CN115088585A - Method for preparing planting soil in alpine and desertification areas by using saline waste residue soil - Google Patents

Method for preparing planting soil in alpine and desertification areas by using saline waste residue soil Download PDF

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CN115088585A
CN115088585A CN202210766717.1A CN202210766717A CN115088585A CN 115088585 A CN115088585 A CN 115088585A CN 202210766717 A CN202210766717 A CN 202210766717A CN 115088585 A CN115088585 A CN 115088585A
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soil
water
alpine
waste residue
saline
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瞿广飞
李海林
陈帮金
金彩悦
吴丰辉
王作亮
邝凌睿
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Kunming University of Science and Technology
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01GHORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
    • A01G24/00Growth substrates; Culture media; Apparatus or methods therefor
    • A01G24/10Growth substrates; Culture media; Apparatus or methods therefor based on or containing inorganic material

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  • Life Sciences & Earth Sciences (AREA)
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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a method for preparing planting soil in alpine and desertification areas by using saline waste residue soil, which is prepared from the following components in percentage by mass: 60-85% of salt-containing waste residue soil, 1-8% of water-holding material, 5-20% of organic solid waste and 3-25% of nutrient solution; the soil prepared by the method has the capability of meeting the growth of plants in alpine regions, has the capability of keeping free water required by the growth of the plants at the temperature of-8 to-11 ℃, and has lower water-soluble salt; the soil has higher nutrient element content, meets most basic substances required by the growth of plants, and can meet the normal growth requirement of the plants in extreme environments.

Description

Method for preparing planting soil in alpine and desertification areas by using saline waste residue soil
Technical Field
The invention belongs to the field of soil utilization of solid wastes in alpine and desertification areas, and particularly relates to a method for preparing planting soil in alpine and desertification areas by using salt-containing solid wastes.
Background
Soil characteristics in alpine and desertification areas: 1. in natural geography, higher plants cannot grow due to low temperature and short growing season, partial water in plant bodies is lost after rootstocks of the plants are frozen, and some physiological functions are also lost to freeze, so that cells of the plants are frozen, the inner walls of the cells are cracked, the water in the cells of the plants is quickly lost, and the partial or whole plants are killed. 2. The salinized soil distribution area generally has the characteristics of low precipitation, strong evaporation, low and flat landform, shallow underground water burying depth, high underground water mineralization, salt-containing formed soil matrix and the like. The saline soil has too high soil salt concentration, so that the root system of the crop cannot effectively absorb water and nutrients in the soil, the symptoms of nutrient deficiency appear, the symptoms are shown as weak growth, yellowing, wilting, weak root system and the like, and the root system is dead in severe cases, so that the whole plant is withered. 3. The damage of the ecological system is caused by the influence of natural factors and human activities, so that the change similar to a desert environment appears in the original non-desert area. The desert soil has large day-night temperature difference and violent water freezing-thawing and volatilization behaviors, so that plants cannot grow normally, and the water content and water retention capacity of the desert soil are reduced, so that the plants cannot be planted due to water shortage in the growth process of the plants.
Aiming at the existing high-cold frozen soil restoration technology, the method mainly comprises two types: one of the methods is to add an antifreeze into the soil to reduce the freezing point of water in the soil and achieve flowing water required by the normal growth of plants, and the other method is to spray a chemical agent on the surface of the plants, solidify the chemical agent into a film to inhibit the dissipation of the heat of the plants, and supply nutrition to the plants to play a role of plant building so as to effectively prevent the occurrence of freezing injury; aiming at the existing restoration technology of the salinized soil, the technologies of planting salt-tolerant plants, fertilizing the soil, scientifically irrigating and the like are selected; aiming at the problem of desertification soil, the method in the prior art has the steps of endowing the mechanical state of sand soil, namely applying universal combination constraint between sand particles, so as to change the mechanical state of the sand, ensure that the sand obtains the ecological mechanical property of the soil, ensure that the sand is in a rheological state when being wet and in a solid state when being dry, and can be continuously and stably converted along with the change of the dry and wet states of the soil.
In CN201710490468.7, the inventor provides a multifunctional nutrient soil formula and a preparation method, wherein the formula comprises sandy loam, wormcast, sika deer feces, urea, calcium superphosphate, attapulgite, sodium bicarbonate, high-quality peat, perlite, decomposed straw, edible fungus sticks, plant ash, controlled release fertilizer, vinasse, rice hulls, aloe and deionized water; although the multifunctional nutrient soil is prepared by combining sandy soil and natural animal and plant organic essential fertilizers, the water and fertilizer retention capacity is improved, the air permeability of the soil is effectively improved, and the stress resistance and disease prevention are strong, the fundamental current situation is not changed, the water absorption and retention capacity cannot be fully exerted, the defect of water loss of sandy soil is overcome, and the performance of the multifunctional nutrient soil in an extreme environment cannot be ensured. CN201910364159.4 provides a desert sand modifier and a preparation method thereof, wherein the desert sand modifier is prepared from the following raw materials: fly ash, bentonite, organic fertilizer, humic acid, chitin fiber, seaweed extract, sodium lignosulphonate and microbial agent. The modifier is added into the desert sandy soil, so that the water absorption and retention performance of the sandy soil is improved to a certain extent, but the fundamental current situation is not changed, the water absorption and retention capacity of the modifier cannot fully play a role, the defect of water loss of the sandy soil is overcome, and the performance of the modifier in an extreme environment cannot be ensured.
The existing soil improvement agent and restoration agent related technologies and methods still have great defects in the aspect of solving the problems of water, soil and nutrition conservation under extreme freeze-thaw conditions in alpine and desertification areas, and the existing salinized soil improvement technology has great defects in plateau areas. Such as: 1. perennial or seasonal frozen soil can appear in alpine and high-altitude areas and desertification areas, so that soil hardening, free water solidification and rapid day and night temperature difference change can be caused, the water in the soil can be quickly volatilized, and the related problems can not be solved by the prior art and the method; 2. the high salinity of the saline-alkali soil is not fundamentally changed, and the prior art does not develop and recycle the saline-alkali soil, thereby causing further deterioration of the soil environment.
The recycling of saline soil and saline solid waste in western and northern plateau areas of China, the reduction of frozen soil period and the limitation of desertification are problems to be solved in the field.
Disclosure of Invention
The invention provides a method for preparing planting soil in alpine and desertification areas by using waste residue soil containing salt, aiming at the problems that the salt washing and improving cost of the existing salinized soil is high, the utilization rate of solid wastes containing salt is low, the cultivation period under the extreme freeze thawing condition in the alpine and desertification areas at high altitude is short, the water and soil and nutrition maintaining performance is poor and the like.
The method comprises the steps of utilizing saline waste residue soil as a soil main body (provided with salts to reduce freezing points, wherein the salt is mainly heavy metal required by plant growth, but has a stabilizing effect on the heavy metal), crushing and screening the saline waste residue soil, fully mixing the crushed and screened saline waste residue soil with an additional material, fermenting the mixture completely in a fermentation tank, and solarizing the fermented mixture to prepare nutrient soil, so that the soil is not frozen and frozen under a natural environment, higher water content can be kept in a high-temperature area, and natural circulation of water in the soil is kept, so that the growth conditions required by plants are met; the soil utilization is realized in a mode of adding materials, and the soil has higher frost resistance, water retention and fertilizer retention performances, so that the purpose of recycling the waste residue soil nearby is realized, and the applicability of the high-nutrition planting soil is greatly improved.
The method for planting soil in the alpine and desertification areas is prepared from the following components in percentage by mass: 60-85% of salt-containing waste residue soil, 1-8% of water-holding material, 5-20% of organic solid waste and 3-25% of nutrient solution.
The method specifically comprises the steps of mixing salt-containing waste residue soil with the particle size of less than 2.5mm with a water-holding material, organic solid waste and a nutrient solution, pouring the mixture into a fermentation tank, wherein the filling amount of the fermentation tank is 1/3-2/3 of the volume of the mixture, the water content of the mixture is 45% -65%, the fermentation temperature is 30-55 ℃, the fermentation days are 15-25 days, and after the fermentation is finished, the water content of the material is reduced to 20% -32% through solarization, and crushing the material to the particle size of less than 2.5 mm.
The saline waste residue soil is one or more of phosphogypsum, desulfurized gypsum, copper tailings, iron tailings, gold tailings and salinized soil, or sandy soil is added into the saline waste residue soil, wherein the salinized soil comprises bicarbonate sodium soil, bicarbonate soil, sulfate calcium soil and sulfate magnesium sodium soil.
The water holding material is one or more of biochar, rice hull, mushroom dreg, coconut husk, bagasse and sawdust.
The organic solid waste is one or more of municipal domestic sewage sludge, pig manure, cattle manure, landscaping waste and biogas residue.
The nutrient solution per liter contains 0.1-0.8 g of calcium nitrate tetrahydrate, 0.04-0.3 g of monopotassium phosphate, 0.05-0.4 g of ferrous sulfate, 0.05-0.3 g of magnesium sulfate and one or more of zinc sulfate, boric acid and ammonium chloride with the addition amount of 0.01g, and the pH value is 6-8.5.
The planting soil in the alpine and desertification areas fully exerts the economic and environment-friendly values of the planting soil by utilizing the nutrient elements contained in the saline waste residue soil, the heavy metal elements can play a role of reducing the freezing point of water in the soil by sodium salt and an additional antifreeze agent to a certain extent, the effect of reducing the freezing point of free water in the soil is achieved, the water required by plant growth is ensured, and the soil antifreezing mechanism is the ice crystal distortion theory. Pure water freezes at 0 ℃, and water molecules are polymerized into a huge molecular aggregate due to the action of hydrogen bonds, so that the frost heaviness is very strong. The water solution doped with available heavy metals (Cu, Zn, Mo, Fe, Mn, etc.) and salts begins to precipitate ice at the temperature lower than the freezing point, and the precipitated ice crystals are fine and flocculent due to the interference effect of the available heavy metals (Cu, Zn, Mo, Fe, Mn, etc.) and the salts on hydrogen bonds between water molecules, and are very soft in macroscopic view, and the frost heaving stress is greatly reduced. The anti-freezing function has the following action modes: available heavy metals (Cu, Zn, Mo, Fe, Mn, etc.) and salts have very low eutectic temperature with water, and can lower the freezing point of water to make the soil still be hydrated at negative temperature, such as sodium nitrite and sodium chloride.
The application of the water-holding material can improve the water-containing capacity of the prepared soil, protect the soil water from drastic temperature change in alpine desert regions to reduce the reaction and fix free heavy metal ions in the cold-resistant drought soil; the organic solid waste is applied to promote the formation of high-nutrient soil and adjust the physicochemical property of the cultured soil; on one hand, the nutrient solution is used for adding nutrient elements in soil, meeting the requirement of normal growth and development of plants, increasing the water content of the soil and promoting soil fermentation; another aspect is to adjust the physicochemical properties between the water holding material, nutrient solution and spoil soil, such as: the leaching of toxic and harmful substances and the leaching of the excited and solidified heavy metals generated when the substances interact with each other are prevented.
The method has the advantages and the technical effects that:
the saline waste residue soil is used as a main body of the nutrient soil, and some heavy metal ions (heavy metal factors required by plant growth such as Cu, Zn, Mo, Fe, Mn and the like) contained in the saline waste residue soil can play a role in reducing the freezing point of water in the soil by using metal salt to a certain extent, so that the saline waste solidification characteristic is fully utilized, and the capability of reducing the freezing point without adding an antifreezing agent is achieved; the application of the salinization and desertification soil not only leads the salinization and desertification soil to be resource and environment-friendly, but also can utilize the rich salt substances and the physical and chemical properties of the soil, thereby achieving the purposes of promoting the formation of the culture cold-resistant and drought-resistant soil and fully utilizing various effects of the abandoned muck; the high-nutrient soil has the corresponding functions of regulating and protecting the normal growth and development of plants in the extreme environment of high cold and high temperature, has the capabilities of retaining water, gathering water and condensing water, can keep sufficient free water and lasting water-retaining and high-nutrition capabilities, and meets the requirement of normal growth and development of the plants in the extreme environment.
Detailed Description
The present invention is further illustrated by the following examples, but the scope of the present invention is not limited to the above-described contents, and the raw materials in the examples are all conventional commercially available raw materials unless otherwise specified;
in the following examples, the leaching content of heavy metals in soil was measured by a heavy metal leaching toxicity detection method, standard No. [ horizontal oscillation method for leaching toxicity of solid waste ]: HJ 557-2010, and measuring the content of free water in the soil below the freezing point by a resistance method. The content of water-soluble salt in the soil is determined by a conductivity method, and the method is used for determining the content of the water-soluble salt (the content of the water-soluble salt in the saline-alkali residue soil is detected before fermentation) by mainly utilizing the relation between the concentrations of metal sodium and magnesium in saline-alkali soil water solution and the conductivity. The total nitrogen is determined by a soil quality Kjeldahl method, and the standard number is as follows: HJ 717-2014. The soil total phosphorus is measured by an alkali fusion-molybdenum-antimony anti-spectrophotometry method, and the standard number is as follows: HJ 632 + 2011. Soil total potassium was determined by soil total potassium assay, standard no: GB/T9836-88.
Performing an experiment on the prepared soil to ensure that the prepared soil fully absorbs water and then is dried, weighing the soil before and after the prepared soil, and then applying the soil water content = (the mass of the aluminum box and the soil sample before drying-the mass of the aluminum box and the soil sample after drying)/(the mass of the aluminum box and the soil sample after drying-the mass of the aluminum box and the soil sample after drying) to 100%; the water content per unit volume of soil can be used as the water retention of the soil.
Example 1: in this example, the method for preparing the planting soil in the alpine and desertification areas from the saline waste residue soil is as follows:
1. the raw materials comprise: 40% of salinized soil (20% of sodium bicarbonate soil and 20% of sodium magnesium sulfate soil) around a salt lake on the Qinghai-Tibet plateau, 20% of phosphogypsum, 1% of biochar, 1% of rice husk, 1% of mushroom residue, 1% of coconut residues, 4% of municipal domestic sewage sludge, 6% of pig manure, 3% of landscaping waste and 3% of biogas residues, wherein the nutrient solution is formed by adding 0.3g of calcium nitrate tetrahydrate, 0.25g of monopotassium phosphate, 0.3g of ferrous sulfate, 0.3g of magnesium sulfate, 0.01g of zinc sulfate and 0.01g of boric acid into 1L of water, and the pH value is 6.8;
2. crushing the salinized soil and the phosphogypsum in a crusher to below 2.5nm, mixing the salinized soil and the phosphogypsum with a water-holding material, organic solid waste and a nutrient solution, pouring the mixture into a fermentation tank, wherein the filling amount of the fermentation tank is 1/2 of the volume of the mixture, adjusting the water content of the mixture to 54%, the temperature of the fermentation tank to 45 ℃, completing fermentation after 17 days of fermentation, taking out a fermentation product, solarizing for 1 day until the water content is 23%, and crushing the fermentation product to a particle size of below 2.5mm to obtain the saline waste residue soil for preparing the planting soil in the alpine and desertification areas;
the detection result is shown in the table, and the table shows that the prepared soil has the capability of meeting the plant growth in alpine regions, has the capability of keeping free water required by the plant growth at the temperature of-8 ℃, and has lower water-soluble salt; the soil has higher nutrient element content, and meets the basic substances required by the growth of most plants; the water content of the prepared soil is improved by 53 percent compared with that of the common soil (the water content is 15 percent).
Figure DEST_PATH_IMAGE002
Figure DEST_PATH_IMAGE004
Example 2: the method for preparing the planting soil in the alpine and desertification areas by using the saline waste residue soil comprises the following steps:
1. the raw materials comprise: 20% of salinized soil (carbonate sodium soil) around a salt lake on the Qinghai-Tibet plateau, 5% of copper tailings, 45% of desertified soil, 1% of biochar, 1% of rice hulls, 1% of bagasse, 1% of sawdust, 6% of pig manure, 5% of landscaping waste and 15% of nutrient solution; the nutrient solution is prepared by adding 0.6 g of calcium nitrate tetrahydrate, 0.25g of monopotassium phosphate, 0.25g of ferrous sulfate, 0.15 g of magnesium sulfate and 0.01g of boric acid into 1L of water, and the pH value is 7.1.
2. Crushing the salinized soil, the copper tailings and the desertification soil in a crusher to below 2.5nm, mixing the salinized soil, the copper tailings and the desertification soil with a water-holding material, organic solid waste and a nutrient solution, pouring the mixture into a fermentation tank, adjusting the water content of the mixture to 65 percent, controlling the temperature of the fermentation tank to be 48 ℃ and the fermentation time to be 22 days, completing fermentation, taking out a fermentation product, solarizing for 1 day until the water content is 20 percent, and crushing the fermentation product to the particle size of below 2.5mm to obtain the saline waste residue soil for preparing the planting soil in the alpine and desertification areas;
the detection result is shown in the table, and the table shows that the prepared soil has the capability of meeting the plant growth in alpine regions, has the capability of keeping free water required by the plant growth at the temperature of-10 ℃, and has lower water-soluble salt; the soil has higher nutrient element content, and meets the basic substances required by the growth of most plants; the water content of the prepared soil is improved by 33 percent compared with that of the common soil (the water content is 15 percent).
Figure DEST_PATH_IMAGE006
Figure DEST_PATH_IMAGE008
Example 3: the method for preparing the planting soil in the alpine and desertification areas by using the saline waste residue soil comprises the following steps:
1. the raw materials comprise: 30% of salinized soil (15% of bicarbonate soil and 15% of calcium sulfate soil) around a salt lake on Qinghai-Tibet plateau, 20% of phosphogypsum, 18% of desertification soil, 2% of biochar, 1% of rice husk, 1% of mushroom dreg, 1% of coconut husk, 1% of bagasse, 1% of sawdust, 4% of domestic sewage sludge, 6% of pig manure, 3% of landscaping waste, 3% of biogas residue and 9% of nutrient solution; the nutrient solution is prepared by adding 0.6 g of calcium nitrate tetrahydrate, 0.25g of potassium dihydrogen phosphate, 0.25g of ferrous sulfate, 0.15 g of magnesium sulfate and 0.01g of boric acid into 1L of water, and the pH value is 7.3.
2. Crushing the salinized soil, the phosphogypsum and the desertification soil in a crusher to below 2.5nm, mixing the salinized soil, the phosphogypsum and the desertification soil with a water-holding material, organic solid waste and nutrient solution, pouring the mixture into a fermentation tank, wherein the filling amount of the fermentation tank is 2/3 of the volume of the fermentation tank, adjusting the water content of the mixture to 60 percent, the temperature of the fermentation tank to 50 ℃, completing fermentation after 20 days of fermentation, taking out a fermentation product, solarizing for 1 day until the water content is 21 percent, and crushing the fermentation product to the particle size of below 2.5mm to obtain the saline waste residue soil for preparing the planting soil in the alpine and desertification areas
The detection result is shown in the table, and the table shows that the prepared soil has the capability of meeting the plant growth in alpine regions, has the capability of keeping free water required by the plant growth at the temperature of-11 ℃, and has lower water-soluble salt; the soil has higher nutrient element content, and meets the basic substances required by the growth of most plants; the water content of the prepared soil is improved by 40 percent compared with that of the common soil (the water content is 15 percent).
Figure DEST_PATH_IMAGE010
Figure DEST_PATH_IMAGE012

Claims (6)

1. The method for preparing the planting soil in the alpine and desertification areas by using the saline waste residue soil is characterized by comprising the following components in percentage by mass: 60-85% of salt-containing waste residue soil, 1-8% of water-holding material, 5-20% of organic solid waste and 3-25% of nutrient solution.
2. The method for preparing planting soil in alpine and desertified areas by using saline waste residue soil according to claim 1, wherein the method comprises the following steps: the salt-containing waste residue soil is one or more of phosphogypsum, desulfurized gypsum, copper tailings, iron tailings, gold tailings and salinized soil, or desertification soil is added into the salt-containing waste residue soil, and the particle size of the salt-containing waste residue soil is less than 2.5 mm.
3. The method for preparing planting soil in alpine and desertified areas by using saline waste residue soil according to claim 1, wherein the method comprises the following steps: the water holding material is one or more of biochar, rice hull, mushroom dreg, coconut husk, bagasse and sawdust.
4. The method for preparing planting soil in alpine and desertified regions by using waste saline soil as claimed in claim 1, wherein: the organic solid waste is one or more of municipal domestic sewage sludge, pig manure, cattle manure, landscaping waste and biogas residue.
5. The method for preparing planting soil in alpine and desertified regions by using waste saline soil as claimed in claim 1, wherein: the nutrient solution is prepared by adding 0.1-0.8 g of calcium nitrate tetrahydrate, 0.04-0.3 g of monopotassium phosphate, 0.05-0.4 g of ferrous sulfate, 0.05-0.3 g of magnesium sulfate and one or more of zinc sulfate, boric acid and ammonium chloride with the addition amount of 0.01g into 1L of water, and the pH value is 6-8.5.
6. The method for preparing planting soil in alpine and desertified regions by using waste saline soil as claimed in claim 2, wherein: mixing the crushed saliferous waste residue soil, a water-holding material, organic solid waste and a nutrient solution, pouring the mixture into a fermentation tank, wherein the filling amount of the fermentation tank is 1/3-2/3 of the volume of the fermentation tank, the water content of the mixture is 45-65%, the fermentation temperature is 30-55 ℃, the fermentation days are 15-25 days, and the water content of the material after fermentation is reduced to 20-32% by solarization, and crushing the material to the particle size of below 2.5 mm.
CN202210766717.1A 2022-07-01 2022-07-01 Method for preparing planting soil in alpine and desertification areas by using saline waste residue soil Pending CN115088585A (en)

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CN111234837A (en) * 2020-03-20 2020-06-05 潍坊科技学院 Saline-alkali soil repairing agent and repairing method
CN112243626A (en) * 2020-10-12 2021-01-22 昆明理工大学 Method for converting copper tailings into soil in alpine and high-altitude areas
CN113134508A (en) * 2021-04-17 2021-07-20 湖南省园艺研究所 Method for improving soil by landscape organic mulch

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