CN114478106A - 一种环境友好全水溶型植物增产剂 - Google Patents
一种环境友好全水溶型植物增产剂 Download PDFInfo
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- CN114478106A CN114478106A CN202011142924.7A CN202011142924A CN114478106A CN 114478106 A CN114478106 A CN 114478106A CN 202011142924 A CN202011142924 A CN 202011142924A CN 114478106 A CN114478106 A CN 114478106A
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- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
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- C05B17/00—Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C5/00—Fertilisers containing other nitrates
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Abstract
本发明是有关一种环境友好全水溶型植物增产剂的复合配方。它由抗坏血酸钛、纳米二氧化钛、取代芳氧酸酯、苯肽胺酸、芸苔素内酯类物质、环状糊精等植物营养素及N、P、K、S、B、Mn、Zn、Mn、Ni、稀土、腐殖酸钾等大量、微量元素、以及OP‑10等表面活性剂按重量配比0.1—3：0.1‑5：1—20：10—80:1‑5混合组成。本发明的协同配方增产剂明显提高了与水相溶性，提高了活性物对植物的渗透能力，提高了光合作用，吸收效率和作用效果，具有多效、稳效、增产幅度增加等优点。可应用于粮食作物、油料作物、经济作物、果树、蔬菜以及花卉园林、食用菌、药材等各种作物,具有增加产量、提高着色、增加糖分、提早成熟、抗病防衰等作用。
Description
技术领域
本发明涉及一种肥料的配方，属于化学与农业技术应用领域。
背景技术
本专利发明人针对农业用植物生长调节剂及微量元素肥料技术进行过研究，发现生长调节剂大多是酸或钠盐、铵盐形式。由于酸难溶于水，配置时需先用酒精溶解，因此使用不方便；同时如配制不当、局部浓度偏高，则极易发生药害。钠、铵盐虽水溶性好，但它们对植物细胞的渗透力较弱，且极易被雨水冲淋，因此植物对有效成分的吸收率不高，影响作用效果。另外，由于是单一的生长调节剂，不能同时提供营养物质，因此效果不稳定，有时营养跟不上，反而导致作物减产。
因此，针对这类类植物生产调节剂存在的问题，发明人申请了一种植物增产剂组合物的发明专利。经过多年的生产实践发现它们仍然存在一些不足，如产品容易结块，成团，难溶于水，影响使用效果，且成本偏高，难以大量推广应用。
因此，为了进一步降低成本，使制剂使用更加方便，增产效果更加稳定、高效，特提出如下改进，提高和新的专利发明。
发明内容
实现上述发明目的技术方案如下，植物增产剂由五种组份配合而成。其中：
A为抗坏血酸钛、柠檬酸钛、乙二胺四乙酸钛、氨基酸钛、纳米二氧化钛中的至少一种或任意二种的混合物；
B为取代芳氧乙酸酯、苯肽胺酸、芸苔素内酯中的至少一种或任意二种的混合物；
C为环状糊精、水溶性淀粉、甲壳素中的至少一种或任意二种的混合物；
D为N、P、K、S、B、Mn、Zn、Ni、稀土、腐殖酸钾中的至少一种或任意二种的混合物；
E为OP-10、十二烷基苯磺酸钠、十二烷基苯磺酸钙、有机硅消泡剂中的至少一种或任意二种的混合物。
B中取代芳氧酸酯包括式1化合物中的至少一种
R＇n—R1—OR2—COOR3 [1]
式中R＇包括氢、氯、溴、碘、甲基，R1包括萘、苯基，R2包括1至3个碳的直链或支链亚烷基，R3包括氢及1至4个碳的直链或支链烷基，n为1至3；
B组份苯肽胺酸（和酯），如下结构Ⅱ物质，
