comprises the following components in percentage by weight: 0.1 to 0.6 percent,
the thickener comprises the following components in percentage by weight: 0.2 to 0.8 percent,
the water-based drier comprises the following components in percentage by weight: 0.5 to 1.5 percent,
the PH regulator is in proportion: 0.5 to 1.0 percent,
the cosolvent ratio is as follows: 35.6 to 58.6 percent.
2. The water-based sealant coating of claim 1, wherein the water-based alkyd resin is 3AK0235Y in Germany chemical industry, and the solid content is 70-75%.
3. The aqueous sealant coating of claim 1 wherein said defoamer is at least one of BYK 028, digao TEGO 810W, or TEGO 902W aqueous defoamers.
4. The aqueous sealant coating of claim 1 wherein the substrate wetting agent is at least one or more of TEGO Twin4100, BYK346, or TEGO 280.
5. The aqueous sealant coating of claim 1, wherein said thickener is a polyurethane-type thickener of at least one or more of OMG 0434 or OMG 0620.
6. The waterborne sealer coating of claim 1, wherein said waterborne drier is a waterborne cobalt drier from isodic WD 016.
7. The aqueous sealant coating of claim 1, wherein the PH adjusting agent is one or more of triethylamine, triethanolamine, or N, N-dimethylethanolamine.
8. The aqueous sealant coating of claim 1, wherein the co-solvent is one or more of absolute ethyl alcohol, isopropyl alcohol, or D40 solvent oil.
9. The preparation method of the water-based sealant coating based on claim 1 is characterized by comprising the following steps: mixing 60-80% of the total weight of the cosolvent with the waterborne alkyd resin, stirring the mixed solution for 10-15 minutes by setting a rotating speed of 500-600 r/min through a stirrer, uniformly stirring, sequentially adding the defoamer, the base material wetting agent, the thickening agent and the waterborne drier, stirring for 10-15 minutes, adding the pH regulator, finally adding the rest cosolvent to adjust the construction viscosity, and filtering and packaging through 200-mesh filter cloth.
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005247906A (en) * 2004-03-01 2005-09-15 Nippon Paint Co Ltd Water-based coating agent for steel material, coating method, and coated steel material
CN103725174A (en) * 2013-12-30 2014-04-16 河北晨阳工贸集团有限公司 Water-based paint for wagon and preparation method thereof
CN104341988A (en) * 2014-11-03 2015-02-11 国家电网公司 Special sealing agent for cold spray zinc
CN106675355A (en) * 2016-12-07 2017-05-17 陕西宝塔山油漆股份有限公司 Water-based alkyd coating and preparation method thereof
CN109054603A (en) * 2018-06-25 2018-12-21 河北晨阳工贸集团有限公司 A kind of water alcohol acid anticorrosion of steel structure paint of environmental protection and preparation method thereof
WO2022010857A1 (en) * 2020-07-07 2022-01-13 Swimc Llc Coating compositions including waterborne alkyd resins and metal catalysts
CN114106671A (en) * 2021-12-06 2022-03-01 广州集泰化工股份有限公司 Alkyd primer capable of being dried at low temperature and high humidity and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005247906A (en) * 2004-03-01 2005-09-15 Nippon Paint Co Ltd Water-based coating agent for steel material, coating method, and coated steel material
CN103725174A (en) * 2013-12-30 2014-04-16 河北晨阳工贸集团有限公司 Water-based paint for wagon and preparation method thereof
CN104341988A (en) * 2014-11-03 2015-02-11 国家电网公司 Special sealing agent for cold spray zinc
CN106675355A (en) * 2016-12-07 2017-05-17 陕西宝塔山油漆股份有限公司 Water-based alkyd coating and preparation method thereof
CN109054603A (en) * 2018-06-25 2018-12-21 河北晨阳工贸集团有限公司 A kind of water alcohol acid anticorrosion of steel structure paint of environmental protection and preparation method thereof
WO2022010857A1 (en) * 2020-07-07 2022-01-13 Swimc Llc Coating compositions including waterborne alkyd resins and metal catalysts
CN114106671A (en) * 2021-12-06 2022-03-01 广州集泰化工股份有限公司 Alkyd primer capable of being dried at low temperature and high humidity and preparation method thereof

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