CN114792846B - New silicon liquid material storage battery - Google Patents
New silicon liquid material storage battery Download PDFInfo
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- CN114792846B CN114792846B CN202210316312.8A CN202210316312A CN114792846B CN 114792846 B CN114792846 B CN 114792846B CN 202210316312 A CN202210316312 A CN 202210316312A CN 114792846 B CN114792846 B CN 114792846B
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/08—Selection of materials as electrolytes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/12—Construction or manufacture
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Abstract
The invention belongs to the technical field of storage batteries, in particular to a storage battery with a new silicon liquid material, which comprises a positive plate, a negative plate, an isolating layer, a storage battery shell and electrolyte; the electrolyte comprises the following components in percentage: 20-45% of sulfuric acid, 1-2% of ammonium phosphate, 10-15% of fumed silica, 2-3% of ammonium persulfate, 1-1.5% of magnesium sulfate, 1-1.5% of sodium silicate, 3-5% of silane, 2-3% of polyvinyl alcohol, 1-2% of carboxymethyl cellulose and the balance of distilled water; the preparation method of the electrolyte is as follows: s1: opening sealed lid and motor, putting into the agitator tank with fumed silica and distilled water through the feed inlet, stirring through the high speed of motor 10-15min, then electrifies the electromagnetic layer, lets the rotating block rotate, solves the agitating unit in the agitator tank and often rotates in fixed position department, can not carry out comprehensive contact stirring to the mixed liquid in the agitator tank, can lead to stirring inefficiency, influences the problem of electrolyte's quality even.
Description
Technical Field
The invention belongs to the technical field of storage batteries, and particularly relates to a storage battery with a new silicon liquid material.
Background
The accumulator is an electrochemical device capable of discharging electric energy, and after discharging, the accumulator can regenerate the internal active substances in a charging mode-store the electric energy as chemical energy; when discharging is needed, chemical energy is converted into electric energy again, and the electric energy has wide application due to high electromotive force, small internal resistance, reliable use performance and low price.
In the prior art, the most important component in the storage battery is electrolyte, and the components of the electrolyte determine the performance and the safety of the storage battery, but the electrolyte in the traditional lead-acid storage battery in the current market can be sulfated during the use period, so that the whole storage battery has poor performance, short service life and even hydrogen evolution and flash explosion, and has great potential safety hazard; therefore, the invention provides a storage battery with a new silicon liquid material.
Disclosure of Invention
In order to overcome the deficiencies of the prior art, at least one technical problem presented in the background art is solved.
The technical scheme adopted for solving the technical problems is as follows: the invention relates to a new silicon liquid material storage battery, which comprises a positive plate, a negative plate, an isolating layer, a storage battery shell and electrolyte, wherein the positive plate is arranged on the negative plate; the electrolyte comprises the following components in percentage: 20-45% of sulfuric acid, 1-2% of ammonium phosphate, 10-15% of fumed silica, 2-3% of ammonium persulfate, 1-1.5% of magnesium sulfate, 1-1.5% of sodium silicate, 3-5% of silane, 2-3% of polyvinyl alcohol, 1-2% of carboxymethyl cellulose and the balance of distilled water; the preparation method of the electrolyte is as follows:
s1: opening a sealing cover and a motor, putting fumed silica and distilled water into a stirring box through a feed inlet, stirring at a high speed for 10-15min by the motor, then electrifying an electromagnetic layer, enabling a rotating block to rotate, and introducing dilute sulfuric acid in a storage box into the stirring box 1 through a glass rod for mixing and stirring reaction;
s2: then adding ammonium phosphate, ammonium persulfate, magnesium sulfate and sodium silicate through a feed inlet, and carrying out mixing and stirring reaction for 10-12min;
s3: adding silane, polyvinyl alcohol and carboxymethyl cellulose, then powering off the electromagnetic layer, covering a feed inlet with a sealing cover, stirring under a normal temperature and normal pressure sealing environment, and carrying out catalytic reaction for 12-24 hours;
s4: after the catalysis is completed, magnetizing the mixed solution to obtain the required electrolyte;
s5: filling the electrolyte obtained in the step S4 into a storage battery shell through a filling device to obtain the product of the invention;
when the electrolyte is in operation, the electrolyte belongs to non-strong acid property, the positive plate and the negative plate cannot be corroded, the electrolyte has no charge-discharge memory effect, the hydrogen evolution potential is high, the gas evolution is weak, the water loss is extremely small, the corrosion to the plates is slight, the self-discharge of the battery is reduced, and the thermal runaway phenomenon of the battery is effectively inhibited.
