CN114835084A - Hydrogen generation physical therapy material bag and preparation method thereof - Google Patents
Hydrogen generation physical therapy material bag and preparation method thereof Download PDFInfo
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 96
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 96
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 238000000554 physical therapy Methods 0.000 title claims abstract description 56
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 title claims description 82
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 93
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 68
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 65
- 238000006243 chemical reaction Methods 0.000 claims description 50
- 239000010455 vermiculite Substances 0.000 claims description 37
- 229910052902 vermiculite Inorganic materials 0.000 claims description 37
- 235000019354 vermiculite Nutrition 0.000 claims description 37
- 239000000292 calcium oxide Substances 0.000 claims description 34
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 34
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 33
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 33
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 33
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 31
- 235000011152 sodium sulphate Nutrition 0.000 claims description 31
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 30
- 239000002994 raw material Substances 0.000 claims description 20
- 239000011261 inert gas Substances 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 9
- 238000002560 therapeutic procedure Methods 0.000 claims description 9
- 238000011049 filling Methods 0.000 claims description 6
- 238000004806 packaging method and process Methods 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000004745 nonwoven fabric Substances 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 229920006255 plastic film Polymers 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 2
- 230000036541 health Effects 0.000 abstract description 5
- 235000012255 calcium oxide Nutrition 0.000 description 27
- 150000002431 hydrogen Chemical class 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 12
- 239000007789 gas Substances 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000012856 packing Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 230000006907 apoptotic process Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 210000004027 cell Anatomy 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 239000012466 permeate Substances 0.000 description 3
- 230000029058 respiratory gaseous exchange Effects 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 235000011121 sodium hydroxide Nutrition 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 208000017520 skin disease Diseases 0.000 description 2
- 230000004083 survival effect Effects 0.000 description 2
- 229910017090 AlO 2 Inorganic materials 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 201000009030 Carcinoma Diseases 0.000 description 1
- 206010052360 Colorectal adenocarcinoma Diseases 0.000 description 1
- 206010061218 Inflammation Diseases 0.000 description 1
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- 241000699666 Mus <mouse, genus> Species 0.000 description 1
- 241000699670 Mus sp. Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 206010062129 Tongue neoplasm Diseases 0.000 description 1
- 210000000683 abdominal cavity Anatomy 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910001586 aluminite Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
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- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 208000037828 epithelial carcinoma Diseases 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000003832 immune regulation Effects 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 201000002313 intestinal cancer Diseases 0.000 description 1
- 239000007928 intraperitoneal injection Substances 0.000 description 1
- 208000032839 leukemia Diseases 0.000 description 1
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- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- -1 moisture Chemical compound 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 208000002154 non-small cell lung carcinoma Diseases 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
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- 230000018406 regulation of metabolic process Effects 0.000 description 1
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- 239000011734 sodium Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 201000006134 tongue cancer Diseases 0.000 description 1
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- 230000004614 tumor growth Effects 0.000 description 1
- 208000029729 tumor suppressor gene on chromosome 11 Diseases 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
The invention belongs to the technical field of health physiotherapy bags, and particularly relates to a hydrogen generation physiotherapy bag and a preparation method thereof The hydrogen is safely generated in a proper amount to carry out physical therapy on the human body.
Description
Technical Field
The invention belongs to the technical field of health physiotherapy bags, and particularly relates to a hydrogen generation physiotherapy bag and a preparation method thereof.
Background
Hydrogen is a colorless gas having a density lower than that of air and hardly soluble in water, and in recent years, studies on hydrogen and human health have been increasingly conducted, and a medical concept of "hydrogen medicine" has emerged, which studies the effects of hydrogen in various systems of the body and related diseases and the mechanism thereof.
Researches find that hydrogen has the characteristic of selective oxidation resistance, and on the basis of the selective oxidation resistance, the hydrogen also has the treatment effect on oxidative damage, inflammatory reaction, apoptosis, abnormal vascular proliferation and the like in various disease processes, and generally, the hydrogen has the following biological effects: beautifying and anti-aging; regulation of metabolism; immune regulation; repairing tissues; anti-inflammatory; anti-allergic; radiation resistance; resisting fatigue; resistance to cellular variation; resisting apoptosis. Release of scientists in different countries around the worldA plurality of research papers or reports on the relationship between hydrogen and health are published in the journal of Science of the United states, wherein the mixed gas of high-pressure hydrogen and oxygen is reported to successfully inhibit the squamous epithelial carcinoma of the skin of the mouse; high pressure H was discovered in 1978 by Roberts et al, USA 2 Inhalation can inhibit growth of tumor cells and leukemia cells; 2008, Japanese scientists reported that hydrogen-rich electrolyzed water can inhibit the growth of human tongue cancer cells; 2011 Chinese scientists report that intraperitoneal injection of hydrogen-rich saline reduces incidence rate and increases survival rate of radiation-induced lymphoma; in 2015, Runtuwene et al in Japan reported that the survival rate of experimental intestinal cancer mice can be improved by injecting hydrogen water into the abdominal cavity; 2018, China Qin stock team reports that hydrogen has an inhibiting effect on the growth of primary human colorectal adenocarcinoma cells and promotes cancer cell apoptosis; 2018 Hebei university of medical science reports that 60% hydrogen inhalation can inhibit growth of non-small cell lung cancer.
The inhalation of hydrogen with a certain dose has an effect of improving the health of a human body, but the concept of improving the physique by inhaling hydrogen is not widely popularized at present, people are inconvenient to obtain hydrogen for breathing, relevant equipment and methods for producing hydrogen for breathing are also lacked in the market, the hydrogen can be combusted, and unstable hydrogen production and potential safety hazards are easily caused if the control in the hydrogen production process is not standard.
Disclosure of Invention
The invention aims to provide a hydrogen generation physiotherapy material bag and a preparation method thereof, and solves the technical problems of inconvenient, unstable and unsafe production of hydrogen for respiratory physiotherapy in the prior art.
To solve the above technical problem, a first aspect of the present invention is:
the utility model provides a hydrogen takes place physiotherapy material package, including reaction material, reaction material parcel is in the ventilative interior parcel layer that permeates water, the interior parcel is equipped with sealed airtight extranal packing layer outward, reaction material comprises the raw materials of following parts by weight: 20-45 parts of aluminum powder, 40-70 parts of calcium oxide, 0.5-2 parts of sodium hydroxide, 5-20 parts of sodium carbonate, 5-15 parts of vermiculite, 5-10 parts of sodium sulfate and 5-15 parts of activated carbon.
Preferably, the reaction material consists of the following raw materials in parts by weight: 25-40 parts of aluminum powder, 45-65 parts of calcium oxide, 1-1.5 parts of sodium hydroxide, 10-15 parts of sodium carbonate, 8-12 parts of vermiculite, 6-9 parts of sodium sulfate and 8-12 parts of activated carbon.
Preferably, the reaction material consists of the following raw materials in parts by weight: 35 parts of aluminum powder, 55 parts of calcium oxide, 1.2 parts of sodium hydroxide, 12 parts of sodium carbonate, 10 parts of vermiculite, 7.5 parts of sodium sulfate and 10 parts of activated carbon.
Preferably, the inner wrapping layer is made of breathable non-woven fabric, and the outer packaging bag is made of an airtight plastic film or an aluminum film.
Preferably, the vermiculite and the activated carbon are granular.
Preferably, the particle size of the vermiculite and the activated carbon is between 20um and 80 um.
The second aspect of the present invention is:
the preparation method of the hydrogen generation physical therapy material bag comprises the following steps:
(1) weighing the following raw materials in parts by weight: 20-45 parts of aluminum powder, 40-70 parts of calcium oxide, 0.5-2 parts of sodium hydroxide, 5-20 parts of sodium carbonate, 5-15 parts of vermiculite, 5-10 parts of sodium sulfate and 5-15 parts of activated carbon;
(2) uniformly mixing the raw materials in the step (1) to ensure that aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate and sodium sulfate are adhered to vermiculite and activated carbon;
(3) and (3) filling the mixed materials obtained in the step (2) into a water-permeable and air-permeable inner wrapping layer, sealing the inner wrapping bag, and filling into a sealed and air-impermeable outer wrapping bag.
