CN114149281A - Sand soil modifier with phosphorus stabilization effect and preparation method thereof - Google Patents

Sand soil modifier with phosphorus stabilization effect and preparation method thereof Download PDF

Info

Publication number
CN114149281A
CN114149281A CN202111597984.2A CN202111597984A CN114149281A CN 114149281 A CN114149281 A CN 114149281A CN 202111597984 A CN202111597984 A CN 202111597984A CN 114149281 A CN114149281 A CN 114149281A
Authority
CN
China
Prior art keywords
sludge
parts
phosphorus
soil
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202111597984.2A
Other languages
Chinese (zh)
Inventor
付登强
刘小玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coconut Research Institute of Chinese Academy of Tropical Agricultural Sciences
Original Assignee
Coconut Research Institute of Chinese Academy of Tropical Agricultural Sciences
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coconut Research Institute of Chinese Academy of Tropical Agricultural Sciences filed Critical Coconut Research Institute of Chinese Academy of Tropical Agricultural Sciences
Priority to CN202111597984.2A priority Critical patent/CN114149281A/en
Publication of CN114149281A publication Critical patent/CN114149281A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05DINORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D9/00Other inorganic fertilisers
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • C05F17/20Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation using specific microorganisms or substances, e.g. enzymes, for activating or stimulating the treatment
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K17/00Soil-conditioning materials or soil-stabilising materials
    • C09K17/40Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K2101/00Agricultural use
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Soil Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Pest Control & Pesticides (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Soil Conditioners And Soil-Stabilizing Materials (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a sandy soil modifier with a phosphorus stabilizing effect and a preparation method thereof, wherein the method is to improve a sludge composting process, improve the performance of a sludge composting product and reduce the sludge composting cost; and secondly, the phosphorus stabilization effect of the sludge compost is endowed, and the application prospect of the sludge compost is expanded.

Description

Sand soil modifier with phosphorus stabilization effect and preparation method thereof
Technical Field
The invention relates to the technical field of soil conditioners, in particular to a sandy soil conditioner with a phosphorus stabilizing effect and a preparation method thereof.
Background
Sandy soil is poor in structure and weak in water and fertilizer retention capacity, and in order to obtain high yield of crops, excessive chemical fertilizer is often applied to the crops planted on the sandy soil. Because the migration and transformation of nitrogenous fertilizer, phosphate fertilizer and potash fertilizer in soil are different, the absorption and utilization amount of crops is different, the phosphorus content of sand soil planted intensively is seriously exceeded standard, the growth of crops is hindered, and water eutrophication and environmental pollution are easily caused. The product of the sludge after harmless treatment has better water absorption and retention performance and is an excellent material for improving sandy soil. However, due to the difficulty in dehydration in the harmless treatment of sludge compost, the use amount of rice hulls, straws and other materials is large, the fermentation treatment cost is high, the product density is high, the product is easy to agglomerate, the product is not easy to be fully combined with soil, and the soil improvement effect cannot be fully exerted.
Disclosure of Invention
In view of the above, the invention provides a sandy soil modifier with a phosphorus stabilizing effect and a preparation method thereof,
the technical means adopted by the invention are as follows:
a preparation method of a sandy soil modifier with a phosphorus stabilizing effect comprises the following steps in parts by weight:
mixing 4000 parts of fresh sludge, 800-doped expanded perlite micro powder and 160-doped 200 parts of straw powder, turning and throwing for 4-5 times, adding 2-4 parts of sludge decomposing agent after uniformly stirring, continuously turning and throwing for 2-3 times, composting once every 6 days, adding 400-doped 480 parts of reduced iron powder after composting for 30-40 days, and uniformly stirring to obtain the sand-soil modifier.
Preferably, the straw powder is corn straw, and is prepared by crushing and sieving through a 20-mesh sieve.
Preferably, the fine reduced iron is sieved through a 100-mesh sieve.
Preferably, the expanded perlite micro powder is 800 parts, the corn straw powder is 200 parts, the sludge-decomposing inoculant is 2 parts, and the reduced iron powder is 480 parts.
The invention also provides a sandy soil modifier prepared by the preparation method.
The invention has the beneficial effects that:
the method provided by the invention has the advantages that firstly, the sludge composting process is improved, the performance of sludge composting products is improved, and the sludge composting cost is reduced; and secondly, the phosphorus stabilization effect of the sludge compost is endowed, and the application prospect of the sludge compost is expanded. The sludge has high water content and is difficult to decompose, the sludge composting performance of a sludge treatment plant is improved mainly by adding dewatering equipment and adding a large amount of rice husks, wood chips and the like, the investment is large, and the cost is high.
According to the invention, the by-product perlite micropowder in the perlite puffing process is used as a filler, secondary dehydration is not required for sludge, and the addition of straws is reduced, so that the sludge composting cost is reduced, and the product is looser and is more suitable for soil improvement. By adding the reduced iron powder, the performance of stabilizing soil phosphorus can be enhanced, the phosphorus concentration of a soil solution is reduced, phosphate fertilizer resources are saved, and the environment is protected.
The invention also provides a sandy soil modifier which has the effects of obviously improving the crop yield, increasing the field water retention rate of soil and reducing the phosphorus concentration of a soil solution after being used, thereby reducing the migration of phosphorus to a water body and protecting the agricultural ecological environment, and is economic and environment-friendly.
Detailed Description
The principles and features of this invention are described below in conjunction with examples which are set forth to illustrate, but are not to be construed to limit the scope of the invention.
Example 1
The fresh sludge is provided by a fish product processing plant, the water content of the fresh sludge is less than 90%, and the pollutant content meets the A-level (cultivated land, garden land and grassland) standard of GB 4284-2018.
The sludge-decomposing inoculant is also called an organic fertilizer leavening agent, is a purchased product sold in the market, is specifically produced by Weifang Rui biological technology Limited, and mainly comprises photosynthetic bacteria, lactic acid bacteria, spore bacteria, fermentation filamentous bacteria and the like.
Mixing 4000 kg of fresh sludge (with the water content of 89 percent), 1000 kg of expanded perlite micropowder and 160 kg of corn straw powder, turning and throwing for 5 times by using a turner, adding 4 kg of sludge decomposing agent, continuously turning and throwing for 3 times, composting, turning and piling once every 6 days, adding 400 kg of reduced iron powder after 40 days, and uniformly stirring to obtain a sand modifier finished product I.
Example 2:
the fresh sludge is provided by a fish product processing plant, the water content of the fresh sludge is less than 90%, and the pollutant content meets the A-level (cultivated land, garden land and grassland) standard of GB 4284-2018.
The sludge-decomposing inoculant is also called an organic fertilizer leavening agent, is a purchased product sold in the market, is specifically produced by Weifang Rui biological technology Limited, and mainly comprises photosynthetic bacteria, lactic acid bacteria, spore bacteria, fermentation filamentous bacteria and the like.
Mixing 4000 kg of fresh sludge (with the water content of 88 percent), 950 kg of expanded perlite micropowder and 180 kg of corn straw powder, turning and throwing for 4 times by using a turner, adding 3 kg of sludge maturity agent (Weifang Ruchen biotechnology limited), continuously turning and throwing for 3 times, composting, turning and piling once every 6 days, adding 440 kg of reduced iron powder after 35 days, and uniformly stirring to obtain a sandy soil modifier finished product II.
Example 3:
the fresh sludge is provided by a fish product processing plant, the water content of the fresh sludge is less than 90%, and the pollutant content meets the A-level (cultivated land, garden land and grassland) standard of GB 4284-2018.
The sludge-decomposing inoculant is also called an organic fertilizer leavening agent, is a purchased product sold in the market, is specifically produced by Weifang Rui biological technology Limited, and mainly comprises photosynthetic bacteria, lactic acid bacteria, spore bacteria, fermentation filamentous bacteria and the like.
Mixing 4000 kg of fresh sludge (with the water content of 86 percent), 800 kg of expanded perlite micropowder and 200 kg of corn straw powder, turning and throwing for 4 times by using a turner, adding 2 kg of sludge maturity agent (Weifang Ruchen biotechnology limited), continuously turning and throwing for 2 times, composting, turning and piling once every 6 days, adding 480 kg of reduced iron powder after 30 days, and uniformly stirring to obtain a third sand modifier product.
The organic matter, pH and lead, zinc, chromium and arsenic contents of the obtained sand modifier finished products are measured by referring to NY/T3034-2016 according to one to three references, and are shown in the following table 1:
TABLE 1 physicochemical indices of soil conditioners
Finished product pH Organic matter (g/kg) Arsenic (mg/kg) Mercury (mg/kg) Lead (mg/kg) Separate (mg/kg) Chromium (mg/kg)
A 5.8 7.88 2.82 0.065 17.9 0.41 61.2
II 5.8 8.03 2.57 0.045 15.7 0.35 54.6
III 5.7 8.15 2.76 0.047 18.4 0.53 64.7
Peanut and sweet potato are used as test crops, field tests are carried out in the ruins of Wenchang city, Hainan province, soil is coastal sandy soil, green-peel wax gourd is planted in the former stubbles, the basic physicochemical property of the soil is pH 5.8, 9.2 g/kg of organic matters, 44.7 mg/kg of alkaline hydrolysis nitrogen, 371.1 mg/kg of available phosphorus and 97.8 mg/kg of quick-acting potassium. In the field test, 2 crops (a peanut variety is 'monkey in one litter', a sweet potato variety is 'watermelon red') are set, each crop is treated by 4 times, the crops are respectively a blank control group (without soil conditioner), a finished product I, a finished product II and a finished product III, the square meter of each cell is 12, the application amount of the finished product I to the finished product III is 18 kg for each cell, and the finished products are subjected to rotary tillage and uniform mixing after surface spreading. After the test is finished, the cell yield is measured, the soil volume weight, the field water holding rate of the soil and the phosphorus content of the soil solution are measured by a cutting ring method (the phosphorus content in the water is measured by centrifugation after the soil sample and the water are cultured in a shaking way for 24 hours according to the ratio of 1: 2.5).
The field test effect is shown in table 2 and table 3:
TABLE 2 soil conditioner peanut field test effect
Treatment of Cell output (kg) Soil volume weight (g/cm)3) Water holdup (%) Phosphorus content of soil solution (mg/L)
Control group 3.16 1.58 8.6 1.27
Finished product one 3.39 1.55 11.6 0.46
Product two 3.47 1.62 11.4 0.51
Product III 3.45 1.58 11.3 0.53
TABLE 3 soil conditioner sweet potato field test effect
Treatment of Cell output (kg) Soil volume weight (g/cm)3) Water holdup (%) Phosphorus content of soil solution (mg/L)
Control group 30.48 1.57 8.8 1.24
Finished product one 35.62 1.59 11.7 0.47
Product two 33.15 1.56 11.7 0.48
Product III 35.87 1.54 11.4 0.44
Compared with a blank control group, the soil conditioner product prepared by the invention is applied to the coastal sandy soil to be tested, the peanut yield is increased by 7.2-9.8%, the sweet potato yield is increased by 8.8-17.7%, the field water-holding rate of the soil is increased by 29.5-34.9%, the phosphorus content of the soil solution is reduced by 58.3-64.5%, and the soil conditioner product has obvious effects on improving the soil fertility of sandy soil, stabilizing soil phosphorus and reducing the migration of phosphorus to a water body.
In conclusion, the method provided by the invention is used for improving the sludge composting process, improving the performance of sludge composting products and reducing the sludge composting cost; and secondly, the phosphorus stabilization effect of the sludge compost is endowed, and the application prospect of the sludge compost is expanded. The sludge has high water content and is difficult to decompose, the sludge composting performance of a sludge treatment plant is improved mainly by adding dewatering equipment and adding a large amount of rice husks, wood chips and the like, the investment is large, and the cost is high.
According to the invention, the by-product perlite micropowder in the perlite puffing process is used as a filler, secondary dehydration is not required for sludge, and the addition of straws is reduced, so that the sludge composting cost is reduced, and the product is looser and is more suitable for soil improvement. By adding the reduced iron powder, the performance of stabilizing soil phosphorus can be enhanced, the phosphorus concentration of a soil solution is reduced, phosphate fertilizer resources are saved, and the environment is protected.
The invention also provides a sandy soil modifier which has the effects of improving crop yield, improving sandy soil water retention performance and reducing the phosphorus concentration of a sandy soil solution after being used, and is economic and environment-friendly.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents, improvements and the like made within the spirit and principle of the present invention should be included in the scope of the present invention.

Claims (5)

1. A preparation method of a sandy soil modifier with a phosphorus stabilizing effect is characterized by comprising the following steps of:
mixing 4000 parts of fresh sludge, 800-doped expanded perlite micro powder and 160-doped 200 parts of straw powder, turning and throwing for 4-5 times, uniformly stirring, adding 2-4 parts of sludge decomposing agent, continuously turning and throwing for 2-3 times, composting, turning and piling once every 6 days, adding 400-doped 480 parts of reduced iron powder after composting for 30-40 days, and uniformly stirring to obtain the sand soil modifier.
2. The method for preparing a sandy soil improver with a phosphorus stabilizing effect as claimed in claim 1, wherein the straw powder is corn straw, and is prepared by crushing and sieving the corn straw with a 20-mesh sieve.
3. The method of claim 1, wherein the reduced iron powder is passed through a 100 mesh sieve.
4. The method for preparing a sand soil modifier with phosphorus stabilization effect as claimed in claim 1, wherein the expanded perlite micropowder is 800 parts, the corn straw powder is 200 parts, the sludge-decomposing inoculant is 2 parts, and the reduced iron powder is 480 parts.
5. A sandy soil improver prepared by the preparation method as claimed in any one of claims 1 to 4.
CN202111597984.2A 2021-12-24 2021-12-24 Sand soil modifier with phosphorus stabilization effect and preparation method thereof Pending CN114149281A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202111597984.2A CN114149281A (en) 2021-12-24 2021-12-24 Sand soil modifier with phosphorus stabilization effect and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202111597984.2A CN114149281A (en) 2021-12-24 2021-12-24 Sand soil modifier with phosphorus stabilization effect and preparation method thereof

Publications (1)

Publication Number Publication Date
CN114149281A true CN114149281A (en) 2022-03-08

Family

ID=80452163

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202111597984.2A Pending CN114149281A (en) 2021-12-24 2021-12-24 Sand soil modifier with phosphorus stabilization effect and preparation method thereof

Country Status (1)

Country Link
CN (1) CN114149281A (en)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102754540A (en) * 2012-06-26 2012-10-31 辽宁大学 Sandy soil improving method
CN104086328A (en) * 2014-06-10 2014-10-08 凤台县余跃蔬菜专业合作社 A biological organic composite fertilizer specially used for vegetables and fruits and a preparing method thereof
CN104232096A (en) * 2014-05-30 2014-12-24 昆明绿色中迅生物有限公司 Soil conditioner
CN105481603A (en) * 2015-11-26 2016-04-13 四川蓉加川大环保工程咨询设计有限公司 Sandy soil conditioner and preparation method thereof
CN106433654A (en) * 2016-08-19 2017-02-22 李娟� Granulated heavy metal contaminated soil passivation conditioning agent, and application thereof
CN107384418A (en) * 2017-07-18 2017-11-24 成都新柯力化工科技有限公司 A kind of soil fixing restoration of the ecosystem agent and preparation method
CN111574308A (en) * 2020-06-12 2020-08-25 中国热带农业科学院椰子研究所 Special liquid fertilizer for young areca nuts and application method thereof
CN112337033A (en) * 2020-11-24 2021-02-09 内蒙古科技大学 Harmless treatment method of abamectin slag, product and application of product as sandy soil modifier
WO2021073207A1 (en) * 2019-10-17 2021-04-22 西安石油大学 Green plant soil based on high temperature thermal oxidized residue of oily solid waste

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102754540A (en) * 2012-06-26 2012-10-31 辽宁大学 Sandy soil improving method
CN104232096A (en) * 2014-05-30 2014-12-24 昆明绿色中迅生物有限公司 Soil conditioner
CN104086328A (en) * 2014-06-10 2014-10-08 凤台县余跃蔬菜专业合作社 A biological organic composite fertilizer specially used for vegetables and fruits and a preparing method thereof
CN105481603A (en) * 2015-11-26 2016-04-13 四川蓉加川大环保工程咨询设计有限公司 Sandy soil conditioner and preparation method thereof
CN106433654A (en) * 2016-08-19 2017-02-22 李娟� Granulated heavy metal contaminated soil passivation conditioning agent, and application thereof
CN107384418A (en) * 2017-07-18 2017-11-24 成都新柯力化工科技有限公司 A kind of soil fixing restoration of the ecosystem agent and preparation method
WO2021073207A1 (en) * 2019-10-17 2021-04-22 西安石油大学 Green plant soil based on high temperature thermal oxidized residue of oily solid waste
CN111574308A (en) * 2020-06-12 2020-08-25 中国热带农业科学院椰子研究所 Special liquid fertilizer for young areca nuts and application method thereof
CN112337033A (en) * 2020-11-24 2021-02-09 内蒙古科技大学 Harmless treatment method of abamectin slag, product and application of product as sandy soil modifier

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
付登强 等: "硫酸铁改性珍珠岩微粉的磷吸附特性", 《应用化工》 *
贺春凤等: "秸秆-膨润土-PAM改良材料对沙质土壤磷素吸附解吸的影响", 《中国农学通报》 *
邢伟 等: "铁盐除磷技术机理及铁盐混凝剂的研究进展", 《给水排水》 *

Similar Documents

Publication Publication Date Title
AU2020101394A4 (en) Microbial fertilizer with double effects of fertilization and disease-resistance, and preparation method and use thereof
CN102816005B (en) Peanut special microbial fertilizer and production method thereof
CN106590671B (en) Soil conditioner and preparation method and application thereof
CN108503495A (en) Special complete first biological organic fertilizer of a kind of leaf vegetables and preparation method thereof
CN112501072B (en) Crop rhizosphere soil conditioner and preparation method and application thereof
Naveed et al. Relative efficacy of Pseudomonas spp., containing ACC-deaminase for improving growth and yield of maize (Zea mays L.) in the presence of organic fertilizer
CN110950707A (en) Sandy soil conditioner and preparation method thereof
CN114368987A (en) Soil activation type microbial fertilizer and preparation method thereof
CN102040430B (en) Method for producing compound microbial fertilizer with insecticidal effect
CN108191550A (en) A kind of multi-element biological organic soil modified form fertilizer and preparation method thereof
CN112194522B (en) Seaweed rice seedbed conditioner and preparation method thereof
CN109593014A (en) A kind of alkaline land modifying agent and saline and alkali land improvement method based on lake silt
CN102816028B (en) Biological disease prevention type greenhouse vegetable planting fertilizer and preparation method and application thereof
CN110015936B (en) Functional organic fertilizer for improving saline-alkali soil and preparation method thereof
CN105624062B (en) Eupatorium adenophorum organic fertilizer solid microbial inoculum, preparation method and application in organic fertilizer production
CN109233863B (en) Saline-alkali soil conditioner using straw and application thereof
CN114342729B (en) Organic planting method for pecans
CN111587762A (en) Environment-friendly vegetable seedling culture substrate and preparation method thereof
CN114149281A (en) Sand soil modifier with phosphorus stabilization effect and preparation method thereof
CN111819946B (en) Comprehensive improvement method for rice field soil ecological environment
CN115160074A (en) Granular fulvic acid organic fertilizer and preparation method and application thereof
CN116410036A (en) Organic fertilizer and preparation method and application thereof
CN112573951A (en) Method for preparing bio-organic fertilizer by mixing sludge and straw
CN112028692A (en) Special biological organic fertilizer for saline-alkali soil and preparation method thereof
CN112094160A (en) Biological organic fertilizer and preparation method thereof

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination