CN114291865A - Self-adaptive two-phase solar photocatalytic degradation device - Google Patents

Self-adaptive two-phase solar photocatalytic degradation device Download PDF

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CN114291865A
CN114291865A CN202111558629.4A CN202111558629A CN114291865A CN 114291865 A CN114291865 A CN 114291865A CN 202111558629 A CN202111558629 A CN 202111558629A CN 114291865 A CN114291865 A CN 114291865A
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degradation
wall
gas
self
disturbance
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CN114291865B (en
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刘力辉
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Jilin Teachers Institute of Engineering and Technology
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Jilin Teachers Institute of Engineering and Technology
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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Abstract

The invention discloses a self-adaptive two-phase solar photocatalytic degradation device, which comprises a degradation shell and a transparent glass cover above the degradation shell, and is characterized in that: the inner bottom wall of the degradation shell is provided with a self-adaptive height adjusting assembly, the upper portion of the self-adaptive height adjusting assembly is provided with an air jet curved surface for capturing a two-phase degradation mechanism, the air jet curved surface captures the inside of the two-phase degradation mechanism and is provided with a circulating uninterrupted air suction assembly, the circulating uninterrupted air suction assembly is provided with a magnetic absorption type nondestructive decontamination assembly, the upper portion of the air jet curved surface for capturing the two-phase degradation mechanism is provided with an upper supporting fixed plate, the outer wall of the upper supporting fixed plate is provided with a self-adjustable buoyancy float, and the upper wall array of the upper supporting fixed plate is provided with a degradation light gathering assembly. The invention belongs to the technical field of sewage degradation, and particularly relates to a self-adaptive two-phase solar photocatalytic degradation device which is simple to operate, can simultaneously catalyze and degrade sewage and toxic gas emitted by the sewage, and increases the light transparency between a photocatalyst and the toxic gas.

Description

Self-adaptive two-phase solar photocatalytic degradation device
Technical Field
The invention belongs to the technical field of sewage degradation, and particularly relates to a self-adaptive two-phase solar photocatalytic degradation device.
Background
With the continuous progress of modern science and technology in the world, solar energy is inexhaustible as a renewable energy source, and has no pollution to the environment, so that the utilization of the solar energy becomes one of important subjects. Light in different bands of the spectrum of sunlight has different characteristics, so the corresponding utilization of sunlight can also have different forms.
The dye wastewater has complex components, high chromaticity and more suspended matters, and is industrial wastewater which is difficult to treat, and the dye wastewater often contains a plurality of toxic substances, such as heavy metals, phenolic compounds and the like, and if the dye wastewater is directly discharged into the nature, immeasurable great harm is caused to the environment. The two methods have the defects that the former method has high energy consumption, and the latter method has low treatment efficiency.
Therefore, the solar photocatalytic degradation is used for treating sewage, but the common solar photocatalytic degradation device has the following defects:
1. the sewage can not be fully contacted with the photocatalyst and is fully mixed, so that the catalytic degradation efficiency is reduced.
2. The sewage can give off toxic gas, and general photocatalysis degradation device only degrades to sewage, can't degrade the toxic gas who gives off, and toxic gas directly causes the pollution of air.
3. In sewage treatment, can directly drop into the waste water with photocatalyst powder, impurity in the waste water or flocculus can glue at the photocatalyst surface, surround the photocatalyst to reduce the degradation effect of photocatalyst, made photocatalyst lose the activity, and directly put in photocatalyst powder greatly increased the catalytic degradation cost.
4. The sewage contains various impurities, so the visibility is low, and the catalytic degradation capability of the photocatalyst is greatly reduced.
Therefore, a self-adaptive two-phase solar photocatalytic degradation device is needed to solve the above problems.
Disclosure of Invention
In view of the above situation, in order to overcome the defects of the prior art, the invention provides a self-adaptive two-phase solar photocatalytic degradation device, which solves the problem of degradation treatment of sewage and toxic gas emitted by sewage at the same time, increases the photocatalytic contact area between a photocatalyst and the sewage in the degradation process, enables the photocatalyst to be fully contacted with the sewage, increases the light transparency between the photocatalyst and the toxic gas, increases the catalytic action of the photocatalyst, and improves the catalytic degradation efficiency of the toxic gas.
The technical scheme adopted by the invention is as follows: the invention relates to a self-adaptive two-phase solar photocatalytic degradation device, which comprises a degradation shell and a transparent glass cover above the degradation shell, and is characterized in that: the inner bottom wall of the degradation shell is provided with a self-adaptive height adjusting assembly, the upper part of the self-adaptive height adjusting assembly is provided with an air jet curved surface capturing two-phase degradation mechanism, the inner part of the air jet curved surface capturing two-phase degradation mechanism is provided with a circulating uninterrupted air suction assembly, the circulating uninterrupted air suction assembly is provided with a magnetic type nondestructive decontamination assembly, the upper part of the air jet curved surface capturing two-phase degradation mechanism is provided with an upper supporting and fixing plate, the outer wall of the upper supporting and fixing plate is provided with a self-adjusting buoyancy float, the upper wall array of the upper supporting and fixing plate is provided with a degradation light gathering assembly, the air jet curved surface capturing two-phase degradation mechanism comprises an air jet disturbance rotating assembly and a gas-liquid two-phase multipurpose degradation assembly, the air jet disturbance rotating assembly is arranged at the lower part of the self-adaptive height adjusting assembly, and the gas-liquid two-phase multipurpose degradation assembly is arranged on the self-adaptive height adjusting assembly, the upper part of the outer wall of the degradation shell is provided with a mobile solar component.
In order to solve because the operation of sewage surface of water height and influence device, self-adaptation altitude mixture control subassembly is including supporting the regulation section of thick bamboo, supporting the regulation post, connecting the rolling disc, adjusting the dog and supporting the rolling disc, support the cavity setting that the regulation section of thick bamboo is lower part open-ended, support and adjust a section of thick bamboo lower extreme and run through the interior diapire of degradation casing, support and adjust a section of thick bamboo array and locate the interior diapire of degradation casing, adjust the dog and locate in supporting the regulation section of thick bamboo, support and adjust the post and locate the adjustable fender upper wall, support and adjust the post and run through and support the regulation section of thick bamboo upper wall, it locates and support the regulation post upper end to connect the rolling disc, it locates and connects the rolling disc upper wall to support the rolling disc rotation.