芸苔素内酯，如下结构物质
加上C组份可溶性淀粉、蔗糖、改性糊精及α、β、γ环状糊精等植物营养素中的至少一种和D组份磷酸二氢钾、硫酸钾、硼砂、硼酸、硫酸钾、硫酸锌、硫酸锰、钼酸铵、稀土、硫酸镍、氯化镍、***钠、腐植酸等微肥中的至少一种。E组份为表面活性剂为OP-10，Triton-X-100，十二烷基苯磺酸钠等中的一种或任意二种的混合物。上述五种组分的配比为0.1-10，0.1-5，1-20，10-80,1-5。
本发明的植物增产剂采用提高光合作用的钛离子以及新的生长调节剂如取代芳氧酸酯类，苯肽胺酸、芸苔素内酯等，它们复合使用，可以显著提高植物的光合作用，更能发挥激活细胞的作用。微量元素镍、硒进一步提高了植物生长需要的营养物质，使之成为富硒、富镍功能性微量元素肥料。
它们可以做为药肥或水溶性肥料使用。增加了表面活性剂，使之水溶性，渗透性，附着力显著增加。
该植物增产剂可以通过调整配方，衍生出系列产品。在作为水溶肥料时可以不加植物调节剂成分。应用范围广、能提高作物光合作用,促进作物生长发育、保花保果、改善品质、增加糖分，还能提高作物抗寒、抗旱、抗病、抗早衰的能力。用于水稻、小麦可减少秕谷、穗大、籽粒饱满，降低镉等重金属含量；用于柑桔、橙子、荔枝、芒果等可以保花保果，提高座果率，且果实表面光滑、个大、品质好，并能提早成熟；用于棉花、西瓜、蔬菜等均有明显的增产及抗病害作用；用于油料作物如茶油树，用于葵花、土豆、大豆、青稞、高粱，药材如三七、红花等。其增产与防病效果详见下列各表。
表1、植物增产剂对甜橙的增产效果
| 处理 | 幼果数（个） | 定果数（个） | 座果率（%） | 增加（%） |
| 植物增产剂 | 7344 | 1051 | 14.3 | 854 |
| 某产品对比 | 6830 | 452 | 6.6 | 255 |
| 清 水 | 7900 | 197 | 2.4 | — |
注：在第一次、第二次生理落果前喷施，浓度为60PPM；某产品对比喷施浓度为50PPM。
表2、植物增产剂对辣椒的增产效果
| 处理 | 株数 | 产量 | 平均株产（公斤） | 增产率（%） |
| 植物增产剂 | 400 | 4.50 | 0.0250 | 42.85 |
| 某对比产品 | 400 | 3.25 | 0.0152 | 3.17 |
| 清 水 | 400 | 3.15 | 0.0146 | — |
注：于谢花期每隔15天喷施一次，浓度30PPM，对比产品也同时以同样浓度喷施。
表3、植物增产剂对茄子的增产效果
| 处理 | 株数 | 产量 | 平均株产（公斤） | 增产率（%） |
| 植物增产剂 | 272 | 195.8 | 0.72 | 58.41 |
| 某对比产品 | 272 | 148.7 | 0.55 | 20.30 |
| 清 水 | 272 | 123.6 | 0.45 | — |
注：喷施时期与浓度同辣椒。
表4、植物增产剂对辣椒的防病效果
| 处理 | 株数 | 病株树 | 病株率（%） | 防病率提高（%） |
| 植物增产剂 | 372 | 160 | 43.01 | 36.25 |
| 某对比产品 | 304 | 195 | 64.14 | 22.31 |
| 清 水 | 372 | 251 | 67.47 | — |
注：施药量为4-50克/亩，本表是施药后50天的调查结果。
表5、植物增产剂对茄子的防病效果
| 处理 | 株数 | 病株树 | 病株率（%） | 防病率提高（%） |
| 植物增产剂 | 190 | 65 | 34.21 | 61.73 |
| 某对比产品 | 196 | 131 | 66.83 | 25.30 |
| 清 水 | 190 | 170 | 89.47 | — |
注：施药量同辣椒，本表是施药后35天的调查结果。
表6、植物增产剂对水稻富硒增产效果
| 处理 | 稻田面积（亩） | 产量（斤/亩） | 增产率（%） | 米硒含量（mg/kg） |
| 植物增产剂 | 50 | 1250 | 21.12 | 0.48 |
| 清 水 | 50 | 986 | — | 0.05 |
本发明研制的植物增产剂水溶效果得到了进一步的提高，增产增收效果增加。生产工艺简便、产品性质稳定、水溶性好、吸附能力强、渗透性好、成本较低、无三废污染，易生物降解，对环境友好具有较好的社会效益及经济效益。
实施例1
称取对氯苯氧乙酸丁酯0.5公斤与环糊精3公斤及聚乙二醇辛基苯基醚乳化剂0.4公斤放入均化器中充分混合研磨；另称取硼酸、硫酸锌和硝酸稀土各20公斤，磷酸二氢钾36.5公斤，充分均化混合；二者合并，混合均匀，合计100公斤，包装。
使用时，称取植物增产剂50克，先用少量清水溶解，再加水稀释至45公斤，充分搅匀后即可喷施。
实施例2
按实例1方法称取下列组分后充分混合，均化，干燥，微粉化。
对碘苯氧乙酸丙酯（活性成分含量98%） 1公斤
苯肽胺酸酯 3公斤
β一环状糊精 2公斤
曲拉通-X-100 0.2公斤
硫酸锌 20公斤
硼酸 20公斤
***钠 1公斤
硫酸镍 20公斤
硝酸铈 32.8公斤
合计 100公斤
实例3
抗坏血酸钛 1公斤
芸苔素内酯 0.8公斤
γ-环状糊精 1.5公斤
聚氧乙烯烷基丙烯酸酯 0.3公斤
十二烷基苯磺酸钙 0.2公斤
尿素 10公斤
亚磷酸钾 20公斤
硼砂 5公斤
硫酸锰 12.2公斤
钼酸铵 1公斤
腐殖酸钾 48公斤
合计 100公斤
实例4微量元素水溶肥料
纳米二氧化钛 0.3公斤
甲壳素 20公斤
β一环状糊精 10公斤
硫酸锌 33.7公斤
硫酸锰 30公斤
十二烷基磺酸钠 6公斤
合计 100公斤
Claims (3)
1.一种环境友好全水溶型植物增产剂，其特征在于该增产剂由下述五种组份配合而成。
2.A为抗坏血酸钛、柠檬酸钛、乙二胺四乙酸钛、氨基酸钛、纳米二氧化钛中的至少一种或任意二种的混合物；B为取代芳氧乙酸酯、苯肽胺酸、芸苔素内酯中的至少一种或任意二种的混合物；C为环状糊精、水溶性淀粉、甲壳素中的至少一种或任意二种的混合物；D为N、P、K、S、B、Mn、Zn、Ni、稀土、腐殖酸钾中的至少一种或任意二种的混合物；E为OP-10、十二烷基苯磺酸钠、十二烷基苯磺酸钙、有机硅消泡剂中的至少一种或任意二种的混合物。
3.根据权利要求1所述的植物增产剂，其特征在于A：B:C:D:E五类组分的重量配比为0.1-10，0.1-5，1-20，10-80,1-5。
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| CN1100709A (zh) * | 1993-09-21 | 1995-03-29 | 曾立华 | 植物增产素 |
| CN104341231A (zh) * | 2013-08-06 | 2015-02-11 | 张庆之 | 一种植物增长素 |
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| CN105272483A (zh) * | 2015-11-25 | 2016-01-27 | 王绪征 | 含钛氨基酸水溶肥料 |
| CN108496965A (zh) * | 2018-06-04 | 2018-09-07 | 佛山市普尔玛农化有限公司 | 一种含有氯化胆碱、萘乙酸和芸苔素内酯的植物生长调节剂组合物 |
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100709A (zh) * | 1993-09-21 | 1995-03-29 | 曾立华 | 植物增产素 |
| CN104341231A (zh) * | 2013-08-06 | 2015-02-11 | 张庆之 | 一种植物增长素 |
| CN104892065A (zh) * | 2015-05-25 | 2015-09-09 | 王绪征 | 含固体钛微量元素水溶肥料多元制剂及制备方法 |
| CN105272483A (zh) * | 2015-11-25 | 2016-01-27 | 王绪征 | 含钛氨基酸水溶肥料 |
| CN108496965A (zh) * | 2018-06-04 | 2018-09-07 | 佛山市普尔玛农化有限公司 | 一种含有氯化胆碱、萘乙酸和芸苔素内酯的植物生长调节剂组合物 |
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