CN114904295A - Efficient energy-saving separation and recovery system of extraction centrifuge in resin production - Google Patents

Efficient energy-saving separation and recovery system of extraction centrifuge in resin production Download PDF

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Publication number
CN114904295A
CN114904295A CN202210668070.9A CN202210668070A CN114904295A CN 114904295 A CN114904295 A CN 114904295A CN 202210668070 A CN202210668070 A CN 202210668070A CN 114904295 A CN114904295 A CN 114904295A
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China
Prior art keywords
extraction
recovery
main pipeline
pipeline
centrifuge
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CN202210668070.9A
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Inventor
刘秉臣
王志武
王鹏
李乃杰
曹水
刘强
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Shandong Minghua New Material Co ltd
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Shandong Minghua New Material Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/04Solvent extraction of solutions which are liquid
    • B01D11/0492Applications, solvents used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D11/00Solvent extraction
    • B01D11/04Solvent extraction of solutions which are liquid
    • B01D11/0476Moving receptacles, e.g. rotating receptacles
    • B01D11/048Mixing by counter-current streams provoked by centrifugal force, in rotating coils or in other rotating spaces
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

The invention discloses an efficient energy-saving separation and recovery system of an extraction centrifuge in resin production, which comprises a waste salt solution main pipeline, a nitrogen main pipeline, a heavy phase main pipeline, a recovery main pipeline and a plurality of extraction centrifuges, wherein the extraction centrifuges are arranged in parallel; the last first storage tank that is connected with of terminal extraction centrifuge, the bottom access connection of terminal extraction centrifuge has extractant storage jar, and the upper portion exit linkage of terminal extraction centrifuge has the extractant main line, and the extractant main line is connected with a plurality of extraction centrifuge. By adopting the structure, the organic solvent and the salt solution which are used as harmful substances in the traditional process are separated and recovered, so that the problems of high cost, environmental pollution and resource waste caused by the separation of waste salt solution and organic solvent are solved, the separated solution has high purity and higher recycling value, the treatment cost of the whole system is greatly reduced, and the enterprise benefit is increased.

