CN114804885A - Preparation method of bucky paper/fly ash wear-resistant ceramic patch - Google Patents
Preparation method of bucky paper/fly ash wear-resistant ceramic patch Download PDFInfo
- Publication number
- CN114804885A CN114804885A CN202210598776.2A CN202210598776A CN114804885A CN 114804885 A CN114804885 A CN 114804885A CN 202210598776 A CN202210598776 A CN 202210598776A CN 114804885 A CN114804885 A CN 114804885A
- Authority
- CN
- China
- Prior art keywords
- fly ash
- paper
- bucky paper
- wear
- ceramic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/56—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
- C04B35/565—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1328—Waste materials; Refuse; Residues without additional clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
- C04B33/1352—Fuel ashes, e.g. fly ash
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/36—Reinforced clay-wares
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
- C04B35/16—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay
- C04B35/18—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silicates other than clay rich in aluminium oxide
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/62204—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products using waste materials or refuse
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/71—Ceramic products containing macroscopic reinforcing agents
- C04B35/78—Ceramic products containing macroscopic reinforcing agents containing non-metallic materials
- C04B35/80—Fibres, filaments, whiskers, platelets, or the like
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/66—Salts, e.g. alums
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
A method for preparing a balsa paper/fly ash wear-resistant ceramic patch comprises the steps of conventionally carboxylating balsa paper, soaking the balsa paper in a dopamine aluminum nitrate solution, and carrying out ultrasonic treatment; preparing a colloidal body by using butyl orthosilicate, alumina sol and micro-nano fly ash, then coating the colloidal body on the bottom layer of a steel mould plate, flatly paving the obtained base paper on the colloidal body, and repeating the steps for 3 to 5 times to form a fly ash/base paper interlayer material; extruding and forming the interlayer material, and drying to obtain a blank. And sintering the blank in a high-temperature vacuum environment or an inert gas protection environment, and cooling to room temperature along with the furnace to obtain the bucky paper/fly ash wear-resistant ceramic patch. The invention has the advantages of simplicity, safety, easy operation, controllability and the like. Compared with the traditional chemical plating, the prepared ceramic patch has more advantages in interface adhesion; the hard and brittle performance of the ceramic wear-resistant sheet can be improved; the customizability of the shape of the ceramic wear-resistant patch is easier to realize.
Description
Technical Field
The invention belongs to the technical field of material preparation.
Background
Mullite is used as a high-quality aluminosilicate raw material, has excellent thermal stability, mechanical strength, electrical and optical properties, and is widely applied to the field of functional ceramics. The fly ash is used as an industrial waste, and the main components of the fly ash are alumina and silicon oxide which are suitable for mullite synthesis raw materials. Partial academic papers show that the components of the composite material are reasonably utilized, and the wear resistance, the mechanics performance and other various performances of the composite material can be obviously improved. However, the disadvantage is also evident, the pure ceramic structure being indicative of an extremely poor toughness, which is hard and brittle without optimization. Limiting its application in the field of surface wear resistant materials. On the other hand, the bucky paper has excellent breaking strength and toughness. Besides the better wear-resisting property, the material can also be used as a material structure support. But are difficult to use directly in composites due to low density and performance stability.
At present, the main stream wear-resistant ceramic paster in the market is zirconia and alumina, compared with the fly ash raw material, in daily use, the cost performance is relatively low besides the problem of extremely high requirement on the installation and fitting degree of a workpiece caused by hard brittleness. If the fly ash and the Baji paper are organically combined by adopting a new technology, the defects of each other can be complemented and a novel wear-resistant paster can be prepared. The invention is in accordance with the theme of energy conservation and environmental protection, effectively solves the problem of environmental pollution caused by the accumulation of the fly ash, reduces the raw material cost of the mullite material, and realizes the high-value resource utilization of the fly ash.
Disclosure of Invention
The invention aims to provide a preparation method of a bucky paper/fly ash wear-resistant ceramic patch, which is characterized in that a flaky bucky paper/fly ash sandwich structure is utilized to prepare the wear-resistant patch. According to the invention, the interlayer sintering is combined through an interface modification method, a viscosity layer is coated on the basepaper, and the viscosity layer and the basepaper layer are promoted to generate micro reaction, so that the optimization of the interface layer with the fly ash ceramic is finally achieved, and the combination effect is increased. And because the Basa paper can be bent, the Basa paper has an obvious shape customization, and is suitable for the performance reinforcement of various complex parts. In addition, the existence of the bucky paper can effectively reduce the hard and brittle defects of the ceramic, so that the toughness of the material can be obviously improved.