Preferably, the gas-liquid two-phase multipurpose degradation component comprises a catalytic degradation reaction cylinder, a light guide plate, an outer photocatalyst layer, an air outlet connecting cavity, an air inlet connecting cavity, a spiral gas degradation tube and an inner photocatalyst layer, wherein the catalytic degradation reaction cylinder is arranged on the upper wall of a supporting rotating disc in an array mode, the catalytic degradation reaction cylinder is arranged in a hollow cavity mode, the catalytic degradation reaction cylinder is arranged in a transparent mode, the air outlet connecting cavity is arranged on the inner bottom wall of the catalytic degradation reaction cylinder, the air inlet connecting cavity is arranged on the inner bottom wall of the catalytic degradation reaction cylinder, the air outlet connecting cavity and the air inlet connecting cavity are symmetrically arranged, the spiral gas degradation tube is arranged in a U shape, one end of the spiral gas degradation tube is arranged at the upper end of the air inlet connecting cavity, the spiral gas degradation tube is communicated with the air inlet connecting cavity, and the other end of the spiral gas degradation tube is arranged at the upper end of the air outlet connecting cavity, the spiral gas degradation pipe is communicated with the gas outlet connecting cavity, the light guide plate is arranged in a cylindrical mode, the light guide plate is arranged between the inner bottom wall and the inner upper wall of the catalytic degradation reaction cylinder, the light guide plate is arranged between the inner wall of the catalytic degradation reaction cylinder and the spiral gas degradation pipe, the inner photocatalyst layer is arranged on the inner side wall of the spiral gas degradation pipe, the outer photocatalyst layer is arranged on the outer side wall of the catalytic degradation reaction cylinder, the toxic substances in sewage and the gas emitted by the sewage are degraded simultaneously under the catalytic degradation effect of the inner photocatalyst layer and the outer photocatalyst layer, and the sewage is subjected to thorough catalytic degradation.
In order to increase the internal disturbance effect of degradation casing, the rotatory subassembly of gas jet disturbance includes disturbance outlet duct, check valve, disturbance gas output casing, gaseous horizontal output tube and gaseous disturbance output tube, the disturbance outlet duct is the setting of L type, disturbance outlet duct one end is run through and is supported rolling disc diapire and catalytic degradation reaction cylinder diapire, disturbance outlet duct one end communicates with each other with the connection cavity of giving vent to anger, the disturbance outlet duct other end is located to the disturbance gas output casing, the lateral wall of disturbance gas output casing one side is located to gaseous horizontal output tube array, gaseous horizontal output tube level sets up, disturbance gas output casing lower wall is located to gaseous disturbance output tube array, the vertical setting of gaseous disturbance output tube, the check valve is located and is close to disturbance gas output casing department on the disturbance outlet duct.
In order to realize the suction of toxic gas in a degradation shell, the circulating uninterrupted air suction assembly comprises a control support shell, a sliding isolation cylinder, a control slider, a reciprocating lead screw, a control motor, a gas circulating piston ring, a sliding magnetic layer II and a sliding magnetic layer III, wherein the support shell is arranged in a hollow cavity, the sliding isolation cylinder is arranged in the support shell, the inner wall array of the sliding isolation cylinder is provided with a limiting chute, the lower end of the reciprocating lead screw is rotatably arranged at the center of the inner bottom wall of the control support shell, the reciprocating lead screw is arranged in the sliding isolation cylinder, the upper end of the reciprocating lead screw penetrates through the center of the lower wall of an upper support fixing plate, the control slider is arranged in the sliding isolation cylinder, the control slider is connected with the reciprocating lead screw through threads, the outer wall array of the control slider is provided with the limiting slider, the limiting slider is arranged in the limiting chute, and the outer wall of the limiting slider is provided with a sliding magnetic block, the gas circulation piston ring is arranged between the control support shell inner wall and the sliding isolation cylinder, the gas circulation piston ring inner wall is arranged on the sliding magnetic layer III, the gas circulation piston ring outer wall is arranged on the sliding magnetic layer II, a motor placing groove is formed in the center of the upper wall of the upper support fixing plate, the control motor is arranged in the motor placing groove, and the control motor is connected with the reciprocating screw rod.
Preferably, the formula of magnetism is inhaled harmless scrubbing subassembly is including connecting slip ring, slip magnetic layer one, connecting rod, scrubbing clearance ring and filth clearance cotton, it supports the casing outer wall to connect the slip ring cover and locate control, slip magnetic layer one is located and is connected the slip ring inner wall, catalytic degradation reaction section of thick bamboo outer wall is located to the scrubbing clearance ring cover, scrubbing clearance ring lateral wall is located to connecting rod one end, the connecting rod other end is located and is connected the slip ring lateral wall, the intraductal wall of scrubbing clearance is located to filth clearance cotton.
The degradation light gathering component comprises a light gathering support frame, an optical fiber and a light gathering lens, the light gathering support frame is arranged on the upper wall of the upper supporting and fixing plate, the light gathering lens is arranged on the light gathering lens, the optical fiber penetrates through the catalytic degradation reaction cylinder and the upper supporting and fixing plate, and one end of the optical fiber is arranged on the light gathering lens.
In the device, an upper degradation air suction pipe is arranged on an upper array of the outer wall of the control support shell, the other end of the upper degradation air suction pipe penetrates through an upper support fixing plate, a lower degradation air suction pipe is arranged on a lower array of the outer wall of the control support shell, the other end of the lower degradation air suction pipe penetrates through the upper support fixing plate, an upper degradation air outlet pipe is arranged on the upper array of the outer wall of the control support shell, the other end of the upper degradation air outlet pipe penetrates through the lower part of the outer wall of the catalytic degradation reaction cylinder, the upper degradation air outlet pipe is connected with an air inlet connecting cavity, a lower degradation air outlet pipe is arranged on the lower array of the outer wall of the control support shell, the other end of the lower degradation air outlet pipe penetrates through the lower part of the outer wall of the catalytic degradation reaction cylinder, the lower degradation air outlet pipe is connected with the air inlet connecting cavity, an upper air suction check valve is arranged on the upper degradation air suction pipe, and an upper air outlet check valve is arranged on the upper degradation air outlet pipe, the lower degradation air suction pipe is provided with a lower air suction one-way valve, the lower degradation air outlet pipe is provided with a lower air outlet one-way valve, the disturbance air outlet pipe is provided with a cover body air-drying pipe, and the cover body air-drying pipe penetrates through the lower wall of the supporting rotating disc and the self-adjusting buoyancy floating lower wall.