Description

Efficient and energy-saving separation and recovery system for extraction centrifuge in resin production
Technical Field
The invention relates to the technical field of separation and recycling, in particular to an efficient and energy-saving separation and recycling system of an extraction centrifuge in resin production.
Background
With the tightening of the national policy on environmental protection, the industrial waste brine is not allowed to be directly discharged, and the zero emission technology becomes an important way for breaking the contradiction between the industrial development and the water resources and the environment. The developed zero-emission process removes organic substances to a certain extent by methods such as ion exchange, biochemistry, membrane method and the like, and realizes salt preparation by purifying high-concentration mother liquor by discharging, but brings about the problem of mother liquor disposal. In addition, the existing near-zero emission project, the produced salt still belongs to dangerous waste, enterprises need solutions for low-cost disposal, and the market demand is urgent. Therefore, the treatment technology research is carried out aiming at the two aspects of concentrated solution and salt, and the zero-emission business range is widened. For several different treatment technologies of high-salt and high-organic matter wastewater, electrodialysis has the defects of high investment, high operation cost and incapability of meeting the recycling standard of produced water. The forward osmosis process is complex, the technology is immature and the energy consumption is high. The biochemical and advanced oxidation methods aim at the problems of low efficiency and high consumption of the high-salt wastewater due to the adsorption of the activated carbon, and the adsorbed activated carbon also needs hazardous waste disposal and has high cost. And organic matters cannot be completely removed, so that the final inorganic salt product does not reach the standard. There are also reports in the prior art relating to the removal of organic matter from industrial wastewater. Patent CN104190697A relates to a method for recycling hazardous wastes containing water-soluble salts and organic matters, and discloses a method for removing organic matters from hazardous wastes containing water-soluble salts and organic matters through high-temperature desorption, dissolution filtration and residue incineration.
Disclosure of Invention
The invention aims to provide an efficient and energy-saving separation and recovery system for an extraction centrifuge in resin production, which separates and recovers an organic solvent and a salt solution which are harmful substances in the traditional process, solves the problems of high cost, environmental pollution and resource waste caused by the separation of a waste salt solution and the organic solvent, has high purity of the separated solution and higher recycling value, greatly reduces the treatment cost of the whole system, and increases the enterprise benefit.
In order to achieve the purpose, the invention provides an efficient and energy-saving separation and recovery system of an extraction centrifuge in resin production, which comprises a waste salt solution main pipeline, a nitrogen main pipeline, a heavy phase main pipeline, a recovery main pipeline and a plurality of extraction centrifuges, wherein the plurality of extraction centrifuges are arranged in parallel, and each extraction centrifuge is connected with the recovery main pipeline, the heavy phase main pipeline, the nitrogen main pipeline and the waste salt solution main pipeline;
the extraction centrifuge at the tail end is connected with a first storage tank, the first storage tank is connected with the end part of the waste salt solution main pipeline, an extracting agent storage tank is connected with an inlet at the bottom of the extraction centrifuge at the tail end, an extracting agent main pipeline is connected with an outlet at the upper part of the extraction centrifuge at the tail end, and the extracting agent main pipeline is connected with a plurality of extraction centrifuges;
the heavy phase main pipeline is connected with a second storage tank, and the recovery main pipeline is connected with a recovery tank. Preferably, the front end part of the waste salt solution main pipeline is provided with a raw material inlet adjusting valve and a raw material inlet stop valve, and the raw material inlet stop valve is arranged at the rear end of the raw material inlet adjusting valve.
