CN114874835A - 一种高速拉拔镀锌细丝的水性润滑剂及其制备方法 - Google Patents
一种高速拉拔镀锌细丝的水性润滑剂及其制备方法 Download PDFInfo
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- 239000000314 lubricant Substances 0.000 title claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 40
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 19
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000005639 Lauric acid Substances 0.000 claims abstract description 16
- 235000019482 Palm oil Nutrition 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 16
- 239000002540 palm oil Substances 0.000 claims abstract description 16
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 10
- LXAHHHIGZXPRKQ-UHFFFAOYSA-N 5-fluoro-2-methylpyridine Chemical compound CC1=CC=C(F)C=N1 LXAHHHIGZXPRKQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims abstract description 8
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- 238000004806 packaging method and process Methods 0.000 claims abstract description 8
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 238000000034 method Methods 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- -1 alkenyl sulfonate Chemical compound 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical group [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 3
- GIWKOZXJDKMGQC-UHFFFAOYSA-L lead(2+);naphthalene-2-carboxylate Chemical group [Pb+2].C1=CC=CC2=CC(C(=O)[O-])=CC=C21.C1=CC=CC2=CC(C(=O)[O-])=CC=C21 GIWKOZXJDKMGQC-UHFFFAOYSA-L 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 3
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims description 3
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- RXMGGVUEZJFBPH-UHFFFAOYSA-J tetrasodium 2-hydroxyethyl phosphate Chemical compound OCCOP(=O)([O-])[O-].[Na+].[Na+].[Na+].[Na+].OCCOP(=O)([O-])[O-] RXMGGVUEZJFBPH-UHFFFAOYSA-J 0.000 claims description 2
- 229940045995 etidronate tetrasodium Drugs 0.000 abstract description 8
- 239000002699 waste material Substances 0.000 abstract description 3
- 208000032544 Cicatrix Diseases 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 231100000241 scar Toxicity 0.000 description 2
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- 238000005491 wire drawing Methods 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
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- 239000010959 steel Substances 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
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- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/10—Carboxylix acids; Neutral salts thereof
- C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
- C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
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- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
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- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
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- C10M2215/222—Triazines
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- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
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- C10M2219/06—Thio-acids; Thiocyanates; Derivatives thereof
- C10M2219/062—Thio-acids; Thiocyanates; Derivatives thereof having carbon-to-sulfur double bonds
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Abstract
本发明公开了一种高速拉拔镀锌细丝的水性润滑剂及其制备方法，润滑剂包括月桂酸15～35％，棕榈油3～20％，阴离子表面活性剂2～15％，EDTA二钠0.5～1.5％，羟乙磷酸四钠0.5～2.0％，极压剂2～8％，二氯异氰尿酸钠0.3～1.2％，余下为去离子水至100％。制备方法包括将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌20分钟；将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至70℃，再搅拌20分钟；停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌30分钟后，冷却至室温包装。本发明主要原材料来源广泛，制得的水性润滑剂价格合适，且储存、运输安全；润滑剂制备方法简捷，一步制备，且无三废排放。
Description
技术领域
本发明涉及涉及金属加工领域，具体涉及一种高速拉拔镀锌细丝的水性润滑剂及其制备方法，尤其涉及镀锌丝拉拔速度≤150米/秒、拉拔细丝≤2毫米的拔丝工艺。
背景技术
现有技术中，镀锌拔丝生产中会产生如下问题：1、模具磨损严重；2、产品表面表面不够光洁；3、拔出的细丝经常有伤痕；4、原来使用的润滑剂成本高。
发明内容