In order to make full use of the clean energy of solar energy, remove solar energy component including slip cell body, vertical support frame, horizontal support frame and solar photovoltaic board, the slip cell body is the setting of ring type, vertical support frame is convex setting, vertical support frame slides and locates in the sliding tray body, vertical support frame lateral wall is located to horizontal backup pad, the solar photovoltaic board is located on horizontal backup pad and the vertical support frame, the solar photovoltaic board is connected with the rotating electrical machines electricity.
In the device, a liquid inlet is arranged on one side of the outer wall of the degradation shell, and a liquid outlet is arranged on the lower part of the other side of the outer wall of the degradation shell.
The invention with the structure has the following beneficial effects:
1. the self-adjusting buoyancy floats to play a role in dynamic support, the adjusting stop block and the supporting adjusting column slide in the supporting adjusting cylinder, and the dynamic automatic adjusting device is arranged at the height according to different heights of sewage in the degradation shell.
2. In the gas-liquid two-phase multipurpose degradation component, the toxic substances in sewage and gas emitted by the sewage are degraded simultaneously by utilizing the principle of versatility and the catalytic degradation effect of the photocatalyst, so that the sewage is subjected to thorough catalytic degradation, and the problem of degradation defect that the toxic substances in the sewage can only be treated in a single way in a common device is solved.
3. Spiral gas degradation pipe in the gas-liquid two-phase multipurpose degradation subassembly sets up to U style of calligraphy helical structure, has increased the area of contact of the interior photocatalyst of spiral gas degradation pipe internal surface and gas, has increased gaseous toxic substance's seizure, has increased catalytic degradation's efficiency.
4. In the gas jet flow disturbance rotating assembly, the disturbance gas output shell is provided with a horizontal gas transverse output pipe and a vertical gas disturbance output pipe, gas after catalytic degradation is guided to form acting forces in different directions, the transverse acting forces provide rotating power for capturing the two-phase degradation mechanism by the gas jet flow curved surface, the catalytic degradation reaction cylinder can stir sewage and greatly improve the capability of capturing harmful substances in the sewage, and the vertical gas jet flow disturbs turbid substances at the bottom of the degradation shell so that the turbid substances are in the disturbance capture range of the catalytic degradation reaction cylinder.
5. The transparent light guide plate is arranged between the catalytic degradation reaction cylinder and the spiral gas degradation tube in a tubular structure, light transmitted by the optical fiber is uniformly guided into the catalytic degradation reaction cylinder, the problem that the length and the contact area of the catalytic degradation reaction cylinder and the spiral gas degradation tube need to be increased, so that the capturing capacity of toxic substances is increased, and the size needs to be reduced is solved, so that the light transmitted by the optical fiber can comprehensively cover the catalytic degradation reaction cylinder and the spiral gas degradation tube, and the technical problem of contradiction of catalytic effects of an outer photocatalyst layer and an inner photocatalyst layer is stimulated to the maximum degree.
6. The circulation does not have the reciprocal effect stroke of breathing in the subassembly through reciprocal lead screw, and the cooperation check valve will degrade the toxic gas in the casing and inhale to spiral gaseous degradation intraductally on the one hand, and the air jet that provides the catalytic degradation of two-way effort simultaneously for air jet disturbance rotating assembly through the effect of magnetism, provides power for the harmless scrubbing subassembly of formula is inhaled to magnetism.
7. The magnetism is inhaled and is set up filth clearance cotton in the harmless scrubbing subassembly on the clearance ring, has solved the flocculent pollutant in the sewage and has glued and glue at catalytic degradation reaction section of thick bamboo outer wall, wraps up outer photocatalyst layer, influences the technical problem on the catalytic effect on outer photocatalyst layer, has also avoided the technical problem that can harm outer photocatalyst layer simultaneously in the clearance process.
8. The gas after the catalytic degradation forms the gas flow in the catalytic degradation reaction cylinder simultaneously, and the mobility of the gas has avoided in the catalytic degradation cylinder because of forming vapor for the difference in temperature, attached to catalytic degradation reaction cylinder, light guide plate and spiral gas degradation pipe, has influenced the effect of light to the catalysis of external photocatalyst layer and interior photocatalyst layer.
9. The transparent glass cover can prevent toxic gas from overflowing due to stirring and provide sufficient sunlight.
10. The solar photovoltaic panel provides clean energy power for the control motor, and full utilization of sunlight is achieved.
Drawings
FIG. 1 is a schematic diagram of an internal three-dimensional structure of a self-adaptive two-phase solar photocatalytic degradation device provided by the invention;
FIG. 2 is a schematic view of a connection structure of an upper degradation air suction pipe, a lower degradation air suction pipe, an upper degradation air outlet pipe and a lower degradation air outlet pipe of the self-adaptive two-phase solar photocatalytic degradation device provided by the invention;
FIG. 3 is a schematic diagram of an internal structure of a circulating uninterrupted air suction assembly of the self-adaptive two-phase solar photocatalytic degradation device provided by the invention;
FIG. 4 is a top view of the internal structure of a self-adaptive two-phase solar photocatalytic degradation device according to the present invention;
FIG. 5 is a schematic view of the internal structure of an air jet curved surface capture two-phase degradation mechanism of the self-adaptive two-phase solar photocatalytic degradation device provided by the invention;
FIG. 6 is a schematic structural view of a magnetic attraction type nondestructive decontamination assembly of the self-adaptive two-phase solar photocatalytic degradation device provided by the invention;
FIG. 7 is an enlarged view of portion A of FIG. 2;
FIG. 8 is an enlarged view of portion B of FIG. 1;
FIG. 9 is a schematic structural diagram of an adaptive height adjustment assembly of an adaptive two-phase solar photocatalytic degradation device according to the present invention;
fig. 10 is a schematic sectional view taken along line a-a in fig. 3.