Preferably, the main waste salt solution pipeline is connected with a raw material inlet of the extraction centrifuge through a waste salt solution branch pipeline, and the main waste salt solution pipeline is connected with an extractant inlet of the extraction centrifuge through an extractant branch pipeline.
Preferably, the main nitrogen pipeline is connected with a nitrogen inlet of the extraction centrifuge through a branch nitrogen pipeline.
Preferably, the heavy phase main pipeline is connected with the heavy phase outlet of the extraction centrifuge through a heavy phase branch pipeline.
Preferably, the main recovery pipeline is connected with the extraction centrifuge through a branch recovery pipeline.
Preferably, the waste salt solution branch line, the extractant branch line, the nitrogen branch line, the heavy phase branch line and the recovery branch line are all provided with control valves.
Preferably, the extraction centrifuge at the tail end is connected with the first storage tank through a light phase pipeline, and a light phase outlet cut-off valve is arranged on the light phase pipeline.
Preferably, the extraction centrifuge at the tail end is connected with the extractant storage tank through an extractant inlet pipeline, and an extractant inlet cut-off valve is arranged on the extractant inlet pipeline.
Preferably, the outlet end of the first storage tank, the outlet end of the second storage tank and the outlet end of the recovery tank are connected with delivery pumps.
Therefore, the efficient energy-saving separation and recovery system for the extraction centrifuge in the resin production, which adopts the structure, separates and recovers the organic solvent and the salt solution which are harmful substances in the traditional process, solves the problems of high cost, environmental pollution and resource waste caused by the separation of the waste salt solution and the organic solvent, has high solution purity after separation and higher recycling value, greatly reduces the treatment cost and increases the enterprise benefit.
The technical solution of the present invention is further described in detail by the accompanying drawings and embodiments.
Drawings
FIG. 1 is a schematic flow diagram of an embodiment of an efficient energy-saving separation and recovery system for an extraction centrifuge in resin production according to the present invention.
Detailed Description
The technical solution of the present invention is further illustrated by the accompanying drawings and examples.
Unless defined otherwise, technical or scientific terms used herein shall have the ordinary meaning as understood by one of ordinary skill in the art to which this invention belongs. The use of "first," "second," and similar terms in the present application do not denote any order, quantity, or importance, but rather the terms are used to distinguish one element from another. The word "comprising" or "comprises", and the like, means that the element or item listed before the word covers the element or item listed after the word and its equivalents, but does not exclude other elements or items. The terms "connected" or "coupled" and the like are not restricted to physical or mechanical connections, but may include electrical connections, whether direct or indirect. "upper", "lower", "left", "right", and the like are used merely to indicate relative positional relationships, and when the absolute position of the object being described is changed, the relative positional relationships may also be changed accordingly.
Examples
Fig. 1 is a schematic flow diagram of an embodiment of an efficient energy-saving separation and recovery system for an extraction centrifuge in resin production, and as shown in the drawing, the efficient energy-saving separation and recovery system for an extraction centrifuge in resin production provided by the invention comprises a waste salt solution main pipeline 1, a nitrogen main pipeline 2, a heavy phase main pipeline 3, a recovery main pipeline 4 and a plurality of extraction centrifuges 5, wherein the plurality of extraction centrifuges 5 are arranged in parallel, and each extraction centrifuge 5 is connected with the recovery main pipeline 4, the heavy phase main pipeline 3, the nitrogen main pipeline 2 and the waste salt solution main pipeline 1; the extraction centrifuge 5 at the tail end is connected with a first storage tank 6, the first storage tank 6 is connected with the end part of a waste salt solution main pipeline 1, an extractant storage tank 7 is connected to an inlet at the bottom of the extraction centrifuge 5 at the tail end, an extractant main pipeline 8 is connected to an outlet at the upper part of the extraction centrifuge 5 at the tail end, and the extractant main pipeline 8 is