The invention is realized by the following technical scheme.
The invention relates to a preparation method of a bucky paper/fly ash wear-resistant ceramic patch, which comprises the following steps.
(1) The buckypaper is conventionally carboxylated. The thickness of the selected bucky paper is controlled to be 0.15-0.2 mm, and the purity is 95-99.9%.
(2) And (2) adding the carboxylated bucky paper obtained in the step (1) into an aluminum nitrate solution with the concentration of 15-25 wt.% for ultrasonic treatment for 10-15 min, wherein the ultrasonic power is not less than 150W.
(3) And (3) adding dopamine into the aluminum nitrate solution obtained in the step (2) according to the mass ratio of 0.2: 1-0.1: 1 of the aluminum nitrate solution to the dopamine, and then continuously carrying out ultrasonic treatment for 20-30 min, wherein the ultrasonic power is not less than 150W.
(4) And (3) adding a trihydroxymethyl aminomethane (TRIS) buffering agent into the solution obtained in the step (3), adjusting the pH value of the solution to 8-9, continuously performing ultrasonic treatment for 3-5 h, taking out the Basil paper, and drying in the air.
(5) Mixing 10-15 vol.% of ethyl orthosilicate or butyl orthosilicate, 5-10 vol.% of alumina sol (the content of alumina is 21-23 wt.%), and 75-85 vol.% of micro-nano fly ash, and performing ultrasonic treatment for 10-30 min to obtain a fly ash colloid.
(6) And (3) uniformly paving the fly ash colloid obtained in the step (5) in a steel mould, wherein the thickness of the fly ash colloid is 1-3 mm, paving the bucky paper obtained in the step (4) on the fly ash colloid in the steel mould, and repeating the steps for multiple times to form the sandwich material with more than 3 layers of bucky paper.
(7) And (4) extruding and forming the interlayer material obtained in the step (6) in a mould under the pressure of 20-100 MPa, taking out and drying at the temperature of below 90 ℃ to obtain the Baji paper/fly ash ceramic paster blank.
(8) Firing the bucky paper/fly ash ceramic paster blank obtained in the step (7) in vacuum or inert gas atmosphereKnot and vacuum degree less than or equal to 10 -3 And torr, sintering temperature is 1100-1500 ℃, and heat preservation time is 2-4 h. Wherein the temperature rising speed from room temperature to 250-350 ℃ is 1-3 ℃/min, the temperature rising speed from 250-350 ℃ to 850-1000 ℃ is 3-10 ℃/min, and the temperature rising speed from 850-1000 ℃ to sintering temperature is 1-3 ℃/min. And obtaining the bucky paper/fly ash ceramic paster.
The main reaction equation generated in the sintering process of the invention is as follows:
SiO 2 +3C=SiC+2CO （1）；
2SiO 2 +3Al 2 O 3 = 3Al 2 O 3 ·2SiO 2 （2）。
compared with the prior art, the invention has the following technical effects: (1) the reactivity of silicon oxide and carbon is utilized to form a reaction transition layer. Compared with the traditional chemical plating, the interface adhesion is more advantageous. (2) The Baji paper has better toughness, so that the hard brittleness of the ceramic wear-resistant sheet can be improved. (3) The customizability of the shape of the ceramic wear-resistant paster is easier to realize by utilizing the foldability of the bucky paper. Therefore, the novel bucky paper/fly ash wear-resistant ceramic patch has wider applicability.
Drawings
FIG. 1 is an SEM micro-topography of a buckypaper/fly ash abrasion resistant ceramic patch made in example 1 of the present invention.
Detailed Description
The invention will be further illustrated by the following examples.
Example 1.
(1) Putting the paper with the purity of 99% and the thickness of 0.2mm into a mixed solution of concentrated nitric acid and concentrated sulfuric acid with the volume ratio of 1:3, and carrying out reflux reaction at 80 ℃ for 4h to obtain the carboxylated paper.
