CN114618297A - Manufacturing method, device and system of flue gas treatment device - Google Patents
Manufacturing method, device and system of flue gas treatment device Download PDFInfo
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- CN114618297A CN114618297A CN202210413909.4A CN202210413909A CN114618297A CN 114618297 A CN114618297 A CN 114618297A CN 202210413909 A CN202210413909 A CN 202210413909A CN 114618297 A CN114618297 A CN 114618297A
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- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 98
- 239000003546 flue gas Substances 0.000 title claims abstract description 98
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 46
- 230000023556 desulfurization Effects 0.000 claims abstract description 46
- 239000003054 catalyst Substances 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 230000003009 desulfurizing effect Effects 0.000 claims abstract description 8
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 20
- 239000000920 calcium hydroxide Substances 0.000 claims description 20
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims description 20
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 19
- 239000002918 waste heat Substances 0.000 claims description 15
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000000779 smoke Substances 0.000 claims description 7
- 229910010293 ceramic material Inorganic materials 0.000 claims description 6
- 239000002657 fibrous material Substances 0.000 claims description 4
- 239000007769 metal material Substances 0.000 claims description 4
- 239000000428 dust Substances 0.000 abstract description 26
- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 abstract description 13
- 238000001914 filtration Methods 0.000 abstract description 12
- 239000002245 particle Substances 0.000 abstract description 10
- 239000003344 environmental pollutant Substances 0.000 abstract description 2
- 239000007789 gas Substances 0.000 abstract description 2
- 231100000719 pollutant Toxicity 0.000 abstract description 2
- 239000000919 ceramic Substances 0.000 description 7
- 239000000835 fiber Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 3
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 2
- 235000017491 Bambusa tulda Nutrition 0.000 description 2
- 241001330002 Bambuseae Species 0.000 description 2
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 2
- 239000011425 bamboo Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- VJRVSSUCOHZSHP-UHFFFAOYSA-N [As].[Au] Chemical compound [As].[Au] VJRVSSUCOHZSHP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000010881 fly ash Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8681—Acidic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D46/00—Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
- B01D46/24—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
- B01D46/2403—Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
- B01D46/2411—Filter cartridges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8659—Removing halogens or halogen compounds
- B01D53/8662—Organic halogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20723—Vanadium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20776—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/20—Halogens or halogen compounds
- B01D2257/206—Organic halogen compounds
- B01D2257/2064—Chlorine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/02—Other waste gases
- B01D2258/0283—Flue gases
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biomedical Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Geometry (AREA)
- Treating Waste Gases (AREA)
- Filtering Of Dispersed Particles In Gases (AREA)
Abstract
The invention discloses a method, a device and a system for manufacturing a flue gas treatment device, wherein the method for manufacturing the flue gas treatment device comprises the following steps: a filter cylinder with an opening at one end is manufactured by adopting a filter material resistant to over 330 ℃; forming an alkaline desulfurization layer by using an alkaline desulfurizing agent, and bonding the alkaline desulfurization layer on the outer surface of the filter cylinder; determining the thickness of an alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through; the catalyst is filled inside the filter cartridge. According to the technical scheme, the filter cartridge is made of a filter material resistant to over 330 degrees and used for filtering particle dust in high-temperature flue gas; deacidifying the high-temperature flue gas by using an alkaline desulfurizer; further denitrating gas pollutants such as dioxin and the like by using a catalyst; dedusting the flue gas passing through the filter cartridge, and then contacting and reacting the flue gas with a catalyst to complete denitration or dioxin treatment; the flue gas only needs to pass through the flue gas processing apparatus and just can accomplish dust removal, deacidification, denitration or dioxin and handle, has simplified the treatment procedure that the flue gas was handled.
Description
Technical Field
The invention relates to the field of pollutant treatment, in particular to a method, a device and a system for manufacturing a flue gas treatment device.
Background
The smoke discharge temperature of the industrial kiln is high, and the waste heat recovery value is high; the process of a conventional integrated processing system includes the steps of: after the kiln flue gas is treated by the heat exchanger, sulfur is pushed through a dry desulfurization tower, denitration is integrally carried out through a ceramic tube, then dust is removed through a dust remover, and finally waste heat is utilized on a secondary boiler. The dust removal, desulfurization and denitration processes of the treatment system are complex, the defects of long flow, more equipment, high power consumption and complex manual maintenance are overcome, and the dry desulfurization system in the integrated system still needs to be independent. Therefore, a method for manufacturing an energy-saving, environment-friendly and simple smoke treatment device is needed.
Disclosure of Invention
The invention mainly aims to provide a manufacturing method of a flue gas treatment device, and aims to overcome the defects of high energy consumption and complex treatment process of the conventional flue gas treatment device.
In order to achieve the above object, the present invention provides a method for manufacturing a flue gas treatment device, comprising:
a filter cylinder with an opening at one end is manufactured by adopting a filter material resistant to over 330 ℃;
forming an alkaline desulfurization layer by using an alkaline desulfurizing agent, and bonding the alkaline desulfurization layer on the outer surface of the filter cylinder;
determining the thickness of an alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through;
the catalyst is filled inside the filter cartridge.
Preferably, the step of manufacturing the filter cartridge with an opening at one end by using the filter material resistant to the temperature of over 330 ℃ comprises the following steps; the filter cartridge is made of filter materials resistant to 330-380 ℃.
Preferably, the step of manufacturing the filter cartridge with an opening at one end by using the filter material resistant to the temperature of over 330 ℃ comprises the following steps; the filter cylinder with the high-porosity filter structure is made of any one of high-temperature-resistant metal materials, high-temperature-resistant ceramic materials and high-temperature-resistant fiber materials which can resist the temperature of more than 330 ℃.
Preferably, the alkaline desulfurizing agent comprises slaked lime powder, and the step of forming the alkaline desulfurizing agent into an alkaline desulfurizing layer to be adhered to the outer surface of the filter cylinder comprises the following steps: and attaching slaked lime powder to the outer surface of the filter cylinder.
Preferably, the alkaline desulfurizing agent comprises slaked lime powder, and the step of adhering the slaked lime powder to the outer surface of the filter cylinder comprises the following steps: the slaked lime powder is uniformly adsorbed on the outer surface of the filter cylinder by utilizing the principle that differential pressure is generated by airflow; the purity of sodium hydroxide in the slaked lime powder is more than 90 percent.
Preferably, the step of determining the thickness of the alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes comprises the following steps: the pressure difference resistance range of the smoke passing through the alkaline desulphurization layer is controlled between 300pa and 2000 pa.
Preferably, the step of filling the catalyst inside the filter cartridge includes the steps of; the catalyst forms a catalyst film attached to the inner wall of the filter cartridge.
Preferably, the step of filling the catalyst inside the filter cartridge includes the steps of; the catalyst forms a catalyst block adhered to the inner wall of the opening of the filter cartridge.
The invention also provides a flue gas treatment device which is manufactured by the manufacturing method of the flue gas treatment device.
The invention also provides a flue gas treatment system, which comprises the flue gas treatment device manufactured by the manufacturing method of the flue gas treatment device, and also comprises a primary waste heat utilization device and a secondary waste heat utilization device; the primary waste heat utilization device, the flue gas treatment device and the secondary waste heat utilization device are sequentially connected.
According to the technical scheme, the filter cylinder is made of a filter material resistant to over 330 ℃ and used for filtering particle dust in high-temperature flue gas, the high-temperature flue gas is subjected to deacidification treatment by using an alkaline desulfurizer, and denitration or dioxin is further performed by using a catalyst; determining the thickness of the alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through, so as to ensure that the flue gas can smoothly pass through the alkaline desulfurization layer; the alkaline desulfurization layer has a certain thickness, so that the dust removal degree of the flue gas can be further improved; after the flue gas passes through the alkaline desulfurization layer, part of particle dust is removed simultaneously, and the flue gas is subjected to secondary dust removal when passing through the filter cartridge; the flue gas passing through the filter cartridge is in contact reaction with a catalyst, and is discharged from the opening after denitration or dioxin treatment is completed; the flue gas only needs to pass through the flue gas processing apparatus and just can accomplish the dust removal deacidification denitration or the dioxin is handled, has simplified the treatment procedure that the flue gas was handled.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.
FIG. 1 is a schematic flow chart of a method for manufacturing a flue gas treatment device according to an embodiment of the present invention.
Fig. 2 is a flowchart illustrating an embodiment of step S100 in fig. 1.
Fig. 3 is a schematic flowchart illustrating an embodiment of step S100 in fig. 1.
Fig. 4 is a flowchart illustrating an embodiment of step S200 in fig. 1.
Fig. 5 is a flowchart illustrating an embodiment of step S21 in fig. 4.
Fig. 6 is a flowchart illustrating an embodiment of step S300 in fig. 1.
Fig. 7 is a flowchart illustrating an embodiment of step S400 in fig. 1.
Fig. 8 is a schematic flowchart of another embodiment of step S400 in fig. 1.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It should be noted that if directional indications (such as up, down, left, right, front, and back … …) are involved in the embodiment of the present invention, the directional indications are only used for explaining the relative position relationship between the components, the motion situation, and the like in a specific posture, and if the specific posture is changed, the directional indications are changed accordingly.
In addition, if there is a description of "first", "second", etc. in an embodiment of the present invention, the description of "first", "second", etc. is for descriptive purposes only and is not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In addition, if the meaning of "and/or" and/or "appears throughout, the meaning includes three parallel schemes, for example," A and/or B "includes scheme A, or scheme B, or a scheme satisfying both schemes A and B. In addition, technical solutions between the embodiments may be combined with each other, but must be based on the realization of the technical solutions by a person skilled in the art, and when the technical solutions are contradictory to each other or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.
The invention provides a manufacturing method of a flue gas treatment device.
Referring to fig. 1 to 8, in an embodiment of the present invention, a method for manufacturing a flue gas treatment device includes:
s100: a filter cylinder with an opening at one end is manufactured by adopting a filter material resistant to over 330 ℃;
s200: forming an alkaline desulfurization layer by using an alkaline desulfurizing agent, and bonding the alkaline desulfurization layer on the outer surface of the filter cylinder;
s300: determining the thickness of an alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through;
s400: the catalyst is filled inside the filter cartridge.
The existing flue gas treatment generally needs to adopt a dry desulfurization tower for desulfurization, ceramic tube integrated denitration and a dust remover for dust removal, the flow resistance of the flue gas is increased in a multilayer treatment structure, the consumption of electric energy and waste heat is increased, and the treatment steps are relatively complicated; the filter cartridge is made of a filter material resistant to over 330 ℃ and used for filtering particle dust in high-temperature flue gas, deacidifying the high-temperature flue gas by using an alkaline desulfurizer, and further performing denitration or dioxin removal by using a catalyst; determining the thickness of the alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through, and ensuring that the flue gas can smoothly pass through the alkaline desulfurization layer; the alkaline desulfurization layer has a certain thickness, so that the dust removal degree of the flue gas can be further improved; after the flue gas passes through the alkaline desulfurization layer, part of particle dust is removed simultaneously, and the flue gas is subjected to secondary dust removal when passing through the filter cartridge; the flue gas passing through the filter cartridge is in contact reaction with a catalyst, and is discharged from the opening after denitration or dioxin treatment is completed; the flue gas can be subjected to dust removal, deacidification and denitration or dioxin treatment only by a flue gas treatment device, so that the treatment flow of the flue gas treatment is simplified; in addition, the smoke problem to be treated is generally above 300 ℃, so the temperature that the filter material can bear is higher than 300 ℃, and in order to ensure that the filter material is melted by high temperature after long-term use, the filter cartridge is made of the filter material which can resist above 330 ℃.
Preferably, the step S100 of manufacturing the filter cartridge with an opening at one end by using the filter material resistant to the temperature of over 330 ℃ includes the following steps;
s11: the filter cartridge is made of filter materials resistant to 330-380 ℃.
The temperature of the flue gas to be treated is generally above 300 ℃, and in order to save the production cost, a filter material resistant to 330-380 ℃ can be adopted to manufacture the filter cartridge, so that the increase of the production cost and the resource waste caused by the adoption of extremely high temperature resistant materials are avoided.
Preferably, the step S100 of manufacturing the filter cartridge with an opening at one end by using the filter material resistant to the temperature of over 330 ℃ includes the following steps;
s12: the filter cylinder with the high-porosity filter structure is made of any one of high-temperature-resistant metal materials, high-temperature-resistant ceramic materials and high-temperature-resistant fiber materials which can resist the temperature of more than 330 ℃.
The filter cartridge in the prior art generally adopts a fiber ceramic filter material, wherein the fiber ceramic is required to adopt aluminum silicate as a raw material, and the aluminum silicate cannot be naturally degraded; in addition, in the existing flue gas filtering device, the catalyst is combined with the pore structure inside the fiber ceramic filter tube, and during recovery processing, substances such as vanadium and titanium attached to the fiber ceramic filter tube need to be separated from the fiber ceramic filter tube, so that the operation steps are complex, and the recovery processing cost is high. The alkaline desulfurization layer not only has the effect of dust removal and deacidification, because the alkaline desulfurization layer is established at the surface of straining a section of thick bamboo, still has the effect of protection filtering material, consequently makes more filtering material can be applied to the preparation and strains a section of thick bamboo, and consequently filtering material can adopt most suitable high temperature resistant filtering material on the market, does not confine to using fiber ceramic material, can also use various high temperature filtering material such as high temperature resistant metal material, high temperature resistant ceramic material, high temperature resistant fiber material pipe to replace fiber ceramic material, more does benefit to the environmental protection and retrieves. When the smoke passes through the high-porosity filter structure, the particle dust is filtered on the outer surface of the filter cylinder; the pore density of the high-porosity filter structure can be adjusted according to the emission standard of gas.
Preferably, the alkaline desulfurization agent comprises slaked lime powder, and the step of forming the alkaline desulfurization layer by the alkaline desulfurization agent to be adhered to the outer surface S200 of the filter cylinder comprises the following steps:
s21: and attaching slaked lime powder to the outer surface of the filter cylinder.
The slaked lime is adopted to remove the acid substances such as sulfur and the like, and has the advantages of low cost and high efficiency.
Preferably, the step S21 of attaching the slaked lime powder to the outer surface of the filter cartridge includes the steps of:
s211: the slaked lime powder is uniformly adsorbed on the outer surface of the filter cylinder by utilizing the principle that differential pressure is generated by airflow; the purity of sodium hydroxide in the slaked lime powder is more than 90 percent.
The slaked lime powder reacts with acidic substances in the flue gas to generate substances such as sulfate and the like, and in order to ensure the removal effect, the purity of calcium hydroxide in the slaked lime powder is at least 90%; the deacidification degree of the treated flue gas is prevented from not meeting the emission standard.
Preferably, the step S300 of determining the thickness of the alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through includes the following steps:
s31: the pressure difference resistance range of the smoke passing through the alkaline desulphurization layer is controlled between 300pa and 2000 pa.
When the flue gas passes through, the larger the pressure difference resistance of the alkaline desulfurization layer is, the higher the degree of the alkaline desulfurization layer for separating dust particles and heavy metal powder is, and the filtering efficiency of the filter cylinder is further improved; in addition, in the waste incineration treatment, the alkaline desulfurization layer with a certain thickness can be used for filtering fly ash containing dioxin and the like, and the aim of discharging particle dust to reach the order of a few points can be made to be a normal state. The alkaline desulfurization layer on the outer surface of the filter cylinder can reduce the probability that the catalyst is poisoned by heavy gold arsenic (As), selenium (Se) and mercury (Hg), so that the service life of the internal catalyst is prolonged; in addition, the catalyst in the catalyst membrane is uniformly distributed, so that the blockage and shielding troubles can be avoided, and the reaction efficiency can be improved, so that the catalyst can keep high-efficiency activity performance for a long time. It should be noted that the thickness can be adjusted by the pressure of the compressed air for blowback and the blowback frequency. The higher the pressure of the compressed air is, the higher the back blowing frequency is, the lower the pressure difference resistance formed by the alkaline desulfurization layer is, and the thinner the thickness of the alkaline desulfurization layer is. Preferably, the step S400 of filling the catalyst in the interior of the filter cartridge includes the steps of;
s41: the catalyst forms a catalyst film attached to the inner wall of the filter cartridge.
The catalyst film is uniformly distributed on the inner wall of the filter cylinder, so that the contact area of the flue gas and the catalyst is increased, and the residence time and the removal efficiency of the flue gas can be maximized.
Preferably, the step S300 of filling the catalyst in the interior of the filter cartridge includes the steps of;
s42: the catalyst forms a catalyst block adhered to the inner wall of the opening of the filter cartridge.
The thickness of the catalyst block is thicker than that of the catalyst film, the residence time of the flue gas is longer, and the removal effect can be improved. The catalyst may be provided differently depending on the different properties of the material used for the cartridge. The invention also provides a flue gas treatment device manufactured by the manufacturing method of the flue gas treatment device.
The present invention further provides a flue gas treatment device, which is manufactured by the manufacturing method of the flue gas treatment device, and the specific structure of the flue gas treatment device refers to the above embodiments.
The present invention further provides a flue gas treatment system, which includes the above flue gas treatment device, and the specific structure of the flue gas treatment device refers to the above embodiments, and since the flue gas treatment system adopts all technical solutions of all the above embodiments, the present invention at least has all the beneficial effects brought by the technical solutions of the above embodiments, and details are not repeated herein. The system also comprises a primary waste heat utilization device and a secondary waste heat utilization device; the primary waste heat utilization device, the flue gas treatment device and the secondary waste heat utilization device are sequentially connected.
According to the technical scheme, the filter cylinder is made of a filter material resistant to over 330 ℃ and used for filtering particle dust in high-temperature flue gas, the high-temperature flue gas is subjected to deacidification treatment by using an alkaline desulfurizer, and denitration or dioxin is further performed by using a catalyst; determining the thickness of the alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through, so as to ensure that the flue gas can smoothly pass through the alkaline desulfurization layer; the alkaline desulfurization layer has a certain thickness, so that the dust removal degree of the flue gas can be further improved; after the flue gas passes through the alkaline desulfurization layer, part of particle dust is removed simultaneously, and the flue gas is subjected to secondary dust removal when passing through the filter cartridge; the flue gas passing through the filter cartridge is in contact reaction with a catalyst, and is discharged from the opening after denitration or dioxin treatment is completed; the flue gas only needs to pass through the flue gas processing apparatus and just can accomplish the dust removal deacidification denitration or the dioxin is handled, has simplified the treatment procedure that the flue gas was handled.
The above description is only a preferred embodiment of the present invention, and is not intended to limit the scope of the present invention, and all modifications and equivalents of the present invention, which are made by the contents of the present specification and the accompanying drawings, or directly/indirectly applied to other related technical fields, are included in the scope of the present invention.
Claims (10)
1. A manufacturing method of a flue gas treatment device is characterized by comprising the following steps:
a filter cylinder with an opening at one end is manufactured by adopting a filter material resistant to over 330 ℃;
forming an alkaline desulfurization layer by using an alkaline desulfurizing agent and attaching the alkaline desulfurization layer to the outer surface of the filter cylinder;
determining the thickness of an alkaline desulfurization layer according to the pressure difference resistance when the flue gas passes through;
the catalyst is filled inside the filter cartridge.
2. The method for manufacturing a flue gas treatment device according to claim 1, wherein the step of manufacturing the filter cartridge with the opening at one end by using the filter material resistant to the temperature of over 330 ℃ comprises the following steps;
the filter cartridge is made of a filter material which can resist 330-380 ℃.
3. The method for manufacturing a flue gas treatment device according to claim 1, wherein the step of manufacturing the filter cartridge with the opening at one end by using the filter material resistant to the temperature of over 330 ℃ comprises the following steps;
the filter cylinder with the high-porosity filter structure is made of any one of high-temperature-resistant metal materials, high-temperature-resistant ceramic materials and high-temperature-resistant fiber materials which can resist the temperature of more than 330 ℃.
4. A method for manufacturing a flue gas treatment device according to any one of claims 1 to 3, wherein the alkaline desulfurization agent comprises slaked lime powder, and the step of forming the alkaline desulfurization agent into an alkaline desulfurization layer to be bonded to the outer surface of the filter cartridge comprises the steps of:
and attaching slaked lime powder to the outer surface of the filter cylinder.
5. The method of manufacturing a flue gas treatment device according to claim 4, wherein the step of attaching the slaked lime powder to the outer surface of the filter cartridge comprises the steps of:
the slaked lime powder is uniformly adsorbed on the outer surface of the filter cylinder by utilizing the principle that differential pressure is generated by airflow; the purity of sodium hydroxide in the slaked lime powder is more than 90 percent.
6. The method for manufacturing a flue gas treatment device according to any one of claims 1 to 3, wherein the step of determining the thickness of the alkaline desulfurization layer based on the pressure difference resistance when the flue gas passes through comprises the steps of:
the pressure difference resistance range of the smoke passing through the alkaline desulphurization layer is controlled between 300pa and 2000 pa.
7. The method for manufacturing a flue gas treatment device according to any one of claims 1 to 3, wherein the step of filling the inside of the filter cartridge with the catalyst comprises the steps of;
the catalyst forms a catalyst film attached to the inner wall of the filter cartridge.
8. The method for manufacturing a flue gas treatment device according to any one of claims 1 to 3, wherein the step of filling the inside of the filter cartridge with the catalyst comprises the steps of;
the catalyst forms a catalyst block adhered to the inner wall of the opening of the filter cartridge.
9. A flue gas treatment device, characterized by being manufactured by the method for manufacturing a flue gas treatment device according to any one of claims 1 to 8.
10. A flue gas treatment system, comprising the flue gas treatment device of claim 9, and further comprising a primary waste heat utilization device and a secondary waste heat utilization device; the primary waste heat utilization device, the flue gas treatment device and the secondary waste heat utilization device are sequentially connected.
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