针对上述问题，本发明提供一种高速拉拔镀锌细丝的水性润滑剂及其制备方法。
为实现上述目的，本发明采用以下技术方案实现：
一种高速拉拔镀锌细丝的水性润滑剂，包括如下重量百分比的原料：月桂酸15～35％，棕榈油3～20％，阴离子表面活性剂2～15％，EDTA二钠0.5～1.5％，羟乙磷酸四钠0.5～2.0％，极压剂2～8％，二氯异氰尿酸钠0.3～1.2％，余下为去离子水，合计百分之百。
作为上述方案的优选，所述阴离子表面活性剂为十二烷基苯磺酸钠、十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠或α-烯基磺酸钠。
作为上述方案的优选，所述极压剂为环烷酸铅、偏硼酸钠、二丁基硫代氨基甲酸锑、二丁基硫代氨基甲酸铅、二烷基二硫代氨基甲酸钼或三聚磷酸钠。
一种高速拉拔镀锌细丝的水性润滑剂的其制备方法，包括以下步骤：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌15～20分钟；
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至60～70℃，再搅拌15～20分钟；
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌20～30分钟后，冷却至室温包装。
作为上述方案的优选，步骤三中制得的润滑剂，在10～35℃为乳白色粘稠液体，固含量≥30％，5％水溶液PH值为8.0～10.0，5％水溶液表面张力≤30mN/m。
由于具有上述结构，本发明的有益效果在于：
本发明的主要原材料来源广泛，制得的水性润滑剂价格合适。而且本发明的润滑剂制备方法简捷，一步制备，且无三废排放。同时本发明的润滑剂为水溶液，储存、运输安全。
具体实施方式
下面将对本发明的技术方案进行清楚、完整地描述。基于本发明中的实施例，本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例，都属于本发明保护的范围。
本申请提供一种高速拉拔镀锌细丝的水性润滑剂，包括如下重量百分比的原料：月桂酸15～35％，棕榈油3～20％，阴离子表面活性剂2～15％，EDTA二钠0.5～1.5％，羟乙磷酸四钠0.5～2.0％，极压剂2～8％，二氯异氰尿酸钠0.3～1.2％，余下为去离子水至100％。
在本实施例中，所述阴离子表面活性剂为十二烷基苯磺酸钠、十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠或α-烯基磺酸钠。所述极压剂为环烷酸铅、偏硼酸钠、二丁基硫代氨基甲酸锑、二丁基硫代氨基甲酸铅、二烷基二硫代氨基甲酸钼或三聚磷酸钠。
本申请还提供一种高速拉拔镀锌细丝的水性润滑剂的其制备方法，包括以下步骤：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌15～20分钟；
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至60～70℃，再搅拌15～20分钟；
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌20～30分钟后，冷却至室温包装。
制得的润滑剂性能：外观：乳白色粘稠液体(10～35℃)；固含量：≥30％；水溶性：常温下与水任意比例混溶；5％水溶液PH：8.0～10.0；5％水溶液PB(Kg)：≥80；5％水溶液表面张力(mN/m)：≤30。
实施例一：
原料组成(重量％)月桂酸20，棕榈油10，阴离子表面活性剂5，EDTA二钠1，羟乙磷酸四钠1.2，极压剂3，二氯异氰尿酸钠0.3，去离子水59.5。
制备过程如下：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌20分钟；
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至70℃，再搅拌20分钟；
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌30分钟后，冷却至室温包装。
实施例二：
原料组成(重量％)月桂酸25，棕榈油8，阴离子表面活性剂4，EDTA二钠0.8，羟乙磷酸四钠1，极压剂5，二氯异氰尿酸钠0.5，去离子水55.7。
制备过程如下：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌20分钟；
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至70℃，再搅拌20分钟；
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌30分钟后，冷却至室温包装。
实施例三：
原料组成(重量％)月桂酸30，棕榈油5，阴离子表面活性剂3，EDTA二钠0.6，羟乙磷酸四钠0.8，极压剂7，二氯异氰尿酸钠0.8，去离子水52.8。制备过程如下：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌20分钟。
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至70℃，再搅拌20分钟。
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌30分钟后，冷却至室温包装。
实施例四：
原料组成(重量％)月桂酸32，棕榈油3，阴离子表面活性剂2，EDTA二钠0.5，羟乙磷酸四钠0.6，极压剂6，二氯异氰尿酸钠0.6，去离子水55.3。制备过程如下：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌20分钟。
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至70℃，再搅拌20分钟。
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌30分钟后，冷却至室温包装。
本申请的一种高速拉拔镀锌细丝的水性润滑剂及其制备方法，解决了镀锌拔丝生产中的1、模具磨损严重；2、产品表面表面不够光洁；3、拔出的细丝经常有伤痕；4、原来使用的润滑剂成本高，等问题。而且主要原材料来源广泛，制得的水性润滑剂价格合适；润滑剂制备方法简捷，一步制备，且无三废排放；润滑剂为水溶液，储存、运输安全。本申请除了应用于镀锌细丝的拉拔外，也可以应用于普通钢丝的拉拔过程。
以上仅为本发明的优选实施例而已，并不用于限制本发明，对于本领域的技术人员来说，本发明可以有各种更改和变化。凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。
Claims (5)
1.一种高速拉拔镀锌细丝的水性润滑剂，其特征在于：包括如下重量百分比的原料：月桂酸15～35％，棕榈油3～20％，阴离子表面活性剂2～15％，EDTA二钠0.5～1.5％，羟乙磷酸四钠0.5～2.0％，极压剂2～8％，二氯异氰尿酸钠0.3～1.2％，余下为去离子水，合计百分之百。
2.根据权利要求1所述的一种高速拉拔镀锌细丝的水性润滑剂，其特征在于：所述阴离子表面活性剂为十二烷基苯磺酸钠、十二烷基硫酸钠、脂肪醇聚氧乙烯醚硫酸钠或α-烯基磺酸钠。
3.根据权利要求1所述的一种高速拉拔镀锌细丝的水性润滑剂，其特征在于：所述极压剂为环烷酸铅、偏硼酸钠、二丁基硫代氨基甲酸锑、二丁基硫代氨基甲酸铅、二烷基二硫代氨基甲酸钼或三聚磷酸钠。
4.根据权利要求1所述的一种高速拉拔镀锌细丝的水性润滑剂的其制备方法，其特征在于：包括以下步骤：
步骤一、将计量好的月桂酸、棕榈油、阴离子表面活性剂，加入搪瓷搅拌釜中搅拌15～20分钟；
步骤二、将计量好的去离子水加入步骤一的反应釜中，边搅拌边加热至60～70℃，再搅拌15～20分钟；
步骤三、停止加热，将计量好的EDTA、羟乙磷酸四钠、极压剂、二氯异氰尿酸钠加入步骤二的反应釜中，搅拌20～30分钟后，冷却至室温包装。
5.根据权利要求4所述的一种高速拉拔镀锌细丝的水性润滑剂的其制备方法，其特征在于：步骤三中制得的润滑剂，在10～35℃为乳白色粘稠液体，固含量≥30％，5％水溶液PH值为8.0～10.0，5％水溶液表面张力≤30mN/m。
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| WO2000056845A1 (fr) * | 1999-03-19 | 2000-09-28 | Yoshitomi Fine Chemicals, Ltd. | Composition d'aide au travail du metal, contenant du thiodipropionate de dialkyle, et procede de travail du metal |
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