Preferably, the top end of the stirring box is provided with symmetrically distributed feed inlets; the feed inlet is hinged with a sealing cover; a motor is fixedly connected to the center of the top end of the stirring box; the output end of the motor is provided with a first rotating shaft; a group of first sliding grooves are formed in the first rotating shaft; a first corrugated groove is formed in the inner wall of the stirring box at a position opposite to the first chute; the first sliding groove is connected with a first sliding block in a sliding manner; a stirring column is arranged between the first sliding block and the corrugated rod; a group of stirring plates are fixedly connected to the stirring column; in the prior art, when the stirring box is used for stirring and mixing the added materials, the stirring device in the stirring box usually rotates at a fixed position, the mixed liquid in the stirring box cannot be comprehensively contacted and stirred, the stirring hollow zone is formed at the position where some stirring plates cannot be contacted, although the stirring is not uniform through long-time stirring, the stirring efficiency is low, and even the material reaction effect is influenced.
Preferably, the stirring column comprises a first column body, a second column body and a corrugated rod; the first cylinder is rotationally connected to the side wall of the first sliding block, and a corrugated rod is fixedly connected to the end part of the first cylinder, which is far away from the first sliding block; a second column is fixedly connected to the end part of the corrugated rod; the second column is connected in the first ripple groove in a sliding way; the stirring plate is fixedly connected to the corrugated rod; during operation, set up the spliced pole and be first cylinder, second cylinder and ripple pole, with the stirring board rigid coupling on the ripple pole, can play the stirring board when rotating the stirring, play the effect that fluctuates, can make things convenient for the stirring board to clap the processing of scattering of the conglomeration material of putting into, guarantee to mix stirring effect.
Preferably, the second column is fixedly connected with a first gear; the bottom end of the first ripple groove is fixedly connected with a rack plate; the first gear and the rack plate are meshed with each other; during operation, because the second post removes in first ripple groove, and when first gear and rack board intermeshed, the ripple pole can rotate around the second post this moment, utilizes the rotation of stirring board, can carry out the quick exchange with the upper and lower liquid of agitator tank, can utilize the rotation of ripple pole simultaneously, can play different rivers rotational speed effects, also can further improve stirring and the collision effect of stirring board, conveniently break up the processing to the floc of agglomeration, also further guarantee the reaction effect.
Preferably, a group of vibration cavities are formed in the corrugated rod; the vibration cavity is internally provided with a vibration ball which is fixedly connected to the side wall of the vibration cavity through an elastic rope; a first groove is formed in the end part of the second cylinder; the bottom of the first groove is fixedly connected with a magnetic column through a spring; a group of first magnetic layers are fixedly connected to the bottom of the first corrugated groove; the first magnetic layer and the magnetic pillar are mutually exclusive; the magnetic column and the group of vibration balls are connected with each other through a string; during operation, when the second post rotates around first axis of rotation, at this moment because of the mutual repulsion of first magnetic layer and magnetic column, when first magnetic layer and magnetic column are mutually exclusive, elastic rope contracts this moment, let vibrations ball and vibrations chamber collide each other, and then collide the ripple pole, simultaneously when first magnetic layer and magnetic column dislocation each other, the magnetic column is outside the spring under the effect of spring force this moment, and then through string pulling vibrations ball removal, and then collide once more to vibrations chamber lateral wall, when the second post rotates, vibrations ball can collide back and forth in vibrations intracavity, can clean the processing to the stirring board through the vibration force that the collision produced, avoid appearing the material and attach at the stirring board, influence stirring and the collision effect of stirring board, also guarantee the clean and tidy nature of stirring board.
Preferably, a rotating block is sleeved on the outer side wall of the first rotating shaft, and the rotating block is rotationally connected to the inner wall of the top end of the stirring tank through a fixed column; the first rotating shaft drives the rotating block to rotate through the clamping piece; the rotating block is fixedly connected with a first annular plate through a first connecting column; a group of second corrugated grooves are fixedly connected to the first annular plate; a group of first through holes are formed in the groove bottom of the second corrugated groove; the top end of the stirring box is fixedly connected with a symmetrically distributed storage box; glass balls are arranged at the bottom end of the storage box, and the bottom ends of the glass balls are fixedly connected with glass rods; the bottom end of the glass rod extends into the stirring box and contacts with the top end of the first annular plate; the glass rod is provided with a group of guide grooves; during operation, when placing dilute sulfuric acid, in order to avoid the dilute sulfuric acid put into and appear splashing and influence the staff, in this end put into the storage box with dilute sulfuric acid earlier, then first axis of rotation drives the rotor through screens piece and rotates, the rotor passes through the head rod and drives on the first annular board, when the first annular board rotates, when second ripple groove lug contact each other on glass stick bottom and the first annular board this moment, the glass stick shifts up, move up the glass ball, and then let the dilute sulfuric acid in the storage box flow down along the glass stick upper guide slot, and flow into in the material of agitator tank through first through-hole, can play the installation, and the effect of slow unloading, can effectively avoid the spill of dilute sulfuric acid, also avoid manual put into the harm that causes the human body.