Preferably, in the step (1), the calcium oxide, the sodium hydroxide, the sodium carbonate and the sodium sulfate are all in powder form, and the vermiculite and the activated carbon are in granular form.
Preferably, in the step (2), the aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate, sodium sulfate, vermiculite and activated carbon are mixed in an inert gas environment; in the step (3), the materials mixed in the step (2) are filled into a sealed water-permeable and air-permeable inner wrapping bag in an inert gas environment, and the inner wrapping bag is sealed in the inert gas environment and then filled into a sealed air-impermeable outer wrapping bag.
Compared with the prior art, the invention has the beneficial effects that:
1. this hydrogen generation physiotherapy material package includes reaction material, and reaction material parcel is equipped with the extranal packaging layer in sealed ventilative interior wrapping layer that permeates water, and reaction material comprises aluminite powder, calcium oxide, sodium hydroxide, sodium carbonate, vermiculite, sodium sulfate, active carbon according to corresponding weight portion, and this hydrogen generation physiotherapy material package can be stable, safe produces appropriate amount hydrogen and supplies to breathe to carry out the physiotherapy to the human body. The two salts of sodium carbonate and sodium sulfate in the reaction materials are anhydrous sodium carbonate and anhydrous sodium sulfate, are water-absorbing drying agents and are mainly used for absorbing trace water permeating into a package and preventing materials such as calcium oxide from losing efficacy gradually, so that the hydrogen generation physical therapy bag can have a long shelf life; vermiculite and active carbon in the reaction materials are typical adsorbents, the surface areas of the vermiculite and the active carbon are large, and the loose and porous structure is beneficial to the adhesion of various reaction effective components, so that related reactants can be fully contacted and carry out chemical reaction, the chemical reaction for generating hydrogen is milder and more stable, explosion caused by violent reaction is avoided, and the reaction process is safer.
2. The hydrogen generation physical therapy material bag can be used for steam therapy, released hydrogen is mixed into indoor air for steam therapy, so that skin can be steamed in a hydrogen environment, the effects of beautifying, resisting aging and assisting in treating skin diseases are achieved, and in addition, part of hydrogen is sucked into the body and also has a physical therapy effect.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The following examples were conducted under the conventional conditions or conditions recommended by the manufacturer, and the reagents or instruments used therefor were not indicated by the manufacturer, but were all conventional products available by commercial purchase. In the following examples, 1 part was 1 g.
Example 1
The utility model provides a hydrogen takes place physiotherapy material package, this hydrogen takes place physiotherapy material package includes reaction material, and reaction material parcel is in the ventilative inner wrapping layer that permeates water, and inner wrapping layer is equipped with sealed airtight outer packaging layer outward to the material that can participate in chemical reaction such as oxygen, moisture, carbon dioxide in the prevention air gets into and leads to reaction material inefficacy. Be equipped with the extranal packing layer outside the inner wrapping layer, in this embodiment, the inner wrapping layer is ventilative non-woven fabrics material, and outer packing bag is ventilative plastic film or aluminium membrane, is equipped with the tear line on the outer packing bag for inner wrapping layer and outer packing bag homoenergetic are torn.
In this example, the reaction mass consisted of the following raw materials in parts by weight: 20 parts of aluminum powder, 40 parts of calcium oxide, 0.5 part of sodium hydroxide, 5 parts of sodium carbonate, 5 parts of vermiculite, 5 parts of sodium sulfate and 5 parts of activated carbon. The vermiculite and the active carbon are granular with the grain diameter of 20um-80 um; the aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate and sodium sulfate are powdery.