(2) And (2) adding the carboxylated bucky paper obtained in the step (1) into a 15wt.% aluminum nitrate solution for ultrasonic treatment for 15min, wherein the ultrasonic power is 160W.
(3) And (3) adding dopamine into the aluminum nitrate solution obtained in the step (2) according to the mass ratio of 0.15:1 of the aluminum nitrate solution to the dopamine, and then continuing ultrasound for 20min with the ultrasound power of 160W.
(4) And (3) adding a TRIS buffer into the solution obtained in the step (3) to adjust the pH value to 8, continuously carrying out ultrasonic treatment for 4h, taking out the bucky paper, and airing.
(5) Mixing 10vol.% of ethyl orthosilicate, 10vol.% of alumina sol (the content of alumina is 22 wt.%), and 80vol.% of micro-nano fly ash into a colloid, and performing ultrasonic treatment for 30 min.
(6) And (3) uniformly paving the fly ash colloid obtained in the step (5) in a steel mould, wherein the thickness of the fly ash colloid is 2mm, and paving the bucky paper obtained in the step (4) on the fly ash colloid in the steel mould, and repeating the steps for multiple times to form the sandwich material sandwiched with 4 layers of bucky paper.
(7) And (4) applying 40MPa pressure to the interlayer material obtained in the step (6) in a steel mould for forming, taking out and drying at 80 ℃ to obtain the Baji paper/fly ash ceramic paster blank.
(8) Putting the Baji paper/fly ash ceramic paster blank obtained in the step (7) into a vacuum sintering furnace for heating and sintering, wherein the vacuum degree is 10 -3 torr, sintering temperature 1300 ℃, and heat preservation time 2 h. Wherein the temperature rising speed from room temperature to 250 ℃ is 2 ℃/min, the temperature rising speed from 250 ℃ to 900 ℃ is 5 ℃/min, and the temperature rising speed from 900 ℃ to 1300 ℃ is 2 ℃/min. And obtaining the bucky paper/fly ash ceramic paster.
Example 2.
(1) Putting the paper with the purity of 99% and the thickness of 0.15mm into a mixed solution of concentrated nitric acid and concentrated sulfuric acid with the volume ratio of 1:3, and carrying out reflux reaction at 80 ℃ for 4h to obtain the carboxylated paper.
(2) Adding the carboxylated bucky paper obtained in the step (1) into an aluminum nitrate solution with the concentration of 20wt.% for ultrasonic treatment for 15min, wherein the ultrasonic power is 150W.
(3) And (3) adding dopamine into the aluminum nitrate solution obtained in the step (2) according to the mass ratio of 0.2:1 of the aluminum nitrate solution to the dopamine, and then continuing ultrasound for 30min with the ultrasound power of 150W.
(4) And (3) adding a TRIS buffer into the solution obtained in the step (3) to adjust the pH value to 9, continuously carrying out ultrasonic treatment for 3h, taking out the bucky paper, and airing.
(5) Mixing 15vol.% of ethyl orthosilicate, 10vol.% of alumina sol (the content of alumina is 23 wt.%), and 75vol.% of micro-nano fly ash into a colloid, and performing ultrasonic treatment for 30 min.
(6) And (3) uniformly paving the fly ash colloid obtained in the step (5) in a steel mould, wherein the thickness of the fly ash colloid is 2mm, and paving the bucky paper obtained in the step (4) on the fly ash colloid in the steel mould, and repeating the steps for multiple times to form the sandwich material sandwiched with 4 layers of bucky paper.
(7) And (4) applying 60MPa pressure to the interlayer material obtained in the step (6) in a steel mould for forming, taking out and drying at 80 ℃ to obtain the Baji paper/fly ash ceramic paster blank.
(8) Putting the Baji paper/fly ash ceramic paster blank obtained in the step (7) into a vacuum sintering furnace for heating and sintering, wherein the vacuum degree is 10 -3 torr, sintering temperature 1100 ℃, and holding time 4 h. Wherein the temperature rising speed from room temperature to 300 ℃ is 2 ℃/min, the temperature rising speed from 250 ℃ to 850 ℃ is 5 ℃/min, and the temperature rising speed from 850 ℃ to 1100 ℃ is 2 ℃/min. And obtaining the bucky paper/fly ash ceramic paster.