Preferably, the clamping piece comprises a clamping groove; the inner wall of the rotating block is provided with symmetrically distributed clamping grooves; the outer side wall of the first rotating shaft is provided with second grooves which are symmetrically distributed; the bottom of the second groove is fixedly connected with a magnetic block through a spring; an electromagnetic layer is fixedly connected to the bottom of the second groove; when the electromagnetic layer is electrified, the electromagnetic layer and the magnetic block repel each other; during operation, when the dilute sulfuric acid needs to be put into, the electromagnetic layer is electrified at this moment, then the repulsive force of the electromagnetic layer and the magnetic block is utilized, when the first rotating shaft rotates, the magnetic block is clamped into the clamping groove, the rotating block is driven to rotate, then the dilute sulfuric acid is discharged through the rotation of the first annular plate, after the discharge is finished, the electromagnetic layer is powered off at this moment, the magnetic block is separated from the clamping groove under the action of the spring and enters the second groove, and at this moment, the rotating block cannot be driven to rotate by the rotation of the first rotating shaft, so that the loss of internal energy is avoided.
Preferably, the inner wall of the stirring tank is provided with a heat dissipation hole; a cutting cavity is arranged in the stirring box, the cutting cavity cuts off the heat dissipation holes, and the cutting cavity is annular; the top end of the cutting cavity is fixedly connected with a sealing plate through a spring; the sealing plate is provided with a group of second through holes; the bottom end of the sealing plate is fixedly connected with a group of first sloping plates; a first through groove is formed in the side wall of the cutting cavity; the side wall of the first annular plate extends into the cutoff cavity through a second connecting column and is fixedly connected with a second annular plate; a group of second sloping plates are fixedly connected to the top end of the second annular plate; the first inclined plate and the second inclined plate are parallel to each other; during operation, put into the agitator tank at dilute sulfuric acid, can produce a large amount of heat this moment, in order to avoid the gel of reaction material, this moment needs quick heat dissipation, can drive the second annular plate through the second spliced pole and rotate when first annular plate rotates, then promote through the mutual contact of first swash plate and second swash plate, and then let the closing plate shift up, let first through-hole and louvre link up each other, the rotation that utilizes the agitator plate, and then conveniently to thermal quick heat dissipation handles, simultaneously when sealing device is needed to follow-up, electromagnetic layer outage this moment, at the time under the action of first swash plate and second swash plate, the closing plate moves down, let the recess tank bottom in glass plate bottom and second ripple groove contact each other, let the closing plate jam post louvre, the closing cap covers the feed inlet, make things convenient for subsequent catalytic sealing reaction.
Preferably, the top end of the cutting cavity is provided with a group of guide grooves; the sealing plate is fixedly connected with a guide post; the guide post is connected to the inner wall of the guide groove in a sliding manner; during operation, because the sealing plate cuts the chamber, utilize the guide pillar at the guiding action of guide way in the guide way this moment, can remove spacingly to the sealing plate, guarantee the state of lining up of second through-hole and louvre, avoid the deformation of spring to influence the heat dissipation state of louvre.
Preferably, a filter screen is fixedly connected to the inner wall of the radiating hole; during operation, the filter screen is utilized to play a certain role in protecting the external environment, so that dust and impurities are prevented from entering, influence factors cannot occur in a reaction state, and the quality of materials after reaction is guaranteed.
The beneficial effects of the invention are as follows:
1. according to the novel silicon liquid material storage battery, the components of the electrolyte are changed, so that the novel silicon liquid material storage battery belongs to non-strong acid property, does not corrode a positive plate and a negative plate, has no charge-discharge memory effect, is high in hydrogen evolution potential, weak in gas evolution, extremely small in water loss, slightly corrodes the positive plate, reduces self-discharge of the battery, and effectively inhibits thermal runaway of the battery.
2. According to the novel silicon liquid material storage battery, the stirring column is driven to move in the first ripple groove through the rotation of the first rotating shaft, and then the stirring column is driven to move up and down through the path of the first ripple groove, so that the position of the stirring plate can be changed, materials in the stirring box can be comprehensively stirred, the occurrence of hollow zones can be effectively avoided, the stirring effect can be further improved, the subsequent materials can be conveniently put into the reaction, and the reaction effect is ensured.
Drawings
The invention is further described below with reference to the accompanying drawings.
FIG. 1 is a flow chart of the preparation of an electrolyte in the present invention;
FIG. 2 is a perspective view of the agitator tank;
FIG. 3 is a cross-sectional view of the present invention;
FIG. 4 is a plan expanded view of the agitator tank;
FIG. 5 is a plan expanded view of the first annular plate;
FIG. 6 is an enlarged view of a portion of FIG. 3 at A;
FIG. 7 is an enlarged view of a portion of FIG. 3 at B;
FIG. 8 is an enlarged view of a portion of FIG. 3 at C;
FIG. 9 is a partial cross-sectional view of a heat sink;
in the figure: 1. a stirring tank; 11. a feed inlet; 12. sealing cover; 13. a motor; 14. a first rotation shaft; 15. a first chute; 16. a first corrugation groove; 17. stirring the column; 18. a stirring plate; 19. a first slider; 2. a first column; 21. a second column; 22. a corrugated rod; 23. a first gear; 24. rack plate; 3. a first magnetic layer; 31. a first groove; 32. a magnetic column; 33. a vibration cavity; 34. a vibrating ball; 35. a string; 4. a rotating block; 41. a first annular plate; 42. a second corrugation groove; 43. a first through hole; 44. a storage bin; 45. a glass rod; 46. glass balls; 47. a guide groove; 5. a clamping groove; 51. a second groove; 52. a magnetic block; 53. an electromagnetic layer; 54. a heat radiation hole; 55. cutting off the cavity; 56. a sealing plate; 57. a second annular plate; 58. a first swash plate; 59. a second swash plate; 6. a guide groove; 61. a guide post; 62. and (3) a filter screen.