connected with a plurality of extraction centrifuges 5; the heavy phase main pipeline 3 is connected with a second storage tank 9, and the recovery main pipeline 4 is connected with a recovery tank 10. The extraction separation is carried out by arranging multistage countercurrent contact, the extracted light-phase component (salt solution) enters a first storage tank for storage, when the light-phase component in the first storage tank still contains a small amount of organic solvent through detection, namely the light-phase component is unqualified, the light-phase component can enter a system again for extraction until the content of the organic solvent in the light-phase component meets the process requirements, if the light-phase component is qualified, the salt solution can be recovered through a delivery pump, and the extracted heavy-phase component (extractant and organic solvent) enters a second storage tank for storage.
The front end of the waste salt solution main pipeline 1 is provided with a raw material inlet regulating valve 11 and a raw material inlet stop valve 12, and the raw material inlet stop valve 12 is arranged at the rear end of the raw material inlet regulating valve 11. The main waste salt solution line 1 is connected with a raw material inlet of the extraction centrifuge 5 through a waste salt solution branch line 13, and the main waste salt solution line 1 is connected with an extractant inlet of the extraction centrifuge 5 through an extractant branch line 14.
The nitrogen main line 2 is connected to the nitrogen inlet of the extraction centrifuge 5 through a nitrogen branch line 15.
The main heavy phase line 3 is connected to the heavy phase outlet of the extractor centrifuge 5 via a heavy phase branch line 16.
The main recovery line 4 is connected to the extraction centrifuge 5 via a recovery branch line 17.
The waste salt solution branch line 13, the extractant branch line 14, the nitrogen branch line 15, the heavy phase branch line 16 and the recovery branch line 17 are all provided with control valves 18. The inlet and outlet of each extraction centrifuge are provided with control valves, when one or more extraction centrifuges are in fault, the control valves of the inlet and outlet of the extraction centrifuges are closed, the faulty extraction centrifuges can be cut out from the system, the whole line shutdown is not needed, the whole continuous production is not influenced, and the overhaul of the faulty extraction centrifuges is not influenced. When the extraction centrifugal system is integrally stopped for maintenance, nitrogen can be introduced to replace two phases in the equipment, the maintenance safety is ensured, and meanwhile, the residual solution in the centrifuge equipment body can be temporarily recovered. The inlet and outlet of the extraction centrifuge are provided with cut-off valves, and when the liquid level of the storage tank is too high or the delivery pump breaks down, the extraction centrifuge automatically closes the cut-off valves to ensure safety.
The extraction centrifuge 5 at the tail end is connected with the first storage tank 6 through a light phase pipeline 19, and a light phase outlet cut-off valve 20 is arranged on the light phase pipeline 19. The extraction centrifuge 5 at the tail end is connected with the extraction agent storage tank 7 through an extraction agent inlet pipeline 21, an extraction agent inlet cut-off valve 22 is arranged on the extraction agent inlet pipeline 21, and the inlet flow of the extraction agent can be controlled by setting a ratio.
The outlet end of the first storage tank 6, the outlet end of the second storage tank 9 and the outlet end of the recovery tank 10 are connected with a delivery pump 23.
Therefore, the efficient energy-saving separation and recovery system for the extraction centrifuge in the resin production, which adopts the structure, separates and recovers the organic solvent and the salt solution which are harmful substances in the traditional process, solves the problems of high cost, environmental pollution and resource waste caused by the separation of the waste salt solution and the organic solvent, has high solution purity after separation and higher recycling value, greatly reduces the treatment cost and increases the enterprise benefit.
Finally, it should be noted that: the above embodiments are only intended to illustrate the technical solution of the present invention and not to limit the same, and although the present invention is described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that: modifications and equivalents may be made to the invention without departing from the spirit and scope of the invention.

Claims (10)

1. An extraction centrifuge is energy-efficient separation recovery system in resin production which characterized in that:
the system comprises a waste salt solution main pipeline, a nitrogen main pipeline, a heavy phase main pipeline, a recovery main pipeline and a plurality of extraction centrifuges, wherein the extraction centrifuges are arranged in parallel, and each extraction centrifuge is connected with the recovery main pipeline, the heavy phase main pipeline, the nitrogen main pipeline and the waste salt solution main pipeline;
the extraction centrifuge at the tail end is connected with a first storage tank, the first storage tank is connected with the end part of the waste salt solution main pipeline, an extracting agent storage tank is connected with an inlet at the bottom of the extraction centrifuge at the tail end, an extracting agent main pipeline is connected with an outlet at the upper part of the extraction centrifuge at the tail end, and the extracting agent main pipeline is connected with a plurality of extraction centrifuges;
the heavy phase main pipeline is connected with a second storage tank, and the recovery main pipeline is connected with a recovery tank.
2. The system for efficiently and energy-saving separation and recovery of the extraction centrifuge in resin production according to claim 1 is characterized in that: the front end part of the waste salt solution main pipeline is provided with a raw material inlet adjusting valve and a raw material inlet stop valve, and the raw material inlet stop valve is arranged at the rear end of the raw material inlet adjusting valve.
3. The system for efficiently and energy-saving separation and recovery of resin production by an extraction centrifuge as claimed in claim 2, wherein: the waste salt solution main pipeline is connected with a raw material inlet of the extraction centrifugal machine through a waste salt solution branch pipeline, and the waste salt solution main pipeline is connected with an extracting agent inlet of the extraction centrifugal machine through an extracting agent branch pipeline.
4. The system for efficiently and energy-saving separation and recovery of resin production by an extraction centrifuge as claimed in claim 3, is characterized in that: the nitrogen main pipeline is connected with a nitrogen inlet of the extraction centrifuge through a nitrogen branch pipeline.
5. The system of claim 4 for efficient and energy-saving separation and recovery of resin in the production of extraction centrifuges, which is characterized in that: and the heavy phase main pipeline is connected with a heavy phase outlet of the extraction centrifuge through a heavy phase branch pipeline.
6. The system of claim 5 for efficient and energy-saving separation and recovery of resin in the production of extraction centrifuges, which is characterized in that: the recovery main pipeline is connected with the extraction centrifugal machine through a recovery branch pipeline.
7. The system of claim 6 for efficient and energy-saving separation and recovery of resin in the production of extraction centrifuges, which is characterized in that: and the waste salt solution branch pipeline, the extractant branch pipeline, the nitrogen branch pipeline, the heavy phase branch pipeline and the recovery branch pipeline are all provided with control valves.
8. The system of claim 7 for efficient and energy-saving separation and recovery of resin in the production of extraction centrifuges, which is characterized in that: the extraction centrifuge at the tail end is connected with the first storage tank through a light phase pipeline, and a light phase outlet cut-off valve is arranged on the light phase pipeline.
9. The system of claim 8 for efficient and energy-saving separation and recovery of resin in the production of extraction centrifuges, which is characterized in that: the extraction centrifuge at the tail end is connected with the extraction agent storage tank through an extraction agent inlet pipeline, and an extraction agent inlet stop valve is arranged on the extraction agent inlet pipeline.
10. The system for efficiently and energy-saving separation and recovery of resin production by an extraction centrifuge as claimed in claim 9, is characterized in that: the outlet end of the first storage tank, the outlet end of the second storage tank and the outlet end of the recovery tank are connected with delivery pumps.
CN202210668070.9A 2022-06-14 2022-06-14 Efficient energy-saving separation and recovery system of extraction centrifuge in resin production Pending CN114904295A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4434028A (en) * 1981-04-17 1984-02-28 Critical Fluid Systems, Inc. Apparatus for removing organic contaminants from inorganic-rich mineral solids
CN101927984A (en) * 2009-06-22 2010-12-29 瓮福(集团)有限责任公司 Phosphoric acid purification device
CN106698575A (en) * 2017-01-12 2017-05-24 北京濮源新材料技术研究院(普通合伙) Method for recovering organic solvent from maleic anhydride wastewater
CN106831472A (en) * 2017-03-03 2017-06-13 北京宇极科技发展有限公司 A kind of DMF salt bearing liquid wastes recovery process and system
CN107601791A (en) * 2017-11-15 2018-01-19 新乡市双诚环保设备有限公司 High salt organic waste water resource reclaim and handling process
CN108101843A (en) * 2018-02-01 2018-06-01 湖南正清制药集团股份有限公司 A kind of Sinomenine and its circular centrifugal preparation method
CN210163166U (en) * 2019-07-04 2020-03-20 江西天宇化工有限公司 Production system for reducing organic impurities in salt-containing wastewater
CN216614332U (en) * 2022-01-27 2022-05-27 聊城鲁西甲胺化工有限公司 High concentration salt and DMF waste water's processing system and waste water treatment line

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4434028A (en) * 1981-04-17 1984-02-28 Critical Fluid Systems, Inc. Apparatus for removing organic contaminants from inorganic-rich mineral solids
CN101927984A (en) * 2009-06-22 2010-12-29 瓮福(集团)有限责任公司 Phosphoric acid purification device
CN106698575A (en) * 2017-01-12 2017-05-24 北京濮源新材料技术研究院(普通合伙) Method for recovering organic solvent from maleic anhydride wastewater
CN106831472A (en) * 2017-03-03 2017-06-13 北京宇极科技发展有限公司 A kind of DMF salt bearing liquid wastes recovery process and system
CN107601791A (en) * 2017-11-15 2018-01-19 新乡市双诚环保设备有限公司 High salt organic waste water resource reclaim and handling process
CN108101843A (en) * 2018-02-01 2018-06-01 湖南正清制药集团股份有限公司 A kind of Sinomenine and its circular centrifugal preparation method
CN210163166U (en) * 2019-07-04 2020-03-20 江西天宇化工有限公司 Production system for reducing organic impurities in salt-containing wastewater
CN216614332U (en) * 2022-01-27 2022-05-27 聊城鲁西甲胺化工有限公司 High concentration salt and DMF waste water's processing system and waste water treatment line

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