CN114409267A - Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface - Google Patents

Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface Download PDF

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Publication number
CN114409267A
CN114409267A CN202210226841.9A CN202210226841A CN114409267A CN 114409267 A CN114409267 A CN 114409267A CN 202210226841 A CN202210226841 A CN 202210226841A CN 114409267 A CN114409267 A CN 114409267A
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China
Prior art keywords
glass
snowflake
glass substrate
cleaning
liquid medicine
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Withdrawn
Application number
CN202210226841.9A
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Chinese (zh)
Inventor
成纵
张梓豪
童江锦
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Changsha Yongan New Material Co ltd
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Changsha Yongan New Material Co ltd
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Priority to CN202210226841.9A priority Critical patent/CN114409267A/en
Publication of CN114409267A publication Critical patent/CN114409267A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C15/00Surface treatment of glass, not in the form of fibres or filaments, by etching

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Surface Treatment Of Glass (AREA)
  • Detergent Compositions (AREA)

Abstract

The invention discloses a liquid medicine for forming snowflake-shaped flash sand effect on the surface of glass, which comprises, by mass, 25-35% of fluoride salt, 5-10% of citric acid, 5-10% of sodium nitrate, 15-10% of sulfuric acid, 20-35% of phosphoric acid and 10-20% of fluorite powder; 10-20% of sodium tripolyphosphate and the balance of water. The invention also discloses a process for forming the snowflake-shaped glittering sand effect on the glass surface, which comprises the steps of preparing the frosting liquid from any liquid medicine, uniformly stirring, and curing for a long time, wherein the process after the liquid medicine is prepared can be used after preparation; the glass has a dazzling effect under the illumination of a lamp and has a glittering effect of snowflake crystals.

Description

Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface
Technical Field
The invention relates to the technical field of glass liquid medicine and a process, in particular to liquid medicine and a process for forming a snowflake-shaped glittering sand effect on the surface of glass.
Background
Along with the great improvement of the consumption level and aesthetic requirements of people, the requirements of consumers on the appearance, functionality and the like of electronic wearing products are also improved, the traditional glass surface decoration effect is realized by film pasting or physical sand blasting, but the defects of easy aging, easy scratching, poor adhesive force, poor fingerprint oil stain resistance and low grade exist in the mode.
Disclosure of Invention
In order to solve the problems, the invention provides a liquid medicine for forming snowflake-shaped flash sand effect on the surface of glass, which comprises, by mass, 25-35% of fluoride salt, 5-10% of citric acid, 5-10% of sodium nitrate, 15-10% of sulfuric acid, 20-35% of phosphoric acid and 10-20% of fluorite powder; 10-20% of sodium tripolyphosphate and the balance of water.
Preferably, the cleaning agent comprises 25% of fluoride salt, 5% of citric acid, 5% of sodium nitrate, 15% of sulfuric acid, 20% of phosphoric acid and 10% of fluorite powder by mass percentage; 10% of sodium tripolyphosphate and the balance of water.
Through citric acid, anion functional group is adjusted to sulphuric acid and phosphoric acid, through the consistency of fluorite powder regulation and control etching solution, utilize sodium nitrate and sodium tripolyphosphate to guarantee the dispersed concentration of fluoride ion in the etching solution, make the glass surface form snowflake form flash of light sand, and the glass surface etching is even under the ratio, glass has the effect of dazzling under the lamp shines, and there is the flash of light effect of snowflake form crystallization, not only the outward appearance is beautiful, the glass surface is difficult for remaining fingerprint and dirty also, anti-soil ability has great promotion, and is more resistant to the fish tail, be difficult for receiving external force and destroy the surface.
The invention also discloses a process for forming snowflake-shaped flash sand effect on the surface of glass, which comprises the steps of preparing a frosting solution from any one of the liquid medicines, and uniformly stirring without curing.
Preferably, the glass substrate to be frosted is cleaned for the first time by clean water, the surface of the glass substrate which does not need to be frosted is protected, and the glass substrate is put into an acid cleaning agent for cleaning for 30-150 seconds.
Preferably, the glass substrate is subjected to a second cleaning with clear water for 30 to 60 seconds after being taken out.
Preferably, the glass is etched by using the prepared glass flash sand solution, and the specific process comprises the steps of placing the glass subjected to secondary cleaning in the flash sand frosting solution for up-and-down swinging for 120-350 seconds, and then taking out the glass.
Preferably, the frosted glass substrate and the etched glass substrate are put into clean water for cleaning for 60 seconds, and residual liquid medicine components are removed.
Preferably, the glass is put into the acid cleaning agent again for cleaning for 60-80 seconds, so that residual glass powder on the surface of the glass is thoroughly cleaned, and a glass substrate finished product with the snowflake crystal form effect can be taken out after rinsing with clean water.
Preferably, the acidic cleaning agent used in the first step is 10% hydrochloric acid.
Preferably, the acidic cleaning agent used in the second step is 10% sulfuric acid.
The process after the liquid medicine is prepared does not need to be cured for a long time, the liquid medicine can be prepared and used immediately, compared with the traditional frosting process, the time and labor are saved, and the etching can be carried out by using a spraying frosting mode and a soaking frosting mode.
Detailed Description
For a further understanding of the invention, reference will now be made to the preferred embodiments of the invention by way of example, and it is to be understood that the description is intended to further illustrate features and advantages of the invention, and not to limit the scope of the claims.
Example 1:
the liquid medicine comprises 25% of fluoride salt, 5% of citric acid, 5% of sodium nitrate, 15% of sulfuric acid, 20% of phosphoric acid and 10% of fluorite powder in percentage by mass; 10% of sodium tripolyphosphate and the balance of water.
(1) The liquid medicine is prepared into frosting liquid and is stirred uniformly without curing;
(2) cleaning a glass substrate to be frosted for the first time by using clear water, and protecting the surface of the glass substrate which does not need to be frosted;
(3) putting the glass substrate into an acid cleaning agent for cleaning for 90 seconds;
(4) taking out the glass substrate, and then cleaning the glass substrate for 60 seconds by using clear water for the second time;
(5) etching with the prepared glass flash sand liquid medicine, wherein the specific process comprises the steps of placing the glass subjected to secondary cleaning in the flash sand frosting liquid for swinging up and down for 120 seconds, and then taking out;
(6) putting the frosted glass substrate and the etched glass substrate into clear water for cleaning for 60 seconds, and removing residual liquid medicine components;
(7) putting the glass into the acid lotion again for cleaning for 80 seconds to thoroughly clean the residual glass powder on the surface of the glass;
(8) and finally, rinsing with clear water to obtain the finished glass substrate with the snowflake crystal form effect.
The cleaning solution in the step (3) is 10% hydrochloric acid;
the cleaning solution in the step (7) is 10% sulfuric acid;
the glass substrate prepared based on the process has the characteristics of uniform particles, fine hand feeling, high flash degree, light transmittance of 88 and roughness of 4600.
Example 2:
the liquid medicine comprises 25% of fluoride salt, 5% of citric acid, 10% of sodium nitrate, 15% of sulfuric acid, 25% of phosphoric acid and 10% of fluorite powder in percentage by mass; 10% of sodium tripolyphosphate and the balance of water.
(1) The liquid medicine is prepared into frosting liquid and is stirred uniformly without curing;
(2) cleaning a glass substrate to be frosted for the first time by using clear water, and protecting the surface of the glass substrate which does not need to be frosted;
(3) putting the glass substrate into an acid cleaning agent for cleaning for 150 seconds;
(4) taking out the glass substrate, and then cleaning the glass substrate for 60 seconds by using clear water for the second time;
(5) etching with the prepared glass flash sand liquid medicine, wherein the specific process comprises the steps of placing the glass subjected to secondary cleaning in the flash sand frosting liquid for swinging up and down for 180 seconds, and then taking out;
(6) putting the frosted glass substrate and the etched glass substrate into clear water for cleaning for 60 seconds, and removing residual liquid medicine components;
(7) putting the glass into the acid lotion again for cleaning for 60 seconds to thoroughly clean the residual glass powder on the surface of the glass;
(8) and finally, rinsing with clear water to obtain the finished glass substrate with the snowflake crystal form effect.
The cleaning solution in the step (3) is 10% hydrochloric acid;
the cleaning solution in the step (7) is 10% sulfuric acid;
the glass substrate prepared based on the process has the characteristics of uniform particles, fine hand feeling, moderate flash, 85 light transmittance and 3500 roughness.
Example 3:
the liquid medicine comprises 25% of fluoride salt, 10% of citric acid, 10% of sodium nitrate, 15% of sulfuric acid, 20% of phosphoric acid and 10% of fluorite powder in percentage by mass; 11% of sodium tripolyphosphate and the balance of water.
(1) The liquid medicine is prepared into frosting liquid and is stirred uniformly without curing;
(2) cleaning a glass substrate to be frosted for the first time by using clear water, and protecting the surface of the glass substrate which does not need to be frosted;
(3) putting the glass substrate into an acid cleaning agent for cleaning for about 30 seconds;
(4) taking out the glass substrate, and then cleaning the glass substrate for about 30 seconds by using clear water for the second time;
(5) etching with the prepared glass flash sand liquid medicine, wherein the specific process comprises the steps of placing the glass subjected to secondary cleaning in the flash sand frosting liquid for swinging up and down for about 350 seconds, and then taking out;
(6) putting the frosted glass substrate and the etched glass substrate into clear water for cleaning for 60 seconds, and removing residual liquid medicine components;
(7) putting the glass into the acid lotion again for cleaning for 60 seconds to thoroughly clean the residual glass powder on the surface of the glass;
(8) and finally, rinsing with clear water to obtain the finished glass substrate with the snowflake crystal form effect.
The cleaning solution in the step (3) is composed of 10% hydrochloric acid;
the cleaning solution in the step (7) is 10% sulfuric acid;
the glass substrate prepared based on the process has the characteristics of uniform particles, fine hand feeling, high flash degree, light transmittance of 85 and roughness of 2800.
According to the three embodiments, the proportion of the liquid medicine and the condition parameters of frosting can be adjusted according to different requirements on the flash degree, the light transmittance and the roughness, so that different effects can be realized.
The foregoing illustrates and describes the principles, general features, and advantages of the present invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are described in the specification and illustrated only to illustrate the principle of the present invention, but that various changes and modifications may be made therein without departing from the spirit and scope of the present invention, which fall within the scope of the invention as claimed.