Example 3.
(1) Putting the paper with the purity of 99% and the thickness of 0.2mm into a mixed solution of concentrated nitric acid and concentrated sulfuric acid with the volume ratio of 1:3, and carrying out reflux reaction at 80 ℃ for 4h to obtain the carboxylated paper.
(2) Adding the carboxylated bucky paper obtained in the step (1) into an aluminum nitrate solution with the concentration of 25wt.% for ultrasonic treatment for 15min, wherein the ultrasonic power is 170W.
(3) And (3) adding dopamine into the aluminum nitrate solution obtained in the step (2) according to the mass ratio of 0.1:1 of the aluminum nitrate solution to the dopamine, and then continuing ultrasound for 25min with the ultrasound power of 170W.
(4) And (3) adding a TRIS buffer into the solution obtained in the step (3) to adjust the pH value to 9, continuously carrying out ultrasonic treatment for 5h, taking out the Bass paper, and airing.
(5) 5vol.% of ethyl orthosilicate, 10vol.% of alumina sol (the content of alumina is 21 wt.%), and 85vol.% of micro-nano fly ash are mixed into colloid, and ultrasonic treatment is carried out for 30 min.
(6) And (3) uniformly paving the fly ash colloid obtained in the step (5) in a steel mould, wherein the thickness of the fly ash colloid is 2mm, and paving the bucky paper obtained in the step (4) on the fly ash colloid in the steel mould, and repeating the steps for multiple times to form the sandwich material sandwiched with 4 layers of bucky paper.
(7) And (4) applying 80MPa pressure to the interlayer material obtained in the step (6) in a steel mould for forming, taking out and drying at 80 ℃ to obtain the Baji paper/fly ash ceramic paster blank.
(8) Putting the Baji paper/fly ash ceramic paster blank obtained in the step (7) into a vacuum sintering furnace for heating and sintering, wherein the vacuum degree is 10 -3 torr, sintering temperature 1500 ℃, and holding time 2 h. Wherein the temperature rising speed from room temperature to 350 ℃ is 2 ℃/min, the temperature rising speed from 350 ℃ to 1000 ℃ is 5 ℃/min, and the temperature rising speed from 1000 ℃ to 1500 ℃ is 2 ℃/min. And obtaining the bucky paper/fly ash ceramic paster.
TABLE 1 Basa paper/fly ash abrasion resistant ceramic Patch Properties
Claims (1)
1. A preparation method of a balsa paper/fly ash wear-resistant ceramic paster is characterized by comprising the following steps:
(1) conventionally carboxylating the bucky paper, wherein the thickness of the selected bucky paper is controlled to be 0.15-0.2 mm, and the purity is 95-99.9%;
(2) adding the carboxylated bucky paper obtained in the step (1) into an aluminum nitrate solution with the concentration of 15-25 wt.% for ultrasonic treatment for 10-15 min, wherein the ultrasonic power is not less than 150W;
(3) adding dopamine into the aluminum nitrate solution obtained in the step (2) according to the mass ratio of 0.2: 1-0.1: 1 of the aluminum nitrate solution to the dopamine, and then continuously carrying out ultrasonic treatment for 20-30 min, wherein the ultrasonic power is more than or equal to 150W;
(4) adding a trihydroxymethyl aminomethane buffering agent into the solution obtained in the step (3) to adjust the pH value of the solution to 8-9, continuously carrying out ultrasonic treatment for 3-5 h, taking out the bucky paper, and airing;
(5) mixing 10-15 vol.% of ethyl orthosilicate or butyl orthosilicate and 5-10 vol.% of alumina sol, wherein the content of alumina is 21-23 wt.%, and 75-85 vol.% of micro-nano fly ash is subjected to ultrasonic treatment for 10-30 min to obtain a fly ash colloid;
(6) uniformly paving the fly ash colloid obtained in the step (5) in a steel mould, wherein the thickness of the fly ash colloid is 1-3 mm, and then paving the bucky paper obtained in the step (4) on the fly ash colloid in the steel mould for many times to form an interlayer material sandwiched with more than 3 layers of bucky paper;