Detailed Description
The invention is further described in connection with the following detailed description in order to make the technical means, the creation characteristics, the achievement of the purpose and the effect of the invention easy to understand.
Example 1
As shown in fig. 1, the novel silicon liquid material storage battery provided by the embodiment of the invention comprises a positive plate, a negative plate, an isolating layer, a storage battery shell and electrolyte; the electrolyte comprises the following components in percentage: 20-45% of sulfuric acid, 1-2% of ammonium phosphate, 10-15% of fumed silica, 2-3% of ammonium persulfate, 1-1.5% of magnesium sulfate, 1-1.5% of sodium silicate, 3-5% of silane, 2-3% of polyvinyl alcohol, 1-2% of carboxymethyl cellulose and the balance of distilled water; the preparation method of the electrolyte is as follows:
s1: the sealing cover 12 and the motor 13 are opened, fumed silica and distilled water are put into the stirring box 1 through the feed inlet 11, high-speed stirring is carried out for 10-15min through the motor 13, then the electromagnetic layer 53 is electrified, the rotating block 4 is rotated, and dilute sulfuric acid in the storage box 44 is led into the stirring box 1 through the glass rod 45 for mixing and stirring reaction;
s2: then adding ammonium phosphate, ammonium persulfate, magnesium sulfate and sodium silicate through a feed inlet 11, and carrying out mixing and stirring reaction for 10-12min;
s3: adding silane, polyvinyl alcohol and carboxymethyl cellulose, powering off the electromagnetic layer 53, covering the feed inlet 11 with the sealing cover 12, stirring under normal temperature and normal pressure sealing environment, and catalyzing for 12-24 hours;
s4: after the catalysis is completed, magnetizing the mixed solution to prepare electrolyte required by the storage battery;
s5: filling the electrolyte obtained in the step S4 into a storage battery shell through a filling device to obtain the product of the invention;
during operation, the electrolyte belongs to non-strong acid property by changing the composition of the electrolyte, the positive plate and the negative plate cannot be corroded, the electrolyte has no charge-discharge memory effect, the hydrogen evolution potential is high, the gas evolution is weak, the water loss is extremely small, the corrosion to the plates is slight, the self-discharge of the battery is reduced, the thermal runaway phenomenon of the battery is effectively inhibited, and meanwhile, the electrolyte is stirred and prepared by the stirring box 1, so that the production efficiency and the production quality can be effectively improved.
As shown in fig. 2 to 8, the top end of the stirring tank 1 is provided with a symmetrically distributed feed inlet 11; the feed inlet 11 is hinged with a sealing cover 12; a motor 13 is fixedly connected to the center of the top end of the stirring box 1; the output end of the motor 13 is provided with a first rotating shaft 14; a group of first sliding grooves 15 are formed in the first rotating shaft 14; a first corrugated groove 16 is formed in the inner wall of the stirring tank 1 at a position corresponding to the first chute 15; the first sliding groove 15 is connected with a first sliding block 19 in a sliding manner; a stirring column 17 is arranged between the first sliding block 19 and the corrugated rod 22; a group of stirring plates 18 are fixedly connected to the stirring column 17; in the prior art, when stirring and mixing reaction is carried out on added materials by using a stirring box 1, a stirring device in the stirring box 1 always rotates at a fixed position, mixed liquid in the stirring box 1 cannot be comprehensively contacted and stirred, a stirring hollow zone is formed at a position where a plurality of stirring plates 18 cannot be contacted, although uneven stirring can be avoided through long-time stirring, stirring efficiency is low, and even a material reaction effect is influenced.
The stirring column 17 comprises a first column body 2, a second column body 21 and a corrugated rod 22; the first cylinder 2 is rotatably connected to the side wall of the first slide block 19, and a corrugated rod 22 is fixedly connected to the end part of the first cylinder 2, which is far away from the first slide block 19; a second column 21 is fixedly connected to the end part of the corrugated rod 22; the second column 21 is slidably connected in the first corrugation groove 16; the stirring plate 18 is fixedly connected to the corrugated rod 22; during operation, the stirring column 17 is arranged to be the first column body 2, the second column body 21 and the corrugated rod 22, the stirring plate 18 is fixedly connected to the corrugated rod 22, the stirring plate 18 can be rotated and stirred, the fluctuation effect is achieved, the stirring plate 18 can be conveniently used for carrying out beating and scattering treatment on the put agglomerated materials, and the mixing and stirring effect is ensured.
