CN114262238A - Preparation method of efficient soft porcelain flexible facing brick - Google Patents
Preparation method of efficient soft porcelain flexible facing brick Download PDFInfo
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- CN114262238A CN114262238A CN202111615675.3A CN202111615675A CN114262238A CN 114262238 A CN114262238 A CN 114262238A CN 202111615675 A CN202111615675 A CN 202111615675A CN 114262238 A CN114262238 A CN 114262238A
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Abstract
The invention provides a curing method of a high-efficiency soft porcelain flexible face brick, which comprises the following steps: 1. preparing a mixed emulsion; 2. preparing mixed powder; 3. adding the mixed emulsion into the mixed powder, and stirring the mixed emulsion and the water of 5-15 parts to obtain soft porcelain slurry; 4. injecting the slurry in the step 3 into a mold; 5. and (5) curing. The microwave curing treatment is carried out in the curing step, and meanwhile, as the outer layer of the soft porcelain slurry has a certain temperature, the whole curing process is carried out simultaneously inside and outside the soft porcelain slurry, and in order to further improve the curing efficiency, the wave absorbing agent is also added into the soft porcelain slurry, so that the curing efficiency is improved.
Description
Technical Field
The application relates to a building material, in particular to a green environment-friendly building material, and more particularly relates to a preparation method of a high-efficiency soft porcelain flexible facing brick and the facing brick.
Background
In building materials, the facing brick is an important branch, can be widely used for wall external facades and indoor walls to decorate buildings, and commonly comprises a stone imitation, a brick imitation and the like. The soft porcelain facing brick is a novel facing material, the preparation method is simple, the process is environment-friendly, the machinability is strong, the demand in the field of flexible facing materials is huge, and the soft porcelain flexible facing brick can greatly improve the beauty and the grade of a building. However, since the aqueous polymer emulsion is obtained by molding with inorganic substances such as cement, clay, quartz sand or mineral powder, the aqueous polymer emulsion needs to be solidified during the molding process. The traditional curing temperature is about 100 ℃, the curing time is about 10 minutes to 2 hours, further drying is needed, and the drying time is generally more than two hours, so that the finished product is obtained.
For the problem of preparation efficiency of soft porcelain flexible facing bricks in the prior art, most of the soft porcelain flexible facing bricks adopt a traditional curing mode, for example, the invention patent with the publication number of CN106380144B discloses a preparation method of a semi-interpenetrating network polymer cement-based flexible facing brick, which is carried out according to the following steps: 1) weighing 15-25 parts of cement, 15-25 parts of stone powder and 30-50 parts of quartz sand by weight, adding into a kneading machine, and uniformly mixing to obtain mixed powder; 2) weighing 10-25 parts of water-based epoxy resin emulsion, 1-5 parts of fluorine-containing polyacrylate elastic emulsion, 5-15 parts of flame retardant, 1-3 parts of inorganic pigment and 10-25 parts of water in parts by weight, adding into a stirring kettle, and uniformly stirring to obtain mixed emulsion; 3) adding the mixed powder obtained in the step 1) into the mixed emulsion obtained in the step 2), fully stirring, after uniformly mixing, adding 1-5 parts of rubber elastomer, stirring, reacting for 0.5-2 hours, adding 3-10 parts of water-soluble epoxy resin curing agent, and uniformly stirring to obtain polymer mortar; 4) and (3) injecting the polymer mortar into a mold, curing for 0.5-1 h at room temperature, and then drying for 2-4 h at 40-90 ℃ to obtain the semi-interpenetrating network polymer cement-based flexible face brick.
And the preparation method of the high-hardness heat-preservation multifunctional soft porcelain decorative material with the authorization notice number of CN107311537B is characterized by comprising the following steps: preparing an emulsion in step (1): adding 20-30 parts of silicone-acrylic emulsion and 1-3 parts of inorganic pigment into a stirring kettle, and uniformly stirring to obtain a mixed emulsion material; preparing a far infrared ceramic powder layer in the step (2): adding 10-20 parts of far infrared ceramic powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain first mixed powder; preparing a negative ion powder layer: adding 10-20 parts of anion powder, 5-30 parts of cement, 25-35 parts of quartz sand and 1-3 parts of coupling agent into a kneader and uniformly mixing to obtain second mixed powder; preparing a mixed material in the step (4): adding the first mixed powder obtained in the step (2) into the mixed emulsion material obtained in the step (1), and stirring to obtain a first mixed material; adding the second mixed powder obtained in the step (3) into the mixed emulsion material obtained in the step (1), and stirring to obtain a second mixed material; step (5) moulding: pouring the first mixed material into a mold, pouring 1/4-1/2 of the total amount of the mold, pouring the second mixed material after the materials are naturally dried, filling the mold, and laying glass fiber mesh containing a low-temperature heating wire; and (6) sending the mould into an oven, curing, forming, drying and demoulding to obtain the multifunctional soft porcelain decorative material with smooth surface and high strength. Wherein the curing condition is curing at 110-130 ℃ for 10-20 minutes, and finally drying for 2-8 hours is needed.
Therefore, in the prior art, the forming process of the soft porcelain flexible facing tile adopts a conventional curing mode, and the curing mode mainly adopts a traditional heat exchange mode to replace moisture in raw materials and promote the crosslinking and curing of emulsion so as to achieve the curing effect, or the curing temperature is too high and exceeds 100 ℃. However, the efficiency of the curing method is low, the curing time is long, and the production efficiency is low.
The present disclosure mainly aims at the problem of low production efficiency, especially low curing efficiency, in the soft porcelain production process in the prior art, and provides a solution.
Disclosure of Invention
The preparation method of the high-efficiency soft porcelain flexible facing brick aims at solving the problems that soft porcelain production efficiency is low in the prior art, especially the problems that curing time is long, energy consumption is high, curing is not uniform and the like.
One of the concepts of the present disclosure is to provide a method for preparing a high-efficiency soft ceramic flexible face brick, which adds a microwave heating manner to a conventional resistance heating manner, and heats the soft ceramic by combining the microwave heating manner and a heat exchange manner, thereby increasing the heating temperature, promoting the curing, simultaneously ensuring that both the inside and the outside of the soft ceramic slurry are heated, promoting the uniform dispersion of moisture, changing the conventional heat exchange curing manner, and improving the curing efficiency.
Another concept of the present disclosure is to provide a method for preparing a high-efficiency soft porcelain flexible facing tile, in which a conventional resistance heating manner is replaced with a microwave heating manner, and by pure microwave heating, the problem of moisture in a soft porcelain material can be rapidly increased, and heating and curing are promoted.
The other concept of the disclosure also provides a preparation method of the high-efficiency soft porcelain flexible facing brick, which comprises the steps of carrying out alternate heating on the traditional resistance heating and microwave heating, changing the curing condition of the soft porcelain facing brick through alternate heating, and improving the curing efficiency.
The other concept of the disclosure is to provide a preparation method of the high-efficiency soft-ceramic flexible facing brick, and the method is characterized in that a wave absorbing agent is added into slurry of the traditional soft-ceramic flexible city tile, the wave absorbing agent can efficiently and rapidly absorb microwaves, high temperature is locally generated inside soft ceramics, solidification of macromolecules inside the soft ceramics is promoted, how the solidified macromolecules show a network state is achieved, and the mechanical property of the soft ceramics can be further improved.
The preparation method is characterized by comprising a curing step, wherein the soft porcelain slurry in the mold is cured to obtain the flexible facing brick, and the curing step comprises microwave curing.
Further, the power of the microwave treatment is more than 200w, preferably more than 250 w.
Further, the microwave treatment time is not less than 10 minutes;
preferably, the microwave treatment time is not less than 20 minutes.
In another embodiment, a method for preparing the high-efficiency soft ceramic flexible facing tile is provided, wherein the soft ceramic slurry in the mold is cured to obtain the flexible facing tile, and in the curing step, microwave and electric heating are adopted for curing together.
The curing temperature is 50-120 ℃, and the preferred curing temperature is 80-90 ℃.
The curing temperature of this disclosure needs to be controlled, prevents that the superficial layer solidification of soft porcelain thick liquids is too fast, forms the membrane sealing layer, prevents the loss of moisture, and the moisture in the soft porcelain thick liquids that is too much, and the influence solidification takes place.
Further, the method of the present disclosure requires controlling the curing temperature, especially the temperature of the soft porcelain slurry environment, to ensure the dissipation of moisture, but not the rapid formation of the film layer, so the solution of the present disclosure controls the curing temperature to be lower than 120 ℃, preferably 80-90 ℃.
In another embodiment, the method for preparing the efficient soft porcelain flexible facing tile comprises the step of curing soft porcelain slurry in a mold to obtain the flexible facing tile, wherein the curing step is alternately carried out by microwave curing and thermal curing.
The microwave curing time is 30-60 seconds, and the heat curing time is 5-20 min;
the alternating times are more than 10 times, and preferably, the alternating times are more than 15 times.
In another embodiment, a method for preparing the efficient soft ceramic flexible facing tile is provided, wherein the soft ceramic slurry in the mold is cured to obtain the flexible facing tile, and the curing step is microwave curing.
The microwave curing time is greater than 5 minutes, preferably greater than 10 minutes, and more preferably greater than 20 minutes.
Further, in another embodiment, the microwave curing is segmented microwave curing.
For example, after microwave curing is set for a certain time, the microwave treatment is stopped, and then the microwave curing treatment is continued and repeated.
Wherein the time of each microwave treatment is 30-150 seconds, preferably 60-120 seconds.
In another embodiment, a method for preparing the high-efficiency soft ceramic flexible facing tile is provided, wherein the soft ceramic slurry in the mold is cured to obtain the flexible facing tile, and the curing step further comprises ventilation treatment.
The ventilation treatment comprises the steps of blowing air to the environment around the soft porcelain by using a vortex machine and controlling the humidity.
The vortex fan can ensure larger wind power, remove moisture in curing equipment and promote the soft porcelain slurry to be cured and formed quickly.
In another embodiment, the preparation method of the high-efficiency soft porcelain flexible facing brick comprises the step of preparing mixed powder, wherein the preparation of the mixed powder comprises the step of adding cement and quartz sand into a kneader and uniformly mixing to obtain the mixed powder.
5-30 parts of cement and 25-35 parts of quartz sand, which are calculated according to parts by weight.
In another embodiment, the preparation method of the high-efficiency soft porcelain flexible facing tile comprises the step of preparing a mixed emulsion, wherein the preparation of the mixed emulsion comprises the step of blending the silicone-acrylic emulsion, the inorganic pigment and the wave absorbing agent to obtain the mixed emulsion.
The wave absorbing agent is carbon black.
20-30 parts of liquid silicone-acrylic emulsion, 1-3 parts of inorganic pigment and 1-3 parts of carbon black, wherein the components are calculated according to parts by weight.
In another embodiment, a preparation method of the high-efficiency soft porcelain flexible face tile comprises pretreatment of the wave absorbing agent, wherein the pretreatment comprises pretreatment of the wave absorbing agent by using a silane coupling agent.
The silane coupling agent is a silane coupling agent KH550 or a silane coupling agent KH 560;
further, the mass ratio of the silane coupling agent to the wave absorbing agent is 1: 2-3.
In some embodiments, a method for preparing a high-efficiency soft porcelain flexible face tile is provided, comprising the following steps:
1. preparing a mixed emulsion; the preparation of the mixed emulsion comprises the steps of blending the silicone-acrylic emulsion, the inorganic pigment and the wave absorbing agent to obtain the mixed emulsion;
2. preparing mixed powder, wherein the preparation of the mixed powder comprises the steps of adding cement and quartz sand into a kneading machine, and uniformly mixing to obtain mixed powder;
3. adding the mixed emulsion into the mixed powder, and stirring the mixed emulsion and the water of 5-15 parts to obtain soft porcelain slurry;
4. injecting the slurry in the step 3 into a mold;
5. and (5) curing.
In some embodiments, a method for preparing a high-efficiency soft porcelain flexible veneer tile is provided, which further comprises drying the cured soft porcelain.
Specifically, the preparation method of the high-efficiency soft porcelain flexible facing brick comprises the following steps:
1. blending 20-30 parts of liquid silicone-acrylic emulsion, 1-3 parts of inorganic pigment and 1-3 parts of carbon black to obtain mixed emulsion;
2. adding 5-30 parts of cement and 25-35 parts of quartz sand into a kneader, and uniformly mixing to obtain mixed powder;
3. and (3) adding the mixed emulsion obtained in the step (1) into the step (2), adding 5-15 parts of water at the same time, and uniformly stirring to obtain the soft porcelain slurry.
4. Injecting the soft porcelain slurry into the mold
5. And (4) curing, namely curing and demolding the mold containing the soft porcelain slurry in the step (4) to obtain the soft porcelain flexible face brick, wherein the curing temperature is 50-120 ℃.
Compared with the prior art, the soft ceramic flexible facing brick has the beneficial effects that the curing process is improved, so that the curing efficiency and the production efficiency are improved, and meanwhile, the mechanical property of the soft ceramic flexible facing brick is improved. Particularly, a microwave curing step is introduced, so that the microwave curing can efficiently promote the high molecules in the slurry to be cured, and the curing efficiency is improved. In addition, this disclosure has still carried out the regulation to the temperature of solidification, guarantees that the peripheral temperature of soft porcelain can not be too high, organizes the outer quick solidification of soft porcelain and forms the rete, organizes the loss of moisture and reduces solidification efficiency.
In order to improve the curing rate of the inside of the soft porcelain slurry, the wave absorbing agent is added into the raw materials, the wave absorbing agent can rapidly raise the temperature under the action of microwaves, local high temperature is formed inside the soft porcelain slurry, the emulsion inside the soft porcelain is promoted to be rapidly cured, the whole curing process is carried out simultaneously on the inside and the outer layer, and the curing efficiency is further improved.
The dispersion of the wave absorbing agent can influence the internal curing effect, and the silane coupling agent is used for pretreating the wave absorbing agent in advance, so that the dispersibility of the wave absorbing agent in the soft porcelain slurry is improved, and the curing efficiency is improved.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The embodiment specifically provides a soft porcelain flexible facing material and a preparation method thereof, wherein the preparation method comprises the steps of pretreating raw materials, namely blending a certain amount of coupling agent and 1-3 parts of carbon black to obtain a composition of the carbon black and the coupling agent, wherein the mass ratio of the coupling agent to the carbon black is 1: 2-3;
because the carbon black material is a better wave absorbing agent, microwaves can be obviously absorbed in the microwave treatment process, and the microenvironment around the carbon black is rapidly heated, so that the inside and the outside of the soft porcelain slurry simultaneously carry out curing reaction, the curing mode that the outer layer of the soft porcelain slurry is cured to the inner layer in the traditional heat exchange process is changed, the double rapid curing forming is realized, and the curing efficiency is improved.
In the curing process, due to the specification of the die, the thickness of the soft porcelain material is different, and in order to solve the problem of difference between outer layer curing and inner layer curing, the microwave heating and heat exchange heating modes can be adjusted, including discontinuous microwave heating and discontinuous heat exchange heating, so that the heating rates of the outer layer and the inner layer of the soft porcelain slurry are controlled, the curing efficiency is improved, and meanwhile, the mechanical property of the cured material can be ensured.
In another embodiment, a method for making a soft porcelain flexible tile is provided, which further comprises removing evaporated water during curing, including removing water vapor from the curing equipment using a vortex machine.
The concentration of aqueous vapor is too high in the space, can influence the volatilizing of soft porcelain thick liquids top layer moisture, and then hinders the solidification of soft porcelain facing brick, and this disclosure uses whirlwind machine, takes away the aqueous vapor in the space, improvement solidification efficiency that can be further.
Specifically, in embodiment 1, a method for preparing a high-efficiency flexible soft porcelain is provided, which comprises the following steps:
1. mixing 30 parts of liquid silicone-acrylic emulsion, 2 parts of inorganic pigment and 2 parts of carbon black to obtain mixed emulsion;
2. adding 15 parts of cement and 25 parts of quartz sand into a kneading machine, and uniformly mixing to obtain mixed powder;
3. and (3) adding the mixed emulsion obtained in the step (1) into the step (2), adding 10 parts of water at the same time, and uniformly stirring to obtain the soft porcelain slurry.
4. Injecting the soft porcelain slurry into the mold
5. And (4) curing, namely curing and demolding the mold containing the soft porcelain slurry in the step (4) to obtain the soft porcelain flexible facing brick, wherein the soft porcelain flexible facing brick is cured at a high temperature of 90 ℃ for 1-4 h.
In the embodiment 2, a preparation method of the high-efficiency soft porcelain flexible facing tile is provided, the main steps and the raw material formula are the same as those of the embodiment 1, and the preparation method is characterized in that microwave curing is adopted in the curing step, the microwave power is 250W, the curing time is 10-40 minutes, and the curing state is observed.
In another embodiment 3, a method for preparing a high-efficiency soft porcelain flexible facing tile is provided, which has the same main steps as those of embodiment 1, except that in the curing step 5, the curing is carried out by microwave and heat exchange, wherein the microwave power is 200W, the heat exchange curing temperature is 80 ℃, the curing time is 10-40 minutes, and the curing state is observed.
In another embodiment 4, a method for preparing a high-efficiency soft porcelain flexible facing tile is provided, which has the same main steps and raw material formula as those of embodiment 1, and is characterized in that the curing is intermittent microwave curing, wherein the microwave curing is performed in a mode that the microwave treatment is performed for 60 seconds, the microwave treatment is stopped for 60 seconds, the microwave treatment is continued for 60 seconds, the microwave treatment is repeated, the curing time is 10-40 minutes, and the curing state is observed.
In another embodiment 5, a method for preparing a high-efficiency soft porcelain flexible facing tile is provided, which has the same main steps and raw material formula as those of embodiment 3, except that a vortex machine is started during the curing process to remove moisture in the curing environment, the curing time is 10-40 minutes, and the curing state is observed.
In another example 6, there is provided a method for manufacturing a high-efficiency soft porcelain flexible tile, comprising the same main steps as in example 5, except that no carbon black is added to the slurry raw material, the curing time is 10-40 minutes, and the cured state is observed.
In another example 7, there is provided a method for manufacturing a high-efficiency soft porcelain flexible tile, comprising the same main steps as in example 5, except that carbon black is pretreated with a silane coupling agent in an amount of 1/2 parts based on carbon black, the curing time is 10 to 40 minutes, and the cured state is observed.
In the curing process, the standard for finishing curing lies in that the fluidity of the soft porcelain slurry is completely lost, the soft porcelain slurry has certain strength, the soft porcelain can be taken out from the silica gel template without fracture, and when the fluidity of the soft porcelain slurry is lost and the soft porcelain slurry can be taken out from the silica gel template, the slurry is considered to be completely cured.
And (3) drying the cured soft porcelain, controlling water, and then carrying out mechanical test, carrying out mechanical property test on the soft porcelain material obtained in the embodiment, and testing the tensile strength, the elongation at break and the bending strength by using a tensile strength tester.
The specific results are as follows:
wherein: the mark of the check mark is solidified; x represents incomplete cure; Δ represents between the completion of cure and uncured.
From the above table, it can be seen that the curing rate and mechanical properties of examples 5 and 7 are the best, and compared with example 1, it is evident that the microwave curing can improve the curing efficiency, and the intermittent multistage microwave treatment during the curing process can improve the curing rate efficiently. In addition, for the use of the vortex machine, certain mechanical strength can be improved under the condition of improving the curing rate of the soft porcelain.
The above description is only for the specific embodiments of the present application, but the scope of the present application is not limited thereto, and any person skilled in the art can easily conceive of the changes or substitutions within the technical scope of the present application, and shall be covered by the scope of the present application. Therefore, the protection scope of the present application shall be subject to the protection scope of the claims.
Claims (8)
1. A preparation method of a high-efficiency soft porcelain flexible facing brick is characterized by comprising a curing step, wherein soft porcelain slurry in a mould is cured to obtain the flexible facing brick, and the curing step comprises microwave curing;
the power of the microwave treatment is more than 200 w;
the total time of the microwave treatment is not less than 5 minutes.
2. The method for preparing the high-efficiency soft porcelain flexible facing tile according to claim 1,
the curing temperature is 50-120 ℃, and the preferred curing temperature is 80-90 ℃.
3. The method for preparing the high-efficiency soft porcelain flexible facing tile according to claim 1,
the curing step is that microwave curing and heat exchange curing are simultaneously performed;
wherein, the microwave curing is multi-section microwave curing, the microwave stops for 30-60 seconds after working for 30-60 seconds, and then continues to work for 30-60 seconds, so as to reciprocate;
the heat exchange curing time is 5-20 min.
4. The method for preparing the high-efficiency soft porcelain flexible facing tile according to claim 1, wherein the curing step is microwave continuous curing;
the microwave curing time is greater than 5 minutes, preferably greater than 10 minutes, and more preferably greater than 20 minutes.
5. The method for preparing the high-efficiency soft porcelain flexible facing tile according to claim 1, wherein the microwave curing is segmented microwave curing;
after microwave curing for a certain time, stopping microwave treatment, and then continuing microwave curing treatment, repeating the steps;
the time for each microwave treatment is 30 to 150 seconds, preferably 60 to 120 seconds.
6. The method for preparing the high-efficiency soft porcelain flexible facing tile according to any one of claims 1 to 5,
the curing step also comprises ventilation treatment;
the ventilation treatment comprises the steps of blowing air to the environment around the soft porcelain by using a vortex machine and controlling the humidity.
7. The method for preparing the high-efficiency soft porcelain flexible facing tile according to any one of claims 1 to 5,
the method also comprises the preparation of mixed powder, wherein the preparation of the mixed powder comprises the steps of adding cement and quartz sand into a kneading machine, and uniformly mixing to obtain the mixed powder;
5-30 parts of cement and 25-35 parts of quartz sand, which are calculated according to the parts by weight;
the method also comprises the preparation of mixed emulsion, wherein the preparation of the mixed emulsion comprises the step of blending the silicone-acrylic emulsion, the inorganic pigment and the wave absorbing agent to obtain the mixed emulsion.
8. The method for preparing the high-efficiency soft porcelain flexible facing tile according to claim 7,
the wave absorbing agent is carbon black; the wave absorbing agent is pretreated, and the pretreatment comprises the step of pretreating the wave absorbing agent by using a silane coupling agent;
the silane coupling agent is a silane coupling agent KH550 or a silane coupling agent KH 560;
the mass ratio of the silane coupling agent to the wave absorbing agent is 1: 2-3.
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Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102806191A (en) * | 2011-06-02 | 2012-12-05 | 昆山金利表面材料应用科技股份有限公司 | Method for solidifying thin polymer film on base material surface through microwave treatment |
| CN104727499A (en) * | 2013-12-18 | 2015-06-24 | 华北水利水电大学 | Art flexible face brick |
| CN104760302A (en) * | 2015-03-19 | 2015-07-08 | 南京航空航天大学 | Method of solidifying composite material with wave-absorbing material mould through microwave heating |
| CN105439438A (en) * | 2014-08-29 | 2016-03-30 | 北新集团建材股份有限公司 | Rock wool board microwave solidification method and microwave solidification apparatus thereof |
| CN105856786A (en) * | 2016-04-26 | 2016-08-17 | 湖北垚美软瓷有限公司 | Production technology for soft ceramic polyurethane heat-insulating decorative compound plate |
| CN107151119A (en) * | 2017-06-01 | 2017-09-12 | 万卓（江苏）新材料有限公司 | A kind of lightweight porcelain tendre ornament materials of adjusting humidity and preparation method thereof |
| CN107159887A (en) * | 2017-05-26 | 2017-09-15 | 深圳粤网节能技术服务有限公司 | A kind of forming method based on microwave adsorption heat-emitting material |
| CN108558437A (en) * | 2017-12-20 | 2018-09-21 | 北京交通大学 | Cordierite foam ceramic material and preparation method thereof and filter |
| CN108863231A (en) * | 2018-07-26 | 2018-11-23 | 万卓（武汉）新材料有限公司 | A kind of waterproof and breathable flexible clay facing tile and preparation method thereof |
| CN110606768A (en) * | 2019-10-15 | 2019-12-24 | 北京交通大学 | Cordierite porous ceramic membrane support and near-net-size preparation method thereof |
| WO2020088172A1 (en) * | 2018-10-29 | 2020-05-07 | 中国石油化工股份有限公司 | Continuous operation method for microwave high-temperature pyrolysis of solid material comprising organic matter |
| CN111187032A (en) * | 2019-12-03 | 2020-05-22 | 万卓（武汉）新材料有限公司 | High-performance sound-absorbing damping soft porcelain decorative material and preparation method thereof |
| CN112679174A (en) * | 2020-12-28 | 2021-04-20 | 广东雄塑环保板业有限公司 | Non-autoclaved energy-saving plate and preparation process thereof |
| CN113135757A (en) * | 2021-04-29 | 2021-07-20 | 华中科技大学 | Ceramic primary blank forming method based on microwave in-situ sintering and product |
| CN113563068A (en) * | 2020-04-29 | 2021-10-29 | 南京理工大学 | Ceramic slurry for direct-writing forming and forming method |
| CN113754284A (en) * | 2021-08-17 | 2021-12-07 | 内蒙古科技大学 | Preparation method of glass ceramic and industrial microwave oven |
-
2021
- 2021-12-27 CN CN202111615675.3A patent/CN114262238A/en active Pending
Patent Citations (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102806191A (en) * | 2011-06-02 | 2012-12-05 | 昆山金利表面材料应用科技股份有限公司 | Method for solidifying thin polymer film on base material surface through microwave treatment |
| CN104727499A (en) * | 2013-12-18 | 2015-06-24 | 华北水利水电大学 | Art flexible face brick |
| CN105439438A (en) * | 2014-08-29 | 2016-03-30 | 北新集团建材股份有限公司 | Rock wool board microwave solidification method and microwave solidification apparatus thereof |
| CN104760302A (en) * | 2015-03-19 | 2015-07-08 | 南京航空航天大学 | Method of solidifying composite material with wave-absorbing material mould through microwave heating |
| CN105856786A (en) * | 2016-04-26 | 2016-08-17 | 湖北垚美软瓷有限公司 | Production technology for soft ceramic polyurethane heat-insulating decorative compound plate |
| CN107159887A (en) * | 2017-05-26 | 2017-09-15 | 深圳粤网节能技术服务有限公司 | A kind of forming method based on microwave adsorption heat-emitting material |
| CN107151119A (en) * | 2017-06-01 | 2017-09-12 | 万卓（江苏）新材料有限公司 | A kind of lightweight porcelain tendre ornament materials of adjusting humidity and preparation method thereof |
| CN108558437A (en) * | 2017-12-20 | 2018-09-21 | 北京交通大学 | Cordierite foam ceramic material and preparation method thereof and filter |
| CN108863231A (en) * | 2018-07-26 | 2018-11-23 | 万卓（武汉）新材料有限公司 | A kind of waterproof and breathable flexible clay facing tile and preparation method thereof |
| WO2020088172A1 (en) * | 2018-10-29 | 2020-05-07 | 中国石油化工股份有限公司 | Continuous operation method for microwave high-temperature pyrolysis of solid material comprising organic matter |
| CN110606768A (en) * | 2019-10-15 | 2019-12-24 | 北京交通大学 | Cordierite porous ceramic membrane support and near-net-size preparation method thereof |
| CN111187032A (en) * | 2019-12-03 | 2020-05-22 | 万卓（武汉）新材料有限公司 | High-performance sound-absorbing damping soft porcelain decorative material and preparation method thereof |
| CN113563068A (en) * | 2020-04-29 | 2021-10-29 | 南京理工大学 | Ceramic slurry for direct-writing forming and forming method |
| CN112679174A (en) * | 2020-12-28 | 2021-04-20 | 广东雄塑环保板业有限公司 | Non-autoclaved energy-saving plate and preparation process thereof |
| CN113135757A (en) * | 2021-04-29 | 2021-07-20 | 华中科技大学 | Ceramic primary blank forming method based on microwave in-situ sintering and product |
| CN113754284A (en) * | 2021-08-17 | 2021-12-07 | 内蒙古科技大学 | Preparation method of glass ceramic and industrial microwave oven |
Non-Patent Citations (5)
| Title |
|---|
| 张富强等: "三种吸波材料对微波加热效率的影响", 《筑路机械与施工机械化》 * |
| 爱德华•艾伦: "《建筑的运作之道》", 31 August 2015 * |
| 王拯: "建筑饰面MCM劈开砖的施工应用", 《山西建筑》 * |
| 苏湘鄂等: "新型软瓷柔性面砖作为外墙外保温***饰面层的性能分析", 《陶瓷》 * |
| 赵学发等: "软瓷劈开砖施工技术", 《天津建设科技》 * |
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