CN114959996A - Cationic modified polyester jean fabric and preparation method thereof - Google Patents

Cationic modified polyester jean fabric and preparation method thereof Download PDF

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Publication number
CN114959996A
CN114959996A CN202210725764.1A CN202210725764A CN114959996A CN 114959996 A CN114959996 A CN 114959996A CN 202210725764 A CN202210725764 A CN 202210725764A CN 114959996 A CN114959996 A CN 114959996A
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China
Prior art keywords
cation modified
modified polyester
terylene
cation
dyeing
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Pending
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CN202210725764.1A
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Chinese (zh)
Inventor
王宗伟
仇振华
姜为民
高水平
徐彬
袁改荣
朱蓉萍
唐金斌
吴俊�
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Black Peony Textile Co ltd
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Black Peony Textile Co ltd
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Priority to CN202210725764.1A priority Critical patent/CN114959996A/en
Publication of CN114959996A publication Critical patent/CN114959996A/en
Pending legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/40—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads
    • D03D15/47—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the structure of the yarns or threads multicomponent, e.g. blended yarns or threads
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/208—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based
    • D03D15/225—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads cellulose-based artificial, e.g. viscose
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/20—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads
    • D03D15/283—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the material of the fibres or filaments constituting the yarns or threads synthetic polymer-based, e.g. polyamide or polyester fibres
    • D—TEXTILES; PAPER
    • D03—WEAVING
    • D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • D03D15/50—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used characterised by the properties of the yarns or threads
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/11—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/327—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof
    • D06M15/333—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated alcohols or esters thereof of vinyl acetate; Polyvinylalcohol
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/41—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using basic dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/82—Textiles which contain different kinds of fibres
    • D06P3/8204—Textiles which contain different kinds of fibres fibres of different chemical nature
    • D06P3/8223—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups
    • D06P3/8228—Textiles which contain different kinds of fibres fibres of different chemical nature mixtures of fibres containing hydroxyl and ester groups using one kind of dye
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/35—Abrasion, pilling or fibrillation resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/50—Modified hand or grip properties; Softening compositions
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
    • D10B2201/20—Cellulose-derived artificial fibres
    • D10B2201/22—Cellulose-derived artificial fibres made from cellulose solutions
    • D10B2201/24—Viscose
    • D—TEXTILES; PAPER
    • D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
    • Y02P70/62—Manufacturing or production processes characterised by the final manufactured product related technologies for production or treatment of textile or flexible materials or products thereof, including footwear

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a cation modified terylene denim fabric and a preparation method thereof, wherein warp yarns are dyed cation modified terylene/viscose blended yarns, and weft yarns are undyed cation modified terylene; the preparation method comprises the following steps: firstly, preparing blended yarns from cation modified terylene and viscose according to a blending ratio, and then warping; secondly, dyeing and sizing are combined to obtain warp yarns; thirdly, weaving the warp and undyed cation modified polyester into grey cloth; and fourthly, after finishing, obtaining the cation modified polyester jean fabric. Compared with the conventional polyester jean fabric, the cation modified polyester jean fabric is more energy-saving and environment-friendly, is soft and comfortable, and has good pilling resistance and hygroscopicity; the cationic modified terylene denim fabric adopts a dyeing and sizing combined process to directly dye and size the cationic modified terylene/viscose blended yarn, and then is woven with undyed cationic modified terylene to form the denim fabric, so that the process is short, and color defects are avoided.

Description

Cationic modified polyester jean fabric and preparation method thereof
Technical Field
The invention belongs to the technical field of denim fabric, and particularly relates to cationic modified polyester denim fabric and a preparation method thereof.
Background
The traditional denim fabric is made of cotton fibers, and the existing denim fabric is more and more made of natural fibers such as hemp, wool and silk, regenerated fibers such as viscose, tencel and modal, and synthetic fibers such as terylene, chinlon, acrylon and spandex.
The conventional polyester has good washing and wearing performance, firmness and durability, smoothness and stiffness, but has obvious defects, such as poor air permeability, poor dyeing performance, easy fluffing and pilling and the like, and the disperse dye is required to be adopted for dyeing under the conditions of high temperature and high pressure, so that the requirements on dyeing equipment and process are high, and the color tone, style and performance of the product are limited.
The cation modified terylene (English name is Cationic Dyeable PET, also called cation Dyeable terylene) is characterized by that it adds third monomer or fourth monomer, and adopts copolymerization method to improve the dyeability of terylene fibre, and its fibre dyeing rate is high, and its dye utilization rate can be raised. The cation modified terylene well solves the problems of the conventional terylene, has low production energy consumption, low cost, wide application and large demand, and the prepared fabric is soft and comfortable, has good pilling resistance and hygroscopicity, thereby being popular.
At present, the documents of applying cation modified terylene to denim fabric are less, and Chinese patent document CN102650089A discloses a denim elastic fabric and a production method thereof, wherein warp yarns of the fabric contain cation dyeable terylene, weft yarns do not contain cation dyeable terylene, and after weaving, the warp yarns are dyed by cation dye, thereby forming the denim fabric. The disadvantages of this document are: dyeing the fabric after weaving is very easy to cause color defects.
Disclosure of Invention
The invention aims to solve the problems and provides the cation modified polyester denim fabric which is short in process, energy-saving and environment-friendly and particularly free of color defects and the preparation method thereof.
The technical scheme for realizing the purpose of the invention is as follows: the warp yarn of the cationic modified terylene denim fabric is dyed cationic modified terylene/viscose blended yarn, and the weft yarn of the cationic modified terylene denim fabric is undyed cationic modified terylene.
In the warp, the blending ratio of the cation modified polyester to the viscose is (60-70%) to (30-40%).
The preparation method of the cationic modified polyester denim fabric comprises the following steps:
firstly, preparing blended yarns from the cation modified terylene and the viscose according to a blending proportion, and then warping the blended yarns.
And secondly, performing a dyeing and sizing combined process on the warped yarns to obtain warp yarns.
And thirdly, weaving the warp yarn obtained in the step two and undyed cation modified polyester into grey cloth.
Fourthly, after-finishing the grey cloth woven in the third step to obtain the cation modified polyester jean fabric.
In the dyeing and sizing combined process of the step II, the formula of the dyeing solution is as follows: 0.5-5.0 g/L of cationic dye, 3-10 g/L of anhydrous sodium sulphate and 0.5-3 g/L of glacial acetic acid; the temperature of the dye vat is 90-110 ℃.
In the dyeing and sizing combined process of the second step, the sizing agent formula is as follows: 50-100 g/L, PVA g of starch slurry 10-20 g/L, 1-5 g/L of paraffin and 1-5 g/L of stabilizer; the temperature of the slurry tank is 90-100 ℃; the sizing speed is 10-50 m/min.
The invention has the following positive effects: (1) compared with the conventional polyester jean fabric, the cation modified polyester jean fabric is more energy-saving and environment-friendly, is soft and comfortable, and has good pilling resistance and moisture absorption. (2) The cationic modified terylene denim fabric adopts a dyeing and sizing combined process to directly dye and size the cationic modified terylene/viscose blended yarn, and then is woven with undyed cationic modified terylene to form the denim fabric, so that the process is short, and color defects are avoided.
Detailed Description
(example 1)
The warp yarn adopted by the cationic modified polyester denim fabric is a dyed cationic modified polyester/viscose (65/35) blended yarn, and the weft yarn adopted by the cationic modified polyester denim fabric is undyed cationic modified polyester.
The preparation method of the cation modified polyester jean fabric provided by the embodiment comprises the following steps:
firstly, blending the cation modified terylene and the viscose according to a blending ratio of 65 percent to 35 percent to prepare blended yarn, and then warping the blended yarn.
And secondly, performing a dyeing-sizing combined process on the warped yarns to obtain warps.
In the dyeing and sizing combined process, the formula of the dye solution is as follows: 2.0g/L of cationic dye, 5g/L of anhydrous sodium sulphate and 1.5g/L of glacial acetic acid; the dye vat temperature was 98 ℃.
In the dyeing and sizing combined process, the sizing agent formula is as follows: starch slurry 75g/L, PVA slurry 15g/L, paraffin 3g/L, stabilizer 3 g/L; the temperature of the slurry tank is 95 ℃; the sizing speed was 30 m/min.
And thirdly, weaving the warp yarn obtained in the step two and undyed cation modified polyester serving as weft yarn into grey cloth by adopting 3/1 right twill weave.
Fourthly, sequentially carrying out singeing finishing, desizing finishing and preshrinking finishing on the grey cloth woven in the third step to obtain the cation modified polyester jean fabric.

Claims (5)

1. A cation modified terylene jean fabric is characterized in that: the warp yarn is dyed cation modified terylene/viscose blended yarn, and the weft yarn is undyed cation modified terylene.
2. The cationic modified polyester denim fabric according to claim 1, characterized in that: in the warp, the blending ratio of the cation modified polyester to the viscose is (60-70%) to (30-40%).
3. The preparation method of the cation modified polyester denim fabric according to claim 1 or 2, characterized by comprising the following steps: firstly, preparing blended yarns from cation modified terylene and viscose according to a blending proportion, and then warping the blended yarns; secondly, dyeing and sizing combined process is carried out on the warped yarns to obtain warps; thirdly, weaving the warp yarn obtained in the second step and undyed cation modified polyester into grey cloth; fourthly, after-finishing the grey cloth woven in the third step to obtain the cation modified polyester jean fabric.
4. The preparation method of the cation modified polyester denim fabric according to claim 3, characterized in that: in the dyeing and sizing combined process of the step II, the formula of the dyeing solution is as follows: 0.5-5.0 g/L of cationic dye, 3-10 g/L of anhydrous sodium sulphate and 0.5-3 g/L of glacial acetic acid; the temperature of the dye vat is 90-110 ℃.
5. The preparation method of the cation modified polyester denim fabric according to claim 3, characterized in that: in the dyeing and sizing combined process of the second step, the sizing agent formula is as follows: 50-100 g/L, PVA g of starch slurry 10-20 g/L, 1-5 g/L of paraffin and 1-5 g/L of stabilizer; the temperature of the slurry tank is 90-100 ℃; the sizing speed is 10-50 m/min.
CN202210725764.1A 2022-06-24 2022-06-24 Cationic modified polyester jean fabric and preparation method thereof Pending CN114959996A (en)

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CN102650089A (en) * 2011-02-24 2012-08-29 东丽纤维研究所（中国）有限公司 Jeans elastic fabric and method for producing same
CN104278410A (en) * 2014-08-14 2015-01-14 江苏德利恒棉业有限公司 Acrylic and Richcel fiber florescent denim and weaving method thereof
US20160230316A1 (en) * 2013-10-04 2016-08-11 Tejidos Royo, S.L. Denim fabric with fire-retardant properties and process of dyeing the warp with indigo blue dye
CN107460600A (en) * 2017-08-18 2017-12-12 佛山市捷邦纺织有限公司 A kind of woven denim fabric of slim four sides elasticity and its weaving process
CN108004642A (en) * 2017-11-22 2018-05-08 海盐县硕创服装研究所 A kind of cooling ventilating type summer clothing denim fabric
CN108385405A (en) * 2018-02-22 2018-08-10 黑牡丹纺织有限公司 There is the indigo denim fabric production method that the age is felt
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CN110016748A (en) * 2019-03-13 2019-07-16 广东前进牛仔布有限公司 A kind of denim fabric and its technique using non-cotton raw material
WO2021115353A1 (en) * 2019-12-13 2021-06-17 侯宇昊 Denim jean fabric cloth and method for manufacture thereof
CN213925234U (en) * 2020-11-24 2021-08-10 韶关市北纺智造科技有限公司 Double-color jean fabric
CN113481740A (en) * 2021-07-01 2021-10-08 韶关市北纺智造科技有限公司 Dyed jean fabric and preparation method thereof

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CN104278410A (en) * 2014-08-14 2015-01-14 江苏德利恒棉业有限公司 Acrylic and Richcel fiber florescent denim and weaving method thereof
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CN108642643A (en) * 2018-06-20 2018-10-12 刘振波 A kind of production method of sizing-dyeing machine environment-friendly dye dyeing denim
CN110016748A (en) * 2019-03-13 2019-07-16 广东前进牛仔布有限公司 A kind of denim fabric and its technique using non-cotton raw material
WO2021115353A1 (en) * 2019-12-13 2021-06-17 侯宇昊 Denim jean fabric cloth and method for manufacture thereof
CN213925234U (en) * 2020-11-24 2021-08-10 韶关市北纺智造科技有限公司 Double-color jean fabric
CN113481740A (en) * 2021-07-01 2021-10-08 韶关市北纺智造科技有限公司 Dyed jean fabric and preparation method thereof

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