Vermiculite and active carbon in the reaction materials are typical adsorbents, the surface areas of the vermiculite and the active carbon are large, the loose and porous structures are beneficial to the adhesion of various reaction active ingredients, and related reactants are fully contacted and subjected to chemical reaction in the reaction process. In addition, the sodium carbonate and sodium sulfate in the reaction materials are divided into anhydrous sodium carbonate and anhydrous sodium sulfate, are common water-absorbing drying agents, are mainly used for absorbing trace water permeating into a package, prevent materials such as calcium oxide from losing efficacy gradually, and play a role in participating in partial chemical reaction.
This hydrogen generation physiotherapy material package can use when steaming to treat, and specific use mode is as follows: tearing a small opening from the inner wrapping layer and the outer packaging bag, then immersing the hydrogen generation physical therapy material bag into a container filled with water, so that the water gradually enters the inner wrapping layer, the hydrogen is gradually released through slow reaction, and the released hydrogen is mixed into the air in a steam treatment room, so that the skin can be steamed in a hydrogen environment, and the effects of beautifying, resisting aging and assisting in treating skin diseases are achieved. In addition, part of hydrogen is absorbed into the body, and has physiotherapy effect.
It should be noted that although hydrogen is nontoxic and physiologically inert to human body, if the content of hydrogen in air is increased, anoxic asphyxia will be caused, therefore, the hydrogen generation physiotherapy bag needs to be used according to the standard.
The chemical reaction principle of the reaction materials in the hydrogen generation physical therapy material bag is as follows:
(1) the calcium oxide reacts in water: CaO + H 2 O=Ca(OH) 2 + heat;
(2) reacting the calcium hydroxide generated in the step (1) with sodium carbonate: ca (OH) 2 +Na 2 CO 3 =CaCO 3 +2NaOH；
(3) Reaction principle for hydrogen generation: aluminum powder + strong base > meta-aluminate + hydrogen:
for example: 2Al + Ca (OH) 2 +2H 2 O=Ca(AlO 2 ) 2 +3H 2 Here, the calcium hydroxide produced in step (2) participates in the reaction;
2Al+2NaOH+2H 2 O=2NaAlO 2 +3H 2 here, sodium hydroxide in the reaction mass participates in the reaction.
The preparation method of the hydrogen generation physical therapy material bag comprises the following steps:
(1) weighing the following raw materials in parts by weight: 20 parts of aluminum powder, 40 parts of calcium oxide, 0.5 part of sodium hydroxide, 5 parts of sodium carbonate, 5 parts of vermiculite, 5 parts of sodium sulfate and 5 parts of activated carbon.
The calcium oxide, the sodium hydroxide, the sodium carbonate and the sodium sulfate are all powder, and the aluminum powder, the calcium oxide, the sodium hydroxide, the sodium carbonate and the sodium sulfate adopt raw material powder stored in a sealed way, or are prepared by respectively grinding blocky or granular calcium oxide, sodium hydroxide, sodium carbonate and sodium sulfate in an inert gas environment; the vermiculite and the active carbon are granular and are prepared by crushing and sieving the vermiculite and the active carbon.
The weighing operation is also carried out in an inert gas atmosphere, which may be nitrogen.
(2) And (2) uniformly mixing the raw materials in the step (1) to ensure that the aluminum powder, the calcium oxide, the sodium hydroxide, the sodium carbonate and the sodium sulfate are adhered to the vermiculite and the activated carbon.
In the step, aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate and sodium sulfate are uniformly distributed on vermiculite and activated carbon, so that the phenomenon that reaction is too violent due to accumulation of reaction materials is avoided, and if the reaction is violent, heat can be intensively generated to cause small-amplitude explosion. In addition, in this step, aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate, sodium sulfate, vermiculite and activated carbon are mixed in an inert gas environment.
(3) And (3) filling the mixed materials in the step (2) into a water-permeable and air-permeable inner wrapping layer, sealing the inner wrapping bag, and filling into a sealed and air-impermeable outer wrapping bag.
In the step, the materials mixed in the step (2) are filled into a water-permeable and air-permeable inner wrapping bag in an inert gas environment, and the inner wrapping bag is sealed and then filled into a sealed and air-impermeable outer wrapping bag in the inert gas environment.