The second cylinder 21 is fixedly connected with a first gear 23; a rack plate 24 is fixedly connected to the bottom end of the first corrugated groove 16; the first gear 23 and the rack plate 24 are engaged with each other; during operation, because the second post 21 moves in the first ripple groove 16, and when first gear 23 and rack board 24 intermesh, ripple pole 22 can rotate around second post 21 this moment, utilize the rotation of stirring board 18, can carry out quick exchange with the upper and lower liquid of agitator tank 1, can utilize the rotation of ripple pole 22 simultaneously, can play different rivers rotational speed effects, also can further improve stirring and the collision effect of stirring board 18, conveniently break up the processing to the floc of agglomeration, also further guarantee the reaction effect.
A group of vibration cavities 33 are formed in the corrugated rod 22; a vibration ball 34 is arranged in the vibration cavity 33, and the vibration ball 34 is fixedly connected to the side wall of the vibration cavity 33 through an elastic rope; the end part of the second cylinder 21 is provided with a first groove 31; the bottom of the first groove 31 is fixedly connected with a magnetic column 32 through a spring; a group of first magnetic layers 3 are fixedly connected to the bottom of the first corrugated groove 16; the first magnetic layer 3 and the magnetic pillar 32 repel each other; the magnetic column 32 and the group of vibration balls 34 are connected with each other through a string 35; during operation, when the second post 21 rotates around the first rotation shaft 14, at this moment, because of the mutual repulsion of the first magnetic layer 3 and the magnetic post 32, when the first magnetic layer 3 and the magnetic post 32 repel each other, the elastic rope contracts at this moment, the vibration ball 34 collides with the vibration cavity 33, and then the corrugated rod 22 collides, and simultaneously when the first magnetic layer 3 and the magnetic post 32 are misplaced with each other, the magnetic post 32 springs outwards under the action of the spring force, and then the vibration ball 34 is pulled to move through the string 35, and then the side wall of the vibration cavity 33 collides again, when the second post 21 rotates, the vibration ball 34 collides back and forth in the vibration cavity 33, the vibration force generated through collision can clean the stirring plate 18, the phenomenon that materials adhere to the stirring plate 18 is avoided, the stirring and collision effect of the stirring plate 18 are affected, and the cleanliness of the stirring plate 18 is ensured.
The outer side wall of the first rotating shaft 14 is sleeved with a rotating block 4, and the rotating block 4 is rotationally connected to the inner wall of the top end of the stirring tank 1 through a fixed column; the first rotating shaft 14 drives the rotating block 4 to rotate through the clamping piece; the rotating block 4 is fixedly connected with a first annular plate 41 through a first connecting column; a group of second corrugated grooves 42 are fixedly connected to the first annular plate 41; a group of first through holes 43 are formed in the groove bottom of the second corrugated groove 42; the top end of the stirring box 1 is fixedly connected with a symmetrically distributed storage box 44; glass balls 46 are arranged at the bottom end of the storage box 44, and the bottom end of each glass ball 46 is fixedly connected with a glass rod 45; the bottom end of the glass rod 45 extends into the stirring box 1 and contacts with the top end of the first annular plate 41; the glass rod 45 is provided with a group of guide grooves 47; during operation, when placing dilute sulfuric acid, in order to avoid the dilute sulfuric acid to put into and splash and influence staff, firstly, dilute sulfuric acid is put into the storage box 44, then the first rotating shaft 14 rotates and drives the rotating block 4 to rotate through the clamping piece, the rotating block 4 drives the first annular plate 41 through the first connecting rod, when the first annular plate 41 rotates, at this moment, when the bottom end of the glass rod 45 and the convex block of the second corrugated groove 42 on the first annular plate 41 are contacted with each other, the glass rod 45 moves upwards, the glass ball 46 moves upwards, and then dilute sulfuric acid in the storage box 44 flows down along the guide groove 47 on the glass rod 45, and flows into materials in the stirring box 1 through the first through hole 43, so that the installation can be realized, and the effect of slow blanking can be effectively avoided, and the harm to human body caused by manual putting into is avoided.
The clamping piece comprises a clamping groove 5; the inner wall of the rotating block 4 is provided with symmetrically distributed clamping grooves 5; the outer side wall of the first rotating shaft 14 is provided with second grooves 51 which are symmetrically distributed; the bottom of the second groove 51 is fixedly connected with a magnetic block 52 through a spring; an electromagnetic layer 53 is fixedly connected to the bottom of the second groove 51; when the electromagnetic layer 53 is electrified, the electromagnetic layer 53 and the magnetic block 52 repel each other; when the dilute sulfuric acid is needed to be put into, the electromagnetic layer 53 is electrified, then the repulsive force of the electromagnetic layer 53 and the magnetic block 52 is utilized, when the first rotating shaft 14 rotates, the magnetic block 52 is clamped into the clamping groove 5, the rotating block 4 is driven to rotate, the rotating block 4 rotates to further discharge the dilute sulfuric acid through the rotation of the first annular plate 41, after the discharging is finished, the electromagnetic layer 53 is powered off, the magnetic block 52 is separated from the clamping groove 5 under the action of the spring and enters the second groove 51, and at the moment, the rotating shaft 14 rotates to not drive the rotating block 4 to rotate, so that the loss of internal energy is avoided.
