CN1147371C - 从土壤中除去烃类污染物的方法 - Google Patents
从土壤中除去烃类污染物的方法Info
- Publication number
- CN1147371C CN1147371C CNB988035472A CN98803547A CN1147371C CN 1147371 C CN1147371 C CN 1147371C CN B988035472 A CNB988035472 A CN B988035472A CN 98803547 A CN98803547 A CN 98803547A CN 1147371 C CN1147371 C CN 1147371C
- Authority
- CN
- China
- Prior art keywords
- soil
- hydrogen peroxide
- accordance
- oxidation
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/26—Separation of sediment aided by centrifugal force or centripetal force
- B01D21/267—Separation of sediment aided by centrifugal force or centripetal force by using a cyclone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03B—SEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
- B03B9/00—General arrangement of separating plant, e.g. flow sheets
- B03B9/02—General arrangement of separating plant, e.g. flow sheets specially adapted for oil-sand, oil-chalk, oil-shales, ozokerite, bitumen, or the like
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/02—Extraction using liquids, e.g. washing, leaching, flotation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G27/00—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation
- C10G27/04—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen
- C10G27/12—Refining of hydrocarbon oils in the absence of hydrogen, by oxidation with oxygen or compounds generating oxygen with oxygen-generating compounds, e.g. per-compounds, chromic acid, chromates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/06—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for by heating, cooling, or pressure treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G31/00—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for
- C10G31/10—Refining of hydrocarbon oils, in the absence of hydrogen, by methods not otherwise provided for with the aid of centrifugal force
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S588/00—Hazardous or toxic waste destruction or containment
- Y10S588/90—Apparatus
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Soil Sciences (AREA)
- Geology (AREA)
- Processing Of Solid Wastes (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
物理基本参数 | |
油和油脂的百分数 | 6.41% |
水和在105℃挥发性物质的百分数 | 5.10% |
松密度 | 2.63 |
绝对密度 | 2.27 |
化学基本分析 | |
EPA方法8240挥发性有机物 | |
分析物: | 相对于油和油脂总量的% |
苯 | 没有检测到 |
甲苯 | 没有检测到 |
乙基苯 | 没有检测到 |
邻-二甲苯 | .002 |
间和对二甲苯 | .004 |
异丙基苯 | .009 |
正丙基苯 | .008 |
对异丙基甲苯 | .006 |
1,2,4-三甲基苯 | .006 |
1,3,5-三甲基苯 | .018 |
正丁基苯 | .020 |
仲丁基苯 | .027 |
叔丁基苯 | 没有检测到 |
萘 | .047 |
C1至C10的脂肪族化合物(没有限定) | 2.72 |
化学基本分析 | |
EPA方法8270半挥发性有机物 | |
分析物: | 相对于油和油脂总量的百分比 |
萘 | .047 |
苊烯 | .017 |
苊 | .236 |
芴 | .213 |
菲 | .549 |
蒽 | .497 |
荧蒽 | .359 |
芘 | 1.280 |
苯并(a)蒽 | 2.256 |
| 1.354 |
苯并(b)荧蒽 | 3.112 |
苯并(K)荧蒽 | 2.423 |
苯并(a)芘 | 1.558 |
茚并(1,2,3-cd)芘 | .183 |
二苯并(a,h)蒽 | 4.032 |
苯并(g,h,i)苝 | 1.278 |
C11至C38的脂肪族化合物(没有限定) | 77.68 |
通过氧化拆开多核芳香烃的降解 | |||
分析物 | 基本值mg/kg | 处理后mg/Kg | 新泽西州标准(残余mg/Kg) |
萘 | 2.25 | .047 | 230. |
苊烯 | .75 | <.02 | NA |
苊 | 11.3 | <.02 | 3400. |
芴 | 10.2 | <.02 | 2300. |
菲 | 26.3 | .178 | NA |
蒽 | 23.8 | .095 | 10000.(1) |
荧蒽 | 17.2 | .176 | 2300 |
芘 | 61.3 | .400 | 1700. |
苯并(a)蒽 | 108. | <.02 | .09 |
| 64.8 | .835 | 9.0 |
苯并(b)荧蒽 | 149. | <.02 | 0.9 |
苯并(k)荧蒽 | 116. | <.02 | 0.9 |
苯并(a)芘 | 74.6 | .515 | 0.66 |
茚并(1,2,3-cd)芘 | 8.75 | <.02 | 0.9 |
二苯并(a,h)蒽 | 193. | <.02 | 0.66 |
苯并(g,h,i)苝 | 61.2 | <.02 | NA |
EPA方法8240挥发性有机物水相 | |
分析物 | 相对有机气体总量的百分比 |
2-甲基-1-丙烯 | 28.2 |
羟基-乙醛 | 32.6 |
2-丙醇 | 8.4 |
环丙烷 | 4.5 |
2-庚酮 | 11.6 |
2-戊酮 | 8.8 |
2-甲基-2-丙烯醛 | 1.2 |
4-甲基-2-庚酮 | 1.6 |
不明化合物 | 3.1 |
EPA方法8240(改良的) | |
分析物 | 相对于气体总量的百分比 |
甲烷 | 18.38 |
氨 | 3.33 |
氮 | 0.84 |
氧 | 3.19 |
甲醛 | 0.05 |
二氧化碳 | 0.86 |
甲醇 | 2.27 |
乙醛 | 4.78 |
丁酮 | 3.25 |
丙酮 | 1.40 |
有机气体(表5) | 61.65 |
Claims (14)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/807,643 US5797701A (en) | 1997-02-27 | 1997-02-27 | Method of treating organic contaminated materials |
US08/807,643 | 1997-02-27 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1251060A CN1251060A (zh) | 2000-04-19 |
CN1147371C true CN1147371C (zh) | 2004-04-28 |
Family
ID=25196857
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB988035472A Expired - Fee Related CN1147371C (zh) | 1997-02-27 | 1998-02-26 | 从土壤中除去烃类污染物的方法 |
Country Status (9)
Country | Link |
---|---|
US (1) | US5797701A (zh) |
EP (1) | EP1015142A4 (zh) |
JP (1) | JP2001513021A (zh) |
CN (1) | CN1147371C (zh) |
AU (1) | AU6327698A (zh) |
CA (1) | CA2286896A1 (zh) |
EA (1) | EA002548B1 (zh) |
HK (1) | HK1027314A1 (zh) |
WO (1) | WO1998037991A1 (zh) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6576145B2 (en) * | 1997-02-27 | 2003-06-10 | Continuum Environmental, Llc | Method of separating hydrocarbons from mineral substrates |
US6096227A (en) * | 1997-02-27 | 2000-08-01 | Continuum Environmental, Inc. | System for processing industrial sludges |
US5928522A (en) * | 1997-02-27 | 1999-07-27 | Continuum Invironmental, Inc. | Method for processing oil refining waste |
US6123483A (en) * | 1999-04-08 | 2000-09-26 | Langenecker; Bertwin | Method and apparatus for decontaminating soil and mud polluted with hazardous waste and petroleum products |
FR2806939B1 (fr) * | 2000-03-30 | 2002-12-06 | Patrice Jean Albert Stengel | Procede et dispositif de depollution des sables ou des terres souilles par des hydrocarbures ou des germes infectieux |
JP4382397B2 (ja) * | 2003-06-10 | 2009-12-09 | 株式会社イーティーエル | 土砂洗浄装置及び土砂洗浄方法 |
CN101103176A (zh) * | 2004-04-13 | 2008-01-09 | 科里巴技术有限公司 | 用于改进采油的组合物和方法 |
US7628909B2 (en) * | 2004-09-27 | 2009-12-08 | Coriba Technologies, L.L.C. | Composition and process for the extraction of bitumen from oil sands |
US7384562B2 (en) * | 2004-10-29 | 2008-06-10 | Ecoplus, Inc. | Treatment of brown grease |
US7678201B2 (en) | 2005-07-22 | 2010-03-16 | Coriba Technologies, L.L.C. | Composition and process for the removal and recovery of hydrocarbons from substrates |
JP2007252972A (ja) * | 2006-03-20 | 2007-10-04 | Idemitsu Kosan Co Ltd | 石油汚染土壌の浄化方法 |
DK2594345T3 (en) * | 2010-07-15 | 2018-02-19 | Dowa Eco System Co Ltd | Soil remediation process |
RU2500479C2 (ru) * | 2011-12-21 | 2013-12-10 | АКЦИОНЕРНАЯ КОМПАНИЯ "АЛРОСА" (открытое акционерное общество) | Способ обработки алмазосодержащих концентратов липкостной сепарации |
CA2807998C (en) | 2012-03-01 | 2020-08-18 | Zeta Global, Ltd. | Systems and methods for recovering hydrocarbons |
US20140069875A1 (en) * | 2012-09-13 | 2014-03-13 | Bill Rippetoe | Mobil Remediation Trailer |
RU2704101C2 (ru) | 2014-10-02 | 2019-10-23 | Рональд Р. ДЭЙ | Система обработки загрязненного грунта и соответствующий способ |
US20160160317A1 (en) * | 2014-12-06 | 2016-06-09 | Sesa Sterlite Limited | Method and system for removing silica from an ore |
US10391532B2 (en) * | 2015-09-30 | 2019-08-27 | SedTech Innovations LLC | System and method for treatment of contaminated sediments or soils using free radical chemical reaction and phase separation processes |
KR20180110737A (ko) * | 2017-03-30 | 2018-10-11 | 주식회사 에코필 | 유기 오염물질을 이용한 산화탄화수소 제조방법 |
CN110014018B (zh) * | 2019-03-28 | 2024-06-28 | 北京云水浩瑞环境科技有限公司 | 餐厨垃圾预处理的*** |
CN110029977B (zh) * | 2019-04-18 | 2021-12-07 | 西南石油大学 | 页岩气井压裂液零返排环境友好提高采收率的氧化-渗吸法 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4230571A (en) * | 1979-01-22 | 1980-10-28 | Dadd Robert C | Ozone/ultraviolet water purification |
DE3125452C2 (de) * | 1981-06-29 | 1985-09-12 | Degussa Ag, 6000 Frankfurt | Verfahren zum Entgiften und zum Absenken des CSB und des BSB in kontinuierlichen Abwasserströmen mit wechselnden Gehalten verschiedener oxidierbarer Inhaltsstoffe mit Wasserstoffperoxid |
DE3232802A1 (de) * | 1982-09-03 | 1984-03-08 | Alfred Prof. Dr.-Ing. 7830 Emmendingen Walz | Verfahren und vorrichtung zum erzeugen ultravioletter strahlung |
US4591443A (en) * | 1984-11-08 | 1986-05-27 | Fmc Corporation | Method for decontaminating a permeable subterranean formation |
DE3836899C1 (zh) * | 1988-10-29 | 1989-11-23 | O & K Orenstein & Koppel Ag, 1000 Berlin, De | |
US4927293A (en) * | 1989-02-21 | 1990-05-22 | Campbell Randy P | Method and apparatus for remediating contaminated soil |
US5178762A (en) * | 1990-10-18 | 1993-01-12 | The Mead Corporation | Soybean peroxidase treatment of contaminated substances |
US5259962A (en) * | 1991-05-30 | 1993-11-09 | Later Roger C | Method and apparatus for decontamination of soils and other particulate materials |
ATE134698T1 (de) * | 1991-11-29 | 1996-03-15 | Noell En Und Entsorgungstechni | Verfahren zur thermischen verwertung von abfallstoffen |
EP0574924A1 (de) * | 1992-06-17 | 1993-12-22 | S.U.T. HÖLSCHER INGENIEUR- UND TECHNOLOGIEPROJEKTE GmbH | Verfahren zur chemischen Sanierung kontaminierter Böden oder Schlämme |
US5368411A (en) * | 1992-08-20 | 1994-11-29 | Tuboscope Vetco International, Inc. | Method and apparatus for on the site cleaning of contaminated soil |
US5304710A (en) * | 1993-02-18 | 1994-04-19 | Envar Services, Inc. | Method of detoxification and stabilization of soils contaminated with chromium ore waste |
US5295761A (en) * | 1993-03-25 | 1994-03-22 | Heacock Gary E | Method for remediating contaminated soil |
US5491443A (en) * | 1994-01-21 | 1996-02-13 | Delco Electronics Corporation | Very low-input capacitance self-biased CMOS buffer amplifier |
GB2301352A (en) * | 1994-03-03 | 1996-12-04 | Serl High Intensity Soil Washi | Method and apparatus for remediating soil |
US5525008A (en) * | 1995-01-11 | 1996-06-11 | Wilson; James T. | Remediation apparatus and method for organic contamination in soil and groundwater |
US5599137A (en) * | 1995-09-13 | 1997-02-04 | Chemtech Analysis Inc. | Mobile soil treatment apparatus and method |
-
1997
- 1997-02-27 US US08/807,643 patent/US5797701A/en not_active Expired - Fee Related
-
1998
- 1998-02-26 WO PCT/US1998/002967 patent/WO1998037991A1/en not_active Application Discontinuation
- 1998-02-26 EA EA199900779A patent/EA002548B1/ru not_active IP Right Cessation
- 1998-02-26 JP JP53770398A patent/JP2001513021A/ja active Pending
- 1998-02-26 AU AU63276/98A patent/AU6327698A/en not_active Abandoned
- 1998-02-26 EP EP98907479A patent/EP1015142A4/en not_active Withdrawn
- 1998-02-26 CN CNB988035472A patent/CN1147371C/zh not_active Expired - Fee Related
- 1998-02-26 CA CA002286896A patent/CA2286896A1/en not_active Abandoned
-
2000
- 2000-10-12 HK HK00106495A patent/HK1027314A1/xx not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EA002548B1 (ru) | 2002-06-27 |
CA2286896A1 (en) | 1998-09-03 |
WO1998037991A1 (en) | 1998-09-03 |
EP1015142A1 (en) | 2000-07-05 |
US5797701A (en) | 1998-08-25 |
JP2001513021A (ja) | 2001-08-28 |
EP1015142A4 (en) | 2003-03-05 |
EA199900779A1 (ru) | 2000-06-26 |
AU6327698A (en) | 1998-09-18 |
CN1251060A (zh) | 2000-04-19 |
HK1027314A1 (en) | 2001-01-12 |
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