Example 2
The utility model provides a hydrogen generation physiotherapy material package, this hydrogen generation physiotherapy material package is the same with the preparation mode of the hydrogen generation physiotherapy material package in embodiment 1, and the difference lies in that the reaction material in this hydrogen generation physiotherapy material package comprises the raw materials of following parts by weight: 25 parts of aluminum powder, 45 parts of calcium oxide, 1 part of sodium hydroxide, 10 parts of sodium carbonate, 8 parts of vermiculite, 6 parts of sodium sulfate and 8 parts of activated carbon.
Example 3
The utility model provides a hydrogen generation physiotherapy material package, this hydrogen generation physiotherapy material package is the same with the preparation mode of the hydrogen generation physiotherapy material package in embodiment 1, and the difference lies in that the reaction material in this hydrogen generation physiotherapy material package comprises the raw materials of following parts by weight: 30 parts of aluminum powder, 50 parts of calcium oxide, 1.2 parts of sodium hydroxide, 13 parts of sodium carbonate, 10 parts of vermiculite, 8 parts of sodium sulfate and 10 parts of activated carbon.
Example 4
The utility model provides a hydrogen generation physiotherapy material package, this hydrogen generation physiotherapy material package is the same with the preparation mode of the hydrogen generation physiotherapy material package in embodiment 1, and the difference lies in that the reaction material in this hydrogen generation physiotherapy material package comprises the raw materials of following parts by weight: 35 parts of aluminum powder, 55 parts of calcium oxide, 1.5 parts of sodium hydroxide, 15 parts of sodium carbonate, 12 parts of vermiculite, 9 parts of sodium sulfate and 12 parts of activated carbon.
Example 5
The utility model provides a hydrogen generation physiotherapy material package, this hydrogen generation physiotherapy material package is the same with the preparation mode of the hydrogen generation physiotherapy material package in embodiment 1, and the difference lies in that the reaction material in this hydrogen generation physiotherapy material package comprises the raw materials of following parts by weight: 40 parts of aluminum powder, 65 parts of calcium oxide, 1.8 parts of sodium hydroxide, 18 parts of sodium carbonate, 13 parts of vermiculite, 9 parts of sodium sulfate and 13 parts of activated carbon.
Example 6
The utility model provides a hydrogen generation physiotherapy material package, this hydrogen generation physiotherapy material package is the same with the preparation mode of the hydrogen generation physiotherapy material package in embodiment 1, and the difference lies in that the reaction material in this hydrogen generation physiotherapy material package comprises the raw materials of following parts by weight: 45 parts of aluminum powder, 70 parts of calcium oxide, 2 parts of sodium hydroxide, 20 parts of sodium carbonate, 15 parts of vermiculite, 10 parts of sodium sulfate and 15 parts of activated carbon.
The hydrogen generation physical therapy material bags in the embodiments 1 to 6 are used one by one to detect the gas generation condition, and in the detection process, a hydrogen gas detector is adopted to detect the hydrogen concentration, and the detection results are shown in the following table 1:
table 1-table for detecting gas production condition of hydrogen generation physical therapy material package:
in table 1, the criteria for gas production completion are: when the hydrogen generation physical therapy material bag does not generate continuous bubbles. In addition, in table 1, the unit of L/(kg · min) is obtained by conversion, and does not indicate the actual gas production rate of the hydrogen generation physiotherapy material package, for example, in example 6, the gas release rate per minute of 50L/(kg · min) is obtained by conversion, which does not represent that the hydrogen generation physiotherapy material package in this example 6 can generate 50L of hydrogen, because the hydrogen generation physiotherapy material package has fewer materials and generates less amount of hydrogen actually, the hydrogen is mainly used for human breathing, and the concentration of hydrogen in a room is within a safe range, and does not generate danger such as explosion.
In table 1, in examples 1 to 6, the gas generation speed is sequentially increased, mainly because in examples 1 to 6, the aluminum powder is gradually added into the physical therapy material package, and the volume of the hydrogen generating physical therapy material package which reacts with water to release hydrogen is in direct proportion to the mass of the aluminum powder in the physical therapy material package; in addition, in examples 1 to 6, the reaction can be promoted by increasing the amounts of the raw materials of calcium oxide, sodium hydroxide and sodium carbonate; in examples 1 to 6, the reaction contact area is increased by increasing the vermiculite and the activated carbon in this order, and the reaction rate can be increased.
It should be noted that, in this document, terms such as "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (9)
1. The utility model provides a hydrogen takes place physiotherapy material package which characterized in that: the reaction material is wrapped in a water-permeable and air-permeable inner wrapping layer, a sealed and airtight outer wrapping layer is arranged outside the inner wrapping layer, and the reaction material is composed of the following raw materials in parts by weight: 20-45 parts of aluminum powder, 40-70 parts of calcium oxide, 0.5-2 parts of sodium hydroxide, 5-20 parts of sodium carbonate, 5-15 parts of vermiculite, 5-10 parts of sodium sulfate and 5-15 parts of activated carbon.
2. The hydrogen generation therapy pack according to claim 1, wherein: the reaction material comprises the following raw materials in parts by weight: 25-40 parts of aluminum powder, 45-65 parts of calcium oxide, 1-1.5 parts of sodium hydroxide, 10-15 parts of sodium carbonate, 8-12 parts of vermiculite, 6-9 parts of sodium sulfate and 8-12 parts of activated carbon.
3. The hydrogen generation therapy pack according to claim 2, wherein: the reaction material comprises the following raw materials in parts by weight: 35 parts of aluminum powder, 55 parts of calcium oxide, 1.2 parts of sodium hydroxide, 12 parts of sodium carbonate, 10 parts of vermiculite, 7.5 parts of sodium sulfate and 10 parts of activated carbon.
4. The hydrogen generation therapy pack according to claim 1, wherein: the inner wrapping layer is made of breathable non-woven fabric, and the outer packaging bag is made of an airtight plastic film or an aluminum film.
5. The hydrogen generation therapy pack according to claim 1, wherein: the vermiculite and the active carbon are granular.
6. The hydrogen generation therapy pack according to claim 5, wherein: the particle size of the vermiculite and the activated carbon is between 20um and 80 um.
7. A preparation method of a hydrogen generation physical therapy material bag is characterized by comprising the following steps:
(1) weighing the following raw materials in parts by weight: 20-45 parts of aluminum powder, 40-70 parts of calcium oxide, 0.5-2 parts of sodium hydroxide, 5-20 parts of sodium carbonate, 5-15 parts of vermiculite, 5-10 parts of sodium sulfate and 5-15 parts of activated carbon;
(2) uniformly mixing the raw materials in the step (1) to ensure that aluminum powder, calcium oxide, sodium hydroxide, sodium carbonate and sodium sulfate are adhered to vermiculite and activated carbon;
(3) and (3) filling the mixed materials obtained in the step (2) into a water-permeable and air-permeable inner wrapping layer, sealing the inner wrapping bag, and filling into a sealed and air-impermeable outer wrapping bag.
8. The method for preparing a hydrogen generation therapy pack according to claim 7, wherein the method comprises the following steps: in the step (1), the calcium oxide, the sodium hydroxide, the sodium carbonate and the sodium sulfate are all in powder form, and the vermiculite and the activated carbon are in granular form.
9. The method for preparing a hydrogen generation therapy pack according to claim 7, wherein the method comprises the following steps: in the step (2), the aluminum powder, the calcium oxide, the sodium hydroxide, the sodium carbonate, the sodium sulfate, the vermiculite and the activated carbon are mixed in an inert gas environment; in the step (3), the materials mixed in the step (2) are filled into a water-permeable and air-permeable inner wrapping bag in an inert gas environment, and the inner wrapping bag is sealed in the inert gas environment and then filled into an air-impermeable outer wrapping bag.
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