(7) extruding and forming the interlayer material obtained in the step (6) in a mould under the pressure of 20-100 MPa, taking out and drying at the temperature of below 90 ℃ to obtain a bucky paper/fly ash ceramic paster blank;
(8) sintering the Baji paper/fly ash ceramic paster blank obtained in the step (7) in vacuum or inert gas atmosphere, wherein the vacuum degree is less than or equal to 10 -3 torr, sintering temperature is 1100-1500 ℃, and heat preservation time is 2-4 h; wherein the temperature rising speed from room temperature to 250-350 ℃ is 1-3 ℃/min, the temperature rising speed from 250-350 ℃ to 850-1000 ℃ is 3-10 ℃/min, and the temperature rising speed from 850-1000 ℃ to the sintering temperature is 1-3 ℃/min, so that the bucky paper/fly ash ceramic patch is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210598776.2A CN114804885B (en) | 2022-05-30 | 2022-05-30 | Preparation method of bucky paper/fly ash wear-resistant ceramic patch |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210598776.2A CN114804885B (en) | 2022-05-30 | 2022-05-30 | Preparation method of bucky paper/fly ash wear-resistant ceramic patch |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN114804885A true CN114804885A (en) | 2022-07-29 |
| CN114804885B CN114804885B (en) | 2023-02-17 |
Family
ID=82518442
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210598776.2A Active CN114804885B (en) | 2022-05-30 | 2022-05-30 | Preparation method of bucky paper/fly ash wear-resistant ceramic patch |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN114804885B (en) |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0231787A2 (en) * | 1986-02-04 | 1987-08-12 | SIGRI GmbH | Method of manufacturing an impervious carbon or graphite article |
| US5711362A (en) * | 1995-11-29 | 1998-01-27 | Electric Power Research Institute | Method of producing metal matrix composites containing fly ash |
| DE102010004933A1 (en) * | 2010-01-18 | 2011-07-21 | Calsitherm Verwaltungs GmbH, 33175 | High temperature resistant hybrid material of calcium silicate and carbon |
| CN102642350A (en) * | 2012-04-24 | 2012-08-22 | 中国人民解放军国防科学技术大学 | Ceramic composite material of high temperature insulation sandwich structure and method for preparing ceramic composite material |
| CN107935543A (en) * | 2017-10-12 | 2018-04-20 | 潘正龙 | A kind of wear-resisting composite ceramic mud of scratch resistance and preparation method thereof |
| CN109210319A (en) * | 2018-11-12 | 2019-01-15 | 中研信源（北京）节能科技有限公司 | A kind of aerogel vacuum thermal insulation plate and its core material with and preparation method thereof |
| CN110156442A (en) * | 2019-04-08 | 2019-08-23 | 启东市聚旺铸造有限公司 | Use the light-weight refractory aggregate and preparation method thereof of model casting antiquated sand |
| KR102157335B1 (en) * | 2019-12-27 | 2020-09-18 | 변경호 | Eco-Friendly Functional Clay Bricks |
| WO2020218631A1 (en) * | 2019-04-23 | 2020-10-29 | 원경에프에이비(주) | Board for building finishing and manufacturing method therefor |
| US20210032521A1 (en) * | 2019-07-31 | 2021-02-04 | King Fahd University Of Petroleum And Minerals | Method of producing alumina ceramics reinforced with oil fly ash |
| CN113773110A (en) * | 2021-09-30 | 2021-12-10 | 东北大学 | Preparation method of carbon nano tube/leucite porous ceramic composite material converted from alkali-activated fly ash |
-
2022
- 2022-05-30 CN CN202210598776.2A patent/CN114804885B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0231787A2 (en) * | 1986-02-04 | 1987-08-12 | SIGRI GmbH | Method of manufacturing an impervious carbon or graphite article |
| US5711362A (en) * | 1995-11-29 | 1998-01-27 | Electric Power Research Institute | Method of producing metal matrix composites containing fly ash |
| DE102010004933A1 (en) * | 2010-01-18 | 2011-07-21 | Calsitherm Verwaltungs GmbH, 33175 | High temperature resistant hybrid material of calcium silicate and carbon |
| CN102642350A (en) * | 2012-04-24 | 2012-08-22 | 中国人民解放军国防科学技术大学 | Ceramic composite material of high temperature insulation sandwich structure and method for preparing ceramic composite material |
