CN1147542A - Safe dirt-cleaning paste and its prepn - Google Patents
Safe dirt-cleaning paste and its prepn Download PDFInfo
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- CN1147542A CN1147542A CN 95116480 CN95116480A CN1147542A CN 1147542 A CN1147542 A CN 1147542A CN 95116480 CN95116480 CN 95116480 CN 95116480 A CN95116480 A CN 95116480A CN 1147542 A CN1147542 A CN 1147542A
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Abstract
The cleaning paste contains surfactant, cleaning assistant, solubilizing agent, skin amendment and abrasive, and has no phoaphate, alkali and alkylbenzene sulfonate. Owing to the synergistic effect of components, it has excellent detergency, so that it can be used for petroleum, coal, machine reparing and other workers to wash hand as well as in scrubbing kitchen ventilator, cooking utensils, ceramic tile, etc. It is prepared through normal-temp mixing and is stable in property.
Description
The present invention is a kind of to environment and human body safety, in stable condition dirt-cleaning cream composing substance and manufacture method.
For many years, workman in industrial and mining enterprises' forefront of the production, both hands usually are subjected to the pollution of working medium and various greases in the work, some heavy dirty greasy dirt is difficult to clean with general articles for washing, therefore the workpeople has to an organic solvent or the special-purpose stain remover of non-skin, waits as gasoline and washing powder and washs.From needless to say, with regard to washing powder commonly used, they contain a large amount of phosphoric acid salt, alkaline matter and sodium alkyl benzene sulfonate to organic solvent usually to the harm of human body.Because phosphorus-containing wastewater is pollution of ecological environment seriously, various countries are making laws one after another and are forbidding, and alkaline matter and alkylbenzene sulfonate can produce very strong stimulation to human body skin, and the lighter chaps pachylosis, serious meeting produces allergic, protein denaturation, causes irremediable consequence.Chinese invention patent CN1078252A discloses a kind of cleaning smeary " high effect detergent " on hand." diffusant " that uses in this patent--sodium lauryl benzene sulfonate is exactly a Sodium dodecylbenzene sulfonate the most frequently used in the washing powder, it to the damaging effect of human body skin as above-mentioned, auxiliary agents such as the yellow soda ash of this patent suggestion adding 15-20% in prescription and sodium polyphosphate, product just more has been similar to common strong basicity washing powder so.During this external product preparation, need heating also can bring inconvenience.Chinese invention patent CN1072716A " a kind of high-efficiency multi-purpose wipe cleaner without damage " also is a kind of decontamination cream.Because main tensio-active agent uses Sodium dodecylbenzene sulfonate, in abrasive, contain alkaline water glass and have toxic chlorine water glass, therefore the use range of this product is only limited to equipment and the crusts such as electric car shell and glass in the bathroom, kitchen, is not used for human body skin.The adducible document of another part is the patent that Japanese Kao Co., Ltd. obtains, the flat 4-41717 of special permission communique (B2), this patent formulation complexity, used multiple amine tensio-active agent, cost is higher, though product contains abrasive material but viscosity is lower, only be used for the housewife and wash vegetables and tableware, and be not used in workman's dirt on hand.The objective of the invention is: 1. propose a kind of dirt-cleaning paste prescription,,, both can wash one's hands, can clean the efficient dirt-cleaning paste of kitchen, bathroom and other crust equipment again environment and human body safety so that make a kind of cheaply.2. need not heating during fabrication, can make high stability product as long as at room temperature each component is mixed.
For addressing the above problem, it is composite that the present invention utilizes selected negatively charged ion and nonionogenic tenside to carry out, and adds buider, solubilizing agent, skin conditioning agent and abrasive material etc. and make it to produce best synergistic effect, reaches ideal decontamination skin-protection effect.
