CN114231082A - Nano ink capable of increasing binding force with aluminum layer - Google Patents
Nano ink capable of increasing binding force with aluminum layer Download PDFInfo
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- CN114231082A CN114231082A CN202111503696.6A CN202111503696A CN114231082A CN 114231082 A CN114231082 A CN 114231082A CN 202111503696 A CN202111503696 A CN 202111503696A CN 114231082 A CN114231082 A CN 114231082A
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- acrylate
- glycol diacrylate
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 42
- 239000002131 composite material Substances 0.000 claims abstract description 35
- 239000007788 liquid Substances 0.000 claims abstract description 34
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 28
- 239000003822 epoxy resin Substances 0.000 claims description 28
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 claims description 28
- 229920000647 polyepoxide Polymers 0.000 claims description 28
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 claims description 14
- ZDQNWDNMNKSMHI-UHFFFAOYSA-N 1-[2-(2-prop-2-enoyloxypropoxy)propoxy]propan-2-yl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(C)COCC(C)OC(=O)C=C ZDQNWDNMNKSMHI-UHFFFAOYSA-N 0.000 claims description 14
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 claims description 14
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 claims description 14
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 14
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 claims description 14
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 14
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 claims description 14
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims description 14
- NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 claims description 14
- 229920000728 polyester Polymers 0.000 claims description 14
- 239000012752 auxiliary agent Substances 0.000 claims description 11
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 9
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 claims description 9
- -1 amine modified acrylate Chemical class 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 8
- 230000002745 absorbent Effects 0.000 claims description 6
- 239000002250 absorbent Substances 0.000 claims description 6
- 239000004925 Acrylic resin Substances 0.000 claims description 4
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 229920002635 polyurethane Polymers 0.000 claims description 4
- 239000004814 polyurethane Substances 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- WSDQIHATCCOMLH-UHFFFAOYSA-N phenyl n-(3,5-dichlorophenyl)carbamate Chemical group ClC1=CC(Cl)=CC(NC(=O)OC=2C=CC=CC=2)=C1 WSDQIHATCCOMLH-UHFFFAOYSA-N 0.000 claims description 3
- 238000000016 photochemical curing Methods 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- 239000003292 glue Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000000391 smoking effect Effects 0.000 abstract 1
- 239000004411 aluminium Substances 0.000 description 8
- 238000003475 lamination Methods 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000002390 adhesive tape Substances 0.000 description 4
- 230000009172 bursting Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- 238000003958 fumigation Methods 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000001723 curing Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to a nano ink capable of increasing the binding force with an aluminum layer, which comprises ink and a composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 9: 1-11: 1, and the nano ink has the advantages that: the prepared ink has good stripping performance, the viscosity of the ink is greatly improved on the premise of not influencing the characteristics of the ink due to the fact that the composite liquid is added into the ink in a ratio of 1: 11-1: 9, the ink is guaranteed to have good aluminum adhesion, the curing speed, the stripping performance, the aluminum adhesion firmness, the scratch resistance, the wear resistance and the water resistance of the ink can be effectively improved, the bonding force between the ink and an aluminum layer is greatly improved during the whole use, the problem of printing crack generated after the nano ink layer and the aluminum layer are subjected to 180-degree corner folding is solved, the UV layer and the aluminum layer are not prone to falling off due to the good water resistance after being subjected to water smoking for 10 seconds, the requirements on the composite glue are lowered, and different production requirements are met.
Description
Technical Field
The invention relates to a nano ink capable of increasing the binding force with an aluminum layer.
Background
The surface of the existing inner corona base film is coated with a water-based release layer, then the surface of the water-based release layer is coated with a layer of nano ink and printed with laser marks required by printing, the printed laser marks are cured by UV light, the cured nano ink is coated with an aluminum layer again by the corona nano ink, the finished product of the aluminum-coated film is cut, the finished product of the aluminum-coated film is adhered to paper by an adhesive and dried, the dried paper peels a film on the surface of the paper by a peeling machine, the existing nano ink and the aluminum layer have poor bonding force, the aluminum layer can be removed by pulling a 3M adhesive tape, the printing risk is increased, the nano ink layer is poor in bursting, the UV layer and the aluminum layer are easy to fall off after being smoked for 10 seconds, and then the requirement on composite glue is high.
Disclosure of Invention
The invention aims to provide the nano ink capable of increasing the binding force with the aluminum layer, improving the binding force of the nano ink layer and the aluminum layer and ensuring that no printing crack occurs after the corner is folded.
In order to solve the technical problems, the invention is realized by the following technical scheme: the nano ink capable of increasing the bonding force with an aluminum layer comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 9: 1-11: 1, and the ink comprises the following components: 8-10 parts by mass of epoxy resin, 3-6 parts by mass of 2-ethylhexyl acrylate, 3-5 parts by mass of iso-acrylate, 18-20 parts by mass of polyester acrylate, 25-35 parts by mass of urethane acrylate, 8-10 parts by mass of hydroxyethyl methacrylate, 26-30 parts by mass of 1, 6-hexanediol diacrylate and 8-10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8-10 parts by mass of epoxy resin, 3-5 parts by mass of amine modified acrylate, 5-8 parts by mass of tripropylene glycol diacrylate, 5-8 parts by mass of dipropylene glycol diacrylate, 15-20 parts by mass of 1, 6-hexanediol diacrylate, 6-8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2-3 parts by mass of 1-hydroxycyclohexyl phenyl ketone and 3-5 parts by mass of p-hydroxyanisole.
Preferably, the ink comprises the following components: 10 parts by mass of an epoxy resin, 6 parts by mass of 2-ethylhexyl acrylate, 5 parts by mass of an isopropyl acrylate, 20 parts by mass of a polyester acrylate, 25 parts by mass of a urethane acrylate, 10 parts by mass of hydroxyethyl methacrylate, 30 parts by mass of 1, 6-hexanediol diacrylate, and 10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 10 parts by mass of an epoxy resin, 5 parts by mass of an amine-modified acrylate, 8 parts by mass of tripropylene glycol diacrylate, 8 parts by mass of dipropylene glycol diacrylate, 15 parts by mass of 1, 6-hexanediol diacrylate, 8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 3 parts by mass of 1-hydroxycyclohexylphenylketone, and 5 parts by mass of p-hydroxyanisole.
Preferably, the ink comprises the following components: 9 parts by mass of an epoxy resin, 4.5 parts by mass of 2-ethylhexyl acrylate, 4.43 parts by mass of isopropyl acrylate, 19.5 parts by mass of a polyester acrylate, 30.5 parts by mass of a urethane acrylate, 8.97 parts by mass of hydroxyethyl methacrylate, 27.1 parts by mass of 1, 6-hexanediol diacrylate, 9.2 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 9.1 parts by mass of an epoxy resin, 4.12 parts by mass of an amine-modified acrylate, 7.01 parts by mass of tripropylene glycol diacrylate, 6.57 parts by mass of dipropylene glycol diacrylate, 18.1 parts by mass of 1, 6-hexanediol diacrylate, 7.2 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2.11 parts by mass of 1-hydroxycyclohexyl phenyl ketone, and 4.25 parts by mass of p-hydroxyanisole.
Preferably, the ink comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of 2-ethylhexyl acrylate, 3 parts by mass of an isopropyl acrylate, 18 parts by mass of a polyester acrylate, 35 parts by mass of a urethane acrylate, 8 parts by mass of hydroxyethyl methacrylate, 26 parts by mass of 1, 6-hexanediol diacrylate, and 8 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of an amine-modified acrylate, 5 parts by mass of tripropylene glycol diacrylate, 5 parts by mass of dipropylene glycol diacrylate, 20 parts by mass of 1, 6-hexanediol diacrylate, 6 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 2 parts by mass of 1-hydroxycyclohexylphenylketone, and 3 parts by mass of p-hydroxyanisole.
Preferably, the nano ink further comprises an auxiliary agent, and the mass ratio of the auxiliary agent to the nano ink is 2: 250-3: 250.
preferably, the auxiliary agent comprises the following components: 25-45 parts by mass of difunctional polyurethane acrylic resin, 20-30 parts by mass of photocuring resin, 15-25 parts by mass of photopolymerization monomer, 3-5 parts by mass of photoinitiator and 5-10 parts by mass of photochromic composition.
Preferably, the photochromic composition comprises the following components: 100 parts by mass of organic solvent, 0.3-2 parts by mass of photochromic organic substance, 0.1-0.5 part by mass of infrared-proof absorbent, 0.1-0.5 part by mass of blue light absorbent and 0.1-0.2 part by mass of antioxidant.
In conclusion, the invention has the advantages that: the ink is prepared by mixing epoxy resin, 2-ethylhexyl acrylate, iso-acrylate, polyester acrylate, urethane acrylate, hydroxyethyl methacrylate, 1, 6-hexanediol diacrylate and dipropylene glycol diacrylate, and the composite liquid is prepared by mixing epoxy resin, amine modified acrylate, tripropylene glycol diacrylate, dipropylene glycol diacrylate, 1, 6-hexanediol diacrylate, 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 1-hydroxycyclohexyl phenyl ketone and p-hydroxyanisole, and the prepared ink has good stripping performance, and as the composite liquid is added into the ink at a ratio of 1: 11-1: 9, the viscosity of the ink is greatly improved on the premise of not influencing the characteristics of the ink, and the ink is ensured to have good aluminum adhesion, and can effectual solidification rate, the peeling off performance that improves the printing ink, attaches aluminium firmness, anti-scratch performance, wear resistance and water resistance, whole when using improved greatly with the aluminium lamination between cohesion good, solved the nanometer printing ink layer with the aluminium lamination through the printing problem of bursting that produces behind the 180 degrees dog-ear, good water resistance makes UV layer and aluminium lamination be difficult to drop after 10 seconds of water fumigation, also reduced the requirement to compound glue, satisfied different production demands.
Detailed Description
The nano ink capable of increasing the bonding force with an aluminum layer comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 9: 1-11: 1, and the ink comprises the following components: 8-10 parts by mass of epoxy resin, 3-6 parts by mass of 2-ethylhexyl acrylate, 3-5 parts by mass of iso-acrylate, 18-20 parts by mass of polyester acrylate, 25-35 parts by mass of urethane acrylate, 8-10 parts by mass of hydroxyethyl methacrylate, 26-30 parts by mass of 1, 6-hexanediol diacrylate and 8-10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8-10 parts by mass of epoxy resin, 3-5 parts by mass of amine modified acrylate, 5-8 parts by mass of tripropylene glycol diacrylate, 5-8 parts by mass of dipropylene glycol diacrylate, 15-20 parts by mass of 1, 6-hexanediol diacrylate, 6-8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2-3 parts by mass of 1-hydroxycyclohexyl phenyl ketone, and 3-5 parts by mass of p-hydroxyanisole,
the ink is prepared by mixing epoxy resin, 2-ethylhexyl acrylate, iso-acrylate, polyester acrylate, urethane acrylate, hydroxyethyl methacrylate, 1, 6-hexanediol diacrylate and dipropylene glycol diacrylate, and the composite liquid is prepared by mixing epoxy resin, amine modified acrylate, tripropylene glycol diacrylate, dipropylene glycol diacrylate, 1, 6-hexanediol diacrylate, 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 1-hydroxycyclohexyl phenyl ketone and p-hydroxyanisole, and the prepared ink has good stripping performance, and as the composite liquid is added into the ink at a ratio of 1: 11-1: 9, the viscosity of the ink is greatly improved on the premise of not influencing the characteristics of the ink, and the ink is ensured to have good aluminum adhesion, and can effectual solidification rate, the peeling off performance that improves the printing ink, attaches aluminium firmness, anti-scratch performance, wear resistance and water resistance, whole when using improved greatly with the aluminium lamination between cohesion good, solved the nanometer printing ink layer with the aluminium lamination through the printing problem of bursting that produces behind the 180 degrees dog-ear, good water resistance makes UV layer and aluminium lamination be difficult to drop after 10 seconds of water fumigation, also reduced the requirement to compound glue, satisfied different production demands.
The nano ink also comprises an auxiliary agent, and the mass ratio of the auxiliary agent to the nano ink is 2: 250-3: 250, by adding an auxiliary agent, the shrinkage cavity of a needle eye can be effectively improved, so that the mixed liquid of the printing ink and the composite liquid can be more fully dissolved, and the auxiliary agent comprises the following components: 25-45 parts by mass of difunctional polyurethane acrylic resin, 20-30 parts by mass of photocuring resin, 15-25 parts by mass of photopolymerization monomer, 3-5 parts by mass of photoinitiator and 5-10 parts by mass of photochromic composition, wherein the problem of poor adhesion caused by overlarge volume shrinkage of traditional UV (ultraviolet) gloss oil during curing can be effectively solved through the high tensile rate of the difunctional polyurethane acrylic resin, and the aluminum layer and the nano ink layer after the film surface is aluminized have good adaptability, and the photochromic composition comprises the following components: the photochromic composition can effectively reduce the yellowing frequency of a layout by 100 parts by mass of an organic solvent, 0.3-2 parts by mass of a photochromic organic substance, 0.1-0.5 part by mass of an infrared-proof absorbent, 0.1-0.5 part by mass of a blue light absorbent and 0.1-0.2 part by mass of an antioxidant.
And stirring the printing ink and the composite liquid by a stirrer for 25-35 min at a stirring speed of 200-300 rpm at a charging tray temperature of 30-40 ℃, adding an auxiliary agent into the mixture after fully stirring uniformly, and stirring for 5-10 min at a stirring speed and a stirring temperature.
Example one
The nano ink capable of increasing the bonding force with the aluminum layer comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 9:1, and the ink comprises the following components: 10 parts by mass of an epoxy resin, 6 parts by mass of 2-ethylhexyl acrylate, 5 parts by mass of an isopropyl acrylate, 20 parts by mass of a polyester acrylate, 25 parts by mass of a urethane acrylate, 10 parts by mass of hydroxyethyl methacrylate, 30 parts by mass of 1, 6-hexanediol diacrylate, and 10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 10 parts by mass of an epoxy resin, 5 parts by mass of an amine-modified acrylate, 8 parts by mass of tripropylene glycol diacrylate, 8 parts by mass of dipropylene glycol diacrylate, 15 parts by mass of 1, 6-hexanediol diacrylate, 8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 3 parts by mass of 1-hydroxycyclohexylphenylketone, and 5 parts by mass of p-hydroxyanisole.
Example two
The nano ink capable of increasing the bonding force with the aluminum layer comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 10:1, and the ink comprises the following components: 9 parts by mass of an epoxy resin, 4.5 parts by mass of 2-ethylhexyl acrylate, 4.43 parts by mass of isopropyl acrylate, 19.5 parts by mass of a polyester acrylate, 30.5 parts by mass of a urethane acrylate, 8.97 parts by mass of hydroxyethyl methacrylate, 27.1 parts by mass of 1, 6-hexanediol diacrylate, 9.2 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 9.1 parts by mass of an epoxy resin, 4.12 parts by mass of an amine-modified acrylate, 7.01 parts by mass of tripropylene glycol diacrylate, 6.57 parts by mass of dipropylene glycol diacrylate, 18.1 parts by mass of 1, 6-hexanediol diacrylate, 7.2 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2.11 parts by mass of 1-hydroxycyclohexyl phenyl ketone, and 4.25 parts by mass of p-hydroxyanisole.
EXAMPLE III
The nano ink capable of increasing the bonding force with the aluminum layer comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 11:1, and the ink comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of 2-ethylhexyl acrylate, 3 parts by mass of an isopropyl acrylate, 18 parts by mass of a polyester acrylate, 35 parts by mass of a urethane acrylate, 8 parts by mass of hydroxyethyl methacrylate, 26 parts by mass of 1, 6-hexanediol diacrylate, and 8 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of an amine-modified acrylate, 5 parts by mass of tripropylene glycol diacrylate, 5 parts by mass of dipropylene glycol diacrylate, 20 parts by mass of 1, 6-hexanediol diacrylate, 6 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 2 parts by mass of 1-hydroxycyclohexylphenylketone, and 3 parts by mass of p-hydroxyanisole.
The nano ink prepared in the first embodiment, the second embodiment and the third embodiment is applied to a PET (polyethylene terephthalate) base film, the produced transfer paper is pasted on the finished paper through a 3M transparent adhesive tape with the width of 8-10 mm and the force of 3-5N, the adhesive tape is pulled up rapidly, the bonding force of the nano ink layer and the aluminum layer is detected, and the aluminum layer cannot fall off after the adhesive tape is pulled up rapidly.
Other embodiments of the present invention than the preferred embodiments described above will be apparent to those skilled in the art from the present invention, and various changes and modifications can be made therein without departing from the spirit of the present invention as defined in the appended claims.
Claims (7)
1. The nano ink capable of increasing the bonding force with an aluminum layer is characterized in that: the ink comprises ink and composite liquid capable of increasing the viscosity of the ink, wherein the mass ratio of the ink to the composite liquid is 9: 1-11: 1, and the ink comprises the following components: 8-10 parts by mass of epoxy resin, 3-6 parts by mass of 2-ethylhexyl acrylate, 3-5 parts by mass of iso-acrylate, 18-20 parts by mass of polyester acrylate, 25-35 parts by mass of urethane acrylate, 8-10 parts by mass of hydroxyethyl methacrylate, 26-30 parts by mass of 1, 6-hexanediol diacrylate and 8-10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8-10 parts by mass of epoxy resin, 3-5 parts by mass of amine modified acrylate, 5-8 parts by mass of tripropylene glycol diacrylate, 5-8 parts by mass of dipropylene glycol diacrylate, 15-20 parts by mass of 1, 6-hexanediol diacrylate, 6-8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2-3 parts by mass of 1-hydroxycyclohexyl phenyl ketone and 3-5 parts by mass of p-hydroxyanisole.
2. The nano ink capable of increasing the bonding force with the aluminum layer as claimed in claim 1, wherein: the ink comprises the following components: 10 parts by mass of an epoxy resin, 6 parts by mass of 2-ethylhexyl acrylate, 5 parts by mass of an isopropyl acrylate, 20 parts by mass of a polyester acrylate, 25 parts by mass of a urethane acrylate, 10 parts by mass of hydroxyethyl methacrylate, 30 parts by mass of 1, 6-hexanediol diacrylate, and 10 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 10 parts by mass of an epoxy resin, 5 parts by mass of an amine-modified acrylate, 8 parts by mass of tripropylene glycol diacrylate, 8 parts by mass of dipropylene glycol diacrylate, 15 parts by mass of 1, 6-hexanediol diacrylate, 8 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 3 parts by mass of 1-hydroxycyclohexylphenylketone, and 5 parts by mass of p-hydroxyanisole.
3. The nano ink capable of increasing the bonding force with the aluminum layer as claimed in claim 1, wherein: the ink comprises the following components: 9 parts by mass of an epoxy resin, 4.5 parts by mass of 2-ethylhexyl acrylate, 4.43 parts by mass of isopropyl acrylate, 19.5 parts by mass of a polyester acrylate, 30.5 parts by mass of a urethane acrylate, 8.97 parts by mass of hydroxyethyl methacrylate, 27.1 parts by mass of 1, 6-hexanediol diacrylate, 9.2 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 9.1 parts by mass of an epoxy resin, 4.12 parts by mass of an amine-modified acrylate, 7.01 parts by mass of tripropylene glycol diacrylate, 6.57 parts by mass of dipropylene glycol diacrylate, 18.1 parts by mass of 1, 6-hexanediol diacrylate, 7.2 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenyl phosphine oxide, 2.11 parts by mass of 1-hydroxycyclohexyl phenyl ketone, and 4.25 parts by mass of p-hydroxyanisole.
4. The nano ink capable of increasing the bonding force with the aluminum layer as claimed in claim 1, wherein: the ink comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of 2-ethylhexyl acrylate, 3 parts by mass of an isopropyl acrylate, 18 parts by mass of a polyester acrylate, 35 parts by mass of a urethane acrylate, 8 parts by mass of hydroxyethyl methacrylate, 26 parts by mass of 1, 6-hexanediol diacrylate, and 8 parts by mass of dipropylene glycol diacrylate; the composite liquid comprises the following components: 8 parts by mass of an epoxy resin, 3 parts by mass of an amine-modified acrylate, 5 parts by mass of tripropylene glycol diacrylate, 5 parts by mass of dipropylene glycol diacrylate, 20 parts by mass of 1, 6-hexanediol diacrylate, 6 parts by mass of 2, 4, 6-trimethylbenzoyl-diphenylphosphine oxide, 2 parts by mass of 1-hydroxycyclohexylphenylketone, and 3 parts by mass of p-hydroxyanisole.
5. The nanoink with increased bonding force with an aluminum layer as recited in any one of claims 1 to 4, wherein: the nano ink also comprises an auxiliary agent, and the mass ratio of the auxiliary agent to the nano ink is 2: 250-3: 250.
6. the nano ink capable of increasing the bonding force with the aluminum layer as claimed in claim 5, wherein: the auxiliary agent comprises the following components: 25-45 parts by mass of difunctional polyurethane acrylic resin, 20-30 parts by mass of photocuring resin, 15-25 parts by mass of photopolymerization monomer, 3-5 parts by mass of photoinitiator and 5-10 parts by mass of photochromic composition.
7. The nano ink capable of increasing the bonding force with the aluminum layer as claimed in claim 6, wherein: the photochromic composition comprises the following components: 100 parts by mass of organic solvent, 0.3-2 parts by mass of photochromic organic substance, 0.1-0.5 part by mass of infrared-proof absorbent, 0.1-0.5 part by mass of blue light absorbent and 0.1-0.2 part by mass of antioxidant.
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| CN202111503696.6A CN114231082A (en) | 2021-12-10 | 2021-12-10 | Nano ink capable of increasing binding force with aluminum layer |
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Citations (2)
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| CN104817880A (en) * | 2015-04-09 | 2015-08-05 | 深圳万佳原精化科技股份有限公司 | Ultraviolet curing anti-anodic oxidation shielding protection printing ink |
| CN108641470A (en) * | 2018-05-17 | 2018-10-12 | 清远慧谷新材料技术有限公司 | A kind of UV-LED solidification pad-transfer printing ink and preparation method thereof, application |
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2021
- 2021-12-10 CN CN202111503696.6A patent/CN114231082A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817880A (en) * | 2015-04-09 | 2015-08-05 | 深圳万佳原精化科技股份有限公司 | Ultraviolet curing anti-anodic oxidation shielding protection printing ink |
| CN108641470A (en) * | 2018-05-17 | 2018-10-12 | 清远慧谷新材料技术有限公司 | A kind of UV-LED solidification pad-transfer printing ink and preparation method thereof, application |
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