Wherein, 1, a degradation shell, 2, a transparent glass cover, 3, a self-adaptive height adjusting component, 4, a gas jet curved surface capturing two-phase degradation mechanism, 5, a circulating uninterrupted air suction component, 6, a magnetic attraction type nondestructive decontamination component, 7, an upper supporting fixed plate, 8, a self-adjusting buoyancy float, 9, a degradation light gathering component, 10, a gas jet disturbance rotating component, 11, a gas-liquid two-phase multipurpose degradation component, 12, a supporting adjusting cylinder, 13, a supporting adjusting column, 14, a connecting rotating disc, 15, an adjusting stop block, 16, a supporting rotating disc, 17, a catalytic degradation reaction cylinder, 18, a light guide plate, 19, an outer photocatalyst layer, 20, an air outlet connecting cavity, 21, an air inlet connecting cavity, 22, a spiral gas degradation pipe, 23, an inner photocatalyst layer, 24, a disturbance air outlet pipe, 25, an anti-backflow absorbing one-way valve, 26, a disturbance gas output shell, 27, a gas transverse output pipe, 28. the device comprises a gas disturbance output pipe, 29, a control support shell, 30, a sliding isolation cylinder, 31, a control slide block, 32, a reciprocating lead screw, 33, a control motor, 34, a gas circulation piston ring, 35, a sliding magnetic layer II, 36, a sliding magnetic layer III, 37, a limiting slide groove, 38, a limiting slide block, 39, a sliding magnetic block, 40, a motor placing groove, 41, a connecting slide ring, 42, a sliding magnetic layer I, 43, a connecting rod, 44, a decontamination cleaning ring, 45, dirt cleaning cotton, 46, a light gathering support frame, 47, optical fiber, 48, a light gathering mirror, 49, an upper degradation air suction pipe, 50, a lower degradation air desorption pipe, 51, an upper degradation air outlet pipe, 52, a lower degradation air outlet pipe, 53, an upper air suction one-way valve, 54, an upper air outlet one-way valve, 55, a lower air suction one-way valve, 56, a lower air outlet one-way valve, 57, a cover body blowing dry pipe, 58, a sliding groove body, 59 and a vertical support frame, 60. horizontal support frame, 61, solar photovoltaic board, 62, inlet, 63, liquid outlet, 64, removal solar energy component.
The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this specification, illustrate embodiments of the invention and together with the description serve to explain the principles of the invention and not to limit the invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments; all other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "left", "right", "top", "bottom", "inner", "outer", and the like, indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, and are only for convenience in describing the present invention and simplifying the description, but do not indicate or imply that the device or element referred to must have a particular orientation, be constructed in a particular orientation, and be operated, and thus should not be construed as limiting the present invention.
As shown in fig. 1, a self-adaptive two-phase solar photocatalytic degradation device comprises a degradation shell 1 and a transparent glass cover 2 arranged above the degradation shell, and is characterized in that: the inner bottom wall of the degradation shell 1 is provided with a self-adaptive height adjusting component 3, the upper part of the self-adaptive height adjusting component 3 is provided with an air jet curved surface capturing two-phase degradation mechanism 4, the inside of the air jet curved surface capturing two-phase degradation mechanism 4 is provided with a circulating uninterrupted air suction component 5, the circulating uninterrupted air suction component 5 is provided with a magnetic type nondestructive decontamination component 6, the upper part of the air jet curved surface capturing two-phase degradation mechanism 4 is provided with an upper supporting fixed plate 7, the outer wall of the upper supporting fixed plate 7 is provided with a self-adjusting buoyancy float 8, the upper wall array of the upper supporting fixed plate 7 is provided with a degradation light focusing component 9, the air jet curved surface capturing two-phase degradation mechanism 4 comprises an air jet disturbance rotating component 10 and a gas-liquid two-phase multipurpose degradation component 11, the air jet disturbance rotating component 10 is arranged at the lower part of the self-adaptive height adjusting component 3, the gas-liquid two-phase multipurpose degradation component 11 is arranged on the self-adaptive height adjusting component 3, the upper part of the outer wall of the degradation shell 1 is provided with a mobile solar component 64.
As shown in fig. 1 and fig. 9, the adaptive height adjusting assembly 3 comprises a supporting adjusting cylinder 12, a supporting adjusting column 13, a connecting rotating disc 14, an adjusting block 15 and a supporting rotating disc 16, wherein the supporting adjusting cylinder 12 is a hollow cavity with an open lower part, the lower end of the supporting adjusting cylinder 12 penetrates through the inner bottom wall of the degradation shell 1, the supporting adjusting cylinder 12 is arranged at the inner bottom wall of the degradation shell 1 in an array manner, the adjusting block 15 is arranged in the supporting adjusting cylinder 12, the supporting adjusting column 13 is arranged at the upper wall of an adjusting baffle, the supporting adjusting column 13 penetrates through the upper wall of the supporting adjusting cylinder 12, the connecting rotating disc 14 is arranged at the upper end of the supporting adjusting column 13, the supporting rotating disc 16 is rotatably arranged at the upper wall of the connecting rotating disc 14, the self-adjusting buoyancy float 8 plays a role of dynamic support, and the adjusting block 15 and the supporting adjusting column 13 slide in the supporting adjusting cylinder 12, according to different heights of sewage in the degradation shell 1, the height of the dynamic automatic adjusting device is adjusted.