| CN107935543A (en) * | 2017-10-12 | 2018-04-20 | 潘正龙 | A kind of wear-resisting composite ceramic mud of scratch resistance and preparation method thereof |
| CN109210319A (en) * | 2018-11-12 | 2019-01-15 | 中研信源（北京）节能科技有限公司 | A kind of aerogel vacuum thermal insulation plate and its core material with and preparation method thereof |
| CN110156442A (en) * | 2019-04-08 | 2019-08-23 | 启东市聚旺铸造有限公司 | Use the light-weight refractory aggregate and preparation method thereof of model casting antiquated sand |
| WO2020218631A1 (en) * | 2019-04-23 | 2020-10-29 | 원경에프에이비(주) | Board for building finishing and manufacturing method therefor |
| US20210032521A1 (en) * | 2019-07-31 | 2021-02-04 | King Fahd University Of Petroleum And Minerals | Method of producing alumina ceramics reinforced with oil fly ash |
| KR102157335B1 (en) * | 2019-12-27 | 2020-09-18 | 변경호 | Eco-Friendly Functional Clay Bricks |
| CN113773110A (en) * | 2021-09-30 | 2021-12-10 | 东北大学 | Preparation method of carbon nano tube/leucite porous ceramic composite material converted from alkali-activated fly ash |
Also Published As
| Publication number | Publication date |
|---|---|
| CN114804885B (en) | 2023-02-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| He et al. | Effects of high-temperature heat treatment on the mechanical properties of unidirectional carbon fiber reinforced geopolymer composites | |
| CN109987941B (en) | High-entropy ceramic composite material with oxidation resistance and preparation method and application thereof | |
| CN112679233B (en) | Preparation method of silicon carbide coating for carbon-carbon composite material | |
| CN111454061B (en) | Polycarbosilane non-melting pretreatment and cracking conversion method for three-dimensional ceramic | |
| CN113024281B (en) | Silicon carbide/graphene bionic laminated coating and preparation method thereof | |
| WO2021259388A1 (en) | Method for using carbon coating to prepare low oxygen content, high thermal conductivity silicon nitride ceramic, and application thereof | |
| US20050209088A1 (en) | Silicon carbide thermostable porous structural material and process for producing the same | |
| KR20080071987A (en) | Silicon carbide precursors and uses thereof | |
| Luo et al. | Effects of fabrication processes on the properties of SiC/SiC composites | |
| Pourasad et al. | Preparation of a nanostructured SiC-ZrO2 coating to improve the oxidation resistance of graphite | |
| CN112374917B (en) | High-temperature ceramic coating and preparation method thereof | |
| CN106904985B (en) | Titanium-silicon-carbon enhanced alumina-based multiphase composite material and preparation method thereof | |
| Yan et al. | In situ synthesis of ultrafine ZrB2–SiC composite powders and the pressureless sintering behaviors | |
| CN112921317A (en) | Method for preparing ternary layered MAX phase ceramic coating through laser cladding | |
| Wang et al. | Performance and structural evolution of high-temperature organic adhesive for joining Al2O3 ceramics | |
| CN105734720A (en) | Preparation method for improving strength and modulus of SiC fibers | |
| CN115536403A (en) | High-toughness silicon nitride ceramic material and preparation method thereof | |
| CN114804885B (en) | Preparation method of bucky paper/fly ash wear-resistant ceramic patch | |
| CN110256093A (en) | A kind of reduction infiltration process preparation SiCfThe method of remaining silicone content in/SiC ceramic matrix composite material | |
| CN116410013A (en) | Silicon carbide ceramic and preparation method thereof | |
| JP4539014B2 (en) | Oxidation resistant C / C composite and method for producing the same | |
| CN110963812A (en) | Preparation method of carbon nano tube toughened silicon carbide ceramic | |
| JP2002104892A (en) | Ceramic composite material | |
| CN104177113B (en) | SiC bonded ceramic matrix composite material and preparation method thereof | |
| CN113105243A (en) | B with silicon carbide and silicon coating on surface4C/graphite composite material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |