CN115043644A - Ceramic hand mold with anti-static function and preparation process thereof - Google Patents

Ceramic hand mold with anti-static function and preparation process thereof Download PDF

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CN115043644A
CN115043644A CN202210387573.9A CN202210387573A CN115043644A CN 115043644 A CN115043644 A CN 115043644A CN 202210387573 A CN202210387573 A CN 202210387573A CN 115043644 A CN115043644 A CN 115043644A
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parts
powder
mixture
hand mold
ceramic hand
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CN115043644B (en
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乔栓虎
谭洪波
袁国梁
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Shandong Electric Shield Polytron Technologies Inc
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Shandong Electric Shield Polytron Technologies Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C41/00Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
    • B29C41/02Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
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    • C04B2235/3293Tin oxides, stannates or oxide forming salts thereof, e.g. indium tin oxide [ITO]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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Abstract

The invention relates to a ceramic hand mould with an antistatic function and a preparation process thereof, wherein the ceramic hand mould comprises the following steps: glass powder, turpentine, butyl carbitol acetate, thickening agent, fluidity control agent, CdO and In 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 . The preparation process comprises the following steps: (1) mixing CdO and In 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 And uniformly stirring after mixing to obtain a mixture A. (2) Mixing the glass powder, turpentine, butyl carbitol acetate, the thickening agent and the fluidity control agent, and then uniformly stirring to obtain a mixture B. (3) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold. According to the ceramic hand mold disclosed by the invention, through redesigning the formula, the prepared ceramic hand mold is good in antistatic performance, the surface of the ceramic hand mold is not easy to leave dirt, the ceramic hand mold is convenient to clean, and the quality of the ceramic hand mold is effectively improved.

Description

Ceramic hand mold with anti-static function and preparation process thereof
Technical Field
The invention relates to the field of glove production, in particular to a ceramic hand mold with an anti-static function and a preparation process thereof.
Background
The hand mold is a forming mold for producing gloves such as PVC, latex, butyronitrile and the like. In the production process, the hand die is continuously operated for a long time, dirt is prevented from being adhered to the hand die, and simultaneously, corn starch is adsorbed by static electricity, when the edge rolling roller is improperly adjusted, materials are adhered to the die while being hung on the edge rolling roller, the materials are brought into a material groove if the materials are not cleaned in time, the gloves have the defects of material adhesion, pinholes, two points and the like, and the yield is seriously influenced.
In order to overcome the problem that static electricity is easily generated in the use process of the hand model, a method of doping a conductive material into the hand model is generally adopted, and the generated static electricity is conducted out in time, so that the accumulation of static charges on the surface of the hand model is avoided. The conventional conductive materials include powders of metals, metal oxides, metal salts, metal alloys, and the like. However, the hand mold prepared by the conventional method still has unsatisfactory antistatic performance, has a problem that dirt is easily adhered to the surface, is not easily cleaned, affects the production efficiency of gloves, and reduces the yield of gloves.
Disclosure of Invention
Aiming at the problems, the invention provides the ceramic hand mould with the anti-static function and the preparation process thereof. In order to achieve the purpose, the invention discloses the following technical scheme:
in a first aspect of the invention, a ceramic hand model with an antistatic function is disclosed, which comprises the following raw materials in parts by weight: 25-35 parts of glass powder, 10-15 parts of turpentine, 3-6 parts of butyl carbitol acetate, 0.5-1.2 parts of thickening agent, 1-2 parts of fluidity control agent, 1.7-2.1 parts of CdO powder, and In 2 O 3 1.5-2.8 parts of powder and Ti 2 O 3 2-2.5 parts of powder and SnO 2 2.4-3.6 parts of powder and MoO 3 0.6-1.3 parts of powder.
Furthermore, the glass powder comprises any one of boron-silicon-lead glass powder, high-boron-silicon glass powder and the like, and the ceramic hand mold with high strength and good thermal stability can be obtained after the glass powder is used as a main material and is fired.
Further, the thickener includes any one of ethyl cellulose, nitrocellulose, and the like.
Further, the fluidity controller is an acrylic copolymer such as polyacrylamide, etc. In the present invention, the fluidity acts to promote the surface finish of the hand mold and to reduce the adhesion of dirt.
Further, the CdO powder and In 2 O 3 Powder, Ti 2 O 3 Powder, SnO 2 Powder, MoO 3 The powder is nano powder to increase the antistatic function and surface smoothness of the hand mould and reduce the attachment of dirt.
Furthermore, the raw materials of the ceramic hand model also comprise 1.5-3 parts by weight of a surfactant. Optionally, the surfactant comprises: stearic acid, sodium dodecylbenzenesulfonate, glyceryl monostearate, etc.