As shown in fig. 1 and 5, the gas-liquid two-phase multipurpose degradation assembly 11 includes a catalytic degradation reaction cylinder 17, a light guide plate 18, an outer photocatalyst layer 19, an outlet connection cavity 20, an inlet connection cavity 21, a spiral gas degradation tube 22 and an inner photocatalyst layer 23, the catalytic degradation reaction cylinder 17 is arranged on the upper wall of the support rotary disc 16 in an array manner, the catalytic degradation reaction cylinder 17 is arranged in a hollow cavity manner, the catalytic degradation reaction cylinder 17 is arranged in a transparent manner, the outlet connection cavity 20 is arranged on the inner bottom wall of the catalytic degradation reaction cylinder 17, the inlet connection cavity 21 is arranged on the inner bottom wall of the catalytic degradation reaction cylinder 17, the outlet connection cavity 20 and the inlet connection cavity 21 are symmetrically arranged, the spiral gas degradation tube 22 is arranged in a U-shape, one end of the spiral gas degradation tube 22 is arranged at the upper end of the inlet connection cavity 21, the spiral gas degradation tube 22 is communicated with the inlet connection cavity 21, the other end of the spiral gas degradation tube 22 is arranged at the upper end of the outlet connection cavity 20, the spiral gas degradation tube 22 is communicated with the gas outlet connection cavity 20, the light guide plate 18 is arranged in a cylindrical shape, the light guide plate 18 is arranged between the inner bottom wall and the inner upper wall of the catalytic degradation reaction cylinder 17, the light guide plate 18 is arranged between the inner wall of the catalytic degradation reaction cylinder 17 and the spiral gas degradation tube 22, the inner photocatalyst layer 23 is arranged on the inner side wall of the spiral gas degradation tube 22, the outer photocatalyst layer 19 is arranged on the outer side wall of the catalytic degradation reaction cylinder 17, the catalytic degradation effect of the inner photocatalyst layer 23 and the outer photocatalyst layer 19 is adopted, the sewage and toxic substances in the gas emitted by the sewage are degraded simultaneously, the sewage is subjected to thorough catalytic degradation, and the problem of degradation defect that only toxic substances in the sewage can be treated in a single mode in a common device is solved.
As shown in fig. 2 and 7, the gas jet disturbance rotating assembly 10 includes a disturbance outlet pipe 24, a suck-back prevention check valve 25, a disturbance gas output casing 26, a gas transverse output pipe 27 and a gas disturbance output pipe 28, the disturbance outlet pipe 24 is disposed in an L-shape, one end of the disturbance outlet pipe 24 penetrates through the bottom wall of the support rotating disk 16 and the bottom wall of the catalytic degradation reaction cylinder 17, one end of the disturbance outlet pipe 24 is communicated with the gas outlet connection cavity 20, the disturbance gas output casing 26 is disposed at the other end of the disturbance outlet pipe 24, the gas transverse output pipes 27 are disposed on one side wall of the disturbance gas output casing 26 in an array, the gas transverse output pipes 27 are disposed horizontally, the gas disturbance output pipes 28 are disposed at the lower wall of the disturbance gas output casing 26 in an array, the gas disturbance outlet pipe 28 is disposed vertically, the suck-back prevention check valve 25 is disposed on the disturbance outlet pipe 24 near the disturbance gas output casing 26, wherein the disturbance gas output casing 26 is provided with the horizontal gas transverse output pipe 27 and the vertical gas disturbance output pipe 28, the gas after the catalytic degradation is guided to form acting forces in different directions, the transverse acting force provides rotating power for the air jet curved surface to capture the two-phase degradation mechanism 4, the catalytic degradation reaction cylinder 17 can stir the sewage and greatly improve the capture capacity of harmful substances in the sewage, and the vertical air jet disturbs the turbid materials at the bottom of the degradation shell 1, so that the turbid materials are in the disturbance capture range of the catalytic degradation reaction cylinder 17.
As shown in fig. 3, the circulating uninterrupted air suction assembly 5 comprises a control support housing 29, a sliding isolation cylinder 30, a control slider 31, a reciprocating lead screw 32, a control motor 33, an air circulating piston ring 34, a second sliding magnetic layer 35 and a third sliding magnetic layer 36, wherein the support housing is arranged in a hollow cavity, the sliding isolation cylinder 30 is arranged in the support housing, a limit chute 37 is arranged on an inner wall array of the sliding isolation cylinder 30, the lower end of the reciprocating lead screw 32 is rotatably arranged at the center of an inner bottom wall of the control support housing 29, the reciprocating lead screw 32 is arranged in the sliding isolation cylinder 30, the upper end of the reciprocating lead screw 32 penetrates through the center of the lower wall of the upper support fixing plate 7, the control slider 31 is arranged in the sliding isolation cylinder 30, the control slider 31 is connected with the reciprocating lead screw 32 through a thread, a limit slider 38 is arranged on an outer wall array of the control slider 31, the limit slider 38 is arranged in the limit chute 37, and a sliding magnetic block 39 is arranged on an outer wall of the limit slider 38, the gas circulation piston ring 34 is arranged between the inner wall of the control support shell 29 and the sliding isolation cylinder 30, the sliding magnetic layer III 36 is arranged on the inner wall of the gas circulation piston ring 34, the sliding magnetic layer II 35 is arranged on the outer wall of the gas circulation piston ring 34, the motor placing groove 40 is arranged at the center of the upper wall of the upper support fixing plate 7, the control motor 33 is arranged in the motor placing groove 40, and the control motor 33 is connected with the reciprocating screw rod 32.
As shown in fig. 2 and 6, the magnetic-type nondestructive decontamination assembly 6 comprises a connecting slip ring 41, a sliding magnetic layer 42, a connecting rod 43, a decontamination cleaning ring 44 and a dirt cleaning cotton 45, the sliding ring 41 is connected to be sleeved on the outer wall of the control support shell 29, the sliding magnetic layer 42 is arranged on the inner wall of the connecting slip ring 41, the decontamination cleaning ring 44 is sleeved on the outer wall of the catalytic degradation reaction cylinder 17, one end of the connecting rod 43 is arranged on the side wall of the decontamination cleaning ring 44, the other end of the connecting rod 43 is arranged on the side wall of the connecting slip ring 41, and the dirt cleaning cotton 45 is arranged on the inner side wall of the decontamination cleaning ring 44.
As shown in fig. 1 and 8, the degradation light-gathering component 9 includes a light-gathering support frame 46, an optical fiber 47 and a light-gathering lens 48, the light-gathering support frame 46 is disposed on the upper wall of the upper support fixing plate 7, the light-gathering lens 48 is disposed on the light-gathering lens 48, the optical fiber 47 penetrates through the catalytic degradation reaction cylinder 17 and the upper support fixing plate 7, and one end of the optical fiber 47 is disposed on the light-gathering lens 48.
As shown in fig. 3, the upper portion of the outer wall of the control support casing 29 is provided with an upper degradation air intake pipe 49 in an array manner, the other end of the upper degradation air intake light penetrates through the upper support fixing plate 7, the lower portion of the outer wall of the control support casing 29 is provided with a lower degradation air intake pipe 50 in an array manner, the other end of the lower degradation air intake pipe 50 penetrates through the upper support fixing plate 7, the upper portion of the outer wall of the control support casing 29 is provided with an upper degradation air outlet pipe 51 in an array manner, the other end of the upper degradation air outlet pipe 51 penetrates through the lower portion of the outer wall of the catalytic degradation reaction cylinder 17, the upper degradation air outlet pipe 51 is connected with the air inlet connection cavity 21, the lower portion of the outer wall of the control support casing 29 is provided with a lower degradation air outlet pipe 52 in an array manner, the other end of the lower degradation air outlet pipe 52 penetrates through the lower portion of the outer wall of the catalytic degradation reaction cylinder 17, the lower degradation air outlet pipe 52 is connected with the air inlet connection cavity 21, the upper degradation air intake check valve 53 is arranged on the upper degradation air intake pipe 49, an upper air outlet one-way valve 54 is arranged on the upper degradation air outlet pipe 51, a lower air inlet one-way valve 55 is arranged on the lower degradation air inlet pipe 50, a lower air outlet one-way valve 56 is arranged on the lower degradation air outlet pipe 52, a cover body air-drying pipe 57 is arranged on the disturbance air outlet pipe 24, and the cover body air-drying pipe 57 penetrates through the lower wall of the supporting rotating disc 16 and the lower wall of the self-adjusting buoyancy float 8.
As shown in fig. 3, the mobile solar module 64 includes a sliding groove 58, a vertical support frame 59, a horizontal support frame 60 and a solar photovoltaic panel 61, the sliding groove 58 is arranged in a circular ring shape, the vertical support frame 59 is arranged in a circular arc shape, the vertical support frame 59 is arranged in the sliding groove 58 in a sliding manner, the horizontal support plate is arranged on the side wall of the vertical support frame 59, the solar photovoltaic panel 61 is arranged on the horizontal support plate and the vertical support frame 59, and the solar photovoltaic panel 61 is electrically connected with the rotating motor.
As shown in fig. 1, a liquid inlet 62 is disposed on one side of the outer wall of the degradation casing 1, and a liquid outlet 63 is disposed on the lower portion of the other side of the outer wall of the degradation casing 1, so that sewage can be conveniently introduced into the degradation casing 1 and degraded water can be conveniently led out from the liquid outlet 63.
When the device is used specifically, after the device is placed stably, sewage is input into the degradation shell 1 from the liquid inlet 62 until the self-adjusting buoyancy floats on the surface of the sewage, at the moment, the supporting adjusting column 13 and the adjusting block 15 slide in the supporting adjusting cylinder 12, the sewage heights of different heights in the degradation shell 1 can be met, the device stably floats in the degradation shell 1, in order to excite the outer photocatalyst layer 19 to degrade toxic substances in the sewage and the inner photocatalyst layer 23 to degrade toxic gases, sunlight penetrates through the transparent glass cover 2 and enters the optical fiber 47 through the light collecting lens 48, the optical fiber 47 conducts the light into the catalytic degradation reaction cylinder 17, the light is conducted into the whole catalytic degradation reaction cylinder 17 under the action of the light guide plate 18, at the moment, the inner photocatalyst layer 23 and the outer photocatalyst layer 19 play a degrading role, the vertical supporting frame 59 is moved to slide in the sliding groove body 58 according to the irradiation angle of the sunlight, the solar photovoltaic panel 61 makes full use of the sunlight, the solar photovoltaic panel 61 supplies power to the control motor 33, the control motor 33 is started, the control motor 33 drives the reciprocating screw rod 32 to rotate, the reciprocating screw rod 32 drives the control slide block 31 to move up and down, the sliding magnet 39 of the control slide block 31 drives the gas circulation piston ring 34 to move up and down, when the gas circulation piston ring 34 moves down to compress the gas in the control support housing 29, the gas enters the gas inlet connection cavity 21 through the lower gas outlet one-way valve 56 and the descending relief gas pipe 52, enters the spiral gas degradation pipe 22 through the connection cavity, enters the gas outlet connection cavity 20 after the catalytic degradation of the inner photocatalyst layer 23, then enters the disturbance gas outlet pipe 24 and the disturbance gas output housing 26, the gas is sprayed out from the gas disturbance outlet pipe 28 to disturb the sewage at the lower part of the degradation housing 1, when the gas is sprayed out from the gas transverse output pipe 27, the disturbance gas output shell 26 is driven to rotate due to the reverse acting force of the sprayed gas, the disturbance gas outlet pipe 24 is driven to rotate by the gas output shell, the supporting rotating disc 16 is driven to rotate, the catalytic degradation reaction cylinder 17 is driven to rotate by the supporting rotating disc 16, the effect of stirring and degrading the sewage in the shell 1 is achieved, meanwhile, the toxic substances in the sewage captured by the outer photocatalyst layer 19 are increased, the gas pressure at the upper part of the gas circulation piston ring 34 is reduced, the toxic gas in the degradation shell 1 is sucked into the degradation shell 1 through the upper degradation gas suction pipe 49 and the upper gas suction check valve 53, when the gas circulation piston ring 34 moves upwards, the sucked toxic gas enters the gas inlet connecting cavity 21 through the upper degradation gas outlet pipe 51 and the upper gas outlet check valve 54 and further enters the spiral gas degradation pipe 22, and the spiral gas degradation pipe 22 enables the toxic gas to be fully contacted with the inner photocatalyst layer 23 to be degraded, and the degraded gas is blown to the inner surface of the transparent glass cover 2 through the cover body blow-drying pipe 57, so that the influence of condensation of evaporated water vapor on the inner surface of the transparent glass cover 2 under the irradiation of sunlight on the sunlight entering the condenser 48 is avoided.
It is noted that, herein, relational terms such as first and second, and the like may be used solely to distinguish one entity or action from another entity or action without necessarily requiring or implying any actual such relationship or order between such entities or actions. Also, the terms "comprises," "comprising," or any other variation thereof, are intended to cover a non-exclusive inclusion, such that a process, method, article, or apparatus that comprises a list of elements does not include only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
The present invention and its embodiments have been described above, and the description is not intended to be limiting, and the drawings are only one embodiment of the present invention, and the actual structure is not limited thereto. In summary, those skilled in the art should appreciate that they can readily use the disclosed conception and specific embodiments as a basis for designing or modifying other structures for carrying out the same purposes of the present invention without departing from the spirit and scope of the invention as defined by the appended claims.

Claims (10)

1. The utility model provides a two-phase solar energy photocatalysis degradation device of self-adaptation, is including degrading the transparent glass cover of casing and top, its characterized in that: the inner bottom wall of the degradation shell is provided with a self-adaptive height adjusting assembly, the upper part of the self-adaptive height adjusting assembly is provided with an air jet curved surface capturing two-phase degradation mechanism, the inner part of the air jet curved surface capturing two-phase degradation mechanism is provided with a circulating uninterrupted air suction assembly, the circulating uninterrupted air suction assembly is provided with a magnetic type nondestructive decontamination assembly, the upper part of the air jet curved surface capturing two-phase degradation mechanism is provided with an upper supporting and fixing plate, the outer wall of the upper supporting and fixing plate is provided with a self-adjusting buoyancy float, the upper wall array of the upper supporting and fixing plate is provided with a degradation light gathering assembly, the air jet curved surface capturing two-phase degradation mechanism comprises an air jet disturbance rotating assembly and a gas-liquid two-phase multipurpose degradation assembly, the air jet disturbance rotating assembly is arranged at the lower part of the self-adaptive height adjusting assembly, and the gas-liquid two-phase multipurpose degradation assembly is arranged on the self-adaptive height adjusting assembly, the upper part of the outer wall of the degradation shell is provided with a mobile solar component.
2. The self-adaptive two-phase solar photocatalytic degradation device according to claim 1, characterized in that: the self-adaptation altitude mixture control subassembly is including supporting the regulation section of thick bamboo, supporting the regulation post, connecting the rolling disc, adjusting the dog and supporting the rolling disc, support the regulation section of thick bamboo and be lower part open-ended cavity setting, support and adjust a section of thick bamboo lower extreme and run through interior diapire of casing, support and adjust a section of thick bamboo array and locate the interior diapire of degradation casing, adjust the dog and locate to support in the regulation section of thick bamboo, support and adjust the post and locate the adjusting baffle upper wall, support and adjust the post and run through and support and adjust a section of thick bamboo upper wall, it locates to support the rolling disc and adjusts the post upper end to connect, it rotates and locates to connect the rolling disc upper wall to support the rolling disc.
3. The self-adaptive two-phase solar photocatalytic degradation device according to claim 2, characterized in that: the gas-liquid two-phase multipurpose degradation component comprises a catalytic degradation reaction cylinder, a light guide plate, an outer photocatalyst layer, an air outlet connecting cavity, an air inlet connecting cavity, a spiral gas degradation pipe and an inner photocatalyst layer, wherein the catalytic degradation reaction cylinder array is arranged on the upper wall of a supporting rotary disc, the catalytic degradation reaction cylinder is arranged in a hollow cavity, the catalytic degradation reaction cylinder is arranged in a transparent mode, the air outlet connecting cavity is arranged on the inner bottom wall of the catalytic degradation reaction cylinder, the air inlet connecting cavity is arranged on the inner bottom wall of the catalytic degradation reaction cylinder, the air outlet connecting cavity is symmetrically arranged with the air inlet connecting cavity, the spiral gas degradation pipe is arranged in a U shape, one end of the spiral gas degradation pipe is arranged at the upper end of the air inlet connecting cavity, the spiral gas degradation pipe is communicated with the air inlet connecting cavity, the other end of the spiral gas degradation pipe is arranged at the upper end of the air outlet connecting cavity, and the spiral gas degradation pipe is communicated with the air outlet connecting cavity, the light guide plate is arranged in a cylindrical mode, the light guide plate is arranged between the inner bottom wall and the inner upper wall of the catalytic degradation reaction cylinder, the light guide plate is arranged between the inner wall of the catalytic degradation reaction cylinder and the spiral gas degradation tube, the inner side wall of the spiral gas degradation tube is arranged on the inner photocatalyst layer, and the outer side wall of the catalytic degradation reaction cylinder is arranged on the outer photocatalyst layer.
4. The self-adaptive two-phase solar photocatalytic degradation device according to claim 3, characterized in that: the gas jet flow disturbance rotating assembly comprises a disturbance outlet pipe, a suck-back prevention check valve, a disturbance gas output shell, a gas transverse output pipe and a gas disturbance output pipe, wherein the disturbance outlet pipe is arranged in an L shape, one end of the disturbance outlet pipe penetrates through the bottom wall of a support rotating disc and the bottom wall of a catalytic degradation reaction cylinder, one end of the disturbance outlet pipe is communicated with a gas outlet connection cavity, the other end of the disturbance outlet pipe is arranged on the disturbance gas output shell, the gas transverse output pipe array is arranged on one side wall of the disturbance gas output shell, the gas transverse output pipe is horizontally arranged, the gas disturbance output pipe array is arranged on the lower wall of the disturbance gas output shell, the gas disturbance output pipe is vertically arranged, and the check valve is arranged on the disturbance outlet pipe and is close to the disturbance gas output shell.
5. The self-adaptive two-phase solar photocatalytic degradation device according to claim 4, characterized in that: the circulating uninterrupted air suction assembly comprises a control support shell, a sliding isolation cylinder, a control slider, a reciprocating lead screw, a control motor, an air circulating piston ring, a sliding magnetic layer II and a sliding magnetic layer III, wherein the support shell is arranged in a hollow cavity, the sliding isolation cylinder is arranged in the support shell, the inner wall array of the sliding isolation cylinder is provided with a limiting chute, the lower end of the reciprocating lead screw is rotatably arranged at the center of the inner bottom wall of the control support shell, the reciprocating lead screw is arranged in the sliding isolation cylinder, the upper end of the reciprocating lead screw penetrates through the center of the lower wall of an upper support fixing plate, the control slider is arranged in the sliding isolation cylinder, the control slider is in threaded connection with the reciprocating lead screw, the outer wall array of the control slider is provided with the limiting slider, the limiting slider is arranged in the limiting chute, the outer wall of the limiting slider is provided with a sliding magnetic block, and the air circulating piston ring is arranged between the inner wall of the control support shell and the sliding isolation cylinder, the gas circulation piston ring inner wall is located to slip magnetic layer three, gas circulation piston ring outer wall is located to slip magnetic layer two, it is equipped with the motor standing groove to go up support fixed plate upper wall center department, control motor locates in the motor standing groove, control motor and reciprocal lead screw connection.
6. The self-adaptive two-phase solar photocatalytic degradation device according to claim 5, characterized in that: the magnetic type nondestructive decontamination assembly comprises a connecting sliding ring, a first sliding magnetic layer, a connecting rod, a decontamination cleaning ring and a sewage cleaning cotton body, wherein the connecting sliding ring is sleeved on the outer wall of the control supporting shell, the first sliding magnetic layer is arranged on the inner wall of the connecting sliding ring, the decontamination cleaning ring is sleeved on the outer wall of the catalytic degradation reaction barrel, one end of the connecting rod is arranged on the side wall of the decontamination cleaning ring, the other end of the connecting rod is arranged on the side wall of the connecting sliding ring, and the sewage cleaning cotton body is arranged on the inner side wall of the decontamination cleaning ring.
7. The self-adaptive two-phase solar photocatalytic degradation device according to claim 6, characterized in that: the degradation spotlight subassembly includes spotlight support frame, optical fiber and condensing lens, the spotlight support frame is located and is supported the fixed plate upper wall, the condensing lens is located on the condensing lens, optical fiber runs through catalytic degradation reaction cylinder and last support fixed plate, optical fiber one end is located on the condensing lens.
8. The self-adaptive two-phase solar photocatalytic degradation device according to claim 7, characterized in that: the upper array of the outer wall of the control support shell is provided with an upper degradation air suction pipe, the other end of the upper degradation air suction pipe penetrates through an upper support fixing plate, the lower array of the outer wall of the control support shell is provided with a lower degradation air suction pipe, the other end of the lower degradation air suction pipe penetrates through an upper support fixing plate, the upper array of the outer wall of the control support shell is provided with an upper degradation air outlet pipe, the other end of the upper degradation air outlet pipe penetrates through the lower part of the outer wall of the catalytic degradation reaction cylinder, the upper degradation air outlet pipe is connected with an air inlet connecting cavity, the lower array of the outer wall of the control support shell is provided with a lower degradation air outlet pipe, the other end of the lower degradation air outlet pipe penetrates through the lower part of the outer wall of the catalytic degradation reaction cylinder, the lower degradation air outlet pipe is connected with the air inlet connecting cavity, the upper degradation air suction check valve is arranged on the upper degradation air outlet pipe, and the lower degradation air suction check valve is arranged on the lower degradation air suction pipe, the descending relief air outlet pipe is provided with a lower air outlet one-way valve, the disturbance air outlet pipe is provided with a cover body blowing-dry pipe, and the cover body blowing-dry pipe penetrates through the lower wall of the supporting rotating disc and the self-regulation buoyancy floating lower wall.
9. The self-adaptive two-phase solar photocatalytic degradation device according to claim 8, characterized in that: the movable solar component comprises a sliding groove body, a vertical supporting frame, a transverse supporting frame and a solar photovoltaic plate, wherein the sliding groove body is arranged in a circular ring shape, the vertical supporting frame is arranged in a circular arc shape, the vertical supporting frame is arranged in the sliding groove body in a sliding mode, the transverse supporting frame is arranged on the side wall of the vertical supporting frame, the solar photovoltaic plate is arranged on the transverse supporting frame and the vertical supporting frame, and the solar photovoltaic plate is electrically connected with the rotating motor.
10. The self-adaptive two-phase solar photocatalytic degradation device according to claim 9, characterized in that: a liquid inlet is formed in one side of the outer wall of the degradation shell, and a liquid outlet is formed in the lower portion of the other side of the outer wall of the degradation shell.
CN202111558629.4A 2021-12-20 2021-12-20 Self-adaptive two-phase solar photocatalytic degradation device Active CN114291865B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2409954A1 (en) * 2010-07-20 2012-01-25 National Center for Scientific Research Demokritos Photocatalytic purification device
CN102363047A (en) * 2011-06-29 2012-02-29 大连林桥科技有限公司 Photo-catalyst air purifier
CN104528871A (en) * 2015-01-04 2015-04-22 安徽理工大学 Solar photocatalytic degradation device
CN107032442A (en) * 2017-05-08 2017-08-11 东北大学秦皇岛分校 A kind of solar energy utilization system for integrating photovoltaic generation and photocatalysis Water warfare
CN108744958A (en) * 2018-06-05 2018-11-06 邢明 A kind of gas-phase photocatalysis reaction unit for volatile organic matter of degrading
CN113198322A (en) * 2021-05-11 2021-08-03 王世超 Spiral channel absorption type optical media catalytic waste gas purifying instrument and purifying method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2409954A1 (en) * 2010-07-20 2012-01-25 National Center for Scientific Research Demokritos Photocatalytic purification device
CN102363047A (en) * 2011-06-29 2012-02-29 大连林桥科技有限公司 Photo-catalyst air purifier
CN104528871A (en) * 2015-01-04 2015-04-22 安徽理工大学 Solar photocatalytic degradation device
CN107032442A (en) * 2017-05-08 2017-08-11 东北大学秦皇岛分校 A kind of solar energy utilization system for integrating photovoltaic generation and photocatalysis Water warfare
CN108744958A (en) * 2018-06-05 2018-11-06 邢明 A kind of gas-phase photocatalysis reaction unit for volatile organic matter of degrading
CN113198322A (en) * 2021-05-11 2021-08-03 王世超 Spiral channel absorption type optical media catalytic waste gas purifying instrument and purifying method thereof

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