The inner wall of the stirring tank 1 is provided with a heat dissipation hole 54; a cutting cavity 55 is arranged in the stirring box 1, the cutting cavity 55 cuts off the heat dissipation holes 54, and the cutting cavity 55 is in an annular arrangement; the top end of the cutting cavity 55 is fixedly connected with a sealing plate 56 through a spring; the sealing plate 56 is provided with a group of second through holes; a group of first sloping plates 58 are fixedly connected to the bottom end of the sealing plate 56; a first through groove is formed in the side wall of the cutoff cavity 55; the side wall of the first annular plate 41 extends into the cutoff cavity 55 through a second connecting column and is fixedly connected with a second annular plate 57; a group of second sloping plates 59 are fixedly connected to the top end of the second annular plate 57; the first inclined plate 58 and the second inclined plate 59 are parallel to each other; during operation, dilute sulfuric acid is put into the stirring tank 1, a large amount of heat is generated at the moment, in order to avoid the gelation of reaction materials, quick heat dissipation is needed at the moment, the second annular plate 57 is driven to rotate through the second connecting column while the first annular plate 41 rotates, then the sealing plate 56 is pushed up through the mutual contact of the first inclined plate 58 and the second inclined plate 59, the first through hole 43 and the heat dissipation hole 54 are mutually communicated, the rotation of the stirring plate 18 is utilized, the quick heat dissipation treatment of the heat is further facilitated, meanwhile, when a sealing device is needed subsequently, the electromagnetic layer 53 is powered off, at the moment, the bottom of the glass plate is contacted with the groove bottom of the second corrugated groove 42, the sealing plate 56 blocks the column heat dissipation hole 54, and the sealing cover 12 covers the feed inlet 11, so that the subsequent catalytic sealing reaction is facilitated.
A group of guide grooves 6 are formed in the top end of the cutting cavity 55; a guide post 61 is fixedly connected to the sealing plate 56; the guide post 61 is connected to the inner wall of the guide groove 6 in a sliding manner; during operation, the sealing plate 56 is in the cutting cavity 55, and at this time, the guiding effect of the guide post 61 in the guide groove 6 is utilized to limit the movement of the sealing plate 56, so that the penetrating state of the second through hole and the heat dissipation hole 54 is ensured, and the heat dissipation state of the heat dissipation hole 54 is prevented from being influenced by the deformation of the spring.
Example two
As shown in fig. 9, in comparative example one, another embodiment of the present invention is: a filter screen 62 is fixedly connected to the inner wall of the radiating hole 54; during operation, the filter screen 62 is utilized to play a certain role in protecting the external environment, so that dust and impurities are prevented from entering, influence factors cannot occur in a reaction state, and the quality of the reacted materials is guaranteed.
Working principle: the fumed silica and distilled water are placed into the stirring box 1 through the feed inlet 11, at the moment, the motor 13 is started, the motor 13 drives the first rotating shaft 14 to rotate, the first rotating shaft 14 rotates to drive the stirring column 17 to move in the first corrugated groove 16, and then the stirring column 17 is driven to move up and down through the path of the first corrugated groove 16 to circulate, so that the position of the stirring plate 18 can be changed, the materials in the stirring box 1 can be comprehensively stirred, the occurrence of hollow zones can be effectively avoided, the stirring effect can be further improved, the subsequent material placement reaction is facilitated, and the reaction effect is ensured; because the second column 21 moves in the first corrugated groove 16, and when the first gear 23 and the rack plate 24 are meshed with each other, the corrugated rod 22 rotates around the second column 21, the upper liquid and the lower liquid of the stirring box 1 can be quickly exchanged by utilizing the rotation of the stirring plate 18, meanwhile, the effect of different water flow rotating speeds can be achieved by utilizing the rotation of the corrugated rod 22, the stirring and collision effects of the stirring plate 18 can be further improved, the agglomerated flocs can be conveniently scattered, and the reaction effect is further ensured; when the second column 21 rotates around the first rotating shaft 14, at this time, due to mutual repulsion of the first magnetic layer 3 and the magnetic column 32, when the first magnetic layer 3 and the magnetic column 32 repel each other, the elastic rope contracts, so that the vibration ball 34 collides with the vibration cavity 33 to collide with the corrugated rod 22, and when the first magnetic layer 3 and the magnetic column 32 are dislocated with each other, the magnetic column 32 springs outwards under the action of the spring force, so that the vibration ball 34 is pulled by the string 35 to move, so that the side wall of the vibration cavity 33 collides again, and when the second column 21 rotates, the vibration ball 34 collides back and forth in the vibration cavity 33, the stirring plate 18 can be cleaned by the vibration force generated by the collision, so that materials are prevented from adhering to the stirring plate 18, the stirring and collision effects of the stirring plate 18 are affected, and the cleanliness of the stirring plate 18 is ensured; when dilute sulfuric acid is required to be placed, the electromagnetic layer 53 is electrified, then the repulsive force of the electromagnetic layer 53 and the magnetic block 52 is utilized, when the first rotating shaft 14 rotates, the magnetic block 52 is clamped into the clamping groove 5, the rotating block 4 is driven to rotate, the first annular plate 41 is driven to rotate, at the moment, when the bottom end of the glass rod 45 and the convex block of the second corrugated groove 42 on the first annular plate 41 are contacted with each other, the glass rod 45 moves upwards, the glass ball 46 moves upwards, so that the dilute sulfuric acid in the storage box 44 flows down along the guide groove 47 on the glass rod 45, flows into materials in the stirring box 1 through the first through hole 43, the installation can be realized, the effect of slow blanking can be realized, the splashing of the dilute sulfuric acid can be effectively avoided, and the harm to a human body caused by manual placement is avoided; in the agitator tank 1, can produce a large amount of heat at this moment, in order to avoid the gel of reaction materials, at this moment need dispel the heat fast, can drive the rotation of second annular plate 57 through the second spliced pole when first annular plate 41 rotates, then promote through the mutual contact of first swash plate 58 and second swash plate 59, and then let closing plate 56 shift up, let first through-hole 43 and louvre 54 link up each other, in utilizing the rotation of agitator plate 18, and then convenient quick heat dissipation to the heat handles, and at the time of follow-up needs sealing device, at this moment electromagnetic layer 53 outage, at this moment under first swash plate 58 and second swash plate 59's the actuation, closing plate 56 moves down, let glass plate bottom and the recess tank bottom of second ripple groove 42 contact each other, let closing plate 56 block up post louvre 54, sealing cover feed inlet 11, the convenience is followed catalytic sealing reaction.
The front, rear, left, right, up and down are all based on fig. 1 in the drawings of the specification, the face of the device facing the observer is defined as front, the left side of the observer is defined as left, and so on, according to the viewing angle of the person.
In the description of the present invention, it should be understood that the terms "center," "longitudinal," "lateral," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate orientations or positional relationships based on the orientation or positional relationships shown in the drawings, merely to facilitate describing the present invention and simplify the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and therefore should not be construed as limiting the scope of the present invention.
The foregoing has shown and described the basic principles, principal features and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and that the above embodiments and descriptions are merely illustrative of the principles of the present invention, and various changes and modifications may be made without departing from the spirit and scope of the invention, which is defined in the appended claims. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (7)
1. A new material battery of silicon liquid, its characterized in that: comprises a positive plate, a negative plate, an isolating layer, a storage battery shell and electrolyte; the electrolyte comprises the following components in percentage: 20-45% of sulfuric acid, 1-2% of ammonium phosphate, 10-15% of fumed silica, 2-3% of ammonium persulfate, 1-1.5% of magnesium sulfate, 1-1.5% of sodium silicate, 3-5% of silane, 2-3% of polyvinyl alcohol, 1-2% of carboxymethyl cellulose and the balance of distilled water; the preparation method of the electrolyte is as follows:
s1: opening a sealing cover (12) and a motor (13), putting fumed silica and distilled water into a stirring box (1) through a feed inlet (11), stirring at a high speed for 10-15min through the motor (13), then electrifying an electromagnetic layer (53), enabling a rotating block (4) to rotate, and introducing dilute sulfuric acid in a storage box (44) into the stirring box (1) through a glass rod (45) for mixing and stirring reaction;
s2: then adding ammonium phosphate, ammonium persulfate, magnesium sulfate and sodium silicate through a feed inlet (11) to carry out mixing and stirring reaction for 10-12min;
s3: adding silane, polyvinyl alcohol and carboxymethyl cellulose, powering off the electromagnetic layer (53), covering the feed inlet (11) with the sealing cover (12), stirring under normal temperature and normal pressure sealing environment, and catalyzing for reaction (12) - (24) hours;
s4: after the catalysis is completed, magnetizing the mixed solution to prepare electrolyte required by the storage battery;
s5: filling the electrolyte obtained in the step S4 into a storage battery shell through a filling device to obtain the product of the invention;
the top end of the stirring box (1) is provided with symmetrically distributed feed inlets (11); a sealing cover (12) is hinged on the feeding hole (11); a motor (13) is fixedly connected to the center of the top end of the stirring box (1); the output end of the motor (13) is provided with a first rotating shaft (14); a group of first sliding grooves (15) are formed in the first rotating shaft (14); a first corrugated groove (16) is formed in the inner wall of the stirring box (1) at a position opposite to the first sliding groove (15); a first sliding block (19) is connected to the first sliding groove (15) in a sliding manner; a stirring column (17) is arranged between the first sliding block (19) and the corrugated rod (22); a group of stirring plates (18) are fixedly connected to the stirring column (17);
the stirring column (17) comprises a first column body (2), a second column body (21) and a corrugated rod (22); the first cylinder (2) is rotationally connected to the side wall of the first sliding block (19), and a corrugated rod (22) is fixedly connected to the end part of the first cylinder (2) far away from the first sliding block (19); a second column (21) is fixedly connected to the end part of the corrugated rod (22); the second column (21) is slidably connected in the first corrugated groove (16); the stirring plate (18) is fixedly connected to the corrugated rod (22);
a first gear (23) is fixedly connected to the second cylinder (21); a rack plate (24) is fixedly connected to the bottom end of the first corrugated groove (16); the first gear (23) and the rack plate (24) are meshed with each other.
2. The new silicon liquid material storage battery as claimed in claim 1, wherein: a group of vibration cavities (33) are formed in the corrugated rod (22); a vibration ball (34) is arranged in the vibration cavity (33), and the vibration ball (34) is fixedly connected to the side wall of the vibration cavity (33) through an elastic rope; a first groove (31) is formed in the end part of the second cylinder (21); the bottom of the first groove (31) is fixedly connected with a magnetic column (32) through a spring; a group of first magnetic layers (3) are fixedly connected to the bottom of the first corrugated groove (16); -said first magnetic layer (3) and magnetic pillar (32) are mutually exclusive; the magnetic column (32) and the group of vibration balls (34) are connected with each other through a string (35).
3. The new silicon liquid material storage battery as claimed in claim 2, wherein: the outer side wall of the first rotating shaft (14) is sleeved with a rotating block (4), and the rotating block (4) is rotationally connected to the inner wall of the top end of the stirring box (1) through a fixed column; the first rotating shaft (14) drives the rotating block (4) to rotate through the clamping piece; the rotating block (4) is fixedly connected with a first annular plate (41) through a first connecting column; a group of second corrugated grooves (42) are fixedly connected to the first annular plate (41); a group of first through holes (43) are formed in the groove bottoms of the second corrugated grooves (42); the top end of the stirring box (1) is fixedly connected with a symmetrically distributed storage box (44); glass balls (46) are arranged at the bottom end of the storage box (44), and the bottom end of each glass ball (46) is fixedly connected with a glass rod (45); the bottom end of the glass rod (45) extends into the stirring box (1) and is contacted with the top end of the first annular plate (41); the glass rod (45) is provided with a group of guide grooves (47).
4. A new material battery for silicon liquid as defined in claim 3, wherein: the clamping piece comprises a clamping groove (5); the inner wall of the rotating block (4) is provided with symmetrically distributed clamping grooves (5); the outer side wall of the first rotating shaft (14) is provided with second grooves (51) symmetrically distributed; the bottom of the second groove (51) is fixedly connected with a magnetic block (52) through a spring; an electromagnetic layer (53) is fixedly connected to the bottom of the second groove (51); when the electromagnetic layer (53) is electrified, the electromagnetic layer (53) and the magnetic block (52) repel each other.
5. The new silicon liquid material storage battery as claimed in claim 4, wherein: the inner wall of the stirring box (1) is provided with a heat dissipation hole (54); a cutting cavity (55) is arranged in the stirring box (1), the cutting cavity (55) cuts off the heat dissipation holes (54), and the cutting cavity (55) is in annular arrangement; the top end of the cutting cavity (55) is fixedly connected with a sealing plate (56) through a spring; a group of second through holes are formed in the sealing plate (56); a group of first inclined plates (58) are fixedly connected to the bottom end of the sealing plate (56); a first through groove is formed in the side wall of the cutting cavity (55); the side wall of the first annular plate (41) extends into the cutting cavity (55) through a second connecting column and is fixedly connected with a second annular plate (57); a group of second inclined plates (59) are fixedly connected to the top end of the second annular plate (57); the first inclined plate (58) and the second inclined plate (59) are parallel to each other.
6. The new silicon liquid material storage battery as claimed in claim 5, wherein: a group of guide grooves (6) are formed in the top end of the cutting cavity (55); a guide post (61) is fixedly connected to the sealing plate (56); the guide post (61) is connected to the inner wall of the guide groove (6) in a sliding way.
7. The new silicon liquid material storage battery as claimed in claim 5, wherein: a filter screen (62) is fixedly connected to the inner wall of the radiating hole (54).
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| Application Number | Priority Date | Filing Date | Title |
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| CN202210316312.8A CN114792846B (en) | 2022-03-28 | 2022-03-28 | New silicon liquid material storage battery |
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| CN202210316312.8A CN114792846B (en) | 2022-03-28 | 2022-03-28 | New silicon liquid material storage battery |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102122729A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Novel silicate electrolyte storage battery |
| CN212680747U (en) * | 2020-06-13 | 2021-03-12 | 山东亿能电源有限公司 | Electrolyte agitating unit is used in lead acid battery production |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102122729A (en) * | 2011-01-19 | 2011-07-13 | 李海明 | Novel silicate electrolyte storage battery |
| CN212680747U (en) * | 2020-06-13 | 2021-03-12 | 山东亿能电源有限公司 | Electrolyte agitating unit is used in lead acid battery production |
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