Claims (10)

1. A liquid medicine for forming snowflake-shaped flash sand effect on the surface of glass is characterized in that: the material comprises, by mass, 25-35% of fluoride salt, 5-10% of citric acid, 5-10% of sodium nitrate, 15-10% of sulfuric acid, 20-35% of phosphoric acid and 10-20% of fluorite powder; 10-20% of sodium tripolyphosphate and the balance of water.
2. The liquid medicine for forming snowflake-like glittering sand effect on a glass surface according to claim 1, wherein: the material comprises 25% of fluoride salt, 5% of citric acid, 5% of sodium nitrate, 15% of sulfuric acid, 20% of phosphoric acid and 10% of fluorite powder in percentage by mass; 10% of sodium tripolyphosphate and the balance of water.
3. A process for forming a snowflake-like sparkling sand effect on a glass surface, characterized in that: a frosting solution prepared from the lotion of any one of claims 1 or 2 and stirred uniformly without aging.
4. A process for creating a snowflake-like sparkling sand effect on a glass surface according to claim 3, wherein: and cleaning the glass substrate to be frosted for the first time by using clear water, protecting the surface of the glass substrate which does not need to be frosted, and cleaning the glass substrate in an acid cleaning agent for 30-150 seconds.
5. A process for creating a snowflake-like sparkling sand effect on a glass surface according to claim 4, wherein: taking out the glass substrate, and then cleaning the glass substrate for 30-60 seconds by using clean water for the second time.
6. A process for imparting a snowflake-like sparkling sand effect to a glass surface according to claim 5, wherein: the glass washed twice is placed in the flash sand frosting solution to swing up and down for 120-350 seconds, and then taken out.
7. A process for imparting a snowflake-like sparkling sand effect to a glass surface according to claim 6, wherein: and (3) putting the frosted glass substrate and the etched glass substrate into clear water for cleaning for 60 seconds, and removing the residual liquid medicine components.
8. A process for imparting a snowflake-like sparkling sand effect to a glass surface according to claim 7, wherein: and (3) putting the glass into the acid cleaning agent again for cleaning for 60-80 seconds to thoroughly clean the residual glass powder on the surface of the glass, and rinsing with clear water to obtain the glass substrate finished product with the snowflake crystal form effect.
9. A process for creating a snowflake-like sparkling sand effect on a glass surface according to claim 4, wherein: the acidic cleaning agent in this step is 10% hydrochloric acid.
10. A process for imparting a snowflake-like sparkling sand effect to a glass surface according to claim 8, wherein: the acidic cleaning agent of this step is 10% sulfuric acid.
CN202210226841.9A 2022-03-10 2022-03-10 Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface Withdrawn CN114409267A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202210226841.9A CN114409267A (en) 2022-03-10 2022-03-10 Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202210226841.9A CN114409267A (en) 2022-03-10 2022-03-10 Liquid medicine and process for forming snowflake-shaped flash sand effect on glass surface

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115505391A (en) * 2022-11-09 2022-12-23 金龙机电(杭州)有限公司 Formula of flash sand liquid medicine, preparation process and application of glass with flash sand effect

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115505391A (en) * 2022-11-09 2022-12-23 金龙机电(杭州)有限公司 Formula of flash sand liquid medicine, preparation process and application of glass with flash sand effect
CN115505391B (en) * 2022-11-09 2024-03-22 金龙机电(杭州)有限公司 Formula of flashing sand liquid medicine and preparation process and application of glass with flashing sand effect

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Application publication date: 20220429