In a second aspect of the present invention, a preparation process of the ceramic hand mold with the antistatic function is disclosed, which comprises the following steps:
(1) mixing the CdO powder and In 2 O 3 Powder, Ti 2 O 3 Powder, SnO 2 Powder, MoO 3 The powder is mixed and stirred evenly to obtain a mixture A for standby.
(2) And mixing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent, and then uniformly stirring to obtain a mixture B.
(3) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold.
Further, in the step (1), the stirring time is 10-30 min, so that the materials are fully and uniformly mixed.
Further, in the step (2), the stirring time is 35-60 min, so that the materials are fully and uniformly mixed.
Further, in the step (3), the firing temperature is 1250-1380 ℃ and the time is 2.5-4 hours.
Compared with the prior art, the invention has the following beneficial effects: according to the ceramic hand mold disclosed by the invention, by redesigning the formula, the prepared ceramic hand mold has good antistatic performance, is not easy to leave dirt on the surface, is convenient to clean, and effectively improves the quality of the ceramic hand mold. In the invention, CdO and In are used 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 The formed compound is a composite conductive agent, and the metal oxide components are matched with each other in a synergistic manner, so that the excellent antistatic performance of the ceramic hand mold is guaranteed, the surface of the ceramic hand mold is not easy to adhere to dirt in the using process, and the self-cleaning function of the ceramic hand mold is improved. In addition, the addition of butyl carbitol acetate ensures that the surface of the ceramic hand mold is smooth, reduces the surface roughness and improves the self-cleaning function of the ceramic hand mold.
Detailed Description
It is to be understood that the following detailed description is exemplary and is intended to provide further explanation of the invention as claimed. The invention will now be further illustrated by specific examples.
Example 1
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, In 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 Nano powderPlacing in a mixer, stirring for 25min to uniformly stir the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 2
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 35 parts of high borosilicate glass powder, 15 parts of turpentine, 3 parts of butyl carbitol acetate, 1.2 parts of nitrocellulose, 2.0 parts of polyacrylamide, 2.1 parts of CdO nano powder, In 2 O 3 2.8 parts of nano powder and Ti 2 O 3 2.0 parts of nano powder and SnO 2 2.4 parts of nano powder and MoO 3 And 1.3 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 30min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 60min to obtain a mixture B.
(4) Adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring into a heating furnace, firing at 1380 ℃ for 2.5 hours, and cooling to room temperature along with the furnace after finishing, thus obtaining the ceramic hand mold.
Example 3
A preparation process of a ceramic hand mold with an anti-static function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 25 parts of high borosilicate glass powder, 10 parts of turpentine, 6 parts of butyl carbitol acetate, 0.5 part of nitrocellulose, 1.0 part of polyacrylamide, 1.7 parts of CdO nano powder, In 2 O 3 1.5 parts of nano powder and Ti 2 O 3 2.3 parts of nano powder and SnO 2 3.6 parts of nano powder and MoO 3 0.6 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 10min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 35min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixture into a hand die mold, applying pressure of 40MPa to press and form, transferring the mixture into a heating furnace, firing at 1250 ℃ for 4 hours, and cooling to room temperature along with the furnace to obtain the ceramic hand die.
Example 4
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 28 parts of high borosilicate glass powder, 11 parts of turpentine, 5 parts of butyl carbitol acetate, 1.0 part of nitrocellulose, 1.3 parts of polyacrylamide, 1.5 parts of sodium dodecyl benzene sulfonate, 1.8 parts of CdO nano powder, In 2 O 3 2.1 parts of nano powder and Ti 2 O 3 2.0 parts of nano powder and SnO 2 3.3 parts of nano powder and MoO 3 And 1.0 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 20min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer, and stirring for 40min to obtain a mixture B.
(4) Adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring into a heating furnace, firing at 1350 ℃ for 3.5 hours, and cooling to room temperature along with the furnace after firing to obtain the ceramic hand mold.
Example 5
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 32 parts of high borosilicate glass powder, 14 parts of turpentine, 4.5 parts of butyl carbitol acetate, 1.1 parts of nitrocellulose, 2.0 parts of polyacrylamide, 3.0 parts of glycerin monostearate, 1.9 parts of CdO nano powder, and In 2 O 3 2.5 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.5 parts of nano powder and MoO 3 0.7 part of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 45min to obtain a mixture B.
(4) Adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring into a heating furnace, firing at 1350 ℃ for 3.5 hours, and cooling to room temperature along with the furnace after firing to obtain the ceramic hand mold.
Example 6
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1)preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Subjecting the In to 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixture into a hand die mould, applying pressure of 40MPa to press and form, transferring the mixture into a heating furnace, firing for 3 hours at 1300 ℃, and cooling to room temperature along with the furnace after the firing to obtain the ceramic hand die.
Example 7
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixture into a hand die mould, applying pressure of 40MPa to press and form, transferring the mixture into a heating furnace, firing for 3 hours at 1300 ℃, and cooling to room temperature along with the furnace after the firing to obtain the ceramic hand die.
Example 8
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, In 2 O 3 2.2 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer, and stirring for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixture into a hand die mould, applying pressure of 40MPa to press and form, transferring the mixture into a heating furnace, firing for 3 hours at 1300 ℃, and cooling to room temperature along with the furnace after the firing to obtain the ceramic hand die.
Example 9
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, In 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder, MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder, SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 10
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 5 parts of butyl carbitol acetate, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder, In 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And placing the glass powder, the turpentine, the butyl carbitol acetate, the thickening agent and the fluidity control agent into a mixer to be stirred for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Example 11
A preparation process of a ceramic hand mold with an antistatic function comprises the following steps:
(1) preparing raw materials: accurately weighing the following components in parts by weight by using a balance: 30 parts of boron-silicon-lead glass powder, 13 parts of turpentine, 0.8 part of ethyl cellulose, 1.4 parts of polyacrylamide, 2.0 parts of CdO nano powder and In 2 O 3 2.2 parts of nano powder and Ti 2 O 3 2.5 parts of nano powder and SnO 2 3.0 parts of nano powder and MoO 3 And 1.1 parts of nano powder.
(2) Mixing the CdO nano powder and In 2 O 3 Nano powder, Ti 2 O 3 Nano powder and SnO 2 Nano powder, MoO 3 And (3) placing the nano powder into a mixer, and stirring for 25min to uniformly stir all the materials to obtain a mixture A.
(3) And (3) placing the glass powder, the turpentine, the thickening agent and the fluidity control agent into a mixer, and stirring for 50min to obtain a mixture B.
(4) And adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, placing the obtained wet mixed material into a hand mold die, then applying pressure of 40MPa to press and form, transferring the formed wet mixed material into a heating furnace, firing the mixture at 1300 ℃ for 3 hours, and cooling the mixture to room temperature along with the furnace after the firing is finished to obtain the ceramic hand mold.
Performance testing
The surface resistance (according to standard: ANSI/ESD541-2008) and surface roughness of the ceramic hand models prepared in the above examples were measured to measure the antistatic ability and self-cleaning ability of the ceramic hand models, and the results are shown in tables 1 and 2.
TABLE 1
Example number 1 2 3 4 5 6
Surface resistance 3.6×10 6 4.4×10 6 4.9×10 6 6.1×10 6 5.8×10 6 8.8×10 7
Roughness/mum 0.27 0.33 0.31 0.23 0.26 0.54
TABLE 2
Example number 7 8 9 10 11
Surface resistance 1.4×10 8 6.6×10 7 2.4×10 8 3.7×10 8 6.9×10 6
Roughness/mum 0.72 0.58 0.69 0.63 0.47
As can be seen from the test results In tables 1 and 2, the surface resistance of the ceramic hand mold obtained In examples 6-10 is generally higher than that of examples 1-5, which indicates that CdO and In are used 2 O 3 、Ti 2 O 3 、SnO 2 、MoO 3 After the compound is a composite conductive agent, the metal oxide components are matched with each other in a synergistic manner, so that the antistatic performance of the ceramic hand mold can be obviously improved, and the ceramic hand mold can be an excellent antistatic body. Meanwhile, the composite conductive agent and the butyl carbitol acetate are added, so that the roughness of the surface of the ceramic hand mold is obviously reduced, and the self-cleaning function of the ceramic hand mold is improved.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. The ceramic hand mold with the antistatic function is characterized in that the raw materials of the ceramic hand mold comprise the following components in parts by weight: 25-35 parts of glass powder, 10-15 parts of turpentine, 3-6 parts of butyl carbitol acetate, 0.5-1.2 parts of thickening agent, 1-2 parts of fluidity control agent, 1.7-2.1 parts of CdO powder, and In 2 O 3 1.5-2.8 parts of powder and Ti 2 O 3 2-2.5 parts of powder and SnO 2 2.4-3.6 parts of powder and MoO 3 0.6-1.3 parts of powder.
2. The ceramic hand mold with antistatic function as claimed in claim 1, wherein the glass powder includes any one of boron-silicon-lead glass powder and high-boron-silicon glass powder.
3. The ceramic hand mold with the antistatic function according to claim 1, wherein the thickener comprises any one of ethyl cellulose and nitrocellulose.
4. The ceramic hand mold with antistatic function according to claim 1, wherein the fluidity control agent is an acrylic copolymer, preferably polyacrylamide.
5. The ceramic hand mold with antistatic function as claimed In claim 1, wherein the CdO powder and In are 2 O 3 Powder, Ti 2 O 3 Powder, SnO 2 Powder, MoO 3 The powder is nanometer powder.
6. The ceramic hand mold with the antistatic function according to any one of claims 1 to 5, characterized in that the raw materials of the ceramic hand mold further comprise 1.5 to 3 parts by weight of a surfactant; preferably, the surfactant comprises: any one of stearic acid, sodium dodecyl benzene sulfonate and glycerin monostearate.
7. The process for preparing the ceramic hand mold with the antistatic function according to any one of claims 1 to 6, which comprises the following steps:
(1) mixing the CdO powder and In 2 O 3 Powder, Ti 2 O 3 Powder, SnO 2 Powder, MoO 3 Mixing the powders, and stirring to obtain mixture A;
(2) mixing the glass powder, turpentine, butyl carbitol acetate, a thickening agent and a fluidity control agent, and then uniformly stirring to obtain a mixture B;
(3) and adding the mixture A into the mixture B while stirring to fully mix the mixture A and the mixture B, and pressing and forming the obtained wet mixture and then firing to obtain the ceramic hand mold.
8. The process for preparing the ceramic hand mold with the antistatic function according to claim 7, wherein in the step (1), the stirring time is 10-30 min.
9. The process for preparing the ceramic hand mold with the antistatic function according to claim 7, wherein in the step (2), the stirring time is 35-60 min.
10. The process for preparing a ceramic hand mold with an antistatic function according to any one of claims 7 to 9, wherein the firing temperature in the step (3) is 1250 to 1380 ℃ for 2.5 to 4 hours.
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Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05319903A (en) * 1992-03-16 1993-12-03 Kawasaki Steel Corp Binder and composition for injection molding of sintering powder
US5380179A (en) * 1992-03-16 1995-01-10 Kawasaki Steel Corporation Binder system for use in the injection molding of sinterable powders and molding compound containing the binder system
US5632942A (en) * 1993-05-24 1997-05-27 Industrial Technoology Research Institute Method for preparing multilayer ceramic/glass substrates with electromagnetic shielding
JPH1044286A (en) * 1996-08-01 1998-02-17 Mitsui Petrochem Ind Ltd Antistatic film and polarizing film employing the antistatic film
JP2000313663A (en) * 1999-04-28 2000-11-14 Kyocera Corp Electroconductive ceramic, antistatic material using the same and magnetic disc device
JP2005104737A (en) * 2003-09-12 2005-04-21 Shinkoo:Kk Surface treating agent for ceramic-made glove mold, ceramic-made glove mold, method for manufacturing the same, and glove
JP2006257610A (en) * 2005-03-14 2006-09-28 Hiroshi Inoue Method for producing static electricity charge-preventive natural rubber latex composition, natural rubber glove and finger suck
US20070190251A1 (en) * 2006-02-10 2007-08-16 Tdk Corporation Release layer paste and method of production of a multilayer type electronic device
CN101786878A (en) * 2010-01-27 2010-07-28 长沙理工大学 Anti-electrostatic ceramic material, preparation method thereof and firecrackers lead knitting needle made of material
CN102030519A (en) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 Anti-static ceramic brick and production method thereof
US20120280184A1 (en) * 2009-12-16 2012-11-08 Consejo Superior De Investigaciones Cientificas (Csic) Composite Material of Electroconductor Having Controlled Coefficient of Thermical Expansion
CN104621800A (en) * 2013-11-11 2015-05-20 江苏东菱塑胶有限公司 Butyronitrile glove preventing static and production method thereof
WO2016099303A1 (en) * 2014-12-19 2016-06-23 Secura B.C. Sp. Z O.O. A method of forming gloves providing insulation from electricity from the latex and latex gloves electro obtained by this method.
CN107473741A (en) * 2017-09-21 2017-12-15 深圳市商德先进陶瓷股份有限公司 Anti-static ceramic and preparation method thereof
CN108439804A (en) * 2018-04-19 2018-08-24 苏州凌科特新材料有限公司 A kind of glass ceramic composite material and preparation method thereof
US20190016642A1 (en) * 2016-10-12 2019-01-17 Wuhan University Of Technology Cellulose nanocrystal-modified ceramic blank and preparation method thereof
CN109837766A (en) * 2019-01-25 2019-06-04 南通倍成劳护用品有限公司 A kind of antistatic butyronitrile gloves and preparation method thereof
CN110128099A (en) * 2019-05-20 2019-08-16 陈海斗 A kind of preparation method of compounded antistatic Ceramic Tiles
US20200199345A1 (en) * 2017-06-23 2020-06-25 Sekisui Chemical Co., Ltd. Resin composition, inorganic fine particle-dispersed slurry composition, inorganic fine particle-dispersed sheet, method for manufacturing all-solid-state battery, and method for manufacturing laminated ceramic capacitor
CN113149429A (en) * 2021-02-25 2021-07-23 浙江工业大学 High borosilicate glass containing metal nanoparticles and preparation method thereof
CN114276592A (en) * 2022-01-17 2022-04-05 苏锦华 Preparation method of anti-static labor protection gloves

Patent Citations (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05319903A (en) * 1992-03-16 1993-12-03 Kawasaki Steel Corp Binder and composition for injection molding of sintering powder
US5380179A (en) * 1992-03-16 1995-01-10 Kawasaki Steel Corporation Binder system for use in the injection molding of sinterable powders and molding compound containing the binder system
US5632942A (en) * 1993-05-24 1997-05-27 Industrial Technoology Research Institute Method for preparing multilayer ceramic/glass substrates with electromagnetic shielding
JPH1044286A (en) * 1996-08-01 1998-02-17 Mitsui Petrochem Ind Ltd Antistatic film and polarizing film employing the antistatic film
JP2000313663A (en) * 1999-04-28 2000-11-14 Kyocera Corp Electroconductive ceramic, antistatic material using the same and magnetic disc device
JP2005104737A (en) * 2003-09-12 2005-04-21 Shinkoo:Kk Surface treating agent for ceramic-made glove mold, ceramic-made glove mold, method for manufacturing the same, and glove
JP2006257610A (en) * 2005-03-14 2006-09-28 Hiroshi Inoue Method for producing static electricity charge-preventive natural rubber latex composition, natural rubber glove and finger suck
US20070190251A1 (en) * 2006-02-10 2007-08-16 Tdk Corporation Release layer paste and method of production of a multilayer type electronic device
US20120280184A1 (en) * 2009-12-16 2012-11-08 Consejo Superior De Investigaciones Cientificas (Csic) Composite Material of Electroconductor Having Controlled Coefficient of Thermical Expansion
CN101786878A (en) * 2010-01-27 2010-07-28 长沙理工大学 Anti-electrostatic ceramic material, preparation method thereof and firecrackers lead knitting needle made of material
CN102030519A (en) * 2010-11-30 2011-04-27 广东特地陶瓷有限公司 Anti-static ceramic brick and production method thereof
CN104621800A (en) * 2013-11-11 2015-05-20 江苏东菱塑胶有限公司 Butyronitrile glove preventing static and production method thereof
WO2016099303A1 (en) * 2014-12-19 2016-06-23 Secura B.C. Sp. Z O.O. A method of forming gloves providing insulation from electricity from the latex and latex gloves electro obtained by this method.
US20190016642A1 (en) * 2016-10-12 2019-01-17 Wuhan University Of Technology Cellulose nanocrystal-modified ceramic blank and preparation method thereof
US20200199345A1 (en) * 2017-06-23 2020-06-25 Sekisui Chemical Co., Ltd. Resin composition, inorganic fine particle-dispersed slurry composition, inorganic fine particle-dispersed sheet, method for manufacturing all-solid-state battery, and method for manufacturing laminated ceramic capacitor
CN107473741A (en) * 2017-09-21 2017-12-15 深圳市商德先进陶瓷股份有限公司 Anti-static ceramic and preparation method thereof
CN108439804A (en) * 2018-04-19 2018-08-24 苏州凌科特新材料有限公司 A kind of glass ceramic composite material and preparation method thereof
CN109837766A (en) * 2019-01-25 2019-06-04 南通倍成劳护用品有限公司 A kind of antistatic butyronitrile gloves and preparation method thereof
CN110128099A (en) * 2019-05-20 2019-08-16 陈海斗 A kind of preparation method of compounded antistatic Ceramic Tiles
CN113149429A (en) * 2021-02-25 2021-07-23 浙江工业大学 High borosilicate glass containing metal nanoparticles and preparation method thereof
CN114276592A (en) * 2022-01-17 2022-04-05 苏锦华 Preparation method of anti-static labor protection gloves

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
伍秋涛: "《软包装薄膜材料及应用》", 31 March 2011, 印刷工业出版社 *
金国庭等: "防静电陶瓷砖的制备与性能研究", 《佛山陶瓷》 *

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