The used anion surfactant of the present invention is alkyl polyoxyethylene ether sodium sulfate AES, and its detersive power is good, to the skin gentleness.Nonionogenic tenside is alkylphenol polyoxyethylene TX (9), and its detersive power is good, and anti-hard water is strong, and skin is had good consistency.Two kinds of promoting agents are composite in the proper ratio can produce good synergy for this.Sodium-chlor is buider, and the still not fine solubilizing agent of urea can also strengthen the dirt-carrying ability, and it is again the moiety of human body natural moisturizing factor, can improve cuticular hydratability, makes the skin softness, plays opsonization.Silica powder and bentonite cooperate in certain proportion as sharpening, and can increase the friction to the anchorage dirt, and the Fouling Cleaning that embeds in the skin slit is come out.
Specifically, dirt-cleaning paste constituent of the present invention, it is characterized in that by a certain proportion of anion surfactant AES, nonionogenic tenside TX (9), buider sodium-chlor, solubilising and skin conditioning agent urea, abrasive material silica powder and bentonite and water cooperate an amount of sequestrant, sanitas, pigment and spices to mix again.
(weight %) is as follows for the content of various compositions:
AES 3.5--5.5 silica powder 45.0--52.0
TX (9) 6.0--9.0 bentonite 5.0--6.0
Urea 2.0--3.0 water 21.0--28.0
Sodium-chlor 2.0--4.0
Still need in addition and add an amount of sequestrant, sanitas, pigment and spices etc.
The manufacture method of dirt-cleaning paste of the present invention is very simple, promptly under normal temperature condition, tensio-active agent is added to the water mixes earlier, adds other component except that abrasive material again, stir into uniform mixture, add silica powder and bentonite at last and continue to stir into uniform lotion.
Product of the present invention detects through articles for washing quality surveillance inspection center of former China National Light Industrial Products Department.Owing to do not have the national standard and the industry standard of dirt-cleaning paste,, all meet the articles for washing standard so only the crucial physicochemical property and the sanitary index of product detected.About soil removability, we have designed the detersive power application test especially, so that compare with the commercial like product.
Pulverized bituminous coal by 300 mesh sieve holes and lubricating grease are with 1; 1 weight ratio is mixed into uniformly artificial grease sample, with soap both hands is cleaned earlier then, and is air-dry.Take by weighing 0.5 artificial grease of gram and the various washing composition of 0.25 gram respectively, the grease sample is coated with leftward equably goes up, again the washing composition sample is coated in the grease place, add several dripping, both hands are carefully rubbed, and final rinse water is if most on hand grease is washed off, reveal clean skin, think wash clean.
The below is the comparative result of product of the present invention and commercial goods detergency ability: the washing agent Acidity of Aikalinity has or not phosphate to have or not sodium alkyl benzene sulfonate clean effect 1. cleaning pastes of the present invention neutral without clean 3.BO hand cleanser alkalescence is arranged without clean 2.GNB degreaser strong basicity----clean 4.SW washing cream (joint) strong basicity have clean 5.LAN-LIN hand-cleansing cream (U.S.) neutral without clean 6.LRC-5 hand-cleansing cream (Britain) property invariably without clean 7.TIP-TOP hand-cleansing cream (Germany) property invariably without without clean
As seen from the above table, have only strong basicity, phosphorous SW washing cream that contains sodium alkyl benzene sulfonate and German TIP-TOP hand-washing paste and product of the present invention can handle on the artificial greasy dirt wash clean of doubling dose.In the product of environmental protection and safety type, have only the clean effect of product of the present invention and TIP-TOP hand-washing paste best.
In a word, product of the present invention has the following advantages, because not phosphorous environmentally safe; Because alkali-free does not have sodium alkyl benzene sulfonate to skin safe; Owing to exist skin conditioning agent can play to a certain degree skin care effect; Abrasive material can increase the friction of anchorage grease and be deep in the skin slit Fouling Cleaning is come out, and does not conform in the washing composition of sodium alkyl benzene sulfonate the detergency ability excellence of this product at without phosphorus alkali-free.Need not heating during fabrication, thereby facility investment is few, simple to operate, save the energy.Add that again raw materials cost is cheap, its price is less than 1/3rd of the import like product.In addition, the lotion excellent stability of this product stands-15 ℃ of freezing and 80 ℃ of high temperature the state and the performance of product is had no effect.
Embodiment: the following example of enumerating is done the preparation method of product of the present invention and is specified.Under normal temperature condition, difference weighing 25.0 kg of water, the AES of 6.0 kilogram of 70% content, 7.0 kilogram TX (9), 3.0 kilogram urea, 2.0 kilograms of sodium-chlor, 52.0 kilograms of silica powder and 5.0 kilograms of bentonites and an amount of sequestrant, sanitas, pigment and spices.Earlier water is joined in the stirred pot, add surfactant A ES and Tx (9) then, start to stir and make its mixing, again other component except that abrasive material, urea, sodium-chlor, sequestrant, sanitas, pigment and spices add wherein, stir into uniform mixture, add silica powder and bentonite at last, continue to stir into uniform lotion.
Claims (3)
1. safe dirt-cleaning paste constituent and preparation method thereof, it is characterized in that by a certain proportion of anion surfactant, nonionogenic tenside, buider, solubilizing agent, skin conditioning agent, abrasive material and water, cooperate an amount of sequestrant, sanitas, pigment and spices again, form through mixing.
2. according to the described constituent composition of claim 1, it is characterized in that anion surfactant is alkyl polyoxyethylene ether sodium sulfate AES, nonionogenic tenside is alkylphenol polyoxyethylene TX (9), buider is a sodium-chlor, solubilising and skin conditioning agent are urea, and abrasive material is bentonite and silica powder.The weight percent of various compositions is:
AES 3.5-5.5 silica powder 45.0-52.0
TX (9) 6.0-9.0 bentonite 5.0-6.0
Urea 2.0-3.0 water 21.0-28.0
Sodium-chlor 2.0-4.0 still needs in addition and adds an amount of sequestrant, sanitas, pigment and spices.
3, according to the described preparation method of claim 1, material temperature is a normal temperature when it is characterized in that preparing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95116480 CN1147542A (en) | 1995-10-09 | 1995-10-09 | Safe dirt-cleaning paste and its prepn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95116480 CN1147542A (en) | 1995-10-09 | 1995-10-09 | Safe dirt-cleaning paste and its prepn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1147542A true CN1147542A (en) | 1997-04-16 |
Family
ID=5080893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95116480 Pending CN1147542A (en) | 1995-10-09 | 1995-10-09 | Safe dirt-cleaning paste and its prepn |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1147542A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104905988A (en) * | 2015-04-24 | 2015-09-16 | 南通蛇类治疗研究所 | Water-free disinfection sterilization hand cleaning cream |
| CN107184404A (en) * | 2017-05-22 | 2017-09-22 | 句容康泰膨润土有限公司 | Hand-cleansing cream containing bentonite and production method for the dirty industry of weight |
| CN109055023A (en) * | 2018-07-20 | 2018-12-21 | 苏州华龙化工有限公司 | A kind of preparation method of the detergent for washing dishware with hand containing sodium xylene sulfonate |
| CN110003994A (en) * | 2019-04-01 | 2019-07-12 | 广州中洁清洗环保科技有限公司 | A kind of efficient cleaning paste and preparation method thereof |
| CN111718809A (en) * | 2020-06-28 | 2020-09-29 | 兰州宁远化工有限责任公司 | Household cleaning agent and manufacturing process thereof |
-
1995
- 1995-10-09 CN CN 95116480 patent/CN1147542A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104905988A (en) * | 2015-04-24 | 2015-09-16 | 南通蛇类治疗研究所 | Water-free disinfection sterilization hand cleaning cream |
| CN107184404A (en) * | 2017-05-22 | 2017-09-22 | 句容康泰膨润土有限公司 | Hand-cleansing cream containing bentonite and production method for the dirty industry of weight |
| CN109055023A (en) * | 2018-07-20 | 2018-12-21 | 苏州华龙化工有限公司 | A kind of preparation method of the detergent for washing dishware with hand containing sodium xylene sulfonate |
| CN110003994A (en) * | 2019-04-01 | 2019-07-12 | 广州中洁清洗环保科技有限公司 | A kind of efficient cleaning paste and preparation method thereof |
| CN111718809A (en) * | 2020-06-28 | 2020-09-29 | 兰州宁远化工有限责任公司 | Household cleaning agent and manufacturing process thereof |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |